CN115746875A - Water-based pigment dispersant and preparation method thereof - Google Patents
Water-based pigment dispersant and preparation method thereof Download PDFInfo
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- 239000000049 pigment Substances 0.000 title claims abstract description 85
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 239000002270 dispersing agent Substances 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 72
- 239000000178 monomer Substances 0.000 claims abstract description 67
- 239000000203 mixture Substances 0.000 claims abstract description 51
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 239000007822 coupling agent Substances 0.000 claims abstract description 20
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 18
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical group CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004584 polyacrylic acid Substances 0.000 claims abstract description 18
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 18
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 62
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- 238000010438 heat treatment Methods 0.000 claims description 26
- 230000002209 hydrophobic effect Effects 0.000 claims description 26
- 239000007767 bonding agent Substances 0.000 claims description 21
- 239000003999 initiator Substances 0.000 claims description 21
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000001179 sorption measurement Methods 0.000 claims description 20
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 13
- 239000000853 adhesive Substances 0.000 claims description 12
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 11
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 11
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 11
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 11
- 239000012986 chain transfer agent Substances 0.000 claims description 11
- 239000011259 mixed solution Substances 0.000 claims description 11
- 229920005554 polynitrile Polymers 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 7
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 7
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000001856 Ethyl cellulose Substances 0.000 claims description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 3
- 229920001249 ethyl cellulose Polymers 0.000 claims description 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 125000003396 thiol group Chemical class [H]S* 0.000 abstract description 7
- 230000006872 improvement Effects 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 2
- 238000004040 coloring Methods 0.000 description 9
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 4
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- GKHOLUJNLGYFHA-UHFFFAOYSA-N [Na].CC(C)=O Chemical compound [Na].CC(C)=O GKHOLUJNLGYFHA-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- KQQCTWHSWXCZHB-UHFFFAOYSA-N azane;propan-2-ol Chemical compound N.CC(C)O KQQCTWHSWXCZHB-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明公开了一种水性颜料分散剂及制造方法,各组分按其重量份计为:高分子聚合物:40‑110份、丙酮:20‑50份、聚丙烯酸钠盐、10‑20份;改性单体、5‑10份,本发明的有益效果是:通过加入了偶联剂和粘连剂,偶联剂为乙烯基三乙氧基硅烷材料,粘连剂为二氧化硅材料,通过乙烯基三乙氧基硅烷材料和二氧化硅材料对水性颜料分散剂制备中进行添加,方便在分散剂加入时对水性颜料的粘性进行提升,提高了分散剂的功能性,通过加入了改性单体,实现了含巯基改性单体和丙烯酸丁酯的混合物进行混合后,对水性颜料内的分子进行改性处理,对水性颜料的分散效果提升。The invention discloses a water-based pigment dispersant and a manufacturing method thereof. The components are calculated in parts by weight: high molecular polymer: 40-110 parts, acetone: 20-50 parts, polyacrylic acid sodium salt, 10-20 parts Modified monomer, 5-10 parts, the beneficial effect of the present invention is: by adding coupling agent and tacking agent, coupling agent is vinyltriethoxysilane material, and tacking agent is silicon dioxide material, by Vinyl triethoxysilane material and silica material are added to the preparation of the water-based pigment dispersant, which facilitates the improvement of the viscosity of the water-based pigment when the dispersant is added, and improves the functionality of the dispersant. By adding the modified The monomer, after the mixture of the mercapto-containing modified monomer and butyl acrylate is mixed, the molecules in the water-based pigment are modified, and the dispersion effect of the water-based pigment is improved.
Description
技术领域technical field
本发明涉及分散剂技术领域,具体为一种水性颜料分散剂及制造方法。The invention relates to the technical field of dispersants, in particular to a water-based pigment dispersant and a manufacturing method.
背景技术Background technique
分散剂是一种在分子内同时具有亲油性和亲水性两种相反性质的界面活性剂。可均一分散那些难于溶解于液体的无机,有机颜料的固体颗粒,同时也能防止固体颗粒的沉降和凝聚,形成安定悬浮液所需的药剂。分散剂分为脂肪酸类、脂肪族酰胺类和酯类,在现有的水性颜料中需要使用分散剂进行颜料分散,便于水性颜料的附着稳定性,然而,现有的大部分水性颜料分散剂由于锚固能力不足和空间位阻差,难以维持高浓度颜料之间粘连性能,导致水性颜料稳定差,分散剂处理后的水性颜料着色稳定性差。A dispersant is a surfactant that has two opposite properties of lipophilicity and hydrophilicity in the molecule. It can uniformly disperse the solid particles of inorganic and organic pigments that are difficult to dissolve in liquid, and at the same time prevent the sedimentation and aggregation of solid particles, forming the medicament needed to stabilize the suspension. Dispersants are divided into fatty acids, aliphatic amides and esters. In existing water-based pigments, dispersants need to be used for pigment dispersion to facilitate the adhesion and stability of water-based pigments. However, most of the existing water-based pigment dispersants are due to Insufficient anchoring ability and poor steric hindrance, it is difficult to maintain the adhesion between high-concentration pigments, resulting in poor stability of water-based pigments, and poor coloring stability of water-based pigments after dispersant treatment.
