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CN115206970A - Capacitor, semiconductor device, electronic device, and manufacturing method thereof - Google Patents

Capacitor, semiconductor device, electronic device, and manufacturing method thereof Download PDF

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Publication number
CN115206970A
CN115206970A CN202110396408.5A CN202110396408A CN115206970A CN 115206970 A CN115206970 A CN 115206970A CN 202110396408 A CN202110396408 A CN 202110396408A CN 115206970 A CN115206970 A CN 115206970A
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China
Prior art keywords
lower electrode
electrode groove
mask pattern
layer
semiconductor substrate
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柳圣浩
李俊杰
周娜
杨红
李俊峰
王文武
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Institute of Microelectronics of CAS
Zhenxin Beijing Semiconductor Co Ltd
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Institute of Microelectronics of CAS
Zhenxin Beijing Semiconductor Co Ltd
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Priority to CN202110396408.5A priority Critical patent/CN115206970A/en
Publication of CN115206970A publication Critical patent/CN115206970A/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/30DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/01Manufacture or treatment
    • H10B12/02Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
    • H10B12/03Making the capacitor or connections thereto

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  • Manufacturing & Machinery (AREA)
  • Semiconductor Integrated Circuits (AREA)

Abstract

The application relates to a capacitor structure comprising: a semiconductor substrate; a plurality of storage node contacts on the semiconductor substrate; each storage node contact part is provided with a lower electrode of a semi-surrounding structure, and each two opposite lower electrodes of the semi-surrounding structure form a pair of lower electrode pairs surrounding the upper electrode; the two opposite lower electrodes and the upper electrodes of the lower electrode pair are separated by a dielectric layer. The capacitor and the semiconductor device obtained by the manufacturing method can effectively reduce the difficulty of the manufacturing process on the premise of ensuring the performance of devices such as the storage capacity of a capacitor storage unit, and the like, and break through the limitation of the traditional 6F2 groove process mode on the basis of simplifying the process, so that the gap between the capacitors is reduced, the size of the prepared capacitor is smaller than that of the existing capacitor, and the integration level of the semiconductor device is improved.

Description

电容器、半导体器件、电子设备及其制造方法Capacitor, semiconductor device, electronic device, and manufacturing method thereof

技术领域technical field

本申请涉及电容器及其制造方法,还涉及包括该电容器的半导体器件、电子设备及其制造方法。The present application relates to a capacitor and a method of manufacturing the same, and also relates to a semiconductor device, an electronic device including the capacitor, and a method of manufacturing the same.

背景技术Background technique

近年来,由于半导体用户要求半导体器件具有低功耗、高存储容量和高速特性,半导体制造商对高集成度、高速率的半导体器件的研究越来越多。特别是动态随机存取存储器(DRAM,Dynamic Random Access Memory)因其具有自由的数据输入输出能力和大的存储容量,被广泛用作半导体存储单元。In recent years, as semiconductor users require semiconductor devices to have low power consumption, high storage capacity, and high-speed characteristics, semiconductor manufacturers have increasingly researched high-integration, high-speed semiconductor devices. In particular, Dynamic Random Access Memory (DRAM, Dynamic Random Access Memory) is widely used as a semiconductor memory unit because of its free data input and output capability and large storage capacity.

然而,为了快速提高存储器的集成度和可扩展性,半导体器件的集成密度被不断增加,半导体器件的设计尺寸标准也随之不断减小。例如通常,DRAM是单元的集合,而每个单元有一个MOS(Metal Oxide Semiconductor)晶体管和一个存储电容。随着集成度的增加,半导体芯片的尺寸减小,电容器的尺寸也必然减小,而电容器尺寸的减小会使得电极之间的间距逐渐减小进而相应地减小电容器的电容,从而减小电容器的存储容量。但是,即使出于半导体存储器的集成度增加的考虑,也必须要使得电容器具有足够的电容,以确保半导体存储器装置的平稳运行和性能。However, in order to rapidly improve the integration and expandability of memories, the integration density of semiconductor devices has been continuously increased, and the design size standards of semiconductor devices have also been continuously reduced. For example, in general, a DRAM is a collection of cells, and each cell has a MOS (Metal Oxide Semiconductor) transistor and a storage capacitor. As the integration level increases, the size of the semiconductor chip decreases, and the size of the capacitor will inevitably decrease, and the decrease in the size of the capacitor will gradually reduce the spacing between the electrodes and accordingly reduce the capacitance of the capacitor, thereby reducing the size of the capacitor. Capacitor storage capacity. However, even in view of the increased integration of semiconductor memories, it is necessary to make the capacitors have sufficient capacitance to ensure smooth operation and performance of the semiconductor memory device.

现有使用的DRAM存储器主要有两种:一种是具有8F2存储单元面积的DRAM存储器;另一种是具有6F2存储单元面积的DRAM存储器。其中,具有8F2存储单元的DRAM存储器由于改善的信噪比而在DRAM存储器中广泛使用,但是因其有很多空闲区域,而与具有6F2存储单元的存储器相比消耗更多的存储单元面积。而具有6F2存储单元的存储器,虽然在减小存储单元面积方面提供了一些改进,但是采用该技术进行生产仍存在一些问题,例如,伴随着更小的存储单元所具有的工艺方面的困难等。There are two main types of DRAM memories in use: one is a DRAM memory with an area of 8F2 memory cells; the other is a DRAM memory with an area of 6F2 memory cells. Among them, DRAM memory with 8F2 memory cells is widely used in DRAM memory due to improved signal-to-noise ratio, but consumes more memory cell area compared to memory with 6F2 memory cells because of its many free areas. While the memory with 6F2 memory cells provides some improvements in reducing the memory cell area, there are still some problems in production using this technology, for example, the process difficulties associated with smaller memory cells.

因此,如何提出一种制造工艺更为简单的电容器存储单元的制造方法,以达到较小的存储单元面积和较高的电荷存储能力,成为本领域技术人员亟待解决的一个重要技术问题。Therefore, how to propose a method for manufacturing a capacitor storage unit with a simpler manufacturing process to achieve a smaller storage unit area and a higher charge storage capacity has become an important technical problem to be solved urgently by those skilled in the art.

