CN114952024A - A kind of laser etching method for plastic workpiece and plastic workpiece - Google Patents
A kind of laser etching method for plastic workpiece and plastic workpiece Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/362—Laser etching
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/60—Preliminary treatment
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Abstract
Description
技术领域technical field
本发明属于塑料电子制造技术领域,尤其涉及一种针对于塑料工件的激光刻蚀方法及塑料工件。The invention belongs to the technical field of plastic electronic manufacturing, and in particular relates to a laser etching method for a plastic workpiece and a plastic workpiece.
背景技术Background technique
激光刻蚀的基本原理是将高光束质量的小功率激光束(一般为紫外激光、光纤激光)聚焦成极小光斑,在焦点处形成很高的功率密度,使材料在瞬间汽化蒸发,形成孔、缝、槽,其具有无接触加工、柔性化程度高、加工速度快、无噪声、热影响区小、可聚焦到激光波长级的极小光斑等优越的加工性能,广泛应用在各领域的制造业。The basic principle of laser etching is to focus a low-power laser beam with high beam quality (usually ultraviolet laser, fiber laser) into a very small spot, and form a high power density at the focus, so that the material vaporizes and evaporates in an instant, forming a hole. , slot, slot, it has excellent processing performance such as non-contact processing, high degree of flexibility, fast processing speed, no noise, small heat-affected zone, extremely small spot that can be focused to the laser wavelength level, etc. It is widely used in various fields. manufacturing.
尽管激光刻蚀的潜力很高,但在一些特定的方面也会存在一些不足,如针对PC、ABS等塑料工件上进行激光刻蚀,由于其塑料材质的耐温性差且存在较大热阻,导致工件在经过激光刻蚀后,其表面容易出现“火山口”形态的烧蚀缺陷,影响工件的加工质量。Although the potential of laser etching is high, there are some deficiencies in some specific aspects, such as laser etching on plastic workpieces such as PC and ABS, due to the poor temperature resistance of the plastic material and the large thermal resistance, As a result, after laser etching, the surface of the workpiece is prone to ablation defects in the form of "crater", which affects the processing quality of the workpiece.
发明内容SUMMARY OF THE INVENTION
有鉴于此,本发明的一个目的是提出一种针对于塑料工件的激光刻蚀方法,以解决现在技术中激光刻蚀难以应用在塑料材质上的问题。In view of this, an object of the present invention is to propose a laser etching method for plastic workpieces, so as to solve the problem that laser etching is difficult to apply to plastic materials in the current technology.
在一些说明性实施例中,所述针对于塑料工件的激光刻蚀方法,包括:步骤1、提供待处理的塑料工件;步骤2、确定所述塑料工件上待刻蚀区域,并至少在所述塑料工件上的待刻蚀区域的周围形成与所述塑料工件之间贴合的导热层;步骤3、基于所述导热层对所述塑料工件上的待刻蚀区域进行激光刻蚀处理。In some illustrative embodiments, the laser etching method for a plastic workpiece includes:
在一些可选地实施例中,步骤2中的所述导热层覆盖所述待刻蚀区域,以及步骤3中连带所述导热层对其下的待刻蚀区域进行激光刻蚀处理。In some optional embodiments, the thermally conductive layer in
在一些可选地实施例中,在所述基于所述导热层对所述塑料工件上的待刻蚀区域进行激光刻蚀处理之后,还包括:移除所述导热层。In some optional embodiments, after the laser etching process is performed on the area to be etched on the plastic workpiece based on the thermally conductive layer, the method further includes: removing the thermally conductive layer.
在一些可选地实施例中,所述导热层的导热系数大于1W/mK。In some optional embodiments, the thermal conductivity of the thermally conductive layer is greater than 1 W/mK.
在一些可选地实施例中,所述导热层由混合有金属颗粒的导电油墨通过印制形成。In some optional embodiments, the thermally conductive layer is formed by printing a conductive ink mixed with metal particles.
