CN114921973A - Infrared stealth high-performance military tent and preparation method thereof - Google Patents
Infrared stealth high-performance military tent and preparation method thereof Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
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- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- E04—BUILDING
- E04H—BUILDINGS OR LIKE STRUCTURES FOR PARTICULAR PURPOSES; SWIMMING OR SPLASH BATHS OR POOLS; MASTS; FENCING; TENTS OR CANOPIES, IN GENERAL
- E04H15/00—Tents or canopies, in general
- E04H15/32—Parts, components, construction details, accessories, interior equipment, specially adapted for tents, e.g. guy-line equipment, skirts, thresholds
- E04H15/58—Closures; Awnings; Sunshades
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Abstract
Description
技术领域technical field
本发明涉及军用帐篷技术领域,更具体地说它涉及一种红外隐身高性能军用帐篷及其制备方法。The invention relates to the technical field of military tents, in particular to an infrared stealth high-performance military tent and a preparation method thereof.
背景技术Background technique
近年来,随着国际形式纷繁复杂,贸易战持续不停,受到发达国家技术封锁的影响越发严重,特别是在军用领域直接威胁到国家安定发展。其中,影响国家军民现代电子技术和各种先进探测系统以及精确制导武器的问世,极大拓展了战争中搜索、跟踪目标的能力,军事目标、武器装备以及作战士兵在战场中所受到的威胁日益严重。而隐身技术作为提高武器装备在战争中生存能力的重要手段,越来越受到世界各国的重视。采用隐身技术,如通过改变目标外部结构,或进行表面涂装,或伪装处理,降低目标的可探测信号特征,使敌方的探测、制导、侦察系统失去功效,从而尽可能地隐蔽自己,掌握战场的主动权;同是兼具在高温高寒等极端条件下使用的高性能要求。因此,具隐身技术和高性能的军用帐篷作为提高武器系统生存、突防及纵深打击能力的有效手段,已成为世界强国角逐军事高新技术的热点之一。In recent years, with the complicated international forms and the continuous trade war, the impact of the technological blockade by developed countries has become more and more serious, especially in the military field, which directly threatens the stability and development of the country. Among them, the advent of modern electronic technology and various advanced detection systems and precision-guided weapons affecting the country's military and civilians has greatly expanded the ability to search and track targets in war, and military targets, weapons and equipment and combat soldiers are increasingly threatened in the battlefield. serious. As an important means to improve the survivability of weapons and equipment in war, stealth technology has been paid more and more attention by countries all over the world. Adopt stealth technology, such as changing the external structure of the target, or carrying out surface coating, or camouflage processing, to reduce the detectable signal characteristics of the target, and make the enemy's detection, guidance, and reconnaissance systems ineffective, so as to conceal themselves as much as possible, master the The initiative in the battlefield; it also has high performance requirements for use in extreme conditions such as high temperature and cold. Therefore, military tents with stealth technology and high performance, as an effective means to improve the survival, penetration and deep strike capabilities of weapon systems, have become one of the hot spots for world powers to compete for military high-tech.
在帐篷品表面涂覆隐身帐篷涂料是实现隐身的关键材料,其性能的好坏直接影响隐身效果。目前,市面上的隐身帐篷涂料种类较多,传统红外隐身帐篷涂料中功能活性成分多为金属粉体及聚氨酯,为实现极端气候的耐磨耐侯性和隐身效果,添加量较大,以此为涂层的红外隐身面料涂层厚重,并且长期使用性能稳定性不佳,耐候性、耐久性和耐水洗牢度有待进一步提高。Coating the stealth tent paint on the surface of the tent is the key material to achieve stealth, and its performance directly affects the stealth effect. At present, there are many types of stealth tent coatings on the market. The functional active ingredients in traditional infrared stealth tent coatings are mostly metal powder and polyurethane. The coated infrared stealth fabric has a thick coating, and the long-term performance stability is not good, and the weather resistance, durability and washing fastness need to be further improved.
因此,开发一种综合性能佳,保持长期有效隐身效果,物理性能稳定性、耐久性、耐候性、耐水洗牢度好的隐身帐篷涂料符合市场需求,具有广泛的市场价值和应用前景,对促进隐身技术的发展具有非常重要的意义。Therefore, the development of a stealth tent coating with good comprehensive performance, long-term effective stealth effect, good physical performance stability, durability, weather resistance, and washing fastness meets market demand and has a wide range of market value and application prospects. The development of stealth technology is of great significance.
发明内容SUMMARY OF THE INVENTION
针对现有技术存在的不足,本发明的第一个目的在于提供一种红外隐身高性能军用帐篷,该红外隐身高性能军用帐篷具有显著延长使用寿命以保持长期隐身效果的作用。In view of the deficiencies in the prior art, the first object of the present invention is to provide an infrared stealth high-performance military tent, which has the effect of significantly extending the service life to maintain long-term stealth effect.