发明内容SUMMARY OF THE INVENTION

本申请的目的是通过以下技术方案实现的:The purpose of this application is achieved through the following technical solutions:

根据一个或多个实施例,本申请公开了一种电容器结构,包括:According to one or more embodiments, the present application discloses a capacitor structure comprising:

半导体基底;semiconductor substrate;

位于半导体基底上的多个存储节点接触部;a plurality of storage node contacts on the semiconductor substrate;

每个所述存储节点接触部上设有一个半包围结构的下电极,并且每两个相对的所述半包围结构的下电极形成一对围绕上电极的下电极对;Each of the storage node contact portions is provided with a lower electrode of a semi-surrounding structure, and every two opposite lower electrodes of the half-surrounding structure form a pair of lower electrodes surrounding the upper electrode;

所述下电极对的两个相对的下电极和所述上电极三者之间彼此被介电层隔开。The two opposite lower electrodes of the lower electrode pair and the upper electrodes are separated from each other by a dielectric layer.

根据一个或多个实施例,本申请还公开了一种电容器结构的制造方法,其包括以下工艺步骤:According to one or more embodiments, the present application also discloses a method for manufacturing a capacitor structure, which includes the following process steps:

提供半导体基底,所述半导体基底上有存储节点接触部;providing a semiconductor substrate having storage node contacts thereon;

在半导体基底上形成牺牲模层;forming a sacrificial mold layer on a semiconductor substrate;

刻蚀所述牺牲模层形成多个下电极凹槽,在每一个所述下电极凹槽中暴露出两个相邻的存储节点接触部的表面;etching the sacrificial mold layer to form a plurality of lower electrode grooves, exposing the surfaces of two adjacent storage node contact portions in each of the lower electrode grooves;

沉积下电极层以填满所述下电极凹槽,随后进行化学机械平坦化处理或者回刻处理以露出所述牺牲模层;depositing a lower electrode layer to fill the lower electrode groove, and then performing chemical mechanical planarization or etchback to expose the sacrificial mold layer;

刻蚀所述下电极层和牺牲模层以形成上电极凹槽,所述上电极凹槽将所述下电极层分割为相对的一对半包围结构的下电极;etching the lower electrode layer and the sacrificial mold layer to form an upper electrode groove, and the upper electrode groove divides the lower electrode layer into a pair of opposite lower electrodes of a half-enclosed structure;

在所述上电极凹槽内形成介电层和上电极。A dielectric layer and an upper electrode are formed in the upper electrode groove.

根据一个或多个实施例,本申请还公开了包括了上述的电容器结构、或者包括了上述制造方法制备得到的电容器结构的半导体器件、电子设备等。According to one or more embodiments, the present application also discloses semiconductor devices, electronic devices, and the like that include the above capacitor structure, or include the capacitor structure prepared by the above manufacturing method.

本申请的其他特征和优点将在随后的说明书中阐述,并且,部分地从说明书中变得显而易见,或者,部分特征和优点可以从说明书中推知或毫无疑义地确定,或者通过实施本申请实施例了解。本申请的目的和其他优点可通过在所写的说明书、权利要求书、以及附图中所特别指出的结构来实现和获得。Other features and advantages of the present application will be set forth in the description which follows, and, in part, will become apparent from the description, or may be inferred or unambiguously determined from the description, or may be implemented by practice of the present application. example to understand. The objectives and other advantages of the application may be realized and attained by the structure particularly pointed out in the written description, claims, and drawings.

附图说明Description of drawings

通过阅读下文优选实施方式的详细描述,各种其他的优点和益处对于本领域普通技术人员将变得清楚明了。附图仅用于示出优选实施方式的目的,而并不认为是对本申请的限制。而且在整个附图中,用相同的参考符号表示相同的部件。在附图中:Various other advantages and benefits will become apparent to those of ordinary skill in the art upon reading the following detailed description of the preferred embodiments. The drawings are for purposes of illustrating preferred embodiments only and are not to be considered limiting of the application. Also, the same components are denoted by the same reference numerals throughout the drawings. In the attached image:

图1a-1h是本申请实施方式的电容器结构的制备工艺示意图。1a-1h are schematic diagrams of a fabrication process of a capacitor structure according to an embodiment of the present application.

图2是本申请实施方式的电容器结构的横截面俯视图。2 is a cross-sectional plan view of a capacitor structure according to an embodiment of the present application.

图3是本申请实施方式中形成下电极凹槽时所使用的图案。FIG. 3 is a pattern used when forming a lower electrode groove in an embodiment of the present application.

图4a-4c是本申请实施方式中形成上电极凹槽时所使用的图案。4a-4c are the patterns used in forming the upper electrode grooves in the embodiments of the present application.

图5是上电极凹槽与下电极凹槽的对应位置关系图。FIG. 5 is a diagram showing the corresponding positional relationship between the upper electrode groove and the lower electrode groove.

具体实施方式Detailed ways

下文将参照附图更完全地描述本申请,在附图中显示本申请的实施例。然而,本申请不局限于在这里阐述的实施例。相反地,提供这些实施例以便彻底地并完全地说明,并完全地将本申请的范围传达给本领域的技术人员。在附图中,为了清楚起见可能夸大了层和区域的厚度。全文中相同的数字标识相同的元件。如这里所使用的,术语“和/或”包括相关所列项目的一个或多个的任何和所有组合。The application will be described more fully hereinafter with reference to the accompanying drawings, in which embodiments of the application are shown. However, the present application is not limited to the embodiments set forth herein. Rather, these embodiments are provided so that they will be thorough and complete, and will fully convey the scope of the application to those skilled in the art. In the drawings, the thickness of layers and regions may be exaggerated for clarity. Like numerals identify like elements throughout. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.

这里所使用的术语仅仅是为了详细的描述实施例而不是想要限制本申请。如这里所使用的,除非本文清楚地指出外,否则单数形式“一”、“该”和“所述”等也包括复数形式。还应当理解的是说明书中使用的术语“包括”说明所述特征、整体、步骤、操作、元件和/或部件的存在,但是不排除一个或多个其他的特征、整体、步骤、操作、元件、部件、和/或其组合的存在或者增加。The terminology used herein is for the purpose of describing the embodiments in detail only and is not intended to limit the application. As used herein, the singular forms "a," "the," and "the" and the like include the plural forms unless the context clearly dictates otherwise. It should also be understood that the term "comprising" used in the specification describes the presence of stated features, integers, steps, operations, elements and/or components, but does not exclude one or more other features, integers, steps, operations, elements The presence or addition of , components, and/or combinations thereof.

