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CN115323782A - 一种耐磨抗起球面料及其制备方法 - Google Patents

一种耐磨抗起球面料及其制备方法 Download PDF

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CN115323782A
CN115323782A CN202211082072.6A CN202211082072A CN115323782A CN 115323782 A CN115323782 A CN 115323782A CN 202211082072 A CN202211082072 A CN 202211082072A CN 115323782 A CN115323782 A CN 115323782A
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parts
pilling
fabric
wear
temperature
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苏浩奇
徐星
徐林琴
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Zhejiang Haoyue Textile Technology Co ltd
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Zhejiang Haoyue Textile Technology Co ltd
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Abstract

本申请涉及家居纺织领域，具体公开了一种耐磨抗起球面料及其制备方法。耐磨抗起球面料包括涤纶混纺布，所述涤纶混纺布为涤纶纤维与棉纤维混纺织物，所述涤纶混纺布为平纹组织，所述涤纶混纺布是由染色后再经过抗起球整理液处理制得；抗起球整理液包括丙烯酸酯粘结剂、氯化镁、柔软剂、平平加、纳米二氧化硅。本申请的耐磨抗起球面料可用于沙发布，其具有耐磨性好、不易起球的优点。

Description

一种耐磨抗起球面料及其制备方法
技术领域
本申请涉及家居纺织领域，更具体地说，它涉及一种耐磨抗起球面料及其制备方法。
背景技术
沙发布是制造各种沙发所用到的纺织布料的统称，沙发布料包括:仿麻布、雪尼尔、提花布、复合布、植绒布等，其中，涤纶沙发布具有价格适中、耐磨性好、强度和弹力高、耐化学性好、不怕霉菌和蛀虫等优点，被广泛应用于制作涤纶沙发布中。
目前，在制作涤纶沙发布的过程中，通过依次对涤纶坯布进行退浆、碱减量、染色、定型等处理，从而获得外观美观、颜色鲜艳的涤纶沙发布。
针对上述中的相关技术，申请人认为涤纶沙发布虽然经过碱减量处理，使涤纶纤维的结晶度略有降低，但是由于纤维间的抱合力小、纤维的强度高，涤纶纤维依然容易滑出织物表面，从而在纤维表面形成小球后，小球相互摩擦，从而使涤纶沙发表面起球，在影响美观的同时，使使用者的舒适度降低。
发明内容
为解决相关技术中存在的涤纶沙发面料起球的问题，本申请提供一种耐磨抗起球面料及其制备方法。
本申请提供的一种耐磨抗起球面料及其制备方法采用如下的技术方案：
第一方面，本申请提供一种耐磨抗起球面料，采用如下的技术方案：
一种耐磨抗起球面料，包括涤纶混纺布，所述涤纶混纺布为涤纶纤维与棉纤维混纺织物，所述涤纶混纺布为平纹组织，所述涤纶混纺布是由染色后再经过抗起球整理液处理制得，所述抗起球整理液包括以下重量份原料制备而成：30-40份丙烯酸酯粘结剂、6-8份氯化镁、10-15份柔软剂、1-3份平平加、6-8份纳米二氧化硅。
