CN115204563A - An evaluation method suitable for sandstone-type uranium ore prospecting target layers - Google Patents
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Abstract
Description
技术领域technical field
本发明属于盆地内砂岩型铀矿找矿技术方法领域,具体涉及一种适用于砂岩型铀矿找矿目标层的评价方法。The invention belongs to the field of prospecting technical methods for sandstone-type uranium deposits in a basin, and particularly relates to an evaluation method suitable for a prospecting target layer of sandstone-type uranium deposits.
背景技术Background technique
沉积盆地砂岩型铀矿资源调查和评价早期阶段需要综合评价找矿目标层不同岩石地球化学带内岩石的元素、矿物和地球化学特征,进而客观评价其铀成矿潜力。其中,不同岩石地球化学带内岩石样品的合理采集以及是否有代表性直接关系到目的层成矿前景的科学评价和有利远景区的预测。In the early stage of investigation and evaluation of sandstone-type uranium ore resources in sedimentary basins, it is necessary to comprehensively evaluate the elements, minerals and geochemical characteristics of rocks in different rock-geochemical zones in the prospecting target layer, and then objectively evaluate their uranium metallogenic potential. Among them, the reasonable collection and representativeness of rock samples in different petro-geochemical zones are directly related to the scientific evaluation of the metallogenic prospects of the target layer and the prediction of favorable prospects.
铀矿地质工作者以往通常采用捡块或劈心法选择性的分别采集目标层不同地球化学带内的部分砂岩样品后直接进行全岩测试分析和评价,但这样获得的数据代表性存在一定的不足,进而对评价其成矿潜力有较大影响。例如,当样品采集的位置刚好处于地层中碳屑或黄铁矿极其发育地带,其有机碳或全硫含量就会极高,从而得出目标层还原容量高的结论,反之则又可能极低,会用来指示目标层还原能力弱,这样可能无法全面合理代表该层位真实的地质地球化学特征;而目标层中的粗粒、中粒、细粒等不同粒度砂岩的各类测试结果也存在很大差异,可对比性较差。同时,浅部(半)开放体系下含矿层中的后期成矿过程中发生的流-岩反应强度多是黏土级别,一般仅会导致砂岩中的细粒杂基成分发生变化;而砂岩本身的石英、长石及各类岩屑主体成分常常会掩盖这些较微弱的地质地球化学含量变化信息,干扰后期流体改造特征、程度的合理评价,从而无法准确发现可能存在的流体后生改造和铀成矿作用信息;此外,过去地质人员多采集容易受后期流体改造的砂岩样品,而不注重目标层中泥岩样品的采集和分析,这样可能会影响对目标层原生地质地球化学特征的准确判别。In the past, uranium mine geologists usually used the block picking or core splitting method to selectively collect some sandstone samples in different geochemical zones of the target layer, and then directly conduct whole-rock testing, analysis and evaluation. However, the representativeness of the data obtained in this way has certain limitations. Insufficient, and then have a greater impact on the evaluation of its metallogenic potential. For example, when a sample is collected in a zone where carbon cuttings or pyrite are extremely developed in the formation, the organic carbon or total sulfur content will be extremely high, leading to the conclusion that the reduction capacity of the target layer is high, and vice versa, it may be extremely low , will be used to indicate that the reduction ability of the target layer is weak, which may not fully and reasonably represent the real geological and geochemical characteristics of the layer; and various test results of the coarse-grained, medium-grained, and fine-grained sandstones in the target layer are also There are large differences and poor comparability. At the same time, the flow-rock reaction intensity in the later metallogenic process in the ore-bearing layer under the shallow (semi) open system is mostly clay level, which generally only leads to the change of the fine-grained matrix composition in the sandstone; The main components of quartz, feldspar, and various types of cuttings often cover up these weaker information on changes in geological and geochemical content, interfere with the reasonable evaluation of the characteristics and extent of fluid transformation in the later stage, and thus fail to accurately discover possible fluid epigenetic transformation and uranium mineralization. In addition, in the past, geologists mostly collected sandstone samples that were easily modified by later fluids, but did not pay attention to the collection and analysis of mudstone samples in the target layer, which may affect the accurate identification of the original geochemical characteristics of the target layer.
因此,以上因素均会不同程度影响对铀矿勘查区整个找矿目标层铀成矿潜力的准确客观评价,从而可能误判或遗漏有效的找矿目标层位。Therefore, the above factors will affect the accurate and objective evaluation of the uranium metallogenic potential of the entire prospecting target layer in the uranium exploration area to varying degrees, so that the effective prospecting target layer may be misjudged or omitted.
