CN115217036A - Construction process for cable-stayed bridge panel of steel-concrete composite beam capable of reducing cracking - Google Patents
Construction process for cable-stayed bridge panel of steel-concrete composite beam capable of reducing cracking Download PDFInfo
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- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
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Classifications
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D21/00—Methods or apparatus specially adapted for erecting or assembling bridges
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D11/00—Suspension or cable-stayed bridges
- E01D11/04—Cable-stayed bridges
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D19/00—Structural or constructional details of bridges
- E01D19/12—Grating or flooring for bridges; Fastening railway sleepers or tracks to bridges
- E01D19/125—Grating or flooring for bridges
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D2101/00—Material constitution of bridges
- E01D2101/20—Concrete, stone or stone-like material
- E01D2101/24—Concrete
- E01D2101/26—Concrete reinforced
- E01D2101/268—Composite concrete-metal
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Engineering & Computer Science (AREA)
- Structural Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
技术领域technical field
本申请涉及桥梁施工工艺的领域,尤其是涉及一种减少开裂的钢混组合梁斜拉桥面板施工工艺。The present application relates to the field of bridge construction techniques, in particular to a construction technique for a steel-concrete composite beam cable-stayed bridge deck that reduces cracking.
背景技术Background technique
钢混组合梁斜拉桥是将钢混组合主梁用许多拉索直接拉在桥塔上的一种桥梁,是由承压的塔、受拉的索和承弯的钢混组合梁组合起来的一种结构体系。The steel-concrete composite beam cable-stayed bridge is a kind of bridge in which the steel-concrete composite main girder is directly pulled on the bridge tower with many cables. a structural system.
桥面板是钢混组合梁斜拉桥中直接承受车辆轮压的承重结构。桥面板通常与钢混组合梁的梁肋和横隔板整体相连,是钢混组合梁截面的组成部分,桥面板将车辆荷载传给钢混组合梁,保证了钢混组合梁的整体作用。The bridge deck is the load-bearing structure of the steel-concrete composite beam cable-stayed bridge that directly bears the wheel pressure of the vehicle. The bridge deck is usually integrally connected with the beam rib and diaphragm of the steel-concrete composite beam, and is an integral part of the steel-concrete composite beam section. The bridge deck transmits the vehicle load to the steel-concrete composite beam, ensuring the overall function of the steel-concrete composite beam.
桥面板通常采用正交异性钢-混凝土组合结构,但混凝土易干缩开裂,导致混凝土与正交异性钢之间形成缝隙,降低了混凝土与正交异性钢之间的粘结强度,桥面板承重时混泥土与正交异性钢之间存在相对移动的趋势,使桥面板稳定性降低,导致正交异性钢-混凝土组合桥面板易开裂。The bridge deck usually adopts an orthotropic steel-concrete composite structure, but the concrete is prone to shrinkage and cracking, resulting in a gap between the concrete and the orthotropic steel, which reduces the bond strength between the concrete and the orthotropic steel, and the bridge deck bears the load. There is a relative movement trend between the concrete and the orthotropic steel, which reduces the stability of the bridge deck and causes the orthotropic steel-concrete composite bridge deck to crack easily.
发明内容SUMMARY OF THE INVENTION
为了减小正交异性钢-混凝土组合桥面板开裂的概率,本申请提供一种减少开裂的钢混组合梁斜拉桥面板施工工艺。In order to reduce the probability of cracking of an orthotropic steel-concrete composite bridge deck, the present application provides a construction process for a steel-concrete composite beam cable-stayed bridge deck that reduces cracking.
本申请提供的一种减少开裂的钢混组合梁斜拉桥面板施工工艺采用如下的技术方案:一种减少开裂的钢混组合梁斜拉桥面板施工工艺包括以下步骤:The construction technology of a steel-concrete composite girder cable-stayed bridge deck with reduced cracking provided by the application adopts the following technical scheme: a construction technology of a steel-concrete composite girder cable-stayed bridge deck with reduced cracking includes the following steps:
S1、正交异性钢表面喷涂表面处理剂;S1. Surface treatment agent is sprayed on the surface of orthotropic steel;
S2、正交异性钢安装,桥面清理及验收;S2, orthotropic steel installation, bridge deck cleaning and acceptance;
S3、测量放样;S3. Measure and stake out;
S4、剪力钉安装,钢筋绑接;S4, shear nail installation, steel bar binding;
S5、钢筋喷涂表面处理剂;S5. Rebar spraying surface treatment agent;
S6、热蒸汽喷洒,混凝土浇筑,热蒸汽喷洒不超过混凝土浇筑前10min;S6. Hot steam spraying, concrete pouring, hot steam spraying shall not exceed 10min before concrete pouring;
S7、收面及养护;S7, surface collection and maintenance;
所述混凝土包括以下重量份的原料:硅酸盐水泥192~360份;减水剂3~5份;拌合水140~150份;粉料64~120份;粗集料720~1100份;细集料420~790份;涂层钢纤维38~146份;膨胀填料18~36份;The concrete comprises the following raw materials in parts by weight: 192-360 parts of Portland cement; 3-5 parts of water reducing agent; 140-150 parts of mixing water; 64-120 parts of powder; 720-1100 parts of coarse aggregate; 420-790 parts of fine aggregates; 38-146 parts of coated steel fibers; 18-36 parts of expanded fillers;
所述膨胀填料包括膨胀剂和改性膨润土,所述膨胀剂和改性膨润土的重量比为(2~8):5;所述表面处理剂包括α—氰基丙烯酸乙酯、高聚物和钕铁硼粉,所述α—氰基丙烯酸乙酯、聚丙烯酸酯和钕铁硼粉的重量比为10:(2~6):1。The expansion filler includes an expansion agent and modified bentonite, and the weight ratio of the expansion agent to the modified bentonite is (2-8):5; the surface treatment agent includes α-cyanoacrylate, high polymer and NdFeB powder, the weight ratio of the α-cyanoacrylate, polyacrylate and NdFeB powder is 10:(2-6):1.
通过采用上述技术方案,将表面处理剂涂覆在正交异性钢表面,与α—氰基丙烯酸乙酯、高聚物混合均匀的钕铁硼粉在磁性作用下吸附在正交异性钢表面,从而提高了表面处理剂与正交异性钢的粘结强度;混凝土浇筑前,蒸汽处理使正交异性钢表面的α—氰基丙烯酸乙酯和高聚物软化,混凝土浇筑后,混凝土中的改性膨润土与氰化有机物α—氰基丙烯酸乙酯相互吸附,且改性膨润土与高聚物粘合,从而提高了膨胀填料与正交异性钢的粘结强度;在混凝土养护期间,膨胀剂发生膨胀,填充混凝土与正交异性钢之间的缝隙,提高了正交异性钢与混凝土的粘结强度,同时提高了混凝土的自密性,减小了混凝土干缩开裂的概率,从而减小正交异性钢-混凝土组合桥面板开裂的概率。By adopting the above technical scheme, the surface treatment agent is coated on the surface of the orthotropic steel, and the NdFeB powder evenly mixed with α-ethyl cyanoacrylate and high polymer is adsorbed on the surface of the orthotropic steel under the magnetic action, Thus, the bonding strength between the surface treatment agent and the orthotropic steel is improved; before the concrete is poured, the steam treatment softens the α-ethyl cyanoacrylate and polymer on the surface of the orthotropic steel. Bentonite and cyanide organic α-ethyl cyanoacrylate are adsorbed to each other, and the modified bentonite is bonded to the polymer, thereby improving the bonding strength of the expansion filler and the orthotropic steel; during the curing of the concrete, the expansion agent occurs. Expansion, filling the gap between concrete and orthotropic steel, improving the bonding strength of orthotropic steel and concrete, improving the self-compactness of concrete, reducing the probability of drying shrinkage cracking of concrete, thereby reducing the positive Probability of cracking in the deck of a composite steel-concrete composite bridge.
可选的,所述高聚物为聚丙烯酸酯。Optionally, the high polymer is polyacrylate.