发明内容Contents of the invention
本发明的目的在于提供一种水性颜料分散剂及制造方法,以解决上述背景技术中提出的问题。The object of the present invention is to provide a water-based pigment dispersant and a manufacturing method to solve the problems raised in the above-mentioned background technology.
为实现上述目的,本发明提供如下技术方案:一种水性颜料分散剂,各组分按其重量份计为:高分子聚合物:40-110份、丙酮:20-50份、聚丙烯酸钠盐、10-20份;改性单体、5-10份;疏水性单体、5-8份;偶联剂、10-15份;分散辅料、5-20份;粘连剂、1-5份;透明剂、2-4份;甲基丙烯酸、1-5份;吸附锚基材料、10-18份;键合剂、1-4份;链转移剂、5-10份;引发剂、1-4份。In order to achieve the above object, the present invention provides the following technical solutions: a water-based pigment dispersant, each component is calculated by weight: high molecular polymer: 40-110 parts, acetone: 20-50 parts, polyacrylic acid sodium salt , 10-20 parts; Modified monomer, 5-10 parts; Hydrophobic monomer, 5-8 parts; Coupling agent, 10-15 parts; Dispersion auxiliary material, 5-20 parts; Adhesive agent, 1-5 parts ; Transparent agent, 2-4 parts; Methacrylic acid, 1-5 parts; Adsorption anchor material, 10-18 parts; Bonding agent, 1-4 parts; Chain transfer agent, 5-10 parts; Initiator, 1- 4 parts.
作为优选,所述高分子聚合物为羧甲基纤维素钠和乙基纤维素中的其中一种,所述改性单体为含巯基改性单体和丙烯酸丁酯的混合物。Preferably, the high molecular polymer is one of sodium carboxymethyl cellulose and ethyl cellulose, and the modified monomer is a mixture of a mercapto-containing modified monomer and butyl acrylate.
作为优选,所述疏水性单体为疏水性丙烯酸酯单体,所述偶联剂为乙烯基三乙氧基硅烷材料。Preferably, the hydrophobic monomer is a hydrophobic acrylate monomer, and the coupling agent is a vinyltriethoxysilane material.
作为优选,所述分散辅料为烯丙基醚,所述粘连剂为二氧化硅材料。Preferably, the dispersing auxiliary material is allyl ether, and the adhesive agent is silica material.
作为优选,所述透明剂为氢氧化钠溶液和稀盐酸中的其中一种,所述键合剂为多腈基羟胺聚合物。Preferably, the transparent agent is one of sodium hydroxide solution and dilute hydrochloric acid, and the bonding agent is polynitrile hydroxylamine polymer.
作为优选,所述链转移剂为异丙醇,所述引发剂为过硫酸铵。Preferably, the chain transfer agent is isopropanol, and the initiator is ammonium persulfate.
作为优选,所述键合剂和引发剂的质量比为1:1。Preferably, the mass ratio of the bonding agent to the initiator is 1:1.
一种水性颜料分散剂的制造方法,包括以下步骤:A kind of manufacture method of water-based pigment dispersant, comprises the following steps:
S1、称取高分子聚合物、丙酮和聚丙烯酸钠盐,将高分子聚合物和聚丙烯酸钠盐倒入反应釜内进行搅拌混合,混合均匀后升温至40-70℃,升温后加入丙酮进行恒温混合处理,得到一号混合剂;S1. Weigh the high molecular polymer, acetone and polyacrylic acid sodium salt, pour the high molecular polymer and polyacrylic acid sodium salt into the reactor for stirring and mixing, after mixing evenly, heat up to 40-70°C, add acetone after heating up Constant temperature mixing treatment, obtain No. 1 mixture;
S2、称取偶联剂、分散辅料和甲基丙烯酸,将偶联剂加入一号混合剂内进行加热混合,加热温度为35-60℃,混合1-2h后冷却至室温,加入分散辅料和甲基丙烯酸继续加热混合,加热温度至55-80℃,搅拌20-45min后得到二号混合剂;S2. Weigh the coupling agent, dispersing auxiliary material and methacrylic acid, add the coupling agent into the No. 1 mixture and heat and mix it. The heating temperature is 35-60°C. After mixing for 1-2 hours, cool to room temperature, add the dispersing auxiliary material and Continue to heat and mix the methacrylic acid, heat the temperature to 55-80°C, and stir for 20-45 minutes to obtain the No. 2 mixture;
S3、称取改性单体、疏水性单体、吸附锚基材料和键合剂,将改性单体、疏水性单体和吸附锚基材料进行常温混合,混合后加入键合剂进行真空加热搅拌处理,得到三号混合剂;S3. Weigh the modified monomer, hydrophobic monomer, adsorption anchor material and bonding agent, mix the modified monomer, hydrophobic monomer and adsorption anchor material at room temperature, and add the bonding agent after mixing for vacuum heating and stirring Process to obtain No. 3 mixture;
S4、称取透明剂和引发剂,将透明剂和引发剂放入二号混合剂内搅拌然后加入S3中得到的三号混合液继续搅拌处理,得到基础分散剂;S4, weigh the clearing agent and the initiator, put the clearing agent and the initiator into the No. 2 mixture and stir, then add the No. 3 mixed solution obtained in S3 and continue the stirring process to obtain the basic dispersant;
S5、称取粘连剂和链转移剂,将粘连剂加入基础分散剂内进行进行加热搅拌,加热温度为80-95℃,搅拌1-2h后降温至60-75℃,继续搅拌2-5h,即可得到水性颜料分散剂。S5. Weigh the adhesion agent and the chain transfer agent, add the adhesion agent into the basic dispersant and heat and stir. The heating temperature is 80-95°C. After stirring for 1-2h, the temperature is lowered to 60-75°C, and the stirring is continued for 2-5h. The water-based pigment dispersant can be obtained.
