CN115652536A - High-strength water-punched composite material for colorful soft towel and preparation method thereof - Google Patents
High-strength water-punched composite material for colorful soft towel and preparation method thereof Download PDFInfo
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Abstract
本发明公开了一种高强度彩色柔巾用水刺复合材料及其制备方法,材料包括重叠设置的梳理成网上层、纺粘中间层、梳理成网下层;梳理成网上层和所述梳理成网下层均由彩色亲水纤维和常规纤维混合梳理而成;纺粘中间层由并列双组分纤维热轧而成。本发明的有益效果为:该水刺复合材料的色彩来源于PVA纤维,避免了水刺复合材料后续的染色操作,避免了染色添加剂的应用,解决了染色牢度性差的问题,及染色剂所带来的环境污染问题;该高强度彩色柔巾用水刺复合材料的梳理成网层与纺粘中间层加固后,梳理成网层中的纤维与纺粘材料中的纤维发生位移、穿插、缠结、抱合,从而使梳理成网层和纺粘层牢固结合,使材料具有高强度,结构稳定的性能。The invention discloses a high-strength colored soft towel spunlaced composite material and a preparation method thereof. The material comprises a carded web upper layer, a spunbonded middle layer, and a carded web lower layer arranged overlappingly; the carded web layer and the carded web The lower layer is made of mixed and carded colored hydrophilic fibers and conventional fibers; the spun-bonded middle layer is made of hot-rolled side-by-side bi-component fibers. The beneficial effects of the present invention are: the color of the spunlace composite material is derived from PVA fiber, which avoids the subsequent dyeing operation of the spunlace composite material, avoids the application of dyeing additives, solves the problem of poor color fastness, and the dyeing agent The environmental pollution problem caused by the high-strength colored soft towel is reinforced by the carded layer of the spunlace composite material and the spunbonded intermediate layer, and the fibers in the carded layer and the fibers in the spunbond material are displaced, interspersed, and entangled. Knotting and cohesion, so that the carded layer and the spunbond layer are firmly combined, so that the material has high strength and stable structure.
Description
技术领域technical field
本发明属于水刺非织造布技术领域,具体涉及一种高强度彩色柔巾用水刺复合材料及其制备方法。The invention belongs to the technical field of spunlace nonwoven fabrics, and in particular relates to a spunlace composite material for high-strength colored soft towels and a preparation method thereof.
背景技术Background technique
近些年来,随着人们生活水平的提高,人们对生活质量的要求也越来越高,柔巾湿巾成为人们生活中常用的一类物品,其在日用品市场中占据的份额也越来越大。水刺非织造材料具有高强度、手感柔软、悬垂性好、吸湿性好、外观光滑、不易起毛、不易感染细菌、不含化学黏合剂等优点,广泛应用于卫生材料领域, 是近年来发展迅速的非织造材料生产技术之一。In recent years, with the improvement of people's living standards, people's requirements for the quality of life are getting higher and higher. Soft towels and wet wipes have become a commonly used item in people's lives, and their share in the daily necessities market is also increasing. big. Spunlaced non-woven materials have the advantages of high strength, soft hand feeling, good drape, good hygroscopicity, smooth appearance, not easy to fluff, not easy to be infected with bacteria, and do not contain chemical adhesives. They are widely used in the field of hygienic materials and are developing rapidly in recent years. One of the advanced nonwoven material production technologies.
水刺非织造柔巾湿巾手感好,且不会对人体皮肤造成伤害,是当前市场上柔巾产品的主要材料。然而随着人们对环保、卫生以及保障身体健康的意识越来越强,同时也对柔巾湿巾提出了更加严格的要求,例如当前市场上的柔巾材料多为素色,产品无差异化,而且水刺材料在使用过程中易发生变形。目前也有一些专利报道了水刺柔巾开发的新技术,例如专利CN114318719A公布了一种木浆复合水刺无纺布的制备方法,其具有色牢度优良、耐干湿磨和耐溶剂性的优点,但制备过程相对复杂,且所需成本较高。专利CN216338281U公布了一种麻纤维水刺无纺布,其采用麻纤维作为擦拭面层,有效提高了去污能力和耐磨性,但所制备的无纺布颜色为麻纤维原色,色彩不明亮,不能满足人们对市场差异化产品的需求。因此开发一种差异化的结构稳定水刺非织造材料用于制备柔巾产品具有较好的市场潜力。Spunlaced non-woven soft wipes have a good hand feeling and will not cause harm to human skin. They are the main materials for soft wipes on the market. However, as people become more and more aware of environmental protection, hygiene and protection of physical health, they also put forward stricter requirements for soft wipes. For example, the materials of soft wipes on the market are mostly plain, and the products have no differentiation. , and the spunlace material is prone to deformation during use. At present, there are also some patents reporting new technologies for the development of spunlace soft towels. For example, patent CN114318719A discloses a preparation method of wood pulp composite spunlace nonwoven fabric, which has excellent color fastness, resistance to dry and wet grinding and solvent resistance. Advantages, but the preparation process is relatively complicated, and the required cost is high. Patent CN216338281U discloses a kind of hemp fiber spunlace non-woven fabric, which adopts hemp fiber as the wiping surface layer, which effectively improves the decontamination ability and wear resistance, but the color of the prepared non-woven fabric is the original color of hemp fiber, and the color is not bright , can not meet people's demand for differentiated products in the market. Therefore, the development of a differentiated structurally stable spunlaced nonwoven material for the preparation of soft towel products has a good market potential.
发明内容Contents of the invention
本发明的目的为提供一种结构稳定的,高强度彩色柔巾用水刺复合材料及其制备方法。The object of the present invention is to provide a structurally stable, high-strength colored soft towel spunlace composite material and its preparation method.
