CN115831752A - Semiconductor device and preparation method thereof - Google Patents
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Abstract
本申请提供了一种半导体器件及其制备方法,该器件包括:第二部分衬底;位于第二部分衬底一侧的空洞层;位于空洞层远离第二部分衬底一侧的纳米片堆叠层;纳米片堆叠层包括多个纳米片形成的叠层;纳米片由半导体材料形成;纳米片形成的叠层构成多个导电沟道;环绕纳米片堆叠层周围的环绕式栅极;源漏极,位于纳米片堆叠层两端;源漏极的材料为掺杂导电元素的半导体材料。从而本申请通过设置空洞层,能够避免底部寄生沟道效应的影响,从而降低泄露电流和栅极电容的影响,能够进一步增加器件的电学性能。能很好的解决堆叠纳米片中自热效应带来的影响。有效的降低了漏致势垒降低效应,提高了亚阈值斜率、开关比等参数。
The present application provides a semiconductor device and a manufacturing method thereof, the device comprising: a second part of the substrate; a cavity layer located on one side of the second part of the substrate; a stack of nanosheets located on the side of the cavity layer away from the second part of the substrate layer; the nanosheet stack layer includes a stack of multiple nanosheets; the nanosheets are formed from a semiconductor material; the stack of nanosheets forms a plurality of conductive channels; wraparound gates around the nanosheet stack; source and drain The electrodes are located at both ends of the nanosheet stack; the material of the source and drain electrodes is a semiconductor material doped with conductive elements. Therefore, by setting the cavity layer in the present application, the influence of the parasitic channel effect at the bottom can be avoided, thereby reducing the influence of leakage current and gate capacitance, and further improving the electrical performance of the device. It can well solve the influence brought by the self-heating effect in the stacked nanosheets. The effect of leakage-induced barrier lowering is effectively reduced, and parameters such as subthreshold slope and on-off ratio are improved.
Description
技术领域technical field
本申请涉及半导体技术领域,特别涉及一种半导体器件及其制备方法。The present application relates to the field of semiconductor technology, in particular to a semiconductor device and a manufacturing method thereof.
背景技术Background technique
随着晶体管特征尺寸的不断微缩,通过不断的引入新材料、新工艺和新结构来提升器件性能,同时降低由于尺寸微缩所带来的短沟道效应的影响。器件的结构经历了由二维的平面CMOS(Complementary Metal Oxide Semiconductor,互补金属氧化物半导体)器件,转变为三维的FinFET(Fin Field-Effect Transistor,鳍式场效应晶体管)结构,到现在主流的Nanowire/Nanosheet纳米线/纳米片环栅晶体管。With the continuous shrinking of the transistor feature size, the device performance is improved through the continuous introduction of new materials, new processes and new structures, while reducing the impact of the short channel effect caused by the shrinking size. The structure of the device has changed from a two-dimensional planar CMOS (Complementary Metal Oxide Semiconductor) device to a three-dimensional FinFET (Fin Field-Effect Transistor, Fin Field-Effect Transistor) structure, and now the mainstream Nanowire /Nanosheet Nanowire/Nanosheet Gate-Round Transistor.
环栅晶体管被认为是3nm技术节点之下中最有希望取代FinFET器件从而实现大规模量产的下一代器件之一。环栅器件有效的增加了Weff(有效栅宽,Effective gatewidth)/footprint(封装大小),提高了栅极对沟道的控制能力,能够有效的抑制短沟道效应,提升器件的电流驱动能力。The gate-all-round transistor is considered to be one of the most promising next-generation devices under the 3nm technology node to replace FinFET devices and achieve mass production. The gate-all-around device effectively increases Weff (Effective gatewidth)/footprint (package size), improves the control ability of the gate to the channel, can effectively suppress the short channel effect, and improve the current driving ability of the device.
目前,Nanosheet-GAAFET(Nanosheet-Gate-all-around Field-EffectTransistor,纳米片环绕栅极场效应晶体管)的研究进展受到了学术界和产业界的广泛关注。通过不断的优化工艺流程和关键工艺,同时基于此结构进行新结构的探索也是新型CMOS器件的热门研究方向。At present, the research progress of Nanosheet-GAAFET (Nanosheet-Gate-all-around Field-Effect Transistor, nanosheet-all-around gate field-effect transistor) has attracted extensive attention from academia and industry. Through continuous optimization of the process flow and key processes, the exploration of new structures based on this structure is also a popular research direction for new CMOS devices.
Nanosheet-GAAFET能够通过叠加纳米片的数量来提高器件的性能。该新型器件结构能够很好的与目前的主流的FinFET工艺相兼容。但由于NSFET(Nanosheet Field-EffectTransistor,纳米片场效应晶体管)和FinFET在其本征沟道下存在着不可避免的寄生沟道,寄生沟道中存在着寄生电容和泄露电流的影响,造成器件电学性能的退化,同时也给晶体管的缩放带来了很大的挑战。由于NSFET的寄生沟道较宽,因此寄生沟道对其影响更为显著。如何降低寄生沟道的影响变成了一个不可忽视的问题。Nanosheet-GAAFET can improve the performance of the device by stacking the number of nanosheets. The novel device structure is well compatible with the current mainstream FinFET process. However, since NSFET (Nanosheet Field-Effect Transistor, Nanosheet Field Effect Transistor) and FinFET have unavoidable parasitic channels under their intrinsic channels, there are parasitic capacitances and leakage currents in the parasitic channels, resulting in poor electrical performance of the device. degradation, but also brings great challenges to the scaling of transistors. Since the parasitic channel of NSFET is wider, the effect of the parasitic channel on it is more significant. How to reduce the influence of the parasitic channel has become a problem that cannot be ignored.
