CN1153700A

CN1153700A - Damping plastics floor for outdoor use and its prodn process

Info

Publication number: CN1153700A
Application number: CN 95117805
Authority: CN
Inventors: 茅青; 裘士廉
Original assignee: Individual
Current assignee: Individual
Priority date: 1995-12-04
Filing date: 1995-12-04
Publication date: 1997-07-09
Anticipated expiration: 2015-12-04
Also published as: CN1049178C

Abstract

The damping plastics floor is for paving gymnasium, children's amusement park and bed room. It is produced with waste rubber, mainly waste tyre, as main material, into which tolylene diisocyanate (TD180), polypropyl ether-glycol (PPG-2000), 2,6-ditertbutyl cresol (or 1010), 2-ethyl hexanoic lead, phenylmercuric acetate, white carbon, pigment and activator are added. The production process includes washing, cutting, crushing, sieving, activating, polymerization, moulding and post treatment.

Description

Damping plastics floor for outdoor use and manufacturing process thereof

The present invention relates to a kind of pavement, specifically a kind of damping plastics floor for outdoor use is modern senior pavement.It can absorb impact energy effectively, with guarantor's comfortable and safe in when motion.Mainly be applicable to the place in place, children amusement park and nursery, senior rooms etc. such as laying gymnasium, sports training ground, golf, tennis.

Domestic most employing cement, plastics, plank and palm fibre pad are made terrace at present, and the problem of existence is: 1. all can not guarantee personal safety effectively, 2. also be unfavorable for bringing into play to greatest extent physical culture personnel's achievement.The patent of not having this respect by retrieval abroad have and use the damping terrace, but cost is too high, and is undesirable in a word.

The objective of the invention is:, for eliminating the pollution of waste old (mainly being junked tire), be the prescription and the manufacturing process of the damping plastics floor of primary raw material with the waste old simultaneously and provide a kind of to environment for addressing the above problem.

Realize that the technical measures that the object of the invention is taked are:

Prescription (unit by weight: kg)

Waste and old rubber particle (8-32 order) 72-90

Toluene diisocyanate (TDI80) 2.7-4.3

Polypropylene ether glycol (PPG-2000) 7.3-11.7

2,6-BHT (or 1010) 0.8-1.0

The plumbous 0.2-0.8 of 2 ethyl hexanoic acid

Phenylmercuric acetate 0.2-0.8

White carbon 0.6-1.0

Pigment (red, orchid, green etc.) 6.0-9.0

Water 40-50

Clorox 12-15

Hydrochloric acid 0.2-0.25

Fig. 1 is technological process of production figure of the present invention

The technological process of production: referring to Fig. 1

Clean 1: will spend old rubber tyre a and put into the cleaning machine cleaning, remove foul, Taking-up is dried;

Slitting 2: will clean dry in the air in junked tire a put into cutting machine and cut into inch strips;

Pulverize 3: the junked tire bar is put into disintegrating machine, and (opening of ZKC-5609 type is rolled The cartridge type disintegrating machine) pulverizes in;

Screening 4: the rubber grain after will pulverizing (being called for short the glue chaff) is crossed 8-32 The purpose sieve aperture screens;

Activation process 5: get glue chaff 72-90kg, put into gasoline No. 120 In, till submergence glue chaff, to soak 2-4 minute, taking-up is dried, and puts into stirring In the device, add activator and mix thoroughly, left standstill 3-10 minute, repeatedly wash with clear water 2-3 time, dry the prescription of activator after cleaning: water 40-50kg, inferior Sodium chlorate 12-15kg, hydrochloric acid 0.2-0.25kg;

Polymerization 6: toluene diisocyanate b and polypropylene ether glycol c are pressed the prescription polymerization Become performed polymer, its technology for earlier with the polypropylene ether glycol 80-130 ℃ with Vacuum is to dewater 1-3 hour in retort under the 5mmHg, is cooled to then 40 ℃, Slowly add toluene diisocyanate, reaction 1-3 is little under vacuum or purity nitrogen protection The time be cooled to the room temperature discharging, the sealing lucifuge is stored stand-by;