应该理解当将一元件例如层、区域或者衬底称为“在另一个元件上”或者延伸“到另一个元件之上”时,可以是直接在另一个元件上或者直接延伸到另一个元件之上或者存在中间元件。相反地,当将一元件称为“直接在另一个元件上”或者“直接延伸到另一个元件之上”,则就不存在中间元件。也应当理解的是当将一种元件称为“连接”或者“耦合”至另一个元件时,可以是直接地连接或者耦合到另一个元件或者存在中间元件。相反地,当将一种元件称为“直接连接”或者“直接耦合”至另一个元件时,就不存在中间元件。It will be understood that when an element such as a layer, region or substrate is referred to as being "on" or extending "over" another element, it can be directly on or extending directly into the other element or intermediate elements are present. In contrast, when an element is referred to as being "directly on" or "extending directly on" another element, there are no intervening elements present. It will also be understood that when an element is referred to as being "connected" or "coupled" to another element, it can be directly connected or coupled to the other element or intervening elements may be present. In contrast, when an element is referred to as being "directly connected" or "directly coupled" to another element, there are no intervening elements present.

应该理解,尽管这里可以使用术语第一、第二等等来描述不同的元件、组件、区域、层和/或部分,但是这些元件、组件、区域、层和/或部分不受这些术语的限制。这些术语仅仅用于将一个元件、组件、区域、层或者部分与另一个元件、组件、区域、层或者部分区分开。因而,在不脱离本申请精神的情况下,可以将下文论述的第一元件、组件、区域、层或者部分称作第二元件、组件、区域、层或者部分。It will be understood that, although the terms first, second, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections are not limited by these terms . These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the spirit of the present application.

而且,相对术语,例如“下面”或者“底部”和“上面”或者“顶端”在这里用于描述如附图中展示的一个元件与另一个元件的关系。应该理解相对术语除了包括附图中所述的方向外还包括器件的不同方向。例如,如果翻转图中的器件,则被描述为在另一元件的下边的元件变为在另一个元件的上边。因此示范性术语“下面”根据图的具体方向包括“下面”和“上面”两个方向。同样地,如果翻转一个图中的装置,描述为“在其他的元件下面”或者“在其他的元件之下”的元件定向为在其它元件上方。因此,示范性术语“在下面”或者“在...之下”包括上面和下面两个方向。Furthermore, relative terms such as "below" or "bottom" and "above" or "top" are used herein to describe one element's relationship to another element as illustrated in the figures. It should be understood that relative terms include different orientations of the device in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as being below other elements would then be above the other elements. The exemplary term "below" thus includes both "below" and "above" directions according to the particular orientation of the figures. Likewise, if the device in one of the figures is turned over, elements described as "below" or "beneath" other elements would be oriented over the other elements. Thus, the exemplary terms "below" or "under" include both an orientation of above and below.

这里参照示意性说明本申请的理想化实施例的横截面图(和/或平面图)来描述本申请的实施例。同样地,可以预计会存在因例如制造工艺和/或容差而导致的与示意图形状的偏离。因而,不将本申请的实施例认为是对这里说明的区域的具体形状的限制,而是包括由例如制造导致的形状的偏差。例如,说明为或者描述为矩形的蚀刻区域典型地具有圆的或者曲线特征。因而,图中说明的区域本质上是示意性的,它们的形状不表示装置区域的精确的形状也不限制本申请的范围。Embodiments of the application are described herein with reference to cross-sectional illustrations (and/or plan views) that are schematic illustrations of idealized embodiments of the application. Likewise, deviations from the schematic shape due to, for example, manufacturing process and/or tolerances, can be expected. Thus, the embodiments of the present application are not to be considered as limitations on the specific shapes of the regions described herein, but rather to include deviations in shapes resulting from, for example, manufacturing. For example, an etched region illustrated or described as a rectangle typically has rounded or curvilinear features. Thus, the regions illustrated in the figures are schematic in nature and their shapes do not represent the precise shape of a region of a device and do not limit the scope of the present application.

除非另有限定,这里使用的全部术语(包括技术和科学名词)与本申请所属领域的普通技术人员通常所理解的具有同样的意义。还应当理解的是术语,例如在常用词典中定义的术语应当被解释为与相关技术的文献中的意义相协调,除非这里清楚地限定外,不解释为理想化或者过分形式意义。本领域的技术人员应当理解,对邻近另一部件配置的结构或功能部件的引用可能具有重叠或者在另一部件之下的部分。Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. It should also be understood that terms, such as those defined in commonly used dictionaries, should be construed to be consistent with the meanings in the related art literature, and not to be construed as idealized or excessively formal, unless expressly defined herein. It will be understood by those skilled in the art that a reference to a structural or functional component disposed adjacent to another component may have portions that overlap or underlie the other component.

本申请公开了一种电容器结构及其制造方法。电容器的每个存储节点上具有一个形状例如可以为半圆筒形的半包围结构的下电极,两个相对的半包围结构的下电极组成一个围绕上电极的下电极对,以及通过本领域技术可以得到的任何适宜的形状。以下的实施例以具有半圆筒形的半包围结构的下电极形成的电容器为例,但本申请并不限制于此,具体的电容器结构和制程工艺如下:The present application discloses a capacitor structure and a manufacturing method thereof. Each storage node of the capacitor has a lower electrode with a semi-circumferential structure that can be, for example, a semi-cylindrical shape, and the lower electrodes of the two opposite semi-circumferential structures form a pair of lower electrodes surrounding the upper electrode, and through the techniques in the art any suitable shape obtained. The following embodiments take a capacitor formed by a lower electrode having a semi-cylindrical semi-enclosed structure as an example, but the present application is not limited to this. The specific capacitor structure and manufacturing process are as follows:

如图1h和图2所示,本申请实施方式中示例了一种包括电容器结构的半导体器件,该半导体器件可用于例如某种电子设备,电子设备可以是智能电话、计算机、平板电脑、可穿戴智能设备、人工智能设备、移动电源等等。半导体器件包括半导体基底,例如MOS(MetalOxide Semiconductor)晶体管的电路元件的半导体基底,半导体基底上例如形成有栅极、源/漏极、位线等功能部件(未图示)。半导体基底上形成有层间绝缘层201(InterlayerInsulation);在层间绝缘层201上形成有存储节点接触部202(Storage Node)。在每个存储节点接触部202上部可以形成有一个下电极209,本实施方式中的下电极208具有例如是半圆筒状呈C形的开口半包围结构,并且,位于两个相邻的存储节点之上的两个下电极209A和下电极209B的C形的开口镜像相对,形成一个下电极对,该下电极对围绕在上电极210的周侧,在下电极209A、下电极209B和上电极219之间均形成有介电层210,将三者彼此分割开来。如此,下电极209A与上电极211以及下电极209B与上电极211形成了两个独立的电容器存储单元。从整体看,在与半导体基底平行的截面上,所有下电极可以沿第一方向呈平行的线性排列,并且这些线性排列的下电极在相邻两条线上呈交错分布;同时,所有上电极也可以沿与第一方向垂直的第二方向呈平行的线性排列,并且这些线性排列的上电极在相邻两条线上也呈交错分布。在其他的实施例中,也可以使得,在与半导体基底平行的截面上,在同一线上的上电极两两相连成为一个整体,或者还可以使得,在同一线上的所有上电极彼此相连成为一个整体。As shown in FIG. 1h and FIG. 2 , a semiconductor device including a capacitor structure is exemplified in the embodiments of the present application, and the semiconductor device can be used in, for example, a certain electronic device, and the electronic device can be a smart phone, a computer, a tablet computer, a wearable Smart devices, artificial intelligence devices, power banks, etc. The semiconductor device includes a semiconductor substrate, such as a semiconductor substrate of a circuit element of a MOS (MetalOxide Semiconductor) transistor, on which functional components (not shown) such as gate, source/drain, and bit lines are formed, for example. An interlayer insulating layer 201 (Interlayer Insulation) is formed on the semiconductor substrate; a storage node contact portion 202 (Storage Node) is formed on the interlayer insulating layer 201 . A lower electrode 209 may be formed on the upper portion of each storage node contact portion 202. In this embodiment, the lower electrode 208 has, for example, a semi-cylindrical C-shaped opening and semi-surrounding structure, and is located at two adjacent storage nodes. The upper two lower electrodes 209A and the C-shaped openings of the lower electrodes 209B are mirror images opposite to each other, forming a lower electrode pair, which surrounds the peripheral side of the upper electrode 210, and the lower electrode 209A, the lower electrode 209B and the upper electrode 219. A dielectric layer 210 is formed therebetween to separate the three from each other. In this way, the lower electrode 209A and the upper electrode 211 and the lower electrode 209B and the upper electrode 211 form two independent capacitor storage units. Viewed as a whole, on a cross section parallel to the semiconductor substrate, all the lower electrodes may be linearly arranged in parallel along the first direction, and these linearly arranged lower electrodes are staggered on two adjacent lines; at the same time, all the upper electrodes It can also be linearly arranged in parallel along a second direction perpendicular to the first direction, and these linearly arranged upper electrodes are also staggered on two adjacent lines. In other embodiments, on a cross section parallel to the semiconductor substrate, the upper electrodes on the same line can be connected to each other to form a whole, or all the upper electrodes on the same line can be connected to each other to form a whole. A whole.

接下来,参照图1a-1h所示,将进一步详细介绍根据本申请的一个实施例公开的,上述半导体器件的制程工艺和所采用的材料:Next, referring to FIGS. 1a-1h, the process technology and materials used for the above-mentioned semiconductor device disclosed according to an embodiment of the present application will be described in further detail:

本申请的制程工艺,可以先提供已经形成有例如BCAT(Buried Channel ArrayTransistor)晶体管的电路元件的半导体衬底,半导体衬底上例如形成有栅极、源/漏极、位线等功能部件(未图示)。The process technology of the present application can first provide a semiconductor substrate on which circuit elements such as BCAT (Buried Channel Array Transistor) transistors have been formed, and on the semiconductor substrate, for example, functional components such as gates, source/drain, and bit lines are formed (not shown). icon).

如图1a所示,半导体衬底上可以形成有层间绝缘层201(InterlayerInsulation);在层间绝缘层201上形成有存储节点202(Storage Node),存储节点202(Storage Node)可以由W或Co等材料所构成。As shown in FIG. 1a, an interlayer insulating layer 201 (InterlayerInsulation) may be formed on the semiconductor substrate; a storage node 202 (Storage Node) may be formed on the interlayer insulating layer 201, and the storage node 202 (Storage Node) may be composed of W or Co and other materials.

随后,可以在层间绝缘层201和存储节点202的表面上形成牺牲模层203(Mold),所述牺牲模层203常见使用氧化物,即为氧化物牺牲模层(Mold Oxide),其材料可包含掺杂氧化物,例如,SiO2、SiOH、PSG(Phosphosilicate glass,磷硅酸盐玻璃)、BPSG(Borophosphosilicate glass,硼磷硅酸盐玻璃)、SiCOH、TEOS(Tetraethylorthosilicate,正硅酸乙酯)中的任意一种或两种以上的组合;牺牲模层也可以采用复数层的层状结构,例如TEOS的层状结构。牺牲模层可以通过化学气相沉积(CVD)、低压化学气相沉积(LPCVD)或等离子增强化学气相沉积(PECVD)等适宜的工艺。Then, a sacrificial mold layer 203 (Mold) can be formed on the surface of the interlayer insulating layer 201 and the storage node 202 , and the sacrificial mold layer 203 is usually made of oxide, that is, an oxide sacrificial mold layer (Mold Oxide). May contain doped oxides, for example, SiO2, SiOH, PSG (Phosphosilicate glass, phosphosilicate glass), BPSG (Borophosphosilicate glass, borophosphosilicate glass), SiCOH, TEOS (Tetraethylorthosilicate, ethyl orthosilicate) Any one or a combination of two or more of the above; the sacrificial mold layer can also adopt a layered structure of multiple layers, such as the layered structure of TEOS. The sacrificial mold layer can be formed by a suitable process such as chemical vapor deposition (CVD), low pressure chemical vapor deposition (LPCVD), or plasma enhanced chemical vapor deposition (PECVD).

随后,可以在氧化物牺牲模层203表面形成硬掩模层204(HM,Hard Mask),硬掩模层可以包括利用CVD工艺形成的多晶硅(Poly-Si)、掺杂硅(Dope-Si)、无定形碳(ACL)、旋涂硅(SOH)层等常见的硬掩模材料。在其他实施例中,也可以不形成硬掩模层而直接采用光刻胶层进行图案化和随后的刻蚀。Subsequently, a hard mask layer 204 (HM, Hard Mask) may be formed on the surface of the oxide sacrificial mold layer 203, and the hard mask layer may include polysilicon (Poly-Si), doped silicon (Dope-Si) formed by a CVD process , Amorphous carbon (ACL), spin-on silicon (SOH) layers and other common hard mask materials. In other embodiments, a photoresist layer may be directly used for patterning and subsequent etching without forming a hard mask layer.

