CN115414292A - Eyebrow pencil composition and preparation method thereof - Google Patents
Eyebrow pencil composition and preparation method thereof Download PDFInfo
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- CN115414292A CN115414292A CN202211025412.1A CN202211025412A CN115414292A CN 115414292 A CN115414292 A CN 115414292A CN 202211025412 A CN202211025412 A CN 202211025412A CN 115414292 A CN115414292 A CN 115414292A
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- 210000004709 eyebrow Anatomy 0.000 title claims abstract description 175
- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000000049 pigment Substances 0.000 claims abstract description 64
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 238000002156 mixing Methods 0.000 claims abstract description 28
- 238000003756 stirring Methods 0.000 claims abstract description 27
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 13
- 239000003899 bactericide agent Substances 0.000 claims abstract description 13
- 239000003906 humectant Substances 0.000 claims abstract description 13
- 244000299461 Theobroma cacao Species 0.000 claims abstract description 12
- 235000009470 Theobroma cacao Nutrition 0.000 claims abstract description 12
- 239000011259 mixed solution Substances 0.000 claims abstract description 11
- 244000017020 Ipomoea batatas Species 0.000 claims abstract description 7
- 235000002678 Ipomoea batatas Nutrition 0.000 claims abstract description 7
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 claims abstract description 7
- 244000088415 Raphanus sativus Species 0.000 claims abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 40
- 229920001577 copolymer Polymers 0.000 claims description 35
- 150000002148 esters Chemical class 0.000 claims description 35
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 15
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 abstract description 31
- 238000009877 rendering Methods 0.000 abstract description 14
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- 238000011161 development Methods 0.000 description 15
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- 239000012530 fluid Substances 0.000 description 8
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- 238000004458 analytical method Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
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- 229920002126 Acrylic acid copolymer Polymers 0.000 description 4
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- 235000012745 brilliant blue FCF Nutrition 0.000 description 3
- 210000000744 eyelid Anatomy 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012935 Averaging Methods 0.000 description 2
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical group CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical group OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
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- 235000012730 carminic acid Nutrition 0.000 description 1
- DGQLVPJVXFOQEV-JNVSTXMASA-N carminic acid Chemical group OC1=C2C(=O)C=3C(C)=C(C(O)=O)C(O)=CC=3C(=O)C2=C(O)C(O)=C1[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O DGQLVPJVXFOQEV-JNVSTXMASA-N 0.000 description 1
- 239000004106 carminic acid Substances 0.000 description 1
- 229940080423 cochineal Drugs 0.000 description 1
- 229940110456 cocoa butter Drugs 0.000 description 1
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- 239000010903 husk Substances 0.000 description 1
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- 102000004169 proteins and genes Human genes 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/85—Polyesters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Cosmetics (AREA)
Abstract
The application relates to the technical field of cosmetics, in particular to an eyebrow pencil composition and a preparation method thereof. The eyebrow pencil composition comprises the following components in percentage by weight: 6-8% of humectant, 0.7-0.9% of bactericide, 3.5-4.5% of natural pigment, 28-32% of film forming agent and 57.2-59.2% of water; the natural pigment comprises cocoa pigment, sweet potato pigment or radish root pigment; the preparation method comprises the following steps: adding water into the mixed solution of the humectant and the bactericide, and stirring and mixing to obtain a mixture; adding natural pigment into the mixture, stirring, adding film-forming agent, and stirring to obtain eyebrow pencil composition. The eyebrow pencil composition has the advantages of being good in waterproofness, good in oil resistance, high in friction resistance, smooth in liquid discharge, good in color rendering, strong in makeup holding effect, good in makeup removing efficiency and free of foundation.
Description
Technical Field
The application relates to the technical field of cosmetics, in particular to an eyebrow pencil composition and a preparation method thereof.
Background
The eyebrow pencil belongs to a color cosmetic, can be used for outlining the eyebrow shape and making the eyebrow more additive. In the production process of the eyebrow pencil, the pigment is generally dispersed in low-melting-point grease, wax base and other raw materials, and then the pigment is filled in a corresponding eyebrow pencil packaging material to obtain the eyebrow pencil.
At present, in order to clean the skin and protect the health of the skin, people can carry out makeup removing treatment on facial makeup before sleep. However, people find that the eyebrow powder remained in the eyebrow can be cleaned only by repeatedly wiping the eyebrow with the makeup remover, so that the makeup remover has the problem of complicated makeup removal.
Therefore, there is a need for an eyebrow pencil that is easy to remove makeup.
