CN115440811B - Semiconductor device and method for manufacturing the same - Google Patents
Semiconductor device and method for manufacturing the same Download PDFInfo
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- H10D30/4755—High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having wider bandgap layer formed on top of lower bandgap active layer, e.g. undoped barrier HEMTs such as i-AlGaN/GaN HEMTs having wide bandgap charge-carrier supplying layers, e.g. modulation doped HEMTs such as n-AlGaAs/GaAs HEMTs
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Abstract
Description
技术领域Technical field
本公开总体上涉及一种氮化物基半导体器件。更确切地说,本公开涉及一种具有刻蝕終止層的耗尽型(Depletion mode,D-mode)氮化物基半导体器件。The present disclosure generally relates to a nitride-based semiconductor device. More specifically, the present disclosure relates to a depletion mode (D-mode) nitride-based semiconductor device having an etching stop layer.
背景技术Background technique
近年来,关于高电子迁移率晶体管(HEMT)的深入研究已经非常普遍,尤其是对于高功率切换和高频率应用。III族氮化物基HEMT利用具有不同带隙的两种材料之间的异质结界面来形成量子阱类结构,所述量子阱类结构容纳二维电子气体(2DEG)区,从而满足高功率/频率装置的需求。除了HEMT之外,具有异质结构的装置的实例进一步包含异质结双极晶体管(HBT)、异质结场效应晶体管(HFET)和调制掺杂FET(MODFET)。为了满足更多设计要求,HEMT装置需要变得更小。因此,在HEMT装置小型化的情况下,需要保持那些HEMT装置的可靠性。In recent years, intensive research on high electron mobility transistors (HEMTs) has become widespread, especially for high-power switching and high-frequency applications. Group III nitride-based HEMTs utilize the heterojunction interface between two materials with different band gaps to form a quantum well-like structure that accommodates a two-dimensional electron gas (2DEG) region to meet the requirements of high power/ Frequency device requirements. In addition to HEMTs, examples of devices with heterostructures further include heterojunction bipolar transistors (HBTs), heterojunction field effect transistors (HFETs), and modulated doped FETs (MODFETs). To meet more design requirements, HEMT devices need to become smaller. Therefore, as HEMT devices are miniaturized, there is a need to maintain the reliability of those HEMT devices.
发明内容Contents of the invention
根据本公开的一个方面,提供一种氮基半导体器件,其特征在于,包括第一氮化物半导体层、第二氮化物半导体层、栅电极介电层、源电极及漏电极、氮化物导电层以及栅电极。第二氮化物半导体层设置在所述第一氮化物半导体层上,所述第二氮化物半导体层的带隙大于所述第一氮化物半导体层的带隙。栅电极介电层设置在所述第二氮化物半导体层上。源电极及漏电极设置在所述栅电极介电层上,并穿过所述栅电极介电层且与所述第二氮化物半导体层接触。氮化物导电层设置在所述栅电极介电层上,并接触所述栅电极介电层,且所述氮化物导电层位在所述源电极与所述漏电极之间。栅电极设置在所述氮化物导电层上。According to one aspect of the present disclosure, a nitrogen-based semiconductor device is provided, which is characterized by including a first nitride semiconductor layer, a second nitride semiconductor layer, a gate electrode dielectric layer, a source electrode and a drain electrode, and a nitride conductive layer. and gate electrode. A second nitride semiconductor layer is disposed on the first nitride semiconductor layer, and the band gap of the second nitride semiconductor layer is larger than the band gap of the first nitride semiconductor layer. A gate electrode dielectric layer is disposed on the second nitride semiconductor layer. The source electrode and the drain electrode are disposed on the gate electrode dielectric layer, pass through the gate electrode dielectric layer and contact the second nitride semiconductor layer. A nitride conductive layer is disposed on the gate electrode dielectric layer and contacts the gate electrode dielectric layer, and the nitride conductive layer is located between the source electrode and the drain electrode. A gate electrode is provided on the nitride conductive layer.
根据本公开的一个方面,提供一种用于制造半导体器件的方法。所述方法包含如下步骤。在第一氮化物半导体层上形成第二氮化物半导体层;在所述第二氮化物半导体层上形成栅电极介电层;在所述栅电极介电层上形成氮化物导电覆盖层;图案化所述氮化物导电覆盖层,以形成氮化物导电层;形成沉积层,且所述沉积层覆盖所述栅电极介电层及所述氮化物导电层;在所述沉积层中形成开口,以暴露出所述氮化物导电层的一部分;以及在所述开口中形成栅电极。According to one aspect of the present disclosure, a method for manufacturing a semiconductor device is provided. The method includes the following steps. forming a second nitride semiconductor layer on the first nitride semiconductor layer; forming a gate electrode dielectric layer on the second nitride semiconductor layer; forming a nitride conductive covering layer on the gate electrode dielectric layer; patterning oxidizing the nitride conductive covering layer to form a nitride conductive layer; forming a deposition layer, and the deposition layer covers the gate electrode dielectric layer and the nitride conductive layer; forming an opening in the deposition layer, to expose a portion of the nitride conductive layer; and form a gate electrode in the opening.
