CN115502208A - Low-carbon steel prepared by low-temperature rolling process and method thereof - Google Patents
Low-carbon steel prepared by low-temperature rolling process and method thereof Download PDFInfo
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Abstract
Description
技术领域technical field
本申请涉及钢材制备领域,尤其涉及一种低温轧制工艺制备的低碳钢及其方法。The present application relates to the field of steel preparation, in particular to a low-carbon steel prepared by a low-temperature rolling process and a method thereof.
背景技术Background technique
采用多模式连铸连轧产线采用低温轧制工艺生产低碳钢,既不属于单纯的奥氏体区轧制, 也不属于单纯的铁素体区轧制,但是多模式连铸连轧产线和其他类型的无头轧制产线一样,在 精轧前需要保温加热设备进行加热保温。The production of low-carbon steel by using a multi-mode continuous casting and rolling production line using a low-temperature rolling process is neither a pure austenite rolling nor a pure ferrite rolling, but multi-mode continuous casting and rolling The production line, like other types of endless rolling production lines, needs heat preservation and heating equipment for heat preservation before finishing rolling.
目前在生产低碳钢阶段,在开始轧制前,一般需要采用隧道炉或者感应加热炉这类保温加 热设备加热板坯,使板坯内的金相组织开始变化,形成预期的金相组织结构,从而降低轧制的 难度,但是由于目前的隧道炉或者感应加热的升温阶段,都需要升温150℃~300℃,导致加热 后再轧制的过程中需要消耗大量的热量,从而提高轧制产线的生产成本;因此如何降轧制产线 的生产成本,是目前亟需解决的技术问题。At present, in the production of low-carbon steel, before rolling, it is generally necessary to use tunnel furnace or induction heating furnace to heat the slab, so that the metallographic structure in the slab begins to change and form the expected metallographic structure. , so as to reduce the difficulty of rolling, but due to the current heating stage of tunnel furnace or induction heating, the temperature needs to be raised by 150 ℃ ~ 300 ℃, resulting in the consumption of a lot of heat in the process of rolling after heating, so as to improve the rolling production The production cost of the rolling line; therefore how to reduce the production cost of the rolling production line is a technical problem that needs to be solved urgently.
发明内容Contents of the invention
本申请提供了一种低温轧制工艺制备的低碳钢及其方法,以解决现有技术中轧制产线的生 产成本过高的技术问题。The application provides a low-carbon steel prepared by a low-temperature rolling process and a method thereof, so as to solve the technical problem of high production cost of a rolling line in the prior art.
第一方面,本申请提供了一种低温轧制工艺制备低碳钢的方法,所述方法包括:In a first aspect, the application provides a method for preparing low-carbon steel by a low-temperature rolling process, the method comprising:
对铸坯进行第一加热、粗轧前除鳞、粗轧、第二加热、精轧前除鳞和精轧,得到热轧卷;Carrying out first heating, descaling before rough rolling, rough rolling, second heating, descaling before finish rolling and finish rolling on the slab to obtain hot-rolled coils;
对所述热轧卷进行层流冷却,再进行卷取,得到低温轧制的低碳钢;Laminar cooling is performed on the hot-rolled coil, and then coiled to obtain low-carbon steel rolled at low temperature;
其中,所述第一加热的前后温度差<250℃,所述第二加热的前后温度差<100℃。Wherein, the temperature difference before and after the first heating is <250°C, and the temperature difference before and after the second heating is <100°C.
可选的,所述第一加热的入口温度为900℃~950℃,所述第一加热的出口温度为1050℃~ 1150℃;Optionally, the inlet temperature of the first heating is 900°C-950°C, and the outlet temperature of the first heating is 1050°C-1150°C;
所述第二加热的入口温度为900℃~950℃,所述第二加热的出口温度为900℃~1030℃。The inlet temperature of the second heating is 900°C-950°C, and the outlet temperature of the second heating is 900°C-1030°C.
可选的,所述第一加热的时间<20min,所述第二加热的时间<10s。Optionally, the first heating time is <20 min, and the second heating time is <10 s.
可选的,所述第一加热和所述第二加热的加热模式包括隧道加热和感应加热中的至少一 种。Optionally, the heating modes of the first heating and the second heating include at least one of tunnel heating and induction heating.
可选的,所述精轧包括以N组机架进行精轧,N≥3且N为正整数;Optionally, the finishing rolling includes finishing rolling with N sets of stands, where N≥3 and N is a positive integer;
其中,第一组机架的压下率>40%,第二组机架至第N-1组机架的压下率<30%,第N组机 架的压下率>25%。Wherein, the reduction rate of the first group of frames>40%, the reduction rate of the second group of frames to the N-1th group of frames<30%, and the reduction rate of the Nth group of frames>25%.
可选的,所述精轧的终点温度为750℃~830℃。Optionally, the finish rolling end point temperature is 750°C-830°C.
可选的,所述卷取的温度为650℃~700℃。Optionally, the coiling temperature is 650°C-700°C.
可选的,所述对铸坯进行第一加热、粗轧前除鳞、粗轧、第二加热、精轧前除鳞和精轧, 得到热轧卷之前,还包括:Optionally, before performing the first heating, descaling before rough rolling, rough rolling, second heating, descaling before finish rolling and finish rolling to the slab, before obtaining hot-rolled coils, it also includes:
对钢水进行浇注,得到铸坯。The molten steel is poured to obtain a slab.
可选的,所述浇注包括以预设拉速进行浇注,所述预设拉速>5.2m/min。Optionally, the pouring includes pouring at a preset casting speed, and the preset casting speed is >5.2m/min.