作为优选,所述S3中的混合后加入键合剂进行真空加热搅拌处理具体包括以下步骤:As a preference, adding a bonding agent after mixing in S3 to carry out vacuum heating and stirring treatment specifically includes the following steps:
S31、改性单体、疏水性单体和吸附锚基材料通过常温进行混合之后,将称取的键合剂倒入内继续混合,混合前将真空反应釜内抽真空处理,真空压力为0.5-1.2Pa;S31. After the modified monomer, hydrophobic monomer and adsorption anchor material are mixed at room temperature, the weighed bonding agent is poured into the interior to continue mixing. Before mixing, the vacuum reactor is vacuumed, and the vacuum pressure is 0.5- 1.2 Pa;
S32、将真空反应釜内进行加热,内部环境温度为60-85℃,以300-450r/min的搅拌转速搅拌1-2h后,得到三号混合剂。S32. Heat the inside of the vacuum reactor, the internal environment temperature is 60-85° C., and stir at a stirring speed of 300-450 r/min for 1-2 hours to obtain No. 3 mixture.
作为优选,所述S4中的将透明剂和引发剂放入二号混合剂内搅拌然后加入S3中得到的三号混合液继续搅拌处理,得到基础分散剂具体包括以下步骤:As preferably, in described S4, put transparent agent and initiator into No. 2 mixed agent and stir and then add No. 3 mixed solution obtained in S3 to continue the stirring process, and obtain the basic dispersant specifically comprising the following steps:
S41、将透明剂和引发剂放入二号混合剂内进行搅拌,搅拌转速为140-200r/min,混合时间为20-55min;S41. Put the transparent agent and the initiator into the No. 2 mixture for stirring, the stirring speed is 140-200r/min, and the mixing time is 20-55min;
S42、然后加入S3中得到的三号混合液,并提升混合转速至300-380r/min,然后继续混合20-40min,得到基础分散剂。S42, then add the No. 3 mixed solution obtained in S3, and increase the mixing speed to 300-380r/min, and then continue mixing for 20-40min to obtain a basic dispersant.
应当理解的是,以上的一般描述和后文的细节描述仅是示例性和解释性的,并不能限制本公开。It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the present disclosure.
与现有技术相比,本发明的有益效果是:通过加入了偶联剂和粘连剂,偶联剂为乙烯基三乙氧基硅烷材料,粘连剂为二氧化硅材料,通过乙烯基三乙氧基硅烷材料和二氧化硅材料对水性颜料分散剂制备中进行添加,方便在分散剂加入时对水性颜料的粘性进行提升,提高了分散剂的功能性,通过加入了改性单体,实现了含巯基改性单体和丙烯酸丁酯的混合物进行混合后,对水性颜料内的分子进行改性处理,对水性颜料的分散效果提升,通过加入了透明剂,透明剂使用氢氧化钠溶液和稀盐酸中的其中一种,实现了对分散剂使用时对水性颜料的透明效果进行增强,对水性颜料的着色稳定性进行提升。Compared with the prior art, the beneficial effect of the present invention is: by adding a coupling agent and an adhesive agent, the coupling agent is a vinyltriethoxysilane material, the adhesive agent is a silicon dioxide material, through vinyl triethyl Oxysilane materials and silica materials are added to the preparation of water-based pigment dispersants, which facilitates the improvement of the viscosity of water-based pigments when the dispersant is added, and improves the functionality of the dispersant. By adding modified monomers, it is realized After mixing the mixture of mercapto-containing modified monomer and butyl acrylate, the molecules in the water-based pigment are modified to improve the dispersion effect of the water-based pigment. By adding a transparent agent, the transparent agent uses sodium hydroxide solution and One of the dilute hydrochloric acid can enhance the transparency of water-based pigments when used as a dispersant, and improve the coloring stability of water-based pigments.
