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CN115117137A - Electroluminescent device, display panel and display device - Google Patents

Electroluminescent device, display panel and display device Download PDF

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CN115117137A
CN115117137A CN202210760320.1A CN202210760320A CN115117137A CN 115117137 A CN115117137 A CN 115117137A CN 202210760320 A CN202210760320 A CN 202210760320A CN 115117137 A CN115117137 A CN 115117137A
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pixel
sub
generating
hole
substructure
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余兆伟
晏荣建
韦钦河
宋广军
杨亚敏
陈文斌
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BOE Technology Group Co Ltd
Chengdu BOE Optoelectronics Technology Co Ltd
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Chengdu BOE Optoelectronics Technology Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • H10K59/122Pixel-defining structures or layers, e.g. banks
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • H10K50/125OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light
    • H10K50/13OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light comprising stacked EL layers within one EL unit
    • H10K50/131OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light comprising stacked EL layers within one EL unit with spacer layers between the electroluminescent layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30Devices specially adapted for multicolour light emission
    • H10K59/35Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
    • H10K59/353Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels characterised by the geometrical arrangement of the RGB subpixels
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/615Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
    • H10K85/624Polycyclic condensed aromatic hydrocarbons, e.g. anthracene containing six or more rings
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/649Aromatic compounds comprising a hetero atom
    • H10K85/654Aromatic compounds comprising a hetero atom comprising only nitrogen as heteroatom
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/649Aromatic compounds comprising a hetero atom
    • H10K85/655Aromatic compounds comprising a hetero atom comprising only sulfur as heteroatom
    • HELECTRICITY
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    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00Properties of the organic materials covered by group H10K85/00
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Abstract

本申请实施例提供了一种电致发光器件、显示面板及显示装置。该电致发光器件,包括:至少两层叠的发光层;电荷产生层,位于相邻两发光层之间,包括层叠的空穴产生层和电子产生层;其中,空穴产生层的主客体掺杂比为第一掺杂比,电子产生层的主客体掺杂比为第二掺杂比,第一掺杂比与第二掺杂比之间的比例不小于3:1且不大于20:1。本申请实施例通过优化叠层的电致发光器件中电荷产生层的掺杂比例,具体是控制空穴产生层的主客体掺杂比大于电子产生层的主客体掺杂比,有利于更好的匹配发光层中各像素的驱动电压,并减轻像素串扰现象。

Figure 202210760320

Embodiments of the present application provide an electroluminescent device, a display panel, and a display device. The electroluminescent device includes: at least two stacked light-emitting layers; a charge generation layer, located between two adjacent light-emitting layers, including stacked hole-generating layers and electron-generating layers; wherein, the host and guest of the hole-generating layers are doped The impurity ratio is the first doping ratio, the host-guest doping ratio of the electron generating layer is the second doping ratio, and the ratio between the first doping ratio and the second doping ratio is not less than 3:1 and not more than 20: 1. In the embodiment of the present application, by optimizing the doping ratio of the charge generating layer in the stacked electroluminescent device, specifically, controlling the host-guest doping ratio of the hole-generating layer to be greater than the host-guest doping ratio of the electron generating layer, it is beneficial to better The driving voltage of each pixel in the light-emitting layer is matched, and the phenomenon of pixel crosstalk is alleviated.

Figure 202210760320

Description

电致发光器件、显示面板及显示装置Electroluminescent device, display panel and display device

技术领域technical field

本申请涉及显示技术领域,具体而言,本申请涉及一种电致发光器件、显示面板及显示装置。The present application relates to the field of display technology, and in particular, the present application relates to an electroluminescent device, a display panel and a display device.

背景技术Background technique

有机发光二极管即OLED,由于自身固有的优点,如自发光、亮度高、响应快、色域广、可制作柔性显示装置等优点,被认为是代替液晶技术的理想下一代显示技术。Organic light-emitting diodes, or OLEDs, are considered to be an ideal next-generation display technology to replace liquid crystal technology due to their inherent advantages, such as self-luminescence, high brightness, fast response, wide color gamut, and the ability to make flexible display devices.

受到现有发光材料特性的限制,现有单层电致发光器件无法满足客户诉求,为了满足客户越来越严苛的信赖性、寿命、功耗等诉求,叠层的电致发光器件应运而生。Limited by the characteristics of existing luminescent materials, existing single-layer electroluminescent devices cannot meet customer demands. pregnancy.

但是,叠层的电致发光器件容易出现像素串扰的现象,影响显示效果。However, the stacked electroluminescent device is prone to the phenomenon of pixel crosstalk, which affects the display effect.

发明内容SUMMARY OF THE INVENTION

本申请针对现有方式的缺点,提出一种电致发光器件、显示面板及显示装置,用以解决现有技术存在叠层的电致发光器件容易出现像素串扰的技术问题。Aiming at the shortcomings of the prior art, the present application proposes an electroluminescent device, a display panel and a display device to solve the technical problem that the layered electroluminescent device is prone to pixel crosstalk in the prior art.

第一个方面,本申请实施例提供了一种电致发光器件,包括:至少两层叠的发光层;In a first aspect, an embodiment of the present application provides an electroluminescent device, comprising: at least two stacked light-emitting layers;

电荷产生层,位于相邻两发光层之间,包括层叠的空穴产生层和电子产生层;The charge generation layer, located between two adjacent light-emitting layers, includes a stacked hole generation layer and an electron generation layer;

其中,空穴产生层的主客体掺杂比为第一掺杂比,电子产生层的主客体掺杂比为第二掺杂比,第一掺杂比与第二掺杂比之间的比例不小于3:1且不大于20:1。The host-guest doping ratio of the hole generating layer is the first doping ratio, the host-guest doping ratio of the electron generating layer is the second doping ratio, and the ratio between the first doping ratio and the second doping ratio Not less than 3:1 and not more than 20:1.

可选地,空穴产生层的主体材料包括以下化合物中的至少一种:Optionally, the host material of the hole generating layer includes at least one of the following compounds:

Figure BDA0003720812540000021
Figure BDA0003720812540000021

可选地,空穴产生层的客体材料包括以下化合物中的至少一种:Optionally, the guest material of the hole-generating layer includes at least one of the following compounds:

Figure BDA0003720812540000022
Figure BDA0003720812540000022

可选地,电子产生层的主体材料包括以下化合物中的至少一种:Optionally, the host material of the electron generating layer includes at least one of the following compounds:

Figure BDA0003720812540000023
Figure BDA0003720812540000023

Figure BDA0003720812540000031
Figure BDA0003720812540000031

可选地,发光层包括:第一子像素和第二子像素;Optionally, the light-emitting layer includes: a first sub-pixel and a second sub-pixel;

空穴产生层包括:对应第一子像素的第一空穴产生子结构,和对应第二子像素的第二空穴产生子结构;The hole generation layer includes: a first hole generation substructure corresponding to the first subpixel, and a second hole generation substructure corresponding to the second subpixel;

其中,第一子像素的驱动电压高于第二子像素的驱动电压,第一空穴产生子结构的导电性高于第二空穴产生子结构的导电性。The driving voltage of the first sub-pixel is higher than the driving voltage of the second sub-pixel, and the conductivity of the first hole-generating substructure is higher than that of the second hole-generating substructure.