第二方面,本申请提供了一种低温轧制工艺制备低碳钢,所述低碳钢由第一方面所述的方 法制备得到,以质量分数计,所述低碳钢的化学成分包括:In a second aspect, the application provides a low-temperature rolling process for preparing low-carbon steel, which is prepared by the method described in the first aspect, and in terms of mass fraction, the chemical composition of the low-carbon steel includes:
C:0.01%~0.08%,Si:0.01%~0.1%,Mn:0.1%~0.3%,S<0.01%,P<0.1%,其余为Fe和 不可避免的杂质。C: 0.01%-0.08%, Si: 0.01%-0.1%, Mn: 0.1%-0.3%, S<0.01%, P<0.1%, and the rest are Fe and unavoidable impurities.
本申请实施例提供的上述技术方案与现有技术相比具有如下优点:Compared with the prior art, the above-mentioned technical solutions provided by the embodiments of the present application have the following advantages:
本申请实施例提供的一种低温轧制工艺制备低碳钢的方法,通过在粗轧前除鳞的阶段之前 采用第一加热,使铸坯的金相组织初步变化,从而降低粗轧的轧制难度,提高粗轧的轧制效 率,再在精轧前除鳞的阶段之前采用第二加热,使铸坯的金相组织完成变化,达到预期标准, 从而能降低精轧的轧制的难度,提高精轧的轧制效率,结合两次加热的方式,将轧制所需的温 度分阶段的进行提升,同时保证第一加热的前后温度差<250℃,第二加热的前后温度差< 100℃,能有效的降低轧制过程中的能耗,降低轧制产线的生产成本。The embodiment of this application provides a method for preparing low-carbon steel by low-temperature rolling process. By using the first heating before the descaling stage before rough rolling, the metallographic structure of the slab is initially changed, thereby reducing the rolling loss of rough rolling. Improve the rolling efficiency of rough rolling, and then use the second heating before the stage of descaling before finishing rolling, so that the metallographic structure of the slab can be completely changed and reach the expected standard, thereby reducing the difficulty of finishing rolling , improve the rolling efficiency of finish rolling, combined with two heating methods, the temperature required for rolling is increased in stages, and at the same time ensure that the temperature difference before and after the first heating is <250°C, and the temperature difference before and after the second heating is < 100 ℃, can effectively reduce the energy consumption in the rolling process and reduce the production cost of the rolling line.
附图说明Description of drawings
此处的附图被并入说明书中并构成本说明书的一部分,示出了符合本发明的实施例,并与 说明书一起用于解释本发明的原理。The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the invention and together with the description serve to explain the principles of the invention.
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描 述中所需要使用的附图作简单地介绍,显而易见地,对于本领域普通技术人员而言,在不付出 创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, for those of ordinary skill in the art, In other words, other drawings can also be obtained from these drawings without paying creative labor.
图1为本申请实施例提供的方法的流程示意图;Fig. 1 is a schematic flow chart of the method provided by the embodiment of the present application;
图2为本申请实施例提供的多模式连铸连轧产线生产2mm的SPHC产品的金相组织的结果示 意图;Fig. 2 is the result schematic diagram of the metallographic structure of the SPHC product of 2mm produced by the multi-mode continuous casting and rolling production line that the embodiment of the application provides;
图3为本申请实施例提供的半连轧产线生产2mm的SPHC产品的金相组织的结果示意图;Fig. 3 is the result schematic diagram of the metallographic structure of the SPHC product of 2mm produced by the semi-continuous rolling production line that the embodiment of the present application provides;
图4为本申请实施例提供的多模式连铸连轧产线生产1.5mm的SPHC产品的金相组织的结果 示意图;Fig. 4 is the result schematic diagram of the metallographic structure of the SPHC product of 1.5mm produced by the multi-mode continuous casting and rolling production line provided by the embodiment of the application;
图5为本申请实施例提供的半连轧产线生产2mm的SPHC产品的金相组织的结果示意图。Fig. 5 is a schematic diagram of the results of the metallographic structure of the 2mm SPHC product produced by the semi-continuous rolling line provided in the embodiment of the present application.
具体实施方式detailed description
下面将结合具体实施方式和实施例,具体阐述本发明,本发明的优点和各种效果将由此更 加清楚地呈现。本领域技术人员应理解,这些具体实施方式和实施例是用于说明本发明,而非 限制本发明。The present invention will be described in detail below in conjunction with specific embodiments and examples, so that the advantages and various effects of the present invention will be presented more clearly. Those skilled in the art should understand that these specific implementations and examples are used to illustrate the present invention, not to limit the present invention.
在整个说明书中,除非另有特别说明,本文使用的术语应理解为如本领域中通常所使用的 含义。因此,除非另有定义,本文使用的所有技术和科学术语具有与本发明所属领域技术人员 的一般理解相同的含义。若存在矛盾,本说明书优先。Throughout the specification, unless otherwise specified, the terms used herein should be understood as commonly used in the art. Therefore, unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, this specification shall take precedence.
除非另有特别说明,本发明中用到的各种原材料、试剂、仪器和设备等,均可通过市场购 买得到或者可通过现有方法制备得到。Unless otherwise specified, various raw materials, reagents, instruments and equipment used in the present invention can be purchased from the market or prepared by existing methods.