具体实施方式Detailed ways
实施例1:Example 1:
本发明实施例的一种水性颜料分散剂,各组分按其重量份计为:高分子聚合物:40-110份、丙酮:20-50份、聚丙烯酸钠盐、10-20份;改性单体、5-10份;疏水性单体、5-8份;偶联剂、10-15份;分散辅料、5-20份;粘连剂、1-5份;透明剂、2-4份;甲基丙烯酸、1-5份;吸附锚基材料、10-18份;键合剂、1-4份;链转移剂、5-10份;引发剂、1-4份。A water-based pigment dispersant according to an embodiment of the present invention, each component is calculated by weight: high molecular polymer: 40-110 parts, acetone: 20-50 parts, polyacrylic acid sodium salt, 10-20 parts; Sexual monomer, 5-10 parts; Hydrophobic monomer, 5-8 parts; Coupling agent, 10-15 parts; Dispersion auxiliary material, 5-20 parts; Adhesive agent, 1-5 parts; parts; methacrylic acid, 1-5 parts; adsorption anchor material, 10-18 parts; bonding agent, 1-4 parts; chain transfer agent, 5-10 parts; initiator, 1-4 parts.
实施例2:Example 2:
其中,高分子聚合物为羧甲基纤维素钠和乙基纤维素中的其中一种,改性单体为含巯基改性单体和丙烯酸丁酯的混合物,加入了改性单体,实现了含巯基改性单体和丙烯酸丁酯的混合物进行混合后,对水性颜料内的分子进行改性处理,对水性颜料的分散效果提升。Among them, the high molecular polymer is one of sodium carboxymethyl cellulose and ethyl cellulose, and the modified monomer is a mixture of mercapto-containing modified monomer and butyl acrylate, and the modified monomer is added to realize After mixing the mixture of the mercapto-containing modified monomer and butyl acrylate, the molecules in the water-based pigment are modified to improve the dispersion effect of the water-based pigment.
其中,疏水性单体为疏水性丙烯酸酯单体,偶联剂为乙烯基三乙氧基硅烷材料。Wherein, the hydrophobic monomer is a hydrophobic acrylate monomer, and the coupling agent is a vinyltriethoxysilane material.
其中,分散辅料为烯丙基醚,粘连剂为二氧化硅材料,加入了偶联剂和粘连剂,偶联剂为乙烯基三乙氧基硅烷材料,粘连剂为二氧化硅材料,通过乙烯基三乙氧基硅烷材料和二氧化硅材料对水性颜料分散剂制备中进行添加,方便在分散剂加入时对水性颜料的粘性进行提升,提高了分散剂的功能性。Among them, the dispersing auxiliary material is allyl ether, the adhesive agent is a silica material, and a coupling agent and an adhesive agent are added. The coupling agent is a vinyltriethoxysilane material, and the adhesive agent is a silica material. Triethoxysilane and silica materials are added to the preparation of the water-based pigment dispersant, which facilitates the improvement of the viscosity of the water-based pigment when the dispersant is added, and improves the functionality of the dispersant.
其中,透明剂为氢氧化钠溶液和稀盐酸中的其中一种,键合剂为多腈基羟胺聚合物,透明剂,透明剂使用氢氧化钠溶液和稀盐酸中的其中一种,实现了对分散剂使用时对水性颜料的透明效果进行增强,对水性颜料的着色稳定性进行提升。Wherein, the transparent agent is one of sodium hydroxide solution and dilute hydrochloric acid, the bonding agent is a polynitrile hydroxylamine polymer, the transparent agent, and the transparent agent uses one of sodium hydroxide solution and dilute hydrochloric acid to realize the When the dispersant is used, the transparency effect of the water-based pigment is enhanced, and the coloring stability of the water-based pigment is improved.
其中,链转移剂为异丙醇,引发剂为过硫酸铵,通过加入了链转移剂为异丙醇,异丙醇是一种有机化合物,正丙醇的同分异构体,无色透明液体,有似乙醇和丙酮混合物的气味,对水性颜料中的链结构进行快速转移处理,提高了工作效率。Among them, the chain transfer agent is isopropanol, the initiator is ammonium persulfate, and the chain transfer agent is isopropanol by adding the chain transfer agent. Isopropanol is an organic compound, an isomer of n-propanol, colorless and transparent It is a liquid with a smell like a mixture of ethanol and acetone. It can quickly transfer the chain structure in water-based pigments and improve work efficiency.
其中,键合剂和引发剂的质量比为1:1。Wherein, the mass ratio of bonding agent and initiator is 1:1.
