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CN115011193A - Low-energy-consumption high-gloss emulsion paint and preparation method thereof - Google Patents

Low-energy-consumption high-gloss emulsion paint and preparation method thereof Download PDF

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Publication number
CN115011193A
CN115011193A CN202210709000.3A CN202210709000A CN115011193A CN 115011193 A CN115011193 A CN 115011193A CN 202210709000 A CN202210709000 A CN 202210709000A CN 115011193 A CN115011193 A CN 115011193A
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Prior art keywords
emulsion
low
gloss
energy
consumption high
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CN202210709000.3A
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Chinese (zh)
Inventor
雷洪正
刘庆林
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Guangdong Dazheng Caiyi Painting Co ltd
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Guangdong Dazheng Caiyi Painting Co ltd
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Priority to CN202210709000.3A priority Critical patent/CN115011193A/en
Publication of CN115011193A publication Critical patent/CN115011193A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to the technical field of emulsion paints, and discloses a low-energy-consumption high-gloss emulsion paint which is prepared from water, a film-forming auxiliary agent, a dispersing agent, a defoaming agent, calcium carbonate, a smell-removing emulsion, a thickening agent and a bactericide. Compared with the prior art, the invention has the following beneficial effects: by utilizing the mutual synergistic effect of all the substances, the prepared finished product has the advantages of high gloss, low energy consumption, low cost, good air permeability, smooth paint film, high hardness and the like; the paint film has fine and smooth hand feeling, low amount of the emulsion added with the acrylic copolymer, saved cost, reduced energy consumption and breathing function, water in the wall can be freely evaporated outwards, the coating can be prevented from foaming, the wall and the coating can be ensured to be dry and smooth, the paint film is hard and smooth, static electricity is not easy to generate, dust is not easy to adsorb, only one finish is needed after the primer is brushed, and time and labor are saved.

Description

Low-energy-consumption high-gloss emulsion paint and preparation method thereof
Technical Field
The invention belongs to the technical field of emulsion paints, and particularly relates to a low-energy-consumption high-gloss emulsion paint.
Background
The high-gloss emulsion paint is widely applied to the inner wall surfaces of buildings due to high gloss and good visual effect. In the existing high-gloss emulsion paint, the high-gloss effect is achieved mostly by improving the content of acrylic emulsion in the components, the content of carbon-containing elements in the acrylic emulsion is high, and meanwhile, the acrylic emulsion is prepared from petroleum serving as a raw material through a chemical process, so that the improvement of the content of the acrylic emulsion can greatly use non-renewable resource petroleum, and is not beneficial to environmental protection.
In view of this, this patent is filed.
Disclosure of Invention
In order to overcome the defects of the prior art, the low-gloss emulsion paint adopts low acrylic emulsion content and is matched with film-forming agents, dispersing agents, defoaming agents and other components, has the characteristics of high gloss and low cost, is lower in energy consumption, is more beneficial to environmental protection, and solves the problems of high acrylic emulsion content, high cost and environmental damage of the existing high-gloss emulsion paint.
The invention aims to provide low-energy-consumption high-gloss emulsion paint.
The invention also aims to provide a preparation method of the low-energy-consumption high-gloss latex paint.
According to the embodiment of the invention, the low-energy-consumption high-gloss emulsion paint is prepared from the following materials: water, film forming assistant, dispersant, defoamer, calcium carbonate, odorless emulsion, thickener and bactericide.
According to the specific embodiment of the invention, the low-energy-consumption high-gloss emulsion paint is prepared from the following materials in parts by mass: 20 to 30 portions of water, 0.5 to 1 portion of film forming additive, 0.5 to 1 portion of dispersant, 0.2 to 0.4 portion of defoamer, 55 to 65 portions of calcium carbonate, 12 to 20 portions of odor-free emulsion, 0.5 to 1 portion of thickener and 0.1 to 0.4 portion of bactericide.