在一些可选地实施例中,步骤2中利用所述导电油墨形成所述导热层的过程中,一并利用所述导电油墨形成附着在所述塑料工件上的导电迹线。In some optional embodiments, in the process of using the conductive ink to form the thermally conductive layer in
在一些可选地实施例中,所述导热层为所述导电迹线的至少一部分。In some optional embodiments, the thermally conductive layer is at least a portion of the conductive trace.
在一些可选地实施例中,所述导热层通过打印、印刷或浸渍方式形成。In some optional embodiments, the thermally conductive layer is formed by printing, printing or dipping.
在一些可选地实施例中,所述塑料工件为PC、ABS、PMMA、PE、PVC、PS、PP、POM、PA、电木中的一种或多种。In some optional embodiments, the plastic workpiece is one or more of PC, ABS, PMMA, PE, PVC, PS, PP, POM, PA, bakelite.
本发明的另一个目的在于提出一种塑料工件,以解决现在技术中的问题。Another object of the present invention is to propose a plastic workpiece to solve the problems in the present technology.
在一些说明性实施例中,所述塑料工件选用上述任一项所述的针对于塑料工件的激光刻蚀方法形成。In some illustrative embodiments, the plastic workpiece is formed using any one of the laser etching methods for plastic workpieces described above.
与现有技术相比,本发明具有如下优势:Compared with the prior art, the present invention has the following advantages:
本申请在进行激光刻蚀之前,预先在塑料工件的待刻蚀区域的周围利用导热材料形成导热层,基于该导热层对待刻蚀区域进行激光刻蚀处理时,待刻蚀区域周围吸收的大量热量可以通过导热层向周围扩散,从而快速降低待刻蚀区域外缘的热量,避免其外缘表面出现类“火山口”式的隆起变形缺陷。同时,由于导热层紧密铺设在塑料工件的表面,由于导热层结构的热稳定性也进一步限制塑料工件的表面变形,有利于提升塑料工件进行激光刻蚀的产品质量。Before laser etching is performed in the present application, a thermally conductive layer is formed around the area to be etched of the plastic workpiece in advance by using a thermally conductive material. Based on the thermal conductivity layer, when the area to be etched is laser etched, a large amount of absorbed energy around the area to be etched is absorbed. The heat can be diffused to the surroundings through the heat conduction layer, so as to quickly reduce the heat of the outer edge of the area to be etched, and avoid the “crater-like” bulge deformation defect on the outer edge surface. At the same time, since the thermally conductive layer is closely laid on the surface of the plastic workpiece, the thermal stability of the thermally conductive layer structure further limits the surface deformation of the plastic workpiece, which is beneficial to improve the product quality of the plastic workpiece for laser etching.
附图说明Description of drawings
图1是本发明实施例中针对于塑料工件的激光刻蚀方法的流程图;1 is a flowchart of a laser etching method for a plastic workpiece in an embodiment of the present invention;
图2是本发明实施例中的针对于塑料工件的激光刻蚀方法的工艺示意图;2 is a process schematic diagram of a laser etching method for a plastic workpiece in an embodiment of the present invention;
图3是现有技术中直接在塑料工件上进行激光打孔的效果示意图。FIG. 3 is a schematic diagram of the effect of directly performing laser drilling on a plastic workpiece in the prior art.
具体实施方式Detailed ways
现将详细地参照本申请的各种实施例,在附图中示出了所述实施例的示例。当结合这些实施例进行描述时,应当理解的是,所述实施例并不旨将本申请限制于这些实施例。相反,本申请旨在覆盖可以包括在所附权利要求书所定义的本申请的精神和范围内的替代形式、修改形式和等效物。此外,在本申请的以下具体实施方式中,阐述了许多具体细节以便提供对本申请的透彻理解。然而,应当理解的是,在没有这些特定细节的情况下也可以实践本申请。Reference will now be made in detail to various embodiments of the present application, examples of which are illustrated in the accompanying drawings. When described in conjunction with these embodiments, it should be understood that the embodiments are not intended to limit the application to these embodiments. On the contrary, this application is intended to cover alternatives, modifications and equivalents, which may be included within the spirit and scope of this application as defined by the appended claims. Furthermore, in the following detailed description of the present application, numerous specific details are set forth in order to provide a thorough understanding of the present application. It should be understood, however, that the application may be practiced without these specific details.
