[go: up one dir, main page]

CN114870560A - Full-load denitration bypass flue system coupled with urea hydrolysis and working method thereof - Google Patents

Full-load denitration bypass flue system coupled with urea hydrolysis and working method thereof Download PDF

Info

Publication number
CN114870560A
CN114870560A CN202210600817.7A CN202210600817A CN114870560A CN 114870560 A CN114870560 A CN 114870560A CN 202210600817 A CN202210600817 A CN 202210600817A CN 114870560 A CN114870560 A CN 114870560A
Authority
CN
China
Prior art keywords
flue
bypass
flue gas
inlet
denitration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202210600817.7A
Other languages
Chinese (zh)
Other versions
CN114870560B (en
Inventor
苏逸峰
张超
陈建英
胡新
齐全
张国富
刘钰天
李元昊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xian Xire Boiler Environmental Protection Engineering Co Ltd
Original Assignee
Xian Xire Boiler Environmental Protection Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xian Xire Boiler Environmental Protection Engineering Co Ltd filed Critical Xian Xire Boiler Environmental Protection Engineering Co Ltd
Priority to CN202210600817.7A priority Critical patent/CN114870560B/en
Publication of CN114870560A publication Critical patent/CN114870560A/en
Application granted granted Critical
Publication of CN114870560B publication Critical patent/CN114870560B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/005Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/12Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/343Heat recovery
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8696Controlling the catalytic process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/90Injecting reactants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/003Arrangements of devices for treating smoke or fumes for supplying chemicals to fumes, e.g. using injection devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/006Layout of treatment plant
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • F23J15/027Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using cyclone separators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/08Arrangements of devices for treating smoke or fumes of heaters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/40Intercepting solids by cyclones
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/10Catalytic reduction devices

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Treating Waste Gases (AREA)
  • Chimneys And Flues (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

The invention discloses a full-load denitration bypass flue system coupled with urea hydrolysis and a working method thereof, wherein an outlet of a flue gas bypass flue is connected with an inlet of a high-efficiency cyclone dust collector through an electric shutoff valve and an electric adjusting valve; the outlet of the steam header is divided into two paths, wherein one path is connected with the urea hydrolyzer through the temperature and pressure reducing device, and the other path is connected with the urea hydrolyzer through the heat exchanger in the main flue of the boiler.

