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CN115421313A - A true three-dimensional stereoscopic color display system and display method based on full-color up-conversion luminescence nanodisplay - Google Patents

A true three-dimensional stereoscopic color display system and display method based on full-color up-conversion luminescence nanodisplay Download PDF

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CN115421313A
CN115421313A CN202211173683.1A CN202211173683A CN115421313A CN 115421313 A CN115421313 A CN 115421313A CN 202211173683 A CN202211173683 A CN 202211173683A CN 115421313 A CN115421313 A CN 115421313A
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贾恒
滕英跃
冯晓锐
杨龙
霍智强
赵佳
刘玲
贺日东
宝呼和
何伟艳
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Inner Mongolia University of Technology
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B30/00Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images
    • G02B30/50Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images the image being built up from image elements distributed over a 3D volume, e.g. voxels
    • G02B30/52Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images the image being built up from image elements distributed over a 3D volume, e.g. voxels the 3D volume being constructed from a stack or sequence of 2D planes, e.g. depth sampling systems
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
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    • G02B27/1006Beam splitting or combining systems for splitting or combining different wavelengths
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
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Abstract

本发明公开了一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统及其显示方法,属于三维显示技术领域,该显示系统由全色上转换发光纳米显示器、光学透镜组、三个不同波长的激光器及激光扫描仪组成;全色上转换发光纳米显示器是由三元正交激发发射体系作为发光介质、高分子材料作为三维显示固体介质,通过掺杂或共聚的方法制备得到;三元正交激发发射体系可产生相互独立的,互不干扰的红、绿、蓝三基色发光,通过调控三束激光激发功率,可在显示器内部产生全色上转换发光;激光扫描仪用于接收3D建模软件输出的立体图像数据,并控制激光汇聚点在显示器中进行X轴、Y轴、Z轴三个方向的寻址扫描,实现纳米体像素点组成的三维立体图像显示。

Figure 202211173683

The invention discloses a true three-dimensional stereoscopic color display system and a display method based on a full-color up-conversion light-emitting nano-display, belonging to the technical field of three-dimensional display. The display system consists of a full-color up-conversion light-emitting nano-display, an optical lens group, three Composed of lasers with different wavelengths and laser scanners; full-color up-conversion luminescent nanodisplays are prepared by doping or copolymerization methods by using a ternary orthogonal excitation emission system as a luminescent medium and a polymer material as a three-dimensional display solid medium; The meta-orthogonal excitation and emission system can produce independent and non-interfering red, green, and blue primary color luminescence. By adjusting the excitation power of the three laser beams, full-color up-conversion luminescence can be generated inside the display; the laser scanner is used to receive The stereoscopic image data output by the 3D modeling software controls the laser convergence point to perform addressing and scanning in the three directions of the X-axis, Y-axis, and Z-axis in the display to realize the three-dimensional image display composed of nano-body pixels.

Figure 202211173683

Description

一种基于全色上转换发光纳米显示器的真三维立体彩色显示 系统及其显示方法A true three-dimensional stereoscopic color display based on a full-color up-conversion luminescent nanodisplay System and display method thereof

技术领域technical field

本发明属于三维显示技术领域,具体涉及一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统及其显示方法。The invention belongs to the technical field of three-dimensional display, and in particular relates to a true three-dimensional stereoscopic color display system and a display method thereof based on a full-color up-conversion light-emitting nanometer display.

背景技术Background technique

我们生活在一个三维立体的空间中,眼睛对于现实世界的感知往往都是立体的三维信息。然而,作为三维立体世界的感知者,人类获取视觉信息的大约70%都是基于二维平面的,包括图片、绘画、视频等;这些基于二维显示技术的平面信息无法满足人脑信息处理机制进行信息处理的习惯,人脑更需要从三维视角获取真实物体的“全部信息”。We live in a three-dimensional space, and the eyes' perception of the real world is often three-dimensional information. However, as the perceiver of the three-dimensional world, about 70% of the visual information that humans acquire is based on two-dimensional planes, including pictures, paintings, videos, etc. These plane information based on two-dimensional display technology cannot satisfy the information processing mechanism of the human brain. The habit of information processing, the human brain needs to obtain "full information" of real objects from a three-dimensional perspective.

随着科学技术的不断发展,三维显示技术逐渐出现在大众的视线。特别是2009年全球第一部3D电影《阿凡达》的上映,其生动逼真的三维立体视觉感急速吸引了人们的眼球,大家对三维显示的兴趣日趋强烈。近几年来,三维显示技术由于信息量大、全视景、多角度、三维视觉效果等特点,在医疗、军事、教育及日常生活等领域展现出广泛的应用前景。目前,市场上常用的三维显示技术例如分光立体显示、全息三维显示等主要是通过人的双眼视差或心理深度暗示形成伪视觉三维空间。然而,这些基于非自然的虚拟三维立体效果事实上并不是真正的三维立体显示,因为它们不能提供物理景深,没有完整的物理深度暗示。并且这种虚拟的立体感通常需要借助眼镜、头盔等助视仪器,长时间很容易引起头痛、视觉疲劳、错觉等。因此,开发具有真正物理深度的真三维立体显示技术对于显示领域的发展具有非常重要的价值和意义。With the continuous development of science and technology, three-dimensional display technology gradually appears in the eyes of the public. Especially when the world's first 3D movie "Avatar" was released in 2009, its vivid and lifelike 3D stereoscopic vision quickly attracted people's attention, and everyone's interest in 3D display has become increasingly strong. In recent years, due to the characteristics of large amount of information, full view, multi-angle, and three-dimensional visual effects, 3D display technology has shown broad application prospects in the fields of medical treatment, military affairs, education, and daily life. At present, commonly used 3D display technologies on the market, such as spectroscopic stereoscopic display and holographic 3D display, etc., mainly form a pseudo-visual 3D space through human binocular parallax or psychological depth hints. However, these unnatural-based virtual 3D stereoscopic effects are not true 3D stereoscopic displays in fact, because they cannot provide physical depth of field and do not have a complete physical depth hint. And this kind of virtual three-dimensional sense usually requires the help of vision aids such as glasses and helmets, which can easily cause headaches, visual fatigue, and illusions for a long time. Therefore, developing a true three-dimensional display technology with real physical depth is of great value and significance to the development of the display field.

真三维立体显示系统采用的主要原理就是光频上转换技术,这种显示方法由于具有实物化、高分辨、运行速度快等优点,在显示领域展现出巨大的应用潜力。在过去几十年,各种基于光频上转换的稀土掺杂材料被应用于三维显示技术中。尽管基于光频上转换技术的三维立体显示研究取得了较大的进展,但由于研究者们一直没有解决共掺多种稀土发光离子引起的激发光串扰、有害的能量传递及多色发光干扰等问题,导致三维显示成像分辨率过低,如何解决成像分辨率低的问题成为攻克真三维立体显示技术的关键。The main principle adopted by the true three-dimensional stereoscopic display system is the optical frequency up-conversion technology. This display method has shown great application potential in the display field due to its advantages of materialization, high resolution, and fast operation speed. In the past few decades, various rare earth doped materials based on optical frequency upconversion have been applied in 3D display technology. Although great progress has been made in the research of 3D stereoscopic display based on optical frequency up-conversion technology, researchers have not solved the crosstalk of excitation light, harmful energy transfer and multicolor luminescence interference caused by the co-doping of various rare earth luminescent ions. How to solve the problem of low imaging resolution has become the key to overcome the true three-dimensional display technology.