According to the specific embodiment of the invention, the low-energy-consumption high-gloss emulsion paint is prepared from the following materials in parts by mass: 20 to 30 portions of water, 0.5 to 1 portion of film forming additive, 0.5 to 1 portion of dispersant, 0.2 to 0.4 portion of defoamer, 55 to 65 portions of calcium carbonate, 12 to 20 portions of odor-free emulsion, 0.5 to 1 portion of thickener and 0.1 to 0.4 portion of bactericide.
According to the low-energy-consumption high-gloss emulsion paint provided by the invention, the film-forming aid is an alcohol ester dodeca film-forming aid selected from American Issman Texanol alcohol ester dodeca film-forming aids.
According to the low-energy-consumption high-gloss emulsion paint provided by the embodiment of the invention, the dispersing agent is a sodium salt dispersing agent, and an alkyd type C20 sodium polyacrylate dispersing agent of Wanhua chemical group GmbH, a Nippon Nupu 5040 dispersing agent or a 5040 dispersing agent of Sansha chemical company of Zhongshan city are selected.
According to the low-energy-consumption high-gloss emulsion paint provided by the embodiment of the invention, the defoaming agent is a mineral oil defoaming agent, and the CF245 mineral oil defoaming agent of Shenzhen Shanghai Runjiang chemical industry Co., Ltd or the Japan Nopopco 1308 defoaming agent is selected.
According to the low-energy-consumption high-gloss emulsion paint disclosed by the embodiment of the invention, the odorless emulsion is odorless acrylic emulsion, and 8120 acrylic copolymer emulsion of Wanhua chemical group, Inc. is selected.
According to the low-energy-consumption high-gloss emulsion paint provided by the embodiment of the invention, the thickener is a hydrophobic association type alkali swelling thickener, and is selected from A401 hydrophobic modified alkali swelling thickener of Wanhua chemical group, Inc., or American Dow TT935 thickener.
According to the low-energy-consumption high-gloss emulsion paint provided by the invention, the bactericide is a broad-spectrum bactericide, and an ElimaC115 rapid high-efficiency broad-spectrum bactericide and an American Dow LX300 broad-spectrum bactericide of Guangdong Yi Austenitic science and technology Limited company are selected.
According to the low-energy-consumption high-gloss emulsion paint disclosed by the embodiment of the invention, 3000-mesh heavy calcium carbonate is selected as the calcium carbonate.
The method for preparing the low-energy-consumption high-gloss emulsion paint comprises the following operation steps:
step A, mixing the water, the defoaming agent, the dispersing agent and the film forming additive, and stirring at 400-600 rpm for 3-5 minutes to obtain uniformly dispersed mixed slurry I;
step B, adding calcium carbonate into the mixed slurry I obtained in the step A, and stirring at 1000-1500 rpm for 20-40 minutes to obtain uniformly dispersed mixed slurry II;
and step C, adding the odorless emulsion, the thickening agent and the bactericide into the mixed slurry II obtained in the step B, mixing, and stirring at 800-1200 rpm for 3-8 minutes to obtain the low-energy-consumption high-gloss emulsion paint.
Compared with the prior art, the invention has the following beneficial effects:
(1) according to the low-energy-consumption high-gloss emulsion paint, the components are proportioned within a certain range by screening the filler, the film-forming substance and the auxiliary agent thereof, and the prepared finished product has the advantages of high gloss, low energy consumption, low cost, good air permeability, smooth paint film, high hardness and the like by utilizing the mutual synergistic effect of the substances and selecting the odorless pure acrylic emulsion with ultralow VOC and formaldehyde content and no APEO (alkylphenol ethoxylates) in the formula;
(2) the low-energy-consumption high-gloss emulsion paint has the advantages that the emulsion paint film is fine and smooth in hand feeling, the amount of the emulsion added with the acrylic copolymer is low, the cost is saved, the energy consumption is reduced, the emulsion paint has a breathing function, the water in the wall can be freely evaporated outwards, the coating can be prevented from foaming, the wall and the coating can be ensured to be dry and smooth, the emulsion paint film is hard and smooth, static electricity is not easily generated, dust is not easily adsorbed, only one finish paint is needed after the primer paint is brushed, and the time and the labor are saved.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
The raw materials used in the present invention are all available from common commercial sources, and are not particularly limited herein.