Disclosure of Invention
In order to improve makeup removal efficiency, the application provides an eyebrow pencil composition and a preparation method thereof.
In a first aspect, the present application provides an eyebrow pencil composition, which adopts the following technical scheme:
the eyebrow pencil composition comprises the following components in percentage by weight:
6-8% of a humectant;
0.7 to 0.9 percent of bactericide;
3.5 to 4.5 percent of natural pigment;
28-32% of film forming agent;
57.2-59.2% of water;
the natural pigment comprises cocoa pigment, sweet potato pigment or radish root pigment.
Through adopting above-mentioned technical scheme, on the one hand, owing to adopt the chemical pigment in the above-mentioned natural pigment to replace the eyebrow pencil, remaining problem in the eyebrow after can fabulous reduction eyebrow pencil uses, and the eyebrow pencil does not leave the trace after removing makeup, has improved the efficiency of removing makeup to facial eyebrow pencil. On the other hand, by optimizing the weight ratio of the natural pigment and other components in the eyebrow pencil composition, the makeup removing efficiency of the eyebrow pencil on the face can be improved, the problem that the eyebrow pencil leaves a base is solved, the stability of the eyebrow pencil on light, heat and oxidizing agents and the adhesion force of protein and starch can be improved, the adhesion force of the eyebrow pencil on the skin surface layer can be improved, and the makeup removing effect of the eyebrow pencil can be reduced. Therefore, the eyebrow pencil composition has the advantages of high adhesive force, difficulty in smudging and removing makeup, long lasting makeup, convenience in makeup removal and cleaning, and no base left after makeup removal, and effectively improves the condition that eyebrow pencils are easy to remain when being removed due to high adhesive force in part of related technologies.
Meanwhile, the natural pigment has good settleability and stable color development, and is less influenced by other conditions such as pH value of the skin substrate. Therefore, the eyebrow pencil composition obtained by the application also has good stability and color rendering property. Moreover, the natural pigment is a pure natural pigment extracted from plants, has no peculiar smell and has high safety.
Preferably, the weight ratio of the natural pigment to the film forming agent in the eyebrow pencil composition is 1 (7.5-8.5).
By adopting the technical scheme, the ratio of the natural pigment to the film forming agent is further optimized, so that the adhesion of the eyebrow pencil composition can be further improved under the condition that the obtained eyebrow pencil composition has good makeup removing efficiency.
Preferably, the film forming agent includes any one of an acrylic copolymer and a polyurethane.
Through adopting above-mentioned technical scheme, above-mentioned kind of film-forming agent all has better compatibility with the natural pigment of this application, is favorable to improving adhesive force and the color development effect of this application eyebrow pencil composition.
Preferably, the film forming agent is an acrylic acid (ester) copolymer, the pH value of the acrylic acid (ester) copolymer is 7-8.5, the viscosity of the acrylic acid (ester) copolymer is 50-100mPa & s, and the particle size of the acrylic acid (ester) copolymer is 80-120nm.
Preferably, the acrylic copolymer is Carfil 9123 or CoVACRYL E14 PF.
By adopting the technical scheme, the acrylic acid (ester) copolymer with the specific physical property has better compatibility with the natural pigment, so that the adhesive force and the color development effect of the eyebrow pencil composition can be improved, and the stability, the water resistance and the oil resistance of the eyebrow pencil composition can be improved.
Preferably, the pH value of the polyurethane is 7-8.5, the viscosity is 10-200mPa.s, and the particle size is 80-120nm.
Preferably, the eyebrow pencil composition has the viscosity of 3-4cP at 25 ℃, the pH value of 7.10-7.50, the particle size of less than 150nm and the solid content of 23.7-25.7%.
By adopting the technical scheme, the eyebrow pencil composition has better stability, liquid discharge performance and fluency, and the makeup removing efficiency of the finally obtained eyebrow pencil is better.
In a second aspect, the present application provides a method for preparing an eyebrow pencil composition, which adopts the following technical scheme:
a preparation method of an eyebrow pencil composition comprises the following preparation steps:
s1, adding water into a mixed solution of a humectant and a bactericide, and stirring and mixing to obtain a mixture;
and S2, adding the natural pigment into the mixture, stirring and mixing, adding the film-forming agent, and stirring and mixing to obtain the eyebrow pencil composition.