发明内容Contents of the invention

针对现有技术中存在的稀土掺杂材料所面临的激发光串扰、不必要的能量传递、多色发光相互干扰、三维显示成像分辨率过低等问题,本发明的目的是提供一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统及其显示方法,该显示系统采用基于三元正交激发发射体系的三维显示固体介质作为显示器,所述三元正交激发发射体系是由具有垂直激发响应正交三基色发射特性的多层核壳结构上转换纳米晶构成;在三元正交激发发射体系中,三基色发光纳米层(核)只能分别响应特定波长的近红外光激发,其中,蓝光发射核响应980nm激发,红光发射层响应1560nm激发,绿光发射层响应808nm激发;并且同一纳米材料中的三个发光过程是相互独立的,互不干扰的;从而可以获得具有高亮度和高色纯度的多色上转换发光,可提高三维显示成像分辨率。Aiming at the problems of excitation light crosstalk, unnecessary energy transfer, multi-color luminescent mutual interference, and low resolution of three-dimensional display imaging faced by rare earth doped materials in the prior art, the purpose of the present invention is to provide a A true three-dimensional stereoscopic color display system and a display method thereof for a color-up-conversion luminescent nanometer display, the display system adopts a three-dimensional display solid medium based on a ternary orthogonal excitation-emission system as a display, and the ternary orthogonal excitation-emission system is composed of The multi-layer core-shell structure up-conversion nanocrystals with vertical excitation response and orthogonal trichromatic emission characteristics; in the ternary orthogonal excitation and emission system, the trichromatic luminescent nanolayers (cores) can only respond to specific wavelengths of near-infrared light excitation respectively. , where the blue light-emitting nucleus responds to 980nm excitation, the red light-emitting layer responds to 1560nm excitation, and the green light-emitting layer responds to 808nm excitation; and the three light-emitting processes in the same nanomaterial are independent of each other and do not interfere with each other; thus, it is possible to obtain Multi-color up-conversion luminescence with high brightness and high color purity can improve the imaging resolution of 3D display.

本发明通过如下技术方案实现:The present invention realizes through following technical scheme:

第一方面,本发明提供了一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,包括全色上转换发光纳米显示器、光学透镜组、三个不同波长的激光器及激光扫描仪;所述光学透镜组包括激光准直透镜、长焦透镜及两个二向色镜,所述三个不同波长的激光器发射的激光依次通过相应波长的激光准直透镜和凸透镜进行准直,准直后的其中两束激光沿45度入射角通过其中一个二向色镜进行合束,合束后的激光沿45度入射角通过另外一个二向色镜与第三束激光进行合束,经过合束后的三束激光通过长焦透镜汇聚在全色上转换发光纳米显示器的三维空间定点位置处;所述全色上转换发光纳米显示器固定在激光扫描仪上,所述激光扫描仪用于根据设定好的立体图像数据,控制激光汇聚点在全色上转换发光纳米显示器上的X轴、Y轴、Z轴三个方向的扫描,并利用人眼视觉的暂留效应,可获得由无数个纳米体像素点组成的动态的三维立体显示图像。In the first aspect, the present invention provides a true three-dimensional color display system based on a full-color up-conversion luminescent nano-display, including a full-color up-conversion luminescent nano-display, an optical lens group, three lasers with different wavelengths, and a laser scanner; The optical lens group includes a laser collimator lens, a telephoto lens and two dichroic mirrors. The laser light emitted by the three different wavelength lasers is collimated sequentially through the laser collimator lens and the convex lens of the corresponding wavelength. The last two laser beams are combined through one of the dichroic mirrors at an incident angle of 45 degrees, and the combined laser beams are combined with the third laser beam through another dichroic mirror at an incident angle of 45 degrees. The three beams of laser light after the beam are converged at the fixed-point position in the three-dimensional space of the full-color up-conversion luminescent nano-display through the telephoto lens; the full-color up-conversion luminescent nano-display is fixed on the laser scanner, and the laser scanner is used to The set stereoscopic image data controls the scanning of the laser convergence point in the three directions of X-axis, Y-axis and Z-axis on the full-color up-conversion luminescent nano-display, and utilizes the persistence effect of human vision to obtain countless A dynamic three-dimensional display image composed of nanobody pixels.

进一步地,所述凸透镜的焦距为25mm,所述长焦透镜的焦距为10cm,所述二向色镜为980/808nm二向色镜或980/808/1560nm二向色镜。Further, the focal length of the convex lens is 25 mm, the focal length of the telephoto lens is 10 cm, and the dichroic mirror is a 980/808 nm dichroic mirror or a 980/808/1560 nm dichroic mirror.

进一步地,所述三个不同波长的激光器分别为980nm激光器、808nm激光器及1560nm激光器。Further, the three lasers with different wavelengths are 980nm laser, 808nm laser and 1560nm laser respectively.

进一步地,所述全色上转换发光纳米显示器是由三元正交激发发射体系作为发光介质、高分子材料作为三维显示固体介质、通过掺杂或共聚的方法制备出的具有高透明度的基于纳米晶/高分子复合材料的全色上转换发光纳米显示器。Furthermore, the full-color up-conversion luminescent nanodisplay is a nano-based nano-display with high transparency prepared by a ternary orthogonal excitation emission system as a luminescent medium, a polymer material as a three-dimensional display solid medium, and a method of doping or copolymerization. Full-color upconversion luminescent nanodisplays from crystal/polymer composites.

进一步地,所述高分子材料为环氧树脂、聚甲基丙烯酸甲酯或聚二甲基硅氧烷。Further, the polymer material is epoxy resin, polymethylmethacrylate or polydimethylsiloxane.

进一步地,所述三元正交激发发射体系通过如下方法制备得到,所述方法具体包括如下步骤:Further, the ternary orthogonal excitation emission system is prepared by the following method, which specifically includes the following steps:

首先,通过热共沉淀法制备蓝光发射核NaYF4:Yb/Tm纳米晶,然后将制备好的核纳米晶作为晶种诱导外延NaYF4惰性壳层的生长,随后将制备好的NaYF4:Yb/Tm@NaYF4核壳结构纳米晶作为晶种诱导外延红光发射层NaYF4:Er/Ho的生长,同样将制备好的双层核壳结构纳米晶作为晶种诱导外延NaYF4惰性壳层的生长,接着将制备好的三层核壳结构纳米晶作为晶种诱导外延绿光发射层NaYF4:Nd/Yb/Er层的生长,最后将四层核壳结构纳米晶作为晶种诱导外延NaYF4:Nd层的生长;制备得到的基于五层核壳结构纳米晶的三元正交激发发射体系。First, the blue light-emitting core NaYF 4 :Yb/Tm nanocrystals were prepared by thermal co-precipitation method, and then the prepared core nanocrystals were used as seeds to induce the growth of the epitaxial NaYF 4 inert shell layer, and then the prepared NaYF 4 :Yb /Tm@NaYF 4 core-shell structure nanocrystals are used as seeds to induce the growth of the epitaxial red light emitting layer NaYF 4 :Er/Ho, and the prepared double-layer core-shell structure nanocrystals are also used as seeds to induce the epitaxy of the NaYF 4 inert shell layer The growth of the prepared three-layer core-shell structure nanocrystal is used as the seed crystal to induce the growth of the epitaxial green light-emitting layer NaYF 4 :Nd/Yb/Er layer, and finally the four-layer core-shell structure nanocrystal is used as the seed crystal to induce the epitaxy NaYF 4 : Growth of Nd layer; prepared ternary orthogonal excitation emission system based on five-layer core-shell nanocrystals.