Description

Full-load denitration bypass flue system coupled with urea hydrolysis and working method thereof
Technical Field
The invention belongs to the technical field of full-load denitration, and relates to a full-load denitration bypass flue system coupled with urea hydrolysis and a working method thereof.
Background
Promote the major hazard source (liquid ammonia tank field) of power generation enterprise to administer, many power plants adopt urea hydrolysis SCR denitration technique to replace, and this safety level of enterprise has obtained the powerful promotion.
However, the traditional wide-load denitration high-temperature bypass has large air extraction amount, large cross section of a flue and limited temperature rise capability (about 20-30 ℃), and for a compact unit, the bypass flue is very difficult to arrange between a vertical shaft flue of a boiler and a denitration inlet flue, so that the limitation is large. Under the working conditions of unit starting and low load, the smoke temperature at the denitration inlet is even as low as about 240 ℃, and the operation requirement of the denitration catalyst on the smoke temperature being more than or equal to 300 ℃ cannot be met.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a full-load denitration bypass flue system coupled with urea hydrolysis and a working method thereof, and the system and the working method thereof can meet the operation requirement of a denitration catalyst on the smoke temperature of more than or equal to 300 ℃.
In order to achieve the aim, the full-load denitration bypass flue system coupled with urea hydrolysis comprises a flue gas bypass flue, a boiler body, an electric shutoff door, an electric adjusting door, a high-efficiency cyclone dust collector, a bypass fan, a bypass flue gas header, a steam header, a temperature and pressure reducing device, a urea hydrolyzer, a boiler main flue, a dilution fan and an ammonia-air mixer;
an inlet of a flue gas bypass flue is connected with a steering chamber in a boiler body, an outlet of the flue gas bypass flue is connected with an inlet of a high-efficiency cyclone dust collector through an electric shutoff valve and an electric adjusting valve, an outlet of the high-efficiency cyclone dust collector is connected with an inlet of a bypass fan, an outlet of the bypass fan is communicated with an inlet of a bypass flue gas header, and a multi-channel large-depth injection device, a flue gas mixer and an ammonia gas injection device are arranged in a denitration inlet flue;
the outlet of the steam header is divided into two paths, wherein one path is connected with the urea hydrolyzer through a temperature and pressure reducing device, and the other path is connected with the urea hydrolyzer through a heat exchanger in a main flue of the boiler; the outlet of the urea hydrolyzer and the outlet of the dilution fan are connected with the inlet of an ammonia-air mixer, and the outlet of the ammonia-air mixer is connected with an ammonia gas injection device;
the flue gas bypass flue is connected with a steering chamber in the boiler body through a first expansion joint.
A second expansion joint is arranged between the high-efficiency cyclone dust collector and the bypass fan, and a third expansion joint is arranged between the bypass fan and the bypass flue gas header.
The outlet of the high-efficiency cyclone dust collector is connected with the inlet of the bypass fan through the circular flue.
High-efficient cyclone arranges in the top or the side of denitration entry flue.
An ash conveying port at the bottom of the high-efficiency cyclone dust collector is connected with an ash hopper at the bottom of the denitration inlet flue through a first electric butterfly valve.
An ash conveying port at the bottom of the bypass flue gas header is connected with an ash hopper at the bottom of the denitration inlet flue through an ash conveying pipeline, and a second electric butterfly valve is arranged on the ash conveying pipeline.
And an adjusting baffle group is arranged at the inlet of the multi-channel large-depth injection device.
The system also comprises a central controller;
control valve sets are respectively arranged at the inlet and the outlet of the temperature and pressure reducer and the inlet and the outlet of the heat exchanger, and a steering chamber temperature measuring device, a main flue gas temperature measuring device and a mixed flue gas temperature measuring device are respectively arranged above the steering chamber, the horizontal section of the main flue and the ammonia gas injection device;
the central controller is connected with the control valve group, the first electric butterfly valve, the steering chamber temperature measuring device, the main flue gas temperature measuring device, the second electric butterfly valve, the bypass fan, the electric shutoff door, the electric adjusting door, the adjusting baffle group and the mixed flue gas temperature measuring device.
The working method of the full-load denitration bypass flue system coupled with urea hydrolysis comprises the following steps:
when the temperature at the downstream of the ammonia gas injection device does not meet the operation requirement of an SCR system at 300 ℃, an electric shutoff door and an electric adjusting door are opened, a bypass fan is started, high-temperature flue gas is extracted from a steering chamber, is dedusted by a high-efficiency cyclone deduster, is conveyed to a bypass flue gas header, is injected into a denitration inlet flue through a multi-channel large-depth injection device, and is uniformly mixed with main flue gas through a flue gas mixer;