为实现上述目的,本发明提供了如下技术方案:For achieving the above object, the present invention provides the following technical solutions:
一种红外隐身高性能军用帐篷,包括由基布层以及涂覆在所述基布层外侧壁的红外雷达隐身层组成的帐篷本体;所述红外雷达隐身层包括如下重量份的组分:An infrared stealth high-performance military tent, comprising a tent body composed of a base cloth layer and an infrared radar stealth layer coated on the outer side wall of the base cloth layer; the infrared radar stealth layer includes the following components by weight:
有机硅酮30-50份;30-50 parts of organic silicone;
超支化聚苯胺1-3份;1-3 copies of hyperbranched polyaniline;
表面环氧基修饰多孔聚吡咯管3-5份;3-5 parts of surface epoxy modified porous polypyrrole tube;
N、P共掺杂碳包覆多孔Fe-Al-La-O 5-10份;N, P co-doped carbon coating porous Fe-Al-La-O 5-10 parts;
端氨基聚氨酯30-40份;30-40 copies of amino-terminated polyurethane;
溶剂10-20份;10-20 parts of solvent;
分散剂1-3份;1-3 parts of dispersant;
增稠剂1-2份。Thickener 1-2 parts.
本发明进一步设置为:所述有机硅酮由液化有机硅橡胶复合而成。The present invention further provides that: the organosilicon is compounded by liquefied organosilicon rubber.
本发明进一步设置为:所述增稠剂为羧甲基纤维素、淀粉、瓜尔胶、聚乙烯醇、聚乙烯吡咯烷酮中的至少一种。The present invention is further provided that: the thickener is at least one of carboxymethyl cellulose, starch, guar gum, polyvinyl alcohol, and polyvinylpyrrolidone.
本发明进一步设置为:所述分散剂为六偏磷酸钠和/或聚羧酸钠盐。The present invention further provides that: the dispersing agent is sodium hexametaphosphate and/or sodium polycarboxylate.
本发明进一步设置为:所述溶剂为二甲苯、醋酸丁酯、丙二醇甲醚醋酸酯中的至少一种。The present invention is further provided that: the solvent is at least one of xylene, butyl acetate and propylene glycol methyl ether acetate.
本发明进一步设置为:所述N、P共掺杂碳包覆多孔Fe-Al-La-O的制备方法包括如下步骤:The present invention is further provided as follows: the preparation method of the N, P co-doped carbon-coated porous Fe-Al-La-O comprises the following steps:
步骤1、将铁源、铝源、镧源倒入到乙醇中搅拌0.4-1小时,再在缓慢加入醋酸钠后剧烈搅拌3-4h,获得混合搅拌溶液;Step 1. Pour iron source, aluminum source and lanthanum source into ethanol and stir for 0.4-1 hour, then slowly add sodium acetate and stir vigorously for 3-4 hours to obtain a mixed stirring solution;
步骤2、将混合搅拌溶液转移至聚氟乙烯内衬的水热反应釜中,在控制温度为190-220℃下反应12-18h后依次经冷却、洗涤和真空干燥处理,获得初料;Step 2. Transfer the mixed and stirred solution to a hydrothermal reactor lined with polyvinyl fluoride, and react at a controlled temperature of 190-220° C. for 12-18 hours, followed by cooling, washing and vacuum drying to obtain the initial material;
步骤3、将初料分散于水中,再加入磷酸铵,控制温度为60-80℃并持续搅拌8-15小时,获得反应料;Step 3, disperse the initial material in water, then add ammonium phosphate, control the temperature to be 60-80 ° C and continue stirring for 8-15 hours to obtain a reaction material;
步骤4、将反应料在550-650℃的惰性气体氛围下灼烧3-5小时,获得的物料经碾磨并过1100-1300目筛,得到N、P共掺杂碳包覆多孔Fe-Al-La-O。Step 4, calcining the reaction material under an inert gas atmosphere of 550-650°C for 3-5 hours, the obtained material is ground and passed through a 1100-1300 mesh sieve to obtain N, P co-doped carbon-coated porous Fe- Al-La-O.
本发明进一步设置为:在步骤1中,所述铁源、铝源、镧源、乙醇、醋酸钠的质量比为1:1:0.1-0.2:25-35:5。The present invention is further provided as follows: in step 1, the mass ratio of the iron source, the aluminum source, the lanthanum source, the ethanol and the sodium acetate is 1:1:0.1-0.2:25-35:5.
本发明进一步设置为:所述铁源为氯化铁、硝酸铁、硫酸铁中的至少一种;所述铝源为氯化铝、硝酸铝中的至少一种;所述镧源为氯化镧、硝酸镧中的至少一种。The present invention is further provided as follows: the iron source is at least one of ferric chloride, ferric nitrate and ferric sulfate; the aluminum source is at least one of aluminum chloride and aluminum nitrate; the lanthanum source is chloride At least one of lanthanum and lanthanum nitrate.
本发明进一步设置为:在步骤3中,所述初料、水和磷酸铵的质量比为1:4-8:0.05-0.15。The present invention is further provided as follows: in step 3, the mass ratio of the initial material, water and ammonium phosphate is 1:4-8:0.05-0.15.