通过采用上述技术方案,聚丙烯酸酯与改性膨润土形成三维网状结构,从而提高了混凝土与正交异性钢之间的粘结强度;聚丙烯酸酯在正交异性钢表面形成防水膜,阻碍水分子渗入混凝土与正交异性钢之间,从而减小了混凝土与正交异性钢剥离的概率,进而减小了桥面板的开裂的概率。By adopting the above technical solution, polyacrylate and modified bentonite form a three-dimensional network structure, thereby improving the bonding strength between concrete and orthotropic steel; polyacrylate forms a waterproof film on the surface of orthotropic steel, preventing water The molecules penetrate between the concrete and the orthotropic steel, thereby reducing the probability of peeling off the concrete and the orthotropic steel, thereby reducing the probability of cracking of the bridge deck.
可选的,所述膨胀剂包括二灰土、矾土和石膏粉,所述二灰土、矾土和石膏粉的重量比为4:1:3。Optionally, the expansion agent includes di-lime, bauxite and gypsum powder, and the weight ratio of the di-lime soil, bauxite and gypsum powder is 4:1:3.
通过采用上述技术方案,在水化热作用下,二灰土中的氧化钙、粉煤灰和矾土中的三氧化二铝以及石膏粉中的硫酸钙反应生成硫铝酸钙晶体,硫铝酸钙晶体填充混凝土中的孔隙,从而减小了混凝土干缩的概率,使桥面板不易形成早期裂缝。By adopting the above technical scheme, under the action of the heat of hydration, calcium oxide in the lime soil, fly ash, aluminum oxide in the bauxite and calcium sulfate in the gypsum powder react to form calcium sulfoaluminate crystals, and sulfoaluminate Calcium crystals fill the pores in the concrete, thereby reducing the probability of concrete shrinkage, making it difficult for the bridge deck to form early cracks.
可选的,所述改性膨润土包括钙基膨润土和鼠李糖,所述钙基膨润土与鼠李糖的重量比为4:1。Optionally, the modified bentonite includes calcium-based bentonite and rhamnose, and the weight ratio of the calcium-based bentonite to rhamnose is 4:1.
通过采用上述技术方案,鼠李糖负载在钙基膨润土上,便于改性膨润土在电荷作用下与含金属阳离子的物质相互吸附;鼠李糖与金属离子形成环状结构络合物,提高了钙基膨润土对二灰土、矾土和石膏粉的吸附强度,便于钙基膨润土将膨胀剂携带至正交异性钢表面,在正交异性钢与混凝土界面形成硫铝酸钙晶体易填充缝隙,从而减小了正交异性钢与混凝土相互剥离的概率,从而减小了桥面板开裂的概率。By adopting the above technical solution, the rhamnose is loaded on the calcium-based bentonite, which facilitates the mutual adsorption of the modified bentonite and the metal cation-containing substance under the action of electric charge; the rhamnose and the metal ion form a cyclic structure complex, which increases the calcium The adsorption strength of base bentonite to dilime, bauxite and gypsum powder is convenient for calcium base bentonite to carry expansion agent to the surface of orthotropic steel, and calcium sulfoaluminate crystals are formed at the interface of orthotropic steel and concrete to easily fill the gap, thereby reducing the problem. The probability of orthotropic steel and concrete peeling off each other is reduced, thereby reducing the probability of bridge deck cracking.
可选的,所述改性膨润土的制备步骤包括:钙基膨润土焙烧;鼠李糖加热至熔融,加入焙烧后的钙基膨润土,搅拌均匀,冷却干燥造粉得到改性膨润土。Optionally, the preparation steps of the modified bentonite include: roasting the calcium-based bentonite; heating the rhamnose to melting, adding the roasted calcium-based bentonite, stirring evenly, cooling, drying and pulverizing to obtain the modified bentonite.
通过采用上述技术方案,钙基膨润土焙烧提高了比表面积,便于负载鼠李糖;熔融的鼠李糖沾附在钙基膨润土颗粒的表面和内部孔隙中,减小了混凝土搅拌期间鼠李糖与钙基膨润土颗粒分离的概率,从而便于改性膨润土负载二灰土、矾土和石膏粉,同时提高了改性膨润土与正交异性钢的粘结强度。By adopting the above technical solution, the calcium-based bentonite roasting increases the specific surface area, which is convenient for loading rhamnose; the molten rhamnose adheres to the surface and internal pores of the calcium-based bentonite particles, reducing the amount of rhamnose and rhamnose during concrete mixing. The probability of separation of calcium-based bentonite particles is convenient for the modified bentonite to be loaded with di-lime, bauxite and gypsum powder, and at the same time, the bonding strength of the modified bentonite and orthotropic steel is improved.
可选的,所述涂层钢纤维包括波形钢纤维和涂覆液,所述涂覆液涂覆于波形钢纤维的外表面。Optionally, the coated steel fibers include corrugated steel fibers and a coating liquid, and the coating liquid is coated on the outer surface of the corrugated steel fibers.
通过采用上述技术方案,相较于平直性钢纤维,波形钢纤维与水泥颗粒等接触面积增加,在混凝土收缩时,波形钢纤维与水泥浆料剥离的概率降低,从而减小了混凝土中产生孔隙的概率,进而减小了桥面板开裂的概率。By adopting the above technical solution, compared with the straight steel fiber, the contact area between the corrugated steel fiber and the cement particles is increased, and the probability of the corrugated steel fiber and the cement slurry peeling off when the concrete shrinks is reduced, thereby reducing the generation of the concrete. The probability of porosity, thereby reducing the probability of bridge deck cracking.
可选的,所述涂覆液包括黑钨矿粉和乙烯基硅油,所述黑钨矿粉和乙烯基硅油的重量比为(2~5):13。Optionally, the coating liquid includes wolframite powder and vinyl silicone oil, and the weight ratio of wolframite powder and vinyl silicone oil is (2-5):13.
通过采用上述技术方案,二灰土、矾土、石膏粉和水泥颗粒作用时,置换出钠离子与水分反应易形成碱性氢氧化钠,此外雨水、滑雪剂等携带的碱性物质渗入混凝土中,增加了波形钢纤维和正交异性钢被腐蚀的概率;黑钨矿粉被乙烯基硅油沾附在波形钢纤维的表面,阻碍碱性物质侵蚀波形钢纤维,从而提高了桥面板耐碱腐蚀能力,延长了桥面板的使用寿命。By adopting the above technical solution, when the limestone, bauxite, gypsum powder and cement particles act, the sodium ions are replaced and the water reacts to easily form alkaline sodium hydroxide. Increases the probability of corrugated steel fibers and orthotropic steel being corroded; wolframite powder is adhered to the surface of corrugated steel fibers by vinyl silicone oil, preventing alkaline substances from eroding corrugated steel fibers, thereby improving the alkali corrosion resistance of bridge decks , extending the service life of the bridge deck.
可选的,S6中的养护方式采用蒸汽养护。Optionally, the curing method in S6 adopts steam curing.
通过采用上述技术方案,在热蒸汽作用下,黑钨矿粉与氢氧化钠水溶液反应生成粗钨酸钠,降低了混凝土中游离钠离子含量,减低了正交异性钢-混凝土结构被碱腐蚀的概率,从而提高了桥面板的抗腐蚀性,桥面板开裂的概率降低。By adopting the above technical scheme, under the action of hot steam, wolframite powder reacts with sodium hydroxide aqueous solution to generate crude sodium tungstate, which reduces the content of free sodium ions in concrete and reduces the corrosion of orthotropic steel-concrete structure by alkali. Therefore, the corrosion resistance of the bridge deck is improved, and the probability of cracking of the bridge deck is reduced.
可选的,S5混凝土浇筑过程中采用插入式振动棒分层振捣。Optionally, insert vibrating rods are used to vibrate in layers during the concrete pouring process of S5.
通过采用上述技术方案,振动棒分层振捣促进混凝土流动,减小了混凝土中的孔隙率,提高了混凝土的密度,从而减小了混凝土收缩产生裂缝的概率,桥面板的抗压强度提高,桥面板开裂的概率降低。By adopting the above technical scheme, the vibrating rods vibrate in layers to promote the flow of concrete, reduce the porosity in the concrete, increase the density of the concrete, thereby reducing the probability of cracks caused by the shrinkage of the concrete, and the compressive strength of the bridge deck is improved. The probability of bridge deck cracking is reduced.
