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CN115179399A - Method for manufacturing ceramic product with ink mist effect - Google Patents

Method for manufacturing ceramic product with ink mist effect Download PDF

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Publication number
CN115179399A
CN115179399A CN202210830041.8A CN202210830041A CN115179399A CN 115179399 A CN115179399 A CN 115179399A CN 202210830041 A CN202210830041 A CN 202210830041A CN 115179399 A CN115179399 A CN 115179399A
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CN
China
Prior art keywords
glaze
stamp
ceramic
ground
ink
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Pending
Application number
CN202210830041.8A
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Chinese (zh)
Inventor
陈金龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Cn Eco Materials Co ltd
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Jiangsu Cn Eco Materials Co ltd
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Priority to CN202210830041.8A priority Critical patent/CN115179399A/en
Publication of CN115179399A publication Critical patent/CN115179399A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/04Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
    • B28B11/044Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers with glaze or engobe or enamel or varnish
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/04Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
    • B28B11/041Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers for moulded articles undergoing a thermal treatment at high temperatures, such as burning, after coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/243Setting, e.g. drying, dehydrating or firing ceramic articles
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Structural Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a method for manufacturing a ceramic product with a water-ink cloud effect, which comprises the following steps: preparing a ceramic blank, preparing a ground glaze: adding water into the dry glaze material and ball-milling to form ground glaze; sieving: sieving the ground glaze with a 150-mesh sieve for later use; preparing a stamp-pad ink solution: mixing and ball-milling 0.1 to 1 percent of sodium carboxymethylcellulose, 10 to 30 percent of ethylene glycol, 0.3 to 0.7 percent of nonionic polyoxyethylene ether and 69 to 89 percent of water according to the mass percentage for 2 to 10 hours to obtain a stamp-pad ink solution; preparing the printing ink paste: taking a ceramic inorganic pigment and a stamp-pad ink solution in a weight ratio of 1 to 30 to 50, and uniformly stirring the ceramic inorganic pigment and the stamp-pad ink solution to obtain a stamp-pad ink color paste; glazing: uniformly coating the screened ground coat on the surface of a ceramic blank, and sparsely spraying the printing ink paste on the ground coat by using a glaze throwing machine before the ground coat is not dried; and (5) firing. In the invention, because the printing oil in the printing oil color paste has hydrophilicity but different tension and ground coat, under the mutual arrangement of the printing oil and the ground coat before drying, the liquid with large tension pulls the liquid with small tension to present a distorted water-ink mist-like pattern texture.

Description

Method for manufacturing ceramic product with ink mist effect
Technical Field
The invention relates to the field of ceramic products, in particular to a manufacturing method of a ceramic product with a water-ink cloud effect.
Background
Most of ceramic surface patterns on the market at present adopt the following common printing process: decals, screen printing, roller printing and ceramic ink jet printing. The ink-wash painting effect pattern of the national style is favored by some designers and customers. Due to the many limitations of the conventional printing production process, the following problems exist: 1. the ink and wash patterns printed by the printing modes of decal paper, silk screen printing, roller printing, ceramic ink jet and the like are batch uniform pattern drawings, and the patterns lack agility and randomness; 2. rollers and ink jet printing machines are relatively expensive; 3. the process of decal paper and screen printing is complicated and needs more manual procedures; 4. the common water and ink drop glaze tension of the common ceramic art is close to the ground glaze tension, most of the common ceramic art can only present a circular threadlike shape, and cannot present a distorted cloud shape.
Disclosure of Invention
The invention aims to provide a manufacturing method of a ceramic product with a water-ink cloud effect.
The innovation point of the invention is that because the printing oil in the printing oil color paste has hydrophilicity but different tension and ground coat, the printing oil and the ground coat can present distorted water-ink mist-like pattern textures by mutual arrangement of the printing oil and the ground coat when the printing oil and the ground coat are not dry and pulling the liquid with high tension and low tension.