进一步地,所述全色上转换发光纳米显示器通过如下方法制备得到,所述方法具体包括如下步骤:Further, the full-color up-conversion light-emitting nano-display is prepared by the following method, which specifically includes the following steps:

将40mg/mL的三元正交激发发射体系与环己烷溶液按照体积比1:10加入到环氧树脂中,在室温条件下搅拌20分钟,然后依次加入体积分数为2%的有机硅消泡剂和体积分数为10%聚酰胺固化剂,将得到的分散液超声震荡30min使其分散均匀,随后通过注射器注入到透明硅胶模具中,待分散液完全固化,即得到全色上转换发光纳米显示器。Add 40 mg/mL ternary orthogonal excitation emission system and cyclohexane solution into the epoxy resin at a volume ratio of 1:10, stir at room temperature for 20 minutes, and then sequentially add 2% organosilicon dispersant Foam agent and polyamide curing agent with a volume fraction of 10%, ultrasonically vibrate the obtained dispersion for 30 minutes to disperse evenly, and then inject it into a transparent silicone mold through a syringe, and wait until the dispersion is completely cured to obtain a full-color up-conversion luminescent nanometer monitor.

进一步地,所述全色上转换发光纳米显示器通过如下方法制备得到,所述方法具体包括如下步骤:Further, the full-color up-conversion light-emitting nano-display is prepared by the following method, which specifically includes the following steps:

将0.02g引发剂偶氮二异丁腈和9g单体甲基丙烯酸甲酯加入到4mL乙酸乙酯中,随后加热到60℃保持70分钟,待低温预聚反应完成后,加入1mL含20mg三元正交激发发射体系的乙酸乙酯溶液,然后将升温到82℃进行高温聚合,待反应液呈透明粘稠状,停止反应并将其转移到玻璃模具中,最后在真空干燥箱中加热到120℃保持24小时完成高温固化,反应结束后即得到全色上转换发光纳米显示器。Add 0.02g initiator azobisisobutyronitrile and 9g monomer methyl methacrylate into 4mL ethyl acetate, then heat to 60°C for 70 minutes, after the low-temperature prepolymerization reaction is completed, add 1mL containing 20mg three Ethyl acetate solution of element orthogonal excitation emission system, then heat up to 82°C for high-temperature polymerization, wait until the reaction liquid is transparent and viscous, stop the reaction and transfer it to a glass mold, and finally heat it in a vacuum drying oven to Keep at 120°C for 24 hours to complete high-temperature curing, and a full-color up-conversion luminescent nanometer display can be obtained after the reaction is completed.

第二方面,本发明还提供了一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统的显示方法,具体包括如下步骤:In the second aspect, the present invention also provides a display method of a true three-dimensional color display system based on a full-color up-conversion light-emitting nano-display, which specifically includes the following steps:

步骤一:通过波长为980nm、808nm及1560nm的激光器发射激光,所述激光依次通过其相应波长的激光准直透镜和凸透镜进行准直,准直后的980nm和808nm激光沿45度入射角首先通过980/808nm二向色镜进行合束,合束后的980/808nm激光沿45度入射角再通过980/808/1560nm二向色镜与1560nm激光进行合束,经过合束后的三束激光最后通过长焦透镜汇聚在全色上转换发光纳米显示器的三维空间的定点处,通过调控三束激光激发功率,可在显示器内部产生蓝、青、黄、红、粉、白、绿全色上转换发光;Step 1: emit laser light through lasers with wavelengths of 980nm, 808nm and 1560nm, and the laser light is collimated through the laser collimating lens and convex lens of the corresponding wavelength in turn, and the collimated 980nm and 808nm lasers first pass through the 980/808nm dichroic mirrors combine beams, and the combined 980/808nm laser beams are combined with 1560nm laser beams through 980/808/1560nm dichroic mirrors along an incident angle of 45 degrees. After beam combining, the three laser beams Finally, the telephoto lens converges at the fixed point in the three-dimensional space of the full-color up-conversion light-emitting nano-display, and by adjusting the excitation power of the three laser beams, blue, cyan, yellow, red, pink, white, and green full-color up-converting can be generated inside the display. convert luminescence;

步骤二:通过3D建模软件输出立体图像数据,利用激光扫描仪的主控制器接收信号,通过激光扫描仪控制激光汇聚点的方法,在显示器中进行X轴、Y轴、Z轴三个方向的寻址扫描,利用人眼视觉的暂留效应,可获得由无数个纳米体像素点组成的三维立体图像的显示。Step 2: Output the stereoscopic image data through the 3D modeling software, use the main controller of the laser scanner to receive the signal, and control the laser convergence point through the laser scanner, and carry out the three directions of the X-axis, Y-axis, and Z-axis on the display. The addressing scan, using the persistence effect of human vision, can obtain the display of a three-dimensional image composed of countless nano-body pixels.

进一步地,通过调控三束激光激发功率,可以实现蓝、青、黄、红、粉、白、绿(如附图2所示从左到右)全色上转换发光的调控;具体地调控方案如下:Further, by adjusting the excitation power of the three laser beams, the adjustment of full-color up-conversion luminescence of blue, cyan, yellow, red, pink, white, and green (from left to right as shown in Figure 2) can be realized; the specific adjustment scheme as follows:

当808nm激光器的激发功率为0.0W,980nm激光器的激发功率为0.5W,1560nm激光器的电流为0.0A,产生蓝色上转换发光;When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.5W, and the current of the 1560nm laser is 0.0A, blue up-conversion luminescence is produced;

当808nm激光器的激发功率为0.8W,980nm激光器的激发功率为1.1W,1560nm激光器的电流为0.0A,产生青色上转换发光;When the excitation power of the 808nm laser is 0.8W, the excitation power of the 980nm laser is 1.1W, and the current of the 1560nm laser is 0.0A, cyan upconversion light is produced;

当808nm激光器激的发功率为1.5W,980nm激光器的激发功率为0.0W,1560nm激光器的电流为1.8A,产生黄色上转换发光;When the excitation power of the 808nm laser is 1.5W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 1.8A, yellow up-conversion luminescence is produced;

当808nm激光器激的发功率为0.0W,980nm激光器激的发功率为0.0W,1560nm激光器的电流为1.6A,产生红色上转换发光;When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 1.6A, red up-conversion luminescence is produced;

当808nm激光器激的发功率为0.0W,980nm激光器的激发功率为0.5W,1560nm激光器的电流为2.0A,产生粉色上转换发光;When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.5W, and the current of the 1560nm laser is 2.0A, pink up-conversion luminescence is produced;

当808nm激光器的激发功率为1.1W,980nm激光器的激发功率为2.5W,1560nm激光器的电流为1.2A,产生白色上转换发光;When the excitation power of the 808nm laser is 1.1W, the excitation power of the 980nm laser is 2.5W, and the current of the 1560nm laser is 1.2A, white up-conversion luminescence is produced;

当808nm激光器的激发功率为1.0W,980nm激光器的激发功率为0.0W,1560nm激光器的电流为0.0A,产生绿色上转换发光。When the excitation power of the 808nm laser is 1.0W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 0.0A, green up-conversion luminescence is generated.