当前,针对盆地砂岩型铀矿找矿目标层不同研究目的样品采集的方法并未有发表过相关文献和也未见申请过相关专利,其一般的样品采集主要借鉴和采用的是传统地质学研究的样品采集手段和方法。然而,上述方法并未从砂岩铀成矿规律和基本特征方面全面考虑,在针对砂岩型铀矿调查评价前期找矿目标层样品采集的适用方面仍存在一些问题和不足。At present, no relevant literature has been published and no relevant patents have been applied for the methods of sample collection for different research purposes in the sandstone-type uranium ore prospecting target layers in the basin, and the general sample collection is mainly based on traditional geological research. methods and methods of sample collection. However, the above methods do not comprehensively consider the sandstone uranium metallogenic regularity and basic characteristics, and there are still some problems and deficiencies in the application of sample collection in the early-stage prospecting target layer for the investigation and evaluation of sandstone-type uranium deposits.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种适用于砂岩型铀矿找矿目标层的评价方法,该方法基于砂岩型铀矿成矿规律和岩石地球化学分带特征,提供一种对盆地铀资源调查评价阶段找矿目标层从分带分段等距连续刻槽采集、处理砂-泥岩样品后到基于常规化学分析结果评价成矿环境和潜力的方法流程,获得的样品数据能全面代表目标层的地质地球化学特征,获得的测试数据有利于对比分析,能准确、真实地用于找矿目标层铀成矿潜力和找矿前景的客观评价,合理指导找矿部署。The purpose of the present invention is to provide an evaluation method suitable for the prospecting target layer of sandstone-type uranium deposits. The ore prospecting target layer is from the zonal and segmented equidistant continuous groove collection and processing of sand-mudstone samples to the method and process of evaluating the metallogenic environment and potential based on the results of conventional chemical analysis. The obtained sample data can fully represent the geological earth of the target layer. The chemical characteristics and the obtained test data are conducive to comparative analysis, which can be accurately and truly used to objectively evaluate the uranium metallogenic potential and prospecting prospects of the ore prospecting target layer, and reasonably guide the prospecting deployment.
实现本发明目的的技术方案:The technical scheme that realizes the object of the present invention:
一种适用于砂岩型铀矿找矿目标层的评价方法,所述方法包括以下步骤:An evaluation method suitable for a sandstone-type uranium ore prospecting target layer, the method comprising the following steps:
步骤(1)、盆地铀矿勘查区内找矿目标层的确定;Step (1), determination of the prospecting target layer in the basin uranium exploration area;
步骤(2)、对目标层砂泥岩分别进行岩性地球化学分带;Step (2), carry out lithologic geochemical zoning to target layer sand and mudstone respectively;
步骤(3)、对目标层不同地球化学带内的砂-泥岩进行等距连续刻槽,采集砂岩样品和泥岩样品;Step (3), carry out equidistant continuous grooves on sand-mudstone in different geochemical zones of the target layer, and collect sandstone samples and mudstone samples;
步骤(4)、对采集的砂岩样品进行机械破碎筛分,获得砂岩细粒组分;Step (4), mechanically crushing and sieving the collected sandstone samples to obtain fine-grained components of sandstone;
步骤(5)、对砂岩细粒组分和泥岩样品进行测试分析,获得测试分析结果;Step (5), test and analyze the fine-grained components of the sandstone and the mudstone sample, and obtain the test and analysis results;
步骤(6)、根据测试分析结果进行目标层铀成矿环境和潜力评价。In step (6), the uranium metallogenic environment and potential of the target layer are evaluated according to the test and analysis results.
所述步骤(1)为:根据盆地区域成矿环境分析,在铀矿勘查区确定砂岩型铀矿找矿目标层位,要求区内有钻孔揭露到该层位,且有相应的岩石样品。The step (1) is: according to the analysis of the metallogenic environment in the basin area, determine the target horizon of sandstone-type uranium ore prospecting in the uranium ore exploration area, and require that there are drill holes in the area to expose the horizon, and there are corresponding rock samples. .
所述步骤(2)包括:Described step (2) comprises:
步骤(2.1)、对目标层按砂岩、泥岩进行岩性分段;Step (2.1), carry out lithology segmentation to the target layer according to sandstone and mudstone;
步骤(2.2)、对目标层中砂岩和泥岩进行颜色分段。In step (2.2), color segmentation is performed on the sandstone and mudstone in the target layer.
所述步骤(3)包括:Described step (3) comprises:
步骤(3.1)、对目标层中颜色分段后的砂岩进行连续刻槽,每个颜色分段按样品数需求采集所有粒级的砂岩;Step (3.1), continuously groove the sandstone after color segmentation in the target layer, and collect all grades of sandstone according to the number of samples required for each color segment;
步骤(3.2)、对目标层中颜色分段后的泥岩进行连续刻槽,每个颜色分段按样品数需求采集泥岩。In step (3.2), continuous grooves are performed on the color-segmented mudstone in the target layer, and the mudstone is collected according to the number of samples required for each color segment.
所述步骤(4)为:根据目标层碎屑颗粒大小设定粒度阈值,将采集的砂岩样品机械破碎后分为粗粒组分和细粒组分,保留砂岩的细粒组分The step (4) is: setting a particle size threshold according to the size of the debris particles in the target layer, mechanically breaking the collected sandstone samples into coarse-grained components and fine-grained components, and retaining the fine-grained components of the sandstone.