可选地,第一空穴产生子结构的主客体掺杂比大于第二空穴产生子结构的主客体掺杂比;Optionally, the host-guest doping ratio of the first hole-generating substructure is greater than the host-guest doping ratio of the second hole-generating substructure;

和/或,第一空穴产生子结构与第二空穴产生子结构之间具有第一间隔。And/or, there is a first separation between the first hole-generating substructure and the second hole-generating substructure.

可选地,第一间隔不小于2微米。Optionally, the first interval is not less than 2 microns.

可选地,发光层包括:第一子像素和第二子像素;Optionally, the light-emitting layer includes: a first sub-pixel and a second sub-pixel;

电子产生层包括:对应第一子像素的第一电子产生子结构,和对应第二子像素的第二电子产生子结构;The electron generating layer includes: a first electron generating substructure corresponding to the first subpixel, and a second electron generating substructure corresponding to the second subpixel;

其中,第一子像素的驱动电压高于第二子像素的驱动电压,第一电子产生子结构的导电性高于第二电子产生子结构的导电性。Wherein, the driving voltage of the first sub-pixel is higher than the driving voltage of the second sub-pixel, and the conductivity of the first electron generating sub-structure is higher than that of the second electron generating sub-structure.

可选地,第一电子产生子结构的主客体掺杂比大于第二电子产生子结构的主客体掺杂比;Optionally, the host-guest doping ratio of the first electron generating substructure is greater than the host-guest doping ratio of the second electron generating substructure;

和/或,第一电子产生子结构与第二电子产生子结构之间具有第二间隔。And/or, there is a second space between the first electron generating substructure and the second electron generating substructure.

可选地,第二间隔不小于2微米。Optionally, the second interval is not less than 2 microns.

可选地,发光层包括:第一子像素、第二子像素和第三子像素;Optionally, the light-emitting layer includes: a first sub-pixel, a second sub-pixel and a third sub-pixel;

第一子像素的驱动电压分别高于第二子像素的驱动电压、第三子像素的驱动电压;The driving voltage of the first sub-pixel is respectively higher than the driving voltage of the second sub-pixel and the driving voltage of the third sub-pixel;

第一子像素与第二子像素之间具有第三间隔,第一子像素与第三子像素之间具有第四间隔。There is a third interval between the first subpixel and the second subpixel, and a fourth interval between the first subpixel and the third subpixel.

可选地,第三间隔和第四间隔中的至少一种不小于2微米。Optionally, at least one of the third interval and the fourth interval is not less than 2 microns.

第二个方面,本申请实施例提供了一种显示面板,包括:如上述第一个方面提供的电致发光器件。In a second aspect, an embodiment of the present application provides a display panel, including: the electroluminescent device provided in the first aspect above.

第三个方面,本申请实施例提供了一种显示装置,包括:如上述第二个方面提供的显示面板。In a third aspect, an embodiment of the present application provides a display device, including: the display panel provided in the above-mentioned second aspect.

本申请实施例提供的技术方案带来的有益技术效果包括:通过优化叠层的电致发光器件中电荷产生层的掺杂比例,具体是控制空穴产生层的主客体掺杂比大于电子产生层的主客体掺杂比,并控制两主客体掺杂比之间的比例不小于3:1且不大于20:1,有利于更好的匹配发光层中各像素的驱动电压,并减轻像素串扰现象。The beneficial technical effects brought by the technical solutions provided in the embodiments of the present application include: by optimizing the doping ratio of the charge generating layer in the stacked electroluminescent device, specifically, controlling the host-guest doping ratio of the hole generating layer to be greater than that of the electron generating layer The host-guest doping ratio of the layer is controlled, and the ratio between the two host-guest doping ratios is controlled to be no less than 3:1 and no greater than 20:1, which is conducive to better matching the driving voltage of each pixel in the light-emitting layer and reducing the pixel. crosstalk phenomenon.

本申请附加的方面和优点将在下面的描述中部分给出,这些将从下面的描述中变得明显,或通过本申请的实践了解到。Additional aspects and advantages of the present application will be set forth in part in the following description, which will become apparent from the following description, or may be learned by practice of the present application.

附图说明Description of drawings

本申请上述的和/或附加的方面和优点从下面结合附图对实施例的描述中将变得明显和容易理解,其中:The above and/or additional aspects and advantages of the present application will become apparent and readily understood from the following description of embodiments taken in conjunction with the accompanying drawings, wherein:

图1为本申请实施例提供的一种电致发光器件的实施方式一的截面结构示意图;FIG. 1 is a schematic cross-sectional structure diagram of Embodiment 1 of an electroluminescent device provided in the embodiment of the present application;

图2为本申请实施例提供的一种电致发光器件的实施方式二的截面结构示意图;FIG. 2 is a schematic cross-sectional structure diagram of Embodiment 2 of an electroluminescent device provided in the embodiment of the present application;

图3为本申请实施例提供的一种电致发光器件的实施方式三的截面结构示意图;FIG. 3 is a schematic cross-sectional structure diagram of Embodiment 3 of an electroluminescent device provided in the embodiment of the present application;

图4为本申请实施例提供的一种电致发光器件的实施方式四的截面结构示意图;FIG. 4 is a schematic cross-sectional structure diagram of Embodiment 4 of an electroluminescent device provided in the embodiment of the present application;

图5为本申请实施例提供的一种电致发光器件的实施方式五的截面结构示意图;FIG. 5 is a schematic cross-sectional structure diagram of Embodiment 5 of an electroluminescent device provided by the embodiment of the present application;

图6为为本申请实施例提供的一种电致发光器件的实施方式五的俯视结构示意图。FIG. 6 is a schematic top-view structural diagram of Embodiment 5 of an electroluminescent device provided in the embodiment of the present application.

图中:In the picture:

100-电致发光器件;100-electroluminescent device;

110-发光层;111-第一子像素;112-第二子像素;113-第三子像素;110-light-emitting layer; 111-first sub-pixel; 112-second sub-pixel; 113-third sub-pixel;

120-电荷产生层;121-空穴产生层;121a-第一空穴产生子结构;121b-第二空穴产生子结构;122-电子产生层;122a-第一电子产生子结构;122b-第二电子产生子结构;120-charge-generating layer; 121-hole-generating layer; 121a-first hole-generating substructure; 121b-second hole-generating substructure; 122-electron-generating layer; 122a-first electron-generating substructure; 122b- the second electron generating substructure;

130-阳极层;140-阴极层;150-空穴传输层;160-电子传输层;130-anode layer; 140-cathode layer; 150-hole transport layer; 160-electron transport layer;

10-第一间隔;20-第三间隔;30-第四间隔。10-first interval; 20-third interval; 30-fourth interval.