根据本公开的一个方面,提供一种氮基半导体器件,其特征在于,包括第一氮化物半导体层、第二氮化物半导体层、栅电极介电层、氮化物导电层、沉积层以及栅电极。第二氮化物半导体层设置在所述第一氮化物半导体层上,所述第二氮化物半导体层的带隙大于所述第一氮化物半导体层的带隙。栅电极介电层设置在所述第二氮化物半导体层上。氮化物导电层设置在所述栅电极介电层上,并接触所述栅电极介电层。沉积层设置在所述栅电极介电层上,并至少覆盖所述氮化物导电层。栅电极设置在所述氮化物导电层上,并接触所述氮化物导电层,且所述栅电极穿过所述沉积层。According to an aspect of the present disclosure, a nitrogen-based semiconductor device is provided, which is characterized by including a first nitride semiconductor layer, a second nitride semiconductor layer, a gate electrode dielectric layer, a nitride conductive layer, a deposition layer and a gate electrode . A second nitride semiconductor layer is disposed on the first nitride semiconductor layer, and the band gap of the second nitride semiconductor layer is larger than the band gap of the first nitride semiconductor layer. A gate electrode dielectric layer is disposed on the second nitride semiconductor layer. A nitride conductive layer is disposed on the gate electrode dielectric layer and contacts the gate electrode dielectric layer. A deposition layer is disposed on the gate electrode dielectric layer and at least covers the nitride conductive layer. A gate electrode is disposed on the nitride conductive layer and contacts the nitride conductive layer, and the gate electrode passes through the deposition layer.
通过以上配置,氮化物导电层可作为刻蚀终止层,因此能避免栅电极介电层于在沉积层形成开口的阶段受到损害,也可利于加快在沉积层内形成开口的工艺速率。也因此,所形成具有D-MIS(depletion mode misfet)结构的氮基半导体器件可具有高可靠度以及高良率。Through the above configuration, the nitride conductive layer can serve as an etching stop layer, thereby preventing the gate electrode dielectric layer from being damaged during the stage of forming openings in the deposited layer, and can also help speed up the process rate of forming openings in the deposited layer. Therefore, the formed nitrogen-based semiconductor device having a D-MIS (depletion mode misfet) structure can have high reliability and high yield.
附图说明Description of drawings
当结合附图阅读时,从以下详细描述容易地理解本公开的各方面。应注意,各种特征可不按比例绘制。也就是说,为了论述的清楚起见,各种特征的尺寸可任意增大或减小。在下文中参考图式更详细地描述本公开的实施例,在图式中:Aspects of the present disclosure are readily understood from the following detailed description when read in conjunction with the accompanying drawings. It should be noted that various features may not be drawn to scale. That is, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion. Embodiments of the present disclosure are described in more detail below with reference to the drawings, in which:
图1是根据本公开的一些实施例的半导体器件的横截面视图;1 is a cross-sectional view of a semiconductor device according to some embodiments of the present disclosure;
图2A、图2B、图2C、图2D和图2E根据本公开的一些实施例展示用于制造氮基半导体器件的方法的不同阶段;2A, 2B, 2C, 2D, and 2E illustrate different stages of a method for fabricating a nitrogen-based semiconductor device according to some embodiments of the present disclosure;
图3是根据本公开的一些实施例的半导体器件的横截面视图;以及3 is a cross-sectional view of a semiconductor device according to some embodiments of the present disclosure; and
图4是根据本公开的一些实施例的半导体器件的横截面视图。4 is a cross-sectional view of a semiconductor device according to some embodiments of the present disclosure.
具体实施方式Detailed ways
在所有附图和详细描述中使用共同参考标号来指示相同或类似组件。根据结合附图作出的以下详细描述将容易理解本公开的实施例。Common reference numbers are used throughout the drawings and detailed description to refer to the same or similar components. Embodiments of the present disclosure will be readily understood from the following detailed description taken in conjunction with the accompanying drawings.
相对于某一组件或组件群组,或者组件或组件群组的某一平面,为相关联图中所展示的组件的定向指定空间描述,例如“上”、“上方”、“下方”、“向上”、“左”、“右”、“向下”、“顶部”、“底部”、“竖直”、“水平”、“侧面”、“较高”、“较低”、“上部”、“之上”、“之下”等等。应理解,本文中所使用的空间描述仅出于说明的目的,且本文中所描述的结构的实际实施方案可任何定向或方式在空间上布置,前提为本公开的实施例的优点是不会因此类布置而有所偏差。Specifies a spatial description for the orientation of the component shown in the associated diagram relative to a component or group of components, or a plane of the component or group of components, such as "above", "above", "below", " "Up", "Left", "Right", "Down", "Top", "Bottom", "Vertical", "Horizontal", "Side", "Higher", "Lower", "Upper" , "above", "below", etc. It is to be understood that the spatial description used herein is for illustrative purposes only and that actual implementations of the structures described herein may be spatially arranged in any orientation or manner, provided that the advantages of embodiments of the present disclosure are not Deviation due to such arrangement.
此外,应注意,在实际装置中,由于装置制造条件,描绘为近似矩形的各种结构的实际形状可能是曲形、具有圆形边缘、具有稍微不均匀的厚度等等。使用直线和直角只是为了方便表示层和特征。Furthermore, it should be noted that in an actual device, due to device manufacturing conditions, the actual shape of various structures depicted as approximately rectangular may be curved, have rounded edges, have slightly uneven thicknesses, etc. Straight lines and right angles are used only for convenience in representing layers and features.
在以下描述中,半导体器件/裸片/封装、其制造方法等被阐述为优选实例。所属领域的技术人员将显而易见,可在不脱离本公开的范围和精神的情况下作出修改,包含添加和/或替代。可省略特定细节以免使本公开模糊不清;然而,编写本公开是为了使所属领域的技术人员能够在不进行不当实验的情况下实践本文中的教示。In the following description, semiconductor devices/die/packages, manufacturing methods thereof, etc. are explained as preferred examples. It will be apparent to those skilled in the art that modifications may be made, including additions and/or substitutions, without departing from the scope and spirit of the disclosure. Specific details may be omitted so as not to obscure the disclosure; however, the disclosure is prepared to enable those skilled in the art to practice the teachings herein without undue experimentation.
