CN115340909B - Multifunctional ecological cleaning particles and preparation method thereof - Google Patents
Multifunctional ecological cleaning particles and preparation method thereof Download PDFInfo
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- CN115340909B CN115340909B CN202211081307.XA CN202211081307A CN115340909B CN 115340909 B CN115340909 B CN 115340909B CN 202211081307 A CN202211081307 A CN 202211081307A CN 115340909 B CN115340909 B CN 115340909B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/044—Solid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3953—Inorganic bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
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- Detergent Compositions (AREA)
Abstract
The invention relates to the technical field of cleaning, in particular to multifunctional ecological cleaning particles and a preparation method thereof. The multifunctional ecological cleaning particles comprise a first water-soluble film, a second water-soluble film, sodium peroxycarbonate, caprylin-caprin glyceride, edible sodium bicarbonate, sodium citrate, sodium chloride and tea seed powder, wherein the inner cavity of the first water-soluble film is coated with the sodium peroxycarbonate, the caprylin-caprin glyceride and the edible sodium bicarbonate, the second water-soluble film is sleeved outside the first water-soluble film, and sodium citrate, sodium chloride and soapberry saponin are filled between the second water-soluble film and the first water-soluble film; the dissolution time of the second water-soluble film is N seconds, and the dissolution time of the first water-soluble film is M seconds, wherein N is less than M. The invention has the advantages of high-efficiency sterilization, good storage stability of washing components, uniform dissolution of the components and high cleaning efficiency.
Description
Technical Field
The invention relates to the technical field of cleaning, in particular to multifunctional ecological cleaning particles and a preparation method thereof.
Background
Traditional cleaners, liquid detergents and the like mostly adopt liquid modes. Although the ability to decontaminate is sufficiently well defined, the functionality is too single and can only be targeted to one feature for decontamination. And most of the product proportion of the product is toxic, irritant and harmful to human bodies. When the product is used for other articles, the product itself is damaged and corroded due to different pH values.
In recent years, the cleaning powder combining the multifunctional biological aerobic factors and plant elements is focused, and the cleaning powder has the advantages of effective sterilization, mite removal, powerful decontamination, safety and skin care, has a strong washing effect on infant clothes and adult underwear, and can be used for cleaning articles such as kitchen ware, furniture, floors, sanitary appliances, smoke exhaust ventilator and the like. However, such cleaning powders have some disadvantages: (1) Part of the components are sterilized efficiently, and the storage stability of the washing components is poor, so that the shelf life of the components is short; (2) non-uniform dissolution of particles; (3) the cleaning time is long.
Disclosure of Invention
The invention aims to provide multifunctional ecological cleaning particles and a preparation method thereof, which overcome the defects of the prior art, and the multifunctional ecological cleaning particles contain high-efficiency sterilization, good storage stability of washing components, uniform dissolution of the components and high cleaning efficiency.
The technical scheme adopted for solving the technical problems is as follows:
the multifunctional ecological cleaning particles comprise a first water-soluble film, a second water-soluble film, sodium peroxycarbonate, caprylin-caprin glyceride, edible sodium bicarbonate, sodium citrate, sodium chloride and tea seed powder, wherein the inner cavity of the first water-soluble film is coated with the sodium peroxycarbonate, the caprylin-caprin glyceride and the edible sodium bicarbonate, the second water-soluble film is sleeved outside the first water-soluble film, and sodium citrate, sodium chloride and tea seed powder are filled between the second water-soluble film and the first water-soluble film; the dissolution time of the second water-soluble film is N seconds, and the dissolution time of the first water-soluble film is M seconds, wherein N is less than M.
Preferably, the weight portions of the raw materials are as follows: 20-35 parts of sodium peroxycarbonate, 8-12 parts of caprylin and caprin, 5-12 parts of edible baking soda, 10-20 parts of sodium citrate, 20-30 parts of sodium chloride and 20-30 parts of tea seed powder.
More preferably, the weight portions of the raw materials are as follows: 27 parts of sodium peroxycarbonate, 10 parts of caprylin-caprin, 8 parts of edible baking soda, 15 parts of sodium citrate, 22 parts of sodium chloride and 26 parts of tea seed powder.
Preferably, the tea seed powder contains 12-18% of natural tea saponin by weight percent.
Preferably, the inner diameter of the second water-soluble film is 0.5-0.8cm, and the inner diameter of the first water-soluble film is 0.2-0.3cm.
Preferably, the inner diameter of the second water-soluble film is 30-90s, and the inner diameter of the first water-soluble film is 300-600s.