发明内容Contents of the invention
有鉴于此,本申请的目的在于提供一种可以避免底部寄生沟道效应的影响,从而降低泄露电流和栅极电容的影响,能够进一步增加器件的电学性能。In view of this, the purpose of the present application is to provide a method that can avoid the influence of the bottom parasitic channel effect, thereby reducing the influence of leakage current and gate capacitance, and can further increase the electrical performance of the device.
为实现上述目的,本申请有如下技术方案:In order to achieve the above object, the application has the following technical solutions:
第一方面,本申请实施例提供了一种半导体器件的制备方法,包括:In a first aspect, an embodiment of the present application provides a method for manufacturing a semiconductor device, including:
提供初始衬底;providing an initial substrate;
在所述初始衬底中注入惰性气体,退火处理形成空洞层,以将所述初始衬底分为第一部分衬底和第二部分衬底;Injecting an inert gas into the initial substrate, annealing to form a cavity layer, so as to divide the initial substrate into a first part of the substrate and a second part of the substrate;
在所述第一部分衬底与所述空洞层相对的远离所述空洞层的面上,外延生长超晶格叠层;所述超晶格叠层由第一半导体层和第二半导体层交替层叠形成;On the surface of the first part of the substrate opposite to the void layer and away from the void layer, epitaxially grow a superlattice stack; the superlattice stack is alternately stacked by first semiconductor layers and second semiconductor layers form;
刻蚀所述超晶格叠层,形成多个鳍片;Etching the superlattice stack to form a plurality of fins;
在所述鳍片上沉积假栅;depositing a dummy gate on the fin;
刻蚀所述鳍片两端至所述初始衬底表面,在刻蚀后鳍片两端外延生长源漏极,所述源漏极的材料为掺杂导电元素的半导体材料;Etching both ends of the fin to the surface of the initial substrate, and epitaxially growing source and drain at both ends of the fin after etching, the material of the source and drain is a semiconductor material doped with conductive elements;
去除所述假栅,刻蚀掉所述第一半导体层,实现所述第二半导体层纳米片的沟道释放,所述纳米片形成的叠层构成为多个导电沟道;removing the dummy gate, etching away the first semiconductor layer, and realizing the channel release of the nanosheets of the second semiconductor layer, and the stack formed by the nanosheets constitutes a plurality of conductive channels;
形成环绕式栅极,环绕于纳米片堆叠层周围;Forming a wrap-around gate that wraps around the stack of nanosheets;
刻蚀去除所述第一部分衬底。Etching removes the first portion of the substrate.
在一种可能的实现方式中,所述刻蚀去除所述第一部分衬底,包括:In a possible implementation manner, the etching to remove the first part of the substrate includes:
刻蚀形成与所述空洞层相连的至少一个刻蚀通孔,通过所述刻蚀通孔刻蚀去除所述第一部分衬底。Etching forms at least one etching via hole connected to the cavity layer, and etching and removing the first part of the substrate through the etching via hole.
在一种可能的实现方式中,所述刻蚀去除所述第一部分衬底,包括:In a possible implementation manner, the etching to remove the first part of the substrate includes:
利用湿法刻蚀刻蚀去除所述第一部分衬底。The first portion of the substrate is etched away using wet etching.
在一种可能的实现方式中,在刻蚀去除所述第一部分衬底之后,还包括:In a possible implementation manner, after removing the first part of the substrate by etching, further include:
将介质常数小于或等于预设阈值的气体和/或液体介质填充所述第一部分衬底和所述空洞层。Filling the first part of the substrate and the cavity layer with a gas and/or liquid medium having a dielectric constant less than or equal to a preset threshold.
在一种可能的实现方式中,所述刻蚀所述超晶格叠层,形成多个鳍片,包括:In a possible implementation manner, the etching the superlattice stack to form a plurality of fins includes:
在所述超晶格叠层上设置第一侧墙;以所述第一侧墙为掩膜刻蚀所述超晶格叠层,形成所述多个鳍片。A first sidewall is set on the superlattice stack; and the superlattice stack is etched using the first sidewall as a mask to form the plurality of fins.
第二方面,本申请实施例提供了一种半导体器件,包括:In a second aspect, an embodiment of the present application provides a semiconductor device, including:
第二部分衬底;the second part of the substrate;
位于所述第二部分衬底一侧的空洞层;a cavity layer located on one side of the second portion of the substrate;
位于所述空洞层远离所述第二部分衬底一侧的纳米片堆叠层;所述纳米片堆叠层包括多个纳米片形成的叠层;所述纳米片由半导体材料形成;所述纳米片形成的叠层构成多个导电沟道;A nanosheet stack layer located on a side of the cavity layer away from the second part of the substrate; the nanosheet stack layer includes a stack formed by a plurality of nanosheets; the nanosheet is formed of a semiconductor material; the nanosheet The stack formed constitutes a plurality of conductive channels;
环绕所述纳米片堆叠层周围的环绕式栅极;a wraparound gate surrounding the nanosheet stack;
源漏极,位于所述纳米片堆叠层两端;所述源漏极的材料为掺杂导电元素的半导体材料。The source and drain electrodes are located at both ends of the nanosheet stack layer; the material of the source and drain electrodes is a semiconductor material doped with conductive elements.
在一种可能的实现方式中,还包括:位于所述空洞层和所述环绕式栅极之间的浅沟槽隔离。In a possible implementation manner, the method further includes: shallow trench isolation between the cavity layer and the surrounding gate.
在一种可能的实现方式中,还包括:位于所述源漏极远离所述空洞层一侧的隔离层。In a possible implementation manner, it further includes: an isolation layer located on a side of the source and drain away from the cavity layer.
在一种可能的实现方式中,还包括:位于所述隔离层和所述环绕式栅极之间的第二侧墙。In a possible implementation manner, the method further includes: a second sidewall located between the isolation layer and the surrounding gate.