所述步骤(5)包括:The step (5) includes:
步骤(5.1)、将砂岩细粒组分和泥岩样品粉碎成粉末样品;Step (5.1), crushing the fine-grained components of sandstone and mudstone samples into powder samples;
步骤(5.2)、对粉末样品进行选择性的矿物、元素和环境地球化学分析。Step (5.2), perform selective mineral, elemental and environmental geochemical analysis on the powder sample.
所述步骤(5.2)中的化学分析包括:主量和微量分析、黏土X定量衍射分析、有机碳分析、全硫分析、氧化还原电位分析、pH值分析和酸解烃分析。The chemical analysis in the step (5.2) includes: major and trace analysis, clay X-ray quantitative diffraction analysis, organic carbon analysis, total sulfur analysis, redox potential analysis, pH value analysis and acid hydrolysis hydrocarbon analysis.
所述步骤(6)包括:Described step (6) comprises:
步骤(6.1)、根据环境地球化学指标,评价目标层的后生聚铀能力;Step (6.1), evaluating the epigenetic polyuranium ability of the target layer according to the environmental geochemical index;
步骤(6.2)、根据不同颜色砂岩地球化学指标对比分析,判别目标层后生氧化或次生还原作用特征及强度;Step (6.2), according to the comparative analysis of different colored sandstone geochemical indexes, to discriminate the characteristics and intensity of epigenetic oxidation or secondary reduction of the target layer;
步骤(6.3)、根据砂泥岩地球化学指标对比分析,综合评价调查区找矿目标层的砂岩铀成矿环境和成矿潜力、规模。Step (6.3): According to the comparative analysis of sandstone and mudstone geochemical indicators, comprehensively evaluate the sandstone uranium metallogenic environment, metallogenic potential and scale of the ore prospecting target layer in the investigation area.
本发明的有益技术效果在于:The beneficial technical effect of the present invention is:
1、本发明提供的一种适用于砂岩型铀矿找矿目标层的评价方法,基于砂岩型铀矿成矿特征及典型的岩石地球化学分带模式,分带分段连续刻槽采集砂、泥岩样品,突破了过去仅采集目标层中某一粒级砂岩的局限性,不仅更具代表性,还可节约前期大量样品采集测试的成本;1. A method for evaluating the target layer of sandstone-type uranium ore prospecting provided by the present invention is based on the metallogenic characteristics of sandstone-type uranium deposits and the typical rock-geochemical zoning mode, and the zoning and subsections are continuously grooved to collect sand, Mudstone samples break through the limitation of only collecting a certain grade of sandstone in the target layer in the past, which is not only more representative, but also saves the cost of collecting and testing a large number of samples in the early stage;
2、本发明提供的一种适用于砂岩型铀矿找矿目标层的评价方法,对各粒级混合砂岩样品分别各自进行机械破碎筛分,剔除粗粒组分,有效减少了母岩本身碎屑矿物对后生蚀变分析结果的影响;2. The present invention provides an evaluation method suitable for the target layer of sandstone-type uranium ore prospecting. The mixed sandstone samples of each particle size are respectively subjected to mechanical crushing and screening, and the coarse-grained components are eliminated, which effectively reduces the fragmentation of the parent rock itself. The effect of clastic minerals on the results of epigenetic alteration analysis;
3、本发明提供的一种适用于砂岩型铀矿找矿目标层的评价方法,对砂岩中细粒组分和泥岩进行化学测试,这样获取的测试数据可以全面准确反映目标层真实的铀成矿环境,防止误判或遗漏有效目标层位,指明正确的找矿方向,直接服务于实际生产需求,具有重要的推广应用价值;3. An evaluation method suitable for sandstone-type uranium ore prospecting target layers provided by the present invention conducts chemical tests on fine-grained components and mudstones in sandstone, so that the obtained test data can comprehensively and accurately reflect the real uranium formation of the target layer. Mining environment, prevent misjudgment or omission of effective target horizons, indicate the correct prospecting direction, directly serve the actual production needs, and have important promotion and application value;
4、本发明提供的一种适用于砂岩型铀矿找矿目标层的评价方法,为铀矿地质工作者在砂岩铀矿勘查过程中提供一种用于实验室化学分析所需岩石样品合理采集、处理和评价的方法,进而客观评价找矿目标层的成矿环境和潜力。4. An evaluation method suitable for the prospecting target layer of sandstone-type uranium ore provided by the present invention provides a reasonable method for collecting rock samples required for laboratory chemical analysis for uranium geologists in the process of sandstone-uranium ore exploration. , processing and evaluation methods, and then objectively evaluate the metallogenic environment and potential of the prospecting target layer.
附图说明Description of drawings
图1为本发明所提供的一种适用于砂岩型铀矿找矿目标层的评价方法流程图;Fig. 1 is a kind of evaluation method flow chart that is applicable to sandstone type uranium ore prospecting target layer provided by the present invention;
图2为本发明所提供的松辽盆地南部SL1钻孔姚家组目标层岩性地球化学分带及样品分布图。FIG. 2 is the lithologic geochemical zoning and sample distribution map of the Yaojia Formation target layer of the SL1 drill hole in the southern Songliao Basin provided by the present invention.