Example 1
The embodiment provides a low-energy-consumption high-gloss emulsion paint which is prepared from the following materials in parts by mass: 0.3 part of defoaming agent, 0.8 part of dispersing agent, 60 parts of calcium carbonate, 0.8 part of thickening agent, 0.8 part of film-forming assistant, 0.3 part of preservative, 15 parts of odor-free emulsion and 25 parts of water.
The film-forming assistant is an alcohol ester dodecafilm-forming assistant, the dispersant is a sodium salt dispersant, a 5040 dispersant of Sansku chemical Co., Ltd, Zhongshan city, the defoamer is a mineral oil defoamer, a Nonopho 1308 defoamer is selected, the odorless emulsion is an odorless pure acrylic emulsion, an 8120 acrylic acid copolymer emulsion of Wanhua chemical group Co., Ltd is selected, the thickener is a hydrophobic association type alkali swelling thickener, an American Dow TT935 thickener is selected, the bactericide is a broad-spectrum bactericide, an American Dow LX300 broad-spectrum bactericide is selected, and the calcium carbonate is 3000-mesh heavy calcium carbonate.
The preparation method of the low-energy-consumption-resistant high-gloss emulsion paint comprises the following steps: the preparation method comprises the following preparation steps:
step A, mixing the water, the defoaming agent, the dispersing agent and the film-forming assistant, and stirring at 400rpm for 5 minutes to obtain uniformly dispersed mixed slurry I;
step B, adding calcium carbonate into the mixed slurry I obtained in the step A, and stirring at 1000rpm for 40 minutes to obtain uniformly dispersed mixed slurry II;
and step C, adding the odorless emulsion, the thickening agent and the bactericide into the mixed slurry II obtained in the step B, mixing, and stirring at 800rpm for 8 minutes to obtain the low-energy-consumption high-gloss emulsion paint.
Example 2
The embodiment provides a low-energy-consumption high-gloss emulsion paint which is prepared from the following materials in parts by mass: 0.3 part of defoaming agent, 0.8 part of dispersing agent, 65 parts of calcium carbonate, 0.9 part of thickening agent, 0.5 part of film-forming assistant, 0.3 part of preservative, 12 parts of odor-free emulsion and 20 parts of water.
The preparation method of the low-energy-consumption-resistant high-gloss emulsion paint comprises the following steps: the preparation method comprises the following preparation steps:
step A, mixing the water, the defoaming agent, the dispersing agent and the film-forming assistant, and stirring for 3 minutes at 600rpm to obtain uniformly dispersed mixed slurry I;
step B, adding calcium carbonate into the mixed slurry I obtained in the step A, and stirring at 1500rpm for 20 minutes to obtain uniformly dispersed mixed slurry II;
and step C, adding the odor-free emulsion, the thickening agent and the bactericide into the mixed slurry II obtained in the step B, mixing, and stirring at 1200rpm for 3 minutes to obtain the low-energy-consumption high-gloss emulsion paint.
Example 3
The embodiment provides a low-energy-consumption high-gloss emulsion paint which is prepared from the following materials in parts by mass: 0.2 part of defoaming agent, 0.5 part of dispersing agent, 62 parts of calcium carbonate, 0.5 part of thickening agent, 1.0 part of film-forming assistant, 0.3 part of preservative, 18 parts of odor-free emulsion and 30 parts of water.