与现有技术相比,本发明的优点如下:Compared with prior art, advantage of the present invention is as follows:

本发明的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统及其显示方法,该显示系统采用基于三元正交激发发射体系的三维显示固体介质作为显示器,同一纳米材料中的三个发光过程是相互独立的,互不干扰的;可以获得具有高亮度和高色纯度的全色上转换发光,从而产生纳米级分辨率的动态真三维彩色立体显示图像及视频,具有显示效果逼真、显示信息量大、显示成像分辨率高等特点。涉及的显示方法是基于人眼视觉暂留效应的动态显示,具有耗用硬件资源少、软件控制方便、价格低廉等特点。A true three-dimensional stereoscopic color display system and display method based on full-color up-conversion luminescent nanodisplays of the present invention, the display system uses a three-dimensional display solid medium based on a ternary orthogonal excitation-emission system as a display, and the same nanomaterials The three luminous processes are independent of each other and do not interfere with each other; full-color up-conversion luminescence with high brightness and high color purity can be obtained, thereby generating dynamic true three-dimensional color stereoscopic images and videos with nanoscale resolution, with display effects Realistic, large amount of display information, high resolution of display imaging, etc. The related display method is a dynamic display based on the persistence effect of human eyes, and has the characteristics of consuming less hardware resources, convenient software control, low price and the like.

附图说明Description of drawings

为了更清楚地说明本发明具体实施方式或现有技术中的技术方案,下面将对具体实施方式或现有技术描述中所需要使用的附图作简单地介绍。在所有附图中,类似的元件或部分一般由类似的附图标记标识。附图中,各元件或部分并不一定按照实际的比例绘制。In order to more clearly illustrate the specific embodiments of the present invention or the technical solutions in the prior art, the following briefly introduces the accompanying drawings that are required in the description of the specific embodiments or the prior art. Throughout the drawings, similar elements or parts are generally identified by similar reference numerals. In the drawings, elements or parts are not necessarily drawn in actual scale.

图1:本发明实施例2制备的三元正交激发发射体系的透射电子显微镜(TEM)照片;Fig. 1: the transmission electron microscope (TEM) photograph of the ternary orthogonal excitation emission system prepared in Example 2 of the present invention;

图2:本发明实施例2制备的三元正交激发发射体系在三种不同波长近红外光(1560/980/808nm)进行合束激发下的发光照片;Fig. 2: The luminescent photo of the ternary orthogonal excitation-emission system prepared in Example 2 of the present invention under the beam-combined excitation of three different wavelengths of near-infrared light (1560/980/808nm);

图3:本发明实施例2制备的基于三元正交激发发射体系的全色上转换发光纳米显示器实物图;Figure 3: The physical picture of the full-color up-conversion luminescence nanodisplay based on the ternary orthogonal excitation emission system prepared in Example 2 of the present invention;

图4:本发明实施例1的基于全色上转换发光纳米显示器的真三维立体彩色显示系统的结构示意图;Figure 4: Schematic diagram of the structure of a true three-dimensional color display system based on a full-color up-conversion light-emitting nanodisplay according to Embodiment 1 of the present invention;

图5:本发明实施例1的基于全色上转换发光纳米显示器的真三维立体彩色显示系统实物图;Fig. 5: The actual figure of the real three-dimensional color display system based on full-color up-conversion light-emitting nano-display according to Embodiment 1 of the present invention;

图6:本发明实施例2的基于全色上转换发光纳米显示器的真三维立体彩色显示系统产生的彩色真三维立体显示图像。Fig. 6: A color true three-dimensional stereoscopic display image generated by the true three-dimensional stereoscopic color display system based on the full-color up-conversion light-emitting nanodisplay according to Embodiment 2 of the present invention.

具体实施方式detailed description

为清楚、完整地描述本发明所述技术方案及其具体工作过程,结合说明书附图,本发明的具体实施方式如下:In order to clearly and completely describe the technical solution of the present invention and its specific working process, in conjunction with the accompanying drawings, the specific implementation of the present invention is as follows:

实施例1Example 1

如图5所示,本实施例提供了一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,包括全色上转换发光纳米显示器、光学透镜组、980nm激光器、808nm激光器、1560nm激光器以及激光扫描仪,所述光学透镜组具体包括980nm、808nm和1560nm三组激光准直透镜、焦距为25mm的凸透镜、焦距为10cm的长焦透镜、980/808nm二向色镜、980/808/1560nm二向色镜。该显示系统通过3D建模软件输出立体图像数据;利用激光扫描仪主控制器接收信号;通过将980nm、808nm或1560nm中任意波长的两束/三束激光汇聚在全色上转换发光纳米显示器的定点位置处产生全色上转换发光;通过激光扫描仪程序化控制激光汇聚点在显示器中进行三维空间快速寻址扫描,利用人眼视觉的暂留效应,就可以获得纳米级分辨率的动态三维立体显示图像。As shown in Figure 5, this embodiment provides a true three-dimensional color display system based on a full-color up-conversion luminescent nano-display, including a full-color up-conversion luminescent nano-display, an optical lens group, a 980nm laser, an 808nm laser, and a 1560nm laser. And a laser scanner, the optical lens group specifically includes three groups of laser collimating lenses of 980nm, 808nm and 1560nm, a convex lens with a focal length of 25mm, a telephoto lens with a focal length of 10cm, a 980/808nm dichroic mirror, a 980/808/ 1560nm dichroic mirror. The display system outputs stereoscopic image data through 3D modeling software; uses the laser scanner main controller to receive signals; gathers two or three laser beams of any wavelength in 980nm, 808nm or 1560nm on the full-color up-conversion luminescent nanometer display Full-color up-conversion luminescence is generated at the fixed-point position; the laser scanner is programmed to control the laser convergence point to perform fast addressing and scanning in three-dimensional space in the display, and the dynamic three-dimensional with nanometer resolution can be obtained by using the persistence effect of human vision. Display images in stereo.

在本实施例中,所述全色上转换发光纳米显示器是由三元正交激发发射体系作为发光介质、高分子材料作为三维显示固体介质、通过掺杂或共聚的方法制备出的具有高透明度的基于纳米晶/高分子复合材料的全色上转换发光纳米显示器;其中,所述高分子材料为环氧树脂、聚甲基丙烯酸甲酯或聚二甲基硅氧烷。In this embodiment, the full-color up-conversion luminescent nanodisplay is prepared by a ternary orthogonal excitation emission system as a luminescent medium, a polymer material as a three-dimensional display solid medium, and has high transparency by doping or copolymerization. A full-color up-conversion luminescence nanodisplay based on nanocrystal/polymer composite material; wherein, the polymer material is epoxy resin, polymethyl methacrylate or polydimethylsiloxane.