具体实施方式Detailed ways
下面结合附图和实施例对本发明作进一步详细说明。The present invention will be described in further detail below with reference to the accompanying drawings and embodiments.
如图1所示,以松辽盆地西南部开鲁坳陷为研究对象,提供一种适用于砂岩型铀矿找矿目标层的评价方法,具体包括以下步骤:As shown in Figure 1, taking Kailu Depression in the southwest of Songliao Basin as the research object, an evaluation method suitable for sandstone-type uranium prospecting target layers is provided, which specifically includes the following steps:
步骤(1)、盆地铀矿勘查区内找矿目标层的确定Step (1), determination of the prospecting target layer in the uranium exploration area of the basin
步骤(1.1)、在某一沉积盆地选择一找矿部位作为研究对象;Step (1.1), select a prospecting site in a sedimentary basin as a research object;
步骤(1.2)、确定铀矿调查区内主要的找矿目标层,要求目标层有钻孔揭露,并能采集到岩石样品。In step (1.2), determine the main prospecting target layers in the uranium ore survey area, and require that the target layers be exposed by drilling holes, and rock samples can be collected.
例如,选择松辽盆地西南部开鲁坳陷为研究对象,以上白垩统姚家组为找矿目标层,并有SL1钻孔揭露到姚家组。For example, the Kailu Depression in the southwest of the Songliao Basin was selected as the research object, the Yaojia Formation of the Upper Cretaceous was the target layer for prospecting, and the Yaojia Formation was exposed by the SL1 drilling hole.
步骤(2)、在上述步骤(1)中选取揭露目标层的钻孔,对目标层砂泥岩分别进行岩性地球化学分带,即岩性、颜色分段Step (2), in the above-mentioned step (1), select the drill hole that exposes the target layer, and carry out lithologic geochemical zoning, i.e., lithology and color segmentation, respectively, on the sand and mudstone of the target layer.
步骤(2.1)、根据上述步骤(1)确定的找矿目标层,对钻孔中目标层按砂岩和泥岩两种岩性进行自上而下依次整体分段;Step (2.1), according to the ore prospecting target layer determined in the above-mentioned step (1), the target layer in the borehole is generally segmented from top to bottom according to two lithologies of sandstone and mudstone;
步骤(2.2)、根据步骤(2.1)分别对目标层中砂岩和泥岩进行颜色分段;Step (2.2), according to step (2.1), color segmentation is performed on the sandstone and mudstone in the target layer respectively;
砂岩各带按颜色不同从上往下依次设为:Sd1、Sd2、Sd3、……、Sdn,岩性包括粗粒、中粒、细粒等不同粒级砂岩;泥岩各带按颜色不同从上往下依次设为:Md1、Md2、Md3、……、Mdm;其中,n、m分别为不同颜色砂、泥岩段总数;当某薄层岩性段厚度小于1m,且在目标层中其它位置含有相似段时,该段可忽略或并入相邻段,否则单独成段。The sandstone belts are set as follows from top to bottom according to different colors: Sd 1 , Sd 2 , Sd 3 ,... Different colors are set as follows from top to bottom: Md 1 , Md 2 , Md 3 ,... , and when other positions in the target layer contain similar segments, the segment can be ignored or merged into the adjacent segment, otherwise it will be a separate segment.
例如,开鲁坳陷SL1钻孔的姚家组找矿目标层埋深在461.5m-596.59m。如图2所示,砂岩类自上而下可分为5段:Sd1(红色砂岩)、Sd2(灰色砂岩)、Sd3(红色砂岩)、Sd4(灰色砂岩)、Sd5(红色砂岩),大致埋深分别为462m-474m、474m-495m、495m-561m、561m-565m、565m-596.59m;泥岩类自上而下可分为7段:Md1、Md2、Md3、Md4、Md5、Md6、Md7,大致埋深分别为:461.5m-500m、500m-502m、502m-534m、534m-537.2m、537.2m-561m、561m-568m、568m-585m。各岩性段内的不同地球化学性质薄层岩性段(一般小于1m)进行了选择性的舍弃和合并,如Sd1红色砂岩段内对埋深472.4m-473.4m、厚度1m的灰色粗砂岩归入到下部相邻的灰色砂岩Sd2段内;而对灰色砂岩Sd4段内埋深564.8m-565.4m、厚度为0.6m的红色粗砂岩进行了舍弃处理。For example, the Yaojia Formation prospecting target layer in the SL1 hole in the Kailu Depression is buried at a depth of 461.5m-596.59m. As shown in Figure 2, sandstones can be divided into 5 sections from top to bottom: Sd 1 (red sandstone), Sd 2 (gray sandstone), Sd 3 (red sandstone), Sd 4 (gray sandstone), Sd 5 (red sandstone) Sandstone), the approximate burial depths are 462m-474m, 474m-495m, 495m-561m, 561m-565m, 565m-596.59m; mudstones can be divided into 7 sections from top to bottom: Md 1 , Md 2 , Md 3 , The approximate burial depths of Md 4 , Md 5 , Md 6 and Md 7 are: 461.5m-500m, 500m-502m, 502m-534m, 534m-537.2m, 537.2m-561m, 561m-568m, 568m-585m. The thin lithological sections with different geochemical properties (generally less than 1m ) in each lithological section are selectively discarded and merged. The sandstone is classified into the adjacent gray sandstone Sd 2 member; the red coarse sandstone with a burial depth of 564.8m-565.4m and a thickness of 0.6m in the gray sandstone Sd 4 member has been discarded.