本发明的第二个目的在于提供一种红外隐身高性能军用帐篷的制备方法,包括制备红外雷达隐身层和将所述红外雷达隐身层涂覆在基布层上;所述红外雷达隐身层的制备方法包括按重量份混合各组分,并在控制搅拌转速为2500-5500r/min,搅拌为4-13小时时获得。The second object of the present invention is to provide a preparation method of an infrared stealth high-performance military tent, which includes preparing an infrared radar stealth layer and coating the infrared radar stealth layer on the base cloth layer; The preparation method comprises the steps of mixing the components by weight, and controlling the stirring speed to be 2500-5500 r/min and the stirring for 4-13 hours.
综上所述,本发明具有以下有益效果:To sum up, the present invention has the following beneficial effects:
1、通过简化红外隐身高性能军用帐篷的制备方法,从而在显著提升制备效率的同时,具有提高成品合格率、综合性能的效果,并实现降低设备依赖性的目的,适于连续规模化生产,从而具有较高的经济价值、社会价值和生态价值;1. By simplifying the preparation method of infrared stealth high-performance military tents, while significantly improving the preparation efficiency, it has the effect of improving the qualified rate of finished products and comprehensive performance, and achieves the purpose of reducing equipment dependence. It is suitable for continuous large-scale production. Therefore, it has higher economic value, social value and ecological value;
2、通过该制备方法获得的红外隐身高性能军用帐篷具有在8-14μm波段红外的发射率可达到0.7,且在匹配厚度7mm时,最小反射率可达-31.5dB,有效吸收带宽为4.1GHz;2. The infrared stealth high-performance military tent obtained by the preparation method has an infrared emissivity of 0.7 in the 8-14μm band, and when the matching thickness is 7mm, the minimum reflectivity can reach -31.5dB, and the effective absorption bandwidth is 4.1GHz ;
3、通过该制备方法获得的红外隐身高性能军用帐篷上的红外雷达隐身层有效克服市面上的隐身帐篷涂料涂层厚重和无透气性导致的穿戴闷热难受的问题,并有效提升与基布层的粘结性,并在解决现有产品的耐候性、耐久性和耐水洗牢度差的缺陷,以通过各组分协同作用,使得该红外隐身高性能军用帐篷具有长期使用保持性能稳定性的效果,显著提升该红外隐身高性能军用帐篷的综合性能、隐身效果、性能稳定性、耐久性、耐候性和耐水洗牢度;3. The infrared radar stealth layer on the infrared stealth high-performance military tent obtained by the preparation method effectively overcomes the problem of sultry and uncomfortable wearing caused by the thick coating and lack of air permeability of the stealth tent on the market, and effectively improves the compatibility with the base fabric layer. It also solves the defects of poor weather resistance, durability and washing fastness of the existing products, so that through the synergy of each component, the infrared stealth high-performance military tent has the ability to maintain performance stability for long-term use. It can significantly improve the comprehensive performance, stealth effect, performance stability, durability, weather resistance and washing fastness of the infrared stealth high-performance military tent;
4、通过添加有机硅酮、超支化聚苯胺、表面环氧基修饰多孔聚吡咯管、N、P共掺杂碳包覆多孔Fe-Al-La-O的协同作用,使得该红外隐身高性能军用帐篷的红外雷达隐身层在具有优异的红外吸收功能的同时,起到红外和雷达双波段隐身,并在创新配置各组分比例时获得最佳阻抗匹配,而且孔径分布可调,并使得多孔Fe-Al-La-O和多孔聚吡咯管极高的比表面积和丰富的孔道结构造成多重散射,实现质轻、导电性强和有效改善隐身效果的目的;4. Through the synergistic effect of adding organosilicon, hyperbranched polyaniline, surface epoxy modified porous polypyrrole tube, and N, P co-doped carbon-coated porous Fe-Al-La-O, the infrared stealth has high performance. The infrared radar stealth layer of the military tent has excellent infrared absorption function, at the same time, it can achieve infrared and radar dual-band stealth, and obtain the best impedance matching when the proportion of each component is innovatively configured, and the pore size distribution is adjustable, and the porous The extremely high specific surface area and rich pore structure of Fe-Al-La-O and porous polypyrrole tubes cause multiple scattering, achieving the purpose of light weight, strong conductivity and effectively improving stealth effect;
5、通过有机硅酮、端氨基聚氨酯的添加,与表面环氧基修饰多孔聚吡咯管上的环氧基发生开环反应,使得各功能成分之间以化学键连接,形成三维网络结构,有效改善综合性能在极端环境条件下的耐高低温、耐磨性,使得该红外隐身高性能军用帐篷在长期使用时保持性能稳定,以有效延长使用寿命。5. Through the addition of organic silicone and amino-terminated polyurethane, a ring-opening reaction occurs with the epoxy group on the surface epoxy group-modified porous polypyrrole tube, so that the functional components are connected by chemical bonds to form a three-dimensional network structure, which effectively improves the The comprehensive performance of high and low temperature resistance and wear resistance under extreme environmental conditions makes the infrared stealth high-performance military tent maintain stable performance during long-term use to effectively prolong the service life.
附图说明Description of drawings
图1是本实施例的结构示意图。FIG. 1 is a schematic structural diagram of this embodiment.