图1是根据本公开的一些实施例的半导体器件1A的横截面视图。半导体器件1A包含衬底10、氮化物基半导体层12和14、栅电极介电层16、电极20和22、氮化物导电层30、沉积层32、栅极电极40。1 is a cross-sectional view of a semiconductor device 1A according to some embodiments of the present disclosure. The semiconductor device 1A includes a substrate 10 , nitride-based semiconductor layers 12 and 14 , a gate electrode dielectric layer 16 , electrodes 20 and 22 , a nitride conductive layer 30 , a deposition layer 32 , and a gate electrode 40 .
衬底10可以是半导体衬底。衬底10的示例性材料可包含例如但不限于Si、SiGe、SiC、砷化镓、p掺杂的Si、n掺杂的Si、蓝宝石、绝缘体上半导体(例如绝缘体上硅(SOI))或其它合适的衬底材料。在一些实施例中,衬底10可包含例如但不限于III族元素、IV族元素、V族元素或其组合(例如III-V化合物)。在其它实施例中,衬底10可包含例如但不限于一个或多个其它特征,例如掺杂区、埋层、外延(epi)层或其组合。在一些实施例中,衬底10的材料可包含具有<111>定向的硅衬底。Substrate 10 may be a semiconductor substrate. Exemplary materials for substrate 10 may include, for example, but not limited to, Si, SiGe, SiC, gallium arsenide, p-doped Si, n-doped Si, sapphire, semiconductor-on-insulator (eg, silicon-on-insulator (SOI)), or Other suitable substrate materials. In some embodiments, substrate 10 may include, for example, but not limited to, Group III elements, Group IV elements, Group V elements, or combinations thereof (eg, III-V compounds). In other embodiments, substrate 10 may include, for example, but not limited to, one or more other features, such as doped regions, buried layers, epitaxial (epi) layers, or combinations thereof. In some embodiments, the material of substrate 10 may include a silicon substrate having a <111> orientation.
在一些实施例中,衬底10可包含缓冲层。缓冲层可与氮化物基半导体层12接触。缓冲层可配置成减小衬底10与氮化物基半导体层12之间的晶格和热失配,由此解决由失配/差异导致的缺陷。缓冲层可包含III-V化合物。III-V化合物可包含例如但不限于铝、镓、铟、氮或其组合。因此,缓冲层的示例性材料还可包含例如但不限于GaN、AlN、AlGaN、InAlGaN或其组合。In some embodiments, substrate 10 may include a buffer layer. The buffer layer may be in contact with the nitride-based semiconductor layer 12 . The buffer layer may be configured to reduce lattice and thermal mismatch between the substrate 10 and the nitride-based semiconductor layer 12, thereby resolving defects caused by mismatch/disparity. The buffer layer may contain III-V compounds. III-V compounds may include, for example, but not limited to, aluminum, gallium, indium, nitrogen, or combinations thereof. Accordingly, exemplary materials for the buffer layer may also include, for example, but not limited to, GaN, AIN, AlGaN, InAlGaN, or combinations thereof.
在一些实施例中,衬底10可进一步包含成核层(图中未展示)。成核层可形成于缓冲层下方。成核层可配置成提供过渡以适应衬底10与缓冲层的III-氮化物层之间的失配/差异。成核层的示例性材料可包含例如但不限于AlN或其合金中的任一个。In some embodiments, substrate 10 may further include a nucleation layer (not shown). A nucleation layer may be formed beneath the buffer layer. The nucleation layer may be configured to provide a transition to accommodate the mismatch/difference between the substrate 10 and the III-nitride layer of the buffer layer. Exemplary materials for the nucleation layer may include, for example, but not limited to, any of AlN or alloys thereof.
氮化物基半导体层12安置于缓冲层上/之上/上方。氮化物基半导体层14安置于氮化物基半导体层12上/之上/上方。氮化物基半导体层12的示例性材料可包含例如但不限于氮化物或III-V族化合物,例如GaN、AlN、InN、InxAlyGa(1-x-y)N(其中x+y≤1)、AlxGa(1-x)N(其中x≤1)。氮化物基半导体层14的示例性材料可包含例如但不限于氮化物或III-V族化合物,例如GaN、AlN、InN、InxAlyGa(1-x-y)N(其中x+y≤1)、AlxGa(1-x)N(其中x≤1)。The nitride-based semiconductor layer 12 is disposed on/on/over the buffer layer. The nitride-based semiconductor layer 14 is disposed on/on/over the nitride-based semiconductor layer 12 . Exemplary materials for the nitride-based semiconductor layer 12 may include, for example, but not limited to, nitrides or III-V compounds, such as GaN, AlN, InN, InxAlyGa ( 1-xy) N (where x+y≤1 ), Al x Ga (1-x) N (where x≤1). Exemplary materials for nitride-based semiconductor layer 14 may include, for example, but not limited to, nitrides or III-V compounds, such as GaN, AlN, InN , InxAlyGa (1-xy) N (where x+y≤1 ), Al x Ga (1-x) N (where x≤1).