A preparation method of multifunctional ecological cleaning particles comprises the following steps:
(1) Mixing sodium peroxycarbonate and caprylin-caprin to form a mixture A, and then sticking and rolling the mixture A in edible sodium bicarbonate to enable the edible sodium bicarbonate to be attached to the surface of the mixture A as much as possible to form a mixture B, packaging the mixture B through a first water-soluble film, and filling the edible sodium bicarbonate which is not attached to the surface of the mixture A into the first water-soluble film;
(2) And uniformly mixing sodium citrate, sodium chloride and tea seed powder, and then doping the mixture with the first water-soluble film encapsulated with the mixture B to form a composition C, and encapsulating the composition C by the second water-soluble film.
The beneficial effects of the invention are as follows: compared with the prior art, the multifunctional ecological cleaning particles and the preparation method thereof have the following advantages: in the invention, ecological cleaning particles are placed in water and are approximately uniformly distributed in the water along with stirring, after a certain distribution time, the second water-soluble film is dissolved, sodium citrate and sodium chloride are released to play a role in cleaning and sterilizing, at the moment, the packaging balls formed by the first water-soluble film can assist in rubbing clothes, tableware and other articles when clothes, tableware and other articles are cleaned, the cleaning efficiency is improved, after a certain time, the first water-soluble film is also dissolved, and sodium peroxycarbonate, caprylic and capric glyceride and edible baking soda are released to further remove greasy dirt and sterilize. The sodium peroxycarbonate has stronger washing, sterilizing and bleaching effects, but the sodium peroxycarbonate has short storage time and is easy to lose effectiveness when being used in common cleaning products, however, in the invention, firstly, the sodium peroxycarbonate powder and the liquid caprylin glyceride are doped, the caprylin glyceride has good performance stability and stronger deoiling capability, the sodium peroxycarbonate and the caprylin glyceride are doped to form stability protection for the sodium peroxycarbonate, the edible sodium bicarbonate is adhered on the appearance of the mixture A to form a mixture B on the basis of the mixture A to form isolation protection for the sodium peroxycarbonate, and then the mixture B is encapsulated through a first water-soluble film, so that the storage stability of the sodium peroxycarbonate is further improved, the shelf life is prolonged, and the bleaching, washing and sterilizing functions of the sodium peroxycarbonate are ensured to be effective for a long time.
Drawings
FIG. 1 is a schematic structural view of a multifunctional ecological cleaning particle of the present invention;
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more clear, the technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention.
Example 1
In the embodiment shown in fig. 1, a multifunctional ecological cleaning particle comprises a first water-soluble film 1, a second water-soluble film 2, sodium peroxycarbonate, caprylin/caprin, edible sodium bicarbonate, sodium citrate, sodium chloride and tea seed powder, wherein the inner cavity of the first water-soluble film is coated with the sodium peroxycarbonate, the caprylin/caprin and the edible sodium bicarbonate, the second water-soluble film is sleeved outside the first water-soluble film, and sodium citrate, sodium chloride and tea seed powder are filled between the second water-soluble film and the first water-soluble film; the inner diameter of the second water-soluble film is 0.6cm, and the inner diameter of the first water-soluble film is 0.2cm; the inner diameter of the second water-soluble film was 40 seconds, and the inner diameter of the first water-soluble film was 550 seconds.
The weight portions of the raw materials are as follows: 27 parts of sodium peroxycarbonate, 10 parts of caprylin-caprin, 8 parts of edible baking soda, 15 parts of sodium citrate, 22 parts of sodium chloride and 26 parts of tea seed powder. The tea seed powder contains 15% of natural tea saponin by weight percentage.
The preparation method of the multifunctional ecological cleaning particles in the embodiment comprises the following steps:
(1) Mixing sodium peroxycarbonate and caprylin-caprin to form a mixture A, and then sticking and rolling the mixture A in edible sodium bicarbonate to enable the edible sodium bicarbonate to be attached to the surface of the mixture A as much as possible to form a mixture B, packaging the mixture B through a first water-soluble film, and filling the edible sodium bicarbonate which is not attached to the surface of the mixture A into the first water-soluble film;
(2) And uniformly mixing sodium citrate, sodium chloride and tea seed powder, and then doping the mixture with the first water-soluble film encapsulated with the mixture B to form a composition C, and encapsulating the composition C by the second water-soluble film.