具体实施方式Detailed ways

下面结合本申请中的附图描述本申请的实施例。应理解,下面结合附图所阐述的实施方式,是用于解释本申请实施例的技术方案的示例性描述,对本申请实施例的技术方案不构成限制。Embodiments of the present application are described below with reference to the accompanying drawings in the present application. It should be understood that the embodiments described below in conjunction with the accompanying drawings are exemplary descriptions for explaining the technical solutions of the embodiments of the present application, and do not limit the technical solutions of the embodiments of the present application.

本技术领域技术人员可以理解,除非特意声明,这里使用的单数形式“一”、“一个”、“所述”和“该”也可包括复数形式。应该进一步理解的是,本申请的说明书中使用的措辞“包括”是指存在所述特征、整数、元件和/或组件,但不排除实现为本技术领域所支持其他特征、信息、数据、元件、组件和/或它们的组合等。应该理解,当我们称一个元件被“连接”或“耦接”到另一元件时,该一个元件可以直接连接或耦接到另一元件,也可以指该一个元件和另一元件通过中间元件建立连接关系。此外,这里使用的“连接”或“耦接”可以包括无线连接或无线耦接。这里使用的术语“和/或”指该术语所限定的项目中的至少一个,例如“A和/或B”可以实现为“A”,或者实现为“B”,或者实现为“A和B”。It will be understood by those skilled in the art that the singular forms "a", "an", "the" and "the" as used herein can include the plural forms as well, unless expressly stated otherwise. It should be further understood that the word "comprising" used in the description of the present application means the presence of the stated features, integers, elements and/or components, but does not preclude the implementation of other features, information, data, elements supported by the technical field , components and/or combinations thereof, etc. It will be understood that when we refer to an element as being "connected" or "coupled" to another element, the one element can be directly connected or coupled to the other element, or the one element and the other element may be intervening through intervening elements Establish a connection relationship. Furthermore, "connected" or "coupled" as used herein may include wirelessly connected or wirelessly coupled. The term "and/or" as used herein refers to at least one of the items defined by the term, eg "A and/or B" can be implemented as "A", or as "B", or as "A and B" ".

为使本申请的目的、技术方案和优点更加清楚,下面将结合附图对本申请实施方式作进一步地详细描述。In order to make the objectives, technical solutions and advantages of the present application clearer, the embodiments of the present application will be further described in detail below with reference to the accompanying drawings.

本申请的研发思路包括:在叠层的电致发光器件中,相邻两层发光层之间可以通过电荷产生层连接起来,即单层器件可以通过电荷产生层连接起来得到叠层的电致发光器件。The research and development ideas of the present application include: in a stacked electroluminescent device, two adjacent light-emitting layers can be connected by a charge generating layer, that is, a single-layer device can be connected by a charge generating layer to obtain a stacked electroluminescent device. light-emitting device.

电荷产生层可以分为空穴产生层(PCGL)和电子产生层(NCGL),其掺杂浓度对产品的特性有着举足轻重的影响。经实验论证,对电荷产生层中的掺杂浓度进行优化能够完美解决器件电压高、产品寿命差等问题。然而材料能级匹配以及电荷产生层对不同颜色的发光器件影响不同,导致在器件优化过程中电压降低的同时,容易导致像素之间的串扰现象明显增加。The charge-generating layer can be divided into a hole-generating layer (PCGL) and an electron-generating layer (NCGL), and its doping concentration has a decisive influence on the characteristics of the product. It has been proved by experiments that optimizing the doping concentration in the charge generation layer can perfectly solve the problems of high device voltage and poor product life. However, material energy level matching and charge generation layers have different effects on light-emitting devices of different colors, which leads to a decrease in voltage during device optimization, and a significant increase in crosstalk between pixels.

具体地,在红绿蓝三基础色中发蓝光的蓝色子像素的驱动电压比较高,导致叠层器件的颜色配比失衡,画质显示异常,PMIC(Power Management IC,电源管理集成电路)驱动电压不足,产品电压的预留量不够。并且,习惯上叠层器件中的电荷产生层(PCGL&NCGL)是同种材料且RGB三种颜色子像素共用,电荷产生层中空穴产生层的客体可用无序排列的有机小分子,电子产生层的客体可用金属性活泼的金属材料,例如:第Ⅰ、第Ⅱ主族和镧系金属材料。为了实现叠层OLED显示器件的电压收益最大化,可以增大空穴产生层或电子产生层的客体浓度,但是空穴产生层的客体材料和电子产生层的电子材料在电场效果下是无序排列的,因此随着高电压像素的点亮会引起低电压像素启亮,形成像素之间的串扰现象。Specifically, the driving voltage of the blue sub-pixel that emits blue light in the three basic colors of red, green and blue is relatively high, which causes the color ratio of the stacked device to be unbalanced, and the image quality display is abnormal. PMIC (Power Management IC, power management integrated circuit) The driving voltage is insufficient, and the reserved amount of product voltage is not enough. In addition, it is customary for the charge generation layers (PCGL & NCGL) in the stacked device to be of the same material and shared by three RGB color sub-pixels. The guest can be made of metallic active metal materials, such as: I, II main group and lanthanide metal materials. In order to maximize the voltage gain of the stacked OLED display device, the guest concentration of the hole-generating layer or the electron-generating layer can be increased, but the guest material of the hole-generating layer and the electron material of the electron-generating layer are disordered under the effect of the electric field Therefore, as the high-voltage pixel is turned on, the low-voltage pixel will be turned on, resulting in a phenomenon of crosstalk between pixels.

因此,在优化电荷产生层的器件结构时会导致RGB三种颜色的电压和电致发光效率改变幅度不同,使得此类方案的功耗收益和串扰效果不够理想。Therefore, when the device structure of the charge generation layer is optimized, the voltage and electroluminescence efficiency of the three colors of RGB will change in different amplitudes, which makes the power consumption gain and crosstalk effect of such a scheme unsatisfactory.

本申请提供的电致发光器件、显示面板及显示装置,旨在解决现有技术的如上技术问题。The electroluminescent device, display panel and display device provided by the present application aim to solve the above technical problems in the prior art.

下面以具体地实施例对本申请的技术方案以及本申请的技术方案如何解决上述技术问题进行详细说明。需要指出的是,下述实施方式之间可以相互参考、借鉴或结合,对于不同实施方式中相同的术语、相似的特征以及相似的实施步骤等,不再重复描述。The technical solutions of the present application and how the technical solutions of the present application solve the above-mentioned technical problems will be described in detail below with specific examples. It should be noted that the following embodiments may refer to, learn from, or combine with each other, and the same terms, similar features, and similar implementation steps in different embodiments will not be described repeatedly.