Moulding (or cast-in-situ) 7:

A. in agitator, add successively the performed polymer after the polymerization, white carbon g, pigment h, 2,6-BHT d, the plumbous e of 2 ethyl hexanoic acid, phenylmercuric acetate f, under 80-100 rev/min with material stirring 5-15 minute that adds, compound is poured in another agitator that has dropped in advance the 8-32 order glue chaff after activated, stirred 5-18 minute rapidly, immediately compound is poured in the frame that encloses in mould or place, at 0.1kg/cm²Pressure, room temperature or the lower curing and demolding of heating;

B. also can be by formulation weight, take by weighing respectively each component, in agitator, drop into successively toluene diisocyanate and polypropylene ether glycol, white carbon, pigment is (such as iron oxide red, chrome green etc.), 2, the 6-BHT, 2 ethyl hexanoic acid lead, phenylmercuric acetate, under 80-100 rev/min with material stirring 5-15 minute that adds, make mixing of materials even, then compound is poured in another agitator that has dropped in advance the 8-32 order glue chaff after activated, stirred rapidly 5-18 minute, immediately compound is poured in the frame that encloses in mould or place, at 0.1kg/cm²Pressure, room temperature or the lower curing and demolding of heating, when adjusting cold curing according to prescription Between can be controlled at 1-6 hour, the heating cure time can shorten about 50%;

Post processing 8: at room temperature deposit a week then completion of cure namely go out finished product 9.

Being designed to mould according to the needs in different places has to produce single, double layer The prefabricated component of difformity and size, when making double-deck floor material, the component of lower floor In remove white carbon and pigment, the glue chaff adopts 32 order granularities, all the other prescriptions with produce Technology is identical with individual layer.

The effect of each component is in this prescription:

Toluene diisocyanate (TDI80) is the master who forms the polyurethane binding agent Want raw material; Polypropylene ether glycol (PPG-2000) is with forming poly-ammonia after the TDI reaction Base formic acid fat binding agent, its molecular weight is 2000, Reaction equation is:

2 ethyl hexanoic acid lead and phenylmercuric acetate are catalyst, and catalytic effect is better when share, and utilizes the close electrical characteristics of catalyst, make the carbimide base change the excessive attitude of high energy into and strengthen reaction from the resonance stable state;

2, the 6-BHT, or 1010, being commercially pure antioxidant, effect is the ageing-resistant performance that improves product;

The effect of white carbon is to improve the diffusivity of pigment in colloid, makes pigment distribution even;

The effect of activation: utilize the active chlorine in the activator, make glue chaff surface chlorination, to strengthen its surface polarity, cohesive force strengthens when making moulding;

Embodiment 1:(is an example with red individual layer)

In agitator, drop into toluene diisocyanate b2.7kg successively, polypropylene ether glycol c7.3kg, white carbon g0.6kh, iron oxide red h6kg, 2,6-BHT d (or 1010) 0.8kg, the plumbous e0.2kg of 2 ethyl hexanoic acid, phenylmercuric acetate f0.2kg, under 80 rev/mins rotating speed, above-mentioned material was stirred 5 minutes, then compound is poured in another agitator that has dropped into the 8 order glue chaff a of 72kg after activated in advance, stirred rapidly 5 minutes, pour compound into mould immediately, at 0.1kg/cm ²Pressure, room temperature under solidify the demoulding after 6 hours, at room temperature deposit again and can dispatch from the factory in a week.

The poling processing technique of glue chaff:

Activator is by water, clorox, and hydrochloric acid is formed.

1. 72kg glue chaff is put into plastic barrel, inject No. 120 gasoline and arrive till the submergence glue chaff, left standstill 2 minutes, taking-up is dried;

2. water 40kg, clorox 12kg, hydrochloric acid 0.2kg are put into agitator, stir, left standstill 3 minutes, start agitator, take out the glue chaff and dry with clear water flushing 2 times.