综上所述,本申请包括以下至少一种有益技术效果:To sum up, the present application includes at least one of the following beneficial technical effects:
1.将表面处理剂涂覆在正交异性钢表面,与α—氰基丙烯酸乙酯、高聚物混合均匀的钕铁硼粉在磁性作用下吸附在正交异性钢表面,从而提高了表面处理剂与正交异性钢的粘结强度,进而减小正交异性钢-混凝土组合桥面板开裂的概率;1. Coat the surface treatment agent on the surface of the orthotropic steel, and the NdFeB powder evenly mixed with α-cyanoacrylate and high polymer is adsorbed on the surface of the orthotropic steel under the magnetic action, thereby improving the surface quality. The bonding strength between the treatment agent and the orthotropic steel, thereby reducing the probability of cracking of the orthotropic steel-concrete composite deck;
2.混凝土浇筑前,蒸汽处理使正交异性钢表面的α—氰基丙烯酸乙酯和高聚物软化,混凝土浇筑后,混凝土中的改性膨润土与氰化有机物α—氰基丙烯酸乙酯相互吸附,且改性膨润土与聚丙烯酸酯形成三维网状粘结结构,从而提高了膨胀填料与正交异性钢的粘结强度;在混凝土养护时,膨胀剂发生膨胀,填充混凝土与正交异性钢之间的缝隙,提高了正交异性钢与混凝土的粘结强度,从而减小正交异性钢-混凝土组合桥面板开裂的概率;2. Before the concrete is poured, steam treatment softens the α-ethyl cyanoacrylate and polymer on the surface of the orthotropic steel. After the concrete is poured, the modified bentonite in the concrete and the cyanide organic α-cyanoacrylate interact with each other. adsorption, and the modified bentonite and polyacrylate form a three-dimensional network bonding structure, thereby improving the bonding strength of the expansion filler and the orthotropic steel; when the concrete is cured, the expansion agent expands, filling the concrete and the orthotropic steel. The gap between the orthotropic steel and concrete improves the bond strength of the orthotropic steel and concrete, thereby reducing the probability of cracking of the orthotropic steel-concrete composite deck;
3.在水化热作用下,二灰土中的氧化钙、粉煤灰与矾土中的三氧化二铝以及石膏粉中的硫酸钙反应生成硫铝酸钙晶体,硫铝酸钙晶体填充混凝土中的孔隙,从而减小了混凝土干缩的概率,使桥面板不易形成早期裂缝;3. Under the action of hydration heat, calcium oxide and fly ash in lime soil react with aluminum oxide in bauxite and calcium sulfate in gypsum powder to form calcium sulfoaluminate crystals, and calcium sulfoaluminate crystals fill concrete Therefore, the probability of drying shrinkage of concrete is reduced, so that the bridge deck is not easy to form early cracks;
4.鼠李糖负载在钙基膨润土上,便于改性膨润土在电荷作用下与含金属阳离子的物质相互吸附;鼠李糖与金属离子形成环状结构络合物,提高了钙基膨润土对二灰土、矾土和石膏粉的吸附强度,便于钙基膨润土将膨胀剂携带至正交异性钢表面,在正交异性钢与混凝土界面形成硫铝酸钙晶体,从而减小了正交异性钢与混凝土相互剥离的概率,从而减小了桥面板开裂的概率;4. Rhamnose is loaded on calcium-based bentonite, which facilitates the mutual adsorption of modified bentonite and metal cation-containing substances under the action of electric charge; The adsorption strength of lime soil, bauxite and gypsum powder is convenient for calcium-based bentonite to carry the expansion agent to the surface of orthotropic steel, and calcium sulfoaluminate crystals are formed at the interface between orthotropic steel and concrete, thereby reducing the amount of orthotropic steel and concrete. The probability of concrete peeling off each other, thereby reducing the probability of bridge deck cracking;
5.部分绝缘油与α—氰基丙烯酸乙酯接触,促进α—氰基丙烯酸乙酯软化,便于α—氰基丙烯酸乙酯与混凝土中的改性膨润土相互吸附,提高了混凝土与正交异性钢粘结强度。5. Part of the insulating oil is in contact with ethyl α-cyanoacrylate, which promotes the softening of ethyl α-cyanoacrylate, facilitates the mutual adsorption of ethyl α-cyanoacrylate and the modified bentonite in concrete, and improves the orthotropy between concrete and concrete. Steel bond strength.
附图说明Description of drawings
图1为本申请实施例中桥面板结构的示意图;1 is a schematic diagram of a bridge deck structure in an embodiment of the application;
图2为本申请实施例中剪力钉的整体结构示意图。FIG. 2 is a schematic diagram of the overall structure of the shear nail in the embodiment of the application.
附图标记说明:Description of reference numbers:
10、正交异性钢;11、异型钢板;12、面板;20、钢筋;30、剪力钉;31、螺纹柱;32、连接圆台;33、顶盖;40、混凝土层。10, orthotropic steel; 11, special-shaped steel plate; 12, panel; 20, steel bar; 30, shear nail; 31, threaded column;
具体实施方式Detailed ways
以下结合实施例、对比例和附图1~2对本申请作进一步详细说明。The present application will be further described in detail below with reference to the examples, comparative examples and accompanying drawings 1-2.
以下实施例中未注明具体条件者按照常规条件或制造商建议的条件进行,以下实施例中所用原料除特殊说明外均可来源于普通市售。Those without specific conditions in the following examples are carried out according to the conventional conditions or the conditions suggested by the manufacturer. The raw materials used in the following examples can be obtained from common commercial sources unless otherwise specified.
减水剂为聚羧酸减水剂;粉料为粉煤灰,粒度为325目,密度为2.1kg/m3;粗集料为碎石,密度为1500kg/m3,规格3~7mm;细集料为河砂,粒度为20~40目;波形钢纤维长度为10~15mm,长径比60±5;黑钨矿粉为黑钨矿石磨粉所得,粒度为400目,FeWO4含量大于80%;二灰土中石灰:粉煤灰:土的比例为10:20:70;矾土规格为120目,表观密度2.6kg/m3;石膏粉密度为2.32kg/m3;钙基膨润土粒度为325目,密度2.6g/cm3;鼠李糖分子量164.16,含量99%;钕铁硼粉粒度为400目,由广州新诺德传动部件有限提供。The water reducing agent is polycarboxylate water reducing agent; the powder is fly ash, the particle size is 325 mesh, and the density is 2.1kg/m 3 ; The fine aggregate is river sand, with a particle size of 20-40 mesh; the length of corrugated steel fiber is 10-15 mm, and the aspect ratio is 60±5; wolframite powder is obtained by grinding wolframite, with a particle size of 400 mesh and FeWO 4 content More than 80%; the ratio of lime: fly ash: soil in the lime soil is 10:20:70; the bauxite specification is 120 mesh, and the apparent density is 2.6kg/m 3 ; the density of gypsum powder is 2.32kg/m 3 ; calcium The particle size of the base bentonite is 325 meshes, the density is 2.6g/cm 3 ; the molecular weight of rhamnose is 164.16, and the content is 99%;
涂层钢纤维制备例Preparation example of coated steel fiber
制备例1Preparation Example 1
S1、将20kg黑钨矿粉与130kg乙烯基硅油混合均匀作为涂覆液;S1, mix 20kg wolframite powder and 130kg vinyl silicone oil uniformly as coating liquid;
S2、将150kg波形钢纤维在涂覆液中浸渍30min,后经40℃烘干,干燥固化后振荡分离成单纤维,即为涂层钢纤维。S2. Immerse 150kg of corrugated steel fibers in the coating solution for 30 minutes, then dry at 40°C, and then shake and separate into single fibers after drying and solidification, which are coated steel fibers.
制备例2Preparation Example 2
S1、将35kg黑钨矿粉与130kg乙烯基硅油混合均匀作为涂覆液;S1, mix 35kg wolframite powder and 130kg vinyl silicone oil uniformly as coating liquid;
S2、将150kg波形钢纤维在涂覆液中浸渍30min,后经40℃烘干,干燥固化后振荡分离成单纤维,即为涂层钢纤维。S2. Immerse 150kg of corrugated steel fibers in the coating solution for 30 minutes, then dry at 40°C, and then shake and separate into single fibers after drying and solidification, which are coated steel fibers.