本实施例的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统的工作原理如下:The working principle of a true three-dimensional stereoscopic color display system based on a full-color up-conversion light-emitting nano-display in this embodiment is as follows:

该显示系统将980nm、808nm或1560nm中任意波长的两束激光汇聚在全色上转换发光纳米显示器的三维空间的定点处,由于正交三基色发光纳米晶分布在显示器的三维空间区域中,通过有选择的激发定点位置,就可以在显示器内部产生上转换发光;处在定点发光位置的纳米晶相当于一个纳米体像素点,通过程序化控制激光汇聚点在显示器中进行立体图像的快速三维寻址扫描,利用人眼视觉的暂留效应,就可以获得由无数个纳米体像素点组成的动态的三维立体显示图像。The display system converges two laser beams with any wavelength in 980nm, 808nm or 1560nm at a fixed point in the three-dimensional space of the full-color up-conversion luminescent nano-display. By selectively exciting the fixed-point position, up-conversion luminescence can be generated inside the display; the nanocrystal at the fixed-point light-emitting position is equivalent to a nanobody pixel, and the rapid three-dimensional image search of the stereoscopic image can be performed in the display by programmatically controlling the laser convergence point. Site scanning, using the persistence effect of human vision, can obtain a dynamic three-dimensional display image composed of countless nano-body pixels.

实施例2Example 2

本实施例提供了全色上转换发光纳米显示器的制备方法,具体包括如下步骤:This embodiment provides a method for preparing a full-color up-conversion luminescent nanodisplay, which specifically includes the following steps:

步骤一:三元正交激发发射体系的制备:Step 1: Preparation of ternary orthogonal excitation emission system:

(1)蓝光发射核NaYF4:Yb/Tm纳米晶的制备:按预定比例将总摩尔量为0.4mmol的稀土盐YCl3·6H2O(0.2mmol)、YbCl3·6H2O(0.196mmol)以及TmCl3·6H2O(0.004mmol)加入到3mL油酸和7mL十八烯的混合溶剂中,加热到150℃反应90分钟得到Y-Yb-Tm-OA油酸配合物,待冷却至室温后,加入氟源和钠源分别为1.6mmol NH4F和1.0mmol NaOH的甲醇溶液,待甲醇挥发后,在惰性气体保护下加热到290℃反应90分钟得到核纳米晶;(1) Preparation of blue light-emitting nucleus NaYF 4 :Yb/Tm nanocrystals: Rare earth salt YCl 3 6H 2 O (0.2mmol), YbCl 3 6H 2 O (0.196mmol ) and TmCl 3 ·6H 2 O (0.004mmol) were added to a mixed solvent of 3mL oleic acid and 7mL octadecene, and heated to 150°C for 90 minutes to obtain the Y-Yb-Tm-OA oleic acid complex, which was cooled to After room temperature, add a methanol solution of 1.6mmol NH 4 F and 1.0mmol NaOH as the fluorine source and sodium source respectively, and after the methanol volatilizes, heat to 290°C under the protection of an inert gas and react for 90 minutes to obtain nuclear nanocrystals;

(2)壳层前驱体的制备:将包裹壳层所需的稀土盐按照预定比例加入到3mL油酸和7mL十八烯的混合溶剂中,加热到150℃反应60分钟就可以分别得到第一壳层、第二壳层、第三壳层、第四壳层和第五壳层所需的Y-OA、Y-Er-Ho、Y-OA、Nd-Yb-Er-OA、Y-Nd-OA油酸配合物;(2) Preparation of the shell precursor: Add the rare earth salt required to wrap the shell into a mixed solvent of 3 mL oleic acid and 7 mL octadecene according to a predetermined ratio, and heat to 150 ° C for 60 minutes to obtain the first Y-OA, Y-Er-Ho, Y-OA, Nd-Yb-Er-OA, Y-Nd required for shell, second shell, third shell, fourth shell and fifth shell -OA oleic acid complex;

(3)NaYF4:Yb/Tm@NaYF4核壳结构纳米晶的制备:将已制备的NaYF4:Yb/Tm核纳米晶作为晶种加入到壳层前驱体Y-OA油酸配合物溶液中,然后加入氟源和钠源分别为1.6mmolNH4F和1.0mmol NaOH的甲醇溶液,待甲醇挥发后,在惰性气体保护下加热到290℃反应90分钟得到核壳结构纳米晶;(3) Preparation of NaYF 4 :Yb/Tm@NaYF 4 core-shell structure nanocrystals: the prepared NaYF 4 :Yb/Tm core nanocrystals were added as seed crystals to the shell precursor Y-OA oleic acid complex solution , then add a methanol solution in which the fluorine source and the sodium source are 1.6 mmol NH 4 F and 1.0 mmol NaOH respectively, and after the methanol volatilizes, it is heated to 290°C under the protection of an inert gas and reacted for 90 minutes to obtain nanocrystals with a core-shell structure;

(4)多层核壳结构纳米晶的制备:制备双壳层、三壳层、四壳层以及五壳层包覆的核壳结构纳米晶的方法与上述制备核壳结构纳米晶的制备方法相同。只需将前一步制备的纳米晶作为晶种,加入到预形成壳层的前驱体Y-Er-Ho、Y-OA、Nd-Yb-Er-OA或Y-Nd-OA油酸配合物溶液中,然后加入氟源和钠源分别为1.6mmol NH4F和1.0mmol NaOH的甲醇溶液,待甲醇挥发后,在惰性气体保护下加热到290℃反应90分钟就可以得到相应双层、三层、四层以及五层包覆的多层核壳结构纳米晶。(4) Preparation of multilayer core-shell structure nanocrystals: methods for preparing double-shell, three-shell, four-shell and five-shell-coated core-shell structure nanocrystals and the above-mentioned preparation method for core-shell structure nanocrystals same. Just use the nanocrystals prepared in the previous step as seeds and add them to the precursor Y-Er-Ho, Y-OA, Nd-Yb-Er-OA or Y-Nd-OA oleic acid complex solution , then add a methanol solution of 1.6mmol NH 4 F and 1.0mmol NaOH as a fluorine source and a sodium source respectively, and after the methanol volatilizes, heat it to 290°C under the protection of an inert gas and react for 90 minutes to obtain the corresponding double-layer and triple-layer , four-layer and five-layer coated multilayer core-shell structure nanocrystals.

步骤二:通过掺杂或共聚的方法制备全色上转换发光纳米显示器:Step 2: Prepare full-color up-conversion luminescent nanodisplays by doping or copolymerization:

(1)掺杂法:将40mg/mL的三元正交激发发射体系与环己烷溶液按照体积比1:10加入到环氧树脂中,在室温条件下搅拌20分钟,然后依次加入体积分数为2%的有机硅消泡剂和体积分数为10%聚酰胺固化剂,将得到的分散液超声震荡30min使其分散均匀,随后通过注射器注入到透明硅胶模具中,待分散液完全固化,即得到全色上转换发光纳米显示器;(1) Doping method: Add 40mg/mL ternary orthogonal excitation emission system and cyclohexane solution into epoxy resin at a volume ratio of 1:10, stir at room temperature for 20 minutes, and then add the volume fraction 2% silicone defoamer and 10% polyamide curing agent by volume fraction, ultrasonically vibrate the obtained dispersion for 30 minutes to disperse evenly, then inject it into a transparent silicone mold through a syringe, and wait until the dispersion is completely cured, that is Obtain a full-color up-conversion luminescent nano-display;

(2)共聚法:将0.02g引发剂偶氮二异丁腈和9g单体甲基丙烯酸甲酯加入到4mL乙酸乙酯中,随后加热到60℃保持70分钟,待低温预聚反应完成后,加入1mL含20mg三元正交激发发射体系的乙酸乙酯溶液,然后将升温到82℃进行高温聚合,待反应液呈透明粘稠状,停止反应并将其转移到玻璃模具中,最后在真空干燥箱中加热到120℃保持24小时完成高温固化,反应结束后即得到全色上转换发光纳米显示器。(2) Copolymerization method: add 0.02g initiator azobisisobutyronitrile and 9g monomer methyl methacrylate into 4mL ethyl acetate, then heat to 60°C for 70 minutes, after the low temperature prepolymerization reaction is completed , add 1mL ethyl acetate solution containing 20mg ternary orthogonal excitation emission system, then raise the temperature to 82°C for high temperature polymerization, wait until the reaction liquid is transparent and viscous, stop the reaction and transfer it to a glass mold, and finally in Heating to 120° C. in a vacuum drying oven for 24 hours to complete high-temperature curing, and a full-color up-conversion luminescent nanometer display can be obtained after the reaction is completed.