为实现本发明的上述目的,本发明采用以下技术方案:For realizing above-mentioned object of the present invention, the present invention adopts following technical scheme:
一种高强度彩色柔巾用水刺复合材料,包括重叠设置的梳理成网上层、纺粘中间层、梳理成网下层;A high-strength colored soft towel hydroentangled composite material, including a carded web layer, a spunbonded middle layer, and a carded web lower layer arranged overlappingly;
所述梳理成网上层和所述梳理成网下层均由彩色亲水纤维和常规纤维混合梳理而成;The upper layer of the carded net and the lower layer of the carded net are formed by mixing and carding colored hydrophilic fibers and conventional fibers;
所述纺粘中间层由并列双组分纤维热轧而成。The spunbond middle layer is hot-rolled from side-by-side bicomponent fibers.
本申请所述高强度彩色柔巾用水刺复合材料采用彩色亲水纤维避免了水刺材料后续颜色添加剂的应用,减少了对环境的污染,以及染色牢度性差的问题。此外,彩色亲水纤维的优异亲水性能赋予复合材料超吸水性能。The high-strength colored soft towel spunlace composite material described in this application uses colored hydrophilic fibers to avoid the application of subsequent color additives for spunlace materials, reduce environmental pollution, and the problems of poor color fastness. In addition, the excellent hydrophilic properties of the colored hydrophilic fibers endow the composites with superabsorbent properties.
梳理成网层与纺粘材料水刺加固后,纤网中的纤维与纺粘材料中的纤维发生位移、穿插、缠结、抱合,从而使梳理成网层和纺粘层牢固结合,使材料具有高强度,结构稳定的性能。After the carded web layer and the spunbond material are spunlace reinforced, the fibers in the fiber web and the fibers in the spunbond material are displaced, interspersed, entangled, and entangled, so that the carded web layer and the spunbond layer are firmly combined, and the material It has high strength and stable structure.
本申请所述复合材料采用的纺粘层为并列双组分纤维,通过热整理后低熔点组分与高熔点组分产生不同程度的收缩,形成螺旋卷曲结构,加固以后赋予水刺材料更好的蓬松性、手感以及透气性。The spunbonded layer used in the composite material described in this application is a side-by-side bi-component fiber. After heat treatment, the low-melting point component and the high-melting point component shrink to different degrees to form a spiral crimped structure, and the spunlace material is better after reinforcement. Fluffy, feel and breathability.
上述一种高强度彩色柔巾用水刺复合材料,作为一种优选的实施方案,所述梳理成网上层和所述梳理成网下层的纤维网克重均为40-200 g/m2,厚度均为5-20mm;纤维直径均为15-30μm;As a preferred embodiment of the above-mentioned high-strength colored soft towel spunlaced composite material, the weight of the fiber webs of the carded net layer and the carded net lower layer are both 40-200 g/m 2 , and the thickness is Both are 5-20mm; fiber diameters are all 15-30μm;
所述纺粘中间层纤维的直径为10-30μm,所述纺粘中间层纤维的克重为20-80 g/m2,厚度为2-10mm。The diameter of the spun-bonded middle layer fiber is 10-30 μm, the weight of the spun-bonded middle layer fiber is 20-80 g/m 2 , and the thickness is 2-10 mm.
上述一种高强度彩色柔巾用水刺复合材料,作为一种优选的实施方案,The above-mentioned high-strength colored soft towel spunlace composite material, as a preferred embodiment,
所述梳理成网上层由下述质量百分比的原料制成:彩色亲水纤维20%-80%、常规纤维20%-80%;The carded net layer is made of the following raw materials in mass percentage: 20%-80% of colored hydrophilic fibers, 20%-80% of conventional fibers;
所述彩色亲水纤维为PVA纤维;The colored hydrophilic fiber is a PVA fiber;
所述常规纤维为粘胶、PP纤维、PLA纤维、PET纤维或棉纤维中的至少一种;The conventional fiber is at least one of viscose, PP fiber, PLA fiber, PET fiber or cotton fiber;
所述梳理成网上层和所述梳理成网下层的材料相同;The materials of the carded upper layer and the lower layer of the carded net are the same;
所述纺粘中间层为并列双组分纤维,包括PP纤维/PE纤维、PP纤维/PET纤维或PA纤维/PP纤维。The spun-bonded middle layer is side-by-side bicomponent fibers, including PP fiber/PE fiber, PP fiber/PET fiber or PA fiber/PP fiber.
PVA纤维为聚乙烯醇纤维的简称,是以高聚合度的优质聚乙烯醇(PVA)为原料,加工而成的一种合成纤维。PVA纤维是强度高模量高、伸度低、耐磨、抗酸碱、耐候性好,与水泥、石膏等基材有良好的亲和力和结合性,且无毒、无污染、不损伤人体肌肤,对人体无害,是新一代高科技的绿色建材之一。PVA fiber is the abbreviation of polyvinyl alcohol fiber. It is a synthetic fiber processed from high-quality polyvinyl alcohol (PVA) with a high degree of polymerization. PVA fiber has high strength, high modulus, low elongation, wear resistance, acid and alkali resistance, and good weather resistance. It has good affinity and bonding with cement, gypsum and other substrates, and is non-toxic, non-polluting, and does not damage human skin. , harmless to the human body, is one of the new generation of high-tech green building materials.
粘胶纤维简称粘纤,是人造纤维的一种,粘胶纤维具有良好的吸湿性,在一般大气条件下,回潮率在13%左右,织物柔软、光滑、透气性好,穿着舒适,染色后色泽鲜艳、色牢度好。Viscose fiber, referred to as viscose fiber, is a kind of man-made fiber. Viscose fiber has good hygroscopicity. Under normal atmospheric conditions, the moisture regain is about 13%. The fabric is soft, smooth, and has good air permeability. Bright color, good color fastness.
PP纤维是聚丙烯纤维的简称,具有质轻、强度高、弹性好、耐磨、耐腐蚀的优点,且具有良好的耐热、耐老化性能。PP fiber is the abbreviation of polypropylene fiber, which has the advantages of light weight, high strength, good elasticity, wear resistance and corrosion resistance, and has good heat resistance and aging resistance.