制备例3Preparation Example 3
S1、将50kg黑钨矿粉与130kg乙烯基硅油混合均匀作为涂覆液;S1, mix 50kg wolframite powder and 130kg vinyl silicone oil uniformly as coating liquid;
S2、将150kg波形钢纤维在涂覆液中浸渍30min,后经40℃烘干,干燥固化后振荡分离成单纤维,即为涂层钢纤维。S2. Immerse 150kg of corrugated steel fibers in the coating solution for 30 minutes, then dry at 40°C, and then shake and separate into single fibers after drying and solidification, which are coated steel fibers.
制备例4Preparation Example 4
S1、取130kg乙烯基硅油混合均匀作为涂覆液;S1. Take 130kg of vinyl silicone oil and mix it uniformly as a coating solution;
S2、将150kg波形钢纤维在涂覆液中浸渍30min,后经40℃烘干,干燥固化后振荡分离成单纤维,即为涂层钢纤维。S2. Immerse 150kg of corrugated steel fibers in the coating solution for 30 minutes, then dry at 40°C, and then shake and separate into single fibers after drying and solidification, which are coated steel fibers.
膨胀填料制备例Expansion filler preparation example
制备例5Preparation Example 5
S1、将4kg二灰土、1kg矾土和3kg石膏粉混合均匀作为膨胀剂;S1, mix 4kg of limestone, 1kg of bauxite and 3kg of gypsum powder as expansion agent;
S2、将8kg钙基膨润土焙烧;将2kg鼠李糖加热至熔融,加入焙烧后的钙基膨润土,搅拌均匀,冷却干燥造粉得到改性膨润土;S2, 8kg calcium-based bentonite is roasted; 2kg of rhamnose is heated to melting, adds the calcium-based bentonite after roasting, stirs, and cools and drys powder to obtain modified bentonite;
S3、将膨胀剂和改性膨润土混合均匀作为膨胀填料。S3. Mix the expansion agent and the modified bentonite uniformly as the expansion filler.
制备例6Preparation Example 6
S1、将6kg二灰土、1.5kg矾土和4.5kg石膏粉混合均匀作为膨胀剂;S1, mix 6kg of limestone, 1.5kg of bauxite and 4.5kg of gypsum powder as expansion agent;
S2、将12kg钙基膨润土焙烧;将3kg鼠李糖加热至熔融,加入焙烧后的钙基膨润土,搅拌均匀,冷却干燥造粉得到改性膨润土;S2, 12kg calcium-based bentonite is roasted; 3kg of rhamnose is heated to melting, adds the calcium-based bentonite after roasting, stirs, and cools and drys powder to obtain modified bentonite;
S3、将膨胀剂和改性膨润土混合均匀作为膨胀填料。S3. Mix the expansion agent and the modified bentonite uniformly as the expansion filler.
制备例7Preparation Example 7
S1、将8kg二灰土、2kg矾土和6kg石膏粉混合均匀作为膨胀剂;S1, mix 8kg of limestone, 2kg of bauxite and 6kg of gypsum powder as expansion agent;
S2、将16kg钙基膨润土焙烧;将4kg鼠李糖加热至熔融,加入焙烧后的钙基膨润土,搅拌均匀,冷却干燥造粉得到改性膨润土;S2, 16kg calcium-based bentonite is roasted; 4kg of rhamnose is heated to melting, adds the calcium-based bentonite after roasting, stirs, and cools and drys powder to obtain modified bentonite;
S3、将膨胀剂和改性膨润土混合均匀作为膨胀填料。S3. Mix the expansion agent and the modified bentonite uniformly as the expansion filler.
制备例8Preparation Example 8
与制备例5的区别在于:S2中添加12kg钙基膨润土和3kg鼠李糖。The difference from Preparation Example 5 is that 12 kg of calcium-based bentonite and 3 kg of rhamnose are added to S2.
制备例9Preparation Example 9
与制备例5的区别在于:S2中添加16kg钙基膨润土和4kg鼠李糖。The difference from Preparation Example 5 is that 16 kg of calcium-based bentonite and 4 kg of rhamnose are added to S2.
制备例10。Preparation Example 10.
与制备例6的区别在于:S2中添加8kg钙基膨润土和2kg鼠李糖。The difference from Preparation Example 6 is that 8kg calcium bentonite and 2kg rhamnose are added to S2.
制备例11Preparation Example 11
与制备例6的区别在于:S2中添加16kg钙基膨润土和4kg鼠李糖。The difference from Preparation Example 6 is that 16 kg of calcium-based bentonite and 4 kg of rhamnose are added to S2.
制备例12Preparation Example 12
与制备例7的区别在于:S2中添加8kg钙基膨润土和2kg鼠李糖。The difference from Preparation Example 7 is that 8kg calcium bentonite and 2kg rhamnose are added to S2.
制备例13Preparation Example 13
与制备例7的区别在于:S2中添加12kg钙基膨润土和3kg鼠李糖。The difference from Preparation Example 7 is that 12 kg of calcium-based bentonite and 3 kg of rhamnose are added to S2.
表1制备例5~制备例13的原料表(kg)Table 1 Raw material list (kg) of Preparation Example 5 to Preparation Example 13
表面处理剂制备例Preparation example of surface treatment agent
制备例14Preparation Example 14
4kg熔融的聚丙烯酸酯与1.5kg钕铁硼粉混合均匀作为表面处理剂。4kg of molten polyacrylate is mixed with 1.5kg of NdFeB powder uniformly as a surface treatment agent.
制备例15Preparation Example 15
15kg熔融的α—氰基丙烯酸乙酯和1.5kg的钕铁硼粉混合均匀作为表面处理剂。15kg of molten ethyl α-cyanoacrylate and 1.5kg of NdFeB powder were mixed uniformly as a surface treatment agent.
制备例16Preparation Example 16
15kg熔融的α—氰基丙烯酸乙酯和4kg熔融的聚丙烯酸酯混合均匀作为表面处理剂。15kg of molten ethyl α-cyanoacrylate and 4kg of molten polyacrylate were mixed uniformly as a surface treatment agent.
制备例17Preparation Example 17
10kg熔融的α—氰基丙烯酸乙酯、2kg熔融的聚丙烯酸酯和1kg的钕铁硼粉混合均匀作为表面处理剂。10kg of molten ethyl α-cyanoacrylate, 2kg of molten polyacrylate and 1kg of NdFeB powder were mixed uniformly as a surface treatment agent.
制备例18Preparation Example 18
与制备例17的区别在于:添加4kg熔融的聚丙烯酸酯。The difference from Preparation 17 is that 4 kg of molten polyacrylate are added.
制备例19Preparation Example 19
与制备例17的区别在于:添加6kg熔融的聚丙烯酸酯。The difference from Preparation 17 is that 6 kg of molten polyacrylate are added.
制备例20Preparation Example 20
15kg熔融的α—氰基丙烯酸乙酯、2kg熔融的聚丙烯酸酯和1.5kg的钕铁硼粉混合均匀作为表面处理剂。15kg of molten ethyl α-cyanoacrylate, 2kg of molten polyacrylate and 1.5kg of NdFeB powder were mixed uniformly as a surface treatment agent.
制备例21Preparation Example 21
与制备例20的区别在于:添加4kg熔融的聚丙烯酸酯。The difference from
制备例22Preparation Example 22
与制备例21的区别在于:添加6kg熔融的聚丙烯酸酯。The difference from Preparation 21 is that 6 kg of molten polyacrylate are added.
制备例23Preparation Example 23
20kg熔融的α—氰基丙烯酸乙酯、2kg熔融的聚丙烯酸酯和2kg的钕铁硼粉混合均匀作为表面处理剂。20kg of molten ethyl α-cyanoacrylate, 2kg of molten polyacrylate and 2kg of NdFeB powder were mixed uniformly as a surface treatment agent.
制备例24Preparation Example 24
与制备例23的区别在于:添加4kg熔融的聚丙烯酸酯。The difference from Preparation 23 is that 4 kg of molten polyacrylate are added.
制备例25Preparation Example 25
与制备例23的区别在于:添加6kg熔融的聚丙烯酸酯。The difference from Preparation 23 is that 6 kg of molten polyacrylate was added.