选择氮化物基半导体层12和14的示例性材料以使得氮化物基半导体层14的带隙(即,禁带宽度)大于/高于氮化物基半导体层12的带隙,这会使其电子亲和势彼此不同并且在其间形成异质结。举例来说,当氮化物基半导体层12是具有约3.4eV的带隙的未掺杂GaN层时,氮化物基半导体层14可选择为具有约4.0eV的带隙的AlGaN层。因而,氮化物基半导体层12和14可分别充当沟道层和势垒层。在沟道层与势垒层之间的接合界面处产生三角阱势,使得电子在三角阱中积聚,由此邻近于异质结而产生二维电子气体(2DEG)区。因此,半导体器件1A可包含至少一个GaN基高电子迁移率晶体管(HEMT)。Exemplary materials of nitride-based semiconductor layers 12 and 14 are selected such that the band gap (i.e., band gap) of nitride-based semiconductor layer 14 is larger/higher than the band gap of nitride-based semiconductor layer 12 , which causes its electrons to The affinities are different from each other and a heterojunction is formed between them. For example, when the nitride-based semiconductor layer 12 is an undoped GaN layer having a band gap of about 3.4 eV, the nitride-based semiconductor layer 14 may be selected to be an AlGaN layer having a band gap of about 4.0 eV. Thus, the nitride-based semiconductor layers 12 and 14 may function as channel layers and barrier layers, respectively. A triangular well potential is generated at the bonding interface between the channel layer and the barrier layer, causing electrons to accumulate in the triangular well, thereby creating a two-dimensional electron gas (2DEG) region adjacent to the heterojunction. Therefore, the semiconductor device 1A may include at least one GaN-based high electron mobility transistor (HEMT).
栅电极介电层16设置在氮化物半导体层14上。栅电极介电层16覆盖在氮化物半导体层14上。栅电极介电层16的材料可包含例如但不限于电介质材料。举例来说,栅电极介电层16可包含SiNx(例如,Si3N4)、SiOx、Si3N4、SiON、SiC、SiBN、SiCBN、氧化物、氮化物、氧化物、等离子体增强氧化物(PEOX),或其组合。Gate electrode dielectric layer 16 is provided on nitride semiconductor layer 14 . The gate electrode dielectric layer 16 covers the nitride semiconductor layer 14 . The material of the gate electrode dielectric layer 16 may include, for example, but not limited to, dielectric materials. For example, gate electrode dielectric layer 16 may include SiNx (eg, Si 3 N 4 ), SiOx, Si 3 N 4 , SiON, SiC, SiBN, SiCBN, oxide, nitride, oxide, plasma enhanced oxidation (PEOX), or a combination thereof.
电极20和22可安置于栅电极介电层16上/之上/上方。电极20和22可穿过栅电极介电层16,以与氮化物半导体层14接触。在一些实施例中,电极20可充当源极电极。在一些实施例中,电极20可充当漏极电极。在一些实施例中,电极22可充当源极电极。在一些实施例中,电极22可充当漏极电极。电极20和22的作用取决于装置设计。Electrodes 20 and 22 may be disposed on/on/over gate electrode dielectric layer 16 . Electrodes 20 and 22 may pass through gate electrode dielectric layer 16 to contact nitride semiconductor layer 14 . In some embodiments, electrode 20 may function as a source electrode. In some embodiments, electrode 20 may function as a drain electrode. In some embodiments, electrode 22 may function as a source electrode. In some embodiments, electrode 22 may function as a drain electrode. The role of electrodes 20 and 22 depends on the device design.
在一些实施例中,电极20和22可包含例如但不限于金属、合金、掺杂半导体材料(例如掺杂结晶硅)、例如硅化物和氮化物的化合物、其它导体材料或其组合。电极20和22的示例性材料可包含例如但不限于Ti、AlSi、TiN或其组合。电极20和22可以是单个层,或者是具有相同或不同组成的多个层。在一些实施例中,电极20和22与氮化物基半导体层14形成欧姆接触。欧姆接触可通过将Ti、Al或其它合适的材料应用于电极20和22来实现。在一些实施例中,电极20和22中的每一个由至少一个共形层和导电填充物形成。共形层可包覆导电填充物。共形层的示例性材料可包含例如但不限于Ti、Ta、TiN、Al、Au、AlSi、Ni、Pt,或其组合。导电填充物的示例性材料可包含例如但不限于AlSi、AlCu或其组合。In some embodiments, electrodes 20 and 22 may include, for example, but not limited to, metals, alloys, doped semiconductor materials (eg, doped crystalline silicon), compounds such as silicides and nitrides, other conductive materials, or combinations thereof. Exemplary materials for electrodes 20 and 22 may include, for example, but not limited to, Ti, AlSi, TiN, or combinations thereof. Electrodes 20 and 22 may be a single layer, or multiple layers of the same or different compositions. In some embodiments, electrodes 20 and 22 form ohmic contacts with nitride-based semiconductor layer 14 . Ohmic contact may be achieved by applying Ti, Al or other suitable materials to electrodes 20 and 22. In some embodiments, electrodes 20 and 22 are each formed from at least one conformal layer and a conductive filler. The conformal layer may encapsulate the conductive filler. Exemplary materials for the conformal layer may include, for example, but not limited to, Ti, Ta, TiN, Al, Au, AlSi, Ni, Pt, or combinations thereof. Exemplary materials for conductive fillers may include, for example, but not limited to, AlSi, AlCu, or combinations thereof.