本申请的创造性思维为:目前针对低碳钢的轧制工序包括ESP产线、CSP产线和半连轧产线 三种,其中,ESP产线轧制阶段要求精轧入口温度为950℃~1050℃、精轧出口温度为740℃~ 800℃、带钢在第一机架和第二机架间的累积压下率为60%~70%,第三机架至第五机架间的累计 压下率为50%~65%;而CSP产线要求板坯出炉温度在1000-1050℃、F4机架的入口温度不大于 870℃、F7机架终轧温度控制在780℃~820℃,并且F1、F2、F3机架的道次压下率为40%~65%, F4机架的压下率小于10%;半连轧产线要求粗轧末道次温度为820℃~860℃的低温奥氏体温度 区、精轧入口温度为800℃~850℃、终轧温度720℃~750℃、卷取温度为630℃-660℃,并且采 用此工艺DC01的r值1.5~1.8,SPCC的r值1.2~1.4。The creative thinking of this application is: the current rolling process for low carbon steel includes ESP production line, CSP production line and semi-continuous rolling production line. Among them, the rolling stage of ESP production line requires the entrance temperature of the finish rolling to be 950°C~ 1050°C, finish rolling exit temperature is 740°C-800°C, cumulative reduction rate of the strip between the first stand and the second stand is 60%-70%, and the rolling reduction rate between the third stand and the fifth stand The cumulative reduction rate is 50% to 65%; while the CSP production line requires the temperature of the slab to be 1000-1050°C, the inlet temperature of the F4 stand to be no more than 870°C, and the final rolling temperature of the F7 stand to be controlled at 780°C to 820°C , and the pass reduction rate of F1, F2, F3 stands is 40% to 65%, and the reduction rate of F4 stand is less than 10%; the semi-continuous rolling production line requires the rough rolling final pass temperature to be 820°C to 860°C ℃ low-temperature austenite temperature zone, finishing rolling entrance temperature is 800℃~850℃, final rolling temperature is 720℃~750℃, coiling temperature is 630℃-660℃, and the r value of DC01 using this process is 1.5~1.8 , the r value of SPCC is 1.2-1.4.
因此ESP产线、CSP产线和半连轧产线都不同于多模式连铸连轧产线,因此在采用多模式连 铸连轧产线进行低碳钢的轧制过程中,目前还未有相关的措施降低轧制前加热的前后温差,以 降低能耗,节约成本。Therefore, the ESP production line, CSP production line and semi-continuous rolling production line are all different from the multi-mode continuous casting and rolling production line. There are related measures to reduce the temperature difference before and after the heating before rolling, so as to reduce energy consumption and save costs.
本发明实施例提供的技术方案为解决上述技术问题,总体思路如下:The technical solutions provided by the embodiments of the present invention are to solve the above-mentioned technical problems, and the general idea is as follows:
在本申请的一个实施例中,如图1所示,提供一种低温轧制工艺制备低碳钢的方法,所述方 法包括:In one embodiment of the present application, as shown in Figure 1, a kind of low temperature rolling process is provided to prepare the method for low carbon steel, described method comprises:
S1.对铸坯进行第一加热、粗轧前除鳞、粗轧、第二加热、精轧前除鳞和精轧,得到热轧 卷;S1. Carrying out first heating, descaling before rough rolling, rough rolling, second heating, descaling before finish rolling and finish rolling to the slab to obtain hot rolled coils;
S2.对所述热轧卷进行层流冷却,再进行卷取,得到低温轧制的低碳钢;S2. laminar cooling the hot-rolled coil, and then coiling to obtain low-carbon steel rolled at low temperature;
其中,所述第一加热的前后温度差<250℃,所述第二加热的前后温度差<100℃。Wherein, the temperature difference before and after the first heating is <250°C, and the temperature difference before and after the second heating is <100°C.
本申请实施例中,第一加热的前后温度差<250℃的积极效果是在该温度差的范围内,既能 保证铸坯的金相组织转变,还能降低粗轧的轧制难度;当温度差的取值大于该范围的端点值, 将导致温度过高,烧损加重,成材率低。In the embodiment of the present application, the positive effect of the temperature difference before and after the first heating <250°C is that within the range of the temperature difference, it can not only ensure the transformation of the metallographic structure of the slab, but also reduce the rolling difficulty of rough rolling; If the temperature difference is greater than the end point of this range, the temperature will be too high, the burning loss will be aggravated, and the yield will be low.
第二加热的前后温度差<100℃的积极效果是在该温度差的范围内,既能保证铸坯的金相组 织转变,还能降低精轧的轧制难度;当温度差的取值大于该范围的端点值,将导致温度过高, 将导致钢材的金相组织变化过度,并影响轧制的效果,同时还将提高生产的能耗,提高钢材生 产成本。The positive effect of the temperature difference before and after the second heating <100°C is that within the range of the temperature difference, it can not only ensure the transformation of the metallographic structure of the slab, but also reduce the rolling difficulty of finish rolling; when the value of the temperature difference is greater than The extreme value of this range will cause the temperature to be too high, which will cause the metallographic structure of the steel to change excessively, and affect the effect of rolling, and will also increase the energy consumption of production and increase the production cost of steel.
在一写可选的实施方式中,所述第一加热的入口温度为900℃~950℃,所述第一加热的出 口温度为1050℃~1150℃;In an optional embodiment, the inlet temperature of the first heating is 900°C to 950°C, and the outlet temperature of the first heating is 1050°C to 1150°C;
所述第二加热的入口温度为900℃~950℃,所述第二加热的出口温度为900℃~1030℃。The inlet temperature of the second heating is 900°C-950°C, and the outlet temperature of the second heating is 900°C-1030°C.