步骤(3)、对上述步骤(2)中划分好岩性地球化学带的找矿目标层进行不同地球化学带内的砂-泥岩等距刻槽,采集砂岩样品和泥岩样品In step (3), the ore-prospecting target layers that have been divided into lithologic geochemical zones in the above step (2) are subjected to sand-mudstone equidistant grooves in different geochemical zones, and sandstone samples and mudstone samples are collected.
步骤(3.1)、基于上述所述步骤(2)中细分的不同颜色砂岩段,铀矿地质工作者根据实际需求分别对各区段(Sdn)连续刻槽采集一定数量的不同颜色不同粒级砂岩混合样品,各段要求至少采集样品1个及以上;即首先对某一Sdn段按实际需要采集样品数量进行等距离平分成更次一级的小段,之后对每个次一级小段等距离连续刻槽采集所有粒级的砂岩,同一次级小段内的不同粒级砂岩需连续刻槽混合成一个砂岩样品;最后依次登记样品为S1、S2、S3、……、Sa;其中,a为砂岩样品数量。In step (3.1), based on the subdivided sandstone sections of different colors in the above-mentioned step (2), the uranium mine geologists collect a certain number of different colors and different grain grades for each section (Sd n ) continuously grooved according to actual needs. For mixed sandstone samples, each section requires at least one sample to be collected; that is, firstly, a certain Sd n section is divided into smaller sections at equal distances according to the actual number of samples to be collected, and then for each subsection, etc. The sandstones of all grades are collected from the continuous grooves, and the sandstones of different grades in the same sub-section need to be continuously grooved and mixed into a sandstone sample; finally, the registered samples are S 1 , S 2 , S 3 , ..., Sa ; where a is the number of sandstone samples.
步骤(3.2)、基于上述所述步骤(2)中细分的不同颜色泥岩段,铀矿地质工作者根据实际需求分别在各区段(Mdm)连续刻槽采集一定数量的不同颜色泥岩样品,各段要求至少采集样品1个及以上;即首先对某一Mdm段按需要采集样品数量进行等距离平分成次级小段,之后对每一次级小段等距离进行连续刻槽采集泥岩样品,并依次登记为M1、M2、M3、……、Mb;b为泥岩样品数量。Step (3.2), based on the different-color mudstone sections subdivided in the above-mentioned step (2), the uranium mine geologists collect a certain number of different-color mudstone samples in each section (Md m ) according to the actual requirements, continuously grooved, Each section requires at least one sample to be collected; that is, a certain Md m section is firstly divided into sub-sections equidistantly according to the number of samples to be collected, and then each sub-section is continuously grooved at equal distances to collect mudstone samples, and then the mudstone samples are collected. Register as M 1 , M 2 , M 3 , ..., M b in sequence; b is the number of mudstone samples.
例如,松辽盆地南部开鲁坳陷SL1钻孔中的姚家组砂岩取样情况如下:如图2所示,Sd1段埋深为462m-474m,之间的砂岩厚度为10.2m,拟采集2个样品,故该岩性段S1和S2样品刻槽厚度分别为5.1m,取样埋深分别大概在462m-468m、468m-474m;类似的,对埋深在474m-495m、厚度为18.1m的灰色砂岩Sd2段拟采集3个样品,每个样品刻槽厚度在6m左右,故采集的S3、S4、S5样品的深部分别大致在474m-481m、481m-489m、489m-495m;依次类推,在5个砂岩段内共采集了11件样品,它们基本上可以囊括了钻孔中整个姚家组找矿目标层中的所有砂岩。For example, the sampling of the Yaojia Formation sandstone in the SL1 hole in the Kailu Depression in the southern Songliao Basin is as follows: As shown in Figure 2, the burial depth of Sd 1 member is 462m-474m, and the thickness of the sandstone between them is 10.2m. There are 2 samples, so the thickness of the grooves in the samples S 1 and S 2 of this lithological section is 5.1m respectively, and the sampling depths are about 462m-468m and 468m-474m respectively; The 18.1m gray sandstone Sd 2 section is planned to collect 3 samples, and the thickness of each sample is about 6m. Therefore, the depths of the collected S 3 , S 4 , and S 5 samples are roughly 474m-481m, 481m-489m, and 489m, respectively. -495m; and so on, a total of 11 samples were collected in the 5 sandstone sections, and they basically covered all the sandstones in the prospecting target layer of the entire Yaojia Formation in the borehole.