By adopting the technical scheme, the liquid discharge performance and the fluency of the obtained eyebrow pencil composition can be improved by controlling the adding sequence of the raw materials, the stability of the eyebrow pencil composition is improved, and the makeup removing efficiency of the finally obtained eyebrow pencil is improved. Meanwhile, the eyebrow pencil composition has fewer preparation steps and a simple preparation method, and is suitable for large-scale production.
Preferably, the preparation method of the eyebrow pencil composition comprises the following specific steps:
s1, adding water into a mixed solution of a humectant and a bactericide at the temperature of 10-30 ℃, and stirring and mixing for 5-8min at the speed of 500-700r/min to obtain a mixture;
s2, adding the natural pigment into the mixture, stirring and mixing at 500-700r/min for 25-35min, controlling the temperature to be 10-30 ℃, adding the film-forming agent, and stirring and mixing at 500-700r/min for 15-25min to obtain the eyebrow pencil composition.
By adopting the technical scheme, in the specific preparation steps of the eyebrow pencil composition, the dispersion performance among the raw materials can be better improved by controlling the process conditions of the raw materials during addition, and the eyebrow pencil composition which has higher liquid discharge performance, smoothness, stability and adhesive force, better color rendering and easier makeup removal can be obtained.
In summary, the present application has the following beneficial effects:
1. according to the eyebrow pencil composition, the cocoa pigment, the sweet potato pigment or the radish root pigment are adopted to replace the chemical pigment under the specific weight ratio, so that the problem of residue in eyebrows after the eyebrow pencil is used is solved, the makeup removing efficiency of the eyebrow pencil on the face is improved, the adhesive force of the eyebrow pencil on the skin surface layer is improved, the eyebrow pencil composition with high adhesive force, good makeup holding effect, convenience in makeup removing and cleaning and no base left after makeup removing is obtained;
2. in the application, an acrylic acid (ester) copolymer is preferably used as a film forming agent, and the film forming agent has good compatibility with natural pigments, so that the stability, color rendering property, water resistance and oil resistance of the finally obtained eyebrow pencil composition are improved;
3. according to the method, the adding sequence of the raw materials and the process conditions during adding are controlled, so that the dispersing performance of the raw materials can be improved, the raw materials can play a role, and the eyebrow pencil composition which is smooth in liquid outlet, higher in stability and adhesion, better in color rendering property and free of makeup removal is obtained.
Detailed Description
The present application will be described in further detail with reference to examples.
Performance detection
The water resistance, oil resistance, rubbing resistance, halation degree, liquid outflow fluency, color rendering and makeup removal detection are carried out on the eyebrow pencils obtained in the examples and the comparative examples, and the detection method comprises the following steps:
and (3) detecting the waterproofness: the eyebrow pencil obtained by the embodiment and the comparative example is adopted to draw two lines with the same thickness and adjacent positions on the skin, after 30s, the eyebrow pencil drips the two lines, then hands are pointed to the same side of the two lines to rub for 3 times, the phenomenon that the two lines rub off on the skin is observed, the skin is scored according to 1-5 minutes, 1 minute represents complete rub-off, and 5 minutes represents no rub-off.
And (3) oil resistance detection: the eyebrow pencil obtained in the embodiment and the comparative example is adopted, two lines with the same thickness and adjacent positions are drawn on the skin, after 30s, oil is dripped on the two lines, then the two lines are rubbed for 3 times by pointing to the same side of the two lines with hands, the rubbing-off phenomenon of the two lines on the skin is observed, the two lines are scored according to 1-5 minutes, 1 minute represents complete rubbing-off, and 5 minutes represents no rubbing-off.
And (3) detecting the friction resistance: the eyebrow pencil obtained in the embodiment and the comparative example is adopted to draw two lines with the same thickness and adjacent positions on the skin, and after 30s, the eyebrow pencil is rubbed 3 times by pointing to the same side of the two lines with hands, the phenomenon of rubbing off of the two lines on the skin is observed, the eyebrow pencil is scored according to 1-5 points, wherein 1 point represents complete rubbing off, and 5 points represent no rubbing off.
Detecting halation degree, liquid outflow fluency and color rendering property: selecting female volunteers aged 18-35 years and having the same skin, drawing eyeliners on eyelids of left eyes of the volunteers by using the water eyebrow pencil obtained in the embodiment, drawing eyeliners on eyelids of right eyes of the same volunteers by using the water eyebrow pencil obtained in the comparative example, controlling the eyeliners at the two eyeliners to be the same in thickness, observing the color development depth of the eyeliners, grading according to 1-5 points, wherein 1 point represents no color development, 5 points represent color development depth, and averaging the grading results.