本申请实施例提供了一种电致发光器件100,该电致发光器件100的结构示意图如图1所示,包括:至少两层叠的发光层110,和位于相邻两发光层110之间的电荷产生层120。The embodiment of the present application provides an electroluminescent device 100 , and a schematic structural diagram of the electroluminescent device 100 is shown in FIG. The charge generation layer 120 .

电荷产生层120包括层叠的空穴产生层121和电子产生层122。The charge generation layer 120 includes a stacked hole generation layer 121 and an electron generation layer 122 .

其中,空穴产生层121的主客体掺杂比为第一掺杂比,电子产生层122的主客体掺杂比为第二掺杂比,第一掺杂比与第二掺杂比之间的比例不小于3:1且不大于20:1。The host-guest doping ratio of the hole generating layer 121 is the first doping ratio, the host-guest doping ratio of the electron generating layer 122 is the second doping ratio, and the difference between the first doping ratio and the second doping ratio is The ratio is not less than 3:1 and not more than 20:1.

在本实施例中,叠层的电致发光器件100中电荷产生层120P型电荷产生层120(PCGL)的掺杂浓度与N型电荷产生层120(NCGL)的掺杂浓度进行差异化设置,具体是控制空穴产生层121的主客体掺杂比大于电子产生层122的主客体掺杂比,并控制两主客体掺杂比(即第一掺杂比与第二掺杂比)之间的比例不小于3:1且不大于20:1,有利于更好的匹配发光层110中各像素的驱动电压,并减轻像素串扰现象。In this embodiment, the doping concentration of the P-type charge generating layer 120 (PCGL) and the doping concentration of the N-type charge generating layer 120 (NCGL) in the charge generating layer 120 in the stacked electroluminescent device 100 are set differently, Specifically, the host-guest doping ratio of the hole-generating layer 121 is controlled to be greater than the host-guest doping ratio of the electron-generating layer 122, and the difference between the two host-guest doping ratios (ie, the first doping ratio and the second doping ratio) is controlled. The ratio is not less than 3:1 and not more than 20:1, which is conducive to better matching the driving voltage of each pixel in the light emitting layer 110 and reducing the phenomenon of pixel crosstalk.

其中,主客体掺杂比指的是:主体材料与客体材料的含量比例。The host-guest doping ratio refers to the content ratio of the host material to the guest material.

在一些可能的实施方式中,电致发光器件100还包括层叠的阳极层130和阴极层140,以及位于阳极层130靠近阴极层140一侧的空穴传输层150、位于阴极层140靠近阳极层130一侧的电子传输层160,所有发光层110依次层叠于空穴传输层150与电子传输层160之间。其中,每一电荷产生层120中的空穴产生层121相对于电子产生层122更靠近阴极层140,同理,每一电荷产生层120中的电子产生层122相对于空穴产生层121更靠近阳极层130。In some possible embodiments, the electroluminescent device 100 further includes a stacked anode layer 130 and a cathode layer 140, and a hole transport layer 150 located on the side of the anode layer 130 close to the cathode layer 140, and a hole transport layer 150 located on the cathode layer 140 close to the anode layer For the electron transport layer 160 on the side of 130 , all the light-emitting layers 110 are sequentially stacked between the hole transport layer 150 and the electron transport layer 160 . The hole generation layer 121 in each charge generation layer 120 is closer to the cathode layer 140 than the electron generation layer 122 . Similarly, the electron generation layer 122 in each charge generation layer 120 is closer to the hole generation layer 121 than the hole generation layer 121 . close to the anode layer 130 .

在一些可能的实施方式中,空穴产生层121的主体材料包括以下化合物中的至少一种:In some possible embodiments, the host material of the hole generation layer 121 includes at least one of the following compounds:

Figure BDA0003720812540000081
Figure BDA0003720812540000081

在一些可能的实施方式中,空穴产生层121的客体材料包括以下化合物中的至少一种:In some possible embodiments, the guest material of the hole-generating layer 121 includes at least one of the following compounds:

Figure BDA0003720812540000082
Figure BDA0003720812540000082

在一些可能的实施方式中,电子产生层122的主体材料包括以下化合物中的至少一种:In some possible embodiments, the host material of the electron generating layer 122 includes at least one of the following compounds:

Figure BDA0003720812540000083
Figure BDA0003720812540000083

Figure BDA0003720812540000091
Figure BDA0003720812540000091

本申请的研发思路还包括:可以针对发光层110中不同驱动电压要求的子像素,对电荷产生层120进行差异化配置,有利于匹配发光层110各子像素的能级。为此,本申请为电致发光器件100提供如下两种可能的实现方式:The research and development ideas of the present application further include that the charge generation layer 120 can be configured differently for sub-pixels with different driving voltage requirements in the light-emitting layer 110 , which is beneficial to match the energy levels of each sub-pixel of the light-emitting layer 110 . To this end, the present application provides the following two possible implementations for the electroluminescent device 100:

在第一种可能的实施方式中,如图2所示,发光层110包括:第一子像素111和第二子像素112。In a first possible implementation manner, as shown in FIG. 2 , the light-emitting layer 110 includes: a first sub-pixel 111 and a second sub-pixel 112 .

空穴产生层121包括:对应第一子像素111的第一空穴产生子结构121a,和对应第二子像素112的第二空穴产生子结构121b。The hole-generating layer 121 includes: a first hole-generating substructure 121 a corresponding to the first sub-pixel 111 , and a second hole-generating sub-structure 121 b corresponding to the second sub-pixel 112 .

其中,第一子像素111的驱动电压高于第二子像素112的驱动电压,第一空穴产生子结构121a的导电性高于第二空穴产生子结构121b的导电性。The driving voltage of the first sub-pixel 111 is higher than the driving voltage of the second sub-pixel 112, and the conductivity of the first hole-generating substructure 121a is higher than that of the second hole-generating substructure 121b.

在本实施例中,第一子像素111和第二子像素112相对而言,第一子像素111是高驱动电压像素,第二子像素112是低驱动电压像素。本实施例提供的电致发光器件100,通过对电荷产生层120中分别对应第一子像素111和第二子像素112的空穴产生层121(即P型电荷产生层120)进行差异化设置,具体是导电性更高的第一空穴产生子结构121a对应高驱动电压像素,导电性相对较低的第二空穴产生子结构121b对应低驱动电压像素,从而更好地匹配发光层110不同驱动电压子像素的能级,优化产品特性和功耗收益。In this embodiment, the first subpixel 111 and the second subpixel 112 are relatively speaking, the first subpixel 111 is a high driving voltage pixel, and the second subpixel 112 is a low driving voltage pixel. In the electroluminescent device 100 provided in this embodiment, the hole-generating layers 121 (ie, the P-type charge-generating layers 120 ) in the charge-generating layer 120 corresponding to the first sub-pixel 111 and the second sub-pixel 112 , respectively, are set differently. Specifically, the first hole-generating substructure 121a with higher conductivity corresponds to a high driving voltage pixel, and the second hole-generating substructure 121b with a relatively low conductivity corresponds to a low driving voltage pixel, so as to better match the light-emitting layer 110 Energy levels of sub-pixels with different driving voltages, optimizing product characteristics and power consumption benefits.