In order to achieve the purpose, the technical scheme of the invention is as follows: a manufacturing method of a ceramic product with a water-ink cloud effect is characterized by comprising the following steps:
(1) Ceramic blank making
(2) Preparing a base glaze: adding water into the dry glaze material, and ball-milling the dry glaze material into a ground glaze with the specific gravity of 1.6-1.7 g/ml, wherein the fineness of the ground glaze is 0-0.5 g/100 ml after being screened by a 325-mesh sieve, and the flow rate of the ground glaze is 10-50 s/100 ml measured by an Oiwell OWE-2N viscosity cup;
(3) Sieving: sieving the ground glaze with a 150-mesh sieve for later use;
(4) Preparing a stamp-pad ink solution: mixing 0.1 to 1 percent of sodium carboxymethylcellulose, 10 to 30 percent of ethylene glycol, 0.3 to 0.7 percent of nonionic polyoxyethylene ether and 69 to 89 percent of water according to mass fraction, and ball-milling for 2 to 10 hours to obtain a stamp-pad ink solution, wherein the fineness of the stamp-pad ink solution is 325 meshes, the content of each 100 milliliters of the stamp-pad ink solution is less than or equal to 0.1g, the specific gravity of the stamp-pad ink solution is 1.0 to 1.1g/ml, and the flow rate of the stamp-pad ink solution is 15 to 30 seconds per 100 milliliters measured by an Oiwell OWE-2N viscosity cup;
(5) Preparing the printing ink paste: taking the ceramic inorganic pigment and the printing ink solution in a weight ratio of 1 to 30 to 50, and uniformly stirring the ceramic inorganic pigment and the printing ink solution to obtain printing ink paste, wherein the specific gravity of the printing ink paste is 1.0 to 1.2g/ml, and the flow rate of the printing ink paste is 15 to 30 seconds per 100 milliliters measured by an Oldham OWE-2N viscosity cup;
(6) Glazing: uniformly coating the screened ground coat on the surface of a ceramic blank, and sparsely spraying printing ink paste on the ground coat by using a glaze throwing machine before the ground coat is not dried;
(7) And (3) firing: and drying the glazed ceramic blank until the water content is lower than 1%, and then sending the ceramic blank into a kiln for firing at the firing temperature of 1000-1200 ℃ for 30-400 minutes to obtain a finished product.
Methyl cellulose in the stamp-pad ink solution thickens and moisturizes, glycol moisturizes and reduces tension, and nonionic polyoxyether is diluted to reduce tension effectively.
Furthermore, the tension difference between the ground coat and the printing ink paste is more than 20mN/m.
Further, the tension of the ground coat is between 70 and 80mN/m.
Furthermore, the fineness of the ceramic inorganic pigment is 325 meshes, and the residual weight is less than or equal to 0.1g per 100 g.
The invention has the beneficial effects that:
1. the glycol and the nonionic polyoxyethylene ether in the printing ink solution can effectively reduce the tension of the printing ink color paste, and because the printing ink in the printing ink color paste has hydrophilicity but different tension from the ground glaze, the printing ink and the ground glaze mutually dissolve and arrange when the printing ink is not dry, and the liquid with high tension pulls the liquid with low tension to present distorted water-ink mist pattern textures.
2. The method of the invention can solve the problem of high cost of the conventional ceramic printing equipment.
3. The glaze material has the advantages of simple preparation, simple production procedure and strong batch reproducibility, and is suitable for all ceramic glaze products.
Drawings
FIG. 1 is a diagram showing effects of example 1.
Detailed Description
The technical solution in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings.