实施例3Example 3

本实施例提供了一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统的显示方法,利用光学透镜和二向色镜对三束不同波长的近红外光(1560/980/808nm)进行合束调制,通过调节三束近红外激发光的激发功率,在基于三元正交激发发射体系的“全色上转换发光纳米显示器”三维空间区域的汇聚点处,可以产生基于三基色原理的全色上转换发光。发光点相当于纳米尺度的体像素点,通过激光扫描仪进行立体图像的快速三维寻址扫描,就可以获得纳米级分辨率的彩色真三维立体显示图像及视频。This embodiment provides a display method for a true three-dimensional color display system based on a full-color up-conversion luminescent nanodisplay, using an optical lens and a dichroic mirror to detect three beams of near-infrared light (1560/980/808nm) with different wavelengths. Combined beam modulation, by adjusting the excitation power of the three near-infrared excitation lights, at the converging point of the three-dimensional space area of the "full-color up-conversion luminescent nanodisplay" based on the three-element orthogonal excitation-emission system, the three-primary color principle can be generated. full-color up-conversion luminescence. The luminescent point is equivalent to the nanoscale volume pixel point, and the fast three-dimensional addressing scanning of the stereoscopic image by the laser scanner can obtain the color true three-dimensional display image and video with nanoscale resolution.

所述显示方法具体包括如下步骤:The display method specifically includes the following steps:

通过调节1560/980/808nm三束近红外激发光的激发功率,在图1制备的三元正交激发发射体系中可以产生全色上转换发光,如图2所示;By adjusting the excitation power of the three beams of near-infrared excitation light at 1560/980/808nm, full-color upconversion luminescence can be produced in the ternary orthogonal excitation emission system prepared in Figure 1, as shown in Figure 2;

具体地,通过调控三束激光激发功率,可以实现蓝、青、黄、红、粉、白、绿(从左往右)全色上转换发光的调控;具体地调控方案如下:Specifically, by adjusting the excitation power of the three laser beams, the adjustment of full-color up-conversion luminescence of blue, cyan, yellow, red, pink, white, and green (from left to right) can be realized; the specific adjustment scheme is as follows:

当808nm激光器的激发功率为0.0W,980nm激光器的激发功率为0.5W,1560nm激光器的电流为0.0A,产生蓝色上转换发光;When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.5W, and the current of the 1560nm laser is 0.0A, blue up-conversion luminescence is produced;

当808nm激光器的激发功率为0.8W,980nm激光器的激发功率为1.1W,1560nm激光器的电流为0.0A,产生青色上转换发光;When the excitation power of the 808nm laser is 0.8W, the excitation power of the 980nm laser is 1.1W, and the current of the 1560nm laser is 0.0A, cyan upconversion light is produced;

当808nm激光器激的发功率为1.5W,980nm激光器的激发功率为0.0W,1560nm激光器的电流为1.8A,产生黄色上转换发光;When the excitation power of the 808nm laser is 1.5W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 1.8A, yellow up-conversion luminescence is produced;

当808nm激光器激的发功率为0.0W,980nm激光器激的发功率为0.0W,1560nm激光器的电流为1.6A,产生红色上转换发光;When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 1.6A, red up-conversion luminescence is produced;

当808nm激光器激的发功率为0.0W,980nm激光器的激发功率为0.5W,1560nm激光器的电流为2.0A,产生粉色上转换发光;When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.5W, and the current of the 1560nm laser is 2.0A, pink up-conversion luminescence is produced;

当808nm激光器的激发功率为1.1W,980nm激光器的激发功率为2.5W,1560nm激光器的电流为1.2A,产生白色上转换发光;When the excitation power of the 808nm laser is 1.1W, the excitation power of the 980nm laser is 2.5W, and the current of the 1560nm laser is 1.2A, white up-conversion luminescence is produced;

当808nm激光器的激发功率为1.0W,980nm激光器的激发功率为0.0W,1560nm激光器的电流为0.0A,产生绿色上转换发光。When the excitation power of the 808nm laser is 1.0W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 0.0A, green up-conversion luminescence is generated.

将图1制备的三元正交激发发射体系通过掺杂或共聚的方法分散到透明的三维显示固体介质(环氧树脂、聚甲基丙烯酸甲酯或聚二甲基硅氧烷)中,得到全色上转换发光纳米显示器,如图3所示;The ternary orthogonal excitation emission system prepared in Fig. 1 is dispersed into a transparent three-dimensional display solid medium (epoxy resin, polymethyl methacrylate or polydimethylsiloxane) by doping or copolymerization to obtain A full-color up-conversion luminescent nanodisplay, as shown in Figure 3;

通过搭建真三维立体彩色显示系统,如图4和5所示,利用3D建模软件输出立体图像数据,通过准直透镜、凸透镜、长焦透镜和二向色镜对三束不同波长的近红外光(1560/980/808nm)进行合束调制,并汇聚在全色上转换发光纳米显示器的定点位置,利用激光扫描仪主控制器接收数据信号并通过程序化控制激光汇聚点在显示器中进行X轴、Y轴、Z轴三个方向快速寻址扫描,利用人眼视觉的暂留效应,就可以获得纳米级分辨率的动态三维立体显示图像,如图6所示。By building a true three-dimensional stereoscopic color display system, as shown in Figures 4 and 5, 3D modeling software is used to output stereoscopic image data, and three near-infrared beams of different wavelengths are analyzed by a collimator lens, a convex lens, a telephoto lens, and a dichroic mirror. The light (1560/980/808nm) is beam-combined and modulated, and converged at the fixed-point position of the full-color up-conversion luminescent nano-display, and the main controller of the laser scanner is used to receive the data signal and control the laser convergence point in the display for X X-axis, Y-axis, and Z-axis fast addressing scanning, using the persistence effect of human vision, can obtain a dynamic three-dimensional display image with nanometer resolution, as shown in Figure 6.

以上结合附图详细描述了本发明的优选实施方式,但是,本发明并不限于上述实施方式中的具体细节,在本发明的技术构思范围内,可以对本发明的技术方案进行多种简单变型,这些简单变型均属于本发明的保护范围。The preferred embodiment of the present invention has been described in detail above in conjunction with the accompanying drawings, but the present invention is not limited to the specific details of the above embodiment, within the scope of the technical concept of the present invention, various simple modifications can be made to the technical solution of the present invention, These simple modifications all belong to the protection scope of the present invention.