随后,可以在硬掩模层204表面形成光刻胶层205(PR,PhotoResist),光刻胶层可以采用例如旋涂工艺等形成;随后,可以通过显影工艺图案化光刻胶层205,以暴露出硬掩模层204的表面。去除光刻胶部分的掩模图案如图3所示,该掩模图案由多个呈矩形的下电极凹槽掩模图案单元组成,该多个下电极凹槽掩模图案单元可以在与半导体基底平行的截面上沿第一方向呈平行的线性排列,并且在相邻两条线上呈交错分布;每个下电极凹槽掩模图案单元在与半导体基底平行的截面的投影以基本覆盖两个相邻的存储节点为标准(参考结合图2中的结构所示)。Subsequently, a photoresist layer 205 (PR, PhotoResist) may be formed on the surface of the hard mask layer 204, and the photoresist layer may be formed by, for example, a spin coating process; then, the photoresist layer 205 may be patterned by a developing process to The surface of the hard mask layer 204 is exposed. The mask pattern for removing the photoresist part is shown in Figure 3. The mask pattern is composed of a plurality of rectangular lower electrode groove mask pattern units. The plurality of lower electrode groove mask pattern units can be The parallel cross-section of the substrate is in parallel linear arrangement along the first direction, and is staggered on two adjacent lines; the projection of each lower electrode groove mask pattern unit on the cross-section parallel to the semiconductor substrate substantially covers two Adjacent storage nodes are standard (reference is shown in conjunction with the structure in Figure 2).

如图1b所示,随后,可以采用常规的刻蚀手段,根据图3所示的掩模图案进行图案化的光刻胶层205,对硬掩模层204和牺牲模层203进行刻蚀处理以得到下电极凹槽206,下电极凹槽206的俯视图截面结构可以结合图2和3所示,其中下电极凹槽掩模图案单元的矩形框基本对应下电极凹槽的位置,也即下电极凹槽206的刻蚀可以以凹槽的底部基本暴露出两个相邻的存储节点202的全部表面为标准。刻蚀可采用常规的干法刻蚀工艺,例如,采用CH2F2/O2/Ar/CHF3的含氟气体的干法刻蚀工艺;也可以采用常规的湿法刻蚀工艺,例如,包括HF和NH4F的混合缓冲溶液,比如,以约1∶6至1∶10的比例混合了HF∶NH4F的LAL溶液。As shown in FIG. 1b, then, conventional etching methods can be used to etch the hard mask layer 204 and the sacrificial mold layer 203 on the photoresist layer 205 patterned according to the mask pattern shown in FIG. 3 . In order to obtain the lower electrode groove 206, the cross-sectional structure of the top view of the lower electrode groove 206 can be combined as shown in FIGS. 2 and 3, wherein the rectangular frame of the lower electrode groove mask pattern unit basically corresponds to the position of the lower electrode groove, that is, the lower electrode groove. The etching of the electrode grooves 206 may be based on the fact that the bottoms of the grooves substantially expose the entire surfaces of the two adjacent storage nodes 202 . The etching can use a conventional dry etching process, for example, a dry etching process using a fluorine-containing gas of CH 2 F 2 /O 2 /Ar/CHF 3 ; a conventional wet etching process can also be used, such as , including a mixed buffer solution of HF and NH4F, eg, a LAL solution of HF:NH4F mixed in a ratio of about 1 : 6 to 1:10.

随后,可以去除硬掩模层204和光刻胶层205,例如采用常规的灰化工艺等除去手段。Subsequently, the hard mask layer 204 and the photoresist layer 205 may be removed, for example, using conventional ashing processes and other removal means.

如图1c所示,随后,可以在下电极凹槽206中沉积下电极材料以填满下电极凹槽206并覆盖牺牲模层203,形成下电极层207(Bottom Electrode);由于当前技术通常采用高介电常数的介电材料,例如,Ta2O5、Al2O3和/或者HfO2等用作电容器的介电层,而介电材料与多晶硅电极之间的界面质量可能降低。特别是,介电材料与多晶硅电极之间的界面质量可能随着介电常数的升高而降低,因此,可以采用高功函(work function)的金属,例如,TiNx、TaNx、WNx等难熔金属材料中的任意一种或两种以上的组合作下电极,以代替传统的多晶硅电极。沉积工艺可以采用常见的CVD、PECVD、ALD(原子层气相沉积)等工艺。As shown in FIG. 1c, subsequently, a lower electrode material may be deposited in the lower electrode groove 206 to fill the lower electrode groove 206 and cover the sacrificial mold layer 203 to form a lower electrode layer 207 (Bottom Electrode); Dielectric materials of dielectric constant, such as Ta 2 O 5 , Al 2 O 3 and/or HfO 2 , etc. are used as the dielectric layers of capacitors, and the quality of the interface between the dielectric materials and the polysilicon electrodes may be degraded. In particular, the quality of the interface between the dielectric material and the polysilicon electrode may decrease as the dielectric constant increases, therefore, metals with high work function such as TiNx , TaNx , WNx can be used Any one or a combination of two or more refractory metal materials is used as the lower electrode to replace the traditional polysilicon electrode. The deposition process may adopt common CVD, PECVD, ALD (atomic layer vapor deposition) and other processes.

如图1d所示,随后,可以对下电极层的表面进行化学机械平坦化(ChemicalMechanical Polish,CMP)处理直至牺牲模层203的顶部表面暴露出来,从而可以将下电极层相互隔离开来。当然也可以采用其他的工艺对下电极层的表面进行回刻(Etch Back)处理,以实现将牺牲模层203的顶部表面暴露出来使得下电极层相互隔离开来,回刻工艺例如是反应离子干法刻蚀工艺(RIE)。As shown in FIG. 1d, then, the surface of the lower electrode layer may be subjected to chemical mechanical planarization (Chemical Mechanical Polish, CMP) treatment until the top surface of the sacrificial mold layer 203 is exposed, so that the lower electrode layers may be isolated from each other. Of course, other processes can also be used to etch back the surface of the lower electrode layer, so as to expose the top surface of the sacrificial mold layer 203 to isolate the lower electrode layers from each other. The etch back process is, for example, reactive ions Dry etching process (RIE).