同时,拟对7个泥岩段分别各采集1个样品,样品编号依次设为M1、M2、M3、M4、M5、M6、M7,其埋深和深度情况见表1,由于泥岩孔渗性差,受后期流体改造弱或无,故它们可以全面代表姚家组找矿目标层原生的地质地球化学特征。At the same time, it is planned to collect one sample from each of the seven mudstone sections, and the sample numbers are set to M 1 , M 2 , M 3 , M 4 , M 5 , M 6 , and M 7 in sequence. The burial depth and depth are shown in Table 1. , due to the poor porosity and permeability of mudstone and weak or non-reformed by late fluids, they can comprehensively represent the original geological and geochemical characteristics of the Yaojia Formation prospecting target layer.
表1松辽盆地南部SL1钻孔姚家组目标层砂-泥岩样品测试结果Table 1. Test results of sand-mudstone samples from the target layer of Yaojia Formation in drill hole SL1 in the southern Songliao Basin
备注:姚家组目标层的埋深在461.5m-596.59m。Remarks: The buried depth of the target layer of the Yaojia Formation is 461.5m-596.59m.
步骤(4)、对上述步骤(3)中采集的砂岩样品进行机械破碎筛分,保留砂岩的细粒组分In step (4), the sandstone samples collected in the above step (3) are mechanically crushed and screened to retain the fine-grained components of the sandstone.
基于上述步骤(3.1)中采集的砂岩样品,室内首先进行人工机械破碎,然后根据目标层碎屑颗粒大小设定粒度阈值,将各样品分别分成大于粒度阀值的粗粒组分和小于粒度阀值的细粒组分,剔除粗粒部分,并将相应的细粒组分保留以备后续测试使用,分别编号为S1'、S2'、S3'、……、Sa'。Based on the sandstone samples collected in the above step (3.1), manual and mechanical crushing is first performed in the room, and then the particle size threshold is set according to the size of the clastic particles in the target layer, and each sample is divided into coarse-grained components larger than the particle size threshold and smaller than the particle size threshold. The fine-grained components of the value, the coarse-grained parts are removed, and the corresponding fine-grained components are retained for subsequent testing, and are respectively numbered as S 1 ', S 2 ', S 3 ', ..., S a '.
例如,将区内SL1钻孔中11个姚家组砂岩按120目为粒度阀值进行二分筛选,剔除大于120目的砂岩粗粒部分,保留粒度小于120目的砂岩细粒组分,编号分别为S1'、S2'、S3'、S4'、S5'、S6'、S7'、S8'、S9'、S10'、S11',以便后续测试利用。For example, the 11 Yaojia Formation sandstones in the SL1 borehole in the area are screened according to the grain size threshold of 120 mesh, and the coarse-grained part of sandstone larger than 120 mesh is excluded, and the fine-grained sandstone with grain size smaller than 120 mesh is retained, and the numbers are S respectively. 1 ', S2', S3 ', S4 ', S5 ', S6 ', S7 ', S8 ', S9 ', S10 ' , S11 ' for subsequent test utilization.
步骤(5)、对上述步骤(4)上的砂岩细粒组分和上述步骤(3)的泥岩样品进行测试分析Step (5), test and analyze the fine-grained components of the sandstone in the above-mentioned step (4) and the mudstone sample in the above-mentioned step (3)
步骤(5.1)、基于上述步骤(4)中的砂岩细粒组分样品(Sa')和所述步骤(3.2)中采集的泥岩样品(Mb),首先分别把样品粉碎成200目的粉末样品;之后将粉末样品按不同测试项目分成若干份,每份样品重量需满足对应的测试要求。Step (5.1), based on the sandstone fine-grained component sample (S a ') in the above step (4) and the mudstone sample (M b ) collected in the step (3.2), first pulverize the samples into 200 mesh powder respectively After that, the powder sample is divided into several parts according to different test items, and the weight of each sample must meet the corresponding test requirements.
步骤(5.2)、分别将相应的样品送至实验室进行选择性的矿物、元素和环境地球化学分析;分析总项目包括:主量和微量分析、黏土X定量衍射分析、有机碳分析、全硫分析、氧化还原电位分析、pH值分析和酸解烃分析,获取相应的测试结果;这样则能全面代表整个目标层的地质地球化学特征,且样品均为细粒组分,方便后续对比分析,准确反映目标层后生蚀变特征和强度。Step (5.2), respectively send the corresponding samples to the laboratory for selective mineral, element and environmental geochemical analysis; the total analysis items include: major and trace analysis, clay X-ray quantitative diffraction analysis, organic carbon analysis, total sulfur Analysis, oxidation-reduction potential analysis, pH value analysis and acid hydrolysis hydrocarbon analysis to obtain the corresponding test results; in this way, the geological and geochemical characteristics of the entire target layer can be fully represented, and the samples are all fine-grained components, which is convenient for subsequent comparative analysis. Accurately reflect the epigenetic alteration characteristics and intensity of the target layer.