附图标记说明:1、帐篷本体;11、基布层;12、红外雷达隐身层。Description of reference numerals: 1. Tent body; 11. Base fabric layer; 12. Infrared radar stealth layer.
具体实施方式Detailed ways
为使本发明的技术方案和优点更加清楚,以下将结合附图对本发明作进一步详细说明,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the technical solutions and advantages of the present invention clearer, the present invention will be further described in detail below with reference to the accompanying drawings. Obviously, the described embodiments are only a part of the embodiments of the present application, rather than all the embodiments. Based on the embodiments in the present application, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present application.
以下针对本发明实施例的红外隐身高性能军用帐篷及其制备方法进行具体说明:The following specifically describes the infrared stealth high-performance military tent and the preparation method thereof according to the embodiment of the present invention:
如图1所示,一种红外隐身高性能军用帐篷,包括由基布层11以及涂覆在基布层11外侧壁的红外雷达隐身层12组成的帐篷本体1。As shown in FIG. 1 , an infrared stealth high-performance military tent includes a tent body 1 composed of a
其中,红外雷达隐身层12包括如下重量份的组分:有机硅酮30-50份、超支化聚苯胺1-3份、表面环氧基修饰多孔聚吡咯管3-5份、N、P共掺杂碳包覆多孔Fe-Al-La-O 5-10份、端氨基聚氨酯30-40份、溶剂10-20份、分散剂1-3份、增稠剂1-2份。Wherein, the infrared
需要提及的是,增稠剂的平均分子量在10000-100000之间。所采用的基布为的纺织品或薄膜材料。薄膜材料的材质不限,在此不再赘述。纺织品为机织、针织、无纺布等形式制备的天然纤维、合成纤维和再生纤维。It should be mentioned that the average molecular weight of the thickener is between 10,000 and 100,000. The base fabric used is a textile or film material. The material of the thin film material is not limited and will not be repeated here. Textiles are natural fibers, synthetic fibers and regenerated fibers prepared in the form of woven, knitted, and non-woven fabrics.
与此同时,所采用的有机硅酮由液化有机硅橡胶复合而成。增稠剂为羧甲基纤维素、淀粉、瓜尔胶、聚乙烯醇、聚乙烯吡咯烷酮中的至少一种。分散剂为六偏磷酸钠和/或聚羧酸钠盐。溶剂为二甲苯、醋酸丁酯、丙二醇甲醚醋酸酯中的至少一种。At the same time, the silicone used is compounded by liquefied silicone rubber. The thickener is at least one of carboxymethyl cellulose, starch, guar gum, polyvinyl alcohol, and polyvinylpyrrolidone. The dispersing agent is sodium hexametaphosphate and/or sodium polycarboxylate. The solvent is at least one of xylene, butyl acetate and propylene glycol methyl ether acetate.
需要说明的是,N、P共掺杂碳包覆多孔Fe-Al-La-O的制备方法包括如下步骤:It should be noted that the preparation method of N, P co-doped carbon-coated porous Fe-Al-La-O includes the following steps:
步骤1、将铁源、铝源、镧源倒入到乙醇中搅拌0.4-1小时,再在缓慢加入醋酸钠后剧烈搅拌3-4h,获得混合搅拌溶液;且铁源为氯化铁、硝酸铁、硫酸铁中的至少一种;所述铝源为氯化铝、硝酸铝中的至少一种;所述镧源为氯化镧、硝酸镧中的至少一种。铁源、铝源、镧源、乙醇、醋酸钠的质量比为1:1:0.1-0.2:25-35:5。Step 1. Pour the iron source, aluminum source and lanthanum source into ethanol and stir for 0.4-1 hour, then slowly add sodium acetate and vigorously stir for 3-4 hours to obtain a mixed stirring solution; and the iron source is ferric chloride, nitric acid At least one of iron and ferric sulfate; the aluminum source is at least one of aluminum chloride and aluminum nitrate; the lanthanum source is at least one of lanthanum chloride and lanthanum nitrate. The mass ratio of iron source, aluminum source, lanthanum source, ethanol and sodium acetate is 1:1:0.1-0.2:25-35:5.
步骤2、将混合搅拌溶液转移至聚氟乙烯内衬的水热反应釜中,在控制温度为190-220℃下反应12-18h后依次经冷却、洗涤和真空干燥处理,获得初料。Step 2: Transfer the mixed and stirred solution to a hydrothermal reaction kettle lined with polyvinyl fluoride, and react at a temperature of 190-220° C. for 12-18 hours, followed by cooling, washing and vacuum drying to obtain the initial material.
步骤3、将初料分散于水中,再加入磷酸铵,控制温度为60-80℃并持续搅拌8-15小时,获得反应料;且初料、水和磷酸铵的质量比为1:4-8:0.05-0.15。Step 3, disperse the initial material in water, then add ammonium phosphate, control the temperature to be 60-80 ° C and continue stirring for 8-15 hours to obtain a reaction material; and the mass ratio of the initial material, water and ammonium phosphate is 1:4- 8:0.05-0.15.