需要说明的是,在不冲突的情况下本发明实施例中的各技术特征均可以相互结合。It should be noted that each technical feature in the embodiments of the present invention can be combined with each other without conflict.
本发明实施例中公开了一种针对于塑料工件的激光刻蚀方法,具体地,如图1-3,图1是本发明实施例中针对于塑料工件的激光刻蚀方法的流程图;图2是本发明实施例中的针对于塑料工件的激光刻蚀方法的工艺示意图;图3是现有技术中直接在塑料工件上进行激光打孔的效果示意图。An embodiment of the present invention discloses a laser etching method for a plastic workpiece, specifically, as shown in Figures 1-3, Figure 1 is a flowchart of a laser etching method for a plastic workpiece in an embodiment of the present invention; 2 is a process schematic diagram of a laser etching method for a plastic workpiece in an embodiment of the present invention; FIG. 3 is a schematic diagram of the effect of directly performing laser drilling on a plastic workpiece in the prior art.
该针对于塑料工件的激光刻蚀方法,包括:The laser etching method for plastic workpieces includes:
步骤S1、提供待处理的塑料工件1;Step S1, providing the
步骤S2、确定所述塑料工件1上待刻蚀区域,并至少在所述塑料工件1上的待刻蚀区域的周围形成与所述塑料工件1之间贴合的导热层4;Step S2, determining the area to be etched on the
步骤S3、基于所述导热层4对所述塑料工件1上的待刻蚀区域进行激光刻蚀处理(例如通孔2)。Step S3 , performing laser etching on the area to be etched on the plastic workpiece 1 (eg, the through hole 2 ) based on the thermally
其中,本发明实施例中的激光刻蚀是指利用高能激光束对工件进行烧蚀减材处理,从而得到目标的槽、孔;槽、孔的结构图案可根据实际需求进行设计,对此不进行限制。Among them, the laser etching in the embodiment of the present invention refers to the use of a high-energy laser beam to ablate the workpiece to reduce the material, so as to obtain the target grooves and holes; the structure patterns of the grooves and holes can be designed according to actual needs limit.
图3中示出了直接在塑料工件进行激光刻蚀通孔2时,其周围产生的类“火山口”式缺陷3。Fig. 3 shows a "crater"-
本申请在进行激光刻蚀之前,预先在塑料工件的待刻蚀区域的周围利用导热材料形成导热层,基于该导热层对待刻蚀区域进行激光刻蚀处理时,待刻蚀区域周围吸收的大量热量可以通过导热层向周围扩散,从而快速降低待刻蚀区域外缘的热量,避免其外缘表面出现类“火山口”式的隆起变形缺陷。同时,由于导热层紧密铺设在塑料工件的表面,由于导热层结构的热稳定性也进一步限制塑料工件的表面变形,有利于提升塑料工件进行激光刻蚀的产品质量。Before laser etching is performed in the present application, a thermally conductive layer is formed around the area to be etched of the plastic workpiece in advance by using a thermally conductive material. Based on the thermal conductivity layer, when the area to be etched is laser etched, a large amount of absorbed energy around the area to be etched is absorbed. The heat can be diffused to the surroundings through the heat conduction layer, so as to quickly reduce the heat of the outer edge of the area to be etched, and avoid the “crater-like” bulge deformation defect on the outer edge surface. At the same time, since the thermally conductive layer is closely laid on the surface of the plastic workpiece, the thermal stability of the thermally conductive layer structure further limits the surface deformation of the plastic workpiece, which is beneficial to improve the product quality of the plastic workpiece for laser etching.