氮化物导电层30设置在栅电极介电层16上。氮化物导电层30可覆盖在栅电极介电层16的部分区域上。氮化物导电层30可接触栅电极介电层16。氮化物导电层30位在电极20与22之间。氮化物导电层30的示例性材料可包含金属或金属化合物。氮化物导电层30可形成为单个层,或者形成为具有相同或不同组成的多个层。金属或金属化合物的示例性材料可包含例如但不限于TiN或TaN。Nitride conductive layer 30 is provided on gate electrode dielectric layer 16 . The nitride conductive layer 30 may cover a portion of the gate electrode dielectric layer 16 . Nitride conductive layer 30 may contact gate electrode dielectric layer 16 . Nitride conductive layer 30 is located between electrodes 20 and 22. Exemplary materials for nitride conductive layer 30 may include metals or metal compounds. The nitride conductive layer 30 may be formed as a single layer, or as multiple layers having the same or different compositions. Exemplary materials of metals or metal compounds may include, for example, but not limited to, TiN or TaN.
沉积层32设置在栅电极介电层16上。沉积层32可覆盖氮化物导电层30、电极20及22。沉积层32可覆盖氮化物导电层30的侧壁。沉积层32可以是单个层,或者是具有相同或不同组成的多个层。沉积层32可充当层间电介质(ILD)或金属间电介质(IMD)。沉积层32也可充当保护层。沉积层32的材料可包含例如但不限于电介质材料。举例来说,沉积层32可包含SiNx(例如,Si3N4)、SiOx、Si3N4、SiON、SiC、SiBN、SiCBN、氧化物、氮化物、氧化物、等离子体增强氧化物(PEOX)或其组合。在一些实施例中,栅电极介电层16与沉积层32可具有相同的材料。在一些实施例中,氮化物导电层30与沉积层32具有不同的材料,例如氮化物导电层30包括氮化钛,而沉积层32具有的电介质材料不包括钛。由于氮化物导电层30与沉积层32具有不同的材料,故其在面对同一种刻蚀剂的时候,可以展现出不同的刻蚀速率。举例来说,当进行刻蚀工艺的时候,沉积层32可因与刻蚀剂产生化学反应而被去除,然而氮化物导电层30能够几乎不与同一刻蚀剂发生反应,并因此作为刻蚀工艺中的刻蚀钝化层或是刻蚀终止层。Deposition layer 32 is provided on gate electrode dielectric layer 16 . Deposition layer 32 may cover nitride conductive layer 30 and electrodes 20 and 22 . Deposition layer 32 may cover sidewalls of nitride conductive layer 30 . Deposited layer 32 may be a single layer, or multiple layers of the same or different compositions. Deposited layer 32 may function as an interlayer dielectric (ILD) or intermetal dielectric (IMD). Deposited layer 32 may also serve as a protective layer. The material of deposited layer 32 may include, for example, but not limited to, dielectric materials. For example, deposition layer 32 may include SiNx (eg, Si3N4), SiOx, Si3N4 , SiON , SiC , SiBN, SiCBN, oxides, nitrides, oxides, plasma enhanced oxides (PEOX) or combinations thereof. In some embodiments, gate electrode dielectric layer 16 and deposition layer 32 may be of the same material. In some embodiments, the nitride conductive layer 30 and the deposition layer 32 have different materials. For example, the nitride conductive layer 30 includes titanium nitride, while the deposition layer 32 has a dielectric material that does not include titanium. Since the nitride conductive layer 30 and the deposition layer 32 are made of different materials, they may exhibit different etching rates when facing the same etchant. For example, when an etching process is performed, the deposition layer 32 may be removed due to a chemical reaction with the etchant. However, the nitride conductive layer 30 can hardly react with the same etchant, and therefore acts as an etching process. The etching passivation layer or etching stop layer in the process.
栅电极40设置在氮化物导电层30以及沉积层32上。栅电极40穿过沉积层32并与氮化物导电层30接触。栅电极40可通过氮化物导电层30而与栅电极介电层16分隔开来。栅电极40位在电极20与22之间。栅电极40可以是后栅极。栅电极40的形成次序可晚于电极20与22。栅电极40相对氮化物半导体层14的位置比电极20及22相对氮化物半导体层14的位置还高。更进一步来说,栅电极40的顶面相对氮化物半导体层14的位置会完全地高过所述电极20及22的整体相对氮化物半导体层14的位置。另外,作为后栅极,栅电极40的顶面的位置也高过沉积层32,且至少一部分的栅电极40会覆盖在沉积层32上。Gate electrode 40 is provided on nitride conductive layer 30 and deposition layer 32 . Gate electrode 40 passes through deposition layer 32 and contacts nitride conductive layer 30 . Gate electrode 40 may be separated from gate electrode dielectric layer 16 by nitride conductive layer 30 . Gate electrode 40 is located between electrodes 20 and 22. Gate electrode 40 may be a back gate. Gate electrode 40 may be formed later than electrodes 20 and 22 . The position of the gate electrode 40 relative to the nitride semiconductor layer 14 is higher than the positions of the electrodes 20 and 22 relative to the nitride semiconductor layer 14 . Furthermore, the position of the top surface of the gate electrode 40 relative to the nitride semiconductor layer 14 is completely higher than the position of the entire electrodes 20 and 22 relative to the nitride semiconductor layer 14 . In addition, as a back gate, the top surface of the gate electrode 40 is also positioned higher than the deposition layer 32 , and at least a part of the gate electrode 40 will cover the deposition layer 32 .