And (3) allowing the volunteers to be in the same environment, observing the halation condition of the eye line at the eyelid of the volunteers at 8h, scoring according to 1-5 points, wherein 5 points represent no halation phenomenon, and averaging the scoring results. Meanwhile, when drawing eye lines, scoring the liquid discharge fluency of the water eyebrow pencil according to 1-5 points, wherein 1 point represents that liquid discharge is not smooth, 5 points represents that liquid discharge is smooth, and the scoring result is averaged.
And (3) makeup removal detection: the two lines with the same thickness and adjacent positions are drawn on the skin by using the eyebrow pencil obtained in the embodiment and the comparative example, after 30s, the makeup removing cotton containing the makeup removing water is used, the same sides of the two lines are wiped for 1 time, the foundation remaining condition of the two lines on the skin is observed and scored according to 1-5 points, wherein 1 point represents that the foundation remaining condition is serious, and 5 points represent that the foundation does not exist.
Examples
Example 1
A fountain eyebrow pencil comprises a fountain eyebrow pencil packaging material and an eyebrow pencil composition filled in the fountain eyebrow pencil packaging material.
The eyebrow pencil composition comprises the following components in parts by weight,
and is prepared by the following preparation steps:
s1, mixing the humectant and the bactericide at 10-30 ℃, and stirring and mixing at 600r/min for 5min to obtain a mixed solution; adding water into the mixed solution at 10-30 ℃, stirring and mixing at 600r/min for 5min to obtain a mixture;
s2, adding the natural pigment into the mixture, stirring and mixing at 600r/min for 30min, controlling the temperature to be 10-30 ℃, adding the film-forming agent, and stirring and mixing at 600r/min for 20min to obtain the eyebrow pencil composition.
In an embodiment of the present application, the humectant is butylene glycol.
The bactericide is phenoxyethanol.
The natural pigment is Cocoa pigment, cocoa Husk, available from Sendzein pigment technology (China).
In the embodiment of the application, as the natural pigment adopts cocoa pigment, sweet potato pigment or radish root pigment, the influence on the finally obtained eyebrow pencil is only different in obvious color, and other properties are the same. Therefore, the examples of the present application only take the natural pigment as cocoa pigment for a brief description, but do not affect the application of sweet potato pigment or radish root pigment in the present application.
The film forming agent is acrylic acid (ester) copolymer Carfil 9123, the pH value of the acrylic acid (ester) copolymer Carfil 9123 is 7-8.5, the viscosity is 50-100mPa & s, and the particle size is 80-120nm.
In the embodiment of the application, as the film forming agents are acrylic acid (ester) copolymer Carfil 9123 and acrylic acid (ester) copolymer COVACRYL E14 PF, the performance detection results of the obtained eyebrow pencil are nearly the same. Therefore, in the examples of the present application, only the film forming agent of the acrylic acid (ester) copolymer Carfil 9123 is taken as an example for brief description, but the application of the acrylic acid (ester) copolymer COVACRYL E14 PF in the present application is not affected.
The eyebrow pencil composition has the viscosity of 3.5cP at 25 ℃, the pH value of 7.10-7.50, the particle size of 120nm and the solid content of 24.7 percent through detection.
The above-mentioned paper-covered eyebrow pencil is T-AEL-128A4-19, and is purchased from Ningbo Jie cosmetics packaging Co.
The preparation method of the ink eyebrow pencil comprises the following steps: filling the eyebrow pencil composition into the cavity of the eyebrow pencil packaging material to obtain the eyebrow pencil.
Examples 2 to 5
An eyebrow pencil is different from example 1 in that the components and their weights in the composition are shown in the following table.
The water resistance, oil resistance, rubbing resistance, halation degree, fluid outflow fluency, color development and makeup removal tests were performed on the pencils obtained in examples 1-5, wherein 25 female volunteers were selected and randomly divided into 5 groups of 5 persons during the detection of halation degree, fluid outflow fluency and color development. The 5 groups were scored using one of the eyebrow pencils of examples 1-5, and the scores were averaged, and the results were shown in the following table.
From the analysis of the performance data in the table above, it can be seen that the water eyebrow pencil obtained in examples 1 to 5 of the present application has a water resistance of 4.0 to 4.8 minutes, an oil resistance of 4.1 to 4.9 minutes, an abrasion resistance of 4.0 to 4.8 minutes, a degree of halation of 4.3 to 4.9 minutes, a liquid outflow smoothness of 4.2 to 4.4 minutes, a color development of 5 minutes, and a base remaining condition in makeup removal and side examination of 5 minutes. Therefore, the water eyebrow pencil has the advantages of good water resistance, oil resistance, friction resistance, liquid outlet smoothness and color rendering property, good makeup holding effect and easiness in makeup removal without leaving a base.