表2制备例14~制备例25的原料表(kg)Table 2 Raw material table (kg) of Preparation Example 14 to Preparation Example 25
实施例Example
实施例1Example 1
S1、将192kg硅酸盐水泥、3kg减水剂、112kg拌合水、64kg粉料和制备例5制备例的膨胀填料搅拌均匀作为初混料;S1, 192kg Portland cement, 3kg water reducing agent, 112kg mixing water, 64kg powder and the expansion filler of Preparation Example 5 are evenly stirred as initial mix;
S2、将720kg粗集料、420kg细集料和28kg拌合水混合均匀作为粗混料;S2. Mix 720kg of coarse aggregate, 420kg of fine aggregate and 28kg of mixing water as a coarse mixture;
S3、将初混料和粗混料混合搅拌均匀作为预混料;S3. Mix and stir the initial mixture and the coarse mixture evenly as a premix;
S4、取35kg制备例1制备的涂层钢纤维加入预混料中,搅拌均匀得到混凝土。S4. Add 35 kg of the coated steel fibers prepared in Preparation Example 1 into the premix, and stir evenly to obtain concrete.
实施例2Example 2
S1、将276kg硅酸盐水泥、4kg减水剂、116kg拌合水、92kg粉料和制备例6制备例的膨胀填料搅拌均匀作为初混料;S1, 276kg Portland cement, 4kg water reducing agent, 116kg mixing water, 92kg powder and the expansion filler of Preparation Example 6 are evenly stirred as initial mix;
S2、将910kg粗集料、605kg细集料和29kg拌合水混合均匀作为粗混料;S2. Mix 910kg of coarse aggregate, 605kg of fine aggregate and 29kg of mixing water as a coarse mixture;
S3、将初混料和粗混料混合搅拌均匀作为预混料;S3. Mix and stir the initial mixture and the coarse mixture evenly as a premix;
S4、将92kg制备例2制备的涂层钢纤维加入预混料中,搅拌均匀得到混凝土。S4. Add 92 kg of the coated steel fibers prepared in Preparation Example 2 into the premix, and stir to obtain concrete.
实施例3Example 3
S1、将360kg硅酸盐水泥、5kg减水剂、120kg拌合水、120kg粉料和制备例7制备例的膨胀填料搅拌均匀作为初混料;S1, 360kg Portland cement, 5kg water reducing agent, 120kg mixing water, 120kg powder and the expansion filler of Preparation Example 7 are evenly stirred as initial mix;
S2、将1100kg粗集料、790kg细集料和30kg拌合水混合均匀作为粗混料;S2. Mix 1100kg of coarse aggregate, 790kg of fine aggregate and 30kg of mixing water as a coarse mixture;
S3、将初混料和粗混料混合搅拌均匀作为预混料;S3. Mix and stir the initial mixture and the coarse mixture evenly as a premix;
S4、将146kg制备例1制备的涂层钢纤维加入预混料中,搅拌均匀得到混凝土。S4, adding 146 kg of the coated steel fibers prepared in Preparation Example 1 into the premix, and stirring uniformly to obtain concrete.
实施例4Example 4
与实施例2的区别在于:添加92kg制备例4制备的涂层钢纤维。The difference from Example 2 is that 92 kg of the coated steel fibers prepared in Preparation Example 4 were added.
实施例5Example 5
与实施例2的区别在于:添加92kg制备例1制备的涂层钢纤维。The difference from Example 2 is that 92 kg of the coated steel fibers prepared in Preparation Example 1 were added.
实施例6Example 6
与实施例2的区别在于:添加92kg制备例3制备的涂层钢纤维。The difference from Example 2 is that 92 kg of the coated steel fibers prepared in Preparation Example 3 were added.
实施例7Example 7
与实施例2的区别在于:采用制备例5制备的膨胀填料。The difference from Example 2 is that the expanded filler prepared in Preparation Example 5 is used.
实施例8~实施例14Example 8 to Example 14
与实施例2的区别在于:依次采用制备例7~制备例13制备的膨胀填料。The difference from Example 2 is that the expanded fillers prepared in Preparation Examples 7 to 13 are used in sequence.
实施例15Example 15
参照图1,一种桥面板结构,包括正交异性钢10、钢筋层和混凝土层40,正交异性钢10包括异型钢板11和面板12,面板12的上表面为矩形,异型钢板11为U型板,异型钢板11与面板12上表面长度方向平行设置,多块异型钢板11沿面板12上表面宽度方向依次设置,且异型钢板11的顶壁与面板12的底壁焊接固定。钢筋层包括横筋和纵筋,横筋与面板12上表面宽度方向平行设置,纵筋与面板12上表面长度方向平行设置,多根横筋和纵筋绑接形成钢筋层,钢筋层的钢筋20与面板12的顶壁固定连接。混凝土层40位于面板12上方,且混凝土层40穿过钢筋层并与面板12的顶壁粘结固定,钢筋层包裹在混凝土层40中。Referring to FIG. 1, a bridge deck structure includes
参照图1和图2,为增加正交异性钢10与混凝土层40之间的连接强度,面板12上设置有多个剪力钉30,剪力钉30包括螺纹柱31、连接圆台32和顶盖33,螺纹柱31与面板12的顶壁垂直设置,且螺纹柱31与面板12的顶壁螺纹固定连接。连接圆台32与螺纹柱31同轴设置,且连接圆台32大端的端壁与螺纹柱31的顶壁固定连接,连接圆台32大端的端壁与面板12的顶壁抵接。顶盖33为与连接圆台32同轴设置的圆柱体,顶盖33的底壁与连接圆台32小端的端壁固定连接。剪力钉30与面板12的顶壁之间形成钝角,便于混凝土填充,减小了混凝土中孔隙量。1 and 2, in order to increase the connection strength between the
实施例15的实施原理为:The implementation principle of Embodiment 15 is:
将横筋和纵筋绑接形成钢筋层,将钢筋层固定在正交异性钢10的面板12上,将多个剪力钉30螺纹连接的正交异性钢10的面板12上,浇筑混凝土,混凝土穿过钢筋层与正交异性钢10的面板12粘结固定,形成桥面板结构。The transverse bars and longitudinal bars are bound to form a reinforcing bar layer, the reinforcing bar layer is fixed on the panel 12 of the
实施例16Example 16
S1、在正交异性钢10表面均匀喷涂制备例14制备的表面处理剂;S1, uniformly spray the surface treatment agent prepared in Preparation Example 14 on the surface of the
S2、将正交异性钢10安装在斜拉桥上,对桥面清理及验收;S2. Install the
S3、在桥面上测量放样,绘制剪力钉30的安装位置;S3. Measure the stake out on the bridge deck, and draw the installation position of the
S4、根据测量放样标记点位置,将剪力钉30安装在正交异性钢10上,钢筋20绑接形成钢筋层,并与正交异性钢固定连接;S4. According to the position of the measured stakeout mark point, the shear nails 30 are installed on the
S5、钢筋20喷涂制备例14制备的表面处理剂;S5, the surface treatment agent prepared by spraying preparation example 14 of
S6、热蒸汽对钢筋20和正交异性钢10进行喷洒,使正交异性钢10和钢筋20上的表面活性剂软化,之后采用实施例2制备的混凝土浇筑,热蒸汽喷洒不超过混凝土浇筑前10min,混凝土浇筑过程中采用插入式振动棒分层振捣,振动棒快插慢拔,减小混凝土中孔隙量;S6, the hot steam sprays the
S7、人工抹平混凝土上表面,采用蒸汽养护法对混凝土进行养护,直至形成混凝土成型,形成桥面板。S7. Manually smooth the upper surface of the concrete, and use the steam curing method to maintain the concrete until the concrete is formed and the bridge deck is formed.
实施例17~实施例27Example 17 to Example 27
与实施例16的区别在于:依次采用制备例15~制备例25制备的表面活性剂。The difference from Example 16 is that the surfactants prepared in Preparation Examples 15 to 25 are used in sequence.
实施例28Example 28
与实施例16的区别在于:实施例2制备的混凝土中添加了5kg绝缘油。The difference from Example 16 is that 5kg of insulating oil is added to the concrete prepared in Example 2.