如图1e所示,随后,可以在下电极层207和牺牲模层203的表面形成硬掩模层204’(HM,Hard Mask),硬掩模层可以包括利用CVD工艺形成的多晶硅(Poly-Si)、掺杂硅(Dope-Si)、无定形碳(ACL)、旋涂硅(SOH)层等常见的硬掩模材料。在其他实施例中,也可以不形成硬掩模层而直接采用光刻胶层进行图案化和随后的刻蚀。As shown in FIG. 1e, subsequently, a hard mask layer 204' (HM, Hard Mask) may be formed on the surfaces of the lower electrode layer 207 and the sacrificial mold layer 203, and the hard mask layer may include polysilicon (Poly-Si) formed by a CVD process. ), doped silicon (Dope-Si), amorphous carbon (ACL), spin-on silicon (SOH) layers and other common hard mask materials. In other embodiments, a photoresist layer may be directly used for patterning and subsequent etching without forming a hard mask layer.

如图1f所示,随后,可以在硬掩模层204’表面形成光刻胶层205’(PR,PhotoResist),光刻胶层可以采用例如旋涂工艺等形成;随后,可以通过显影工艺图案化光刻胶层205’,以暴露出硬掩模层204’的表面,图案化例如可以采用双重图案化技术或者多重图案化技术。去除光刻胶部分的掩模图案如图4a所示,该掩模图案由多个呈“+”十字交叉的上电极凹槽掩模图案单元组成,该多个上电极凹槽掩模图案单元可以在与半导体基底平行的截面上沿与第一方向垂直的第二方向上呈平行的线性排列,并且在相邻两条线上呈交错分布;如图5所示,上电极凹槽掩模图案单元可以与下电极凹槽掩模图案单元一一对应,并且,每个上电极凹槽掩模图案单元在与半导体基底平行的截面上的投影的“+”十字交叉的交叉点以对准相对应的下电极凹槽掩模图案单元在与半导体基底平行的截面上的投影的中心为准,如此,该“+”十字交叉的其中沿第一方向延伸的图案的投影全部落入下电极凹槽掩模图案单元投影的内部,以主要用于在下电极层内形成介电层和上电极的沉积凹槽,而沿第二方向延伸的图案的投影延伸到下电极凹槽掩模图案单元投影的外部,以用于将每一个下电极层单元分“割开”来成为两个独立的下电极以形成围绕上电极的下电极对;在本实施例中,与下电极凹槽掩模图案单元呈矩形相似,上电极凹槽掩模图案单元沿第一方向延伸的图案,以及上电极凹槽掩模图案单元沿第二方向延伸的图案,均呈矩形,并且为实现各自的功能,以下电极凹槽掩模图案单元的宽度大于上电极凹槽掩模图案单元沿第一方向延伸的图案的宽度(从而保证上电极凹槽掩模图案单元沿第一方向延伸的图案全部落入下电极凹槽掩模图案内部),上电极凹槽掩模图案单元沿第一方向延伸的图案的宽度大于上电极凹槽掩模图案单元沿第二方向延伸的图案的宽度(上电极凹槽掩模图案单元沿第二方向延伸的图案能实现“隔开”作用即可),同时,上电极凹槽掩模图案单元沿第二方向延伸的图案的长度至少略大于下电极凹槽掩模图案单元的宽度(从而保证上电极凹槽掩模图案单元沿第二方向延伸的图案延伸到下电极凹槽掩模图案的外部以保证“隔开”)。在其他的实施例中,也可以如图4b所示,将同一线上相邻的“+”十字交叉两两相连,可以使得图案化工艺变得更为简单易行,在不影响器件性能的前提下减小工艺难度;并且进一步在其他的实施例中,还可以如图4c所示,将同一线上的所有“+”十字交叉彼此相连,以进一步简化图案和工艺。As shown in FIG. 1f, subsequently, a photoresist layer 205' (PR, PhotoResist) can be formed on the surface of the hard mask layer 204', and the photoresist layer can be formed by, for example, a spin coating process; The photoresist layer 205 ′ is exposed to expose the surface of the hard mask layer 204 ′. For example, the patterning can be performed by a double patterning technique or a multi-patterning technique. The mask pattern for removing the photoresist part is shown in Figure 4a, the mask pattern is composed of a plurality of upper electrode groove mask pattern units crossed by "+", and the plurality of upper electrode groove mask pattern units It can be in a parallel linear arrangement along a second direction perpendicular to the first direction on a cross-section parallel to the semiconductor substrate, and in a staggered distribution on two adjacent lines; as shown in FIG. 5, the upper electrode groove mask The pattern units may be in one-to-one correspondence with the lower electrode groove mask pattern units, and the intersections of the "+" crosses of the projections of each upper electrode groove mask pattern unit on a cross-section parallel to the semiconductor substrate are aligned to align The center of the projection of the corresponding lower electrode groove mask pattern unit on the cross-section parallel to the semiconductor substrate is the criterion, so that the projection of the pattern extending in the first direction of the "+" cross all falls into the lower electrode The inside of the projection of the groove mask pattern unit to be mainly used to form the deposition grooves of the dielectric layer and the upper electrode in the lower electrode layer, and the projection of the pattern extending in the second direction extends to the lower electrode groove mask pattern unit The outside of the projection is used to "cut" each lower electrode layer unit into two independent lower electrodes to form a lower electrode pair surrounding the upper electrode; in this embodiment, with the lower electrode groove mask The pattern unit is similar to a rectangle, and the pattern of the upper electrode groove mask pattern unit extending in the first direction and the pattern of the upper electrode groove mask pattern unit extending in the second direction are all rectangular, and in order to achieve their respective functions, The width of the lower electrode groove mask pattern unit is greater than the width of the pattern extended along the first direction by the upper electrode groove mask pattern unit (so as to ensure that all the patterns of the upper electrode groove mask pattern unit extending along the first direction fall into the lower Inside the electrode groove mask pattern), the width of the pattern extended in the first direction by the upper electrode groove mask pattern unit is greater than the width of the pattern extended in the second direction by the upper electrode groove mask pattern unit (the upper electrode groove mask pattern unit is extended in the second direction). The pattern of the mold pattern unit extending in the second direction can achieve a "separation" effect), and at the same time, the length of the pattern extended in the second direction by the upper electrode groove mask pattern unit is at least slightly larger than that of the lower electrode groove mask pattern. The width of the cells (thereby ensuring that the pattern of the upper electrode groove mask pattern cells extending in the second direction extends outside the lower electrode groove mask pattern to ensure "spaced apart"). In other embodiments, as shown in FIG. 4b, adjacent “+” crosses on the same line may be connected two by two, which can make the patterning process simpler and easier, without affecting the performance of the device. On the premise, the difficulty of the process is reduced; and further in other embodiments, as shown in FIG. 4c , all “+” crosses on the same line may be connected to each other to further simplify the pattern and process.

