CN115637583A - Antibacterial and hydrophilic treatment process for burnt-out velvet fabric - Google Patents
Antibacterial and hydrophilic treatment process for burnt-out velvet fabric Download PDFInfo
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- CN115637583A CN115637583A CN202211251520.0A CN202211251520A CN115637583A CN 115637583 A CN115637583 A CN 115637583A CN 202211251520 A CN202211251520 A CN 202211251520A CN 115637583 A CN115637583 A CN 115637583A
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- 239000004744 fabric Substances 0.000 title description 45
- 230000000844 anti-bacterial effect Effects 0.000 title description 10
- 238000000034 method Methods 0.000 title description 8
- 230000008569 process Effects 0.000 title description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 22
- 239000004408 titanium dioxide Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 238000010409 ironing Methods 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229920001661 Chitosan Polymers 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000012362 glacial acetic acid Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 2
- 238000003980 solgel method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 208000035143 Bacterial infection Diseases 0.000 description 1
- 208000008454 Hyperhidrosis Diseases 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 208000013460 sweaty Diseases 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
技术领域technical field
本发明涉及烂花绒面料的生产技术领域,更具体地说,本发明涉及一种烂花绒面料的抗菌亲水处理工艺。The invention relates to the technical field of production of burnt-out velvet fabrics, more specifically, the invention relates to an antibacterial and hydrophilic treatment process for burnt-out velvet fabrics.
背景技术Background technique
随着人们生活节奏的加快和对运动旅游的重视,人体微环境的湿热严重影响了人们着衣的舒适度。导湿排汗类纺织品成为当今消费时尚,其需求呈上升趋势,这一庞大的目标群体对纺织业来说是一个充满诱惑力的巨大市场。With the acceleration of people's life rhythm and the emphasis on sports tourism, the humidity and heat of the human microenvironment have seriously affected the comfort of people's clothing. Moisture-wicking and sweat-wicking textiles have become the fashion of today's consumption, and their demand is on the rise. This huge target group is a huge market full of temptation for the textile industry.
一般导湿排汗的烂花绒面料由于其所处的湿热环境,加之纤维表面的沟槽状结构,为细菌滋生繁衍提供了理想环境,使穿着者更容易遭受细菌感染产生异味,或者汗液直接产生汗臭味。开发舒适健康与清洁安全为基调的导湿排汗、抗菌消臭自清洁复合保健功能的烂花绒面料,将有着广阔的市场前景,鉴于此,本发明提出一种烂花绒面料亲水抗菌的处理工艺。Generally, the moisture-wicking burnt-out velvet fabric provides an ideal environment for the growth and reproduction of bacteria due to its hot and humid environment and the groove-like structure on the fiber surface, making the wearer more susceptible to bacterial infection and odor, or sweat directly Produces a sweaty odor. The development of burnt-out velvet fabrics with moisture-wicking, anti-bacterial, deodorizing and self-cleaning composite health care functions based on comfort, health, cleanliness and safety will have broad market prospects. In view of this, the present invention proposes a burnt-out velvet fabric that is hydrophilic and antibacterial treatment process.
发明内容Contents of the invention
为了克服现有技术的上述缺陷,本发明的实施例提供一种烂花绒面料的抗菌亲水处理工艺。In order to overcome the above-mentioned defects of the prior art, an embodiment of the present invention provides an antibacterial and hydrophilic treatment process for burnt-out velvet fabrics.
为实现上述目的,本发明创新点如下:具体包括以下步骤:In order to achieve the above object, the innovation of the present invention is as follows: specifically comprising the following steps:
S1、制备改性多元羧酸并对面料进行交联处理;S1, preparing modified polycarboxylic acid and cross-linking the fabric;
S2、制备二氧化钛整理剂并对面料进行浸轧处理;S2, preparing a titanium dioxide finishing agent and padding the fabric;
S3、采用等离子烘干机对面料进行烘干处理;S3, using a plasma dryer to dry the fabric;
在步骤S1中,改性多元羧酸是由多种多元羧酸、壳聚糖、次亚磷酸钠混合而成,并在190℃下作用90s;In step S1, the modified polycarboxylic acid is formed by mixing various polycarboxylic acids, chitosan, and sodium hypophosphite, and acts at 190°C for 90s;
在步骤S2中,二氧化钛整理剂是通过溶胶-凝胶法制备而成,并以钛酸丁酯、无水乙醇、冰醋酸、去离子水为原料制备而成。In step S2, the titanium dioxide finishing agent is prepared by a sol-gel method, and is prepared from butyl titanate, absolute ethanol, glacial acetic acid, and deionized water as raw materials.