实施例3:Example 3:
一种水性颜料分散剂的制造方法,包括以下步骤:A kind of manufacture method of water-based pigment dispersant, comprises the following steps:
S1、称取高分子聚合物、丙酮和聚丙烯酸钠盐,将高分子聚合物和聚丙烯酸钠盐倒入反应釜内进行搅拌混合,混合均匀后升温至40-70℃,升温后加入丙酮进行恒温混合处理,得到一号混合剂;S1. Weigh the high molecular polymer, acetone and polyacrylic acid sodium salt, pour the high molecular polymer and polyacrylic acid sodium salt into the reactor for stirring and mixing, after mixing evenly, heat up to 40-70°C, add acetone after heating up Constant temperature mixing treatment, obtain No. 1 mixture;
S2、称取偶联剂、分散辅料和甲基丙烯酸,将偶联剂加入一号混合剂内进行加热混合,加热温度为35-60℃,混合1-2h后冷却至室温,加入分散辅料和甲基丙烯酸继续加热混合,加热温度至55-80℃,搅拌20-45min后得到二号混合剂;S2. Weigh the coupling agent, dispersing auxiliary material and methacrylic acid, add the coupling agent into the No. 1 mixture and heat and mix it. The heating temperature is 35-60°C. After mixing for 1-2 hours, cool to room temperature, add the dispersing auxiliary material and Continue to heat and mix the methacrylic acid, heat the temperature to 55-80°C, and stir for 20-45 minutes to obtain the No. 2 mixture;
S3、称取改性单体、疏水性单体、吸附锚基材料和键合剂,将改性单体、疏水性单体和吸附锚基材料进行常温混合,混合后加入键合剂进行真空加热搅拌处理,得到三号混合剂,加入了改性单体,实现了含巯基改性单体和丙烯酸丁酯的混合物进行混合后,对水性颜料内的分子进行改性处理,对水性颜料的分散效果提升,加入了改性单体,实现了含巯基改性单体和丙烯酸丁酯的混合物进行混合后,对水性颜料内的分子进行改性处理,对水性颜料的分散效果提升;S3. Weigh the modified monomer, hydrophobic monomer, adsorption anchor material and bonding agent, mix the modified monomer, hydrophobic monomer and adsorption anchor material at room temperature, and add the bonding agent after mixing for vacuum heating and stirring After treatment, the No. 3 mixture is obtained, and the modified monomer is added to realize the mixture of the mercapto-containing modified monomer and butyl acrylate. After the mixture is mixed, the molecules in the water-based pigment are modified, and the dispersion effect on the water-based pigment Improvement, the addition of modified monomers, after the mixture of mercapto-containing modified monomers and butyl acrylate is mixed, the molecules in the water-based pigments are modified, and the dispersion effect of water-based pigments is improved;
S4、称取透明剂和引发剂,将透明剂和引发剂放入二号混合剂内搅拌然后加入S3中得到的三号混合液继续搅拌处理,得到基础分散剂,透明剂,透明剂使用氢氧化钠溶液和稀盐酸中的其中一种,实现了对分散剂使用时对水性颜料的透明效果进行增强,对水性颜料的着色稳定性进行提升;S4. Weigh the clearing agent and the initiator, put the clearing agent and the initiator into the No. 2 mixture and stir, then add the No. 3 mixed solution obtained in S3 and continue stirring to obtain the basic dispersant, the clearing agent, and the clearing agent using hydrogen One of sodium oxide solution and dilute hydrochloric acid can enhance the transparency of water-based pigments when the dispersant is used, and improve the coloring stability of water-based pigments;
S5、称取粘连剂和链转移剂,将粘连剂加入基础分散剂内进行进行加热搅拌,加热温度为80-95℃,搅拌1-2h后降温至60-75℃,继续搅拌2-5h,即可得到水性颜料分散剂,加入了偶联剂和粘连剂,偶联剂为乙烯基三乙氧基硅烷材料,粘连剂为二氧化硅材料,通过乙烯基三乙氧基硅烷材料和二氧化硅材料对水性颜料分散剂制备中进行添加,方便在分散剂加入时对水性颜料的粘性进行提升,提高了分散剂的功能性。S5. Weigh the adhesion agent and the chain transfer agent, add the adhesion agent into the basic dispersant and heat and stir. The heating temperature is 80-95°C. After stirring for 1-2h, the temperature is lowered to 60-75°C, and the stirring is continued for 2-5h. The water-based pigment dispersant can be obtained, and a coupling agent and an adhesive agent are added. The coupling agent is vinyltriethoxysilane material, and the adhesive agent is silica material. Through vinyltriethoxysilane material and dioxide The silicon material is added to the preparation of the water-based pigment dispersant, which facilitates the improvement of the viscosity of the water-based pigment when the dispersant is added, and improves the functionality of the dispersant.
其中,S3中的混合后加入键合剂进行真空加热搅拌处理具体包括以下步骤:Wherein, after mixing in S3, adding a bonding agent to carry out vacuum heating and stirring treatment specifically includes the following steps:
S31、改性单体、疏水性单体和吸附锚基材料通过常温进行混合之后,将称取的键合剂倒入内继续混合,混合前将真空反应釜内抽真空处理,真空压力为0.5-1.2Pa;S31. After the modified monomer, hydrophobic monomer and adsorption anchor material are mixed at room temperature, the weighed bonding agent is poured into the interior to continue mixing. Before mixing, the vacuum reactor is vacuumed, and the vacuum pressure is 0.5- 1.2 Pa;
S32、将真空反应釜内进行加热,内部环境温度为60-85℃,以300-450r/min的搅拌转速搅拌1-2h后,得到三号混合剂。S32. Heat the inside of the vacuum reactor, the internal environment temperature is 60-85° C., and stir at a stirring speed of 300-450 r/min for 1-2 hours to obtain No. 3 mixture.