步骤4、将反应料在550-650℃的惰性气体氛围下灼烧3-5小时,获得的物料经碾磨并过1100-1300目筛,得到N、P共掺杂碳包覆多孔Fe-Al-La-O。Step 4, calcining the reaction material under an inert gas atmosphere of 550-650°C for 3-5 hours, the obtained material is ground and passed through a 1100-1300 mesh sieve to obtain N, P co-doped carbon-coated porous Fe- Al-La-O.
一种红外隐身高性能军用帐篷的制备方法,包括制备红外雷达隐身层12和将所述红外雷达隐身层12涂覆在基布层11上。红外雷达隐身层12的制备方法包括按重量份混合各组分,并在控制搅拌转速为2500-5500r/min,搅拌为4-13小时时获得。A preparation method of an infrared stealth high-performance military tent includes preparing an infrared
实施例一Example 1
如图1所示,一种红外隐身高性能军用帐篷,包括由基布层11以及涂覆在基布层11外侧壁的红外雷达隐身层12组成的帐篷本体1。As shown in FIG. 1 , an infrared stealth high-performance military tent includes a tent body 1 composed of a
其中,红外雷达隐身层12包括如下重量份的组分:有机硅酮30份、超支化聚苯胺1份、表面环氧基修饰多孔聚吡咯管3份、N、P共掺杂碳包覆多孔Fe-Al-La-O 5份、端氨基聚氨酯30份、溶剂10份、分散剂1份、增稠剂1份。Among them, the infrared
需要提及的是,增稠剂的平均分子量在10000-100000之间。所采用的基布为的纺织品或薄膜材料。薄膜材料的材质不限,在此不再赘述。纺织品为机织、针织、无纺布等形式制备的天然纤维、合成纤维和再生纤维。It should be mentioned that the average molecular weight of the thickener is between 10,000 and 100,000. The base fabric used is a textile or film material. The material of the thin film material is not limited and will not be repeated here. Textiles are natural fibers, synthetic fibers and regenerated fibers prepared in the form of woven, knitted, and non-woven fabrics.
与此同时,所采用的有机硅酮由液化有机硅橡胶复合而成。增稠剂为羧甲基纤维素。分散剂为六偏磷酸钠。溶剂为二甲苯。At the same time, the silicone used is compounded by liquefied silicone rubber. The thickener is carboxymethyl cellulose. The dispersant is sodium hexametaphosphate. The solvent is xylene.
需要说明的是,N、P共掺杂碳包覆多孔Fe-Al-La-O的制备方法包括如下步骤:It should be noted that the preparation method of N, P co-doped carbon-coated porous Fe-Al-La-O includes the following steps:
步骤1、将铁源、铝源、镧源倒入到乙醇中搅拌0.4小时,再在缓慢加入醋酸钠后剧烈搅拌3h,获得混合搅拌溶液;且铁源为氯化铁;铝源为氯化铝;所述镧源为氯化镧。铁源、铝源、镧源、乙醇、醋酸钠的质量比为1:1:0.1:25:5。Step 1. Pour the iron source, aluminum source and lanthanum source into ethanol and stir for 0.4 hours, then slowly add sodium acetate and vigorously stir for 3 hours to obtain a mixed stirring solution; and the iron source is ferric chloride; the aluminum source is chloride Aluminum; the lanthanum source is lanthanum chloride. The mass ratio of iron source, aluminum source, lanthanum source, ethanol and sodium acetate is 1:1:0.1:25:5.
步骤2、将混合搅拌溶液转移至聚氟乙烯内衬的水热反应釜中,在控制温度为190℃下反应12h后依次经冷却、洗涤和真空干燥处理,获得初料。Step 2: Transfer the mixed and stirred solution to a hydrothermal reactor lined with polyvinyl fluoride, and react at a controlled temperature of 190° C. for 12 hours, followed by cooling, washing and vacuum drying to obtain the initial material.
步骤3、将初料分散于水中,再加入磷酸铵,控制温度为60℃并持续搅拌8小时,获得反应料;且初料、水和磷酸铵的质量比为1:4:0.05。Step 3: Disperse the initial material in water, then add ammonium phosphate, control the temperature to 60° C. and continue stirring for 8 hours to obtain a reaction material; and the mass ratio of the initial material, water and ammonium phosphate is 1:4:0.05.
步骤4、将反应料在550℃的惰性气体氛围下灼烧3小时,获得的物料经碾磨并过1100目筛,得到N、P共掺杂碳包覆多孔Fe-Al-La-O。Step 4, calcining the reaction material under an inert gas atmosphere at 550° C. for 3 hours, the obtained material is ground and passed through a 1100-mesh sieve to obtain N, P co-doped carbon-coated porous Fe-Al-La-O.