随后,可以采用常规的刻蚀手段,根据图案化的光刻胶层205’,对硬掩模层204’和下电极层207进行刻蚀处理以得到上电极凹槽208,上电极凹槽208的横截面俯视图可以与如图4a、4b或4c所示对应,上电极凹槽208的底部以暴露出两个相邻的存储节点202的表面为标准,刻蚀后将每个下电极层207分割形成了两个半圆筒状呈C形的开口的半包围结构的下电极209A和209B。刻蚀可采用常规的干法刻蚀工艺,例如,采用CH2F2/O2/Ar/CHF3的含氟气体的干法刻蚀工艺;也可以采用常规的湿法刻蚀工艺,例如,包括HF和NH4F的混合缓冲溶液,比如,以约1∶6至1∶10的比例混合了HF∶NH4F的LAL溶液。Then, conventional etching methods can be used to etch the hard mask layer 204 ′ and the lower electrode layer 207 according to the patterned photoresist layer 205 ′ to obtain the upper electrode groove 208 and the upper electrode groove 208 4a, 4b or 4c, the bottom of the upper electrode groove 208 is based on the exposed surface of the two adjacent storage nodes 202. After etching, each lower electrode layer 207 The lower electrodes 209A and 209B are divided to form two semi-cylindrical C-shaped openings with a semi-surrounding structure. The etching can use a conventional dry etching process, for example, a dry etching process using a fluorine-containing gas of CH 2 F 2 /O 2 /Ar/CHF 3 ; a conventional wet etching process can also be used, such as , including a mixed buffer solution of HF and NH4F, eg, a LAL solution of HF:NH4F mixed in a ratio of about 1 : 6 to 1:10.

随后,可以去除硬掩模层204’和光刻胶层205’,例如采用常规的灰化工艺等除去手段。Subsequently, the hard mask layer 204' and the photoresist layer 205' may be removed, for example, using conventional ashing processes and other removal means.

如图1g所示,随后,可以在上电极凹槽208内壁和下电极(包括209A和209B的所有下电极)以及牺牲模层203的表面沉积高介电材料以形成介电层210;高介电材料可以采用AlOx、HfOx、ZrOx、TaOx等中的任意一种或两种以上的组合;沉积工艺例如为ALD工艺。As shown in FIG. 1g, subsequently, a high dielectric material may be deposited on the inner wall of the upper electrode groove 208 and the lower electrode (including all the lower electrodes of 209A and 209B) and the surface of the sacrificial mold layer 203 to form a dielectric layer 210; The electrical material can be any one or a combination of two or more of AlO x , HfO x , ZrO x , TaO x , etc. The deposition process is, for example, an ALD process.

如图1h所示,随后,可以在介电层210表面沉积上电极材料以覆盖介电层210并填充上电极凹槽208,以形成上电极211;上电极材料采用金属W或者掺杂硅等。沉积工艺可以为CVD、PECVD等。如此,如横截面俯视图图2所示,即可得到,在每个存储节点202上部形成有一个下电极209,下电极209具有半圆筒状呈C形的半包围结构,并且,半圆筒状呈C形的开口部镜像相对,从而使得位于两个相邻的存储节点之上的两个下电极209A和下电极209B形成一个下电极对,该下电极对围绕在上电极211的周侧,在下电极209A、下电极209B和上电极211之间均形成有介电层210,将三者彼此分割开来,下电极209A与上电极211以及下电极209B与上电极211形成了两个独立的电容器存储单元。当然,基于图案化的不同,也可以得到沿第二方向同一线上相邻的上电极在整个与半导体基底垂直方向上都两两相连成为一个整体的电容器,即相当于四个下电极(两个下电极对)对应于该在整个与半导体基底垂直方向上成为一个整体的上电极;还可以使得沿第二方向同一线上的所有上电极在整个与半导体基底垂直方向上彼此相连成为一个整体,即相当于同一列上的所有下电极对对应于该在整个与半导体基底垂直方向上成为一个整体的上电极。As shown in FIG. 1h, subsequently, an upper electrode material can be deposited on the surface of the dielectric layer 210 to cover the dielectric layer 210 and fill the upper electrode groove 208 to form the upper electrode 211; the upper electrode material is metal W or doped silicon, etc. . The deposition process may be CVD, PECVD, or the like. In this way, as shown in the cross-sectional plan view in FIG. 2 , it can be obtained that a lower electrode 209 is formed on the upper part of each storage node 202 . The lower electrode 209 has a semi-cylindrical C-shaped semi-enclosed structure, and the semi-cylindrical shape is The C-shaped openings are mirrored opposite, so that the two lower electrodes 209A and 209B located on the two adjacent storage nodes form a lower electrode pair that surrounds the peripheral side of the upper electrode 211, and A dielectric layer 210 is formed between the electrode 209A, the lower electrode 209B and the upper electrode 211 to separate the three from each other. The lower electrode 209A and the upper electrode 211 and the lower electrode 209B and the upper electrode 211 form two independent capacitors storage unit. Of course, based on the difference in patterning, it is also possible to obtain a capacitor in which the adjacent upper electrodes on the same line along the second direction are connected in pairs in the vertical direction to the semiconductor substrate to form a whole, that is, equivalent to four lower electrodes (two A pair of lower electrodes) corresponds to the upper electrode that is integrated in the entire vertical direction to the semiconductor substrate; it is also possible to make all the upper electrodes on the same line along the second direction to be connected to each other in the entire vertical direction to the semiconductor substrate. , that is, all the lower electrode pairs on the same column correspond to the upper electrodes that are integrated in the vertical direction to the semiconductor substrate.

本申请中的制造方法得到的电容器及半导体器件,能够在保证电容器存储单位存储能力等器件性能前提下,有效减少制造工艺的难度,并且在简化工艺的基础上,突破了传统6F2沟槽工艺方式的限制,从而减小了电容器之间的间隙,制备得到比现有电容器更小的尺寸,提高了半导体器件的集成度。The capacitor and semiconductor device obtained by the manufacturing method in the present application can effectively reduce the difficulty of the manufacturing process on the premise of ensuring the device performance such as the storage capacity of the capacitor storage unit, and on the basis of simplifying the process, break through the traditional 6F2 trench process method Therefore, the gap between the capacitors is reduced, the size of the capacitor is smaller than that of the existing capacitor, and the integration degree of the semiconductor device is improved.