The preparation method of the low-energy-consumption-resistant high-gloss emulsion paint comprises the following steps: the preparation method comprises the following preparation steps:
step A, mixing the water, the defoaming agent, the dispersing agent and the film forming additive, and stirring at 500rpm for 3-5 minutes to obtain uniformly dispersed mixed slurry I;
step B, adding calcium carbonate into the mixed slurry I obtained in the step A, and stirring at 1200rpm for 30 minutes to obtain uniformly dispersed mixed slurry II;
and step C, adding the odor-free emulsion, the thickening agent and the bactericide into the mixed slurry II obtained in the step B, mixing, and stirring at 1000rpm for 5 minutes to obtain the low-energy-consumption high-gloss emulsion paint.
Example 4
The embodiment provides a low-energy-consumption high-gloss emulsion paint which is prepared from the following materials in parts by mass: 0.4 part of defoaming agent, 0.6 part of dispersing agent, 55 parts of calcium carbonate, 0.8 part of thickening agent, 1.0 part of film-forming assistant, 0.3 part of preservative, 20 parts of odor-free emulsion and 25 parts of water.
The film-forming assistant is alcohol ester dodeca film-forming assistant, the American Issman Texanol ester dodeca film-forming assistant is selected, the dispersing agent is sodium salt dispersing agent, the alkyd type C20 sodium polyacrylate dispersing agent of Wanhua chemical group Co., Ltd is selected, the defoaming agent is mineral oil defoaming agent, the CF245 mineral oil defoaming agent of Shenzhen Haizun chemical industry Co., Ltd is selected, the odorless emulsion is pure acrylic emulsion, the 8120 acrylic acid copolymer emulsion of Wanhua chemical group Co., Ltd is selected, the thickening agent is hydrophobic association type alkali swelling thickening agent, the A401 hydrophobic modification alkali swelling thickening agent of Wanhua chemical group Co., Ltd is selected, the bactericide is broad spectrum bactericide, the ElimaC115 fast high-efficiency broad spectrum bactericide of Guangdong Yiyan technology Co., Ltd is selected, and the calcium carbonate is 3000 mesh heavy calcium carbonate.
The preparation method of the low-energy-consumption-resistant high-gloss emulsion paint comprises the following steps: the preparation method comprises the following preparation steps:
step A, mixing the water, the defoaming agent, the dispersing agent and the film-forming assistant, and stirring for 4 minutes at 450rpm to obtain uniformly dispersed mixed slurry I;
step B, adding calcium carbonate into the mixed slurry I obtained in the step A, and stirring at 1300rpm for 35 minutes to obtain uniformly dispersed mixed slurry II;
and step C, adding the odor-free emulsion, the thickening agent and the bactericide into the mixed slurry II obtained in the step B, mixing, and stirring at 900rpm for 6 minutes to obtain the low-energy-consumption high-gloss emulsion paint.
Performance test
The present invention was compared to existing coatings for specific physical property testing and cost comparison, wherein gloss was measured using a Coishika WGG60-E4 gloss meter with the following data:
TABLE 1 gloss comparison of latex paints
Figure BDA0003706410450000061
As can be seen from the above table, the gloss of the product prepared by the formulation and the preparation method of this example is equivalent to that of the existing product at a lower emulsion content, and the product is lower in cost, so that the product has more commercial value.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.

Claims (10)

1. The low-energy-consumption high-gloss emulsion paint is characterized by being prepared from the following materials: water, film forming assistant, dispersant, defoamer, calcium carbonate, odorless emulsion, thickener and bactericide.
2. The low-energy-consumption high-gloss emulsion paint according to claim 1, characterized in that the emulsion paint is prepared from the following materials in parts by mass: 20 to 30 portions of water, 0.5 to 1 portion of film forming additive, 0.5 to 1 portion of dispersant, 0.2 to 0.4 portion of defoamer, 55 to 65 portions of calcium carbonate, 12 to 20 portions of odor-free emulsion, 0.5 to 1 portion of thickener and 0.1 to 0.4 portion of bactericide.