Example 2
The multifunctional ecological cleaning particles comprise a first water-soluble film, a second water-soluble film, sodium peroxycarbonate, caprylin-caprin glyceride, edible sodium bicarbonate, sodium citrate, sodium chloride and tea seed powder, wherein the inner cavity of the first water-soluble film is coated with the sodium peroxycarbonate, the caprylin-caprin glyceride and the edible sodium bicarbonate, the second water-soluble film is sleeved outside the first water-soluble film, and sodium citrate, sodium chloride and tea seed powder are filled between the second water-soluble film and the first water-soluble film; the inner diameter of the second water-soluble film is 0.5cm, and the inner diameter of the first water-soluble film is 0.2cm. The second water-soluble film had an inner diameter of 30 seconds, and the first water-soluble film had an inner diameter of 300 seconds.
The weight portions of the raw materials in the embodiment are as follows: 20 parts of sodium peroxycarbonate, 8 parts of caprylin-caprin, 5 parts of edible baking soda, 10 parts of sodium citrate, 20 parts of sodium chloride and 20 parts of tea seed powder. The tea seed powder contains 12 weight percent of natural tea saponin.
The preparation method of the multifunctional ecological cleaning particles comprises the following steps:
(1) Mixing sodium peroxycarbonate and caprylin-caprin to form a mixture A, and then sticking and rolling the mixture A in edible sodium bicarbonate to enable the edible sodium bicarbonate to be attached to the surface of the mixture A as much as possible to form a mixture B, packaging the mixture B through a first water-soluble film, and filling the edible sodium bicarbonate which is not attached to the surface of the mixture A into the first water-soluble film;
(2) And uniformly mixing sodium citrate, sodium chloride and tea seed powder, and then doping the mixture with the first water-soluble film encapsulated with the mixture B to form a composition C, and encapsulating the composition C by the second water-soluble film.
Example 3
The multifunctional ecological cleaning particles comprise a first water-soluble film, a second water-soluble film, sodium peroxycarbonate, caprylin-caprin glyceride, edible sodium bicarbonate, sodium citrate, sodium chloride and tea seed powder, wherein the inner cavity of the first water-soluble film is coated with the sodium peroxycarbonate, the caprylin-caprin glyceride and the edible sodium bicarbonate, the second water-soluble film is sleeved outside the first water-soluble film, and sodium citrate, sodium chloride and tea seed powder are filled between the second water-soluble film and the first water-soluble film; the inner diameter of the second water-soluble film is 0.8cm, and the inner diameter of the first water-soluble film is 0.3cm. The inner diameter of the second water-soluble film is 90s, and the inner diameter of the first water-soluble film is 600s.
The weight portions of the raw materials in the embodiment are as follows: 35 parts of sodium peroxycarbonate, 12 parts of caprylin-caprin, 12 parts of edible sodium bicarbonate, 20 parts of sodium citrate, 30 parts of sodium chloride and 30 parts of tea seed powder. The tea seed powder contains 18 weight percent of natural tea saponin.
The preparation method of the multifunctional ecological cleaning particles in the embodiment comprises the following steps:
(1) Mixing sodium peroxycarbonate and caprylin-caprin to form a mixture A, and then sticking and rolling the mixture A in edible sodium bicarbonate to enable the edible sodium bicarbonate to be attached to the surface of the mixture A as much as possible to form a mixture B, packaging the mixture B through a first water-soluble film, and filling the edible sodium bicarbonate which is not attached to the surface of the mixture A into the first water-soluble film;
(2) And uniformly mixing sodium citrate, sodium chloride and tea seed powder, and then doping the mixture with the first water-soluble film encapsulated with the mixture B to form a composition C, and encapsulating the composition C by the second water-soluble film.
Comparative example 1
The weight parts of the raw materials in comparative example 1 are: 27 parts of sodium peroxycarbonate, 10 parts of caprylin-caprin, 8 parts of edible baking soda, 15 parts of sodium citrate, 22 parts of sodium chloride and 26 parts of tea seed powder. The tea seed powder contains 15% of natural tea saponin by weight percentage. The same as in example 1, but without the first and second dissolution films.
The preparation method of the comparative example 1 is to mix the components together and stir the components uniformly.
Test example 1
Storage stability test: examples 1 to 3 and comparative example 1 were subjected to a storage stability test, and after 18 months of storage at normal temperature, the loss of sodium percarbonate content was measured, and the detergency and antibacterial properties of each group at the time of washing laundry were measured before the start of the experiment and after the end of the experiment, respectively. The test results are shown in table 1:
from the table above, the multifunctional ecological cleaning particles of the invention have good storage stability, strong detergency and strong sterilization performance.