在以上的描述中,对于各层的构图、刻蚀等技术细节并没有做出详细的说明。但是本领域技术人员应当理解,可以通过各种技术手段,来形成所需形状的层、区域等。另外,为了形成同一结构,本领域技术人员还可以设计出与以上描述的方法并不完全相同的方法。另外,尽管在以上分别描述了各实施例,但是这并不意味着各个实施例中的措施不能有利地结合使用。In the above description, technical details such as patterning and etching of each layer are not described in detail. However, those skilled in the art should understand that various technical means can be used to form layers, regions, etc. of desired shapes. In addition, in order to form the same structure, those skilled in the art can also design methods that are not exactly the same as those described above. Additionally, although the various embodiments have been described above separately, this does not mean that the measures in the various embodiments cannot be used in combination to advantage.

以上对本公开的实施例进行了描述。但是,这些实施例仅仅是为了说明的目的,而并非为了限制本公开的范围。本公开的范围由所附权利要求及其等价物限定。不脱离本公开的范围,本领域技术人员可以做出多种替代和修改,这些替代和修改都应落在本公开的范围之内。Embodiments of the present disclosure have been described above. However, these examples are for illustrative purposes only, and are not intended to limit the scope of the present disclosure. The scope of the present disclosure is defined by the appended claims and their equivalents. Without departing from the scope of the present disclosure, those skilled in the art can make various substitutions and modifications, and these substitutions and modifications should all fall within the scope of the present disclosure.

Claims (15)

1. A capacitor structure, comprising:
a semiconductor substrate;
a plurality of storage node contacts on the semiconductor substrate;
each storage node contact part is provided with a lower electrode of a semi-surrounding structure, and each two opposite lower electrodes of the semi-surrounding structure form a pair of lower electrode pairs surrounding the upper electrode;
the two opposite lower electrodes and the upper electrodes of the lower electrode pair are separated by a dielectric layer.
2. The capacitor structure of claim 1, wherein:
on a cross section parallel to the semiconductor substrate, the lower electrodes are linearly arranged in parallel along a first direction, and the upper electrodes are linearly arranged in parallel along a second direction perpendicular to the first direction.
3. A capacitor structure according to claim 2, characterized in that:
the lower electrodes in linear arrangement are in staggered distribution on two adjacent lines; or, the lower electrodes arranged linearly are distributed in a staggered manner on two adjacent lines, and the upper electrodes arranged linearly are distributed in a staggered manner on two adjacent lines.
4. A capacitor structure according to claim 2, characterized in that:
the upper electrodes on the same line are connected into a whole in pairs; alternatively, all the upper electrodes on the same line are connected to each other as a single body.
5. The capacitor structure of any one of claims 1-4, wherein:
and on a section parallel to the semiconductor substrate, each two opposite lower electrodes of the semi-surrounding structure are in opposite C shapes.
6. A method for manufacturing a capacitor structure comprises the following process steps:
providing a semiconductor substrate, wherein a storage node contact part is arranged on the semiconductor substrate;
forming a sacrificial mold layer on a semiconductor substrate;
etching the sacrificial mold layer to form a plurality of lower electrode grooves, and exposing the surfaces of two adjacent storage node contact parts in each lower electrode groove;
depositing a lower electrode layer to fill the lower electrode groove, and then carrying out chemical mechanical planarization treatment or back etching treatment to expose the sacrificial mold layer;
etching the lower electrode layer and the sacrificial mold layer to form an upper electrode groove, wherein the upper electrode groove divides the lower electrode layer into a pair of opposite lower electrodes with a semi-surrounding structure;
and forming a dielectric layer and an upper electrode in the upper electrode groove.
7. The manufacturing method according to claim 6, characterized in that:
when the sacrificial film layer is etched to form a plurality of lower electrode grooves, the adopted plurality of lower electrode groove mask pattern units are linearly arranged on the section parallel to the semiconductor substrate along the first direction in a parallel mode, and the lower electrode groove mask pattern units are distributed in a staggered mode on two adjacent lines.
8. The manufacturing method according to claim 7, characterized in that:
when the lower electrode layer and the sacrificial mold layer are etched to form the upper electrode groove, a plurality of upper electrode groove mask pattern units which correspond to the lower electrode groove mask pattern units one by one are adopted, the upper electrode groove mask pattern units are linearly arranged in parallel along a second direction perpendicular to the first direction on a cross section parallel to the semiconductor substrate, each upper electrode groove mask pattern unit is approximately in a cross shape of a plus sign, the cross point of the projection of each upper electrode groove mask pattern unit on the cross section parallel to the semiconductor substrate of the plus sign is aligned with the center of the projection of the corresponding lower electrode groove mask pattern unit on the cross section parallel to the semiconductor substrate, the projections of the patterns extending along the first direction of the plus sign all fall into the projection of the lower electrode groove mask pattern units, and the projections of the patterns extending along the second direction extend to the outside of the projection of the lower electrode groove mask pattern units.
9. The manufacturing method according to claim 8, characterized in that:
every two adjacent pattern units which are crossed in a plus shape and are on the same line in the second direction are connected; alternatively, all pattern units crossing at a "+" cross on the same line in the second direction are connected to each other.
10. The manufacturing method according to claim 8, characterized in that:
the pattern of the lower electrode groove mask pattern unit, the pattern of the upper electrode groove mask pattern unit extending along the first direction and the pattern of the upper electrode groove mask pattern unit extending along the second direction are rectangular, and the width of the pattern of the upper electrode groove mask pattern unit extending along the first direction is larger than the width of the pattern of the upper electrode groove mask pattern unit extending along the second direction.
11. The manufacturing method according to claim 6, characterized in that:
the etching is carried out according to the patterned photoresist layer and the mask layer; alternatively, the etching is performed only on the basis of a patterned photoresist layer.
12. The manufacturing method according to claim 11, characterized in that:
the patterning is performed by double patterning (double patterning) or multiple patterning (multiple patterning) techniques.
13. A semiconductor device comprising a capacitor structure according to any one of claims 1 to 5 or a capacitor structure produced by the method of manufacture according to any one of claims 6 to 12.
14. An electronic device comprising the semiconductor device according to claim 13.
15. The electronic device of claim 14, comprising a smartphone, a computer, a tablet, a wearable smart device, an artificial smart device, a mobile power source.
CN202110396408.5A 2021-04-13 2021-04-13 Capacitor, semiconductor device, electronic device, and manufacturing method thereof Pending CN115206970A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024146036A1 (en) * 2023-01-05 2024-07-11 长鑫存储技术有限公司 Semiconductor structure and preparation method therefor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024146036A1 (en) * 2023-01-05 2024-07-11 长鑫存储技术有限公司 Semiconductor structure and preparation method therefor

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