通过采用上述技术方案，采用涤纶纤维和棉纤维混纺，通过利用涤纶纤维和棉纤维的机械性能不同的特点，从而改善涤纶沙发布易起球的特点，同时，由于涤纶混纺布为平纹组织，在经纬交织处的连结点较多，纤维不易移动和滑落，最后，通过抗起球整理液处理，提高了涤纶混纺布的抗起球效果。
优选的，所述丙烯酸酯粘结剂包括以下重量份原料制备而成：30-50份丙烯酸单体、2-6份碳酸氢钠、1-5份十二烷基硫酸钠、2-8份乳化剂OP-10、1-2份过硫酸铵、5-10份甲基丙烯酸缩水甘油酯、60-80份去离子水。
通过采用上述技术方案，通过采用乳液聚合的方式，获得热稳定性好、耐水和力学强度高的丙烯酸酯粘结剂，进一步的提高胶膜与涤纶混纺布的粘结性能。
优选的，所述丙烯酸单体包括丙烯酸丁酯、甲基丙烯酸甲酯、丙烯酸和丙烯酸羟丙酯中的一种或多种。
通过采用上述技术方案，通过以丙烯酸为单体进行共聚，便于将羧基基团引入丙烯酸酯大分子链中，同时，通过羧基与甲基丙烯酸缩水甘油酯中环氧基团发生开环交联反应，在形成体型大分子的同时，又具有很大的极性，便于与织物表面的羟基形成氢键结构，进而提高了织物表面形成涂层的稳定性。
优选的，所述丙烯酸粘结剂的制备，包括以下步骤：将碳酸氢钠、十二烷基硫酸钠、乳化剂OP-10、甲基丙烯酸缩水甘油酯和去离子水混合均匀，搅拌并控制反应温度在70-80℃，加入1/5-1/4的丙烯酸单体，搅拌2-4min，接着加入1/3的过硫酸铵，10min后加入剩余的丙烯酸单体和过硫酸铵，保温30min，冷却至室温，加入氨水调节PH为7-8。
通过采用上述技术方案，通过使丙烯酸单体过硫酸铵分批加入，提高了丙烯酸乳液的稳定性，降低出现体系黏度过大或出现乳液局部不均匀的状态。
第二方面，本申请提供一种耐磨抗起球面料的制备方法，采用如下的技术方案：一种耐磨抗起球面料的制备方法，包括包括以下步骤：
S1、前处理；
S2、预定型；
S3、染色前处理；
S3.1、将步骤S2中预定型的涤纶混纺布浸渍于10-20g/L的蔗糖脂肪酸酯处理液中，调节温度为为130-140℃、浴比为1:30，浸渍时间为40-50min，降低温度至30-40℃，保温20-30min；
S3.2、清洗、烘干；
S4、染色；
S5、后处理；
S6、定型。
通过采用上述技术方案，由于涤纶混纺布中的涤纶纤维的表面不含极性集团，染料不易上染于涤纶纤维的表面，因此，需要通过对涤纶纤维进行表面处理，本申请中，通过采用蔗糖脂肪酸酯对涤纶纤维进行表面处理，使染料能够吸附于涤纶纤维表面，提高了上染效率，同时，相较于碱减量处理涤纶纤维，在不使涤纶纤维的结构强度下降的同时，还具有较好的上染效率。
优选的，步骤S1前处理，包括以下步骤：
S1.1、对涤纶混纺布进行烧毛处理，火口采用一正一反，烧毛温度为230-240℃，车速为130m/min；
S1.2、对烧毛后的涤纶混纺布进行精炼处理，将涤纶混纺布浸扎于精炼液中，精炼液包括1-2g/L的十二烷基磺酸钠水溶液、1-2g/L的烧碱、0.5-1g/L过氧化氢、精炼剂CL-91、0.1-0.3g/L的水玻璃，浴比为1:50，洗涤温度为50-60℃，洗涤时间为30-40min，精炼液处理后，清水冲洗、烘干。
通过采用上述技术方案，通过采用烧毛热处理过程，赋予涤纶混纺布一定的身骨和弹性，并改善织物起毛、起球的状况，接着通过对涤纶混纺布进行精炼处理，从而在涤纶混纺布的表面起到了轻微的剥皮效果，提高了抗起毛、抗起球的效果。
优选的，步骤S4中染色的染液包括4-8份分散黄E-3RL、0.1-2份匀染剂、0.1-0.5防泳移剂RG-SDV、0.5-2份渗透剂JFC、1-3份络合剂EDTA四钠、2-4份冰醋酸、2-4份平滑剂ET。
通过采用上述技术方案，通过调节染色过程中的染液配方，使其制备的染液的染色效果更好，降低了染色不均匀和产生色块的可能性。
优选的，所述匀染剂包括匀染剂JS-603和分散匀染剂GS中的一种或多种。
通过采用上述技术方案，匀染剂JS-603具有很强的分散性，同时具有优异的缓染性，有效的降低了染色过程中产生色花，同时，匀染剂JS-603和分散匀染剂GS具有良好的配伍性，两者配合使用进一步的提高匀染效果。