进一步的,在步骤S2中,优先对所述面料进行去烫平处理。Further, in step S2, the fabric is preferentially de-ironed.
进一步的,上述面料的烫平处理步骤如下:Further, the ironing treatment steps of the above-mentioned fabrics are as follows:
A、将面料进行浸湿处理;A. Soak the fabric;
B、将浸湿后的面料在90℃下进行半烘干,此时面料处于半湿润状态;B. Semi-dry the soaked fabric at 90°C, and the fabric is in a semi-wet state at this time;
C、将半湿润状态的面料在烫平机下进行烫平处理。C. Iron the semi-wet fabric under the ironing machine.
进一步的,在步骤C中,烫平机分别对半湿润状态面料的正反两面进行烫平处理。Further, in step C, the ironing machine performs ironing treatment on both sides of the fabric in a semi-wet state, respectively.
进一步的,上述钛酸丁酯、无水乙醇、冰醋酸、去离子水之间的摩尔比为:1:25:5:0.5,在经过密封放置陈化15h以后,以450℃进行焙烧得到二氧化钛粉末。Further, the molar ratio between the above-mentioned butyl titanate, absolute ethanol, glacial acetic acid, and deionized water is: 1:25:5:0.5, after being sealed and aged for 15 hours, roasting at 450°C to obtain titanium dioxide powder.
本发明的技术效果和优点:通过多元羧酸对烂花绒面料的改性,使涤纶纤维负载羧基,纳米二氧化钛和等离子复合整理,能够得到亲水性和抗菌性的舒适保健功能烂花绒面料。The technical effects and advantages of the present invention: through the modification of the burnt-out velvet fabric with polycarboxylic acid, the polyester fiber is loaded with carboxyl groups, nano-titanium dioxide and plasma composite finishing, and the comfortable and health-care burnt-out velvet fabric with hydrophilicity and antibacterial properties can be obtained .
具体实施方式Detailed ways
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below. Obviously, the described embodiments are only some of the embodiments of the present invention, but not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
本发明提供了一种烂花绒面料的抗菌亲水处理工艺,具体包括以下步骤:The invention provides an antibacterial and hydrophilic treatment process for burnt-out velvet fabrics, which specifically includes the following steps:
S1、制备改性多元羧酸并对面料进行交联处理;S1, preparing modified polycarboxylic acid and cross-linking the fabric;
S2、制备二氧化钛整理剂并对面料进行浸轧处理;S2, preparing a titanium dioxide finishing agent and padding the fabric;
S3、采用等离子烘干机对面料进行烘干处理;S3, using a plasma dryer to dry the fabric;
在步骤S1中,改性多元羧酸是由多种多元羧酸、壳聚糖、次亚磷酸钠混合而成,并在190℃下作用90s;In step S1, the modified polycarboxylic acid is formed by mixing various polycarboxylic acids, chitosan, and sodium hypophosphite, and acts at 190°C for 90s;
在步骤S2中,二氧化钛整理剂是通过溶胶-凝胶法制备而成,并以钛酸丁酯、无水乙醇、冰醋酸、去离子水为原料制备而成。In step S2, the titanium dioxide finishing agent is prepared by a sol-gel method, and is prepared from butyl titanate, absolute ethanol, glacial acetic acid, and deionized water as raw materials.
在本发明中,通过多种多元羧酸的协同作用,可以大幅度提高面料的褶皱弹性,而多种羧酸的共聚物在和纤维素牢固交联时,也可以提供较多的自由羧基,有利于壳聚糖的吸附,而壳聚糖较好的吸附能够确保面料的亲水性能,而且使得面料具有较好的耐洗性能,同时,二氧化钛整理剂的使得面料具有较好的抗菌性能,从而使得面料在抗菌、亲水方面具有较好的性能。In the present invention, through the synergistic effect of multiple polycarboxylic acids, the wrinkle elasticity of the fabric can be greatly improved, and the copolymers of various carboxylic acids can also provide more free carboxyl groups when they are firmly cross-linked with cellulose, It is beneficial to the adsorption of chitosan, and the better adsorption of chitosan can ensure the hydrophilic performance of the fabric, and make the fabric have better washability. At the same time, the titanium dioxide finishing agent makes the fabric have better antibacterial performance. So that the fabric has better performance in terms of antibacterial and hydrophilic.