对比例Comparative ratio
对比例1Comparative Example 1
本对比例与实施例2的区别在于:未添加涂层钢纤维,添加了92kg波纹钢纤维。The difference between this comparative example and Example 2 is that no coated steel fibers are added, and 92 kg of corrugated steel fibers are added.
对比例2Comparative Example 2
本对比例与实施例2的区别在于:未添加膨胀填料。The difference between this comparative example and Example 2 is that no expansion filler is added.
对比例3Comparative Example 3
本对比例与实施例2的区别在于:未添加改性膨润土。The difference between this comparative example and Example 2 is that no modified bentonite is added.
对比例4Comparative Example 4
本对比例与实施例15的区别在于:正交异性钢和钢筋上未喷涂表面活性剂。The difference between this comparative example and Example 15 is that no surfactant was sprayed on the orthotropic steel and the steel bar.
表3实施例1~实施例14以及对比例1~对比例3的原料表(kg)Table 3 Raw material table (kg) of Examples 1 to 14 and Comparative Examples 1 to 3
性能检测试验performance test
试验方法experiment method
1.采用《GB/T50081-2002普通混凝土力学性能试验方法标准》中的方法对混凝土的抗压强度(MPa)进行测定,试验结果详见表4。1. The compressive strength (MPa) of concrete was measured by the method in "GB/T50081-2002 Standard for Mechanical Properties of Ordinary Concrete". The test results are shown in Table 4.
2.采用《GB/T50081-2002普通混凝土力学性能试验方法标准》中的方法对混凝土的抗折强度(MPa)进行测定,试验结果详见表4。2. The flexural strength (MPa) of concrete was measured by the method in "GB/T50081-2002 Standard for Mechanical Properties of Ordinary Concrete". The test results are shown in Table 4.
4.采用《GB/T50082-2009普通混凝土长期性能和耐久性能试验方法标准》中的方法对混凝土的收缩率(%)进行测定,试验结果详见表4。4. The shrinkage rate (%) of concrete is measured by the method in "GB/T50082-2009 Standard for Long-term Performance and Durability Test of Ordinary Concrete", and the test results are shown in Table 4.
5.采用《GB50550-2010建筑结构加固工程施工质量验收规范》中的方法对混凝土与正交异性钢之间的正拉粘结强度(MPa)进行测定,试验结果详见表5。5. The positive tensile bond strength (MPa) between concrete and orthotropic steel was measured by the method in "GB50550-2010 Code for Acceptance of Construction Quality of Building Structural Reinforcement Engineering". The test results are shown in Table 5.
表4实施例1~实施例14以及对比例1~对比例3的试验结果数据表Table 4 Data table of test results of Example 1 to Example 14 and Comparative Example 1 to Comparative Example 3
结合实施例1、实施例2和实施例3并结合表4通过调整硅酸盐水泥、减水剂、拌合水、粉料、粗集料、细集料、涂层钢纤维和膨胀填料的类型和添加量,提高混凝土的抗压强度和抗折强度,减小混凝土的收缩率。Combined with Example 1, Example 2 and Example 3 and combined with Table 4, by adjusting the ratio of Portland cement, water reducing agent, mixing water, powder, coarse aggregate, fine aggregate, coated steel fiber and expansion filler The type and amount of addition can improve the compressive strength and flexural strength of concrete and reduce the shrinkage rate of concrete.
结合实施例2和对比例1并结合表4可以看出,相较于添加波形钢纤维,涂层钢纤维的添加,提高了混凝土的抗压强度和抗折强度,降低了混凝土的收缩率。涂层钢纤维包括波形钢纤维和涂覆在波形钢纤维表面的涂覆液。涂覆液由乙烯基硅油和黑钨矿粉混合而成,黑钨矿粉被乙烯基硅油沾附在波形钢纤维的表面,使波形钢纤维表面形成柔性涂层,波形钢纤维不易折断,从而提高了混凝土的抗压强度和抗折强度。涂层钢纤维收缩率低于混凝土,在混凝土中水分蒸发的过程中,涂层钢纤维粘连支撑水泥颗粒和骨料,使混凝土不易收缩,从而降低了混凝土的收缩率。Combining Example 2 and Comparative Example 1 with Table 4, it can be seen that compared with the addition of corrugated steel fibers, the addition of coated steel fibers improves the compressive strength and flexural strength of concrete, and reduces the shrinkage rate of concrete. The coated steel fibers include corrugated steel fibers and a coating liquid coated on the surface of the corrugated steel fibers. The coating liquid is mixed with vinyl silicone oil and wolframite powder. Wolframite powder is adhered to the surface of the corrugated steel fiber by vinyl silicone oil, so that the surface of the corrugated steel fiber forms a flexible coating, and the corrugated steel fiber is not easy to break, thus Improve the compressive strength and flexural strength of concrete. The shrinkage rate of coated steel fibers is lower than that of concrete. During the evaporation of water in the concrete, the coated steel fibers adhere to support cement particles and aggregates, so that the concrete is not easy to shrink, thereby reducing the shrinkage rate of the concrete.
结合实施例2和实施例4并结合表4可以看出,黑钨矿粉的添加,提高了混凝土的抗折强度,降低了混凝土的收缩率。黑钨矿粉中的钨与混凝土中的氢氧化钠溶液反应生成粗钨酸钠,降低了混凝土中游离钠离子含量,减低了混凝土被碱腐蚀的概率,从而提高了混凝土的抗折强度。黑屋矿粉内的铁离子与空气和水分子生成致密膜,阻隔水分与涂层钢纤维,减小了涂层钢纤维腐蚀的概率,提高了混凝土的抗压强度和抗折强度。黑钨矿粉中的金属阳离子吸附膨胀填料中的改性膨润土,从而提高了波形钢纤维与膨胀剂的粘结强度,混凝土膨胀时,膨胀剂填充膨胀剂内孔隙,提高了混凝土的自密性,使混凝土不易干缩,从而降低了混凝土的收缩率。Combining Example 2 and Example 4 with Table 4, it can be seen that the addition of wolframite powder improves the flexural strength of concrete and reduces the shrinkage rate of concrete. Tungsten in wolframite powder reacts with sodium hydroxide solution in concrete to form crude sodium tungstate, which reduces the content of free sodium ions in concrete and reduces the probability of concrete being corroded by alkali, thereby improving the flexural strength of concrete. The iron ions in the black house powder form a dense film with air and water molecules, which blocks the water and the coated steel fibers, reduces the probability of corrosion of the coated steel fibers, and improves the compressive strength and flexural strength of concrete. The metal cations in wolframite powder adsorb the modified bentonite in the expansion filler, thereby improving the bonding strength between the corrugated steel fiber and the expansion agent. When the concrete expands, the expansion agent fills the pores of the expansion agent, which improves the self-tightness of the concrete. , so that the concrete is not easy to shrink, thereby reducing the shrinkage of the concrete.
结合实施例2、实施例5和实施例6并结合表4可以看出,随着黑钨矿粉与乙烯基硅油重量比的增加,混凝土的抗压强度和抗折强度均先提高后降低,混凝土的收缩率先降低后升高。混凝土抗压强度降低的原因在于黑钨矿粉的添加,降低了涂覆液与波形钢纤维的粘结强度,混凝土搅拌期间,波纹钢纤维表面的涂覆层容易被剥落,涂覆层对波纹钢纤维的缓冲作用降低,从而使涂层钢纤维易断裂,混凝土的抗压强度降低。In combination with Example 2, Example 5 and Example 6 and in combination with Table 4, it can be seen that with the increase in the weight ratio of wolframite powder to vinyl silicone oil, the compressive strength and flexural strength of concrete both increase first and then decrease, The shrinkage of concrete first decreases and then increases. The reason for the decrease in the compressive strength of concrete is that the addition of wolframite powder reduces the bonding strength of the coating solution and the corrugated steel fibers. During concrete mixing, the coating on the surface of the corrugated steel fibers is easily peeled off, and the coating has no effect on the corrugated steel fibers. The buffering effect of the steel fibers is reduced, so that the coated steel fibers are easily broken and the compressive strength of the concrete is reduced.