优选的，步骤S4染色，包括以下步骤：
S4.1、将步骤S3染色前处理的涤纶混纺布浸入染液中进行染色，两浸两轧，扎液率为80％，染液PH为4-6，浴比为1:20，染色起始温度为40℃，以2℃/min的速度升高温度至80℃，接着以1.5℃/min的速度升高温度至110℃，然后以1℃/min的速度升高温度至130℃，在130℃保温染色30-40min,最后以3℃/min降低温度至80℃，取出；
S4.2、清洗步骤S4.1中染色后的面料本体坯布。
通过采用上述技术方案，通过调整染色过程中的温度和上染速度，降低了分散染料上染效率慢，容易产生色块和染色不均匀的现象。
优选的，步骤S5后处理，包括以下步骤：
S5.1、将步骤S4染色后的涤纶混纺布浸渍于抗起球整理液中，处理温度为40-50℃，处理时间为10-20min，浴比为1:20；
S5.2、用1-2g/L的十二烷基磺酸钠水溶液清洗步骤S5.1中的涤纶混纺布，清水冲洗、烘干。
通过采用上述技术方案，通过采用抗起球整理液处理，在涤纶混纺布的表面形成一层抗起球胶膜，降低了涤纶混纺布起球的可能性。
综上所述，本申请具有以下有益效果：
1.由于本申请通过采用抗起球整理液对涤纶混纺布进行处理，使其在涤纶混纺布的表面形成抗起球膜，同时由于涤纶混纺布为平纹组织，连结点较多，涤纶纤维不易滑出，进而降低了涤纶混纺布起球的可能性；
2.通过采用蔗糖脂肪酸酯对涤纶混纺布进行表面处理，便于后续进行染色处理的同时，不会使涤纶纤维的强度下降，同时，采用蔗糖脂肪酸酯对涤纶进行处理，污染较小，较为环保。
具体实施方式
原料和/或中间体的制备例
纳米二氧化硅选用纳米级二氧化硅粉M-5；
柔软剂选用型号为RX-62柔软平蓬松剂；
制备例
制备例1，丙烯酸胶粘剂的制备，包括以下步骤：
将0.4kg碳酸氢钠、0.3kg十二烷基硫酸钠、0.4kg乳化剂OP-10、0.8kg甲基丙烯酸缩水甘油酯和7kg去离子水混合均匀，搅拌并控制反应温度在75℃，加入1/4的丙烯酸单体，即，加入1kg丙烯酸单体，其中，丙烯酸单体采用2kg丙烯酸丁酯、1kg甲基丙烯酸甲酯、0.5kg丙烯酸和0.5kg丙烯酸羟丙酯，搅拌3min，接着加入1/3的过硫酸铵，即，0.15kg过硫酸铵，10min后加入剩余的丙烯酸单体和过硫酸铵，保温30min，冷却至室温，加入氨水调节PH为7.5，得丙烯酸酯胶粘剂。
实施例
实施例1
一种耐磨抗起球面料，包括涤纶混纺布，涤纶混纺布为涤纶纤维与棉纤维混纺织物，且涤纶混纺布为平纹组织。
耐磨抗起球面料的制备方法，包括以下步骤：
S1、前处理；
S1.1、对涤纶混纺布进行烧毛处理，火口采用一正一反，烧毛温度为230℃，车速为130m/min；
S1.2、对烧毛后的涤纶混纺布进行精炼处理，将涤纶混纺布浸扎于精炼液中，精炼液包括2g/L的十二烷基磺酸钠水溶液、2g/L的烧碱、0.5g/L过氧化氢、精炼剂CL-91、0.3g/L的水玻璃，浴比为1:50，洗涤温度为60℃，洗涤时间为40min，精炼液处理后，清水冲洗、烘干；
S2、预定型；将步骤S1.1前处理的涤纶混纺布送至定形机，预定型的温度为190℃，时间为30s；
S3、染色前处理；
S3.1、将步骤S2中预定型的涤纶混纺布浸渍于20g/L的蔗糖脂肪酸酯处理液中，调节温度为为140℃、浴比为1:30，浸渍时间为50min，降低温度至40℃，保温30min；
S3.2、用1g/L的十二烷基磺酸钠水溶液清洗步骤S3.1中的面料本体坯布，接着用清水冲洗、60℃烘干；
S4、染色；
S4.1、将步骤S3染色前处理的涤纶混纺布浸入染液中进行染色，两浸两轧，扎液率为80％，染液PH为5，浴比为1:20，染液包括0.6kg分散黄E-3RL、0.1kg匀染剂、0.03kg防泳移剂RG-SDV、0.1kg份渗透剂JFC、0.2kg份络合剂EDTA四钠、0.2份冰醋酸、0.3份平滑剂ET，其中匀染剂包括0.05kg匀染剂JS-603和0.05kg分散匀染剂GS；