Through further analysis of the performance data in the table, the water resistance of the ink eyebrow pencil obtained in the examples 1 to 3 is relatively improved by 15.00 to 17.07 percent, the oil resistance is relatively improved by 12.20 to 19.51 percent, the friction resistance is relatively improved by 17.07 to 17.50 percent, the degree of halation is relatively improved by 9.30 to 11.36 percent, and the liquid outflow fluency is relatively improved by 2.38 to 4.76 percent, compared with the ink eyebrow pencil obtained in the examples 4 to 5. Therefore, in the total raw materials for preparing the water eyebrow pencil, when the natural pigment and the film-forming agent in the eyebrow pencil composition are mixed according to the weight ratio of 1 (7.5-8.5), the water resistance, the oil resistance, the friction resistance, the liquid outflow fluency and the makeup holding effect of the finally obtained water eyebrow pencil can be improved.
Example 6
An aqueous eyebrow pencil is different from example 1 in that an equivalent amount of polyurethane is used instead of an acrylic copolymer, wherein the polyurethane is under the trademark COTRUNE P520C, the pH value of the polyurethane COTRUNE P520C is 7-8.5, the viscosity is 10-200mPa · s, and the particle size is 80-120nm.
Example 7
A water eyebrow pencil is different from that in example 1 in that polyacrylate with the trade name of SYNTRAN 5762 is used instead of acrylic acid copolymer, pH value of 7-8.5, viscosity of 10-200mPa.s and grain size of 80-120nm.
The water resistance, oil resistance, rubbing resistance, halation degree, fluid outflow fluency, color development and makeup removal tests were performed on the pencils obtained in examples 6 to 7, wherein 10 female volunteers were selected and randomly divided into 2 groups of 5 persons each during the detection of halation degree, fluid outflow fluency and color development. The 2 groups were scored using one of the eyebrow pencil according to any one of examples 6 to 7, and the scoring results were averaged, and the specific test results are shown in the following table.
As can be seen from the analysis of the above performance data, in the eyebrow pencil prepared by using the acrylic acid (ester) copolymer Carfil 9123 in example 1 of the present application, compared with the eyebrow pencil prepared by using the polyurethane count P520C in example 6, the water resistance is relatively improved by 6.67%, the oil resistance is relatively improved by 6.52%, the abrasion resistance is relatively improved by 2.13%, the degree of halation is relatively improved by 4.26%, and the liquid discharge smoothness is relatively improved by 2.33%. Therefore, in the total raw materials for preparing the eyebrow pencil, when the film-forming agent in the eyebrow pencil composition is acrylic acid (ester) copolymer or polyurethane, the eyebrow pencil with good water resistance, oil resistance, friction resistance, liquid outflow smoothness and lasting makeup can be obtained. However, the water eyebrow pencil prepared by adopting the acrylic acid (ester) copolymer Carfil 9123 has better water resistance, oil resistance, friction resistance, liquid outflow fluency and makeup holding effect.
Compared with the ink eyebrow pencil prepared by polyacrylate SYNTRAN 5762 in example 7, the ink eyebrow pencil prepared by acrylic acid (ester) copolymer Carfil 9123 in example 1 has the advantages that the water resistance is relatively improved by 14.29%, the oil resistance is relatively improved by 13.95%, the friction resistance is relatively improved by 20.00%, the degree of halation is relatively improved by 19.51%, and the liquid outflow smoothness is relatively improved by 10.00%. Therefore, in the total raw materials for preparing the eyebrow pencil, when the film forming agent in the eyebrow pencil composition is the acrylic acid (ester) copolymer, the obtained eyebrow pencil has good water resistance, oil resistance, friction resistance, liquid discharge smoothness and makeup holding effect.
Example 8
A water eyebrow pencil is different from example 1 in that an equivalent amount of acrylic acid copolymer Yodosol GH 256F is used in place of acrylic acid copolymer Carfil 9123, wherein the acrylic acid copolymer Yodosol GH 256F has a pH of 8.61, a viscosity of 200-250 mPas and a particle diameter of 90-100nm.