when the temperature in the denitration inlet flue is more than or equal to 300 ℃, steam output by the steam header is subjected to temperature and pressure reduction by the temperature reduction and pressure reduction device and then injected into the urea hydrolyzer, when the temperature in the denitration inlet flue is less than 300 ℃, part or all of the steam output by the steam header is preheated by the heat exchanger and then injected into the urea hydrolyzer after the temperature and pressure reduction of high-parameter steam is realized, ammonia product gas output by the urea hydrolyzer is mixed with dilution air output by the dilution fan in the ammonia-air mixer, then the mixed gas is injected into the mixed flue gas by the ammonia gas injection device and then enters the denitration inlet flue, and full-load denitration is realized.
The invention has the following beneficial effects:
when the full-load denitration bypass flue system coupled with urea hydrolysis and the working method thereof are operated specifically, the method fully utilizes the redundant heat of the steam used for urea hydrolysis to preheat the flue gas of the main path, and then secondarily heats the flue gas of the main path through the high-temperature bypass flue gas, thereby avoiding energy waste caused by direct temperature reduction and pressure reduction of high-parameter steam, effectively reducing the cross section area and the air suction quantity of the bypass flue gas due to preheating, reducing the influence of the high-temperature bypass on the boiler efficiency, meeting the operation requirement of a denitration catalyst on the flue gas temperature being more than or equal to 300 ℃, being beneficial to the arrangement of the bypass flue between the main flue and a denitration inlet flue, and being provided with a high-efficiency cyclone dust collector, a bypass fan and a multi-channel large-depth injection device in the bypass, the abrasion and the dust deposition of the bypass flue can be reduced, the injection depth of the bypass flue gas is ensured, and the controllable uniformity of the flue gas temperature is realized.
Drawings
FIG. 1 is a system flow diagram of the present invention;
wherein, 1 is a first expansion joint, 2 is an electric shutoff door, 3 is an electric adjusting door, 4 is a high-efficiency cyclone dust collector, 5 is a second expansion joint, 6 is a bypass fan, 7 is a third expansion joint, 8 is a bypass flue gas header, 9 is an adjusting baffle group, 10 is a multi-channel large-depth injection device, 11 is a flue gas mixer, 12 is a steam header, 13 is a temperature and pressure reducer, 14 is a urea hydrolyzer, 15 is a control valve group, 16 is a heat exchanger, 17 is an ammonia-air mixer, 18 is a dilution fan, 19 is an ammonia gas injection device, 201 is a first electric butterfly valve, 202 is a second electric butterfly valve, 21 is an ash hopper, 22 is a mixed flue gas temperature measuring device, 23 is a main flue gas temperature measuring device, 24 is a steering chamber temperature measuring device, and 25 is a central controller.
Detailed Description
In order to make the technical solutions of the present invention better understood, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, not all of the embodiments, and are not intended to limit the scope of the present disclosure. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present disclosure. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
There is shown in the drawings a schematic block diagram of a disclosed embodiment in accordance with the invention. The figures are not drawn to scale, wherein certain details are exaggerated and possibly omitted for clarity of presentation. The shapes of various regions, layers and their relative sizes and positional relationships shown in the drawings are merely exemplary, and deviations may occur in practice due to manufacturing tolerances or technical limitations, and a person skilled in the art may additionally design regions/layers having different shapes, sizes, relative positions, according to actual needs.
Referring to fig. 1, the full-load denitration bypass flue system coupled with urea hydrolysis according to the present invention includes a first expansion joint 1, an electric shutoff valve 2, an electric adjustment door 3, a high efficiency cyclone 4, a second expansion joint 5, a bypass fan 6, a third expansion joint 7, a bypass flue gas header 8, an adjustment baffle group 9, a multi-channel large depth injection device 10, a flue gas mixer 11, a steam header 12, a temperature and pressure reduction device 13, a urea hydrolyzer 14, a control valve group 15, a heat exchanger 16, an ammonia-air mixer 17, a dilution fan 18, an ammonia gas injection device 19, a first electric butterfly valve 201, a second electric butterfly valve 202, an ash bucket 21, a mixed flue gas temperature measuring device 2, a main flue gas temperature measuring device 23, a steering chamber temperature measuring device 24, and a central controller 25;