PLA纤维一般指玉米纤维,是以玉米、小麦等淀粉为原料,经发酵转化成乳酸再经聚合,纺丝而制成的合成纤维。玉米纤维是以人体内含有的乳酸作原料合成的乳酸聚合物,对人体而言是绝对安全的。玉米纤维性能优越,有极好的悬垂性、滑爽性、吸湿透气性、天然抑菌和令皮肤放心的弱酸性、良好的耐热性及抗紫外线功能并富有光泽和弹性。PLA fiber generally refers to corn fiber, which is a synthetic fiber made from starch such as corn and wheat, which is fermented into lactic acid and then polymerized and spun. Corn fiber is a lactic acid polymer synthesized from lactic acid contained in the human body, which is absolutely safe for the human body. Corn fiber has superior performance, excellent drapability, smoothness, moisture absorption and air permeability, natural antibacterial and reassuring weak acidity for the skin, good heat resistance and anti-ultraviolet function, and is full of luster and elasticity.
PET纤维指聚酯纤维,是由有机二元酸和二元醇缩聚而成的聚酯经纺丝所得的合成纤维,属于高分子化合物。聚酯纤维最大的优点是抗皱性和保形性很好,具有较高的强度与弹性恢复能力。其坚牢耐用、抗皱免烫、不粘毛。PET fiber refers to polyester fiber, which is a synthetic fiber obtained by spinning polyester formed by polycondensation of organic dibasic acid and dibasic alcohol, and belongs to polymer compounds. The biggest advantage of polyester fiber is that it has good wrinkle resistance and shape retention, and has high strength and elastic recovery ability. It is strong and durable, anti-wrinkle and non-ironing, and non-sticky.
棉纤维是由受精胚珠的表皮细胞经伸长、加厚而成的种子纤维,不同于一般的韧皮纤维,它的主要组成物质是纤维素。棉纤维的强度高、透气性好、抗皱性差、拉伸性也较差;耐热性较好,仅次于麻;耐酸性差,在常温下耐稀碱;对染料具有良好的亲和力,染色容易,色谱齐全,色泽也比较鲜艳。Cotton fiber is a seed fiber formed by elongating and thickening the epidermal cells of fertilized ovules. It is different from ordinary bast fibers, and its main component is cellulose. Cotton fiber has high strength, good air permeability, poor wrinkle resistance, and poor stretchability; good heat resistance, second only to hemp; poor acid resistance, and dilute alkali resistance at room temperature; good affinity for dyes, easy to dye , the color spectrum is complete, and the color is relatively bright.
PE纤维为超高分子量聚乙烯纤维的简称,PE纤维具有很高的韧性,具有耐腐蚀、防紫外光的优点。PE fiber is the abbreviation of ultra-high molecular weight polyethylene fiber. PE fiber has high toughness, corrosion resistance and UV protection.
PA纤维是聚酰胺纤维的简称。机械强度高、韧性好、抗拉、抗压强度高。PA fiber is the abbreviation of polyamide fiber. High mechanical strength, good toughness, high tensile and compressive strength.
本申请的第二方面,提供一种高强度彩色柔巾用水刺复合材料的制备方法,包括以下步骤:The second aspect of the present application provides a method for preparing a high-strength colored soft towel spunlace composite material, comprising the following steps:
(1)制备梳理成网层:以彩色亲水纤维和常规纤维为原料通过罗拉式梳理机进行梳理成网;(1) Prepare the carded web layer: use colored hydrophilic fibers and conventional fibers as raw materials to form a web through a roller carding machine;
(2)制备纺粘中间层:通过并列双组分纺粘设备进行双组分纺丝,将双组分原料母粒分别投入两个螺杆挤出机,进行熔融挤出并经过滤、计量、喷丝、细流牵伸,铺设在成型网上形成网状结构,将形成的两个网状结构进行热轧黏合加固,对加固好的材料烘箱中热处理,获得螺旋卷曲结构双组分纺粘中间层;(2) Preparation of spunbond middle layer: Two-component spinning is carried out through parallel two-component spunbond equipment, and two-component raw material masterbatches are respectively put into two screw extruders for melt extrusion and filtered, metered, Spinning, fine-flow drafting, laying on the forming net to form a network structure, the two formed network structures are hot-rolled and bonded for reinforcement, and the reinforced material is heat-treated in an oven to obtain a two-component spunbond intermediate with a spiral crimp structure layer;
(3)水刺复合加固:将步骤(1)所得梳理成网层,步骤(2)所得纺粘中间层、步骤(1)所得梳理成网层由下往上重叠放置在水刺托网帘上,通过水刺设备对其加固,使得纤维层之间相互穿插、缠结复合为一体;(3) Spunlace composite reinforcement: The carded net layer obtained in step (1), the spunbond intermediate layer obtained in step (2), and the carded net layer obtained in step (1) are stacked on the hydroentangled web curtain from bottom to top On the other hand, it is reinforced by spunlace equipment, so that the fiber layers are interspersed with each other, entangled and combined into one;
(4)烘干整理:将水刺后的材料经轧辊挤压去除水分,再经烘燥、成卷处理,得所述水刺复合材料。(4) Drying and finishing: the spunlace composite material is obtained by extruding the spunlaced material to remove moisture, and then drying and coiling.
上述一种高强度彩色柔巾用水刺复合材料的制备方法,作为一种优选的实施方案,步骤(1)中,所述彩色亲水纤维的长度为38mm或53mm,所述彩色亲水纤维的直径为15-30μm;The above-mentioned method for preparing a high-strength colored soft towel spunlace composite material, as a preferred embodiment, in step (1), the length of the colored hydrophilic fiber is 38mm or 53mm, and the length of the colored hydrophilic fiber 15-30μm in diameter;
所述常规纤维的长度为38mm或53mm,所述常规纤维的直径为15-30μm。The length of the conventional fiber is 38 mm or 53 mm, and the diameter of the conventional fiber is 15-30 μm.