在一种可能的实现方式中,所述器件的类型包括:正沟道纳米片环绕栅极场效应晶体管或负沟道纳米片环绕栅极场效应晶体管。In a possible implementation manner, the type of the device includes: a positive channel nanosheet surrounding gate field effect transistor or a negative channel nanosheet surrounding gate field effect transistor.
与现有技术相比,本申请具有以下有益效果:Compared with the prior art, the present application has the following beneficial effects:
本申请实施例提供了一种半导体器件及其制备方法,该器件包括:第二部分衬底;位于第二部分衬底一侧的空洞层;位于空洞层远离第二部分衬底一侧的纳米片堆叠层;纳米片堆叠层包括多个纳米片形成的叠层;纳米片由半导体材料形成;纳米片形成的叠层构成多个导电沟道;环绕纳米片堆叠层周围的环绕式栅极;源漏极,位于纳米片堆叠层两端;源漏极的材料为掺杂导电元素的半导体材料。从而本申请通过设置空洞层,能够避免底部寄生沟道效应的影响,从而降低泄露电流和栅极电容的影响,能够进一步增加器件的电学性能。能很好的解决堆叠纳米片中自热效应带来的影响。有效的降低了漏致势垒降低效应,提高了亚阈值斜率、开关比等参数。An embodiment of the present application provides a semiconductor device and a manufacturing method thereof, the device comprising: a second part of the substrate; a cavity layer located on the side of the second part of the substrate; a nanometer layer located on the side of the cavity layer away from the second part of the substrate The sheet stack layer; the nanosheet stack layer includes a stack formed by a plurality of nanosheets; the nanosheet is formed of a semiconductor material; the stack formed by the nanosheet forms a plurality of conductive channels; a wrap-around gate around the nanosheet stack layer; The source and drain electrodes are located at both ends of the nanosheet stack; the material of the source and drain electrodes is a semiconductor material doped with conductive elements. Therefore, by setting the cavity layer in the present application, the influence of the parasitic channel effect at the bottom can be avoided, thereby reducing the influence of leakage current and gate capacitance, and further improving the electrical performance of the device. It can well solve the influence brought by the self-heating effect in the stacked nanosheets. The effect of leakage-induced barrier lowering is effectively reduced, and parameters such as subthreshold slope and on-off ratio are improved.
附图说明Description of drawings
为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其它的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present application or the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are For some embodiments of the present application, those skilled in the art can also obtain other drawings based on these drawings without creative effort.
图1示出了本申请实施例提供的一种半导体器件的制备方法的流程图;FIG. 1 shows a flow chart of a method for manufacturing a semiconductor device provided in an embodiment of the present application;
图2-13示出了本申请实施例提供的一种半导体器件的制备过程中的各结构的剖视图;2-13 show cross-sectional views of various structures in the manufacturing process of a semiconductor device provided by the embodiment of the present application;
图14示出了本申请实施例提供的一种半导体器件的剖视图;FIG. 14 shows a cross-sectional view of a semiconductor device provided by an embodiment of the present application;
图15示出了本申请实施例提供的一种半导体器件的俯视图。FIG. 15 shows a top view of a semiconductor device provided by an embodiment of the present application.
具体实施方式Detailed ways
为使本申请的上述目的、特征和优点能够更加明显易懂,下面结合附图对本申请的具体实施方式做详细的说明。In order to make the above-mentioned purpose, features and advantages of the present application more obvious and understandable, the specific implementation manners of the present application will be described in detail below in conjunction with the accompanying drawings.
在下面的描述中阐述了很多具体细节以便于充分理解本申请,但是本申请还可以采用其它不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本申请内涵的情况下做类似推广,因此本申请不受下面公开的具体实施例的限制。In the following description, a lot of specific details are set forth in order to fully understand the application, but the application can also be implemented in other ways different from those described here, and those skilled in the art can do it without violating the content of the application. By analogy, the present application is therefore not limited by the specific embodiments disclosed below.
正如背景技术中的描述,随着晶体管特征尺寸的不断微缩,通过不断的引入新材料、新工艺和新结构来提升器件性能,同时降低由于尺寸微缩所带来的短沟道效应的影响。器件的结构经历了由二维的平面CMOS(Complementary Metal Oxide Semiconductor,互补金属氧化物半导体)器件,转变为三维的FinFET(Fin Field-Effect Transistor,鳍式场效应晶体管)结构,到现在主流的Nanowire/Nanosheet纳米线/纳米片环栅晶体管。As described in the background technology, as the feature size of transistors continues to shrink, device performance is improved by continuously introducing new materials, new processes and new structures, while reducing the impact of the short channel effect caused by size shrinking. The structure of the device has changed from a two-dimensional planar CMOS (Complementary Metal Oxide Semiconductor) device to a three-dimensional FinFET (Fin Field-Effect Transistor, Fin Field-Effect Transistor) structure, and now the mainstream Nanowire /Nanosheet nanowire/nanosheet gate-around transistor.
环栅晶体管被认为是3nm技术节点之下中最有希望取代FinFET器件从而实现大规模量产的下一代器件之一。环栅器件有效的增加了Weff(有效栅宽,Effective gatewidth)/footprint(封装大小),提高了栅极对沟道的控制能力,能够有效的抑制短沟道效应,提升器件的电流驱动能力。The gate-all-round transistor is considered to be one of the most promising next-generation devices under the 3nm technology node to replace FinFET devices and achieve mass production. The gate-all-around device effectively increases Weff (Effective gatewidth)/footprint (package size), improves the control ability of the gate to the channel, can effectively suppress the short channel effect, and improve the current driving ability of the device.
目前,Nanosheet-GAAFET(Nanosheet-Gate-all-around Field-EffectTransistor,纳米片环绕栅极场效应晶体管)的研究进展受到了学术界和产业界的广泛关注。通过不断的优化工艺流程和关键工艺,同时基于此结构进行新结构的探索也是新型CMOS器件的热门研究方向。At present, the research progress of Nanosheet-GAAFET (Nanosheet-Gate-all-around Field-Effect Transistor, nanosheet-all-around gate field-effect transistor) has attracted extensive attention from academia and industry. Through continuous optimization of the process flow and key processes, the exploration of new structures based on this structure is also a popular research direction for new CMOS devices.