Example 1: a method for manufacturing a ceramic product with a water-ink cloud effect,
ceramic blank making
Preparing a base glaze: adding water into the dry glaze material, and ball-milling the dry glaze material into a ground coat with the specific gravity of 1.6g/ml, wherein the dry glaze material is a matte ground coat, the fineness of the ground coat is 325 meshes, 0g is left per 100 ml, and the flow rate of the ground coat is measured by an Oldham OWE-2N viscosity cup and is 10 seconds per 100 ml;
sieving: sieving the ground glaze with a 150-mesh sieve for later use;
preparing a stamp-pad ink solution: mixing 0.1% of sodium carboxymethylcellulose, 10.2% of ethylene glycol, 0.7% of nonionic polyoxyethylene ether and 89% of water according to mass fraction, and ball-milling for 2 hours to obtain a stamp-pad ink solution, wherein the fineness of the stamp-pad ink solution is 0.1g per 100 milliliters of a 325-mesh sieve residue, the specific gravity of the stamp-pad ink solution is 1.0g/ml, and the flow rate of the stamp-pad ink solution is measured by an Oldham OWE-2N viscosity cup for 15 seconds per 100 milliliters;
preparing the printing ink paste: taking a ceramic inorganic pigment and a stamp-pad ink solution in a weight ratio of 1; the specific gravity of the printing ink color paste is 1.0g/ml, and the flow rate of the printing ink color paste is measured by an Owell OWE-2N viscosity cup and is 15 seconds per 100 milliliters; the tension of the ground coat is 70mN/m, and the tension difference between the ground coat and the printing ink color paste is 20mN/m.
Glazing: uniformly coating the screened ground coat on the surface of a ceramic blank, and sparsely spraying printing ink paste on the ground coat by using a glaze throwing machine before the ground coat is not dried; the pressure of the ground glaze spraying machine is 7Mpa, the glazing weight of the ground glaze is 5 grams per square centimeter, and the glazing weight of the printing ink color paste is 0.3 grams per square centimeter.
And (3) firing: and drying the glazed ceramic blank until the moisture content is lower than 1%, and then feeding the ceramic blank into a kiln for firing at the firing temperature of 1000 ℃ for 30 minutes to obtain a finished product.
Example 2: a method for manufacturing a ceramic product with a water-ink cloud effect,
ceramic blank making
Preparing a base glaze: adding water into the dry glaze material, and ball-milling the dry glaze material into a ground glaze with the specific gravity of 1.65 g/ml, wherein the dry glaze material is a bright ground glaze, the fineness of the ground glaze is 0.2 g of residual glaze per 100 ml after being screened by a 325-mesh sieve, and the flow rate of the ground glaze is 30 seconds per 100 ml measured by an Oldham OWE-2N viscosity cup;
sieving: sieving the ground glaze with a 150-mesh sieve for later use;
preparing a stamp-pad ink solution: mixing 0.5% of sodium carboxymethylcellulose, 30% of glycol, 0.5% of nonionic polyoxyethylene ether and 69% of water according to mass fraction, and performing ball milling for 5 hours to obtain a stamp-pad ink solution, wherein the fineness of the stamp-pad ink solution is 0.05g per 100 ml of 325-mesh sieve residue, the specific gravity of the stamp-pad ink solution is 1.05g/ml, and the flow rate of the stamp-pad ink solution is 20 seconds per 100 ml measured by an Oiwell OWE-2N viscosity cup;
preparing the printing ink paste: taking a ceramic inorganic pigment and a stamp-pad ink solution in a weight ratio of 1; the specific gravity of the printing ink color paste is 1.1g/ml, and the flow rate of the printing ink color paste is measured by an Oldham OWE-2N viscosity cup and is 20 seconds per 100 milliliters; the tension of the ground coat is 75mN/m, and the tension difference between the ground coat and the printing ink color paste is 30mN/m.
Glazing: uniformly coating the screened ground coat on the surface of a ceramic blank, and sparsely spraying printing ink paste on the ground coat by using a glaze throwing machine before the ground coat is not dried; the pressure of the ground glaze spraying machine is 7Mpa, the glazing weight of the ground glaze is 5 grams per square centimeter, and the glazing weight of the printing ink color paste is 1 gram per square centimeter.