本发明实施例中的塑料工件可选用PC、ABS、PMMA、PE、PVC、PS、PP、POM、PA、电木等中的一种或多种。The plastic workpiece in the embodiment of the present invention can be selected from one or more of PC, ABS, PMMA, PE, PVC, PS, PP, POM, PA, bakelite and the like.
本发明实施例中的导热层可选用导热系数大于塑料工件导热系数的导热材料,包括但不限于硅、硅化物、硅脂、陶瓷、聚合物、金属、金属氧化物、碳、石墨烯、以及包含有上述导热颗粒的高分子混合物(如导热膏、导电油墨、电子浆料等)中的一种或多种。The thermally conductive layer in the embodiment of the present invention can be selected from thermally conductive materials whose thermal conductivity is greater than that of the plastic workpiece, including but not limited to silicon, silicide, silicone grease, ceramics, polymers, metals, metal oxides, carbon, graphene, and One or more of the polymer mixtures (such as thermally conductive pastes, conductive inks, electronic pastes, etc.) containing the above-mentioned thermally conductive particles.
其中,导热层的形成方式不限于贴合、印刷、打印、浸渍等方式形成;优选地,本发明实施例中的导热层可选用如高分子混合物或硅脂类的浆料,通过打印、印刷、浸渍等方式形成,该类工艺相比于传统贴合而言,操作简单、成本低、易于实施,并且形成后的导热层与塑料工件表面之间结合紧密,不易产生孔隙,进一步提升其导热性能。Wherein, the formation method of the thermally conductive layer is not limited to lamination, printing, printing, dipping, etc.; Compared with traditional lamination, this type of process is simple in operation, low in cost, and easy to implement, and the formed thermal conductive layer and the surface of the plastic workpiece are closely combined, and pores are not easily generated, which further improves its thermal conductivity. performance.
本发明实施例中的激光刻蚀处理中选用的激光不限于红外激光束或紫外激光束;优选地,本发明实施例中的激光刻蚀处理可搭配相应的定位系统(不限于CCD定位系统),保证激光刻蚀的准确度;同时,塑料工件上可以形成与定位系统相互配合的定位标识(不限于定位孔);其中,该定位标识可以位于塑料工件上未被导热层所覆盖的区域,又或者形成在导热层上。The laser selected in the laser etching process in the embodiment of the present invention is not limited to an infrared laser beam or an ultraviolet laser beam; preferably, the laser etching process in the embodiment of the present invention can be matched with a corresponding positioning system (not limited to a CCD positioning system) , to ensure the accuracy of laser etching; at the same time, a positioning mark (not limited to positioning holes) that cooperates with the positioning system can be formed on the plastic workpiece; wherein, the positioning mark can be located on the plastic workpiece. The area not covered by the thermal conductive layer, Alternatively, it is formed on the thermally conductive layer.
进一步的,本发明实施例中的导热层可选用导热系数大于1W/mK的导热材料形成,该类导热材料的导热系数远大于塑料工件,对于激光刻蚀中的余热的扩散有显著的效果。其中,导热系数大于1W/mK的导热材料不限于硅、硅化物、硅脂、陶瓷、金属、金属氧化物、以及含有以上材料的高分子混合物等中的一种或多种。Further, the thermally conductive layer in the embodiment of the present invention can be formed of a thermally conductive material with a thermal conductivity greater than 1W/mK. The thermal conductivity of this type of thermally conductive material is much larger than that of a plastic workpiece, and has a significant effect on the diffusion of waste heat in laser etching. The thermally conductive materials with thermal conductivity greater than 1W/mK are not limited to one or more of silicon, silicide, silicone grease, ceramics, metals, metal oxides, and polymer mixtures containing the above materials.