另外需要说明的是,在上述具体实施方式中所描述的各个具体技术特征,在不矛盾的情况下,可以通过任何合适的方式进行组合,为了避免不必要的重复,本发明对各种可能的组合方式不再另行说明。In addition, it should be noted that the various specific technical features described in the above specific embodiments can be combined in any suitable way if there is no contradiction. The combination method will not be described separately.

此外,本发明的各种不同的实施方式之间也可以进行任意组合,只要其不违背本发明的思想,其同样应当视为本发明所公开的内容。In addition, various combinations of different embodiments of the present invention can also be combined arbitrarily, as long as they do not violate the idea of the present invention, they should also be regarded as the disclosed content of the present invention.

Claims (10)

1.一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,其特征在于,包括全色上转换发光纳米显示器、光学透镜组、三个不同波长的激光器及激光扫描仪;所述光学透镜组包括激光准直透镜、凸透镜、长焦透镜及两个二向色镜,所述三个不同波长的激光器发射的激光依次通过相应波长的激光准直透镜和凸透镜进行准直,准直后的其中两束激光沿45度入射角通过其中一个二向色镜进行合束,合束后的激光沿45度入射角通过另外一个二向色镜与第三束激光进行合束,经过合束后的三束激光通过长焦透镜汇聚在全色上转换发光纳米显示器的三维空间定点位置处;所述全色上转换发光纳米显示器固定在激光扫描仪上,所述激光扫描仪用于根据设定好的立体图像数据来控制激光汇聚点在全色上转换发光纳米显示器上的X轴、Y轴、Z轴三个方向的扫描,并利用人眼视觉的暂留效应,可获得由无数个纳米体像素点组成的动态的三维立体显示图像。1. A true three-dimensional stereoscopic color display system based on full-color up-conversion light-emitting nano-displays, characterized in that, comprising full-color up-conversion light-emitting nano-displays, optical lens groups, lasers and laser scanners of three different wavelengths; The optical lens group includes a laser collimator lens, a convex lens, a telephoto lens and two dichroic mirrors. The lasers emitted by the three different wavelength lasers are collimated sequentially through the laser collimator lens and the convex lens of the corresponding wavelength. The last two laser beams are combined through one of the dichroic mirrors at an incident angle of 45 degrees, and the combined laser beams are combined with the third laser beam through another dichroic mirror at an incident angle of 45 degrees. The three beams of laser light after the beam are converged at the fixed-point position in the three-dimensional space of the full-color up-conversion luminescent nano-display through the telephoto lens; the full-color up-conversion luminescent nano-display is fixed on the laser scanner, and the laser scanner is used to The set stereoscopic image data is used to control the scanning of the laser convergence point in the three directions of X-axis, Y-axis, and Z-axis on the full-color up-conversion luminescent nano-display, and by using the persistence effect of human vision, countless A dynamic three-dimensional display image composed of nanobody pixels. 2.如权利要求1所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,其特征在于,所述凸透镜的焦距为25mm,所述长焦透镜的焦距为10cm,所述二向色镜为980/808nm二向色镜或980/808/1560nm二向色镜。2. a kind of true three-dimensional stereoscopic color display system based on full-color up-conversion light-emitting nano-display as claimed in claim 1, is characterized in that, the focal length of described convex lens is 25mm, and the focal length of described telephoto lens is 10cm, so The dichroic mirror is a 980/808nm dichroic mirror or a 980/808/1560nm dichroic mirror. 3.如权利要求1所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,其特征在于,所述三个不同波长的激光器分别为980nm激光器、808nm激光器及1560nm激光器。3. A true three-dimensional color display system based on full-color up-conversion luminescent nanodisplays as claimed in claim 1, wherein the three lasers with different wavelengths are 980nm lasers, 808nm lasers and 1560nm lasers respectively. 4.如权利要求1所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,其特征在于,所述全色上转换发光纳米显示器是由三元正交激发发射体系作为发光介质、高分子材料作为三维显示固体介质、通过掺杂或共聚的方法制备出的具有高透明度的基于纳米晶/高分子复合材料的全色上转换发光纳米显示器。4. A kind of true three-dimensional stereoscopic color display system based on full-color up-conversion luminescence nano-display as claimed in claim 1, it is characterized in that, described full-color up-conversion luminescence nano-display is made of ternary orthogonal excitation emission system as Luminescent medium, polymer material as a three-dimensional display solid medium, a full-color up-conversion luminescent nano-display based on nanocrystal/polymer composite material with high transparency prepared by doping or copolymerization. 5.如权利要求1所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,其特征在于,所述高分子材料为环氧树脂、聚甲基丙烯酸甲酯或聚二甲基硅氧烷。5. A kind of true three-dimensional stereoscopic color display system based on full-color up-conversion luminescent nano-display as claimed in claim 1, it is characterized in that, described macromolecular material is epoxy resin, polymethyl methacrylate or polydimethacrylate Methylsiloxane. 6.如权利要求1所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,其特征在于,所述三元正交激发发射体系通过如下方法制备得到,所述方法具体包括如下步骤:6. A kind of true three-dimensional stereoscopic color display system based on full-color up-conversion luminescent nano-display as claimed in claim 1, it is characterized in that, described ternary orthogonal excitation emission system is prepared by following method, and described method is specific Including the following steps: 首先,通过热共沉淀法制备蓝光发射核NaYF4:Yb/Tm纳米晶,然后将制备好的核纳米晶作为晶种诱导外延NaYF4惰性壳层的生长,随后将制备好的NaYF4:Yb/Tm@NaYF4核壳结构纳米晶作为晶种诱导外延红光发射层NaYF4:Er/Ho的生长,同样将制备好的双层核壳结构纳米晶作为晶种诱导外延NaYF4惰性壳层的生长,接着将制备好的三层核壳结构纳米晶作为晶种诱导外延绿光发射层NaYF4:Nd/Yb/Er层的生长,最后将四层核壳结构纳米晶作为晶种诱导外延NaYF4:Nd层的生长;制备得到的基于五层核壳结构纳米晶的三元正交激发发射体系。First, the blue light-emitting core NaYF 4 :Yb/Tm nanocrystals were prepared by thermal co-precipitation method, and then the prepared core nanocrystals were used as seeds to induce the growth of the epitaxial NaYF 4 inert shell layer, and then the prepared NaYF 4 :Yb /Tm@NaYF 4 core-shell structure nanocrystals are used as seeds to induce the growth of the epitaxial red light emitting layer NaYF 4 :Er/Ho, and the prepared double-layer core-shell structure nanocrystals are also used as seeds to induce the epitaxy of the NaYF 4 inert shell layer The growth of the prepared three-layer core-shell structure nanocrystal is used as the seed crystal to induce the growth of the epitaxial green light-emitting layer NaYF 4 :Nd/Yb/Er layer, and finally the four-layer core-shell structure nanocrystal is used as the seed crystal to induce the epitaxy NaYF 4 : Growth of Nd layer; prepared ternary orthogonal excitation emission system based on five-layer core-shell nanocrystals. 7.