其中,S4中的将透明剂和引发剂放入二号混合剂内搅拌然后加入S3中得到的三号混合液继续搅拌处理,得到基础分散剂具体包括以下步骤:Wherein, putting the transparent agent and the initiator in S4 into the No. 2 mixture and stirring, then adding the No. 3 mixed solution obtained in S3 to continue the stirring process, and obtaining the basic dispersant specifically includes the following steps:
S41、将透明剂和引发剂放入二号混合剂内进行搅拌,搅拌转速为140-200r/min,混合时间为20-55min;S41. Put the transparent agent and the initiator into the No. 2 mixture for stirring, the stirring speed is 140-200r/min, and the mixing time is 20-55min;
S42、然后加入S3中得到的三号混合液,并提升混合转速至300-380r/min,然后继续混合20-40min,得到基础分散剂。S42, then add the No. 3 mixed solution obtained in S3, and increase the mixing speed to 300-380r/min, and then continue mixing for 20-40min to obtain a basic dispersant.
实施例4:Example 4:
一种水性颜料分散剂,各组分按其重量份计为:羧甲基纤维素钠:40份、丙酮:20份、聚丙烯酸钠盐、10份;改性单体、5份;疏水性丙烯酸酯单体、5份;乙烯基三乙氧基硅烷材料、10份;烯丙基醚、5份;二氧化硅材料、1份;氢氧化钠溶液、2份;甲基丙烯酸、1份;吸附锚基材料、10份;多腈基羟胺聚合物、1份;异丙醇、5份;过硫酸铵、1份A water-based pigment dispersant, the components are calculated in parts by weight: sodium carboxymethylcellulose: 40 parts, acetone: 20 parts, polyacrylic acid sodium salt, 10 parts; modified monomer, 5 parts; hydrophobicity Acrylate monomer, 5 parts; Vinyl triethoxysilane material, 10 parts; Allyl ether, 5 parts; Silica material, 1 part; Sodium hydroxide solution, 2 parts; Methacrylic acid, 1 part ;Adsorbent anchor material, 10 parts; Polynitrile hydroxylamine polymer, 1 part; Isopropanol, 5 parts; Ammonium persulfate, 1 part
一种水性颜料分散剂的制造方法,包括以下步骤:A kind of manufacture method of water-based pigment dispersant, comprises the following steps:
S1、称取羧甲基纤维素钠、丙酮和聚丙烯酸钠盐,将羧甲基纤维素钠和聚丙烯酸钠盐倒入反应釜内进行搅拌混合,混合均匀后升温至40℃,升温后加入丙酮进行恒温混合处理,得到一号混合剂;S1. Weigh carboxymethyl cellulose sodium, acetone and polyacrylic acid sodium salt, pour carboxymethyl cellulose sodium and polyacrylic acid sodium salt into the reaction kettle for stirring and mixing, heat up to 40°C after mixing evenly, and add Acetone is carried out constant temperature mixing process, obtains No. 1 mixing agent;
S2、称取乙烯基三乙氧基硅烷材料、烯丙基醚和甲基丙烯酸,将乙烯基三乙氧基硅烷材料加入一号混合剂内进行加热混合,加热温度为35℃,混合1h后冷却至室温,加入烯丙基醚和甲基丙烯酸继续加热混合,加热温度至55℃,搅拌20min后得到二号混合剂;S2. Weigh the vinyltriethoxysilane material, allyl ether and methacrylic acid, add the vinyltriethoxysilane material into the No. 1 mixture for heating and mixing, the heating temperature is 35°C, after mixing for 1 hour Cool to room temperature, add allyl ether and methacrylic acid to continue heating and mixing, heat the temperature to 55°C, and stir for 20 minutes to obtain the No. 2 mixture;
S3、称取改性单体、疏水性丙烯酸酯单体、吸附锚基材料和多腈基羟胺聚合物,将改性单体、疏水性丙烯酸酯单体和吸附锚基材料进行常温混合,改性单体、疏水性丙烯酸酯单体和吸附锚基材料通过常温进行混合之后,将称取的多腈基羟胺聚合物倒入内继续混合,混合前将真空反应釜内抽真空处理,真空压力为0.5Pa,将真空反应釜内进行加热,内部环境温度为60℃,以300r/min的搅拌转速搅拌1h后,得到三号混合剂;S3. Weigh the modified monomer, hydrophobic acrylate monomer, adsorption anchor material and polynitrile hydroxylamine polymer, mix the modified monomer, hydrophobic acrylate monomer and adsorption anchor material at room temperature, and modify After the neutral monomer, hydrophobic acrylate monomer and adsorption anchor material are mixed at room temperature, the weighed polynitrile hydroxylamine polymer is poured into the interior to continue mixing. Before mixing, the vacuum reactor is evacuated, and the vacuum pressure to 0.5 Pa, heat the inside of the vacuum reactor, the internal ambient temperature is 60°C, and stir at a stirring speed of 300r/min for 1 hour to obtain the No. 3 mixture;
S4、称取氢氧化钠溶液和过硫酸铵,将氢氧化钠溶液和过硫酸铵放入二号混合剂内进行搅拌,搅拌转速为140r/min,混合时间为20min,然后加入S3中得到的三号混合液,并提升混合转速至300r/min,然后继续混合20min,得到基础分散剂;S4, take sodium hydroxide solution and ammonium persulfate, put sodium hydroxide solution and ammonium persulfate into No. 2 mixture and stir, the stirring speed is 140r/min, and the mixing time is 20min, then add the obtained in S3 No. 3 mixed solution, and increase the mixing speed to 300r/min, and then continue to mix for 20min to obtain the basic dispersant;
S5、称取二氧化硅材料和异丙醇,将二氧化硅材料加入基础分散剂内进行进行加热搅拌,加热温度为80℃,搅拌1h后降温至60℃,继续搅拌2h,即可得到水性颜料分散剂。S5. Weigh the silica material and isopropanol, add the silica material into the basic dispersant and heat and stir. The heating temperature is 80°C. After stirring for 1 hour, cool down to 60°C and continue stirring for 2 hours to obtain the water-based Pigment dispersant.