Embodiment 2:(is an example with red individual layer)

In agitator, drop into toluene diisocyanate 3.5kg successively, polypropylene ether glycol 9.5kg, white carbon 0.8kg, iron oxide red 7.5kg, 2,6-BHT 0.9kg, the plumbous 0.5kg of 2 ethyl hexanoic acid, phenylmercuric acetate 0.5kg, under 90 rev/mins of rotating speeds, stirred 10 minutes, then compound is poured in another agitator that has dropped in advance the 8 order glue chaffs of 81kg after activated and stirred 10 minutes rapidly, pour compound into mould immediately, at 0.1kg/cm ²Pressure, room temperature under solidify the demoulding after 4 hours, at room temperature deposit a week again.

The poling processing technique of glue chaff:

1. 81kg glue chaff is put into plastic barrel, inject No. 120 gasoline and arrive till the submergence glue chaff, left standstill 3 minutes, taking-up is dried;

2. with water i45kg, clorox j13.5kg, hydrochloric acid k0.226kg puts into agitator, stirs, and leaves standstill 6 minutes, starts agitator, and water flushing 2 times is taken out the glue chaff and is dried.

Embodiment 3:(is an example with red individual layer)

In agitator, drop into toluene diisocyanate b4.3kg successively, polypropylene ether glycol c11.7kg, white carbon g1kg, iron oxide red h9kg, 2,6-BHT d1kg, the plumbous e0.8kg of 2 ethyl hexanoic acid, phenylmercuric acetate f0.8kg under 100 rev/mins of rotating speeds, stirred 15 minutes, then compound is poured in another agitator that has dropped in advance the 8 order glue chaff a of 90kg after activated, stirred 18 minutes rapidly, pour compound into mould immediately, at 0.1kg/cm ²Pressure, room temperature under solidify the demoulding after 1 hour, at room temperature deposit a week again.

The poling processing technique of glue chaff:

1. 90kg glue chaff is put into plastic barrel, inject No. 120 gasoline and arrive till the submergence glue chaff, left standstill 4 minutes, taking-up is dried;

2. with water i50kg, clorox j15kg, hydrochloric acid k0.25kg puts into agitator, stirs; Left standstill 10 minutes, and started agitator water flushing 3 times, take out glue chaff a and dry;

Just discarded soon after use as tire, can be without activation processing.

Advantage of the present invention:

1. turn waste into wealth, the present invention is with waste old (mainly being junked tire) Be primary raw material, can be made into the terrace that thickness is the 3-110mm all size, With the old rubber of the degree that digests a large amount of contaminated environment, China has 500,000 tons to give up present every year Old rubber is not utilized, and primary raw material of the present invention is exactly waste old, along with this The promotion and implementation of invention will provide for the comprehensive utilization of waste old wide approach.

2. security and comfortableness are very high, at the thickness range of 50-110mm In, its safety critical height can be from 1.3 meters-2.9 meters, namely under this height, The people does not throw can be subjected to mortal injury;

3. resistance to sliding is big, can satisfy the optimum state of human motion and vehicle greatly The needs that normally travel on the gradient;

4. wearability surpasses natural rubber more than three times;

5. production process three-waste free discharge, environmentally safe.

Detect the detection of London CST inspection center of authoritative institution through the world, this The relevant main performance index of invention product meets the BS international standard fully. (see attached Part 1)

For example: 1. critical altitude is 1.3-2.9 rice.

2. resistance to sliding＞40.

3. cohesive force is strong, meets the BS standard.

4. anti-flammability meets the BS standard.