结合实施例2和对比例2并结合表4可以看出,膨胀填料的添加,提高了混凝土的抗折强度,降低了混凝土的收缩率。膨胀填料包括膨胀剂和改性膨润土,膨胀剂包括二灰土、矾土和石膏粉,改性膨润土包括钙基膨润土和鼠李糖。鼠李糖附着在钙基膨润土的表面和孔中,鼠李糖作为阴离子表面活性剂,而二灰土、矾土和石膏粉中存在金属阳离子,从而提高了二灰土、矾土和石膏粉与钙基膨润土的连接强度。在水化热作用下,二灰土中的氧化钙和粉煤灰与矾土中的三氧化二铝以及石膏粉中的硫酸钙反应生成硫铝酸钙晶体,硫铝酸钙晶体填充混凝土中的孔隙,提高了混凝土的自密性,从而减小了混凝土干缩的概率,降低了混凝土的收缩率,进而提高了混凝土的抗压强度和抗折强度。Combining Example 2 and Comparative Example 2 with Table 4, it can be seen that the addition of expansion fillers improves the flexural strength of concrete and reduces the shrinkage rate of concrete. Expansion fillers include expansion agents and modified bentonites, expansion agents include di-lime, bauxite and gypsum powder, and modified bentonites include calcium-based bentonite and rhamnose. Rhamnose is attached to the surface and pores of calcium-based bentonite, and rhamnose acts as an anionic surfactant, while the presence of metal cations in di-lime, bauxite, and gypsum powder increases the efficiency of di-lime, bauxite, and gypsum powder with calcium. Bonding strength of base bentonite. Under the action of the heat of hydration, calcium oxide and fly ash in the lime soil react with aluminum oxide in the bauxite and calcium sulfate in the gypsum powder to form calcium sulfoaluminate crystals, and the calcium sulfoaluminate crystals fill the concrete in the concrete. The pores improve the self-compactness of the concrete, thereby reducing the probability of concrete shrinkage, reducing the shrinkage rate of the concrete, and then improving the compressive strength and flexural strength of the concrete.
结合实施例2、对比例2和对比例3并结合表面可以看出,膨胀填料中改性膨润土的添加,提高了混凝土的抗折强度和抗压强度,降低了混凝土的收缩率。改性膨润土负载二灰土、矾石和石膏粉,便于三者在水化热和水分作用下发生反应;改性膨润土中的鼠李糖与涂层钢纤维表面的金属离子相互吸附,提高了膨胀填料与涂层钢纤维的粘结强度,膨胀剂生成硫铝酸钙晶体,紧密包裹涂层钢纤维,减小了混凝土收缩导致浆料与涂层钢纤维之间形成缝隙的概率,从而减小了混凝土中的孔隙量,降低了混凝土的收缩率,提高了混凝土的抗折强度和抗压强度。Combining Example 2, Comparative Example 2 and Comparative Example 3 with the surface, it can be seen that the addition of modified bentonite in the expansion filler improves the flexural strength and compressive strength of concrete, and reduces the shrinkage rate of concrete. The modified bentonite is loaded with limestone, bauxite and gypsum powder, which is convenient for the three to react under the action of hydration heat and moisture; the rhamnose in the modified bentonite and the metal ions on the surface of the coated steel fiber are mutually adsorbed, which improves the expansion of the filler. The bonding strength with the coated steel fibers, the expansion agent generates calcium sulfoaluminate crystals, which tightly wrap the coated steel fibers, reducing the probability of the formation of gaps between the slurry and the coated steel fibers due to concrete shrinkage, thereby reducing the The amount of porosity in the concrete reduces the shrinkage rate of the concrete and increases the flexural strength and compressive strength of the concrete.
结合实施例2以及实施例7~实施例14并结合表4,通过添加膨胀剂与改性膨润土的比例,提高了混凝土的抗折强度和抗压强度,降低混凝土的收缩率。Combined with Example 2 and Examples 7 to 14 and Table 4, by adding the ratio of expansion agent and modified bentonite, the flexural strength and compressive strength of concrete are improved, and the shrinkage rate of concrete is reduced.
结合实施例2、实施例11和实施例12并结合表4可以看出,在膨胀剂添加量不变的情况下,增加改性膨润土的添加量,混凝土的抗压强度和抗折强度均先提高后降低,混凝土的收缩率先减小后增加。改性膨润土包括钙基膨润土和鼠李糖,鼠李糖提高了钙基膨润土对膨胀剂的吸附效率和吸附量,钙基膨润土将膨胀剂束缚在一起,提高了膨胀剂的膨胀效率,从而提高了混凝土的自密性,混凝土的抗压强度和抗折强度提高,收缩率减小。但钙基膨润土的比表面积较大,随着钙基膨润土和鼠李糖添加量的增加,部分膨胀剂进入钙基膨润土的空隙中,钙基膨润土阻碍了膨胀剂与水接触,从而使膨胀剂的膨胀效率降低,混凝土的抗压强度和抗折强度降低,收缩率增加。Combined with Example 2, Example 11 and Example 12 and combined with Table 4, it can be seen that under the condition of the same amount of expansion agent added, increasing the amount of modified bentonite added, the compressive strength and flexural strength of concrete are both higher. Increase and then decrease, the shrinkage of concrete decreases first and then increases. Modified bentonite includes calcium-based bentonite and rhamnose. Rhamnose improves the adsorption efficiency and adsorption capacity of calcium-based bentonite to swelling agent. The self-compactness of concrete is improved, the compressive strength and flexural strength of concrete are improved, and the shrinkage rate is reduced. However, the specific surface area of calcium-based bentonite is relatively large. With the increase of the addition amount of calcium-based bentonite and rhamnose, part of the swelling agent enters the gap of calcium-based bentonite, and calcium-based bentonite hinders the contact between the swelling agent and water, so that the swelling agent The expansion efficiency of concrete decreases, the compressive strength and flexural strength of concrete decrease, and the shrinkage rate increases.
结合实施例2、实施例9和实施例14,并结合表4可以看出,在改性膨润土添加量不变的情况下,增加膨胀剂的添加量,混凝土的抗压强度和抗折强度均先提高后降低,混凝土的收缩率先减小后增加。膨胀剂包括二灰土、矾土和石膏粉,在水化热作用下,二灰土中的氧化钙和粉煤灰与矾土中的三氧化二铝以及石膏粉中的硫酸钙反应生成硫铝酸钙晶体,硫铝酸钙晶体填充混凝土中的孔隙,从而减小了混凝土收缩率,混凝土不易形成早期裂缝,混凝土的抗压强度和抗折强度提高。随着灰土、矾土和石膏粉的添加量增加,改性膨润土只能负载部分灰土、矾土和石膏粉,其它灰土、矾土和石膏粉与改性膨润土分离,灰土、矾土和石膏粉分散于混凝土中,导致混凝土养护期间,灰土、矾土和石膏粉不易接触并发生反应,降低了膨胀剂的膨胀效率,混凝土的抗压强度和抗折强度降低,收缩率增加。Combined with Example 2, Example 9 and Example 14, and combined with Table 4, it can be seen that when the addition amount of the modified bentonite is unchanged, the addition amount of the expansion agent is increased, and the compressive strength and flexural strength of the concrete are both. First increase and then decrease, the shrinkage of concrete decreases first and then increases. Expansion agents include di-lime, bauxite and gypsum powder. Under the action of hydration heat, calcium oxide and fly ash in di-lime soil react with aluminum oxide in bauxite and calcium sulfate in gypsum powder to form sulfoaluminate. Calcium crystals, calcium sulfoaluminate crystals fill the pores in the concrete, thereby reducing the concrete shrinkage rate, the concrete is not easy to form early cracks, and the compressive strength and flexural strength of the concrete are improved. With the addition of lime soil, bauxite and gypsum powder, the modified bentonite can only support part of the lime soil, bauxite and gypsum powder, other lime soil, bauxite and gypsum powder are separated from the modified bentonite, and the lime soil, bauxite and gypsum powder are separated from the modified bentonite. Dispersed in concrete, lime soil, bauxite and gypsum powder are not easy to contact and react during concrete curing, which reduces the expansion efficiency of the expansion agent, reduces the compressive strength and flexural strength of concrete, and increases the shrinkage rate.