例如,对松辽盆地西南部开鲁坳陷SL1钻孔姚家组的11件砂岩细粒组分和7件泥岩样品首先粉碎成200目,之后每个样品分成了3份,分别送到相应的实验室进行主微量测试、有机碳测试(C有)和全硫(S全)测试,获取了整个姚家组目标层的元素和环境地球化学指标数据,结果如表1所示。For example, 11 pieces of fine-grained sandstone and 7 pieces of mudstone samples from the Yaojia Formation in the SL1 borehole of Kailu Depression in the southwestern Songliao Basin were first crushed into 200 mesh, and then each sample was divided into 3 parts and sent to the corresponding The laboratory conducted the main trace test, organic carbon test (C with ) and total sulfur (S total ) test, and obtained the elemental and environmental geochemical index data of the target layer of the entire Yaojia Formation. The results are shown in Table 1.
步骤(6)、根据上述步骤(5)获得的测试结果,评价目标层的铀成矿地质地球化学环境和潜力Step (6), according to the test results obtained in the above-mentioned step (5), evaluate the uranium metallogenetic geochemical environment and potential of the target layer
铀矿地质工作者根据上述步骤(5.2)获得的砂岩细粒组分和泥岩的分析测试数据,地质人员基于盆地砂岩型铀矿成矿规律,从砂岩铀成矿特征、规律和模式出发,对不同颜色带砂岩和泥岩的矿物学、元素含量和环境地化指标变化进行综合对比分析,开展对调查区找矿目标层铀成矿地质地球化学环境和成矿潜力的科学评价;具体步骤包括:Uranium geologists based on the analysis and test data of fine-grained components of sandstone and mudstone obtained in the above step (5.2), based on the mineralization law of sandstone-type uranium deposits in the basin, starting from the characteristics, laws and patterns of sandstone uranium mineralization, Comprehensive comparative analysis of changes in mineralogy, element content and environmental geochemical indicators of sandstone and mudstone in different color zones was carried out, and a scientific evaluation of the uranium metallogenic geochemical environment and metallogenic potential of the ore prospecting target layer in the survey area was carried out; the specific steps include:
步骤(6.1)、根据原生灰色泥岩和灰色砂岩细粒组分的铀含量评价目标层的预富集强度和本身含铀性;根据它们的黏土矿物含量差异和特征,查明目标层原生水体环境;根据他们两者之间的环境地球化学指标(C有、S全、Eh等),评价目标层的后生聚铀能力等。Step (6.1), evaluate the pre-enrichment strength and inherent uranium content of the target layer according to the uranium content of the primary gray mudstone and gray sandstone fine-grained components; identify the primary water environment of the target layer according to their clay mineral content differences and characteristics ; According to the environmental geochemical indicators between them (C, S, Eh, etc.), the epigenetic polyuranium ability of the target layer is evaluated.
步骤(6.2)、根据上述步骤(6.1)原生灰色砂、泥岩样品与(红、黄)暖色调砂岩细粒组分样品和(灰、浅灰、灰白、灰绿、绿色)冷色调砂岩细粒组分样品的矿物学、元素和环境地球化学特征差异程度的综合对比结果,判别目标层后生氧化或次生还原作用特征及强度。Step (6.2), according to the above step (6.1) primary gray sand, mudstone samples and (red, yellow) warm-colored sandstone fine-grained component samples and (gray, light gray, gray-white, gray-green, green) cool-colored sandstone fine-grained samples The comprehensive comparison results of the differences in the mineralogy, elemental and environmental geochemical characteristics of the component samples are used to identify the characteristics and intensity of epigenetic oxidation or secondary reduction in the target layer.
步骤(6.3)、根据上述步骤(6.1)和上述步骤(6.2)不同颜色砂-泥岩样品的地质地球化学特征和差异对比,综合评价调查区找矿目标层的砂岩铀成矿环境和成矿潜力、规模等。In step (6.3), according to the above-mentioned steps (6.1) and the above-mentioned steps (6.2), the geological and geochemical characteristics and differences of sand-mudstone samples of different colors are compared, and the sandstone-uranium metallogenic environment and metallogenic potential of the ore prospecting target layer in the survey area are comprehensively evaluated. , size, etc.