Claims

1. a damping plastics floor for outdoor use is a primary raw material with waste old (mainly being junked tire), it is characterized in that, in waste old, add toluene diisocyanate (TDI80), polypropylene ether glycol (PPG-2000), 2,6-BHT (or 1010), 2 ethyl hexanoic acid lead, phenylmercuric acetate, white carbon, pigment, water, clorox, be processed into behind the hydrochloric acid

Prescription (unit by weight: kg):

Waste and old rubber particle (8-32 order) 72-90

Toluene diisocyanate (TDI80) 2.7-4.3

Polypropylene ether glycol (PPG-2000) 7.3-11.7

2,6-BHT (or 1010) 0.8-1.0

The plumbous 0.2-0.8 of 2 ethyl hexanoic acid

Phenylmercuric acetate 0.2-0.8

White carbon 0.6-1.0

Pigment (red, orchid, green etc.) 6.0-9.0

Water 40-50

Clorox 12-15

Hydrochloric acid 0.2-0.25.

2. the manufacturing process of a damping plastics floor for outdoor use is characterized in that, comprises following technological process:

Clean (1): waste and used rubber tyre (a) is put into cleaning machine clean, remove foul, taking-up is dried;

Slitting (2): the junked tire of cleaning (a) is put into cutting machine cut into inch strips;

Pulverize (3): the junked tire bar is put into disintegrating machine pulverize;

Screening (4): the glue chaff after will pulverizing sieves and screens;

Activation processing (5): get glue chaff 72-90kg, put in No. 120 gasoline, till submergence glue chaff, soaked 2-4 minute, taking-up is dried, and puts into agitator, adds activator and mixes thoroughly, leaves standstill 3-10 minute, washes 2-3 time repeatedly with clear water, dries after clean;

Polymerization (6): toluene diisocyanate (b) and polypropylene ether glycol (c) are aggregated into performed polymer by prescription, be 5mmHg under in retort to dewater 1-3 hour at 80-130 ℃ with vacuum with the polypropylene ether glycol earlier, be cooled to 40 ℃ then, slowly add toluene diisocyanate, reaction was cooled to the room temperature discharging in 1-3 hour under vacuum or purity nitrogen protection, with polyurethane binding agent performed polymer sealing lucifuge stored for future use;

Moulding or cast-in-situ (7):

In agitator, add the performed polymer after the polymerization successively, white carbon (g), pigment (h), 2,6-BHT (d), 2 ethyl hexanoic acid lead (e), phenylmercuric acetate (f) stirs the material that adds 5-15 minute under 80-100 rev/min, compound is poured in another agitator that has dropped in advance the 8-32 order glue chaff after activated, stirred 5-18 minute rapidly, compound is poured in the used frame in mould or place, immediately at 0.1kg/cm ²Pressure, room temperature or the curing and demolding of heating down;

Post processing (8): the product after the demoulding is at room temperature deposited a week;

Finished product (9).

3. by the described manufacturing process of claim 2, it is characterized in that the disintegrating machine during pulverizing adopts ZKC-5609 type disintegrating machine.

4. by the described manufacturing process of claim 2, it is characterized in that 8-32 purpose sieve is adopted in screening.

5. by the described manufacturing process of claim 2, the prescription of used activator is in the activation processing: water (i) 40-50kg, clorox (j) 12-15kg, hydrochloric acid (k) 0.2-0.25kg.

6. by the described manufacturing process of claim 2, it is characterized in that, also can take by weighing each component respectively when moulding or cast-in-situ, in agitator, drop into toluene diisocyanate (b) successively by formulation weight, polypropylene ether glycol (c), white carbon (g), pigment (h), 2,6-BHT (d), 2 ethyl hexanoic acid lead (e), phenylmercuric acetate (f) is under 80-100 rev/min, the material that adds was stirred 5-15 minute, make mixing of materials even, then compound is poured in another agitator that has dropped in advance the 8-32 order glue chaff after activated, stirred rapidly 5-18 minute, compound is poured in the used frame in mould or place, immediately at 0.1kg/cm ²Pressure, room temperature or the curing and demolding of heating down.

7. by the described manufacturing process of claim 2, it is characterized in that adjust room temperature controlled built in 1-6 hour according to prescription, the heating cure time can shorten about 50%.

8. by the described manufacturing process of claim 2, it is characterized in that, design different moulds and can be made into individual layer or bilayer and have different shape and dimensional thickness from 3---the prefabricated component of 110mm.