Nanosheet-GAAFET能够通过叠加纳米片的数量来提高器件的性能。该新型器件结构能够很好的与目前的主流的FinFET工艺相兼容。但由于NSFET(Nanosheet Field-EffectTransistor,纳米片场效应晶体管)和FinFET在其本征沟道下存在着不可避免的寄生沟道,寄生沟道中存在着寄生电容和泄露电流的影响,造成器件电学性能的退化,同时也给晶体管的缩放带来了很大的挑战。由于NSFET的寄生沟道较宽,因此寄生沟道对其影响更为显著。如何降低寄生沟道的影响变成了一个不可忽视的问题。Nanosheet-GAAFET can improve the performance of the device by stacking the number of nanosheets. The novel device structure is well compatible with the current mainstream FinFET process. However, since NSFET (Nanosheet Field-Effect Transistor, Nanosheet Field Effect Transistor) and FinFET have unavoidable parasitic channels under their intrinsic channels, there are parasitic capacitances and leakage currents in the parasitic channels, resulting in poor electrical performance of the device. degradation, but also brings great challenges to the scaling of transistors. Since the parasitic channel of NSFET is wider, the effect of the parasitic channel on it is more significant. How to reduce the influence of the parasitic channel has become a problem that cannot be ignored.
此外,如何有效的降低漏致势垒降低效应,提高亚阈值斜率、开关比等参数,也是本领域需要解决的技术问题。In addition, how to effectively reduce the leakage-induced barrier lowering effect and improve parameters such as subthreshold slope and on-off ratio are also technical problems to be solved in this field.
为了解决以上技术问题,本申请实施例提供了一种半导体器件及其制备方法,该器件包括:第二部分衬底;位于第二部分衬底一侧的空洞层;位于空洞层远离第二部分衬底一侧的纳米片堆叠层;纳米片堆叠层包括多个纳米片形成的叠层;纳米片由半导体材料形成;纳米片形成的叠层构成多个导电沟道;环绕纳米片堆叠层周围的环绕式栅极;源漏极,位于纳米片堆叠层两端;源漏极的材料为掺杂导电元素的半导体材料。从而本申请通过设置空洞层,能够避免底部寄生沟道效应的影响,从而降低泄露电流和栅极电容的影响,能够进一步增加器件的电学性能。能很好的解决堆叠纳米片中自热效应带来的影响。有效的降低了漏致势垒降低效应,提高了亚阈值斜率、开关比等参数。In order to solve the above technical problems, an embodiment of the present application provides a semiconductor device and a manufacturing method thereof. The device includes: a second part of the substrate; a cavity layer located on one side of the second part of the substrate; A stack of nanosheets on one side of the substrate; the stack of nanosheets includes a stack of multiple nanosheets; the nanosheet is formed of a semiconductor material; the stack of nanosheets forms a plurality of conductive channels; surrounding the stack of nanosheets The surrounding gate; the source and drain are located at both ends of the nanosheet stack; the material of the source and drain is a semiconductor material doped with conductive elements. Therefore, by setting the cavity layer in the present application, the influence of the parasitic channel effect at the bottom can be avoided, thereby reducing the influence of leakage current and gate capacitance, and further improving the electrical performance of the device. It can well solve the influence brought by the self-heating effect in the stacked nanosheets. The effect of leakage-induced barrier lowering is effectively reduced, and parameters such as subthreshold slope and on-off ratio are improved.
参见图1所示,为本申请实施例提供的一种半导体器件的制备方法的流程图,包括:Referring to Figure 1, it is a flow chart of a method for manufacturing a semiconductor device provided by the embodiment of the present application, including:
S101:提供初始衬底。S101: providing an initial substrate.
在本申请实施例中,参见图2所示,首先可以准备好初始衬底0,初始衬底0可以为半导体衬底,例如可以为Si衬底、Ge衬底、SiGe衬底、SOI(绝缘体上硅,Silicon OnInsulator)或GOI(绝缘体上锗,Germanium On Insulator)等。在其它实施例中,所述半导体衬底还可以为包括其它元素半导体或化合物半导体的衬底,例如GaAs、InP或SiC等,还可以为叠层结构,例如Si/SiGe等,还可以为其它外延结构,例如SGOI(绝缘体上锗硅)等。在本实施例中,初始衬底0为体硅衬底。In the embodiment of the present application, as shown in FIG. 2, the
具体的,初始衬底0是适合于形成一个或多个半导体器件的半导体晶圆的部分,当采用体硅衬底,在体硅衬底中通过注入杂质,扩散,退火后形成高掺杂阱区,达到所需阱深。其中对P(positive,正)型FET,上述高掺杂阱区为N阱,注入的杂质为n型杂质离子,比如磷(P)离子;其中对N(negative,负)型FET,上述高掺杂阱区为P阱,注入的杂质为p型杂质离子,比如硼(B)离子。Specifically, the
S102:在所述初始衬底中注入惰性气体,退火处理形成空洞层,以将所述初始衬底分为第一部分衬底和第二部分衬底。S102: Injecting an inert gas into the initial substrate, and annealing to form a cavity layer, so as to divide the initial substrate into a first partial substrate and a second partial substrate.
在本申请实施例中,参见图3所示,可以在初始衬底中注入惰性气体,例如氨气,在高温惰性气体环境中退火,以形成空洞层1,以将初始衬底分为第一部分衬底0’和第二部分衬底0”。In the embodiment of the present application, as shown in FIG. 3, an inert gas, such as ammonia, can be injected into the initial substrate, and annealed in a high-temperature inert gas environment to form a
在第一部分衬底0’表面生长有二氧化硅层11。A
S103:在所述第一部分衬底与所述空洞层相对的远离所述空洞层的面上,外延生长超晶格叠层;所述超晶格叠层由第一半导体层和第二半导体层交替层叠形成。S103: Epitaxially grow a superlattice stack on the surface of the first part of the substrate opposite to the void layer and away from the void layer; the superlattice stack consists of a first semiconductor layer and a second semiconductor layer Alternate layers are formed.