the flue gas bypass flue is connected with a steering chamber in the boiler body through a first expansion joint 1, the outlet of the flue gas bypass flue is connected with the inlet of a high-efficiency cyclone dust collector 4 through an electric shutoff valve 2 and an electric adjusting valve 3, the outlet of the high-efficiency cyclone dust collector 4 is connected with the inlet of a bypass fan 6 through a circular flue, the outlet of the bypass fan 6 is communicated with the inlet of a bypass flue gas header 8 through a third expansion joint 7, and a multi-channel large-depth injection device 10, a flue gas mixer 11 and an ammonia gas injection device 19 are arranged in the denitration inlet flue, wherein the multi-channel large-depth injection device 10, the flue gas mixer 11 and the ammonia gas injection device 19 are sequentially arranged along the flue gas flowing direction, and the bypass flue gas header 8 is connected with the multi-channel large-depth injection device 10;
the outlet of the steam header 12 is divided into two paths, wherein one path is connected with a urea hydrolyzer 14 through a temperature and pressure reducing device 13, and the other path is communicated with the urea hydrolyzer 14 through a heat exchanger 16 in a main flue of the boiler; the outlet of the urea hydrolyzer 14 and the outlet of the dilution fan 18 are connected to the inlet of the ammonia air mixer 17, and the outlet of the ammonia air mixer 17 is connected to the ammonia gas injection device 19.
High-efficient cyclone 4 arranges in the top or the side of denitration entry flue, and the defeated ash mouth of high-efficient cyclone 4 bottom links to each other with the ash bucket 21 of denitration entry flue bottom through first electric butterfly valve 201.
A second expansion joint 5 is arranged between the high-efficiency cyclone dust collector 4 and the bypass fan 6, and a third expansion joint 7 is arranged between the bypass fan 6 and the bypass flue gas header 8.
An ash conveying port at the bottom of the bypass flue gas header 8 is connected with an ash hopper 21 at the bottom of the denitration inlet flue through an ash conveying pipeline, and a second electric butterfly valve 202 is arranged on the ash conveying pipeline.
An adjusting baffle group 9 is arranged at the inlet of the multi-channel large-depth injection device 10, and each baffle in the adjusting baffle group 9 controls the flue gas flow of one channel.
Control valve sets 15 are installed at the inlet and the outlet of the temperature and pressure reducer 13 and the inlet and the outlet of the heat exchanger 16, wherein the control valve sets 15 are composed of one or more valves, and path selection and flow control are achieved.
A steering chamber temperature measuring device 24, a main flue gas temperature measuring device 23 and a mixed flue gas temperature measuring device 22 are respectively arranged above the steering chamber, the horizontal section of the main flue and the ammonia gas injection device 19.
The central controller 25 is connected with the control valve group 15, the second electric butterfly valve 202, the steering chamber temperature measuring device 24, the main flue gas temperature measuring device 23, the first electric butterfly valve 201, the bypass fan 6, the electric shutoff door 2, the electric adjusting door 3, the adjusting baffle group 9 and the mixed flue gas temperature measuring device 22.
The working method of the full-load denitration bypass flue system coupled with urea hydrolysis comprises the following steps:
when the feedback temperature measured by the mixed flue gas temperature measuring device 22 does not meet the operation requirement of the SCR system at 300 ℃, an electric shutoff door 2 and an electric adjusting door 3 are opened, a bypass fan 6 is started, part of high-temperature flue gas is extracted from a steering chamber, is dedusted by a high-efficiency cyclone dust collector 4, is conveyed to a bypass flue gas header 8, is distributed by each channel in the multi-channel large-depth injection device 10, is injected into a denitration inlet flue, and is uniformly mixed with the main flue gas at a flue gas mixer 11.
High-parameter steam (the pressure is more than or equal to 1MPa and the temperature is about 350 ℃) used for urea hydrolysis is taken from a steam header 12, when the temperature of a denitration inlet flue is more than or equal to 300 ℃, the steam output by the steam header 12 is adjusted to the pressure of 0.4-0.6 MPa and the temperature is about 180 ℃ through a temperature reduction and pressure reduction device 13 and then injected into a urea hydrolyzer 14, when the temperature of the denitration inlet flue is less than 300 ℃, a central controller 25 synchronously controls the opening and closing and the opening of a control valve group 15, so that part or all of the steam preheats main flue gas through a heat exchanger 16, the high-parameter steam is injected into the urea hydrolyzer 14 after being subjected to temperature reduction and pressure reduction, ammonia product gas output by the urea hydrolyzer 14 is mixed with dilution air output by a dilution fan 18 in an ammonia air mixer 17, then the mixed flue gas is injected through an ammonia gas injection device 19 and then enters the denitration inlet flue, and full-load denitration is realized.
Finally, the invention couples urea hydrolysis, fully utilizes the redundant heat of steam used for urea hydrolysis and high-temperature flue gas to heat the flue gas in the main path, can effectively increase the temperature of the denitration inlet flue gas to the SCR working temperature, ensures the temperature uniformity of mixed flue gas, and has the advantages of automatic adjustment of the whole system, simple structure, convenient operation and strong practicability.