在一个示例中,第一子像素111为蓝色子像素,第二子像素112为红色子像素或绿色子像素。In one example, the first subpixel 111 is a blue subpixel, and the second subpixel 112 is a red subpixel or a green subpixel.

基于上述第一种可能的实施方式,为实现第一空穴产生子结构121a的导电性高于第二空穴产生子结构121b的导电性,具体可以采用:第一空穴产生子结构121a的主客体掺杂比大于第二空穴产生子结构121b的主客体掺杂比。Based on the above-mentioned first possible implementation manner, in order to realize that the conductivity of the first hole generating substructure 121a is higher than that of the second hole generating substructure 121b, specifically: The host-guest doping ratio is greater than the host-guest doping ratio of the second hole-generating substructure 121b.

在本实施例中,通过控制第一空穴产生子结构121a以及第二空穴产生子结构121b中的主客体掺杂比例,来实现针对第一空穴产生子结构121a以及第二空穴产生子结构121b导电性能差异化。In this embodiment, by controlling the host-guest doping ratios in the first hole-generating substructure 121a and the second hole-generating substructure 121b, the first hole-generating substructure 121a and the second hole-generating substructure 121a are generated The conductive properties of the substructures 121b are differentiated.

基于上述第一种可能的实施方式,如图4所示,第一空穴产生子结构121a与第二空穴产生子结构121b之间具有第一间隔10。Based on the above-mentioned first possible implementation manner, as shown in FIG. 4 , there is a first space 10 between the first hole generating substructure 121a and the second hole generating substructure 121b.

在本实施例中,第一间隔10有利于第一空穴产生子结构121a与第二空穴产生子结构121b断开,可有效降低因空穴材料搭接而引起的串扰现象的发生概率。In this embodiment, the first spacer 10 facilitates the disconnection of the first hole-generating substructure 121a and the second hole-generating substructure 121b, which can effectively reduce the occurrence probability of crosstalk caused by the overlap of hole materials.

在一些示例中,第一间隔10不小于2微米。以确保足够地绝缘。In some examples, the first spacing 10 is not less than 2 microns. to ensure adequate insulation.

在一些示例中,第一空穴产生子结构121a与第二空穴产生子结构121b之间的第一间隔10,可以通过缩小制备第一空穴产生子结构121a或第二空穴产生子结构121b的掩膜板开口尺寸形成;也可以在制备得到第一空穴产生子结构121a与第二空穴产生子结构121b之后,通过刻蚀形成。In some examples, the first space 10 between the first hole-generating substructure 121a and the second hole-generating substructure 121b can be fabricated by shrinking the first hole-generating substructure 121a or the second hole-generating substructure The size of the opening of the mask plate 121b is formed; it can also be formed by etching after the first hole generating substructure 121a and the second hole generating substructure 121b are prepared.

需要说明的是,发光层110还可以包括第三子像素113,该第三子像素113的驱动电压也比第一子像素111的驱动电压低,第二空穴产生子结构121b可以同时对应第二子像素112和第三子像素113,即第二子像素112与第三子像素113共用第二空穴产生子结构121b。It should be noted that, the light emitting layer 110 may further include a third sub-pixel 113, the driving voltage of the third sub-pixel 113 is also lower than the driving voltage of the first sub-pixel 111, and the second hole-generating substructure 121b may correspond to the third sub-pixel 113 at the same time. The second sub-pixel 112 and the third sub-pixel 113 , that is, the second sub-pixel 112 and the third sub-pixel 113 share the second hole-generating sub-structure 121 b.

在第二种可能的实施方式中,如图3所示,发光层110包括:第一子像素111和第二子像素112。In a second possible implementation manner, as shown in FIG. 3 , the light-emitting layer 110 includes: a first sub-pixel 111 and a second sub-pixel 112 .

电子产生层122包括:对应第一子像素111的第一电子产生子结构122a,和对应第二子像素112的第二电子产生子结构122b。The electron generation layer 122 includes: a first electron generation substructure 122 a corresponding to the first subpixel 111 , and a second electron generation substructure 122 b corresponding to the second subpixel 112 .

其中,第一子像素111的驱动电压高于第二子像素112的驱动电压,第一电子产生子结构122a的导电性高于第二电子产生子结构122b的导电性。The driving voltage of the first sub-pixel 111 is higher than the driving voltage of the second sub-pixel 112, and the conductivity of the first electron generating sub-structure 122a is higher than that of the second electron generating sub-structure 122b.

在本实施例中,第一子像素111和第二子像素112相对而言,第一子像素111是高驱动电压像素,第二子像素112是低驱动电压像素。本实施例提供的电致发光器件100,通过对电荷产生层120中分别对应第一子像素111和第二子像素112的电子产生层122(即N型电荷产生层120)进行差异化设置,具体是导电性更高的第一电子产生子结构122a对应高驱动电压像素,导电性相对较低的第二电子产生子结构122b对应低驱动电压像素,从而更好地匹配发光层110不同驱动电压子像素的能级,优化产品特性和功耗收益。In this embodiment, the first subpixel 111 and the second subpixel 112 are relatively speaking, the first subpixel 111 is a high driving voltage pixel, and the second subpixel 112 is a low driving voltage pixel. In the electroluminescent device 100 provided in this embodiment, the electron generating layers 122 (ie, the N-type charge generating layers 120 ) in the charge generating layer 120 corresponding to the first sub-pixel 111 and the second sub-pixel 112 respectively are set differently, Specifically, the first electron generating substructure 122a with higher conductivity corresponds to a high driving voltage pixel, and the second electron generating substructure 122b with a relatively low conductivity corresponds to a low driving voltage pixel, so as to better match the different driving voltages of the light emitting layer 110 Energy levels of sub-pixels, optimizing product characteristics and power consumption benefits.

在一个示例中,第一子像素111为蓝色子像素,第二子像素112为红色子像素或绿色子像素。In one example, the first subpixel 111 is a blue subpixel, and the second subpixel 112 is a red subpixel or a green subpixel.

基于上述第二种可能的实施方式,第一电子产生子结构122a的主客体掺杂比大于第二电子产生子结构122b的主客体掺杂比。Based on the above-mentioned second possible embodiment, the host-guest doping ratio of the first electron generating substructure 122a is greater than the host-guest doping ratio of the second electron generating substructure 122b.

在本实施例中,通过控制第一电子产生子结构122a以及第二电子产生子结构122b中的主客体掺杂比例,来实现针对第一电子产生子结构122a以及第二电子产生子结构122b导电性能差异化。In the present embodiment, by controlling the host-guest doping ratios in the first electron generating substructure 122a and the second electron generating substructure 122b, conduction is achieved for the first electron generating substructure 122a and the second electron generating substructure 122b Performance differentiation.