染色起始温度为40℃，以2℃/min的速度升高温度至80℃，接着以1.5℃/min的速度升高温度至110℃，然后以1℃/min的速度升高温度至130℃，在130℃保温染色30-40min,最后以3℃/min降低温度至80℃，取出；
S4.2、清洗，将步骤S4.1所制备的面料本体坯布浸渍于清洗液中，清洗液包括2g/L的氢氧化钠溶液和2g/L的保险粉，接着用80℃水洗15min，最后用冷水洗，烘干；
S5、后处理；
S5.1、将步骤S4染色后的涤纶混纺布浸渍于抗起球整理液中，抗起球整理由制备例1中的3kg丙烯酸酯粘结剂、0.6kg氯化镁、1.5kg柔软剂、0.2kg平平加、0.6kg纳米二氧化硅组成；处理温度为40-50℃，处理时间为10-20min，浴比为1:20；
S5.2、用1-2g/L的十二烷基磺酸钠水溶液清洗步骤S5.1中的涤纶混纺布，清水冲洗、烘干；
S6、定型，将涤纶沙发布送入热定型机内进行热定型处理，定型温度为185-190℃，定形时间为20-90s，冷却温度为40℃，得成品涤纶沙发布。
实施例2，实施例2与实施例1的不同之处在于：步骤S5.1中所采用的丙烯酸酯粘结剂为4kg。
实施例3，实施例3与实施例2的不同之处在于：步骤S5.1中所采用的丙烯酸酯粘结剂为3.5kg。
实施例4，实施例4与实施例3的不同之处在于：步骤S5.1中所采用的纳米二氧化硅为0.8kg。
实施例5，实施例5与实施例4的不同之处在于：步骤S5.1中所采用的纳米二氧化硅为0.7kg。
实施例6，实施例6与实施例3的不同之处在于：步骤S3.1为碱减量处理。
对比例
对比例1，对比例1与实施例1的不同之处在于：步骤S5.1中所采用的丙烯酸酯粘结剂为2kg。
对比例2，对比例2与实施例1的不同之处在于：步骤S5.1中所采用的丙烯酸酯粘结剂为6kg。
对比例3，对比例3与实施例3的不同之处在于：步骤S5.1中所采用的纳米二氧化硅为0.4kg。
对比例4，对比例4与实施例3的不同之处在于：步骤S5.1中所采用的纳米二氧化硅为1kg。
对比例5，对比例5与实施例1的不同之处在于：耐磨抗起球面料的制备方法不含步骤S5后处理。
性能检测试验
耐皂洗色牢度测试：按照《纺织品色牢度试验耐皂洗色牢度》，对涤纶沙发布进行色牢度测试。
抗起球测试:采用Y561型织物起球仪，按照GB5433-85《织物起球试验方法》操作。
检测方法/试验方法
表1是本申请实施例的性能测试数据
Figure BDA0003833727240000061
Figure BDA0003833727240000071
表2是本申请对比例的性能测试数据
Figure BDA0003833727240000072
结合实施例1-3和对比例1-2并结合表1、2可以看出，当丙烯酸酯粘结剂的含量在30-40份之间时，效果较佳，尤其是当丙烯酸酯含量为35份时，效果最佳，而当丙烯酸酯胶粘剂含量继续升高时，其抗起球效果和断裂强度并无明显变化。
结合实施例3-5并结合对比例3、4可以看出，当纳米二氧化硅的含量为6-8份时，其效果较佳，尤其是纳米二氧化硅的含量为7份时，其效果最佳，主要是由于纳米二氧化硅的加入，其均匀的分布于胶膜内，且部分位于胶膜表面，增大了相邻的纤维间的摩擦，进而提高了抗起球性能。
结合实施例5和实施例6并结合表1、2可以看出，相较于碱减量处理，虽然能提高涤纶混纺布的抗起球性能，但是会使强度下降。
结合实施例1和对比例5可以看出，通过对涤纶混纺布进行抗起球整理液处理，其抗起球性能和结构强度均有所提高。
本具体实施例仅仅是对本申请的解释，其并不是对本申请的限制，本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改，但只要在本申请的权利要求范围内都受到专利法的保护。

Claims (10)