Claims (10)

1. A full-load denitration bypass flue system coupled with urea hydrolysis is characterized by comprising a flue gas bypass flue, a boiler body, an electric shutoff valve (2), an electric adjusting valve (3), a high-efficiency cyclone dust collector (4), a bypass fan (6), a bypass flue gas header (8), a steam header (12), a temperature and pressure reducing device (13), a urea hydrolyzer (14), a boiler main flue, a dilution fan (18) and an ammonia-air mixer (17);
an inlet of a flue gas bypass flue is connected with a steering chamber in a boiler body, an outlet of the flue gas bypass flue is connected with an inlet of a high-efficiency cyclone dust collector (4) through an electric shutoff valve (2) and an electric adjusting valve (3), an outlet of the high-efficiency cyclone dust collector (4) is connected with an inlet of a bypass fan (6), an outlet of the bypass fan (6) is communicated with an inlet of a bypass flue gas header (8), a multi-channel large-depth injection device (10), a flue gas mixer (11) and an ammonia injection device (19) are arranged in a denitration inlet flue, wherein the multi-channel large-depth injection device (10), the flue gas mixer (11) and the ammonia injection device (19) are sequentially arranged along the flue gas flowing direction, and the bypass flue gas header (8) is connected with the multi-channel large-depth injection device (10);
an outlet of the steam header (12) is divided into two paths, wherein one path is connected with the urea hydrolyzer (14) through a temperature and pressure reducing device (13), and the other path is connected with the urea hydrolyzer (14) through a heat exchanger (16) in a main flue of the boiler; the outlet of the urea hydrolyzer (14) and the outlet of the dilution fan (18) are connected with the inlet of an ammonia-air mixer (17), and the outlet of the ammonia-air mixer (17) is connected with an ammonia gas injection device (19).
2. The full-load denitration bypass flue system coupled with urea hydrolysis as claimed in claim 1, wherein the flue gas bypass flue is connected with the turning chamber in the boiler body through a first expansion joint (1).
3. The full-load denitration bypass flue system coupled with urea hydrolysis as claimed in claim 2, wherein a second expansion joint (5) is arranged between the high-efficiency cyclone (4) and the bypass fan (6), and a third expansion joint (7) is arranged between the bypass fan (6) and the bypass flue gas header (8).
4. The full-load denitration bypass flue system coupled with urea hydrolysis as recited in claim 1, wherein the outlet of the high-efficiency cyclone (4) is connected with the inlet of the bypass fan (6) through a circular flue.
5. The full-load denitration bypass flue system coupled with urea hydrolysis as recited in claim 1, wherein the high-efficiency cyclone (4) is arranged above or at the side of the denitration inlet flue.
6. The full-load denitration bypass flue system coupled with urea hydrolysis as recited in claim 1, wherein an ash conveying port at the bottom of the high-efficiency cyclone (4) is connected with an ash hopper (21) at the bottom of the denitration inlet flue through a first electric butterfly valve (201).
7. The full-load denitration bypass flue system coupled with urea hydrolysis as claimed in claim 6, wherein an ash conveying port at the bottom of the bypass flue gas header (8) is connected with an ash hopper (21) at the bottom of the denitration inlet flue through an ash conveying pipeline, and a second electric butterfly valve (202) is arranged on the ash conveying pipeline.
8. The full-load denitration bypass flue system coupled with urea hydrolysis as recited in claim 1, characterized in that an adjusting baffle group (9) is arranged at the inlet of the multi-channel large-depth injection device (10).
9. The full load denitration bypass flue system coupled with urea hydrolysis according to claim 7, further comprising a central controller (25);
control valve sets (15) are respectively arranged at the inlet and the outlet of the temperature and pressure reducer (13) and the inlet and the outlet of the heat exchanger (16), and a steering chamber temperature measuring device (24), a main flue gas temperature measuring device (23) and a mixed flue gas temperature measuring device (22) are respectively arranged above the steering chamber, the horizontal section of the main flue and the ammonia gas injection device (19);
the central controller (25) is connected with the control valve group (15), the first electric butterfly valve (201), the steering chamber temperature measuring device (24), the main flue gas temperature measuring device (23), the second electric butterfly valve (202), the bypass fan (6), the electric shutoff door (2), the electric adjusting door (3), the adjusting baffle group (9) and the mixed flue gas temperature measuring device (22).
10. A method of operating a full-load denitration bypass flue system coupled with urea hydrolysis as set forth in claim 1, comprising the steps of:
when the temperature of the downstream of the ammonia gas injection device (19) does not meet the operation requirement of an SCR system at 300 ℃, an electric shutoff door (2) and an electric adjusting door (3) are opened, a bypass fan (6) is started, high-temperature flue gas is extracted from a steering chamber, is dedusted by a high-efficiency cyclone deduster (4), is conveyed to a bypass flue gas header (8), is injected into a denitration inlet flue through a multi-channel large-depth injection device (10), and is uniformly mixed with main flue gas through a flue gas mixer (11);
when the temperature in the denitration inlet flue is more than or equal to 300 ℃, steam output by the steam header (12) is subjected to temperature and pressure reduction through the temperature and pressure reduction device (13) and then injected into the urea hydrolyzer (14), when the temperature in the denitration inlet flue is less than 300 ℃, part or all of the steam output by the steam header (12) preheats main flue gas through the heat exchanger (16), high-parameter steam is subjected to temperature and pressure reduction and then injected into the urea hydrolyzer (14), and ammonia product gas output by the urea hydrolyzer (14) is mixed with dilution air output by the dilution fan (18) in the ammonia-air mixer (17), then is injected into mixed flue gas through the ammonia injection device (19), and then enters the denitration inlet flue to realize full-load denitration.
CN202210600817.7A 2022-05-30 2022-05-30 Full-load denitration bypass flue system coupled with urea hydrolysis and working method thereof Active CN114870560B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210600817.7A CN114870560B (en) 2022-05-30 2022-05-30 Full-load denitration bypass flue system coupled with urea hydrolysis and working method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210600817.7A CN114870560B (en) 2022-05-30 2022-05-30 Full-load denitration bypass flue system coupled with urea hydrolysis and working method thereof