上述一种高强度彩色柔巾用水刺复合材料的制备方法,作为一种优选的实施方案,步骤(2)中,两种组分纺丝时计量泵转速比为1:1,热轧黏合的温度为100-160℃,热处理的温度为100-160℃,热处理的时间为1-3min。As a preferred embodiment of the above-mentioned method for preparing a high-strength colored soft towel spunlaced composite material, in step (2), the speed ratio of the metering pump during spinning of the two components is 1:1, and the hot-rolled and bonded The temperature is 100-160°C, the heat treatment temperature is 100-160°C, and the heat treatment time is 1-3min.
上述一种高强度彩色柔巾用水刺复合材料的制备方法,作为一种优选的实施方案,步骤(3)中,水刺压力为2-5 MPa,水刺头个数为1-4个,水刺道数为正反各1-3道。As a preferred embodiment of the method for preparing a high-strength colored soft towel spunlace composite material, in step (3), the spunlace pressure is 2-5 MPa, and the number of spunlace heads is 1-4. The number of spunlace passes is 1-3 for the front and back.
上述一种高强度彩色柔巾用水刺复合材料的制备方法,作为一种优选的实施方案,步骤(4)中,所述烘燥为采用烘房烘燥,烘燥温度为50℃-80℃,烘燥时间为1-5 min。The above-mentioned method for preparing a high-strength colored soft towel spunlaced composite material, as a preferred embodiment, in step (4), the drying is drying in a drying room, and the drying temperature is 50°C-80°C , drying time is 1-5 min.
本发明的有益效果为:The beneficial effects of the present invention are:
1、本发明所述高强度彩色柔巾用水刺复合材料的色彩来源于PVA纤维,避免了水刺复合材料后续的染色操作,避免了染色添加剂的应用,解决了染色牢度性差的问题,及染色剂所带来的环境污染问题。1. The color of the high-strength colored soft towel spunlace composite material of the present invention comes from PVA fiber, which avoids the subsequent dyeing operation of the spunlace composite material, avoids the application of dyeing additives, and solves the problem of poor color fastness, and Environmental pollution problems caused by dyes.
2、本发明所述高强度彩色柔巾用水刺复合材料的梳理成网层与纺粘中间层加固后,梳理成网层中的纤维与纺粘材料中的纤维发生位移、穿插、缠结、抱合,从而使梳理成网层和纺粘层牢固结合,使材料具有高强度,结构稳定的性能。2. After the carded layer of the high-strength colored soft towel of the present invention is reinforced with the spunbonded intermediate layer of the spunlace composite material, the fibers in the carded layer and the fibers in the spunbond material are displaced, interspersed, entangled, Cohesion, so that the carded layer and the spunbonded layer are firmly combined, so that the material has high strength and stable structure.
3、本发明所述高强度彩色柔巾用水刺复合材料采用的纺粘材料为并列双组分纤维,通过热整理后低熔点组分与高熔点组分产生不同程度的收缩,形成螺旋卷曲结构,加固以后赋予水刺材料更好的蓬松性、手感以及透气性。3. The spunbond material used in the high-strength colored soft towel spunlace composite material of the present invention is a side-by-side two-component fiber, and the low-melting point component and the high-melting point component shrink to different degrees after heat treatment to form a spiral crimp structure , After reinforcement, the spunlace material has better bulkiness, hand feeling and air permeability.
4、本发明所述高强度彩色柔巾用水刺复合材料的制备方法简单,便于工业化推广。4. The preparation method of the high-strength colored soft towel spunlaced composite material of the present invention is simple and convenient for industrialization.
具体实施方式Detailed ways
为使本发明的目的、技术方案和优点更加清楚,下面将对本发明的技术方案进行详细的描述。显然,所描述的实施例仅仅是本发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所得到的所有其它实施方式,都属于本发明所保护的范围。In order to make the purpose, technical solution and advantages of the present invention clearer, the technical solution of the present invention will be described in detail below. Apparently, the described embodiments are only some of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other implementations obtained by persons of ordinary skill in the art without making creative efforts fall within the protection scope of the present invention.
本发明所述一种高强度彩色柔巾用水刺复合材料的色彩来源于原料本身,在后期无需染色,且梳理成网层和纺粘中间层加固后梳理成网层中的纤维与纺粘材料中的纤维发生位移、穿插、缠结、抱合,从而使梳理成网层和纺粘层牢固结合,使材料具有高强度,结构稳定的性能。The color of a high-strength colored soft towel spunlaced composite material in the present invention comes from the raw material itself, and no dyeing is required in the later stage, and the fiber and spunbond material in the carded web layer and the spunbond intermediate layer are reinforced after being carded into the web layer The fibers in the fiber are displaced, interspersed, entangled, and entangled, so that the carded layer and the spunbond layer are firmly combined, so that the material has high strength and stable structure.
实施例1Example 1
实施例1所述一种高强度彩色柔巾用水刺复合材料,包括梳理成网上层、纺粘中间层、梳理成网下层,三层材料层叠水刺加固而成。The high-strength colored soft towel described in Example 1 is a hydroentangled composite material, which comprises a carded web layer, a spunbond middle layer, and a carded web lower layer, and is formed by stacking and hydroentangled reinforcement of three layers of materials.