And (3) firing: and drying the glazed ceramic blank until the moisture content is lower than 1%, and then, sending the ceramic blank into a kiln for firing at the firing temperature of 1100 ℃ for 200 minutes to obtain a finished product.
Example 3: a method for manufacturing a ceramic product with a water-ink cloud effect,
ceramic blank making
Preparing a base glaze: adding water into the dry glaze material, and ball-milling the dry glaze material into a ground glaze with the specific gravity of 1.7 g/ml, wherein the fineness of the ground glaze is 325 meshes, the residual weight of 0.5 g per 100 ml, and the flow rate of the ground glaze is measured by an Oldham OWE-2N viscosity cup and is 50 seconds per 100 ml;
sieving: sieving the ground glaze with a 150-mesh sieve for later use;
preparing a stamp-pad ink solution: mixing 1% of sodium carboxymethylcellulose, 10% of ethylene glycol, 0.3% of nonionic polyoxyethylene ether and 88.7% of water according to mass fraction, and performing ball milling for 10 hours to obtain a stamp-pad ink solution, wherein the fineness of the stamp-pad ink solution is 0.03g per 100 ml of a 325-mesh sieve, the specific gravity of the stamp-pad ink solution is 1.1g/ml, and the flow rate of the stamp-pad ink solution is 30 seconds per 100 ml measured by an Oldham-2N viscosity cup;
preparing the printing ink paste: taking a ceramic inorganic pigment and a stamp-pad ink solution in a weight ratio of 1: 50, and uniformly stirring the ceramic inorganic pigment and the stamp-pad ink solution to obtain stamp-pad ink paste, wherein the fineness of the ceramic inorganic pigment is 325 meshes, and the screen residue is 0.03g per 100 g; the specific gravity of the printing ink color paste is 1.2g/ml, and the flow rate of the printing ink color paste is measured by an Oldham OWE-2N viscosity cup and is 30 seconds per 100 milliliters; the tension of the ground coat is between 80mN/m, and the tension difference between the ground coat and the printing ink paste is 40mN/m.
Glazing: uniformly coating the screened ground coat on the surface of a ceramic blank, and sparsely spraying the printing ink paste on the ground coat by using a glaze throwing machine before the ground coat is not dried; the pressure of the ground glaze spraying machine is 7Mpa, the glazing weight of the ground glaze is 5 grams per square centimeter, and the glazing weight of the printing ink color paste is 0.1 gram per square centimeter.
And (3) firing: and drying the glazed ceramic blank until the moisture content is lower than 1%, and then, sending the ceramic blank into a kiln for firing at the firing temperature of 1200 ℃ for 400 minutes to obtain a finished product.
The described embodiments are only some embodiments of the invention, not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Claims (4)

1. A manufacturing method of a ceramic product with a water-ink cloud-mist effect is characterized by comprising the following steps:
ceramic blank making
Preparing a base glaze: adding water into the dry glaze material, and ball-milling the dry glaze material into a ground glaze with the specific gravity of 1.6-1.7 g/ml, wherein the fineness of the ground glaze is 0-0.5 g/100 ml after being screened by a 325-mesh sieve, and the flow rate of the ground glaze is 10-50 s/100 ml measured by an Oiwell OWE-2N viscosity cup;
sieving: sieving the ground glaze with a 150-mesh sieve for later use;
preparing a stamp-pad ink solution: mixing 0.1 to 1 percent of sodium carboxymethylcellulose, 10 to 30 percent of ethylene glycol, 0.3 to 0.7 percent of nonionic polyoxyethylene ether and 69 to 89 percent of water according to mass fraction, and ball-milling for 2 to 10 hours to obtain a stamp-pad ink solution, wherein the fineness of the stamp-pad ink solution is 325 meshes, the content of each 100 milliliters of the stamp-pad ink solution is less than or equal to 0.1g, the specific gravity of the stamp-pad ink solution is 1.0 to 1.1g/ml, and the flow rate of the stamp-pad ink solution is 15 to 30 seconds per 100 milliliters measured by an Oiwell OWE-2N viscosity cup;
preparing the printing ink paste: taking the ceramic inorganic pigment and the printing ink solution in a weight ratio of 1 to 30 to 50, and uniformly stirring the ceramic inorganic pigment and the printing ink solution to obtain printing ink paste, wherein the specific gravity of the printing ink paste is 1.0 to 1.2g/ml, and the flow rate of the printing ink paste is 15 to 30 seconds per 100 milliliters measured by an Oldham OWE-2N viscosity cup;
glazing: uniformly coating the screened ground coat on the surface of a ceramic blank, and sparsely spraying printing ink paste on the ground coat by using a glaze throwing machine before the ground coat is not dried;
and (3) firing: and drying the glazed ceramic blank until the water content is lower than 1%, and then sending the ceramic blank into a kiln for firing at the firing temperature of 1000-1200 ℃ for 30-400 minutes to obtain a finished product.