本申请实施例中,第一加热的入口温度为900℃~950℃的积极效果是在该温度的范围内, 保证板坯处于奥氏体区;当温度大于950℃,将导致氧化烧损增加,温度小于1050℃,则影响 后续的加热能耗。In the embodiment of this application, the positive effect of the inlet temperature of the first heating being 900°C to 950°C is to ensure that the slab is in the austenite zone within this temperature range; when the temperature is greater than 950°C, it will lead to increased oxidation burning loss , the temperature is less than 1050 ° C, it will affect the subsequent heating energy consumption.
第一加热的出口温度为1050℃~1150℃的积极效果是在该温度的范围内,保证粗轧工序的 轧制稳定性;当温度大于1150℃,导致氧化烧损快速增加,温度小于1050℃,容易导致粗轧 后,中间坯的微观组织不均。The positive effect of the outlet temperature of the first heating is 1050°C ~ 1150°C. The positive effect is that within this temperature range, the rolling stability of the rough rolling process is guaranteed; when the temperature is greater than 1150°C, the oxidation burning loss will increase rapidly, and the temperature is less than 1050°C. , It is easy to cause uneven microstructure of the intermediate billet after rough rolling.
第二加热的入口温度为900℃~950℃,属于粗轧后中间坯温度的自然温降。The inlet temperature of the second heating is 900°C-950°C, which belongs to the natural temperature drop of the intermediate billet temperature after rough rolling.
第二加热的出口温度为900℃~1030℃的积极效果是在该温度的范围内,保证轧制过程 的;当出口温度<900℃或>1030℃时,会导致终轧温度超出设计范围,影响最终产品的组织性 能。The positive effect of the outlet temperature of the second heating is 900 ° C ~ 1030 ° C, the rolling process is guaranteed within this temperature range; when the outlet temperature is < 900 ° C or > 1030 ° C, the final rolling temperature will exceed the design range, Affects the tissue properties of the final product.
在一些可选的实施方式中,所述第一加热的时间<20min,所述第二加热的时间<10s。In some optional embodiments, the first heating time is <20 min, and the second heating time is <10 s.
本申请实施例中,第一加热的时间<20min的积极效果是在该时间范围内,能保证第一加 热的充分,铸坯达到预定温度并且温度均匀性良好。当时间的取值大于该范围的端点值,将导 致氧化损失大,成材率降低。In the embodiment of the present application, the positive effect of the first heating time <20 minutes is that within this time range, sufficient first heating can be ensured, the slab reaches the predetermined temperature and the temperature uniformity is good. When the value of time is greater than the end point of this range, it will lead to large oxidation loss and reduced yield.
第二加热的时间>10s的积极效果是在该时间范围内,能保证第二加热的充分,从而保证 粗轧后铸坯的金相组织变化完全,从而降低精轧的轧制难度;当时间的取值小于该范围的端点 值,将导致加热不充分,影响粗轧后铸坯的金相组织的变化。The positive effect of the second heating time > 10s is that within this time range, sufficient second heating can be ensured, thereby ensuring that the metallographic structure of the slab after rough rolling is completely changed, thereby reducing the rolling difficulty of finish rolling; If the value is less than the end point value of this range, it will lead to insufficient heating, which will affect the change of the metallographic structure of the slab after rough rolling.
在一些可选的实施方式中,所述第一加热和所述第二加热的加热模式包括隧道加热和感应 加热中的至少一种。In some optional embodiments, the heating modes of the first heating and the second heating include at least one of tunnel heating and induction heating.
本申请实施例中,限定第一加热和第二加热的加热模式,能保证加热充分,促使铸坯经过 两次加热后金相组织的变化完全,并且保证第一加热的前后温度差<250℃,第二加热的前后温 度差<100℃,从而降低加热的能耗,减少生产的成本。In the embodiment of the present application, the heating modes of the first heating and the second heating are limited to ensure that the heating is sufficient to promote the complete change of the metallographic structure of the slab after two heatings, and to ensure that the temperature difference before and after the first heating is <250°C , the temperature difference before and after the second heating is less than 100°C, thereby reducing heating energy consumption and production cost.
在一些可选的实施方式中,所述精轧包括以N组机架进行精轧,N≥3且N为正整数;In some optional embodiments, the finish rolling includes finishing rolling with N groups of stands, where N≥3 and N is a positive integer;
其中,第一组机架的压下率>40%,第二组机架至第N-1组机架的压下率<30%,第N组机 架的压下率>25%。Wherein, the reduction rate of the first group of frames>40%, the reduction rate of the second group of frames to the N-1th group of frames<30%, and the reduction rate of the Nth group of frames>25%.
本申请实施例中,第一组机架的压下率>40%的积极效果是促进奥氏体再结晶,有利于细化 最终产品晶粒,保证强塑性;当压下率的取值小于该范围的端点值,会使得产品的强塑性降 低。In the embodiment of the present application, the positive effect of the reduction rate of the first group of racks > 40% is to promote austenite recrystallization, which is beneficial to refine the grains of the final product and ensure strong plasticity; when the reduction rate is less than The end value of this range will reduce the strong plasticity of the product.
第二组机架至第N-1组机架的压下率<30%的积极效果是当先共析铁素体出现时,保证变 形后尺寸均匀;当压下率的取值大于该范围的端点值,将导致奥氏体和铁素体的变形后尺寸不 均匀。The positive effect of the reduction rate <30% from the second group of racks to the N-1th group of racks is to ensure uniform size after deformation when pro-eutectoid ferrite appears; when the reduction rate is greater than the range Endpoint values will result in inhomogeneous austenite and ferrite sizes after deformation.