在本申请实施例中,参见图4所示,去除第一部分衬底0’表面的二氧化硅(SiO2),并在第一部分衬底0’上外延生长出多个周期的第一半导体层51/第二半导体层52的超晶格结构的叠层;超晶格结构中的第一半导体层51厚度可以设置为3-100nm,第二半导体层52厚度可以设置为1-50nm,最终生产出的厚度会直接决定纳米片沟道的高度以及静电性能。In the embodiment of the present application, as shown in FIG. 4 , the silicon dioxide (SiO2) on the surface of the first part of the substrate 0' is removed, and multiple periods of the
其中,上述第一半导体层51/第二半导体层52超晶格可以为Si/SiGe叠层、SiGe/Si叠层、SiGe/Ge叠层、Ge/SiGe叠层、Si/Ge叠层或Ge/Si叠层。Wherein, the above-mentioned
S104:刻蚀所述超晶格叠层,形成多个鳍片。S104: Etching the superlattice stack to form a plurality of fins.
在本申请实施例中,参见图5所示,在一种可能的实现方式中,可以在在超晶格叠层上设置第一侧墙61;以第一侧墙61为掩膜刻蚀超晶格叠层,形成多个鳍片。In the embodiment of the present application, as shown in FIG. 5 , in a possible implementation manner,
具体的,可以采用自对准的侧墙转移(SIT,Self aligned sidewall transfer)工艺形成纳米尺度第一侧墙61器件,第一侧墙61的材料可以为氮化硅(SiNX),具体形成过程为:在超晶格叠层上覆盖一层牺牲层62,牺牲层具体可为多晶硅(PolySi,p-si)或非晶硅(a-si),刻蚀掉部分牺牲层62,积淀氮化硅(SiNx)层,再采用各向异性刻蚀,刻蚀掉剩余的牺牲层62,使其仅保留在超晶格叠层上多道周期性氮化硅(SiNx)第一侧墙(spacers)61,氮化硅(SiNx)第一侧墙61在光刻中起到硬掩膜(Hard Mask)的作用。Specifically, a nanoscale
参见图6所示,可以通过刻蚀工艺把外延生长的超晶格叠层做成多个周期分布的鳍片。As shown in FIG. 6 , the epitaxially grown superlattice stack can be formed into a plurality of periodically distributed fins through an etching process.
具体的,以第一侧墙61为掩膜进行刻蚀,形成带有超晶格叠层结构的鳍片。鳍片上部为超晶格叠层形成的导电沟道区,下部为第一部分衬底0’,形成如图6所示的鳍片。Specifically, etching is performed using the
该鳍片不仅包括超晶格叠层结构,还包括深入到衬底的单晶硅结构。刻蚀工艺可以为干法刻蚀工艺,在一个实施例中可采用反应离子刻蚀(Reactive ion etching,RIE)。鳍片将用以形成一或多个n型场效晶体管以及/或p型场效晶体管的水平纳米片。The fin includes not only a superlattice stack structure, but also a single crystal silicon structure that penetrates deep into the substrate. The etching process may be a dry etching process, and in one embodiment, reactive ion etching (Reactive ion etching, RIE) may be used. The fins will be used to form horizontal nanosheets of one or more n-FETs and/or p-FETs.
需要说明的是,尽管图6示出了一个鳍片,应能理解本申请实施例可使用任何合适数量与形态的鳍片。鳍片的高度大约10nm-400nm,宽度大约为1-100nm。It should be noted that although FIG. 6 shows one fin, it should be understood that any suitable number and shape of fins can be used in the embodiments of the present application. The height of the fin is about 10nm-400nm, and the width is about 1-100nm.
如图7所示,刻蚀去除第一侧墙61,然后可以在在相邻的两个鳍片之间形成浅沟槽隔离(shallow trench isolation,STI)区7。首先进行介电绝缘材料沉积,然后进行平坦化,例如用CMP(chemical mechanical polish,化学机械研磨)工艺,然后进行介电绝缘材料选择性回刻,露出三维的鳍片结构,由此邻近于鳍片以形成浅沟槽隔离区7。As shown in FIG. 7 , the
浅沟槽隔离区7其上表面一般和鳍片中超晶格叠层结构与衬底单晶硅的界面齐平,也可高于或低于该界面水平线。浅沟槽隔离区7可由合适的介电材料所形成,如二氧化硅(SiO2)、氮化硅(SiNx)等。浅沟槽隔离区7的作用是隔开相邻鳍片上的晶体管。浅沟槽隔离区7使得超晶格叠层的最底层的第一半导体层51露出。The upper surface of the shallow
S105:在所述鳍片上沉积假栅。S105: Depositing a dummy gate on the fin.
在本申请实施例中,参见图8所示,可以在露出的鳍片上、与鳍线相垂直的方向(即B-B’方向)上形成假栅8,可以采用热氧化、化学气相沉积、溅射(sputtering)等工艺形成假栅8。假栅8横跨鳍片上部的超晶格叠层,多个假栅8沿着鳍线方向周期性分布。In the embodiment of the present application, as shown in FIG. 8 ,
假栅8所使用的材料可以是多晶硅(PolySi,p-si)或非晶硅(a-si)。The material used for the
S106:刻蚀所述鳍片两端至所述初始衬底表面,在刻蚀后鳍片两端外延生长源漏极,所述源漏极的材料为掺杂导电元素的半导体材料。S106: Etching both ends of the fin to the surface of the initial substrate, and epitaxially growing source and drain at both ends of the fin after etching, the material of the source and drain is a semiconductor material doped with conductive elements.