基于上述第二种可能的实施方式,如图4所示,第一电子产生子结构122a与第二电子产生子结构122b之间具有第二间隔(图中未绘出,可参见第一间隔10)。Based on the above-mentioned second possible implementation manner, as shown in FIG. 4 , there is a second space between the first electron generating substructure 122a and the second electron generating substructure 122b (not shown in the figure, please refer to the first space 10 ).

在本实施例中,第二间隔有利于第一电子产生子结构122a与第二电子产生子结构122b断开,也可有效降低因电子材料搭接而引起的串扰现象的发生概率。In the present embodiment, the second interval facilitates the disconnection of the first electron generating substructure 122a and the second electron generating substructure 122b, and can also effectively reduce the occurrence probability of crosstalk caused by overlapping of electronic materials.

在一些示例中,第二间隔不小于2微米。以确保足够地绝缘。In some examples, the second separation is not less than 2 microns. to ensure adequate insulation.

在一些示例中,第一电子产生子结构122a与第二电子产生子结构122b之间的第二间隔,可以通过缩小制备第一电子产生子结构122a或第二电子产生子结构122b的掩膜板开口尺寸形成;也可以在制备得到第一电子产生子结构122a与第二电子产生子结构122b之后,通过刻蚀形成。In some examples, the second space between the first electron generating substructure 122a and the second electron generating substructure 122b can be reduced by reducing the mask for preparing the first electron generating substructure 122a or the second electron generating substructure 122b The size of the opening is formed; it can also be formed by etching after the first electron generating substructure 122a and the second electron generating substructure 122b are prepared.

需要说明的是,发光层110还可以包括第三子像素113,该第三子像素113的驱动电压也比第一子像素111的驱动电压低,第二电子产生子结构122b可以同时对应第二子像素112和第三子像素113,即第二子像素112与第三子像素113共用第二电子产生子结构122b。It should be noted that the light-emitting layer 110 may further include a third sub-pixel 113, and the driving voltage of the third sub-pixel 113 is also lower than the driving voltage of the first sub-pixel 111, and the second electron generating sub-structure 122b may simultaneously correspond to the second sub-pixel 113. The sub-pixel 112 and the third sub-pixel 113, that is, the second sub-pixel 112 and the third sub-pixel 113 share the second electron generating sub-structure 122b.

基于上述第一种可能的实施方式和第二种可能的实施方式中的至少一种,发光层110包括:第一子像素111、第二子像素112和第三子像素113。Based on at least one of the first possible implementation manner and the second possible implementation manner, the light emitting layer 110 includes: a first subpixel 111 , a second subpixel 112 and a third subpixel 113 .

第一子像素111的驱动电压分别高于第二子像素112的驱动电压、第三子像素113的驱动电压。The driving voltage of the first sub-pixel 111 is higher than the driving voltage of the second sub-pixel 112 and the driving voltage of the third sub-pixel 113, respectively.

如图5和图6所示,第一子像素111与第二子像素112之间具有第三间隔20,第一子像素111与第三子像素113之间具有第四间隔30。As shown in FIG. 5 and FIG. 6 , there is a third interval 20 between the first subpixel 111 and the second subpixel 112 , and a fourth interval 30 between the first subpixel 111 and the third subpixel 113 .

在本实施例中,第一子像素111、第二子像素112和第三子像素113可以分别是蓝色子像素、绿色子像素和红色子像素,三基础色的配置有利于发光层110实现全色系的出光效果。In this embodiment, the first sub-pixel 111 , the second sub-pixel 112 and the third sub-pixel 113 may be blue sub-pixels, green sub-pixels and red sub-pixels respectively, and the configuration of the three basic colors is beneficial to the realization of the light-emitting layer 110 Full color lighting effect.

第一子像素111、第二子像素112和第三子像素113三者相对而言,第一子像素111是高驱动电压像素,第二子像素112和第三子像素113均是低驱动电压像素。Relatively speaking, the first sub-pixel 111, the second sub-pixel 112 and the third sub-pixel 113 have a high driving voltage pixel, and both the second sub-pixel 112 and the third sub-pixel 113 have a low driving voltage. pixel.

本实施例提供的电致发光器件100,通过第二间隔有利于第一子像素111与第二子像素112断开,第三间隔20有利于第一子像素111与第三子像素113断开,可有效降低因子像素材料搭接而引起的串扰现象的发生概率。In the electroluminescent device 100 provided in this embodiment, the second interval facilitates the disconnection between the first subpixel 111 and the second subpixel 112 , and the third interval 20 facilitates the disconnection between the first subpixel 111 and the third subpixel 113 , which can effectively reduce the probability of occurrence of crosstalk caused by overlapping of pixel materials.

在一些示例中,第三间隔20不小于2微米。In some examples, the third spacing 20 is not less than 2 microns.

在一些示例中,第四间隔30不小于2微米。In some examples, the fourth spacing 30 is not less than 2 microns.

在一些示例中,第三间隔20和第四间隔30均不小于2微米。In some examples, both the third spacing 20 and the fourth spacing 30 are not less than 2 microns.

基于同一发明构思,本申请实施例提供了一种显示面板,该显示面板包括:如上述各实施例提供的任一种电致发光器件100。Based on the same inventive concept, an embodiment of the present application provides a display panel, and the display panel includes: any one of the electroluminescent devices 100 provided in the foregoing embodiments.

在本实施例中,由于显示面板包括了前述实施例提供的任一种电致发光器件100,其实现原理和有益效果相类似,此处不再赘述。In this embodiment, since the display panel includes any of the electroluminescent devices 100 provided in the foregoing embodiments, the implementation principles and beneficial effects thereof are similar, and will not be repeated here.

在一些示例中,显示面板可以是柔性面板、曲面面板等。In some examples, the display panel may be a flexible panel, a curved panel, or the like.

基于同一发明构思,本申请实施例提供了一种显示装置,该显示装置包括:如上述各实施例提供的任一种显示面板。Based on the same inventive concept, an embodiment of the present application provides a display device, and the display device includes: any one of the display panels provided in the above-mentioned embodiments.

在本实施例中,由于显示装置包括了前述实施例提供的任一种显示面板,其实现原理和有益效果相类似,此处不再赘述。In this embodiment, since the display device includes any one of the display panels provided in the foregoing embodiments, the implementation principles and beneficial effects thereof are similar, and are not repeated here.

在一些示例中,显示装置可以包括手机、平板电脑、移动终端、电子书、电子相框等等。In some examples, the display device may include a cell phone, a tablet computer, a mobile terminal, an electronic book, an electronic photo frame, and the like.