在进行栅电极40的制作工艺前,可先去除一部分的沉积层32,以在沉积层32中形成开口,其为用来填充栅电极40的空间。在一些实施例中,去除一部分的沉积层32可由刻蚀工艺实现。在此刻蚀工艺的过程中,作为刻蚀终止层的氮化物导电层30可以避免栅电极介电层16受到刻蚀影响。也就是说,由于使用氮化物导电层30作为刻蚀终止层,故可更容易控制在沉积层32中形成开口的工艺。Before performing the manufacturing process of the gate electrode 40 , a portion of the deposition layer 32 may be removed first to form an opening in the deposition layer 32 , which is used to fill the space of the gate electrode 40 . In some embodiments, removing a portion of the deposited layer 32 may be accomplished by an etching process. During the etching process, the nitride conductive layer 30 as an etching stop layer can prevent the gate electrode dielectric layer 16 from being affected by etching. That is, since the nitride conductive layer 30 is used as the etching stop layer, the process of forming the opening in the deposition layer 32 can be more easily controlled.
具体来说,若是无使用氮化物导电层作为刻蚀终止层,则会需要精密控制工艺参数,以避免栅电极介电层受到损伤。在大量制作的需求下,精密控制工艺参数会降低生产速度。此外,即便采用精密控制,仍会有使栅电极介电层受到损伤的可能性。因此,使用氮化物导电层30作为刻蚀终止层,可使在沉积层32中形成开口的工艺具有更大的弹性。例如,所采用的工艺可以是对沉积层32有较快刻蚀速度的参数。Specifically, if the nitride conductive layer is not used as the etching stop layer, the process parameters will need to be precisely controlled to avoid damage to the gate electrode dielectric layer. Under the demand for mass production, precise control of process parameters will slow down production speed. In addition, even with precise control, there is still the possibility of damage to the gate electrode dielectric layer. Therefore, using the nitride conductive layer 30 as the etching stop layer can make the process of forming openings in the deposition layer 32 more flexible. For example, the process used may be a parameter with a faster etching speed for the deposition layer 32 .
在进行栅电极40的制作工艺后,栅电极40的侧壁可以与沉积层32的内侧壁接触并形成交界面。在如图1所绘的示例性附图中,此交界面相对氮化物半导体层14为垂直的。此外,由于可对沉积层32的开口形成使用较快的刻蚀速度参数,故沉积层32的内侧壁的表面粗糙度可以相对大。例如,沉积层32的内侧壁的表面粗糙度可以大于沉积层32的顶面的表面粗糙度。After the gate electrode 40 is fabricated, the sidewalls of the gate electrode 40 may contact the inner sidewalls of the deposition layer 32 to form an interface. In the exemplary drawing shown in FIG. 1 , the interface is vertical with respect to the nitride semiconductor layer 14 . In addition, since a faster etching speed parameter can be used for forming the openings of the deposition layer 32 , the surface roughness of the inner sidewall of the deposition layer 32 can be relatively large. For example, the surface roughness of the inner sidewall of the deposition layer 32 may be greater than the surface roughness of the top surface of the deposition layer 32 .
另一方面,在沉积层32内形成的开口宽度会小于氮化物导电层30的宽度,此将使得栅电极40的底面的宽度也小于氮化物导电层30的宽度。而由于栅电极40是作为后栅极,故其顶面的宽度可以形成为大于氮化物导电层30的宽度。On the other hand, the width of the opening formed in the deposition layer 32 will be smaller than the width of the nitride conductive layer 30 , which will make the width of the bottom surface of the gate electrode 40 smaller than the width of the nitride conductive layer 30 . Since the gate electrode 40 serves as a back gate, the width of its top surface can be formed larger than the width of the nitride conductive layer 30 .
通过如图1所绘的结构,可避免栅电极介电层16受到损害,也可利于加快在沉积层内形成开口的工艺速率。也因此,所形成具有D-MIS(depletion mode misfet)结构的氮基半导体器件可具有高可靠度以及高良率。Through the structure as shown in FIG. 1 , damage to the gate electrode dielectric layer 16 can be avoided, and the process speed of forming openings in the deposited layer can also be accelerated. Therefore, the formed nitrogen-based semiconductor device having a D-MIS (depletion mode misfet) structure can have high reliability and high yield.
用于制造氮基半导体器件1A的方法的不同阶段在图2A、图2B、图2C、图2D和图2E中展示,如下文所描述。在下文中,沉积技术可包含例如但不限于原子层沉积(ALD)、物理气相沉积(PVD)、化学气相沉积(CVD)、金属有机CVD(MOCVD)、等离子体增强型CVD(PECVD)、低压力CVD(LPCVD)、等离子体辅助气相沉积、外延生长或其它合适的工艺。The different stages of the method for manufacturing the nitrogen-based semiconductor device 1A are illustrated in Figures 2A, 2B, 2C, 2D and 2E, as described below. In the following, deposition techniques may include, for example, but not limited to, atomic layer deposition (ALD), physical vapor deposition (PVD), chemical vapor deposition (CVD), metal organic CVD (MOCVD), plasma enhanced CVD (PECVD), low pressure CVD (LPCVD), plasma-assisted vapor deposition, epitaxial growth or other suitable processes.
参考图2A,提供衬底10。氮化物基半导体层12和14可通过使用上文提及的沉积技术依次形成于衬底10上方。栅电极介电层16可通过使用上文提及的沉积技术形成于氮化物基半导体层14上方。氮化物导电覆盖层50可通过使用上文提及的沉积技术形成于栅电极介电层16上方。Referring to Figure 2A, a substrate 10 is provided. Nitride-based semiconductor layers 12 and 14 may be sequentially formed over substrate 10 using the above-mentioned deposition techniques. Gate electrode dielectric layer 16 may be formed over nitride-based semiconductor layer 14 using the deposition techniques mentioned above. Nitride conductive capping layer 50 may be formed over gate electrode dielectric layer 16 using the deposition techniques mentioned above.