在本申请实施例中,参见图9所示,可以在每个假栅8两侧沉积氮化硅或掺杂氧化硅材料并进行刻蚀,形成第二侧墙9。In the embodiment of the present application, as shown in FIG. 9 , silicon nitride or doped silicon oxide material may be deposited on both sides of each
然后,参见图10所示,可以刻蚀鳍片两端至初始衬底表面,在刻蚀后鳍片两端外延生长源漏极41/42,源漏极41/42的材料为掺杂导电元素的半导体材料。Then, as shown in FIG. 10, the two ends of the fin can be etched to the initial substrate surface, and the source and drain
具体的,可以对沉积SiGe或Si等半导体材料并进行重掺杂,对于P型半导体器件采用掺杂元素为B或者BF2,对于N型半导体器件采用掺杂元素为P/As,形成重掺杂源漏极41/42。对源漏极41/42采用低温快速热退火激活杂质。Specifically, semiconductor materials such as SiGe or Si can be deposited and heavily doped. For P-type semiconductor devices, the doping element is B or BF2, and for N-type semiconductor devices, the doping element is P/As to form heavy doping. Source and drain 41/42. Low-temperature rapid thermal annealing is used for the source and drain
S107:去除所述假栅,刻蚀掉所述第一半导体层,实现所述第二半导体层纳米片的沟道释放,所述纳米片形成的叠层构成为多个导电沟道。S107: removing the dummy gate, etching away the first semiconductor layer, and realizing channel release of the nanosheets of the second semiconductor layer, and the stack formed by the nanosheets constitutes a plurality of conductive channels.
在本申请实施例中,参见图11所示,可以在源漏极41/42上淀积隔离层10,隔离层10的材料可以为二氧化硅等氧化物。In the embodiment of the present application, as shown in FIG. 11 , an
然后,通过选择性刻蚀或腐蚀工艺,将前述的多晶硅(PolySi,p-si)或非晶Then, through a selective etching or etching process, the aforementioned polysilicon (PolySi, p-si) or amorphous
硅(a-si)形成的假栅8刻蚀或腐蚀掉,即去掉假栅8。The
随后,如图12,选择性刻蚀超晶格叠层中的第一半导体层51,进行纳米片2(nanosheet)沟道释放。对鳍片露出的导电沟道区进行刻蚀/腐蚀,去除每层第一半导体层51,第一半导体层51即为牺牲层,对第二半导体层形成的纳米片2进行释放。Subsequently, as shown in FIG. 12 , the
纳米片2宽度范围为1-100nm,厚度范围为1-50nm,各纳米片2之间的间隔范围为3-100nm。The width range of the
一种实施例,对于P型和N型FET,牺牲层均为SiGe层,选择性移除SiGe层,保留Si层,形成Si水平叠层纳米片堆栈器件。选择性移除工艺中可使用相对于Si以较快的速率选择性地刻蚀SiGe的刻蚀剂。在一个实施例中,常规湿法工艺,各向同性腐蚀牺牲层进行纳米片沟道释放,从而形成纳米片导电沟道。In one embodiment, for both P-type and N-type FETs, the sacrificial layers are both SiGe layers, and the SiGe layer is selectively removed while the Si layer is retained to form a Si horizontally stacked nanosheet stack device. An etchant that selectively etches SiGe at a faster rate relative to Si may be used in the selective removal process. In one embodiment, the conventional wet process is used to isotropically etch the sacrificial layer to release the nanosheet channel, thereby forming the nanosheet conductive channel.
另外一种实施例,对于P型和N型FET,分别进行沟道释放。In another embodiment, for P-type and N-type FETs, channel release is performed separately.
对于P型FET,牺牲层为Si层,选择性移除Si层,保留SiGe层,形成SiGe水平叠层纳米片堆栈器件。选择性移除工艺中可使用相对于SiGe以较快的速率选择性地刻蚀Si的刻蚀剂。在一个实施例中,常规湿法工艺,各向同性腐蚀牺牲层进行纳米片沟道释放,从而形成纳米片导电沟道。For a P-type FET, the sacrificial layer is a Si layer, the Si layer is selectively removed, and the SiGe layer is retained to form a SiGe horizontally stacked nanosheet stack device. An etchant that selectively etches Si at a faster rate relative to SiGe may be used in the selective removal process. In one embodiment, the conventional wet process is used to isotropically etch the sacrificial layer to release the nanosheet channel, thereby forming the nanosheet conductive channel.
对于N型FET,牺牲层为SiGe层,选择性移除SiGe层,保留Si层,形成Si水平叠层纳米片堆栈器件。选择性移除工艺中可使用相对于Si以较快的速率选择性地刻蚀SiGe的刻蚀剂。在一个实施例中,常规湿法工艺,各向同性腐蚀牺牲层进行纳米片沟道释放,从而形成纳米片导电沟道。第二半导体纳米层片2叠层,形成了纳米片堆叠层。For N-type FETs, the sacrificial layer is a SiGe layer, the SiGe layer is selectively removed, and the Si layer is retained to form a Si horizontally stacked nanosheet stack device. An etchant that selectively etches SiGe at a faster rate relative to Si may be used in the selective removal process. In one embodiment, the conventional wet process is used to isotropically etch the sacrificial layer to release the nanosheet channel, thereby forming the nanosheet conductive channel. The
接着,如图12所示,沉积高K介质层12,使得高K介质层12环绕纳米片堆叠层表面,且覆盖第二侧墙9表面。高K介质层12可具有高于约6.0的介电常数,所述高k介质层12材料可采用为HfO2、HfSiOx、HfON、HfSiON、HfAlOx、HfLaOx、Al2O3、ZrO2、ZrSiOx、Ta2O5或La2O3的一种或几种的组合。Next, as shown in FIG. 12 , a high-
S108:形成环绕式栅极,环绕于纳米片堆叠层周围。S108 : forming a wrap-around gate to wrap around the nanosheet stack.