第N组机架的压下率>25%的积极效果是为了满足最终产品的尺寸要求,同时保证产品厚 度方向的组织均匀性;当压下率的取值小于该范围的端点值,将导致的不利影响是厚度方向的 组织容易不均匀,出现组织分层现象。The positive effect of the reduction rate > 25% of the Nth group of racks is to meet the size requirements of the final product while ensuring the uniformity of the structure in the thickness direction of the product; when the reduction rate is less than the end point value of this range, it will cause The adverse effect is that the tissue in the thickness direction is easy to be uneven, and the phenomenon of tissue delamination occurs.
在一些可选的实施方式中,所述精轧的终点温度为750℃~830℃。In some optional embodiments, the finish rolling end temperature is 750°C-830°C.
本申请实施例中,精轧的终点温度为750℃~830℃的积极效果是保证在可以稳定轧制的基 础上,降低屈强比,提高产品成型能力;当温度的取值大于830℃时,接近常规奥氏体轧制, 屈强比升高。当温度的取值小于750℃时,则中间坯会在后机架的变形抗力急剧增加,影响轧 制稳定性。In the embodiment of the present application, the positive effect of the finish rolling end temperature being 750°C to 830°C is to reduce the yield ratio and improve the product forming ability on the basis of stable rolling; when the temperature is greater than 830°C , close to conventional austenitic rolling, and the yield ratio increases. When the temperature is lower than 750°C, the deformation resistance of the intermediate billet in the rear stand will increase sharply, which will affect the rolling stability.
在一些可选的实施方式中,所述卷取的温度为650℃~700℃。In some optional embodiments, the coiling temperature is 650°C-700°C.
本申请实施例中,卷取的温度为650℃~700℃的积极效果是保证晶粒的回复和生长;当温 度的取值>700℃时,晶粒尺寸大,强度很低。当温度<650℃,会出现变形铁素体回复不充 分,力学性能的各向异性大。In the examples of this application, the positive effect of the coiling temperature being 650°C to 700°C is to ensure the recovery and growth of grains; when the temperature is greater than 700°C, the grain size is large and the strength is very low. When the temperature is less than 650℃, the recovery of deformed ferrite will be insufficient, and the anisotropy of mechanical properties will be large.
在一些可选的实施方式中,所述对铸坯进行第一加热、粗轧前除鳞、粗轧、第二加热、精 轧前除鳞和精轧,得到热轧卷之前,包括:In some optional embodiments, the first heating, descaling before rough rolling, rough rolling, second heating, descaling before finish rolling and finish rolling are carried out on the slab, before obtaining hot rolled coils, including:
S101.对钢水进行浇注,得到铸坯。S101. Pouring molten steel to obtain a cast slab.
在一些可选的实施方式中,所述浇注包括以预设拉速进行浇注,所述预设拉速>In some optional embodiments, the pouring includes pouring at a preset casting speed, and the preset casting speed >
5.2m/min。5.2m/min.
本申请实施例中,预设拉速>5.2m/min的积极效果是保证精轧区的温降合理;当预设拉速 的取值小于该范围的端点值,将导致的不利影响是精轧区的温降大,同样的精轧入口温度,终 轧温度低,影响产品性能。In the embodiment of this application, the positive effect of the preset casting speed>5.2m/min is to ensure that the temperature drop in the finishing rolling area is reasonable; The temperature drop in the rolling area is large, and the same finish rolling entrance temperature, the final rolling temperature is low, which affects the product performance.
在本申请的一个实施例中,提供一种低温轧制工艺制备的低碳钢,所述低碳钢由所述方法 制备得到,以质量分数计,所述低碳钢的化学成分包括:In one embodiment of the present application, a kind of low-carbon steel prepared by low-temperature rolling process is provided, and the low-carbon steel is prepared by the method, and in mass fraction, the chemical composition of the low-carbon steel includes:
C:0.01%~0.08%,Si:0.01%~0.1%,Mn:0.1%~0.3%,S<0.01%,P<0.1%,其余为Fe和 不可避免的杂质。C: 0.01%-0.08%, Si: 0.01%-0.1%, Mn: 0.1%-0.3%, S<0.01%, P<0.1%, and the rest are Fe and unavoidable impurities.
本申请实施例中,C的质量分数为0.01%~0.08%的积极效果是保证轧制过程中的相变温度 在预测范围内;当质量分数的取值大于或小于该范围的端点值,将导致产品的生产稳定性和最 终力学性能不合格。In the embodiment of the present application, the positive effect of the mass fraction of C being 0.01% to 0.08% is to ensure that the phase transition temperature in the rolling process is within the predicted range; when the value of the mass fraction is greater than or less than the endpoint value of the range, the The production stability and final mechanical properties of the product are unqualified.
实施例1Example 1
以多模式连铸连轧产线生产的厚度为2mm的DC01产品为例:Take the DC01 product with a thickness of 2mm produced by the multi-mode continuous casting and rolling production line as an example:
如图1所示,一种低温轧制工艺制备低碳钢的方法,包括:As shown in Figure 1, a method for preparing low-carbon steel by a low-temperature rolling process, comprising:
S101.对钢水进行浇注,得到铸坯;S101. Pouring molten steel to obtain a slab;
S1.对铸坯进行第一加热、粗轧前除鳞、粗轧、第二加热、精轧前除鳞和精轧,得到热轧 卷;S1. Carrying out first heating, descaling before rough rolling, rough rolling, second heating, descaling before finish rolling and finish rolling to the slab to obtain hot rolled coils;
S2.对热轧卷进行层流冷却,再进行卷取,得到低温轧制的低碳钢。S2. Laminar cooling is performed on the hot-rolled coil, and then coiled to obtain low-carbon steel rolled at low temperature.