一种红外隐身高性能军用帐篷的制备方法,包括制备红外雷达隐身层12和将所述红外雷达隐身层12涂覆在基布层11上。红外雷达隐身层12的制备方法包括按重量份混合各组分,并在控制搅拌转速为2500r/min,搅拌为4小时时获得。A preparation method of an infrared stealth high-performance military tent includes preparing an infrared
实施例二Embodiment 2
如图1所示,一种红外隐身高性能军用帐篷,包括由基布层11以及涂覆在基布层11外侧壁的红外雷达隐身层12组成的帐篷本体1。As shown in FIG. 1 , an infrared stealth high-performance military tent includes a tent body 1 composed of a
其中,红外雷达隐身层12包括如下重量份的组分:有机硅酮40份、超支化聚苯胺2份、表面环氧基修饰多孔聚吡咯管4份、N、P共掺杂碳包覆多孔Fe-Al-La-O 7份、端氨基聚氨酯35份、溶剂15份、分散剂2份、增稠剂1.5份。Among them, the infrared
需要提及的是,增稠剂的平均分子量在10000-100000之间。所采用的基布为的纺织品或薄膜材料。薄膜材料的材质不限,在此不再赘述。纺织品为机织、针织、无纺布等形式制备的天然纤维、合成纤维和再生纤维。It should be mentioned that the average molecular weight of the thickener is between 10,000 and 100,000. The base fabric used is a textile or film material. The material of the thin film material is not limited and will not be repeated here. Textiles are natural fibers, synthetic fibers and regenerated fibers prepared in the form of woven, knitted, and non-woven fabrics.
与此同时,所采用的有机硅酮由液化有机硅橡胶复合而成。增稠剂为聚乙烯吡咯烷酮。分散剂为聚羧酸钠盐。溶剂为丙二醇甲醚醋酸酯。At the same time, the silicone used is compounded by liquefied silicone rubber. The thickener is polyvinylpyrrolidone. The dispersant is sodium polycarboxylate. The solvent is propylene glycol methyl ether acetate.
需要说明的是,N、P共掺杂碳包覆多孔Fe-Al-La-O的制备方法包括如下步骤:It should be noted that the preparation method of N, P co-doped carbon-coated porous Fe-Al-La-O includes the following steps:
步骤1、将铁源、铝源、镧源倒入到乙醇中搅拌0.7小时,再在缓慢加入醋酸钠后剧烈搅拌3.5h,获得混合搅拌溶液;且铁源为硫酸铁;铝源为硝酸铝;镧源为硝酸镧。铁源、铝源、镧源、乙醇、醋酸钠的质量比为1:1:0.15:30:5。Step 1. Pour the iron source, aluminum source and lanthanum source into ethanol and stir for 0.7 hours, then slowly add sodium acetate and vigorously stir for 3.5 hours to obtain a mixed stirring solution; and the iron source is iron sulfate; the aluminum source is aluminum nitrate ; Lanthanum source is lanthanum nitrate. The mass ratio of iron source, aluminum source, lanthanum source, ethanol and sodium acetate is 1:1:0.15:30:5.
步骤2、将混合搅拌溶液转移至聚氟乙烯内衬的水热反应釜中,在控制温度为200℃下反应15h后依次经冷却、洗涤和真空干燥处理,获得初料。Step 2: Transfer the mixed and stirred solution to a hydrothermal reaction kettle lined with polyvinyl fluoride, react at a controlled temperature of 200° C. for 15 hours, and sequentially cool, wash and vacuum dry to obtain the initial material.
步骤3、将初料分散于水中,再加入磷酸铵,控制温度为70℃并持续搅拌11小时,获得反应料;且初料、水和磷酸铵的质量比为1:6:0.1。Step 3: Disperse the initial material in water, then add ammonium phosphate, control the temperature to 70° C. and continue stirring for 11 hours to obtain a reaction material; and the mass ratio of the initial material, water and ammonium phosphate is 1:6:0.1.
步骤4、将反应料在600℃的惰性气体氛围下灼烧4小时,获得的物料经碾磨并过1200目筛,得到N、P共掺杂碳包覆多孔Fe-Al-La-O。Step 4, calcining the reaction material under an inert gas atmosphere at 600° C. for 4 hours, the obtained material is ground and passed through a 1200-mesh sieve to obtain N, P co-doped carbon-coated porous Fe-Al-La-O.
一种红外隐身高性能军用帐篷的制备方法,包括制备红外雷达隐身层12和将所述红外雷达隐身层12涂覆在基布层11上;所述红外雷达隐身层12的制备方法包括按重量份混合各组分,并在控制搅拌转速为4000r/min,搅拌为8小时时获得。A preparation method of an infrared stealth high-performance military tent, including preparing an infrared
实施例三Embodiment 3
如图1所示,一种红外隐身高性能军用帐篷,包括由基布层11以及涂覆在基布层11外侧壁的红外雷达隐身层12组成的帐篷本体1。As shown in FIG. 1 , an infrared stealth high-performance military tent includes a tent body 1 composed of a
其中,红外雷达隐身层12包括如下重量份的组分:有机硅酮50份、超支化聚苯胺3份、表面环氧基修饰多孔聚吡咯管5份、N、P共掺杂碳包覆多孔Fe-Al-La-O 10份、端氨基聚氨酯40份、溶剂20份、分散剂3份、增稠剂2份。The infrared
需要提及的是,增稠剂的平均分子量在10000-100000之间。所采用的基布为的纺织品或薄膜材料。薄膜材料的材质不限,在此不再赘述。纺织品为机织、针织、无纺布等形式制备的天然纤维、合成纤维和再生纤维。It should be mentioned that the average molecular weight of the thickener is between 10,000 and 100,000. The base fabric used is a textile or film material. The material of the thin film material is not limited and will not be repeated here. Textiles are natural fibers, synthetic fibers and regenerated fibers prepared in the form of woven, knitted, and non-woven fabrics.