在本申请实施例中,参见图13所示,在假栅8所形成的空间、高K介质层12外沉积金属栅3,形成多层高K/金属栅结构。In the embodiment of the present application, as shown in FIG. 13 , the
金属栅3包含覆盖层、阻挡层、功函数层、填充层多层结构。可通过选择光刻和腐蚀形成不同有效功函数的膜层结构,以调控器件阈值。一般利用化学气相沉积、物理气相沉积等工艺形成金属栅3。The
金属栅3材料为TaC、TaN、TiN、TaTbN、TaErN、TaYbN、TaSiN、HfSiN、MoSiN、RuTax、NiTax,MoNx、TiSiN、TiCN、TaAlC、TiAl、TiAlC、TiAlN、PtSix、Ni3Si、Pt、Ru、Ir、Mo、Ti、Al、W、Co、Cr、Au、Cu、Ag、HfRu或RuOx的一种或几种的组合。
如图13中所示出,金属栅3填充了假栅8去除后的空间。其后进行高K介质层12、金属栅3结构进行化学机械抛光,使其平坦化,并去除暴露于假栅8空间之外介质层表面的多余高K介质层12、金属栅3材料。其中,高K介质层12和金属栅极3填充在原第一半导体层51的空间形成环栅结构,即环绕式栅极,其环绕于纳米片2周围。As shown in FIG. 13 , the
S109:刻蚀去除所述第一部分衬底。S109: Etching and removing the first part of the substrate.
在本申请实施例中,参见图15所示,为本申请实施例提供的一种半导体器件的俯视图,包括器件区、湿法腐蚀Si衬底区、刻蚀通孔和Si衬底区。In the embodiment of the present application, see FIG. 15 , which is a top view of a semiconductor device provided in the embodiment of the present application, including a device region, a wet-etched Si substrate region, an etched via hole, and an Si substrate region.
A-A’为沿鳍线方向、鳍片的中心线,B-B’线为垂直鳍线方向、鳍片的中心线,附图2-14均是以A-A’、B-B’两条线的剖面示意图。A-A' is the direction along the fin line and the center line of the fin, and the line BB' is the direction perpendicular to the fin line and the center line of the fin. Figures 2-14 are based on A-A' and BB' Schematic cross-section of two lines.
参见图14所示,可以刻蚀形成与空洞层相连的至少一个刻蚀通孔,通过刻蚀通孔刻蚀去除所述第一部分衬底。可选的,可以利用湿法刻蚀刻蚀去除第一部分衬底。Referring to FIG. 14 , at least one etching via hole connected to the void layer may be formed by etching, and the first part of the substrate is etched and removed through the etching via hole. Optionally, the first part of the substrate may be removed by wet etching.
举例来说,可以通过调节Si衬底的与SiGe和SiO2的刻蚀选择比,采用湿法腐蚀进行选择性去除体硅材料,即第一部分衬底。即通过增加刻蚀版图,形成从顶部至底部的刻蚀通孔,接着利用湿法腐蚀选择性去除sub-Fin寄生沟道和STI下方的体硅材料。For example, wet etching can be used to selectively remove the bulk silicon material, that is, the first part of the substrate, by adjusting the etching selectivity ratio of the Si substrate to SiGe and SiO2. That is, by increasing the etching layout, etching via holes from top to bottom are formed, and then wet etching is used to selectively remove the sub-Fin parasitic channel and the bulk silicon material under the STI.
本申请实施例通过增加了SON(silicon on nothing)衬底结构,能够加快湿法腐蚀选择性去除的速度。通过控制湿法腐蚀的时间和速率,从而控制去除体硅材料的厚度。In the embodiment of the present application, by adding a SON (silicon on nothing) substrate structure, the speed of selective removal by wet etching can be accelerated. By controlling the time and rate of wet etching, the thickness of bulk silicon material removed can be controlled.
可选的,在刻蚀去除所述第一部分衬底之后,还包括:Optionally, after etching and removing the first part of the substrate, further comprising:
将介质常数小于或等于预设阈值的气体和/或液体介质填充第一部分衬底和空洞层,能很好的解决堆叠纳米片中自热效应带来的影响。Filling the first part of the substrate and the void layer with a gas and/or liquid medium with a dielectric constant less than or equal to a preset threshold can well solve the impact of the self-heating effect in the stacked nanosheets.
本申请实施例在SON衬底上结合常规Nanasheet-GAAFET制备方法,通过形成了SON衬底结构来降低底部寄生沟道效应带来的影响,能够增加器件的电学性能。The embodiment of the present application combines the conventional Nanasheet-GAAFET preparation method on the SON substrate to reduce the influence of the parasitic channel effect at the bottom by forming the SON substrate structure, and can increase the electrical performance of the device.
本申请提供了一种半导体器件的制备方法,利用该方法制备的器件包括:第二部分衬底;位于第二部分衬底一侧的空洞层;位于空洞层远离第二部分衬底一侧的纳米片堆叠层;纳米片堆叠层包括多个纳米片形成的叠层;纳米片由半导体材料形成;纳米片形成的叠层构成多个导电沟道;环绕纳米片堆叠层周围的环绕式栅极;源漏极,位于纳米片堆叠层两端;源漏极的材料为掺杂导电元素的半导体材料。从而本申请通过设置空洞层,能够避免底部寄生沟道效应的影响,从而降低泄露电流和栅极电容的影响,能够进一步增加器件的电学性能。能很好的解决堆叠纳米片中自热效应带来的影响。有效的降低了漏致势垒降低效应,提高了亚阈值斜率、开关比等参数。The present application provides a method for manufacturing a semiconductor device. The device prepared by the method includes: a second part of the substrate; a cavity layer on the side of the second part of the substrate; Nanosheet stack; the nanosheet stack includes a stack of nanosheets; the nanosheets are formed from a semiconductor material; the stack of nanosheets forms a plurality of conductive channels; a wraparound gate around the nanosheet stack ; The source and drain electrodes are located at both ends of the nanosheet stack; the material of the source and drain electrodes is a semiconductor material doped with conductive elements. Therefore, by setting the cavity layer in the present application, the influence of the parasitic channel effect at the bottom can be avoided, thereby reducing the influence of leakage current and gate capacitance, and further improving the electrical performance of the device. It can well solve the influence brought by the self-heating effect in the stacked nanosheets. The effect of leakage-induced barrier lowering is effectively reduced, and parameters such as subthreshold slope and on-off ratio are improved.