2. The method for manufacturing the ceramic product with the ink and mist effect according to claim 1, wherein the tension difference between the ground glaze and the printing ink paste is more than 20mN/m.
3. The method for manufacturing the ceramic product with the ink mist effect according to claim 1, wherein the tension of the ground coat is 70 to 80mN/m.
4. The method for manufacturing the ceramic product with the water-ink cloud and mist effect according to claim 1, wherein the fineness of the ceramic inorganic pigment is 325 meshes and the residual weight of the ceramic inorganic pigment is less than or equal to 0.1g per 100 g.
CN202210830041.8A 2022-07-15 2022-07-15 Method for manufacturing ceramic product with ink mist effect Pending CN115179399A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008202041A (en) * 2007-01-26 2008-09-04 Kyocera Corp Paste composition, ceramic molded body, and method for producing ceramic structure
CN101786904A (en) * 2009-12-22 2010-07-28 咸阳陶瓷研究设计院 Color-changing glaze for metallic luster ceramics and preparation method thereof
CN103694797A (en) * 2013-12-06 2014-04-02 华南农业大学 Brown nano-ceramics ink-jet ink and preparation method thereof
CN103693992A (en) * 2013-12-23 2014-04-02 宾阳县明翔新材料科技有限公司 Color-changing glaze ceramic and production method thereof
KR20180026041A (en) * 2016-09-02 2018-03-12 주식회사 중원희토세라믹 Manufacturing Method for Ceramic Ware Having Indeterminate Pattern
CN109293237A (en) * 2018-09-18 2019-02-01 禹州市元丰钧陶瓷有限公司 A kind of roe Bluepoint shape pottery glaze and preparation method thereof
CN114478069A (en) * 2021-12-31 2022-05-13 肇庆乐华陶瓷洁具有限公司 Ceramic tile with relief effect and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008202041A (en) * 2007-01-26 2008-09-04 Kyocera Corp Paste composition, ceramic molded body, and method for producing ceramic structure
CN101786904A (en) * 2009-12-22 2010-07-28 咸阳陶瓷研究设计院 Color-changing glaze for metallic luster ceramics and preparation method thereof
CN103694797A (en) * 2013-12-06 2014-04-02 华南农业大学 Brown nano-ceramics ink-jet ink and preparation method thereof
CN103693992A (en) * 2013-12-23 2014-04-02 宾阳县明翔新材料科技有限公司 Color-changing glaze ceramic and production method thereof
KR20180026041A (en) * 2016-09-02 2018-03-12 주식회사 중원희토세라믹 Manufacturing Method for Ceramic Ware Having Indeterminate Pattern
CN109293237A (en) * 2018-09-18 2019-02-01 禹州市元丰钧陶瓷有限公司 A kind of roe Bluepoint shape pottery glaze and preparation method thereof
CN114478069A (en) * 2021-12-31 2022-05-13 肇庆乐华陶瓷洁具有限公司 Ceramic tile with relief effect and preparation method thereof

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Application publication date: 20221014