如权利要求6所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,其特征在于,所述全色上转换发光纳米显示器通过如下方法制备得到,所述方法具体包括如下步骤:7. A kind of true three-dimensional stereoscopic color display system based on a full-color up-conversion luminescent nano-display as claimed in claim 6, wherein the full-color up-conversion luminescent nano-display is prepared by the following method, and the method is specifically Including the following steps: 将40mg/mL的三元正交激发发射体系与环己烷溶液按照体积比1:10加入到环氧树脂中,在室温条件下搅拌20分钟,然后依次加入体积分数为2%的有机硅消泡剂和体积分数为10%聚酰胺固化剂,将得到的分散液超声震荡30min使其分散均匀,随后通过注射器注入到透明硅胶模具中,待分散液完全固化,即得到全色上转换发光纳米显示器。Add 40 mg/mL ternary orthogonal excitation emission system and cyclohexane solution into the epoxy resin at a volume ratio of 1:10, stir at room temperature for 20 minutes, and then sequentially add 2% organosilicon dispersant Foam agent and polyamide curing agent with a volume fraction of 10%, ultrasonically vibrate the obtained dispersion for 30 minutes to disperse evenly, and then inject it into a transparent silicone mold through a syringe, and wait until the dispersion is completely cured to obtain a full-color up-conversion luminescent nanometer monitor. 8.如权利要求6所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统,其特征在于,所述全色上转换发光纳米显示器通过如下方法制备得到,所述方法具体包括如下步骤:8. A true three-dimensional color display system based on a full-color up-conversion luminescent nanodisplay as claimed in claim 6, wherein the full-color up-conversion luminescent nanodisplay is prepared by the following method, and the method is specifically Including the following steps: 将0.02g引发剂偶氮二异丁腈和9g单体甲基丙烯酸甲酯加入到4mL乙酸乙酯中,随后加热到60℃保持70分钟,待低温预聚反应完成后,加入1mL含20mg三元正交激发发射体系的乙酸乙酯溶液,然后将升温到82℃进行高温聚合,待反应液呈透明粘稠状,停止反应并将其转移到玻璃模具中,最后在真空干燥箱中加热到120℃保持24小时完成高温固化,反应结束后即得到全色上转换发光纳米显示器。Add 0.02g initiator azobisisobutyronitrile and 9g monomer methyl methacrylate into 4mL ethyl acetate, then heat to 60°C for 70 minutes, after the low temperature prepolymerization reaction is completed, add 1mL containing 20mg Ethyl acetate solution of the element orthogonal excitation emission system, and then heated up to 82°C for high-temperature polymerization. After the reaction liquid was transparent and viscous, stop the reaction and transfer it to a glass mold, and finally heated it in a vacuum drying oven to Keep at 120°C for 24 hours to complete the high-temperature curing, and a full-color up-conversion luminescent nanometer display can be obtained after the reaction is completed. 9.如权利要求1所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统的显示方法,其特征在于,具体包括如下步骤:9. The display method of a true three-dimensional color display system based on full-color up-conversion light-emitting nano-displays as claimed in claim 1, characterized in that, specifically comprising the following steps: 步骤一:通过波长为980nm、808nm及1560nm的激光器发射激光,所述激光依次通过其相应波长的激光准直透镜和凸透镜进行准直,准直后的980nm和808nm激光沿45度入射角首先通过980/808nm二向色镜进行合束,合束后的980/808nm激光沿45度入射角再通过980/808/1560nm二向色镜与1560nm激光进行合束,经过合束后的三束激光最后通过长焦透镜汇聚在全色上转换发光纳米显示器的三维空间的定点处,通过调控三束激光激发功率及电流,可在显示器内部产生蓝、青、黄、红、粉、白、绿全色上转换发光;Step 1: emit laser light through lasers with wavelengths of 980nm, 808nm and 1560nm, and the laser light is collimated through the laser collimating lens and convex lens of the corresponding wavelength in turn, and the collimated 980nm and 808nm lasers first pass through the 980/808nm dichroic mirrors combine beams, and the combined 980/808nm laser beams are combined with 1560nm laser beams through 980/808/1560nm dichroic mirrors along an incident angle of 45 degrees. After beam combining, the three laser beams Finally, the telephoto lens converges at the fixed point in the three-dimensional space of the full-color up-conversion light-emitting nano-display. color conversion luminescence; 步骤二:通过3D建模软件输出立体图像数据,利用激光扫描仪的主控制器接收信号,通过激光扫描仪控制激光汇聚点的方法,在显示器中进行X轴、Y轴、Z轴三个方向的寻址扫描,利用人眼视觉的暂留效应,可获得由无数个纳米体像素点组成的三维立体图像的显示。Step 2: Output the stereoscopic image data through the 3D modeling software, use the main controller of the laser scanner to receive the signal, and control the laser convergence point through the laser scanner, and carry out the three directions of the X-axis, Y-axis, and Z-axis on the display. The addressing scan, using the persistence effect of human vision, can obtain the display of a three-dimensional image composed of countless nano-body pixels. 10.如权利要求9所述的一种基于全色上转换发光纳米显示器的真三维立体彩色显示系统的显示方法,其特征在于,三束激光激发功率及电流的调控具体如下:10. A display method of a true three-dimensional color display system based on a full-color up-conversion light-emitting nanodisplay as claimed in claim 9, wherein the regulation of the three-beam laser excitation power and current is as follows: A、当808nm激光器的激发功率为0.0W,980nm激光器的激发功率为0.5W,1560nm激光器的电流为0.0A时,产生蓝色上转换发光;A. When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.5W, and the current of the 1560nm laser is 0.0A, blue up-conversion luminescence is produced; B、当808nm激光器的激发功率为0.8W,980nm激光器的激发功率为1.1W,1560nm激光器的电流为0.0A时,产生青色上转换发光;B. When the excitation power of the 808nm laser is 0.8W, the excitation power of the 980nm laser is 1.1W, and the current of the 1560nm laser is 0.0A, cyan upconversion light is produced; C、当808nm激光器激的发功率为1.5W,980nm激光器的激发功率为0.0W,1560nm激光器的电流为1.8A时,产生黄色上转换发光;C. When the excitation power of the 808nm laser is 1.5W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 1.8A, yellow up-conversion luminescence is produced; D、当808nm激光器激的发功率为0.0W,980nm激光器激的发功率为0.0W,1560nm激光器的电流为1.6A时,产生红色上转换发光;D. When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 1.6A, red up-conversion luminescence is produced; E、当808nm激光器激的发功率为0.0W,980nm激光器的激发功率为0.5W,1560nm激光器的电流为2.0A时,产生粉色上转换发光;E. When the excitation power of the 808nm laser is 0.0W, the excitation power of the 980nm laser is 0.5W, and the current of the 1560nm laser is 2.0A, pink up-conversion luminescence is produced; F、当808nm激光器的激发功率为1.1W,980nm激光器的激发功率为2.5W,1560nm激光器的电流为1.2A时,产生白色上转换发光;F. When the excitation power of the 808nm laser is 1.1W, the excitation power of the 980nm laser is 2.5W, and the current of the 1560nm laser is 1.2A, white up-conversion luminescence is produced; G、当808nm激光器的激发功率为1.0W,980nm激光器的激发功率为0.0W,1560nm激光器的电流为0.0A时,产生绿色上转换发光。G. When the excitation power of the 808nm laser is 1.0W, the excitation power of the 980nm laser is 0.0W, and the current of the 1560nm laser is 0.0A, green up-conversion luminescence is produced.
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