例如,对松辽盆地西南部开鲁坳陷SL1钻孔姚家组的样品测试结果分析如下:由表1结果可知,结合灰色砂岩细粒组分S3'、S4'、S5'、S9'和灰色泥岩M2、M4、M6的测试结果发现,姚家组原生灰色岩石铀含量较高,为2.77ppm-30.2ppm,具有较强的同沉积成岩铀预富集作用;其有机碳和全硫中等偏低,分别为0.029%-0.714%、<0.003%-0.131%,指示本身的聚铀能力一般,尤其是砂岩的有机碳总体偏低,还原容量并不高;因此,本次结果与前人由于采集到局部碳屑岩石的有机碳能达到1%,从而得出目标层本身还原能力较强的观点有所不同,我们的采样方法为同一岩性地球化学带内连续岩石样品采集,结果更为可靠,符合姚家组为干旱炎热古气候条件下形成的弱还原性红杂色建造的地质事实,进而表明姚家组后期成矿可能需要外来还原剂参与,并指出深部还原性流体渗出是该区找矿的重要标志。本次M1、M3、M5、M7原生红色泥岩样品的铀含量(2.74ppm-4.42ppm)、有机碳含量(0.044%-0.161%)和全硫含量(均小于0.003%)均很低也可说明目标层属于一套红杂色弱还原性的沉积建造。For example, the analysis of the sample test results of the Yaojia Formation from the SL1 borehole in the Kailu Depression in the southwest of the Songliao Basin is as follows: From the results in Table 1 , it can be seen that combined with the fine - grained components of gray sandstone S3', S4', S5', The test results of S 9 ' and gray mudstone M 2 , M 4 , M 6 show that the primary gray rock of Yaojia Formation has a high uranium content ranging from 2.77ppm to 30.2ppm, which has strong synsedimentary diagenetic uranium pre-enrichment; Its organic carbon and total sulfur are moderately low, 0.029%-0.714%, <0.003%-0.131%, respectively, indicating that its own uranium accumulation ability is general, especially the organic carbon of sandstone is generally low, and the reduction capacity is not high; therefore , this result is different from the previous view that the organic carbon of the local carbonaceous rock can reach 1%, so the target layer itself has a strong reducing ability. Our sampling method is within the same lithological and geochemical zone. The results of continuous rock sample collection are more reliable, which are consistent with the geological fact that the Yaojia Formation is a weakly reducing red variegated formation formed under arid and hot paleoclimate conditions. It is pointed out that the exudation of deep reducing fluid is an important sign of prospecting in this area. The uranium content (2.74ppm-4.42ppm), organic carbon content (0.044%-0.161%) and total sulfur content (all less than 0.003%) of the M 1 , M 3 , M 5 , M 7 primary red mudstone samples this time are all very high. Low value can also indicate that the target layer belongs to a set of red variegated deposits with weak reducibility.
本次姚家组红色砂岩细粒组分S1'、S2'、S6'、S7'S8'、S10'、S11'的铀含量(1.72ppm-3.76ppm)、有机碳含量(0.012%-0.088%)和全硫含量(均小于0.003%)等很低的测试结果(表1)反映出本区砂岩遭受过强烈的后生氧化改造,砂体中铀淋滤丢失强烈,在其它部位可能产生较大规模的铀矿沉淀富集成矿,这从研究区已发现钱家店超大型铀矿田可以得到侧面验证;同时也反映松辽盆地西南部铀矿调查区姚家组存在十分有利的铀成矿潜力和找矿前景,值得进一步加大勘探部署。The red sandstone fine-grained components S 1 ', S 2 ', S 6 ', S 7 ', S 8 ', S 10 ', and S 11 ' of this Yaojia Formation have uranium content (1.72ppm-3.76ppm), organic carbon The very low test results (Table 1) of the total sulfur content (0.012%-0.088%) and total sulfur content (both less than 0.003%) reflect that the sandstone in this area has been subjected to strong epigenetic oxidation transformation, and the uranium leaching loss in the sand body is strong. Large-scale precipitation and enrichment of uranium deposits may occur in other parts, which can be verified from the discovery of the Qianjiadian ultra-large uranium ore field in the study area; it also reflects the Yaojia Formation in the uranium ore survey area in the southwestern Songliao Basin. There are very favorable uranium metallogenic potential and prospecting prospects, and it is worth further increasing exploration deployment.
本发明能够广泛用于国内外中新生代沉积盆地砂岩型铀矿找矿及评价过程中,按本发明提供的方法采集的样品及其测试获得的数据能全面、准确反映出铀矿调查区找矿目标层的地质地球化学特征和成矿环境,为客观评价砂岩铀成矿潜力和规模提供准确的数据参考,直接服务于找矿部署需求,具有重要的实际应用和推广价值。The invention can be widely used in the process of prospecting and evaluation of sandstone-type uranium deposits in Mesozoic and Cenozoic sedimentary basins at home and abroad. The geological and geochemical characteristics and metallogenic environment of the ore target layer provide accurate data reference for objective evaluation of sandstone uranium metallogenic potential and scale, directly serve the needs of prospecting and deployment, and have important practical application and promotion value.
上面结合附图和实施例对本发明作了详细说明,但是本发明并不限于上述实施例,在本领域普通技术人员所具备的知识范围内,还可以在不脱离本发明宗旨的前提下作出各种变化。本发明中未作详细描述的内容均可以采用现有技术。The present invention has been described in detail above in conjunction with the accompanying drawings and embodiments, but the present invention is not limited to the above-mentioned embodiments, and within the scope of knowledge possessed by those of ordinary skill in the art, various kind of change. The content that is not described in detail in the present invention can use the prior art.
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CN117129656A (en) * | 2023-09-19 | 2023-11-28 | 昆明理工大学 | A method and device for screening and determining geochemical exploration index elements |
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