梳理成网上层和所述梳理成网下层均由彩色亲水纤维和常规纤维混合梳理而成;纺粘中间层由并列双组分纤维热轧而成;The upper layer of the carded web and the lower layer of the carded web are both formed by mixing and carding colored hydrophilic fibers and conventional fibers; the spun-bonded middle layer is formed by hot rolling of side-by-side bi-component fibers;
梳理成网上层和梳理成网下层的纤维网克重为40 g/m2,厚度均为5 mm,采用的彩色亲水纤维为PVA纤维,PVA纤维质量占混合纤维的比例为20%,常规纤维为PP纤维,PP纤维质量占混合纤维的比例为80%;The weight of the fiber web carded into the upper layer and the lower layer of the carded web is 40 g/m 2 , and the thickness is 5 mm. The colored hydrophilic fiber used is PVA fiber, and the proportion of PVA fiber to the mixed fiber is 20%. Conventional The fiber is PP fiber, and the mass of PP fiber accounts for 80% of the mixed fiber;
纺粘中间层为并列双组分纤维热轧加固而成,PP纤维/PET纤维( PP纤维和PET纤维的用量比例为1:1),纺粘中间层纤维直径为15μm,克重为20 g/m2,厚度为2 mm。纺粘中间层纤维具有螺旋卷曲结构,自然状态下卷曲数为1个/cm。The spun-bonded middle layer is made of side-by-side bi-component fibers hot-rolled and reinforced, PP fiber/PET fiber (the ratio of PP fiber to PET fiber is 1:1), the fiber diameter of the spun-bonded middle layer is 15 μm, and the weight is 20 g /m 2 , with a thickness of 2 mm. The fibers of the spunbonded middle layer have a helical crimp structure, and the number of crimps in the natural state is 1/cm.
实施例1所述一种高强度彩色柔巾用水刺复合材料的制备方法,包括以下步骤:The preparation method of a kind of high-strength colored soft towel spunlaced composite material described in embodiment 1 comprises the following steps:
(1)制备梳理成网层:以彩色亲水PVA纤维和常规PP纤维为原料通过罗拉式梳理机进行梳理成网,彩色亲水PVA纤维长度为38 mm,纤维直径为15 μm,PP纤维长度为38 mm,纤维直径18μm,PVA纤维质量占混合纤维的比例为20%,PP纤维质量占混合纤维的比例为80%,调节纤维喂入量控制纤网克重和厚度,以梳理好的纤维网(梳理成网层的纤维克重为40 g/m2,厚度均为5 mm,纤维直径均为15μm)作为水刺复合材料的梳理成网上层和梳理成网下层;(1) Preparation of the carded web layer: the colored hydrophilic PVA fiber and conventional PP fiber were used as raw materials to be carded into a web by a roller carding machine. The length of the colored hydrophilic PVA fiber was 38 mm, the fiber diameter was 15 μm, and the length of the PP fiber was The fiber diameter is 38 mm, the fiber diameter is 18 μm, the proportion of PVA fiber mass to the mixed fiber is 20%, and the proportion of PP fiber mass to the mixed fiber is 80%. The web (the fiber weight of the carded web layer is 40 g/m 2 , the thickness is 5 mm, and the fiber diameter is 15 μm) is used as the carded web layer and the carded web lower layer of the spunlace composite material;
(2)制备纺粘中间层:通过并列型双组分纺粘设备进行双组分纺丝,将PP纤维和PET纤维母粒分别投入两个螺杆挤出机,进行熔融挤出并经过滤、计量、喷丝、细流牵伸,两种组分纺丝时计量泵转速比为1:1,长丝铺设在成型网上形成网状结构,然后再进行热轧黏合加固,热轧黏合温度为150℃,最后对加固好的材料烘箱中热处理,热处理温度为155℃,处理1min获得螺旋卷曲结构双组分纺粘中间层;(2) Preparation of spun-bonded middle layer: Two-component spinning is carried out through parallel two-component spunbond equipment, and PP fiber and PET fiber masterbatch are respectively put into two screw extruders for melt extrusion and filtered, Metering, spinning, and fine-flow drafting. The speed ratio of the metering pump is 1:1 when the two components are spinning. The filaments are laid on the forming net to form a network structure, and then hot-rolled and bonded for reinforcement. The hot-rolled bonding temperature is 150°C, and finally heat-treat the reinforced material in an oven at a temperature of 155°C for 1 minute to obtain a two-component spunbonded middle layer with a spiral crimp structure;
(3)水刺复合加固:将步骤(1)所得梳理成网层、步骤(2)所得纺粘中间层、步骤(1)所得梳理成网层由下往上重叠放置在水刺托网帘上,通过水刺设备对其加固,使得纤维层之间相互穿插、缠结后复合为一体;水刺压力为2 MPa,水刺头个数为1,水刺道数为正反各1道;(3) Spunlace composite reinforcement: The carded net layer obtained in step (1), the spunbond intermediate layer obtained in step (2), and the carded net layer obtained in step (1) are stacked on the hydroentangled web curtain from bottom to top On top, it is reinforced by spunlace equipment, so that the fiber layers are interspersed with each other, entangled and combined into one; the spunlace pressure is 2 MPa, the number of spunlace heads is 1, and the number of spunlace passes is 1 for the front and back. ;
(4)烘干整理:将水刺后的材料通过轧辊挤压去除水分,再经过烘燥、成卷处理,制成水刺复合材料,采用烘房烘燥,烘燥的温度为75℃,烘燥时间为2 min。(4) Drying and finishing: the spunlaced material is squeezed to remove water by rollers, and then dried and coiled to make a spunlace composite material, which is dried in a drying room at a temperature of 75°C. The drying time is 2 min.
实施例2Example 2
实施例2所述一种高强度彩色柔巾用水刺复合材料,包括梳理成网上层、纺粘中间层、梳理成网下层,三层材料层叠水刺加固而成。The high-strength colored soft towel described in Example 2 is a spunlace composite material, which comprises a carded web layer, a spunbonded middle layer, and a carded web lower layer, and is formed by stacking and spunlace reinforcement of three layers of materials.