3. The low-energy-consumption high-gloss emulsion paint according to claim 1 or 2, characterized in that the emulsion paint is prepared from the following materials in parts by mass: 25 parts of water, 0.8 part of film-forming additive, 0.8 part of dispersant, 0.3 part of defoamer, 60 parts of calcium carbonate, 15 parts of odor-free emulsion, 0.8 part of thickener and 0.3 part of bactericide.
4. The low energy and high gloss latex paint of claims 1-3 wherein said coalescent is an alcohol ester dodecacoalescent.
5. The low energy consumption high gloss latex paint according to any of claims 1-3 wherein said dispersant is a sodium salt dispersant.
6. The low energy consumption high gloss latex paint of claims 1-3 wherein said defoamer is a mineral oil defoamer.
7. The low energy and high gloss latex paint according to any of claims 1-3, wherein said neat emulsion is a neat acrylic emulsion.
8. The low energy consumption high gloss latex paint of claims 1-3 wherein said thickener is a hydrophobically associative alkali swellable thickener.
9. The low energy consumption high gloss latex paint according to any one of claims 1-3, wherein said biocide is a broad spectrum biocide.
10. A process for preparing a low energy and high gloss latex paint according to any of claims 1 to 9, comprising the following steps:
step A, mixing the water, the defoaming agent, the dispersing agent and the film forming additive, and stirring at 400-600 rpm for 3-5 minutes to obtain uniformly dispersed mixed slurry I;
step B, adding calcium carbonate into the mixed slurry I obtained in the step A, and stirring at 1000-1500 rpm for 20-40 minutes to obtain uniformly dispersed mixed slurry II;
and step C, adding the odor-free emulsion, the thickening agent and the bactericide into the mixed slurry II obtained in the step B, mixing, and stirring at 800-1200 rpm for 3-8 minutes to obtain the low-energy-consumption high-gloss emulsion paint.
CN202210709000.3A 2022-06-21 2022-06-21 Low-energy-consumption high-gloss emulsion paint and preparation method thereof Pending CN115011193A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101333356A (en) * 2007-06-28 2008-12-31 上海汇丽涂料有限公司 Environment-protecting health interior wall coatings
CA2869959A1 (en) * 2012-04-30 2013-11-07 Dow Global Technologies Llc Low voc glycol ether coalescents for water based coatings
CN107722769A (en) * 2017-11-16 2018-02-23 中山市阿里大师新材料有限公司 A kind of net odor interior wall latex paint and preparation method thereof
CN109082164A (en) * 2018-06-15 2018-12-25 德华兔宝宝装饰新材股份有限公司 A kind of smell-clearing full-effective is except formaldehyde interior wall coating and preparation method thereof
CN109735233A (en) * 2019-01-25 2019-05-10 上海贝塔建筑科技有限公司 A kind of coating and its preparation method and application
CN113861766A (en) * 2021-09-09 2021-12-31 广西标牌化学科技有限公司 Thin-coating type interior wall paint and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101333356A (en) * 2007-06-28 2008-12-31 上海汇丽涂料有限公司 Environment-protecting health interior wall coatings
CA2869959A1 (en) * 2012-04-30 2013-11-07 Dow Global Technologies Llc Low voc glycol ether coalescents for water based coatings
CN107722769A (en) * 2017-11-16 2018-02-23 中山市阿里大师新材料有限公司 A kind of net odor interior wall latex paint and preparation method thereof
CN109082164A (en) * 2018-06-15 2018-12-25 德华兔宝宝装饰新材股份有限公司 A kind of smell-clearing full-effective is except formaldehyde interior wall coating and preparation method thereof
CN109735233A (en) * 2019-01-25 2019-05-10 上海贝塔建筑科技有限公司 A kind of coating and its preparation method and application
CN113861766A (en) * 2021-09-09 2021-12-31 广西标牌化学科技有限公司 Thin-coating type interior wall paint and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
党常华等: "高效净味水性分散剂的合成与应用", 《上海涂料》 *

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Application publication date: 20220906