参考图2B,屏蔽层52可通过使用上文提及的沉积技术形成于氮化物导电覆盖层50上方。屏蔽层52可用来作为后续图案化工艺中的屏蔽层,其可定义位于其下方层体的轮廓或形状。Referring to FIG. 2B , a shielding layer 52 may be formed over the nitride conductive capping layer 50 using the deposition techniques mentioned above. The shielding layer 52 can be used as a shielding layer in subsequent patterning processes and can define the outline or shape of the layer beneath it.
参考图2C,可利用屏蔽层52对氮化物导电覆盖层50进行图案化,以形成氮化物导电层30。氮化物导电层30的轮廓或形状可由屏蔽层52转移而成。Referring to FIG. 2C , the nitride conductive capping layer 50 may be patterned using the shielding layer 52 to form the nitride conductive layer 30 . The contour or shape of nitride conductive layer 30 may be transferred from shielding layer 52 .
参考图2D,电极20及22可通过使用沉积技术和一系列图案化工艺依次形成。在一些实施例中,图案化工艺可以包含光刻、曝光和显影、蚀刻、其它合适的工艺或其组合。沉积层32可通过使用沉积技术形成,且沉积层32覆盖栅电极介电层16、电极20及22、氮化物导电层30。接下来,屏蔽层54可通过使用沉积技术形成形成在沉积层32上。屏蔽层54具有开口,且屏蔽层54的开口位置对准氮化物导电层30。Referring to FIG. 2D , electrodes 20 and 22 may be formed sequentially using deposition techniques and a series of patterning processes. In some embodiments, the patterning process may include photolithography, exposure and development, etching, other suitable processes, or combinations thereof. The deposition layer 32 may be formed using a deposition technology, and the deposition layer 32 covers the gate electrode dielectric layer 16 , the electrodes 20 and 22 , and the nitride conductive layer 30 . Next, a shielding layer 54 may be formed on the deposition layer 32 using a deposition technique. The shielding layer 54 has an opening, and the position of the opening of the shielding layer 54 is aligned with the nitride conductive layer 30 .
参考图2E,可可利用屏蔽层54在沉积层32中形成开口322,以暴露出所述氮化物导电层30的一部分。在一些实施例中,在沉积层32中形成开口322的步骤包括对沉积层32执行刻蚀,且氮化物导电层30作为刻蚀停止层。在开口322形成后,即可在开口322中形成栅电极;其中,在开口322中形成栅电极的步骤包括使栅电极能够完全地将开口322填满。于填满后,再使栅电极高过沉积层32,从而得到前述图1的结构。Referring to FIG. 2E , the shielding layer 54 may be used to form an opening 322 in the deposition layer 32 to expose a portion of the nitride conductive layer 30 . In some embodiments, forming the opening 322 in the deposited layer 32 includes etching the deposited layer 32 with the nitride conductive layer 30 serving as an etch stop layer. After the opening 322 is formed, the gate electrode can be formed in the opening 322 ; wherein, the step of forming the gate electrode in the opening 322 includes enabling the gate electrode to completely fill the opening 322 . After filling, the gate electrode is made higher than the deposition layer 32 to obtain the structure of FIG. 1 .
图3是根据本公开的一些实施例的半导体器件1B的横截面视图。半导体器件1B类似于如参考图1所描述和说明的半导体器件1A,不同之处在于氮化物导电层30由氮化物导电层30B替换。氮化物导电层30B在其顶表面处具有凹槽。氮化物导电层30B的凹槽可以在对沉积层32进行刻蚀期间产生的。在一些实施例中,在对沉积层32进行刻蚀期间,使用的刻蚀剂除了对沉积层32有快速的刻蚀速率以外,对于氮化物导电层30B也具有慢速的刻蚀速率,使得一部分的氮化物导电层30B也会在刻蚀期间被去除,从而形成凹槽。栅极电极40穿过沉积层32且其底部位于凹槽内。通过凹槽,可以增加氮化物导电层30B与栅极电极40之间的接触面积,以满足不同的电性需求。例如可借由调整氮化物导电层30B与栅极电极40之间的接触面积,以对应地调控器件的阈值电压。3 is a cross-sectional view of semiconductor device 1B according to some embodiments of the present disclosure. The semiconductor device 1B is similar to the semiconductor device 1A as described and illustrated with reference to FIG. 1 , except that the nitride conductive layer 30 is replaced by a nitride conductive layer 30B. Nitride conductive layer 30B has grooves at its top surface. The grooves in nitride conductive layer 30B may be created during etching of deposited layer 32 . In some embodiments, during etching of the deposition layer 32 , the etchant used not only has a fast etching rate for the deposition layer 32 but also has a slow etching rate for the nitride conductive layer 30B, so that A portion of the nitride conductive layer 30B is also removed during etching, thereby forming grooves. Gate electrode 40 passes through deposition layer 32 and has its bottom located within the groove. Through the grooves, the contact area between the nitride conductive layer 30B and the gate electrode 40 can be increased to meet different electrical requirements. For example, the contact area between the nitride conductive layer 30B and the gate electrode 40 can be adjusted to correspondingly adjust the threshold voltage of the device.