The invention can be used for washing clothes, tableware, fixtures and household appliances.
The foregoing embodiments are merely examples of the present invention, and the scope of the present invention includes, but is not limited to, the forms and styles of the foregoing embodiments, and any suitable changes or modifications made by those skilled in the art, which are consistent with the claims of the present invention, shall fall within the scope of the present invention.
Claims (7)
1. A multifunctional ecological cleaning granule, which is characterized in that: the tea seed powder comprises a first water-soluble film, a second water-soluble film, sodium peroxycarbonate, caprylin-capric acid glyceride, edible sodium bicarbonate, sodium citrate, sodium chloride and tea seed powder, wherein the inner cavity of the first water-soluble film is coated with sodium peroxycarbonate, caprylin-capric acid glyceride and edible sodium bicarbonate, the second water-soluble film is sleeved outside the first water-soluble film, and sodium citrate, sodium chloride and tea seed powder are filled between the second water-soluble film and the first water-soluble film; the dissolution time of the second water-soluble film is N seconds, and the dissolution time of the first water-soluble film is M seconds, wherein N is less than M.
2. A multifunctional ecological cleaning granule according to claim 1, characterized in that: the weight portions of the raw materials are as follows: 20-35 parts of sodium peroxycarbonate, 8-12 parts of caprylin and caprin, 5-12 parts of edible baking soda, 10-20 parts of sodium citrate, 20-30 parts of sodium chloride and 20-30 parts of tea seed powder.
3. A multifunctional ecological cleaning granule according to claim 2, characterized in that: the weight portions of the raw materials are as follows: 27 parts of sodium peroxycarbonate, 10 parts of caprylin-caprin, 8 parts of edible baking soda, 15 parts of sodium citrate, 22 parts of sodium chloride and 26 parts of tea seed powder.
4. A multifunctional ecological cleaning granule according to any one of claims 1-3, characterized in that: the tea seed powder contains 12-18% of natural tea saponin by weight percentage.
5. A multifunctional ecological cleaning granule according to any one of claims 1-3, characterized in that: the inner diameter of the second water-soluble film is 0.5-0.8cm, and the inner diameter of the first water-soluble film is 0.2-0.3cm.
6. A multifunctional ecological cleaning granule according to any one of claims 1-3, characterized in that: the second water-soluble film has an inner diameter of 30-90 seconds, and the first water-soluble film has an inner diameter of 300-600 seconds.
7. A method for preparing a multifunctional ecological cleaning granule according to any one of claims 1-3, characterized in that: the method comprises the following steps:
(1) Mixing sodium peroxycarbonate and caprylin-caprin to form a mixture A, sticking and rolling the mixture A in edible sodium bicarbonate to enable the edible sodium bicarbonate to be attached to the surface of the mixture A to form a mixture B, and packaging the mixture B through a first water-soluble film;
(2) And uniformly mixing sodium citrate, sodium chloride and tea seed powder, and then doping the mixture with the first water-soluble film encapsulated with the mixture B to form a composition C, and encapsulating the composition C by the second water-soluble film.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4344831A1 (en) * | 1993-12-29 | 1995-07-06 | Solvay Interox Gmbh | Stabilised coated alkali metal per:oxo salt |
| US5478488A (en) * | 1993-05-08 | 1995-12-26 | Solvay Interox Gmbh | Detergent composition containing alkali metal peroxysalt stabilized with alkali metal sulfate and chloride |
| CN109897744A (en) * | 2019-03-22 | 2019-06-18 | 东莞市宏裕生物科技有限公司 | A kind of biological enzyme cleaning particle and its manufacture craft |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5478488A (en) * | 1993-05-08 | 1995-12-26 | Solvay Interox Gmbh | Detergent composition containing alkali metal peroxysalt stabilized with alkali metal sulfate and chloride |
| DE4344831A1 (en) * | 1993-12-29 | 1995-07-06 | Solvay Interox Gmbh | Stabilised coated alkali metal per:oxo salt |
| CN109897744A (en) * | 2019-03-22 | 2019-06-18 | 东莞市宏裕生物科技有限公司 | A kind of biological enzyme cleaning particle and its manufacture craft |
Non-Patent Citations (1)
| Title |
|---|
| 新癸酸缩水甘油酯在粉末涂料用聚酯树脂中的应用;许国徽等;涂料工业;第51卷(第8期);17-24 * |
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