在本发明中,作为优选方案,在步骤S2中,优先对所述面料进行去烫平处理。In the present invention, as a preferred solution, in step S2, the fabric is preferentially de-ironed.
在本发明中,面料进行烫平处理,使得后续的多元羧酸、二氧化钛能够较好的吸附在面料上,从而确保了面料的亲水、抗菌性能。In the present invention, the fabric is ironed, so that the subsequent polycarboxylic acid and titanium dioxide can be better adsorbed on the fabric, thereby ensuring the hydrophilic and antibacterial properties of the fabric.
在本发明中,作为优选方案,上述面料的烫平处理步骤如下:In the present invention, as a preferred solution, the ironing treatment steps of the above-mentioned fabric are as follows:
A、将面料进行浸湿处理;A. Soak the fabric;
B、将浸湿后的面料在90℃下进行半烘干,此时面料处于半湿润状态;B. Semi-dry the soaked fabric at 90°C, and the fabric is in a semi-wet state at this time;
C、将半湿润状态的面料在烫平机下进行烫平处理。C. Iron the semi-wet fabric under the ironing machine.
在本发明中,面料从半湿润状态进行烫平,在烫平过程中会产生较多的水蒸气,这种水蒸气覆盖在面料上,使得面料具有更好的烫平效果。In the present invention, when the fabric is ironed from a semi-wet state, more water vapor will be generated during the ironing process, and this water vapor will cover the fabric so that the fabric has a better ironing effect.
在本发明中,作为优选方案,在步骤C中,烫平机分别对半湿润状态面料的正反两面进行烫平处理。In the present invention, as a preferred solution, in step C, the ironing machine performs ironing treatment on the front and back sides of the fabric in a semi-wet state, respectively.
在本发明中,正反两面对面料进行烫平,能够确保面料正反两面都是平整状态,从而保证多元羧酸、二氧化钛在面料的正反两面度具有较好的吸附效果。In the present invention, the front and back sides of the fabric are ironed to ensure that the front and back sides of the fabric are in a flat state, thereby ensuring that the polycarboxylic acid and titanium dioxide have a better adsorption effect on the front and back of the fabric.
在本发明中,作为优选方案,上述钛酸丁酯、无水乙醇、冰醋酸、去离子水之间的摩尔比为:1:25:5:0.5,在经过密封放置陈化15h以后,以450℃进行焙烧得到二氧化钛粉末。In the present invention, as a preferred solution, the molar ratio between the above-mentioned butyl titanate, absolute ethanol, glacial acetic acid, and deionized water is: 1:25:5:0.5, after being sealed and aged for 15 hours, the Calcined at 450°C to obtain titanium dioxide powder.
在本发明中,上述方法最终制得的二氧化钛颗粒的粒径小于20nm,从而保证二氧化钛能够更好的吸附在面料上。In the present invention, the particle size of the titanium dioxide particles finally prepared by the above method is less than 20nm, so as to ensure that the titanium dioxide can be better adsorbed on the fabric.
最后应说明的几点是:首先,在本申请的描述中,需要说明的是,除非另有规定和限定,术语“安装”、“相连”、“连接”应做广义理解,可以是机械连接或电连接,也可以是两个元件内部的连通,可以是直接相连,“上”、“下”、“左”、“右”等仅用于表示相对位置关系,当被描述对象的绝对位置改变,则相对位置关系可能发生改变;The last few points should be explained: First, in the description of this application, it should be explained that, unless otherwise specified and limited, the terms "installation", "connection" and "connection" should be understood in a broad sense, which can be mechanical connection Or electrical connection, it can also be the internal communication of two components, it can be directly connected, "up", "down", "left", "right", etc. are only used to indicate the relative positional relationship, when the absolute position of the object being described change, the relative positional relationship may change;
其次:本发明公开实施例中,只涉及到与本公开实施例涉及到的结构,其他结构可参考通常设计,在不冲突情况下,本发明同一实施例及不同实施例可以相互组合;Secondly: in the disclosed embodiments of the present invention, only the structures related to the disclosed embodiments are involved, and other structures can refer to the general design. In the case of no conflict, the same embodiment and different embodiments of the present invention can be combined with each other;
最后:以上所述仅为本发明的优选实施例而已,并不用于限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。Finally: the above is only a preferred embodiment of the present invention, and is not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the present invention within the scope of protection.
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