在一些情况下,本发明实施例中的导热层并非作为塑料工件上的目标结构,仅作为用于激光刻蚀过程中的临时辅助功能结构,因此在步骤S3完成对塑料工件上的激光刻蚀后,可移除导热层,从而得到目标的塑料工件。其中,移除方式不限于擦除、机械剥离、切割、药剂等方式中的一种或多种。然后在导热层为塑料工件上的目标结构时,则可无需对其进行移除处理。In some cases, the thermal conductive layer in the embodiment of the present invention is not used as a target structure on the plastic workpiece, but only as a temporary auxiliary functional structure used in the laser etching process. Therefore, the laser etching on the plastic workpiece is completed in step S3 Afterwards, the thermally conductive layer can be removed, resulting in the targeted plastic workpiece. The removal method is not limited to one or more of erasing, mechanical peeling, cutting, and medicine. Then when the thermally conductive layer is the target structure on the plastic workpiece, it may not need to be removed.
在一些实施例中,本发明实施例中步骤2中的至少在所述塑料工件上的待刻蚀区域的周围形成与所述塑料工件之间贴合的导热层,具体包括:导热层的图案与待刻蚀区域之间为互补结构,即导热层与待刻蚀区域在垂直投影上相互接连且相互不重叠。In some embodiments, in
又或者是,导热层的图案与待刻蚀区域之间可为非接连互补,即导热层与待刻蚀区域之间可以存在一定的距离,该距离可根据导热层的导热系数决定。Alternatively, the pattern of the thermally conductive layer and the region to be etched may be non-continuous and complementary, that is, there may be a certain distance between the thermally conductive layer and the region to be etched, and the distance may be determined according to the thermal conductivity of the thermally conductive layer.
除此之外,还可包括:导热层覆盖了待刻蚀区域的情况,即导热层与待刻蚀区域在垂直投影上相互重叠且导热层的尺寸大于待刻蚀区域,以形成一定范围的导热区。在该情况下,步骤3中的连带导热层对其下的待刻蚀区域一并进行激光刻蚀处理。In addition, it can also include: the thermal conductive layer covers the area to be etched, that is, the thermal conductive layer and the area to be etched overlap each other in the vertical projection and the size of the thermal conductive layer is larger than the area to be etched, so as to form a certain range of Thermal zone. In this case, the associated thermal conductive layer in
优选地,本发明实施例中的导热层覆盖待刻蚀区域,该结构可以尽可能忽略导热层的图案要求,成型更易、操作更简单。Preferably, the thermally conductive layer in the embodiment of the present invention covers the area to be etched, and the structure can ignore the pattern requirements of the thermally conductive layer as much as possible, making it easier to form and operate.
优选地,导热层的铺设范围与待刻蚀区域接连,且导热层远离待刻蚀区域的边缘与待刻蚀区域的最小距离为0.5mm,即待刻蚀区域周围至少0.5mm范围内铺设有导热层。其中,该距离不限于0.5mm、0.8mm、1mm、1.5mm、3mm、5mm等。优选地,导热层的铺设范围至少覆盖待刻蚀区域周围0.5mm的区域,即可达到对激光刻蚀余热良好的散热效果,另一方面,亦可有效的降低导热层的用量,满足高精度塑料工件上的加工处理。Preferably, the laying range of the thermally conductive layer is continuous with the area to be etched, and the minimum distance between the edge of the thermally conductive layer far away from the area to be etched and the area to be etched is 0.5mm, that is, there are at least 0.5mm around the area to be etched. Thermal layer. Wherein, the distance is not limited to 0.5mm, 0.8mm, 1mm, 1.5mm, 3mm, 5mm and the like. Preferably, the laying range of the thermal conductive layer at least covers an area of 0.5 mm around the area to be etched, so as to achieve a good heat dissipation effect on the residual heat of laser etching. Machining on plastic workpieces.