梳理成网上层和所述梳理成网下层均由彩色亲水纤维和常规纤维混合梳理而成;纺粘中间层由并列双组分纤维热轧而成;The upper layer of the carded web and the lower layer of the carded web are both formed by mixing and carding colored hydrophilic fibers and conventional fibers; the spun-bonded middle layer is formed by hot rolling of side-by-side bi-component fibers;
梳理成网上层和梳理成网下层的纤维网克重为100 g/m2,厚度均为11 mm,采用的彩色亲水纤维为PVA纤维,PVA纤维质量占混合纤维的比例为50%,常规纤维为粘胶纤维,粘胶纤维质量占混合纤维的比例为50%;The weight of the fiber webs carded into the upper layer and the lower layer of the carded web is 100 g/m 2 , and the thickness is 11 mm. The colored hydrophilic fibers used are PVA fibers, and the proportion of PVA fibers to the mixed fibers is 50%. The fiber is viscose fiber, and the mass of viscose fiber accounts for 50% of the mixed fiber;
纺粘中间层为并列双组分纤维热轧加固而成,PP纤维/PA纤维(PP纤维和PA纤维的用量比为1:1),纺粘中间层纤维直径为20μm,克重为40g/m2,厚度为4mm。纺粘中间层纤维具有螺旋卷曲结构,自然状态下卷曲数为2个/cm。The spun-bonded middle layer is made of side-by-side two-component fibers hot-rolled and reinforced, PP fiber/PA fiber (the ratio of PP fiber to PA fiber is 1:1), the fiber diameter of the spun-bonded middle layer is 20μm, and the weight is 40g/ m 2 and a thickness of 4mm. The fibers of the spunbonded middle layer have a helical crimp structure, and the number of crimps in the natural state is 2/cm.
实施例2所述一种高强度彩色柔巾用水刺复合材料的制备方法,包括以下步骤:The preparation method of a kind of high-strength colored soft towel spunlace composite material described in embodiment 2 comprises the following steps:
(1)制备梳理成网层:以彩色亲水PVA纤维和常规粘胶纤维为原料通过罗拉式梳理机进行梳理成网,彩色亲水PVA纤维长度为38 mm,纤维直径为20μm,粘胶纤维长度为38 mm,纤维直径为25μm,PVA纤维质量占混合纤维的比例为50%,粘胶纤维质量占混合纤维的比例为50%,调节纤维喂入量控制纤网克重和厚度,以梳理好的纤维网(梳理成网层的纤维克重为100g/m2,厚度均为11 mm,纤维直径均为20μm )作为水刺复合材料的梳理成网上层和梳理成网下层;(1) Preparation of the carded web layer: the colored hydrophilic PVA fiber and conventional viscose fiber were used as raw materials to be carded into a web by a roller carding machine. The length of the colored hydrophilic PVA fiber was 38 mm, the fiber diameter was 20 μm, and the viscose fiber The length is 38 mm, the fiber diameter is 25 μm, the proportion of PVA fiber mass to the mixed fiber is 50%, the proportion of viscose fiber mass to the mixed fiber is 50%, and the fiber feeding amount is adjusted to control the weight and thickness of the fiber web to card A good fiber web (the fiber weight of the carded web layer is 100g/m 2 , the thickness is 11 mm, and the fiber diameter is 20 μm) is used as the carded web layer and the carded web lower layer of the spunlace composite material;
(2)制备纺粘中间层:通过并列型双组分纺粘设备进行双组分纺丝,将PP纤维和PA纤维母粒分别投入两个螺杆挤出机,进行熔融挤出并经过滤、计量、喷丝、细流牵伸,两种组分纺丝时计量泵转速比为1:1,长丝铺设在成型网上形成网状结构,然后再进行热轧黏合加固,热轧黏合温度为155℃,最后对加固好的材料烘箱中热处理,热处理温度为160℃,处理1.5min获得螺旋卷曲结构双组分纺粘中间层;(2) Preparation of spunbond middle layer: Two-component spinning is carried out through parallel two-component spunbond equipment, PP fiber and PA fiber masterbatch are respectively put into two screw extruders, melt-extruded and filtered, Metering, spinning, and fine-flow drafting. The speed ratio of the metering pump is 1:1 when the two components are spinning. The filaments are laid on the forming net to form a network structure, and then hot-rolled and bonded for reinforcement. The hot-rolled bonding temperature is 155°C, and finally heat-treat the reinforced material in an oven at a temperature of 160°C for 1.5 minutes to obtain a two-component spunbonded middle layer with a spiral crimp structure;
(3)水刺复合加固:将步骤(1)所得梳理成网层、步骤(2)所得纺粘中间层、步骤(1)所得梳理成网层由下往上重叠放置在水刺托网帘上,通过水刺设备对其加固,使得纤维层之间相互穿插、缠结后复合为一体;水刺压力为3.5 MPa,水刺头个数为2,水刺道数为正反各2道;(3) Spunlace composite reinforcement: The carded net layer obtained in step (1), the spunbond intermediate layer obtained in step (2), and the carded net layer obtained in step (1) are stacked on the hydroentangled web curtain from bottom to top Above, it is reinforced by spunlace equipment, so that the fiber layers are interspersed with each other, entangled and combined into one; the spunlace pressure is 3.5 MPa, the number of spunlace heads is 2, and the number of spunlace passes is 2 for the front and back. ;
(4)烘干整理:将水刺后的材料通过轧辊挤压去除水分,再经过烘燥、成卷处理,制成水刺复合材料,采用烘房烘燥,烘燥的温度为55℃,烘燥时间为3 min。(4) Drying and finishing: the spunlaced material is squeezed to remove water by rollers, and then dried and coiled to make a spunlace composite material, which is dried in a drying room at a temperature of 55°C. The drying time is 3 min.
实施例3Example 3
实施例3所述一种高强度彩色柔巾用水刺复合材料,包括梳理成网上层、纺粘中间层、梳理成网下层,三层材料层叠水刺加固而成。A high-strength colored soft towel spunlace composite material described in Example 3 comprises a carded web layer, a spunbonded middle layer, a carded web lower layer, and three layers of materials laminated and reinforced with spunlace.