第一加热的入口温度为926℃,第一加热的出口温度为1123℃;The inlet temperature of the first heating is 926°C, and the outlet temperature of the first heating is 1123°C;
第二加热的入口温度为917℃,第二加热的出口温度为1020℃。The inlet temperature of the second heating is 917°C, and the outlet temperature of the second heating is 1020°C.
第一加热的时间为16min,第二加热的时间为8s。The time for the first heating is 16 minutes, and the time for the second heating is 8 s.
第一加热的加热模式为隧道加热,第二加热的加热模式为感应加热。The heating mode of the first heating is tunnel heating, and the heating mode of the second heating is induction heating.
精轧包括以5组机架进行精轧;其中,第一组机架的压下率为45%,第二组机架至第四组 机架的压下率<30%,第五组机架的压下率为26%。Finish rolling includes finishing rolling with 5 groups of stands; among them, the reduction rate of the first group of stands is 45%, the reduction rate of the second group to the fourth group of stands is <30%, and the fifth group of stands The reduction rate of the frame was 26%.
精轧的终点温度为772℃。The finish rolling end point temperature was 772°C.
卷取的温度为676℃。The coiling temperature was 676°C.
浇注包括以预设拉速进行浇注,预设拉速为5.3m/min。Pouring includes pouring at a preset casting speed, which is 5.3m/min.
一种低温轧制工艺制备的低碳钢,低碳钢由方法制备得到,以质量分数计,低碳钢的化学 成分包括:A low-carbon steel prepared by a low-temperature rolling process, the low-carbon steel is prepared by the method, and in mass fraction, the chemical composition of the low-carbon steel includes:
C:0.02%,Si:0.01%,Mn:0.1%,S<0.01%,P<0.1%,其余为Fe和不可避免的杂质。C: 0.02%, Si: 0.01%, Mn: 0.1%, S<0.01%, P<0.1%, and the rest are Fe and unavoidable impurities.
实施例2Example 2
将实施例2和实施例1进行对比,实施例2和实施例1的区别在于:Embodiment 2 is compared with embodiment 1, and the difference between embodiment 2 and embodiment 1 is:
以多模式连铸连轧产线生产的厚度为1.5mm的SPHC为例:Take the SPHC with a thickness of 1.5mm produced by the multi-mode continuous casting and rolling production line as an example:
第一加热的入口温度为931℃,第一加热的出口温度为1128℃;The inlet temperature of the first heating is 931°C, and the outlet temperature of the first heating is 1128°C;
第二加热的入口温度为918℃,第二加热的出口温度为1030℃。The inlet temperature of the second heating is 918°C, and the outlet temperature of the second heating is 1030°C.
第一加热的时间为15min,第二加热的时间为7s。The first heating time is 15 minutes, and the second heating time is 7s.
其中,第一组机架的压下率为42%,第二组机架至第四组机架的压下率<30%,第五组机架 的压下率为28%。Wherein, the reduction rate of the first group of frames is 42%, the reduction rate of the second group to the fourth group of frames <30%, and the reduction rate of the fifth group of frames is 28%.
精轧的终点温度为768℃。The finish rolling end point temperature was 768°C.
卷取的温度为669℃。The coiling temperature was 669°C.
预设拉速为5.3m/minThe preset pulling speed is 5.3m/min
以质量分数计,低碳钢的化学成分包括:In terms of mass fraction, the chemical composition of low carbon steel includes:
C:0.04%,Si:0.03%,Mn:0.15%,S<0.01%,P<0.1%,其余为Fe和不可避免的杂质。C: 0.04%, Si: 0.03%, Mn: 0.15%, S<0.01%, P<0.1%, and the rest are Fe and unavoidable impurities.
对比例1Comparative example 1
以多模式连铸连轧产线常规生产工艺生产的厚度为2.0mm的DC01为例:Take DC01 with a thickness of 2.0mm produced by the conventional production process of the multi-mode continuous casting and rolling production line as an example:
第一加热的入口温度为935℃,第一加热的出口温度为1168℃;The inlet temperature of the first heating is 935°C, and the outlet temperature of the first heating is 1168°C;
第二加热的入口温度为938℃,第二加热的出口温度为1182℃。The inlet temperature of the second heating is 938°C, and the outlet temperature of the second heating is 1182°C.
精轧的终点温度为872℃。The finish rolling end point temperature was 872°C.
卷取的温度为619℃。The coiling temperature was 619°C.
以质量分数计,低碳钢的化学成分包括:In terms of mass fraction, the chemical composition of low carbon steel includes:
C:0.02%,Si:0.01%,Mn:0.1%,S<0.01%,P<0.1%,其余为Fe和不可避免的杂质。C: 0.02%, Si: 0.01%, Mn: 0.1%, S<0.01%, P<0.1%, and the rest are Fe and unavoidable impurities.
对比例2Comparative example 2
以多模式连铸连轧产线常规生产工艺生产的厚度为1.5mm的SPHC为例:Take the SPHC with a thickness of 1.5mm produced by the conventional production process of the multi-mode continuous casting and rolling production line as an example:
第一加热的入口温度为936℃,第一加热的出口温度为1157℃;The inlet temperature of the first heating is 936°C, and the outlet temperature of the first heating is 1157°C;
第二加热的入口温度为928℃,第二加热的出口温度为1153℃。The inlet temperature of the second heating is 928°C, and the outlet temperature of the second heating is 1153°C.