Example 9
The difference between the water eyebrow pencil and the example 1 is that the same amount of acrylic acid (ester) copolymer Carfil 9120NP is adopted to replace the acrylic acid (ester) copolymer Carfil 9123, wherein the pH value of the acrylic acid (ester) copolymer Carfil 9120NP is 8.25, the viscosity is 200-300mPa & s, and the particle size is 130-150nm.
Example 10
An aqueous eyebrow pencil is different from the one in example 1 in that an equivalent amount of acrylic copolymer syntan 5190CG is used to replace acrylic copolymer Carfil 9123, wherein the acrylic copolymer syntan 5190CG has a pH value of 7-8.5, a viscosity of 10-200mPa · s and a particle size of 80-120nm.
The water resistance, oil resistance, rubbing resistance, halation degree, fluid outflow fluency, color development and makeup removal tests were performed on the pencils obtained in examples 8 to 10, wherein 15 female volunteers were selected and randomly divided into 3 groups of 5 persons each during the detection of halation degree, fluid outflow fluency and color development. The 3 groups were scored using one of the eyebrow pencils of examples 8-10, and the scores were averaged, and the specific test results are shown in the table below.
As can be seen from the analysis of the above performance data, in the eyebrow pencil prepared by using the acrylic acid (ester) copolymer Carfil 9123 in example 1 of the present application, compared with the eyebrow pencil prepared by using the acrylic acid (ester) copolymer YODOSOL GH 256F in example 8, the water resistance is relatively improved by 9.09%, the oil resistance is relatively improved by 8.89%, the friction resistance is relatively improved by 6.67%, the halation degree is relatively improved by 8.89%, and the liquid outflow fluency is relatively improved by 2.33%.
Compared with the water eyebrow pencil prepared by adopting acrylic acid (ester) copolymer Carfil 9120NP in embodiment 9, the water resistance of the water eyebrow pencil prepared by adopting acrylic acid (ester) copolymer Carfil 9123 in embodiment 1 is relatively improved by 11.63%, the oil resistance of the water eyebrow pencil is relatively improved by 11.36%, the friction resistance of the water eyebrow pencil is relatively improved by 9.09%, the halation degree of the water eyebrow pencil is relatively improved by 8.89%, and the liquid outflow fluency of the water eyebrow pencil is relatively improved by 2.33%.
Therefore, in the total raw materials for preparing the eyebrow pencil, when the eyebrow pencil composition is prepared, the pH value of the acrylic acid (ester) copolymer is 7-8.5, the viscosity is 50-100mPa & s, and the particle size is 80-120nm, so that the water resistance, oil resistance, friction resistance, liquid outflow smoothness and makeup holding effect of the finally obtained eyebrow pencil can be improved.
Compared with the water eyebrow pencil prepared by adopting the acrylic acid (ester) copolymer SYNTRAN 5190CG in the embodiment 10, the water resistance, the oil resistance, the friction resistance, the liquid outflow fluency, the anti-halation degree and the liquid outflow fluency of the water eyebrow pencil prepared by adopting the acrylic acid (ester) copolymer Carfil 9123 in the embodiment 1 are improved to some extent.
Example 11
An eyebrow pencil which is different from example 1 in that an eyebrow pencil composition is prepared by the following preparation steps:
s1, mixing the humectant and the bactericide at 10-30 ℃, and stirring and mixing for 5min at 500r/min to obtain a mixed solution; adding water into the mixed solution at 10-30 ℃, stirring and mixing at 500r/min for 8min to obtain a mixture;
s2, adding the natural pigment into the mixture, stirring and mixing at 500r/min for 25min, controlling the temperature to be 10-30 ℃, adding the film-forming agent, and stirring and mixing at 500r/min for 15min to obtain the eyebrow pencil composition.
The eyebrow pencil composition has viscosity of 3.0cP at 25 deg.C, pH of 7.10-7.50, particle diameter of 150nm, and solid content of 23.7%.
Example 12
An eyebrow pencil which is different from example 1 in that an eyebrow pencil composition is prepared by the following steps:
s1, mixing the humectant and the bactericide at 10-30 ℃, and stirring and mixing at 700r/min for 5min to obtain a mixed solution; adding water into the mixed solution at 10-30 ℃, stirring and mixing at 500r/min for 8min to obtain a mixture;
s2, adding the natural pigment into the mixture, stirring and mixing at 700r/min for 35min, controlling the temperature to be 10-30 ℃, adding the film-forming agent, and stirring and mixing at 700r/min for 25min to obtain the eyebrow pencil composition.
The eyebrow pencil composition has viscosity of 4cP at 25 ℃, pH value of 7.10-7.50, particle size of 100nm and solid content of 25.7% by detection.