实施例5:Example 5:
一种水性颜料分散剂,各组分按其重量份计为:羧甲基纤维素钠:110份、丙酮:50份、聚丙烯酸钠盐、20份;改性单体、10份;疏水性丙烯酸酯单体、8份;乙烯基三乙氧基硅烷材料、15份;烯丙基醚、20份;二氧化硅材料、5份;氢氧化钠溶液、4份;甲基丙烯酸、5份;吸附锚基材料、18份;多腈基羟胺聚合物、4份;异丙醇、10份;过硫酸铵、4份A water-based pigment dispersant, the components are calculated by weight: sodium carboxymethyl cellulose: 110 parts, acetone: 50 parts, polyacrylic acid sodium salt, 20 parts; modified monomer, 10 parts; hydrophobicity Acrylate monomer, 8 parts; Vinyl triethoxysilane material, 15 parts; Allyl ether, 20 parts; Silica material, 5 parts; Sodium hydroxide solution, 4 parts; Methacrylic acid, 5 parts ;Adsorbent anchor material, 18 parts; Polynitrile hydroxylamine polymer, 4 parts; Isopropanol, 10 parts; Ammonium persulfate, 4 parts
一种水性颜料分散剂的制造方法,包括以下步骤:A kind of manufacture method of water-based pigment dispersant, comprises the following steps:
S1、称取羧甲基纤维素钠、丙酮和聚丙烯酸钠盐,将羧甲基纤维素钠和聚丙烯酸钠盐倒入反应釜内进行搅拌混合,混合均匀后升温至70℃,升温后加入丙酮进行恒温混合处理,得到一号混合剂;S1. Weigh carboxymethyl cellulose sodium, acetone and polyacrylic acid sodium salt, pour carboxymethyl cellulose sodium and polyacrylic acid sodium salt into the reaction kettle for stirring and mixing, heat up to 70°C after mixing evenly, and add Acetone is carried out constant temperature mixing process, obtains No. 1 mixing agent;
S2、称取乙烯基三乙氧基硅烷材料、烯丙基醚和甲基丙烯酸,将乙烯基三乙氧基硅烷材料加入一号混合剂内进行加热混合,加热温度为60℃,混合2h后冷却至室温,加入烯丙基醚和甲基丙烯酸继续加热混合,加热温度至80℃,搅拌45min后得到二号混合剂;S2. Weigh the vinyltriethoxysilane material, allyl ether and methacrylic acid, add the vinyltriethoxysilane material into the No. 1 mixture for heating and mixing, the heating temperature is 60°C, after mixing for 2 hours Cool to room temperature, add allyl ether and methacrylic acid to continue heating and mixing, heat the temperature to 80°C, and stir for 45 minutes to obtain the No. 2 mixture;
S3、称取改性单体、疏水性丙烯酸酯单体、吸附锚基材料和多腈基羟胺聚合物,将改性单体、疏水性丙烯酸酯单体和吸附锚基材料进行常温混合,改性单体、疏水性丙烯酸酯单体和吸附锚基材料通过常温进行混合之后,将称取的多腈基羟胺聚合物倒入内继续混合,混合前将真空反应釜内抽真空处理,真空压力为1.2Pa,将真空反应釜内进行加热,内部环境温度为85℃,以450r/min的搅拌转速搅拌2h后,得到三号混合剂;S3. Weigh the modified monomer, hydrophobic acrylate monomer, adsorption anchor material and polynitrile hydroxylamine polymer, mix the modified monomer, hydrophobic acrylate monomer and adsorption anchor material at room temperature, and modify After the neutral monomer, hydrophobic acrylate monomer and adsorption anchor material are mixed at room temperature, the weighed polynitrile hydroxylamine polymer is poured into the interior to continue mixing. Before mixing, the vacuum reactor is evacuated, and the vacuum pressure to 1.2Pa, heat the inside of the vacuum reactor, the internal ambient temperature is 85°C, and after stirring for 2 hours at a stirring speed of 450r/min, the No. 3 mixture is obtained;
S4、称取氢氧化钠溶液和过硫酸铵,将氢氧化钠溶液和过硫酸铵放入二号混合剂内进行搅拌,搅拌转速为200r/min,混合时间为55min,然后加入S3中得到的三号混合液,并提升混合转速至380r/min,然后继续混合40min,得到基础分散剂;S4, take sodium hydroxide solution and ammonium persulfate, put sodium hydroxide solution and ammonium persulfate into No. 2 mixture and stir, the stirring speed is 200r/min, and the mixing time is 55min, then add the obtained in S3 No. 3 mixed solution, and increase the mixing speed to 380r/min, and then continue to mix for 40min to obtain the basic dispersant;
S5、称取二氧化硅材料和异丙醇,将二氧化硅材料加入基础分散剂内进行进行加热搅拌,加热温度为95℃,搅拌2h后降温至75℃,继续搅拌5h,即可得到水性颜料分散剂。S5. Weigh the silica material and isopropanol, add the silica material into the basic dispersant and heat and stir. The heating temperature is 95°C. After stirring for 2 hours, cool down to 75°C and continue stirring for 5 hours to obtain the water-based Pigment dispersant.