Publications (2)

Publication Number Publication Date
CN114870560A true CN114870560A (en) 2022-08-09
CN114870560B CN114870560B (en) 2024-08-23

Family

ID=82680607

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210600817.7A Active CN114870560B (en) 2022-05-30 2022-05-30 Full-load denitration bypass flue system coupled with urea hydrolysis and working method thereof

Country Status (1)

Country Link
CN (1) CN114870560B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119413260A (en) * 2024-12-25 2025-02-11 中国计量科学研究院 Fixed pollution source flow in-situ calibration device and calibration method

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030118494A1 (en) * 2001-12-21 2003-06-26 Environmental Elements Corporation Process and apparatus for conditioning of combustion flue gases with ammonia from hydrolyzed urea
US20040057887A1 (en) * 2000-12-01 2004-03-25 Sun William H. Selective catalytic reduction of nox enabled by sidestream urea decomposition
CN104192862A (en) * 2014-09-23 2014-12-10 东方电气集团东方锅炉股份有限公司 Urea hydrolysis ammonia preparation method and device using boiler gas
CN204307517U (en) * 2014-10-30 2015-05-06 北京西山新干线除尘脱硫设备有限公司 Rapidly pre-warming type boiler SCR denitration reducing agent preparation system
CN207025088U (en) * 2017-08-07 2018-02-23 广州发展集团股份有限公司 A kind of electric heater dust stratification removal system
WO2020024384A1 (en) * 2018-08-03 2020-02-06 南京凯盛国际工程有限公司 Scr denitration system for cement kiln flue gas
CN214345615U (en) * 2021-02-05 2021-10-08 辽宁大唐国际葫芦岛热电有限责任公司 SCR denitrification facility
CN113511659A (en) * 2021-08-24 2021-10-19 西安热工研究院有限公司 Urea hydrolysis ammonia production device and method for denitration of flue gas of thermal power plant
CN113669748A (en) * 2021-09-13 2021-11-19 西安热工研究院有限公司 Full-load denitration system and method adopting dividing wall type heat exchange coupling coal-fired boiler
CN114151814A (en) * 2021-12-15 2022-03-08 西安西热锅炉环保工程有限公司 Back-out side-in multistage adjustable depth peak regulation bypass flue system
CN217410251U (en) * 2022-05-30 2022-09-13 西安西热锅炉环保工程有限公司 Full-load denitration bypass flue system coupled with urea hydrolysis