The water eyebrow pencils obtained in examples 11 to 12 were subjected to the detection of degree of halation, smoothness of discharge, and makeup removal, wherein 10 female volunteers were selected and randomly divided into 2 groups of 5 persons each during the detection of degree of halation and smoothness of discharge. The 2 groups were scored using one of the eyebrow pencils of examples 11-12, and the scores were averaged, and the results were shown in the table below.
According to the analysis of various performance data in the table, the water eyebrow pencil has the advantages that the water eyebrow pencil which is good in makeup holding effect, smooth in liquid discharge and free of foundation removal is obtained by controlling the process conditions of adding the raw materials in the preparation step of the eyebrow pencil composition.
Comparative example
Comparative examples 1 to 2
An aqueous eyebrow pencil is different from example 1 in that the components and the weights thereof in the eyebrow pencil composition are as shown in the following table.
Comparative example 3
An aqueous eyebrow pencil which is different from example 1 in that cocoa butter is replaced with cochineal carmine colorant in the same amount.
Comparative example 4
A water eyebrow pencil is different from example 1 in that an equal amount of blue 1 pigment is used instead of cocoa pigment, wherein the blue 1 pigment is purchased from Shanghai Tommar daily chemical industry Co.
And (3) carrying out waterproof property, oil resistance, rubbing resistance, halation degree, fluid outflow fluency, color rendering property and makeup removal detection on the eyebrow pencils obtained in the comparative examples 1-4, wherein 20 female volunteers are selected and randomly divided into 4 groups of 5 persons in each group during the halation degree detection, the fluid outflow fluency and the color rendering property detection. The 4 groups were scored using one of the aqueous eyebrow pencils of comparative examples 1 to 4, and the scoring results were averaged, and the specific test results are shown in the table below.
As can be seen from the analysis of the above performance data, the water eyebrow pencil obtained in comparative examples 1-2 has a water resistance of 3.4-3.6 minutes, an oil resistance of 3.3-3.5 minutes, a rub resistance of 3.2-3.4 minutes, a degree of halation of 3.5-3.7 minutes, a degree of fluidity of liquid discharge of 3.6-3.8 minutes, a color development of 4.1-4.3 minutes, and a condition of leaving a base when the makeup is removed and examined is 4.0-4.2 minutes.
Compared with the ink eyebrow pencil obtained in the comparative example 1-2, the ink eyebrow pencil obtained in the embodiment 1 has the advantages that the waterproofness is relatively improved by 33.33-41.18%, the oil resistance is relatively improved by 40.00-48.48%, the friction resistance is relatively improved by 41.18-50.00%, the degree of halation is relatively improved by 32.43-40.00%, the liquid outflow fluency is relatively improved by 15.79-22.22%, the color rendering is relatively improved by 16.28-21.95%, and the makeup removal detection score is relatively improved by 19.05-25.00%. Therefore, the eyebrow pencil composition is prepared from the following components in percentage by weight in the total raw materials for preparing the water eyebrow pencil: 6-8% of humectant, 0.7-0.9% of bactericide, 3.5-4.5% of natural pigment, 28-32% of film forming agent and 57.2-59.2% of water, and can improve the water resistance, oil resistance, rubbing resistance, liquid outflow smoothness and color rendering property of the obtained water eyebrow pencil, and meanwhile, the water eyebrow pencil has good makeup holding effect, is not tinged and can not leave a foundation for makeup removal.
Compared with the ink eyebrow pencil prepared by cochineal red in the comparative example 3, the ink eyebrow pencil prepared by cocoa pigment in the embodiment 1 of the application has the advantages that the water resistance, the oil resistance, the friction resistance, the liquid outflow fluency, the color rendering property, the anti-halation performance and the makeup removing efficiency are obviously improved.
Compared with the ink eyebrow pencil prepared by adopting the blue 1 pigment in the comparative example 4, the ink eyebrow pencil prepared by adopting the cocoa pigment in the embodiment 1 has the advantages that the water resistance is relatively improved by 54.84%, the oil resistance is relatively improved by 22.50%, the friction resistance is relatively improved by 26.32%, the halation degree is relatively improved by 22.50%, the liquid outflow smoothness is relatively improved by 20.00%, the color rendering is relatively improved by 66.67%, and the makeup removal detection score is relatively improved by 284.62%.