示例性器件Exemplary device
参见图14所示,为本申请实施例提供的一种半导体器件的示意图,包括:Referring to FIG. 14, it is a schematic diagram of a semiconductor device provided by the embodiment of the present application, including:
第二部分衬底0”;
位于所述第二部分衬底0”一侧的空洞层1;A
位于所述空洞层1远离所述第二部分衬底0”一侧的纳米片堆叠层;所述纳米片堆叠层包括多个纳米片2形成的叠层;所述纳米片2由半导体材料形成;所述纳米片2形成的叠层构成多个导电沟道;The nanosheet stack layer located on the side of the
环绕所述纳米片2堆叠层周围的环绕式栅极3;Surrounding the
源漏极41/42,位于所述纳米片堆叠层两端;所述源漏极41/42的材料为掺杂导电元素的半导体材料。The source and drain
在一种可能的实现方式中,还包括:位于所述空洞层1和所述环绕式栅极3之间的浅沟槽隔离7。In a possible implementation manner, it further includes: a
在一种可能的实现方式中,还包括:位于所述源漏极41/42远离所述空洞层1一侧的隔离层10。In a possible implementation manner, it further includes: an
在一种可能的实现方式中,还包括:位于所述隔离层10和所述环绕式栅极3之间的第二侧墙9。In a possible implementation manner, it further includes: a
在一种可能的实现方式中,所述器件的类型包括:正沟道纳米片环绕栅极场效应晶体管或负沟道纳米片环绕栅极场效应晶体管。In a possible implementation manner, the type of the device includes: a positive channel nanosheet surrounding gate field effect transistor or a negative channel nanosheet surrounding gate field effect transistor.
本申请实施例提供了一种半导体器件,该器件包括:第二部分衬底;位于第二部分衬底一侧的空洞层;位于空洞层远离第二部分衬底一侧的纳米片堆叠层;纳米片堆叠层包括多个纳米片形成的叠层;纳米片由半导体材料形成;纳米片形成的叠层构成多个导电沟道;环绕纳米片堆叠层周围的环绕式栅极;源漏极,位于纳米片堆叠层两端;源漏极的材料为掺杂导电元素的半导体材料。从而本申请通过设置空洞层,能够避免底部寄生沟道效应的影响,从而降低泄露电流和栅极电容的影响,能够进一步增加器件的电学性能。能很好的解决堆叠纳米片中自热效应带来的影响。有效的降低了漏致势垒降低效应,提高了亚阈值斜率、开关比等参数。An embodiment of the present application provides a semiconductor device, the device comprising: a second part of the substrate; a cavity layer located on one side of the second part of the substrate; a nanosheet stack layer located on the side of the cavity layer away from the second part of the substrate; The stack of nanosheets includes a stack of multiple nanosheets; the nanosheets are formed of semiconductor materials; the stack of nanosheets forms a plurality of conductive channels; the surrounding gate around the stack of nanosheets; the source and drain, Located at both ends of the nanosheet stack; the source and drain materials are semiconductor materials doped with conductive elements. Therefore, by setting the cavity layer in the present application, the influence of the parasitic channel effect at the bottom can be avoided, thereby reducing the influence of leakage current and gate capacitance, and further improving the electrical performance of the device. It can well solve the influence brought by the self-heating effect in the stacked nanosheets. The effect of leakage-induced barrier lowering is effectively reduced, and parameters such as subthreshold slope and on-off ratio are improved.
本说明书中的各个实施例均采用递进的方式描述,各个实施例之间相同相似的部分互相参见即可,每个实施例重点说明的都是与其它实施例的不同之处。尤其,对于器件实施例而言,由于其基本相似于方法实施例,所以描述得比较简单,相关之处参见方法实施例的部分说明即可。Each embodiment in this specification is described in a progressive manner, the same and similar parts of each embodiment can be referred to each other, and each embodiment focuses on the differences from other embodiments. In particular, as for the device embodiment, since it is basically similar to the method embodiment, the description is relatively simple, and for relevant parts, please refer to part of the description of the method embodiment.
以上所述仅是本申请的优选实施方式,虽然本申请已以较佳实施例披露如上,然而并非用以限定本申请。任何熟悉本领域的技术人员,在不脱离本申请技术方案范围情况下,都可利用上述揭示的方法和技术内容对本申请技术方案做出许多可能的变动和修饰,或修改为等同变化的等效实施例。因此,凡是未脱离本申请技术方案的内容,依据本申请的技术实质对以上实施例所做的任何的简单修改、等同变化及修饰,均仍属于本申请技术方案保护的范围内。The above descriptions are only the preferred embodiments of the present application. Although the present application has been disclosed as above with preferred embodiments, it is not intended to limit the present application. Any person familiar with the art, without departing from the scope of the technical solution of the application, can use the methods and technical content disclosed above to make many possible changes and modifications to the technical solution of the application, or to modify the equivalent of equivalent changes Example. Therefore, any simple modifications, equivalent changes and modifications made to the above embodiments based on the technical essence of the present application that do not deviate from the content of the technical solution of the present application still fall within the protection scope of the technical solution of the present application.
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