应用本申请实施例,至少能够实现如下有益效果:By applying the embodiments of the present application, at least the following beneficial effects can be achieved:

1、叠层的电致发光器件100中电荷产生层120P型电荷产生层120(PCGL)的掺杂浓度与N型电荷产生层120(NCGL)的掺杂浓度进行差异化设置,具体是控制空穴产生层121的主客体掺杂比大于电子产生层122的主客体掺杂比,并控制两主客体掺杂比(即第一掺杂比与第二掺杂比)之间的比例不小于3:1且不大于20:1,有利于更好的匹配发光层110中各像素的驱动电压,并减轻像素串扰现象。1. In the stacked electroluminescent device 100, the doping concentration of the charge generation layer 120 of the P-type charge generation layer 120 (PCGL) and the doping concentration of the N-type charge generation layer 120 (NCGL) are set differently. The host-guest doping ratio of the hole-generating layer 121 is greater than the host-guest doping ratio of the electron-generating layer 122, and the ratio between the two host-guest doping ratios (ie, the first doping ratio and the second doping ratio) is controlled to be not less than The ratio of 3:1 and not more than 20:1 is beneficial to better match the driving voltage of each pixel in the light emitting layer 110 and reduce the phenomenon of pixel crosstalk.

2、通过对电荷产生层120中分别对应第一子像素111和第二子像素112的空穴产生层121(即P型电荷产生层120)进行差异化设置,具体是导电性更高的第一空穴产生子结构121a对应高驱动电压像素,导电性相对较低的第二空穴产生子结构121b对应低驱动电压像素,从而更好地匹配发光层110不同驱动电压子像素的能级,优化产品特性和功耗收益。2. The hole-generating layers 121 (ie, the P-type charge-generating layers 120 ) in the charge-generating layer 120 corresponding to the first sub-pixel 111 and the second sub-pixel 112 respectively are set differently, specifically, the first sub-pixel with higher conductivity. A hole-generating substructure 121a corresponds to a high driving voltage pixel, and a second hole-generating substructure 121b with relatively low conductivity corresponds to a low driving voltage pixel, so as to better match the energy levels of the light-emitting layer 110 with different driving voltage sub-pixels. Optimize product features and power benefits.

3、通过控制第一空穴产生子结构121a以及第二空穴产生子结构121b中的主客体掺杂比例,来实现针对第一空穴产生子结构121a以及第二空穴产生子结构121b导电性能差异化。3. By controlling the host-guest doping ratios in the first hole-generating substructure 121a and the second hole-generating substructure 121b, conduction is achieved for the first hole-generating substructure 121a and the second hole-generating substructure 121b Performance differentiation.

4、第一间隔10有利于第一空穴产生子结构121a与第二空穴产生子结构121b断开,可有效降低因空穴材料搭接而引起的串扰现象的发生概率。4. The first spacer 10 facilitates the disconnection of the first hole-generating substructure 121a from the second hole-generating substructure 121b, which can effectively reduce the occurrence probability of crosstalk caused by the overlap of hole materials.

5、通过对电荷产生层120中分别对应第一子像素111和第二子像素112的电子产生层122(即N型电荷产生层120)进行差异化设置,具体是导电性更高的第一电子产生子结构122a对应高驱动电压像素,导电性相对较低的第二电子产生子结构122b对应低驱动电压像素,从而更好地匹配发光层110不同驱动电压子像素的能级,优化产品特性和功耗收益。5. The electron generating layers 122 (ie the N-type charge generating layers 120 ) in the charge generating layer 120 corresponding to the first sub-pixel 111 and the second sub-pixel 112 respectively are set differently, specifically, the first and second sub-pixels 111 with higher conductivity are differentiated. The electron generating substructure 122a corresponds to a high driving voltage pixel, and the second electron generating substructure 122b with relatively low conductivity corresponds to a low driving voltage pixel, so as to better match the energy levels of the sub-pixels with different driving voltages of the light-emitting layer 110 and optimize product characteristics and power gains.

6、通过控制第一电子产生子结构122a以及第二电子产生子结构122b中的主客体掺杂比例,来实现针对第一电子产生子结构122a以及第二电子产生子结构122b导电性能差异化。6. By controlling the host-guest doping ratios in the first electron generating substructure 122a and the second electron generating substructure 122b, the conductive properties of the first electron generating substructure 122a and the second electron generating substructure 122b are differentiated.

7、第二间隔有利于第一电子产生子结构122a与第二电子产生子结构122b断开,也可有效降低因电子材料搭接而引起的串扰现象的发生概率。7. The second interval facilitates the disconnection of the first electron generating substructure 122a from the second electron generating substructure 122b, and can also effectively reduce the occurrence probability of crosstalk caused by overlapping of electronic materials.

8、通过第二间隔有利于第一子像素111与第二子像素112断开,第三间隔20有利于第一子像素111与第三子像素113断开,可有效降低因子像素材料搭接而引起的串扰现象的发生概率。8. The second interval facilitates the disconnection of the first sub-pixel 111 and the second sub-pixel 112, and the third interval 20 facilitates the disconnection of the first sub-pixel 111 and the third sub-pixel 113, which can effectively reduce the factor of pixel material overlap The probability of occurrence of crosstalk phenomenon caused.

本技术领域技术人员可以理解,本申请的描述中,词语“中心”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方向或位置关系,为基于附图所示的示例性的方向或位置关系,是为了便于描述或简化描述本申请的实施例,而不是指示或暗示所指的装置或部件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。Those skilled in the art can understand that in the description of this application, the words "center", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal" "," "top", "bottom", "inside", "outside", etc. indicate the direction or positional relationship, which is based on the exemplary direction or positional relationship shown in the accompanying drawings, and is for the convenience of description or simplified description of the present application Examples, rather than indicating or implying that the device or component referred to must have a particular orientation, be constructed and operate in a particular orientation, should not be construed as a limitation of the present application.

术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本申请的描述中,除非另有说明,“多个”的含义是两个或两个以上。The terms "first" and "second" are only used for descriptive purposes, and should not be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first", "second" may expressly or implicitly include one or more of that feature. In the description of this application, unless stated otherwise, "plurality" means two or more.

在本申请的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本申请中的具体含义。In the description of this application, it should be noted that, unless otherwise expressly specified and limited, the terms "installed", "connected" and "connected" should be understood in a broad sense, for example, it may be a fixed connection or a detachable connection Connection, or integral connection; it can be directly connected, or indirectly connected through an intermediate medium, and it can be the internal communication of two elements. For those of ordinary skill in the art, the specific meanings of the above terms in this application can be understood in specific situations.

在本说明书的描述中,具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, the particular features, structures, materials or characteristics may be combined in any suitable manner in any one or more embodiments or examples.

以上所述仅是本申请的部分实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本申请的方案技术构思的前提下,采用基于本申请技术思想的其他类似实施手段,同样属于本申请实施例的保护范畴。The above are only some embodiments of the present application. It should be pointed out that for those skilled in the art, other similar implementation means based on the technical idea of the present application can be adopted without departing from the technical idea of the solution of the present application. , which also belong to the protection category of the embodiments of the present application.