Therefore, in the total raw materials for preparing the eyebrow pencil, when the natural pigment in the eyebrow pencil composition is cocoa pigment, sweet potato pigment or radish root pigment, the water resistance, oil resistance, friction resistance, liquid outlet smoothness, color development and makeup holding effect of the finally obtained eyebrow pencil can be improved. Meanwhile, the makeup removing efficiency of the water eyebrow pencil can be obviously improved.
The specific embodiments are only for explaining the present application and are not limiting to the present application, and those skilled in the art can make modifications to the embodiments without inventive contribution as required after reading the present specification, but all the embodiments are protected by patent law within the scope of the claims of the present application.
Claims (9)
1. The eyebrow pencil composition is characterized by comprising the following components in percentage by weight:
6-8% of a humectant;
0.7 to 0.9 percent of bactericide;
3.5 to 4.5 percent of natural pigment;
28-32% of a film forming agent;
57.2 to 59.2 percent of water;
the natural pigment comprises cocoa pigment, sweet potato pigment or radish root pigment.
2. The eyebrow pencil composition of claim 1, wherein: in the eyebrow pencil composition, the weight ratio of the natural pigment to the film-forming agent is 1 (7.5-8.5).
3. The eyebrow pencil composition of claim 1, wherein: the film forming agent comprises any one of acrylic acid (ester) copolymer and polyurethane.
4. The eyebrow pencil composition of claim 3, wherein: the film forming agent is an acrylic acid (ester) copolymer, the pH value of the acrylic acid (ester) copolymer is 7-8.5, the viscosity of the acrylic acid (ester) copolymer is 50-100mPa.s, and the particle size of the acrylic acid (ester) copolymer is 80-120nm.
5. The eyebrow pencil composition of claim 4, wherein: the acrylic acid (ester) copolymer is preferably acrylic acid (ester) copolymer Carfil 9123 or acrylic acid (ester) copolymer COVACRYL E14 PF.
6. The eyebrow pencil composition of claim 3, wherein: the film forming agent is polyurethane, the pH value of the polyurethane is 7-8.5, the viscosity is 10-200mPa.s, and the particle size is 80-120nm.
7. The eyebrow pencil composition of claim 1, wherein: the eyebrow pencil composition has the viscosity of 3-4cP at 25 ℃, the pH value of 7.10-7.50, the particle size of less than 150nm and the solid content of 23.7-25.7%.
8. A process for the preparation of a eyebrow pencil composition according to any one of claims 1 to 7, which comprises the steps of:
s1, adding water into a mixed solution of a humectant and a bactericide, and stirring and mixing to obtain a mixture;
and S2, adding the natural pigment into the mixture, stirring and mixing, adding the film-forming agent, and stirring and mixing to obtain the eyebrow pencil composition.
9. The method of preparing a eyebrow pencil composition of claim 8, wherein: the preparation method of the eyebrow pencil composition comprises the following specific steps:
s1, adding water into a mixed solution of a humectant and a bactericide at 10-30 ℃, and stirring and mixing for 5-8min at 500-700r/min to obtain a mixture;
s2, adding the natural pigment into the mixture, stirring and mixing at 500-700r/min for 25-35min, controlling the temperature to be 10-30 ℃, adding the film-forming agent, and stirring and mixing at 500-700r/min for 15-25min to obtain the eyebrow pencil composition.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100659040B1 (en) * | 2006-01-26 | 2006-12-19 | 정성원 | Eye Makeup Cosmetics Composition |
| CN101352400A (en) * | 2007-07-24 | 2009-01-28 | 株式会社太平洋 | Eye cosmetic composition containing natural pigment |
| CN107349147A (en) * | 2017-07-10 | 2017-11-17 | 山西大学 | A kind of plant type eyebrow pencil composition and preparation method thereof |
| CN109789083A (en) * | 2016-09-30 | 2019-05-21 | 株式会社爱茉莉太平洋 | Eyebrow makeup cosmetic composition |
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- 2022-08-25 CN CN202211025412.1A patent/CN115414292A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100659040B1 (en) * | 2006-01-26 | 2006-12-19 | 정성원 | Eye Makeup Cosmetics Composition |
| CN101352400A (en) * | 2007-07-24 | 2009-01-28 | 株式会社太平洋 | Eye cosmetic composition containing natural pigment |
| CN109789083A (en) * | 2016-09-30 | 2019-05-21 | 株式会社爱茉莉太平洋 | Eyebrow makeup cosmetic composition |
| CN107349147A (en) * | 2017-07-10 | 2017-11-17 | 山西大学 | A kind of plant type eyebrow pencil composition and preparation method thereof |
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