表5实施例16~实施例28以及对比例4的试验结果数据表Table 5 Test result data table of Examples 16 to 28 and Comparative Example 4
结合实施例23和对比例4并结合表5可以看出,表面活性剂的添加,提高了混凝土与正交异性钢的粘结强度。表面活性剂包括α—氰基丙烯酸乙酯、聚丙烯酸酯和钕铁硼粉,将表面处理剂涂覆在正交异性钢表面,与α—氰基丙烯酸乙酯、聚丙烯酸酯混合均匀的钕铁硼粉在磁性作用下吸附在正交异性钢表面,从而提高了表面处理剂与正交异性钢的粘结强度。Combining Example 23 and Comparative Example 4 with Table 5, it can be seen that the addition of surfactant improves the bond strength between concrete and orthotropic steel. The surfactants include α-cyanoacrylate, polyacrylate and NdFeB powder, the surface treatment agent is coated on the surface of orthotropic steel, and the neodymium is uniformly mixed with α-cyanoacrylate and polyacrylate. The iron boron powder is adsorbed on the surface of the orthotropic steel under the magnetic action, thereby improving the bonding strength between the surface treatment agent and the orthotropic steel.
结合实施例16和实施例23并结合表5可以看出,α—氰基丙烯酸乙酯的添加,提高了混凝土与正交易型钢的正拉粘结强度。混凝土中的改性膨润土与氰化有机物α—氰基丙烯酸乙酯相互吸附,且改性膨润土与高聚物粘合,从而提高了混凝土与正交异性钢的粘结强度。Combining Example 16 and Example 23 and combining with Table 5, it can be seen that the addition of α-ethyl cyanoacrylate improves the positive tensile bond strength between concrete and trade steel. The modified bentonite in the concrete and the cyanide organic compound α-cyanoacrylate are mutually adsorbed, and the modified bentonite is bonded with the high polymer, thereby improving the bonding strength between the concrete and the orthotropic steel.
结合实施例17和实施例23并结合表5可以看出,聚丙烯酸酯的添加,提高了混凝土与正交易型钢的正拉粘结强度。聚丙烯酸酯与改性膨润土形成三维网状结构,从而提高了混凝土与正交异性钢之间的粘结强度;聚丙烯酸酯在正交异性钢表面形成防水膜,阻碍水分子渗入混凝土与正交异性钢之间,从而减小了混凝土与正交异性钢剥离的概率,从而提高了混凝土与正交异性钢的粘结强度。Combining Example 17 and Example 23 with Table 5, it can be seen that the addition of polyacrylate improves the positive tensile bond strength between the concrete and the normal trade section steel. Polyacrylate and modified bentonite form a three-dimensional network structure, thereby improving the bonding strength between concrete and orthotropic steel; polyacrylate forms a waterproof film on the surface of orthotropic steel, preventing water molecules from infiltrating concrete and orthotropic steel. between the anisotropic steels, thereby reducing the probability of peeling off the concrete and the orthotropic steel, thereby improving the bond strength between the concrete and the orthotropic steel.
结合实施例18和实施例23并结合表5可以看出,钕铁硼粉的添加,提高了混凝土与正交易型钢的正拉粘结强度。钕铁硼在磁性作用下吸附在正交异性钢表面,从而提高了表面处理剂与正交异性钢的粘结强度。改性膨润土中的鼠李糖与金属离子形成环状结构络合物,提高了钙基膨润土对二灰土、矾土和石膏粉的吸附强度,便于钙基膨润土将膨胀剂携带至正交异性钢表面,在正交异性钢与混凝土界面形成硫铝酸钙晶体,从而减小了正交异性钢与混凝土相互剥离的概率,提高了混凝土与正交异性钢的粘结强度。Combining Example 18 and Example 23 and combining with Table 5, it can be seen that the addition of NdFeB powder improves the positive tensile bond strength between concrete and normal traded steel. NdFeB is adsorbed on the surface of the orthotropic steel under the magnetic action, thereby improving the bonding strength between the surface treatment agent and the orthotropic steel. The rhamnose in the modified bentonite forms a cyclic structure complex with metal ions, which improves the adsorption strength of the calcium-based bentonite to di-lime, bauxite and gypsum powder, and facilitates the calcium-based bentonite to carry the swelling agent to the orthotropic steel. On the surface, calcium sulfoaluminate crystals are formed at the interface of orthotropic steel and concrete, thereby reducing the probability of orthotropic steel and concrete peeling off each other, and improving the bonding strength of concrete and orthotropic steel.
结合实施例19~实施例27并结合表5,通过调整α—氰基丙烯酸乙酯、聚丙烯酸酯和钕铁硼粉的添加量,提高混凝土与正交异性钢的粘结强度。With reference to Examples 19 to 27 and Table 5, the bonding strength between concrete and orthotropic steel is improved by adjusting the addition amounts of α-ethyl cyanoacrylate, polyacrylate and NdFeB powder.
结合实施例22、实施例23和实施例24并结合表5可以看出,在α—氰基丙烯酸乙酯和钕铁硼粉添加量不变的情况下,增加聚丙烯酸酯的添加量,混凝土与正交异性钢之间的正拉粘结强度先提高后降低。正拉粘结强度降低的原因在于聚丙烯酸酯生成的拒水膜阻碍α—氰基丙烯酸乙酯与正交异性钢接触,从而降低了表面处理剂与正交异性钢的粘结强度,进而降低了混凝土与正交异性钢的粘结强度。Combining Example 22, Example 23 and Example 24 with Table 5, it can be seen that under the condition that the addition amount of α-ethyl cyanoacrylate and NdFeB powder is unchanged, increasing the addition amount of polyacrylate, concrete The positive tensile bond strength with orthotropic steel increases first and then decreases. The reason for the decrease in the positive tensile bond strength is that the water-repellent film generated by the polyacrylate hinders the contact between α-cyanoacrylate and the orthotropic steel, thereby reducing the bonding strength of the surface treatment agent and the orthotropic steel, thereby reducing the The bond strength between concrete and orthotropic steel.
结合实施例20、实施例23和实施例26并结合表5可以看出,在聚丙烯酸酯添加量不变的情况下,增加α—氰基丙烯酸乙酯和钕铁硼粉的添加量,混凝土与正交异性钢之间的正拉粘结强度先提高后降低。正拉粘结强度降低的原因在于表面处理剂中聚丙烯酸酯的含量降低,聚丙烯酸酯与混凝土中改性膨润土的粘结受到阻碍,混凝土与正交异性钢的粘结强度降低。Combined with Example 20, Example 23 and Example 26 and combined with Table 5, it can be seen that under the condition that the addition amount of polyacrylate remains unchanged, increasing the addition amount of α-ethyl cyanoacrylate and NdFeB powder, concrete The positive tensile bond strength with orthotropic steel increases first and then decreases. The reason for the decrease of positive tensile bond strength is that the content of polyacrylate in the surface treatment agent decreases, the bond between polyacrylate and modified bentonite in concrete is hindered, and the bond strength between concrete and orthotropic steel decreases.
结合实施例23和实施例28并结合表5可以看出,绝缘油的添加,提高了混凝土与正交易型钢的正拉粘结强度。部分绝缘油与α—氰基丙烯酸乙酯接触,促进α—氰基丙烯酸乙酯软化,便于α—氰基丙烯酸乙酯与混凝土中的改性膨润土相互吸附,提高了混凝土与正交异性钢的粘结强度。Combining Example 23 and Example 28 with Table 5, it can be seen that the addition of insulating oil improves the positive tensile bond strength between the concrete and the traded steel. Part of the insulating oil is contacted with ethyl α-cyanoacrylate, which promotes the softening of ethyl α-cyanoacrylate, facilitates the mutual adsorption of ethyl α-cyanoacrylate and modified bentonite in concrete, and improves the adhesion between concrete and orthotropic steel. Bond strength.
本具体实施例仅仅是对本申请的解释,其并不是对本申请的限制,本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改,但只要在本申请的权利要求范围内都受到专利法的保护。This specific embodiment is only an explanation of the application, and it does not limit the application. Those skilled in the art can make modifications to the embodiment without creative contribution as needed after reading this specification, but as long as the rights of the application are All claims are protected by patent law.
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