梳理成网上层和所述梳理成网下层均由彩色亲水纤维和常规纤维混合梳理而成;纺粘中间层由并列双组分纤维热轧而成;The upper layer of the carded web and the lower layer of the carded web are both formed by mixing and carding colored hydrophilic fibers and conventional fibers; the spun-bonded middle layer is formed by hot rolling of side-by-side bi-component fibers;
梳理成网上层和梳理成网下层的纤维网克重为200 g/m2,厚度均为20 mm,采用的彩色亲水纤维为PVA纤维,PVA纤维质量占混合纤维的比例为80%,常规纤维为PLA纤维,粘胶纤维质量占混合纤维的比例为20%;The weight of the fiber webs carded into the upper layer and the lower layer of the carded web is 200 g/m 2 , and the thickness is 20 mm. The colored hydrophilic fibers used are PVA fibers, and the proportion of PVA fibers to the mixed fibers is 80%. The fiber is PLA fiber, and the mass of viscose fiber accounts for 20% of the mixed fiber;
纺粘中间层为并列双组分纤维热轧加固而成,PP纤维/PE纤维(PP纤维和PE纤维的用量比为1:1) ,纺粘中间层纤维直径为20μm,克重为60g/m2,厚度为6mm。纺粘中间层纤维具有螺旋卷曲结构,自然状态下卷曲数为4个/cm。The spun-bonded middle layer is made of side-by-side two-component fibers hot-rolled and reinforced, PP fiber/PE fiber (the ratio of PP fiber to PE fiber is 1:1), the fiber diameter of the spun-bonded middle layer is 20μm, and the weight is 60g/ m 2 and a thickness of 6mm. The fibers of the spunbonded middle layer have a helical crimp structure, and the number of crimps in the natural state is 4/cm.
实施例3所述一种高强度彩色柔巾用水刺复合材料的制备方法,包括以下步骤:The preparation method of a kind of high-strength colored soft towel spunlace composite material described in embodiment 3 comprises the following steps:
(1)制备梳理成网层:以彩色亲水PVA纤维和常规PLA纤维为原料通过罗拉式梳理机进行梳理成网,彩色亲水PVA纤维长度为53 mm,纤维直径为25μm,PLA纤维长度为53mm,纤维直径为30μm,PVA纤维质量占混合纤维的比例为80%,PLA纤维质量占混合纤维的比例为20%,调节纤维喂入量控制纤网克重和厚度,以梳理好的纤维网(梳理成网层的纤维克重为200g/m2,厚度均为20mm,纤维直径均为30μm)作为水刺复合材料的梳理成网上层和梳理成网下层;(1) Preparation of the carded web layer: the colored hydrophilic PVA fiber and conventional PLA fiber were used as raw materials to be carded into a web by a roller carding machine. The length of the colored hydrophilic PVA fiber was 53 mm, the fiber diameter was 25 μm, and the length of the PLA fiber was 53mm, fiber diameter 30μm, PVA fiber mass accounted for 80% of the mixed fiber, PLA fiber mass accounted for 20% of the mixed fiber, adjust the fiber feeding amount to control the weight and thickness of the fiber web, to ensure that the carded fiber web (The fiber weight of the carded web layer is 200g/m 2 , the thickness is 20mm, and the fiber diameter is 30μm) as the carded web layer and the carded web lower layer of the spunlace composite material;
(2)制备纺粘中间层:通过并列型双组分纺粘设备进行双组分纺丝,将PP纤维和PE纤维母粒分别投入两个螺杆挤出机,进行熔融挤出并经过滤、计量、喷丝、细流牵伸,两种组分纺丝时计量泵转速比为1:1,长丝铺设在成型网上形成网状结构,然后再进行热轧黏合加固,热轧黏合温度为115℃,最后对加固好的材料烘箱中热处理,热处理温度为110℃,处理2.5min获得螺旋卷曲结构双组分纺粘中间层;(2) Preparation of spunbond middle layer: Two-component spinning is carried out through parallel two-component spunbond equipment, and PP fiber and PE fiber masterbatch are respectively put into two screw extruders for melt extrusion and filtered, Metering, spinning, and fine-flow drafting. The speed ratio of the metering pump is 1:1 when the two components are spinning. The filaments are laid on the forming net to form a network structure, and then hot-rolled and bonded for reinforcement. The hot-rolled bonding temperature is 115°C, and finally heat-treat the reinforced material in an oven at a temperature of 110°C for 2.5 minutes to obtain a two-component spunbonded middle layer with a spiral crimp structure;
(3)水刺复合加固:将步骤(1)所得梳理成网层、步骤(2)所得纺粘中间层、步骤(1)所得梳理成网层由下往上重叠放置在水刺托网帘上,通过水刺设备对其加固,使得纤维层之间相互穿插、缠结后复合为一体;水刺压力为5 MPa,水刺头个数为3,水刺道数为正反各3道;(3) Spunlace composite reinforcement: The carded net layer obtained in step (1), the spunbond intermediate layer obtained in step (2), and the carded net layer obtained in step (1) are stacked on the hydroentangled web curtain from bottom to top On the surface, it is reinforced by spunlace equipment, so that the fiber layers are interspersed with each other, entangled and combined into one; the spunlace pressure is 5 MPa, the number of spunlace heads is 3, and the number of spunlace passes is 3 for each front and back ;
(4)烘干整理:将水刺后的材料通过轧辊挤压去除水分,再经过烘燥、成卷处理,制成水刺复合材料,采用烘房烘燥,烘燥的温度为55℃,烘燥时间为5 min。(4) Drying and finishing: the spunlaced material is squeezed to remove water by rollers, and then dried and coiled to make a spunlace composite material, which is dried in a drying room at a temperature of 55°C. The drying time is 5 min.