图4是根据本公开的一些实施例的半导体器件1C的横截面视图。半导体器件1C类似于如参考图1所描述和说明的半导体器件1A,不同之处在于沉积层32和栅极电极40由沉积层32C和栅极电极40C替换。栅电极40C的侧壁可以与沉积层32C的内侧壁接触并形成交界面。在如图4所绘的示例性附图中,此交界面相对氮化物半导体层14为倾斜的。由于可对沉积层32C的开口形成使用较快的刻蚀速度参数,故沉积层32C的内侧壁可因应较快的刻蚀速度参数而呈现微倾斜的。4 is a cross-sectional view of a semiconductor device 1C according to some embodiments of the present disclosure. The semiconductor device 1C is similar to the semiconductor device 1A as described and illustrated with reference to FIG. 1 , except that the deposition layer 32 and the gate electrode 40 are replaced by the deposition layer 32C and the gate electrode 40C. The sidewalls of the gate electrode 40C may contact the inner sidewalls of the deposition layer 32C and form an interface. In the exemplary drawing shown in FIG. 4 , the interface is inclined relative to the nitride semiconductor layer 14 . Since faster etching speed parameters can be used to form openings in the deposition layer 32C, the inner sidewall of the deposition layer 32C can be slightly inclined in response to the faster etching speed parameters.
选择和描述实施例是为了最佳地解释本公开的原理及其实际应用,使得所属领域的其他技术人员能够理解各种实施例的公开内容,并且能够进行适合于预期的特定用途的各种修改。The embodiments were chosen and described in order to best explain the principles of the disclosure and its practical application, thereby enabling others skilled in the art to understand the disclosure of the various embodiments and with various modifications as are suited to the particular use contemplated. .
如本文中所使用且不另外定义,术语“基本上”、“大体上”、“近似”和“约”用于描述并考虑较小变化。当与事件或情形结合使用时,所述术语可涵盖事件或情形明确发生的情况以及事件或情形近似于发生的情况。举例来说,当结合数值使用时,术语可涵盖小于或等于所述数值的±10%的变化范围,例如小于或等于±5%、小于或等于±4%、小于或等于±3%、小于或等于±2%、小于或等于±1%、小于或等于±0.5%、小于或等于±0.1%、或小于或等于±0.05%。术语“大体上共面”可指沿同一平面定位的在数微米内的两个表面,例如沿同一平面定位的在40μm内、30μm内、20μm内、10μm内或1μm内的两个表面。As used herein and not otherwise defined, the terms "substantially," "substantially," "approximately" and "approximately" are used to describe and account for minor variations. When used in connection with an event or situation, the terms may cover situations in which the event or situation clearly occurs as well as situations in which the event or situation approximates the occurrence. For example, when used in conjunction with a numerical value, the term may encompass a variation of less than or equal to ±10% of the stated numerical value, such as less than or equal to ±5%, less than or equal to ±4%, less than or equal to ±3%, less than Or equal to ±2%, less than or equal to ±1%, less than or equal to ±0.5%, less than or equal to ±0.1%, or less than or equal to ±0.05%. The term "substantially coplanar" may refer to two surfaces located along the same plane within a few microns, for example two surfaces located along the same plane within 40 μm, within 30 μm, within 20 μm, within 10 μm or within 1 μm.
如本文中所使用,除非上下文另外明确规定,否则单数术语“一(a/an)”和“所述”可包含多个提及物。在一些实施例的描述中,提供于另一组件“上”或“之上”的组件可涵盖前一组件直接在后一组件上(例如,与后一组件物理接触)的情况,以及一或多个中间组件位于前一组件与后一组件之间的情况。As used herein, the singular terms "a/an" and "the" may include plural references unless the context clearly dictates otherwise. In the description of some embodiments, a component provided "on" or "over" another component may encompass situations where the former component is directly on (e.g., in physical contact with) the latter component, as well as one or The situation where multiple intermediate components are located between the previous component and the following component.
虽然已参考本公开的具体实施例描述且说明本公开,但这些描述和说明并非限制性的。所属领域的技术人员应理解,在不脱离如由所附权利要求书定义的本公开的真实精神和范围的情况下,可作出各种改变且可取代等效物。所述说明可能未必按比例绘制。由于制造工艺和公差,本公开中的工艺再现与实际设备之间可能存在区别。此外,应了解,实际装置和层可能相对于图式的矩形层描绘存在偏差,且可能由于例如共形沉积、蚀刻等等制造工艺而包含角表面或边缘、圆角等等。可存在未特别说明的本公开的其它实施例。应将本说明书和图式视为说明性而非限制性的。可进行修改,以使特定情形、材料、物质组成、方法或工艺适应本公开的目标、精神和范围。所有此类修改都既定在所附权利要求书的范围内。虽然本文中公开的方法已参考按特定次序执行的特定操作加以描述,但应理解,可在不脱离本公开的教示的情况下组合、细分或重新排序这些操作以形成等效方法。因此,除非在本文中特定指示,否则操作的次序和分组并非限制性的。While the disclosure has been described and illustrated with reference to specific embodiments of the disclosure, these descriptions and illustrations are not limiting. It will be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the true spirit and scope of the disclosure as defined by the appended claims. Illustrations may not necessarily be drawn to scale. Due to manufacturing processes and tolerances, there may be differences between the process reproductions in this disclosure and actual devices. Furthermore, it is to be understood that actual devices and layers may deviate from the rectangular layer depictions of the drawings and may contain corner surfaces or edges, rounded corners, etc. due to manufacturing processes such as conformal deposition, etching, and the like. There may be other embodiments of the disclosure not specifically illustrated. The specification and drawings are to be regarded as illustrative rather than restrictive. Modifications may be made to adapt a particular situation, material, composition of matter, method or process to the objectives, spirit and scope of the disclosure. All such modifications are intended to be within the scope of the appended claims. Although the methods disclosed herein have been described with reference to specific operations performed in a specific order, it should be understood that these operations may be combined, subdivided, or reordered to form equivalent methods without departing from the teachings of this disclosure. Accordingly, the order and grouping of operations is not limiting unless specifically indicated herein.
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