1.试验分组1. Test groups
试验组1-2采用实施例4至5中制得的水性颜料分散剂,对照组为市售水性颜料分散剂,取10ml水性颜料,将水性颜料分散剂滴入水性颜料内,每30s滴入0.5ml,持续滴入3min;The test group 1-2 adopts the water-based pigment dispersant prepared in Examples 4 to 5, and the control group is a commercially available water-based pigment dispersant. Take 10ml of water-based pigment, drop the water-based pigment dispersant into the water-based pigment, and drop it every 30s. 0.5ml, drip continuously for 3min;
2.试验方法2. Test method
取5份实施例4制备的水性颜料分散剂,对水性颜料进行加热,加热温度为30℃,每30s滴入0.5ml的水性颜料分散剂,3min后观察状况,对水性颜料的状态进行检测。Take 5 parts of the water-based pigment dispersant prepared in Example 4, and heat the water-based pigment at a heating temperature of 30° C., drop 0.5 ml of the water-based pigment dispersant every 30 seconds, observe the condition after 3 minutes, and detect the state of the water-based pigment.
取5份实施例5制备的水性颜料分散剂,对水性颜料进行加热,加热温度为30℃,每30s滴入0.5ml的水性颜料分散剂,3min后观察状况,对水性颜料的状态进行检测。Take 5 parts of the water-based pigment dispersant prepared in Example 5, and heat the water-based pigment at a heating temperature of 30°C, drop 0.5ml of the water-based pigment dispersant every 30s, observe the situation after 3 minutes, and detect the state of the water-based pigment.
取5份对照组的水性颜料分散剂,对水性颜料进行加热,加热温度为30℃,每30s滴入0.5ml的水性颜料分散剂,3min后观察状况,对水性颜料的状态进行检测。Take 5 parts of the water-based pigment dispersant of the control group, heat the water-based pigment at a heating temperature of 30°C, drop 0.5ml of the water-based pigment dispersant every 30s, observe the situation after 3 minutes, and detect the state of the water-based pigment.
3.试验结果3. Test results
检测结果见如下表所示:The test results are shown in the table below:
下表实施例4至5中水性颜料分散剂以及对照组的检测结果The detection result of water-based pigment dispersant and control group in the following table embodiment 4 to 5
由上表中的检测结果数据可知,实验组中水性颜料分散剂的着色、附着力的效果远远优于市售水性颜料分散剂的着色、附着力的效果。From the test result data in the above table, it can be seen that the coloring and adhesion effects of the water-based pigment dispersant in the experimental group are far superior to those of the commercially available water-based pigment dispersant.
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those skilled in the art can understand that various changes, modifications and substitutions can be made to these embodiments without departing from the principle and spirit of the present invention. and modifications, the scope of the invention is defined by the appended claims and their equivalents.
本领域技术人员在考虑说明书及实践这里公开的公开后,将容易想到本公开的其它实施方案。本申请旨在涵盖本公开的任何变型、用途或者适应性变化,这些变型、用途或者适应性变化遵循本公开的一般性原理并包括本公开未公开的本技术领域中的公知常识或惯用技术手段。说明书和实施例仅被视为示例性的,本公开的真正范围由下面的权利要求指出。Other embodiments of the disclosure will be readily apparent to those skilled in the art from consideration of the specification and practice of the disclosure disclosed herein. This application is intended to cover any modification, use or adaptation of the present disclosure, and these modifications, uses or adaptations follow the general principles of the present disclosure and include common knowledge or conventional technical means in the technical field not disclosed in the present disclosure . The specification and examples are to be considered exemplary only, with the true scope of the disclosure being indicated by the following claims.
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