与此同时,所采用的有机硅酮由液化有机硅橡胶复合而成。增稠剂为淀粉、瓜尔胶和聚乙烯醇。分散剂为六偏磷酸钠和聚羧酸钠盐。溶剂为醋酸丁酯。At the same time, the silicone used is compounded by liquefied silicone rubber. Thickeners are starch, guar gum and polyvinyl alcohol. The dispersants are sodium hexametaphosphate and sodium polycarboxylate. The solvent is butyl acetate.
需要说明的是,N、P共掺杂碳包覆多孔Fe-Al-La-O的制备方法包括如下步骤:It should be noted that the preparation method of N, P co-doped carbon-coated porous Fe-Al-La-O includes the following steps:
步骤1、将铁源、铝源、镧源倒入到乙醇中搅拌1小时,再在缓慢加入醋酸钠后剧烈搅拌4h,获得混合搅拌溶液;且铁源为硫酸铁;铝源为氯化铝和硝酸铝;镧源为氯化镧和硝酸镧。铁源、铝源、镧源、乙醇、醋酸钠的质量比为1:1:0.2:35:5。Step 1. Pour the iron source, aluminum source and lanthanum source into ethanol and stir for 1 hour, then slowly add sodium acetate and vigorously stir for 4 hours to obtain a mixed stirring solution; and the iron source is ferric sulfate; the aluminum source is aluminum chloride and aluminum nitrate; lanthanum sources are lanthanum chloride and lanthanum nitrate. The mass ratio of iron source, aluminum source, lanthanum source, ethanol and sodium acetate is 1:1:0.2:35:5.
步骤2、将混合搅拌溶液转移至聚氟乙烯内衬的水热反应釜中,在控制温度为220℃下反应18h后依次经冷却、洗涤和真空干燥处理,获得初料。Step 2: Transfer the mixed and stirred solution to a polyvinyl fluoride-lined hydrothermal reaction kettle, and react at a controlled temperature of 220° C. for 18 hours, followed by cooling, washing and vacuum drying to obtain the initial material.
步骤3、将初料分散于水中,再加入磷酸铵,控制温度为80℃并持续搅拌15小时,获得反应料;且初料、水和磷酸铵的质量比为1:8:0.15。Step 3: Disperse the initial material in water, then add ammonium phosphate, control the temperature to be 80° C. and continue stirring for 15 hours to obtain a reaction material; and the mass ratio of the initial material, water and ammonium phosphate is 1:8:0.15.
步骤4、将反应料在650℃的惰性气体氛围下灼烧5小时,获得的物料经碾磨并过1300目筛,得到N、P共掺杂碳包覆多孔Fe-Al-La-O。Step 4, calcining the reaction material under an inert gas atmosphere at 650° C. for 5 hours, the obtained material is ground and passed through a 1300-mesh sieve to obtain N, P co-doped carbon-coated porous Fe-Al-La-O.
一种红外隐身高性能军用帐篷的制备方法,包括制备红外雷达隐身层12和将所述红外雷达隐身层12涂覆在基布层11上;所述红外雷达隐身层12的制备方法包括按重量份混合各组分,并在控制搅拌转速为5500r/min,搅拌为13小时时获得。A preparation method of an infrared stealth high-performance military tent, including preparing an infrared
实施例四Embodiment 4
实施例四与实施例一的区别在于,实施例四中的增稠剂为羧甲基纤维素、聚乙烯醇和聚乙烯吡咯烷酮。溶剂为二甲苯和醋酸丁酯。The difference between Example 4 and Example 1 is that the thickeners in Example 4 are carboxymethyl cellulose, polyvinyl alcohol and polyvinylpyrrolidone. Solvents were xylene and butyl acetate.
实施例五Embodiment 5
实施例五与实施例一的区别在于,实施例五中的溶剂为二甲苯、醋酸丁酯和丙二醇甲醚醋酸酯。The difference between Example 5 and Example 1 is that the solvents in Example 5 are xylene, butyl acetate and propylene glycol methyl ether acetate.
实施例六Embodiment 6
实施例六与实施例一的区别在于,实施例六中的铁源为氯化铁、硝酸铁和硫酸铁。The difference between Example 6 and Example 1 is that the iron source in Example 6 is ferric chloride, ferric nitrate and ferric sulfate.