Claims (14)

1.一种电致发光器件,其特征在于,包括:1. An electroluminescent device, characterized in that, comprising: 至少两层叠的发光层;at least two stacked light-emitting layers; 电荷产生层,位于相邻两所述发光层之间,包括层叠的空穴产生层和电子产生层;A charge generation layer, located between two adjacent light-emitting layers, includes a stacked hole generation layer and an electron generation layer; 其中,所述空穴产生层的主客体掺杂比为第一掺杂比,所述电子产生层的主客体掺杂比为第二掺杂比,所述第一掺杂比与所述第二掺杂比之间的比例不小于3:1且不大于20:1。The host-guest doping ratio of the hole generating layer is a first doping ratio, the host-guest doping ratio of the electron generating layer is a second doping ratio, and the first doping ratio is the same as the first doping ratio. The ratio between the two doping ratios is not less than 3:1 and not more than 20:1. 2.根据权利要求1所述的电致发光器件,其特征在于,所述空穴产生层的主体材料包括以下化合物中的至少一种:2. The electroluminescent device according to claim 1, wherein the host material of the hole generating layer comprises at least one of the following compounds:
Figure FDA0003720812530000011
Figure FDA0003720812530000011
3.根据权利要求1所述的电致发光器件,其特征在于,所述空穴产生层的客体材料包括以下化合物中的至少一种:3. The electroluminescent device according to claim 1, wherein the guest material of the hole generating layer comprises at least one of the following compounds:
Figure FDA0003720812530000021
Figure FDA0003720812530000021
4.根据权利要求1所述的电致发光器件,其特征在于,所述电子产生层的主体材料包括以下化合物中的至少一种:4. The electroluminescent device according to claim 1, wherein the host material of the electron generating layer comprises at least one of the following compounds:
Figure FDA0003720812530000022
Figure FDA0003720812530000022
5.根据权利要求1-4中任一所述的电致发光器件,其特征在于,所述发光层包括:第一子像素和第二子像素;5. The electroluminescent device according to any one of claims 1-4, wherein the light-emitting layer comprises: a first sub-pixel and a second sub-pixel; 所述空穴产生层包括:对应所述第一子像素的第一空穴产生子结构,和对应所述第二子像素的第二空穴产生子结构;The hole generation layer includes: a first hole generation substructure corresponding to the first subpixel, and a second hole generation substructure corresponding to the second subpixel; 其中,所述第一子像素的驱动电压高于所述第二子像素的驱动电压,所述第一空穴产生子结构的导电性高于所述第二空穴产生子结构的导电性。Wherein, the driving voltage of the first sub-pixel is higher than the driving voltage of the second sub-pixel, and the conductivity of the first hole-generating substructure is higher than that of the second hole-generating substructure. 6.根据权利要求5中任一所述的电致发光器件,其特征在于,所述第一空穴产生子结构的主客体掺杂比大于所述第二空穴产生子结构的主客体掺杂比;6 . The electroluminescent device according to claim 5 , wherein the host-guest doping ratio of the first hole-generating substructure is greater than the host-guest doping ratio of the second hole-generating substructure. 7 . hybrid ratio; 和/或,所述第一空穴产生子结构与所述第二空穴产生子结构之间具有第一间隔。And/or, there is a first space between the first hole-generating substructure and the second hole-generating substructure. 7.根据权利要求6所述的电致发光器件,其特征在于,所述第一间隔不小于2微米。7. The electroluminescent device according to claim 6, wherein the first interval is not less than 2 microns. 8.根据权利要求1-4中任一所述的电致发光器件,其特征在于,所述发光层包括:第一子像素和第二子像素;8. The electroluminescent device according to any one of claims 1-4, wherein the light-emitting layer comprises: a first sub-pixel and a second sub-pixel; 所述电子产生层包括:对应所述第一子像素的第一电子产生子结构,和对应所述第二子像素的第二电子产生子结构;The electron generating layer includes: a first electron generating substructure corresponding to the first subpixel, and a second electron generating substructure corresponding to the second subpixel; 其中,所述第一子像素的驱动电压高于所述第二子像素的驱动电压,所述第一电子产生子结构的导电性高于所述第二电子产生子结构的导电性。Wherein, the driving voltage of the first sub-pixel is higher than the driving voltage of the second sub-pixel, and the conductivity of the first electron generating sub-structure is higher than that of the second electron generating sub-structure. 9.根据权利要求8所述的电致发光器件,其特征在于,所述第一电子产生子结构的主客体掺杂比大于所述第二电子产生子结构的主客体掺杂比;9 . The electroluminescent device according to claim 8 , wherein the host-guest doping ratio of the first electron generating substructure is greater than the host-guest doping ratio of the second electron generating substructure; 10 . 和/或,所述第一电子产生子结构与所述第二电子产生子结构之间具有第二间隔。And/or, there is a second space between the first electron generating substructure and the second electron generating substructure. 10.根据权利要求9所述的电致发光器件,其特征在于,所述第二间隔不小于2微米。10. The electroluminescent device according to claim 9, wherein the second interval is not less than 2 microns. 11.根据权利要求1-4中任一所述的电致发光器件,其特征在于,所述发光层包括:第一子像素、第二子像素和第三子像素;11. The electroluminescent device according to any one of claims 1-4, wherein the light-emitting layer comprises: a first sub-pixel, a second sub-pixel and a third sub-pixel; 所述第一子像素的驱动电压分别高于所述第二子像素的驱动电压、所述第三子像素的驱动电压;The driving voltage of the first sub-pixel is respectively higher than the driving voltage of the second sub-pixel and the driving voltage of the third sub-pixel; 所述第一子像素与所述第二子像素之间具有第三间隔,所述第一子像素与所述第三子像素之间具有第四间隔。There is a third interval between the first subpixel and the second subpixel, and a fourth interval between the first subpixel and the third subpixel. 12.根据权利要求11所述的电致发光器件,其特征在于,所述第三间隔和所述第四间隔中的至少一种不小于2微米。12. The electroluminescent device of claim 11, wherein at least one of the third interval and the fourth interval is not less than 2 microns. 13.一种显示面板,其特征在于,包括:如上述权利要求1-12中任一所述的电致发光器件。13. A display panel, characterized by comprising: the electroluminescent device according to any one of the preceding claims 1-12. 14.一种显示装置,其特征在于,包括:如上述权利要求13所述的显示面板。14. A display device, comprising: the display panel according to claim 13.
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CN114586186A (en) * 2020-09-28 2022-06-03 京东方科技集团股份有限公司 Organic electroluminescent device and display device
CN113054124A (en) * 2021-02-20 2021-06-29 京东方科技集团股份有限公司 Organic light-emitting device, display device, manufacturing method and storage medium
CN114361372A (en) * 2022-01-04 2022-04-15 京东方科技集团股份有限公司 Organic compounds, light-emitting devices and display devices

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115915851A (en) * 2022-10-26 2023-04-04 京东方科技集团股份有限公司 A display substrate and a display device
WO2024124868A1 (en) * 2022-12-13 2024-06-20 武汉华星光电半导体显示技术有限公司 Display panel and mobile terminal

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