1.一种耐磨抗起球面料，包括涤纶混纺布，其特征在于：所述涤纶混纺布为涤纶纤维与棉纤维混纺织物，所述涤纶混纺布为平纹组织，所述涤纶混纺布是由染色后再经过抗起球整理液处理制得，所述抗起球整理液包括以下重量份原料制备而成：30-40份丙烯酸酯粘结剂、6-8份氯化镁、10-15份柔软剂、1-3份平平加、6-8份纳米二氧化硅。
2.根据权利要求1所述的一种耐磨抗起球面料，其特征在于：所述丙烯酸酯粘结剂包括以下重量份原料制备而成：30-50份丙烯酸单体、2-6份碳酸氢钠、1-5份十二烷基硫酸钠、2-8份乳化剂OP-10、1-2份过硫酸铵、5-10份甲基丙烯酸缩水甘油酯、60-80份去离子水。
3.根据权利要求2所述的一种耐磨抗起球面料，其特征在于：所述丙烯酸单体包括丙烯酸丁酯、甲基丙烯酸甲酯、丙烯酸和丙烯酸羟丙酯中的一种或多种。
4.根据权利要求3所述的一种耐磨抗起球面料，其特征在于：所述丙烯酸粘结剂的制备，包括以下步骤：将碳酸氢钠、十二烷基硫酸钠、乳化剂OP-10、甲基丙烯酸缩水甘油酯和去离子水混合均匀，搅拌并控制反应温度在70-80℃，加入1/5-1/4的丙烯酸单体，搅拌2-4min，接着加入1/3的过硫酸铵，10min后加入剩余的丙烯酸单体和过硫酸铵，保温30min，冷却至室温，加入氨水调节PH为7-8。
5.一种根据权利要求1-4任一所述的耐磨抗起球面料的制备方法，其特征在于，包括以下步骤：
S1、前处理；
S2、预定型；
S3、染色前处理；
S3.1、将步骤S2中预定型的涤纶混纺布浸渍于10-20g/L的蔗糖脂肪酸酯处理液中，调节温度为为130-140℃、浴比为1:30，浸渍时间为40-50min，降低温度至30-40℃，保温20-30min；
S3.2、清洗、烘干；
S4、染色；
S5、后处理；
S6、定型。
6.根据权利要求5所述的一种耐磨抗起球面料的制备方法，其特征在于：步骤S1前处理，包括以下步骤：
S1.1、对涤纶混纺布进行烧毛处理，火口采用一正一反，烧毛温度为230-240℃，车速为130m/min；
S1.2、对烧毛后的涤纶混纺布进行精炼处理，将涤纶混纺布浸扎于精炼液中，精炼液包括1-2g/L的十二烷基磺酸钠水溶液、1-2g/L的烧碱、0.5-1g/L过氧化氢、精炼剂CL-91、0.1-0.3g/L的水玻璃，浴比为1:50，洗涤温度为50-60℃，洗涤时间为30-40min，精炼液处理后，清水冲洗、烘干。
7.根据权利要求5所述的一种耐磨抗起球面料的制备方法，其特征在于：步骤S4中染色的染液包括4-8份分散黄E-3RL、0.1-2份匀染剂、0.1-0.5防泳移剂RG-SDV、0.5-2份渗透剂JFC、1-3份络合剂EDTA四钠、2-4份冰醋酸、2-4份平滑剂ET。
8.根据权利要求7所述的一种耐磨抗起球面料的制备方法，其特征在于：所述匀染剂包括匀染剂JS-603和分散匀染剂GS中的一种或多种。
9.根据权利要求7所述的一种耐磨抗起球面料的制备方法，其特征在于，步骤S4染色，包括以下步骤：
S4.1、将步骤S3染色前处理的涤纶混纺布浸入染液中进行染色，两浸两轧，扎液率为80%，染液PH为4-6，浴比为1:20，染色起始温度为40℃，以2℃/min的速度升高温度至80℃，接着以1.5℃/min的速度升高温度至110℃，然后以1℃/min的速度升高温度至130℃，在130℃保温染色30-40min,最后以3℃/min降低温度至80℃，取出；
S4.2、清洗步骤S4.1中染色后的面料本体坯布。
10.根据权利要求5所述的一种耐磨抗起球面料的制备方法，其特征在于，步骤S5后处理，包括以下步骤：
S5.1、将步骤S4染色后的涤纶混纺布浸渍于抗起球整理液中，处理温度为40-50℃，处理时间为10-20min，浴比为1:20；
S5.2、用1-2g/L的十二烷基磺酸钠水溶液清洗步骤S5.1中的涤纶混纺布，清水冲洗、烘干。
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