精轧的终点温度为861℃。The finish rolling end point temperature was 861°C.
卷取的温度为617℃。The coiling temperature was 617°C.
以质量分数计,低碳钢的化学成分包括:In terms of mass fraction, the chemical composition of low carbon steel includes:
C:0.04%,Si:0.03%,Mn:0.15%,S<0.01%,P<0.1%,其余为Fe和不可避免的杂质。C: 0.04%, Si: 0.03%, Mn: 0.15%, S<0.01%, P<0.1%, and the rest are Fe and unavoidable impurities.
对比例3Comparative example 3
半连轧产线生产2mm的DC01产品为例:Take the semi-continuous rolling line to produce 2mm DC01 products as an example:
加热炉出钢温度1200℃;The tapping temperature of the heating furnace is 1200°C;
精轧出口温度880℃;The exit temperature of finish rolling is 880℃;
卷取温度640℃。The coiling temperature is 640°C.
化学成分包括:Chemical composition includes:
C:0.02%,Si:0.01%,Mn:0.1%,S<0.01%,P<0.1%,其余为Fe和不可避免的杂质。C: 0.02%, Si: 0.01%, Mn: 0.1%, S<0.01%, P<0.1%, and the rest are Fe and unavoidable impurities.
对比例4Comparative example 4
半连轧产线生产1.5mm的SPHC产品为例:Take the production of 1.5mm SPHC products in the semi-continuous rolling line as an example:
加热炉出钢温度1180℃;The tapping temperature of the heating furnace is 1180°C;
精轧出口温度870℃;The exit temperature of finish rolling is 870℃;
卷取温度620℃。The coiling temperature is 620°C.
化学成分包括:Chemical composition includes:
C:0.04%,Si:0.03%,Mn:0.15%,S<0.01%,P<0.1%,其余为Fe和不可避免的杂质。C: 0.04%, Si: 0.03%, Mn: 0.15%, S<0.01%, P<0.1%, and the rest are Fe and unavoidable impurities.
相关实验:Related experiments:
分别统计各实施例和对比例过程中的感应加热阶段的成本,同时统计所得产品的力学性 能,结果如表1所示。The cost of the induction heating stage in each embodiment and comparative example process is counted respectively, and the mechanical properties of the product obtained are counted simultaneously, and the results are shown in Table 1.
相关实验的测试方法:Test methods for related experiments:
产品的力学性能:采用GB/T228-09的金属室温拉伸试验方法,对产品的屈服强度、抗拉强 度和断后延伸率进行测量;采用GB/T5027-2016对加工硬化指数n值和塑性应变比r值进行测 量。Mechanical properties of the product: adopt GB/T228-09 metal room temperature tensile test method to measure the yield strength, tensile strength and elongation of the product; adopt GB/T5027-2016 to measure the work hardening index n value and plastic strain The ratio r value is measured.
表1Table 1
表1的具体分析:Specific analysis of Table 1:
屈服强度(Rp0.2)是指钢材在非比例延伸率为0.2%时的延伸强度,屈服强度越符合标准, 说明钢材的力学性能良好。The yield strength (R p0.2 ) refers to the elongation strength of the steel when the non-proportional elongation is 0.2%. The more the yield strength meets the standard, the better the mechanical properties of the steel are.
抗拉强度(Rm)是指试件拉断前单位面积上承受的最大应力,抗拉强度越符合标准,说明 钢材的力学性能良好。Tensile strength (R m ) refers to the maximum stress per unit area before the specimen is broken. The more the tensile strength meets the standard, the better the mechanical properties of the steel.
断后延伸率是指试样拉伸断裂后标距段的总变形ΔL与原标距长度L之比的百分数,总延伸 率越符合标准,说明钢材的力学性能良好。The elongation after fracture refers to the percentage of the ratio of the total deformation ΔL of the gauge section after tensile fracture of the sample to the original gauge length L. The more the total elongation meets the standard, the better the mechanical properties of the steel.
由实施例1-3的数据可知:By the data of embodiment 1-3 as can be known:
采用本申请的方法,通过第一加热和第二加热,不仅能使铸坯的金相组织完成预期的变 化,还能分别降低粗轧和精轧的轧制难度,并且结合两次加热的方式,将轧制所需的温度分阶 段的进行提升,保证第一加热的前后温度差<250℃,第二加热的前后温度差<100℃,能有效 的降低轧制过程中的能耗,降低轧制产线的生产成本。Using the method of this application, through the first heating and the second heating, not only can the metallographic structure of the slab complete the expected change, but also reduce the rolling difficulty of rough rolling and finish rolling respectively, and combine the two heating methods , the temperature required for rolling is raised in stages to ensure that the temperature difference before and after the first heating is less than 250°C, and the temperature difference before and after the second heating is less than 100°C, which can effectively reduce the energy consumption during the rolling process and reduce the Production costs of the rolling line.
由对比例1-2的数据可知:From the data of Comparative Example 1-2, it can be seen that:
若不采用本申请的多模式连铸连轧产线,而采用半连轧产线生产钢材,由于半连轧产线的 加热升温的温差较大,因此导致半连轧产线生产的钢材产品的性能较多模式连铸连轧产线所生 产出来的钢材性能较低。If the multi-mode continuous casting and rolling production line of the application is not adopted, and the semi-continuous rolling production line is used to produce steel products, due to the large temperature difference between the heating and heating of the semi-continuous rolling production line, the steel products produced by the semi-continuous rolling production line The performance of the steel produced by the continuous casting and rolling production line is relatively low.