如下表为本申请实施例一至实施例六的检测数据:The following table is the detection data of Example 1 to Example 6 of the present application:
综上,本申请通过简化红外隐身高性能军用帐篷的制备方法,从而在显著提升制备效率的同时,具有提高成品合格率、综合性能的效果,并实现降低设备依赖性的目的,适于连续规模化生产,从而具有较高的经济价值、社会价值和生态价值;并在通过该制备方法获得红外隐身高性能军用帐篷时使得该红外隐身高性能军用帐篷具有在8-14μm波段红外的发射率可达到0.7,且在匹配厚度7mm时,最小反射率可达-31.5dB,有效吸收带宽为4.1GHz。需要提及的是,通过该制备方法获得的红外隐身高性能军用帐篷上的红外雷达隐身层12有效克服市面上的隐身帐篷涂料涂层厚重和无透气性导致的穿戴闷热难受的问题,并有效提升与基布层11的粘结性,并在解决现有产品的耐候性、耐久性和耐水洗牢度差的缺陷,以通过各组分协同作用,使得该红外隐身高性能军用帐篷具有长期使用保持性能稳定性的效果,显著提升该红外隐身高性能军用帐篷的综合性能、隐身效果、性能稳定性、耐久性、耐候性和耐水洗牢度。To sum up, by simplifying the preparation method of the infrared stealth high-performance military tent, the present application not only significantly improves the preparation efficiency, but also has the effect of improving the qualified rate of finished products and comprehensive performance, and achieves the purpose of reducing equipment dependence, which is suitable for continuous scale. Therefore, it has high economic value, social value and ecological value; and when the infrared stealth high-performance military tent is obtained through the preparation method, the infrared stealth high-performance military tent has a high infrared emissivity in the 8-14 μm band. It reaches 0.7, and when the matching thickness is 7mm, the minimum reflectivity can reach -31.5dB, and the effective absorption bandwidth is 4.1GHz. It should be mentioned that the infrared
具体的,在该红外隐身高性能军用帐篷通过添加有机硅酮、超支化聚苯胺、表面环氧基修饰多孔聚吡咯管、N、P共掺杂碳包覆多孔Fe-Al-La-O的协同作用,使得该红外隐身高性能军用帐篷的红外雷达隐身层12在具有优异的红外吸收功能的同时,起到红外和雷达双波段隐身,并在创新配置各组分比例时获得最佳阻抗匹配,而且孔径分布可调,并使得多孔Fe-Al-La-O和多孔聚吡咯管极高的比表面积和丰富的孔道结构造成多重散射,实现质轻、导电性强和有效改善隐身效果的目的。并在通过有机硅酮、端氨基聚氨酯的添加时,与表面环氧基修饰多孔聚吡咯管上的环氧基发生开环反应,使得各功能成分之间以化学键连接,形成三维网络结构,有效改善综合性能在极端环境条件下的耐高低温、耐磨性,使得该红外隐身高性能军用帐篷在长期使用时保持性能稳定,以有效延长使用寿命。Specifically, in this infrared stealth high-performance military tent, the porous Fe-Al-La-O is coated by adding organic silicone, hyperbranched polyaniline, surface epoxy group modified porous polypyrrole tube, and N, P co-doped carbon. The synergistic effect enables the infrared
本申请涉及的“第一”、“第二”、“第三”、“第四”等(如果存在)是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的实施例能够以除了在这里图示或描述的内容以外的顺序实施。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元的过程、方法或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法或设备固有的其它步骤或单元。References in this application to "first", "second", "third", "fourth", etc. (if any) are used to distinguish similar objects and are not necessarily used to describe a specific order or sequence. It is to be understood that data so used may be interchanged under appropriate circumstances so that the embodiments described herein can be practiced in sequences other than those illustrated or described herein. Furthermore, the terms "comprising" and "having", and any variations thereof, are intended to cover non-exclusive inclusion, for example, a process, method or apparatus comprising a series of steps or elements is not necessarily limited to those steps or elements expressly listed , but may include other steps or elements not expressly listed or inherent to these processes, methods or apparatus.
需要说明的是,在本申请中涉及“第一”、“第二”等的描述仅用于描述目的,而不能理解为指示或暗示其相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。另外,各个实施例之间的技术方案可以相互结合,但是必须是以本领域普通技术人员能够实现为基础,当技术方案的结合出现相互矛盾或无法实现时应当认为这种技术方案的结合不存在,也不在本申请要求的保护范围之内。It should be noted that the descriptions involving "first", "second", etc. in this application are only for the purpose of description, and should not be construed as indicating or implying their relative importance or implying the number of indicated technical features . Thus, a feature delimited with "first", "second" may expressly or implicitly include at least one of that feature. In addition, the technical solutions between the various embodiments can be combined with each other, but must be based on the realization by those of ordinary skill in the art. When the combination of technical solutions is contradictory or cannot be realized, it should be considered that the combination of such technical solutions does not exist. , is not within the scope of protection claimed in this application.
本文中应用了具体个例对本申请的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本申请的方法及其核心思想;同时,对于本领域的一般技术人员,依据本申请的思想,在具体实施方式及应用范围上均会有改变之处,综上所述,本说明书内容不应理解为对本申请的限制。The principles and implementations of the present application are described herein by using specific examples. The descriptions of the above embodiments are only used to help understand the methods and core ideas of the present application. There will be changes in the specific implementation and application scope. To sum up, the content of this specification should not be construed as a limitation to the application.
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