对比例1Comparative example 1
对比例1所述一种高强度彩色柔巾用水刺复合材料与实施例1所述一种高强度彩色柔巾用水刺复合材料不同之处在于:对比例1所述梳理成网上层和所述梳理成网下层均为彩色亲水PVA纤维层,其余材料及制备方法均与实施例1相同。The difference between a high-strength colored soft towel spunlaced composite material described in Comparative Example 1 and a high-strength colored soft towel spunlaced composite material described in Example 1 is that the carded net layer described in Comparative Example 1 and the The lower layer of the carded net is a colored hydrophilic PVA fiber layer, and all the other materials and preparation methods are the same as in Example 1.
对比例2Comparative example 2
对比例2所述一种高强度彩色柔巾用水刺复合材料与实施例1所述一种高强度彩色柔巾用水刺复合材料不同之处在于:对比例2所述复合材料不含纺粘中间层。其余材料与制备方法均与实施例1相同。The difference between the high-strength colored soft towel spunlace composite material described in Comparative Example 2 and the high-strength colored soft towel spunlace composite material described in Example 1 is that the composite material described in Comparative Example 2 does not contain spunbond intermediates. layer. All the other materials and preparation method are the same as in Example 1.
本申请所述一种高强度彩色柔巾用水刺复合材料的性能研究,研究结果如表1所示:The performance research of a high-strength colored soft towel spunlaced composite material described in this application, the research results are shown in Table 1:
表1Table 1
从表1可以看出:本申请所述高强度彩色柔巾用水刺复合材料具有较好的断裂强度,且吸水率和透气性优于对比例1和对比例2所述复合材料。It can be seen from Table 1 that the high-strength colored soft towel spunlaced composite material described in this application has better breaking strength, and the water absorption rate and air permeability are better than the composite materials described in Comparative Example 1 and Comparative Example 2.
且对比例1的断裂强度、透气性均低于本申请所述复合材料;And the breaking strength and gas permeability of Comparative Example 1 are all lower than the composite material described in this application;
但从表1数据可以看出,实施例1与对比例1相比,纯PVA纤维网的吸水性会稍好一些,但对比例1与实施例2、3相比,吸水率明显偏低,但是实验的时候,纯PVA不宜梳理,均匀性差,材料强力相较于实施1更低,故而复合设置更易提高材料的综合特性。But can find out from table 1 data, embodiment 1 compares with comparative example 1, the water absorption of pure PVA fiber net can be slightly better, but comparative example 1 compares with embodiment 2,3, and water absorption is obviously on the low side, However, during the experiment, pure PVA is not suitable for combing, the uniformity is poor, and the material strength is lower than that of implementation 1, so the composite setting is easier to improve the comprehensive characteristics of the material.
对比例2所述复合材料不含中间的纺粘层,其断裂强度、吸水率和透气性均低于本申请所述复合材料。The composite material described in Comparative Example 2 does not contain an intermediate spunbond layer, and its breaking strength, water absorption rate and air permeability are all lower than those of the composite material described in the present application.
并且,针对实施例1-3的数据对比可以发现,采用亲水PVA纤维比例较高,吸水性好,强力高;克重大,强力高,但透气性降低不明显。Moreover, according to the data comparison of Examples 1-3, it can be found that the proportion of hydrophilic PVA fiber is higher, the water absorption is good, and the strength is high; the weight is heavy, the strength is high, but the air permeability is not significantly reduced.
且结合实施例1和实施例3的数据对比,纵向断裂强度明显增大。And combined with the comparison of the data of Example 1 and Example 3, the longitudinal fracture strength is obviously increased.
同时,本方案相比较与对比例1和对比例2,在透气性能上提升明显,保证材料强度的同时,更具备优异的透气性能。At the same time, compared with Comparative Example 1 and Comparative Example 2, this solution has significantly improved air permeability, and has excellent air permeability while ensuring the strength of the material.
综上所述,本发明所述高强度彩色柔巾用水刺复合材料的色彩来源于PVA纤维,避免了水刺复合材料后续的染色操作,避免了染色添加剂的应用,解决了染色牢度性差的问题,及染色剂所带来的环境污染问题。In summary, the color of the high-strength colored soft towel spunlace composite material of the present invention comes from PVA fibers, which avoids the subsequent dyeing operation of the spunlace composite material, avoids the application of dyeing additives, and solves the problem of poor color fastness. problems, and the environmental pollution problems caused by dyes.
本发明所述高强度彩色柔巾用水刺复合材料的梳理成网层与纺粘中间层加固后,梳理成网层中的纤维与纺粘材料中的纤维发生位移、穿插、缠结、抱合,从而使梳理成网层和纺粘层牢固结合,使材料具有高强度,结构稳定的性能。After the carded layer of the high-strength colored soft towel of the present invention is reinforced with the spunbonded intermediate layer of the spunlace composite material, the fibers in the carded layer and the fibers in the spunbonded material are displaced, interspersed, entangled, and entangled. Thus, the carded layer and the spunbonded layer are firmly combined, so that the material has high strength and stable structure.
本发明所述高强度彩色柔巾用水刺复合材料采用的纺粘材料为并列双组分纤维,通过热整理后低熔点组分与高熔点组分产生不同程度的收缩,形成螺旋卷曲结构,加固以后赋予水刺材料更好的蓬松性、手感以及透气性。The spunbond material used in the high-strength colored soft towel spunlaced composite material of the present invention is a side-by-side bicomponent fiber, and the low-melting-point component and the high-melting-point component shrink to different degrees after heat treatment to form a spiral crimped structure and strengthen In the future, the spunlace material will be given better bulkiness, hand feeling and air permeability.
以上所述仅为本申请的优选实施例而已,并不用于限制本申请,对于本领域的技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本申请的保护范围之内。The above descriptions are only preferred embodiments of the present application, and are not intended to limit the present application. For those skilled in the art, there may be various modifications and changes in the present application. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of this application shall be included within the protection scope of this application.
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