本申请实施例中的一个或多个技术方案,至少还具有如下技术效果或优点:One or more technical solutions in the embodiments of the present application also have at least the following technical effects or advantages:
(1)本申请实施例提供的方法,通过第一加热和第二加热,不仅能使铸坯的金相组织完成 预期的变化,还能分别降低粗轧和精轧的轧制难度,并且结合两次加热的方式,将轧制所需的 温度分阶段的进行提升,保证第一加热的前后温度差<250℃,第二加热的前后温度差<100℃,能有效的降低轧制过程中的能耗,降低轧制产线的生产成本。(1) The method provided in the embodiment of this application, through the first heating and the second heating, can not only make the metallographic structure of the slab complete the expected change, but also reduce the rolling difficulty of rough rolling and finish rolling respectively, and combine The two-time heating method increases the temperature required for rolling in stages to ensure that the temperature difference before and after the first heating is less than 250°C, and the temperature difference before and after the second heating is less than 100°C, which can effectively reduce the rolling process. energy consumption and reduce the production cost of the rolling line.
(2)本申请实施例提供的方法,所得的钢材产品具有组织性能中晶粒粗大、力学性能中屈 服强度较低的优点,因此具有良好的成型能力。(2) According to the method provided in the embodiments of the present application, the steel product obtained has the advantages of coarse grains in the structural properties and low yield strength in the mechanical properties, so it has good forming ability.
(4)本申请实施例提供的低碳钢,微观组织均匀,产品性能稳定。(4) The low-carbon steel provided in the embodiment of the present application has a uniform microstructure and stable product performance.
附图解释:Explanation of the drawings:
图2为本申请实施例提供的多模式连铸连轧产线生产2mm的DC01产品的金相组织的结果示 意图;Fig. 2 is the result schematic diagram of the metallographic structure of the DC01 product that the multi-mode continuous casting and rolling production line that Fig. 2 provides for the embodiment of the application produces 2mm;
图3为本申请实施例提供的半连轧产线生产2mm的DC01产品的金相组织的结果示意图;Fig. 3 is the result schematic diagram of the metallographic structure of the DC01 product of 2mm produced by the semi-continuous rolling production line that the embodiment of the application provides;
由图2和图3的数据可知,多模式连铸连轧产线生产2mm的SPHC晶粒相对粗大,屈服强度 低,具有更好的成型能力。From the data in Figure 2 and Figure 3, it can be seen that the 2mm SPHC produced by the multi-mode continuous casting and rolling line has relatively coarse grains, low yield strength, and better forming ability.
图4为本申请实施例提供的多模式连铸连轧产线生产1.5mm的SPHC产品的金相组织的结果 示意图;Fig. 4 is the result schematic diagram of the metallographic structure of the SPHC product of 1.5mm produced by the multi-mode continuous casting and rolling production line provided by the embodiment of the application;
图5为本申请实施例提供的半连轧产线生产2mm的SPHC产品的金相组织的结果示意图。Fig. 5 is a schematic diagram of the results of the metallographic structure of the 2mm SPHC product produced by the semi-continuous rolling line provided in the embodiment of the present application.
由图4和图5可知,多模式连铸连轧产线生产1.5mm的SPHC晶粒相对粗大,屈服强度低, 具有更好的成型能力。It can be seen from Figure 4 and Figure 5 that the 1.5mm SPHC produced by the multi-mode continuous casting and rolling production line has relatively coarse grains, low yield strength, and better formability.
需要说明的是,在本文中,诸如“第一”和“第二”等之类的关系术语仅仅用来将一个实 体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任 何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非 排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而 且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的 要素。在没有更多限制的情况下,由语句“包括……”限定的要素,并不排除在包括所述要素 的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that in this article, relative terms such as "first" and "second" are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply these No such actual relationship or order exists between entities or operations. Furthermore, the term "comprises", "comprises" or any other variation thereof is intended to cover a non-exclusive inclusion such that a process, method, article or apparatus comprising a set of elements includes not only those elements, but also includes elements not expressly listed. other elements of or also include elements inherent in such a process, method, article, or device. Without further limitations, an element defined by the statement "comprising..." does not exclude the presence of additional identical elements in the process, method, article or device comprising said element.
在本文中所披露的范围的端点和任何值都不限于该精确的范围或值,这些范围或值应当理 解为包含接近这些范围或值的值。对于数值范围来说,各个范围的端点值之间、各个范围的端 点值和单独的点值之间,以及单独的点值之间可以彼此组合而得到一个或多个新的数值范围, 这些数值范围应被视为在本文中具体公开。Neither the endpoints of the ranges nor any values disclosed herein are limited to that precise range or value, and these ranges or values are understood to include values approaching these ranges or values. For numerical ranges, between the endpoints of each range, between the endpoints of each range and individual point values, and between individual point values can be combined with each other to obtain one or more new numerical ranges, these values Ranges should be considered as specifically disclosed herein.
以上所述仅是本发明的具体实施方式,使本领域技术人员能够理解或实现本发明。对这些 实施例的多种修改对本领域的技术人员来说将是显而易见的,本文中所定义的一般原理可以在 不脱离本发明的精神或范围的情况下,在其它实施例中实现。因此,本发明将不会被限制于本 文所示的这些实施例,而是要符合与本文所申请的原理和新颖特点相一致的最宽的范围。The above descriptions are only specific embodiments of the present invention, so that those skilled in the art can understand or implement the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. Accordingly, the present invention will not be limited to the embodiments shown herein, but is to be accorded the widest scope consistent with the principles and novel features claimed herein.
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