优选地,本发明实施例中的导热层可利用由混合有导热金属颗粒的导电油墨通过印制形成,其可通过喷涂、丝印、移印、涂布、浸渍中的一种或多种方式形成,相比于表面镀(蒸镀、电镀或化镀)而言,具有工艺简单、层厚密度等参数易控、生产高效和低成本的优势。另一方面,该导电油墨主要有导热金属颗粒和树脂载体构成,其在成型后可通过适当的方式(例如与树脂载体相应的溶剂)进行移除,移除简单,不易产生残留,尤其适用于作为塑料工件上针对激光刻蚀形成的临时导热层。Preferably, the thermally conductive layer in the embodiment of the present invention may be formed by printing using conductive ink mixed with thermally conductive metal particles, which may be formed by one or more of spraying, silk-screen printing, pad printing, coating, and dipping. Compared with surface plating (evaporation, electroplating or electroless plating), it has the advantages of simple process, easy control of parameters such as layer thickness and density, high production efficiency and low cost. On the other hand, the conductive ink is mainly composed of thermally conductive metal particles and a resin carrier, which can be removed by appropriate means (such as a solvent corresponding to the resin carrier) after molding. As a temporary thermally conductive layer for laser etching on plastic workpieces.
在一些情况下,本发明实施例中的塑料工件可用于制作塑料电子产品,在塑料工件上加工电子线路时,可利用导电油墨在塑料工件上形成导电迹线;由于导电迹线和本发明实施例中的导热层均可采用导电油墨通过相同的工艺形成,因此本发明实施例中的导热层可在形成导电迹线的过程中一并形成,或者说导电迹线可在形成导热层的过程中一并形成。该实施例中导电迹线和导热层可采用导电油墨通过相同的工艺同时形成,因此针对于塑料电子产品而言可节省制作工序,进一步提高生产效率。In some cases, the plastic workpieces in the embodiments of the present invention can be used to make plastic electronic products. When processing electronic circuits on the plastic workpieces, conductive inks can be used to form conductive traces on the plastic workpieces; since the conductive traces and the implementation of the present invention The thermally conductive layers in the examples can be formed by the same process using conductive ink, so the thermally conductive layers in the embodiments of the present invention can be formed together in the process of forming the conductive traces, or the conductive traces can be formed in the process of forming the thermally conductive layer. formed together. In this embodiment, the conductive traces and the heat-conducting layer can be simultaneously formed by the same process using conductive ink, so for plastic electronic products, the manufacturing process can be saved, and the production efficiency can be further improved.
在一些实施例中,所述经过所述激光刻蚀处理后的导热层为所述导电迹线的至少一部分。即,激光刻蚀处理后导热层可为导电迹线的一部分,该实施例中无需考虑导热层的后续移除。In some embodiments, the laser-etched thermally conductive layer is at least a portion of the conductive traces. That is, the thermally conductive layer may be part of the conductive traces after the laser etching process, and subsequent removal of the thermally conductive layer need not be considered in this embodiment.
在一些可选地实施例中,所述导电油墨选用导电银浆。In some optional embodiments, the conductive ink is selected from conductive silver paste.
本发明的另一个目的在于提出一种塑料工件,该塑料工件可通过上述任一项所述的针对于塑料工件的激光刻蚀方法形成。Another object of the present invention is to provide a plastic workpiece, which can be formed by any one of the above-mentioned laser etching methods for plastic workpieces.
本领域技术人员还应当理解,结合本文的实施例描述的各种说明性的逻辑框、模块、电路和算法步骤均可以实现成电子硬件、计算机软件或其组合。为了清楚地说明硬件和软件之间的可交换性,上面对各种说明性的部件、框、模块、电路和步骤均围绕其功能进行了一般地描述。至于这种功能是实现成硬件还是实现成软件,取决于特定的应用和对整个系统所施加的设计约束条件。熟练的技术人员可以针对每个特定应用,以变通的方式实现所描述的功能,但是,这种实现决策不应解释为背离本申请的保护范围。Those skilled in the art will also appreciate that the various illustrative logical blocks, modules, circuits, and algorithm steps described in connection with the embodiments herein may be implemented as electronic hardware, computer software, or combinations thereof. To clearly illustrate this interchangeability of hardware and software, various illustrative components, blocks, modules, circuits, and steps have been described above generally in terms of their functionality. Whether this functionality is implemented as hardware or software depends on the specific application and design constraints imposed on the overall system. Skilled artisans may implement the described functionality in varying ways for each particular application, however, such implementation decisions should not be interpreted as a departure from the scope of the present application.
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