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040057887A1 (en) * 2000-12-01 2004-03-25 Sun William H. Selective catalytic reduction of nox enabled by sidestream urea decomposition
US20030118494A1 (en) * 2001-12-21 2003-06-26 Environmental Elements Corporation Process and apparatus for conditioning of combustion flue gases with ammonia from hydrolyzed urea
CN104192862A (en) * 2014-09-23 2014-12-10 东方电气集团东方锅炉股份有限公司 Urea hydrolysis ammonia preparation method and device using boiler gas
CN204307517U (en) * 2014-10-30 2015-05-06 北京西山新干线除尘脱硫设备有限公司 Rapidly pre-warming type boiler SCR denitration reducing agent preparation system
CN207025088U (en) * 2017-08-07 2018-02-23 广州发展集团股份有限公司 A kind of electric heater dust stratification removal system
WO2020024384A1 (en) * 2018-08-03 2020-02-06 南京凯盛国际工程有限公司 Scr denitration system for cement kiln flue gas
CN214345615U (en) * 2021-02-05 2021-10-08 辽宁大唐国际葫芦岛热电有限责任公司 SCR denitrification facility
CN113511659A (en) * 2021-08-24 2021-10-19 西安热工研究院有限公司 Urea hydrolysis ammonia production device and method for denitration of flue gas of thermal power plant
CN113669748A (en) * 2021-09-13 2021-11-19 西安热工研究院有限公司 Full-load denitration system and method adopting dividing wall type heat exchange coupling coal-fired boiler
CN114151814A (en) * 2021-12-15 2022-03-08 西安西热锅炉环保工程有限公司 Back-out side-in multistage adjustable depth peak regulation bypass flue system
CN217410251U (en) * 2022-05-30 2022-09-13 西安西热锅炉环保工程有限公司 Full-load denitration bypass flue system coupled with urea hydrolysis

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张弛: "烟气脱硝中尿素法制氨工艺比较", 能源化工, vol. 35, no. 06, 28 December 2014 (2014-12-28), pages 35 - 39 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119413260A (en) * 2024-12-25 2025-02-11 中国计量科学研究院 Fixed pollution source flow in-situ calibration device and calibration method

Also Published As

Publication number Publication date
CN114870560B (en) 2024-08-23

Similar Documents

Publication Publication Date Title
WO2021184786A1 (en) Urea direct-injection pyrolysis denitrification device arranged inside outlet flue duct of gas turbine
CN207065552U (en) A kind of low-temperature smoke recirculation system for reducing CFBB NOx emission
CN112880416B (en) Ultralow emission method and system for cement kiln flue gas NOx
CN106969351A (en) It is a kind of to reduce the flue gas recirculation method and system of CFBB NOx emission
CN217410251U (en) Full-load denitration bypass flue system coupled with urea hydrolysis
CN217082504U (en) Wide-load denitration system with stable combustion performance of boiler
CN115218197A (en) A kind of flue gas recirculation air distribution method
CN114870560A (en) Full-load denitration bypass flue system coupled with urea hydrolysis and working method thereof
CN114961903A (en) Combined heat and power generation system capable of flexibly supplying industrial steam and operation method
CN106823792B (en) Full-load SCR flue gas denitration system
CN211084104U (en) Composite reduction type low NOx emission device suitable for power station boiler
CN106402928A (en) Oxygen-enriched combustion system for coal gas electricity generation boiler
CN210473607U (en) Full-load SCR denitration system of coal-fired boiler
CN110671817B (en) Mine pit antifreeze air heating device based on methanol nanocatalytic oxidation
CN113405086B (en) Steam mixing system for realizing denitration and temperature raising and adjusting method thereof
CN103353123A (en) Synchronous Gas Supply Method and Structure for Two Beds of Updraft Fixed Bed Gasifier
CN212456936U (en) Wide load denitration flue gas temperature lift system
CN212296657U (en) A low-concentration gas premixing system
CN212057310U (en) A domestic waste fuel dosing device
CN209909893U (en) Smoke-air flow field pressure and power balance regulating and controlling system of double fluidized bed boiler
CN203454193U (en) Secondary air circulating system
CN218763367U (en) High-pressure fluidized air supply device of circulating fluidized bed boiler
CN111878843A (en) Wide load denitration flue gas temperature lift system
CN220496029U (en) SCR denitrification facility
CN217441664U (en) Flue regulating valve for low-nitrogen energy-saving combustion of hydrogen-fired boiler

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant