CN114847516B - A kind of explosive bead for cigarettes coated with water-soluble flavor and preparation method thereof - Google Patents
A kind of explosive bead for cigarettes coated with water-soluble flavor and preparation method thereof Download PDFInfo
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- CN114847516B CN114847516B CN202210353874.XA CN202210353874A CN114847516B CN 114847516 B CN114847516 B CN 114847516B CN 202210353874 A CN202210353874 A CN 202210353874A CN 114847516 B CN114847516 B CN 114847516B
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- 239000011324 bead Substances 0.000 title claims abstract description 218
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 235000019504 cigarettes Nutrition 0.000 title claims description 20
- 239000000796 flavoring agent Substances 0.000 title abstract description 157
- 235000019634 flavors Nutrition 0.000 title abstract description 157
- 239000002360 explosive Substances 0.000 title description 33
- 239000000463 material Substances 0.000 claims abstract description 400
- 239000007788 liquid Substances 0.000 claims abstract description 301
- -1 diterpenoid compound Chemical class 0.000 claims abstract description 27
- 239000000654 additive Substances 0.000 claims abstract description 17
- 230000000996 additive effect Effects 0.000 claims abstract description 12
- 239000003292 glue Substances 0.000 claims description 288
- 239000000243 solution Substances 0.000 claims description 101
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 85
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 53
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 53
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 53
- 229920005989 resin Polymers 0.000 claims description 45
- 239000011347 resin Substances 0.000 claims description 45
- 238000003756 stirring Methods 0.000 claims description 43
- 239000003755 preservative agent Substances 0.000 claims description 38
- 230000002335 preservative effect Effects 0.000 claims description 38
- 230000001681 protective effect Effects 0.000 claims description 33
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 30
- 235000013871 bee wax Nutrition 0.000 claims description 30
- 239000012166 beeswax Substances 0.000 claims description 30
- 235000010413 sodium alginate Nutrition 0.000 claims description 30
- 239000000661 sodium alginate Substances 0.000 claims description 30
- 229940005550 sodium alginate Drugs 0.000 claims description 30
- 239000002562 thickening agent Substances 0.000 claims description 30
- 239000001993 wax Substances 0.000 claims description 29
- 238000005406 washing Methods 0.000 claims description 25
- 235000010418 carrageenan Nutrition 0.000 claims description 18
- 239000000679 carrageenan Substances 0.000 claims description 18
- 229920001525 carrageenan Polymers 0.000 claims description 18
- 229940113118 carrageenan Drugs 0.000 claims description 18
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 18
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 239000001110 calcium chloride Substances 0.000 claims description 14
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- 239000003381 stabilizer Substances 0.000 claims description 14
- 108010010803 Gelatin Proteins 0.000 claims description 13
- 229920000159 gelatin Polymers 0.000 claims description 13
- 239000008273 gelatin Substances 0.000 claims description 13
- 235000019322 gelatine Nutrition 0.000 claims description 13
- 235000011852 gelatine desserts Nutrition 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 229920002545 silicone oil Polymers 0.000 claims description 11
- 241000238631 Hexapoda Species 0.000 claims description 10
- 235000013869 carnauba wax Nutrition 0.000 claims description 10
- 239000004203 carnauba wax Substances 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 10
- 150000004676 glycans Chemical class 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 229920001282 polysaccharide Polymers 0.000 claims description 10
- 239000005017 polysaccharide Substances 0.000 claims description 10
- 239000002518 antifoaming agent Substances 0.000 claims description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims description 6
- 239000003899 bactericide agent Substances 0.000 claims description 6
- 239000012188 paraffin wax Substances 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 4
- 229940014259 gelatin Drugs 0.000 claims description 3
- 239000000419 plant extract Substances 0.000 claims description 3
- 238000004880 explosion Methods 0.000 claims 6
- 235000019809 paraffin wax Nutrition 0.000 claims 1
- 235000019271 petrolatum Nutrition 0.000 claims 1
- 241000208125 Nicotiana Species 0.000 abstract description 142
- 235000002637 Nicotiana tabacum Nutrition 0.000 abstract description 142
- 238000007789 sealing Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 3
- 239000011162 core material Substances 0.000 description 282
- 239000010410 layer Substances 0.000 description 242
- 239000000203 mixture Substances 0.000 description 57
- 230000009172 bursting Effects 0.000 description 46
- 239000000284 extract Substances 0.000 description 26
- 230000005484 gravity Effects 0.000 description 22
- 238000000926 separation method Methods 0.000 description 22
- 239000002245 particle Substances 0.000 description 17
- 238000002347 injection Methods 0.000 description 16
- 239000007924 injection Substances 0.000 description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 13
- 239000013530 defoamer Substances 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 229920002125 Sokalan® Polymers 0.000 description 8
- 229960001631 carbomer Drugs 0.000 description 8
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 6
- 239000000600 sorbitol Substances 0.000 description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 5
- 239000010643 fennel seed oil Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- 150000004702 methyl esters Chemical class 0.000 description 5
- 239000001738 pogostemon cablin oil Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229960005323 phenoxyethanol Drugs 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002028 Biomass Substances 0.000 description 3
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 3
- 239000004831 Hot glue Substances 0.000 description 3
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 3
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- 229930002839 ionone Natural products 0.000 description 3
- 150000002499 ionone derivatives Chemical class 0.000 description 3
- 239000010668 rosemary oil Substances 0.000 description 3
- 229940058206 rosemary oil Drugs 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 2
- CQLYXIUHVFRXLT-UHFFFAOYSA-N 2-methoxyethylbenzene Chemical compound COCCC1=CC=CC=C1 CQLYXIUHVFRXLT-UHFFFAOYSA-N 0.000 description 2
- MFEIKQPHQINPRI-UHFFFAOYSA-N 3-Ethylpyridine Chemical compound CCC1=CC=CN=C1 MFEIKQPHQINPRI-UHFFFAOYSA-N 0.000 description 2
- XINCECQTMHSORG-UHFFFAOYSA-N Isoamyl isovalerate Chemical compound CC(C)CCOC(=O)CC(C)C XINCECQTMHSORG-UHFFFAOYSA-N 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 229930004069 diterpene Natural products 0.000 description 2
- 239000003571 electronic cigarette Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- ZYTMANIQRDEHIO-KXUCPTDWSA-N isopulegol Chemical compound C[C@@H]1CC[C@@H](C(C)=C)[C@H](O)C1 ZYTMANIQRDEHIO-KXUCPTDWSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 239000006187 pill Substances 0.000 description 2
- 239000004302 potassium sorbate Substances 0.000 description 2
- 235000010241 potassium sorbate Nutrition 0.000 description 2
- 229940069338 potassium sorbate Drugs 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- 239000001871 (1R,2R,5S)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-ol Substances 0.000 description 1
- 239000001606 7-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-5-hydroxy-2-(4-hydroxyphenyl)chroman-4-one Substances 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- OUGPMNMLWKSBRI-UHFFFAOYSA-N Hexyl formate Chemical compound CCCCCCOC=O OUGPMNMLWKSBRI-UHFFFAOYSA-N 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 241001409321 Siraitia grosvenorii Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000000202 analgesic effect Effects 0.000 description 1
- 230000000954 anitussive effect Effects 0.000 description 1
- 229940124584 antitussives Drugs 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BGLUXFNVVSVEET-UHFFFAOYSA-N beta-angelica lactone Chemical compound CC1OC(=O)C=C1 BGLUXFNVVSVEET-UHFFFAOYSA-N 0.000 description 1
- 229940055416 blueberry extract Drugs 0.000 description 1
- 235000019216 blueberry extract Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229930003633 citronellal Natural products 0.000 description 1
- 235000000983 citronellal Nutrition 0.000 description 1
- 229940119429 cocoa extract Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- FYTRVXSHONWYNE-UHFFFAOYSA-N delta-octanolide Chemical compound CCCC1CCCC(=O)O1 FYTRVXSHONWYNE-UHFFFAOYSA-N 0.000 description 1
- 238000012938 design process Methods 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- 239000003172 expectorant agent Substances 0.000 description 1
- 230000003419 expectorant effect Effects 0.000 description 1
- 239000008369 fruit flavor Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229940095045 isopulegol Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 229940069445 licorice extract Drugs 0.000 description 1
- 230000007721 medicinal effect Effects 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000008368 mint flavor Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000001114 myogenic effect Effects 0.000 description 1
- DFPMSGMNTNDNHN-ZPHOTFPESA-N naringin Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1O[C@H]1[C@H](OC=2C=C3O[C@@H](CC(=O)C3=C(O)C=2)C=2C=CC(O)=CC=2)O[C@H](CO)[C@@H](O)[C@@H]1O DFPMSGMNTNDNHN-ZPHOTFPESA-N 0.000 description 1
- 229940052490 naringin Drugs 0.000 description 1
- 229930019673 naringin Natural products 0.000 description 1
- ZYTMANIQRDEHIO-UHFFFAOYSA-N neo-Isopulegol Natural products CC1CCC(C(C)=C)C(O)C1 ZYTMANIQRDEHIO-UHFFFAOYSA-N 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B15/00—Solidifying fatty oils, fats, or waxes by physical processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Medicinal Preparation (AREA)
Abstract
本发明涉及一种包覆水溶性香精的烟用爆珠及其制备方法，属于烟草领域。所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜡和三环二萜类化合物，所述芯液包括水溶性香精和添加剂。本方案通过使用三环二萜类化合物作为支撑材料，赋予爆珠一定的强度，并且进一步加强壁材对芯液的密封效果，防止爆珠空壳化。
The present invention relates to a tobacco popping bead coated with a water-soluble flavor and a preparation method thereof, and belongs to the field of tobacco. The tobacco popping bead is provided with a skin-core structure, and the skin-core structure includes an outer wall material and a core liquid; the outer wall material includes wax and a tricyclic diterpenoid compound, and the core liquid includes a water-soluble flavor and an additive. This scheme uses a tricyclic diterpenoid compound as a supporting material to give the popping bead a certain strength, and further strengthens the sealing effect of the wall material on the core liquid to prevent the popping bead from becoming a hollow shell.
Description
技术领域Technical Field
本发明属于烟草领域，具体涉及一种包覆水溶性香精的烟用爆珠及其制备方法。The invention belongs to the field of tobacco, and particularly relates to a tobacco explosive bead coated with a water-soluble flavor and a preparation method thereof.
背景技术Background Art
在香烟过滤嘴部位添加爆珠可以增加烟草香型、抽吸体验感以及丰富口味。通常商业化爆珠内容物一般以辛癸酸甘油酯为芯材基底，通过添加不同油溶性香精来调配爆珠口味，并以多糖类材料(动物明胶、海藻酸钠、卡拉胶等)作为壁材实现密封，达到对不同香气的油溶性香精包负与密封。但多糖类材料类的吸水溶胀性特点，限制了水溶性香精做为爆珠添加香型的使用。Adding popping beads to the filter of cigarettes can increase the tobacco flavor, smoking experience and rich taste. Usually, the contents of commercial popping beads are generally based on caprylic decanoic acid glyceride as the core material, and the flavor of the popping beads is adjusted by adding different oil-soluble flavors, and polysaccharide materials (animal gelatin, sodium alginate, carrageenan, etc.) are used as wall materials to achieve sealing, so as to achieve the packaging and sealing of oil-soluble flavors with different aromas. However, the water absorption and swelling characteristics of polysaccharide materials limit the use of water-soluble flavors as popping beads to add flavor.
为拓展水溶性香精在爆珠中的应用，当前包覆水溶性香精的方法和途径主要为：(1)单层结构：a)将芯液经反相乳化形成油包水型微乳液，采用生物质胶或合成树脂做为壁材；b)非水溶性高聚物及其单体经自由基引发聚合成膜包负芯液。c)壁材为蜡、长链脂质材料与增强材料的复合体。(2)双皮层结构：a)即内层为蜡，外层为光敏性树脂材料；b)内层为疏水热熔胶膜，外层为生物质胶。(3)三层结构：内层为蜡层，中间层为包裹粉层，外层为亲水膜层。In order to expand the application of water-soluble flavors in popping beads, the current methods and approaches for coating water-soluble flavors are mainly: (1) Single-layer structure: a) The core liquid is emulsified by reverse phase to form an oil-in-water microemulsion, and biomass glue or synthetic resin is used as the wall material; b) Non-water-soluble polymers and their monomers are polymerized by free radicals to form a film to coat the core liquid. c) The wall material is a composite of wax, long-chain lipid material and reinforcing material. (2) Double-layer structure: a) The inner layer is wax and the outer layer is photosensitive resin material; b) The inner layer is a hydrophobic hot melt adhesive film and the outer layer is biomass glue. (3) Three-layer structure: The inner layer is a wax layer, the middle layer is a coating powder layer, and the outer layer is a hydrophilic film layer.
上述方法和途径中，单层结构中芯液微乳液存在稳定性的隐患。双层结构中蜡层与光敏性树脂的附着力较差，较难均匀地包覆在蜡层表面；而疏水性热熔胶膜一般透汽性较好，芯液中水分子极易从内部透过热熔胶膜挥发出来而导致外层生物质胶软化而失效。三层结构中工艺设计流程较复杂，实施困难较高。因此，本领域需要开发一种制备工艺简单、结构稳定、密封性能好的烟用爆珠。In the above methods and approaches, the core liquid microemulsion in the single-layer structure has a hidden danger of stability. The wax layer in the double-layer structure has poor adhesion to the photosensitive resin, and it is difficult to evenly coat the surface of the wax layer; and the hydrophobic hot melt adhesive film generally has good vapor permeability, and the water molecules in the core liquid can easily evaporate from the inside through the hot melt adhesive film, causing the outer biomass adhesive to soften and fail. The process design process in the three-layer structure is more complicated and difficult to implement. Therefore, the art needs to develop a tobacco explosive bead with a simple preparation process, stable structure, and good sealing performance.
发明内容Summary of the invention
本发明的目的是基于上述现有技术的不足而提供一种包覆水溶性香精的烟用爆珠及其制备方法。The object of the present invention is to provide a tobacco popping bead coated with a water-soluble flavor and a preparation method thereof based on the above-mentioned deficiencies of the prior art.
本发明是通过下述技术方案进行实现的：The present invention is achieved through the following technical solutions:
本发明提供一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜡和三环二萜类化合物，所述蜡和所述三环二萜类化合物的重量份数比为1:(0.5～2)。The present invention provides a tobacco popping bead coated with a water-soluble flavor. The tobacco popping bead is provided with a skin-core structure, wherein the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises wax and a tricyclic diterpene compound, and the weight ratio of the wax to the tricyclic diterpene compound is 1:(0.5-2).
本发明烟用爆珠的外层壁材以蜡类防水材料为基础，进一步加入三环二萜类化合物作为支撑材料。由于三环二萜类化合物具有硬而脆的特点，从而能够赋予爆珠一定的强度，在爆珠使用捏破时发出清脆的响声；同时三环二萜类化合物具有良好的黏结、密封性能，能够加强壁材对芯液的密封效果，防止水分子以汽态形式从壁材渗透出去，造成爆珠空壳化。The outer wall material of the cigarette popping bead of the present invention is based on a wax waterproof material, and tricyclic diterpenoid compounds are further added as supporting materials. Since the tricyclic diterpenoid compounds are hard and brittle, they can give the popping bead a certain strength, and a crisp sound is emitted when the popping bead is crushed; at the same time, the tricyclic diterpenoid compounds have good bonding and sealing properties, and can enhance the sealing effect of the wall material on the core liquid, preventing water molecules from penetrating from the wall material in the form of vapor, causing the popping bead to become hollow.
作为本发明所述包覆水溶性香精的烟用爆珠的优选实施方式，按重量份数计，所述外层壁材的重量份为55-80份，所述芯液的重量份为20-45份。As a preferred embodiment of the tobacco explosive beads coated with water-soluble flavors of the present invention, the weight of the outer wall material is 55-80 parts, and the weight of the core liquid is 20-45 parts.
作为本发明所述包覆水溶性香精的烟用爆珠的优选实施方式，在所述外层壁材和芯液之间还设有内层壁材，来避免蜡质材料与水性芯液接触时互相排斥的不足，进一步增强爆珠材料的稳定性。所述内层壁材为多糖类材料；所述多糖类材料为海藻酸钠、明胶、卡拉胶中的至少一种。As a preferred embodiment of the water-soluble flavor-coated popping beads of the present invention, an inner wall material is provided between the outer wall material and the core liquid to avoid the mutual repulsion between the wax material and the aqueous core liquid when in contact, and further enhance the stability of the popping bead material. The inner wall material is a polysaccharide material; the polysaccharide material is at least one of sodium alginate, gelatin, and carrageenan.
作为本发明所述包覆水溶性香精的烟用爆珠的优选实施方式，按重量份数计，所述内层壁材为55-80份，所述芯液为20-45份。As a preferred embodiment of the tobacco explosive beads coated with water-soluble flavors of the present invention, the inner wall material is 55-80 parts by weight, and the core liquid is 20-45 parts by weight.
作为本发明所述包覆水溶性香精的烟用爆珠的优选实施方式，所述蜡为蜂蜡、巴西棕榈蜡、固体石蜡、虫蜡中的至少一种；所述三环二萜类化合物为松香树脂、氢化松香树脂、甘油松香树脂、顺丁烯二酸酐松香树脂、松香改性酚醛树脂、松香甲酯、松香乙烯醇酯中的至少一种；所述芯液包括水溶性香精和添加剂，所述水溶性香精和添加剂的重量份数比1：(0.5～1)；所述水溶性香精为调配香精、天然植物提取物中的至少一种；所述添加剂为稳定剂、防腐剂、消泡剂、增稠剂、杀菌剂中的至少一种。As a preferred embodiment of the tobacco explosive beads coated with water-soluble flavors according to the present invention, the wax is at least one of beeswax, carnauba wax, solid paraffin, and insect wax; the tricyclic diterpenoid compound is at least one of rosin resin, hydrogenated rosin resin, glycerol rosin resin, maleic anhydride rosin resin, rosin-modified phenolic resin, rosin methyl ester, and rosin vinyl alcohol ester; the core liquid includes water-soluble flavors and additives, and the weight ratio of the water-soluble flavors and the additives is 1:(0.5-1); the water-soluble flavor is at least one of blended flavors and natural plant extracts; the additive is at least one of a stabilizer, a preservative, a defoamer, a thickener, and a bactericide.
优选地，所述水溶性香精为调配香精、天然植物提取物中的至少一种；该类组分在香烟或加热不燃烧电子烟烟用爆珠捏破或者其他外力破坏后，能被释放出来，赋予或增强香烟或加热不燃烧电子烟一定的风格风味，如薄荷味、奶香味、水果味、草本味、烟叶味等。Preferably, the water-soluble flavor is at least one of a blended flavor and a natural plant extract; such components can be released after the cigarette or the heat-not-burn electronic cigarette is crushed by a bursting bead or destroyed by other external forces, thereby giving or enhancing a certain style and flavor to the cigarette or the heat-not-burn electronic cigarette, such as mint flavor, milk flavor, fruit flavor, herbal flavor, tobacco flavor, etc.
优选地，所述调配香精为小茴香油、广藿香油等精油类，迷迭香油、玫瑰净油等净油类，薰衣草醇、薄荷醇、异胡薄荷醇等醇类，大茴香醚、甲基苯乙基醚等醚类，香茅醛、苯甲醛等醛类，紫罗兰酮、甲基丙烯基酮等酮类，乙酸、乳酸等酸类，甲酸己酯、异戊酸异戊酯等酯类，辛内酯、当归内酯等酯类以及糠醇、3-乙基吡啶等杂环类。Preferably, the blended essence is essential oils such as fennel oil and patchouli oil, absolute oils such as rosemary oil and rose absolute, alcohols such as lavender alcohol, menthol, isopulegol, ethers such as anisole and methyl phenethyl ether, aldehydes such as citronellal and benzaldehyde, ketones such as ionone and methyl propylene ketone, acids such as acetic acid and lactic acid, esters such as hexyl formate and isopentyl isovalerate, esters such as octanolactone and angelica lactone, and heterocyclics such as furfuryl alcohol and 3-ethylpyridine.
作为本发明所述包覆水溶性香精的烟用爆珠的优选实施方式，所述天然提取物为罗汉果提取物、可可提取物、蓝莓提取物、柚皮苷提取物、甘草提取物、咖啡提取物、津巴布韦提取物、烟草提取物中的至少一种。As a preferred embodiment of the tobacco popping beads coated with water-soluble flavors according to the present invention, the natural extract is at least one of monk fruit extract, cocoa extract, blueberry extract, naringin extract, licorice extract, coffee extract, Zimbabwe extract, and tobacco extract.
作为本发明所述包覆水溶性香精的烟用爆珠的优选实施方式，所述爆珠的重量为50-100mg，直径为3-7mm，抗碎强度为5-30N。As a preferred embodiment of the tobacco exploding beads coated with water-soluble flavors of the present invention, the weight of the exploding beads is 50-100 mg, the diameter is 3-7 mm, and the crushing strength is 5-30N.
本发明还提供了上述包覆水溶香精烟用爆珠的制备方法，包括以下步骤：The present invention also provides a method for preparing the above-mentioned water-soluble flavored tobacco explosive beads, comprising the following steps:
(1)取水溶性香精和添加剂混合均匀，得芯液；所述水溶性香精与所述芯液的重量份数比为1:(2.5～22)；所述添加剂与所述芯液的重量份数比为1:(5～22)；(1) taking a water-soluble flavor and an additive and mixing them evenly to obtain a core liquid; the weight ratio of the water-soluble flavor to the core liquid is 1:(2.5-22); the weight ratio of the additive to the core liquid is 1:(5-22);
(2)将所述蜡、三环二萜类化合物按所述重量份数比混合均匀，搅拌，加热熔融，得外层壁材胶液；(2) mixing the wax and the tricyclic diterpenoid compound in the weight ratio, stirring, heating and melting to obtain an outer wall material glue;
(3)将步骤(1)所得的芯液和步骤(2)所得的外层壁材胶液分别送入滴孔，滴出的所述芯液液滴和所述外层壁材胶液制成同心球形液滴；滴入保护液冷却，分离并洗涤，即得。(3) The core liquid obtained in step (1) and the outer wall material glue obtained in step (2) are respectively fed into the dripping holes, and the core liquid droplets and the outer wall material glue droplets are dripped out to form concentric spherical droplets; the protective liquid is dripped in to cool, separate and wash, and the result is obtained.
作为本发明所述包覆水溶性香精的烟用爆珠的制备方法的优选实施方式，所述步骤(2)中，外层壁材胶液的加热熔融温度为80℃-140℃；所述步骤(3)中，所述送入滴孔时，所述外层壁材胶液的流速：所述芯液的流速＝(1.2～2.5)：1；所述外层壁材胶液的温度为80℃-140℃，滴孔处的温度为80℃-110℃，所述芯液的温度为25℃-60℃；所述保护液为二甲基硅油，所述冷却温度为10℃-40℃。As a preferred embodiment of the method for preparing tobacco explosive beads coated with water-soluble flavors according to the present invention, in the step (2), the heating and melting temperature of the outer wall material glue is 80°C-140°C; in the step (3), when the glue is fed into the drip hole, the flow rate of the outer wall material glue: the flow rate of the core liquid = (1.2-2.5): 1; the temperature of the outer wall material glue is 80°C-140°C, the temperature at the drip hole is 80°C-110°C, and the temperature of the core liquid is 25°C-60°C; the protective liquid is dimethyl silicone oil, and the cooling temperature is 10°C-40°C.
本发明还提供了上述内外双层壁材包覆水溶性香精的烟用爆珠的制备方法，包括以下步骤：The present invention also provides a method for preparing the above-mentioned tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors, comprising the following steps:
(1)取水溶性香精和添加剂混合均匀，得芯液；所述水溶性香精与所述芯液的重量份数比为1:(2.5～22)；所述添加剂与所述芯液的重量份数比为1:(5～22)；(1) taking a water-soluble flavor and an additive and mixing them evenly to obtain a core liquid; the weight ratio of the water-soluble flavor to the core liquid is 1:(2.5-22); the weight ratio of the additive to the core liquid is 1:(5-22);
(2)将所述蜡、三环二萜类化合物按所述重量份数比混合均匀，搅拌，加热熔融，得外层壁材胶液；(2) mixing the wax and the tricyclic diterpenoid compound in the weight ratio, stirring, heating and melting to obtain an outer wall material glue;
(3)将所述多糖类材料在加热搅拌条件下溶解于水，得内层壁材胶液；所述多糖类材料占所述内层壁材胶液的质量百分比为10％～30％；(3) dissolving the polysaccharide material in water under heating and stirring conditions to obtain an inner wall material glue solution; the mass percentage of the polysaccharide material in the inner wall material glue solution is 10% to 30%;
(4)将步骤(1)所得的芯液和步骤(3)所得的内层壁材胶液分别送入滴孔，滴出的所述芯液液滴和所述内层壁材胶液形成制心球形液滴；滴入保护液冷却，分离并洗涤，即得烟用爆珠内层结构；(4) feeding the core liquid obtained in step (1) and the inner wall material glue obtained in step (3) into the dripping holes respectively, and the core liquid droplets and the inner wall material glue droplets dripped out form core spherical droplets; dripping into the protective liquid for cooling, separation and washing, so as to obtain the inner layer structure of the popping bead for cigarettes;
(5)将步骤(4)所得烟用爆珠内层结构浸没于步骤(2)所得外层壁材胶液中，冷却，即得。(5) immersing the inner layer structure of the tobacco explosive beads obtained in step (4) in the outer layer wall material glue obtained in step (2) and cooling the mixture to obtain the product.
作为本发明所述内外双层壁材包覆水溶性香精的烟用爆珠的制备方法的优选实施方式，所述步骤(2)中，外层壁材胶液加热熔融温度为80℃-140℃；所述步骤(3)中，内层壁材胶液的加热温度为65℃-80℃；所述步骤(4)中，所述送入滴孔时，所述内层壁材胶液的流速：所述芯液的流速＝(1.2～2.5)：1；所述内层壁材胶液的温度为65℃-80℃，滴孔处的温度为65℃-80℃，所述芯液的温度为25℃-60℃；所述保护液为质量分数5％-20％的氯化钙水溶液，所述冷却温度为10℃-40℃。As a preferred embodiment of the method for preparing the tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors according to the present invention, in the step (2), the heating melting temperature of the outer layer wall material glue is 80°C-140°C; in the step (3), the heating temperature of the inner layer wall material glue is 65°C-80°C; in the step (4), when the glue is fed into the drip hole, the flow rate of the inner layer wall material glue: the flow rate of the core liquid = (1.2-2.5): 1; the temperature of the inner layer wall material glue is 65°C-80°C, the temperature at the drip hole is 65°C-80°C, and the temperature of the core liquid is 25°C-60°C; the protective liquid is a calcium chloride aqueous solution with a mass fraction of 5%-20%, and the cooling temperature is 10°C-40°C.
本发明的有益效果在于：(1)与现有单层结构设计方案相比，在采用蜡类防水材料基础上，使用三环二萜类化合物作为支撑材料，一方面利用三环二萜类化合物硬而脆的特点，赋予爆珠一定的强度，在使用捏破时发出清脆的响声；另一方面利用三环二萜类化合物良好的黏结、密封性能，可进一步加强壁材对芯液的密封效果，防止水分子以汽态形式从壁材渗透出去，造成爆珠空壳化，增强了爆珠结构的稳定性；此外三环二萜类化合物还具有一定的药效，比如：镇咳祛痰、生肌止痛等。(2)与采用其他长链脂类材料和支撑材料相比，三环二萜类化合物不仅源于自然，其使用符合当前环保理念与要求，而且其价格低廉，可进一步降低爆珠生产成本，提升产品利润空间。(3)本方案中的结构设计较三层结构相比，精简了后续工艺步骤，缩短了爆珠制备周期，提高了生产效率。The beneficial effects of the present invention are as follows: (1) Compared with the existing single-layer structure design scheme, tricyclic diterpenoid compounds are used as supporting materials on the basis of wax waterproof materials. On the one hand, the hard and brittle characteristics of tricyclic diterpenoid compounds are utilized to give the popping beads a certain strength, and a crisp sound is emitted when they are squeezed in use; on the other hand, the good bonding and sealing properties of tricyclic diterpenoid compounds can be utilized to further enhance the sealing effect of the wall material on the core liquid, prevent water molecules from penetrating from the wall material in the form of vapor, causing the popping beads to become hollow shells, and enhance the stability of the popping bead structure; in addition, tricyclic diterpenoid compounds also have certain medicinal effects, such as antitussive and expectorant, myogenic and analgesic, etc. (2) Compared with the use of other long-chain lipid materials and supporting materials, tricyclic diterpenoid compounds are not only derived from nature, and their use is in line with current environmental protection concepts and requirements, but also have low prices, which can further reduce the production cost of popping beads and increase product profit margins. (3) Compared with the three-layer structure, the structural design in this scheme simplifies the subsequent process steps, shortens the popping bead preparation cycle, and improves production efficiency.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为外层壁材包覆芯液的烟用爆珠制备示意图；FIG1 is a schematic diagram of the preparation of a cigarette-use explosive bead with an outer wall material coated with a core liquid;
图2为内外双层芯材注射针筒壁材包覆芯液的烟用爆珠制备示意图；FIG2 is a schematic diagram of the preparation of a cigarette-use explosive bead with an inner and outer double-layer core material injection syringe wall material coated with a core liquid;
其中，1-芯材注射针筒，2-壁材注射针筒，3-注射泵，4-同轴双层滴头，5-内芯输送通道，6-外壁输送通道，7-保护液，8-筛网，9-熔融的外层胶液Among them, 1-core material injection syringe, 2-wall material injection syringe, 3-injection pump, 4-coaxial double-layer dripper, 5-inner core delivery channel, 6-outer wall delivery channel, 7-protective liquid, 8-screen, 9-molten outer layer glue
具体实施方式DETAILED DESCRIPTION
为更好地说明本发明的目的、技术方案和优点，下面将结合具体实施例对本发明作进一步说明。本领域技术人员应当理解，此处所描述的具体实施例仅用以解释本发明，并不用于限定本发明。To better illustrate the purpose, technical solutions and advantages of the present invention, the present invention will be further described below in conjunction with specific embodiments. It should be understood by those skilled in the art that the specific embodiments described herein are only used to explain the present invention and are not intended to limit the present invention.
实施例中所用的试验方法如无特殊说明，均为常规方法；所用的材料、试剂等，如无特殊说明，均可从商业途径得到。下述“份”均为重量份数。Unless otherwise specified, the test methods used in the examples are all conventional methods; the materials and reagents used are all commercially available unless otherwise specified. The following "parts" are all parts by weight.
实施例1Example 1
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂160份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)2.5份、增稠剂(海藻酸钠)2.5份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 160 parts of rosin resin; the core liquid comprises 100 parts of water, 5 parts of a water-soluble flavor (Zimbabwe extract), 2.5 parts of a preservative (kathion), and 2.5 parts of a thickener (sodium alginate).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液；1) mixing water, water-soluble flavor, preservative and thickener according to a formula to obtain a core liquid;
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到120℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 120° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)如图1外层壁材包覆芯液的烟用爆珠制备示意图所示，图1所示的滴丸机，包括芯材注射针筒1、壁材注射针筒2、同轴双层滴头4；所述同轴双层滴头4内设有内芯输送通道5和外壁输送通道6，所述芯材注射针筒1通过所述注射泵3连通所述内芯输送通道5，所述壁材注射针筒2通过所述注射泵3连通所述外壁输送通道6，所述同轴双层滴头4下方设有盛装有保护液7的结构。将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在120℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in the schematic diagram of preparing the tobacco-use explosive beads with the core liquid coated by the outer wall material in FIG1, the pill machine shown in FIG1 comprises a core material injection syringe 1, a wall material injection syringe 2, and a coaxial double-layer dripper 4; the coaxial double-layer dripper 4 is provided with an inner core delivery channel 5 and an outer wall delivery channel 6, the core material injection syringe 1 is connected to the inner core delivery channel 5 through the injection pump 3, the wall material injection syringe 2 is connected to the outer wall delivery channel 6 through the injection pump 3, and a structure containing a protective liquid 7 is provided below the coaxial double-layer dripper 4. The core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively delivered into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 120°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue liquid form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the molten wall material glue liquid. The droplets drip into the 25°C protective liquid (dimethyl silicone oil) under their own gravity to cool, forming popping beads with a certain hardness. After separation and washing by a sieve, the popping beads for cigarettes coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝2.2：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 2.2:1.
所得到包覆水溶性香精的烟用爆珠的重量为60.7mg，直径为4.5mm，抗碎强度为15.2N，6个月失水率<5.0％。The obtained tobacco explosive beads coated with water-soluble flavors have a weight of 60.7 mg, a diameter of 4.5 mm, a crushing strength of 15.2 N, and a water loss rate of <5.0% in 6 months.
实施例2Example 2
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂100份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)4.75份、增稠剂(卡波姆)0.25份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 100 parts of rosin resin; the core liquid comprises 100 parts of water, 5 parts of a water-soluble flavor (Zimbabwe extract), 4.75 parts of a preservative (Carbomer), and 0.25 parts of a thickener (Carbomer).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到140℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 140° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在140℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively delivered into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 140°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue outside. Under the action of their own gravity, the droplets are dripped into a protective liquid (dimethyl silicone oil) at 25°C to cool, forming popping beads with a certain hardness. After separation and washing by a sieve, the popping beads for tobacco coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝2：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 2:1.
所得到包覆水溶性香精的烟用爆珠的重量为80.4mg，直径为5.5mm，抗碎强度为20.4N，6个月失水率<4.5％。The obtained tobacco explosive beads coated with water-soluble flavors have a weight of 80.4 mg, a diameter of 5.5 mm, a crushing strength of 20.4 N, and a water loss rate of <4.5% in 6 months.
实施例3Example 3
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂120份；所述芯液包括水100份、水溶性香精(小茴香油与广藿香油混合物)20份、防腐剂(卡松)4.75份、增稠剂(卡波姆)0.25份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 120 parts of rosin resin; the core liquid comprises 100 parts of water, 20 parts of a water-soluble flavor (a mixture of fennel oil and patchouli oil), 4.75 parts of a preservative (carbomer), and 0.25 parts of a thickener (carbomer).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到100℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 100° C. under stirring conditions, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在100℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 100°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue outside. Under the action of their own gravity, the droplets are dripped into a protective liquid (dimethyl silicone oil) at 25°C to cool, forming bursting bead particles with a certain hardness. After separation and washing by a sieve, the bursting beads for tobacco coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝2：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 2:1.
所得到包覆水溶性香精的烟用爆珠的重量为70.5mg，直径为5.3mm，抗碎强度为22.3N，6个月失水率<4.0％。The obtained tobacco explosive beads coated with water-soluble flavors have a weight of 70.5 mg, a diameter of 5.3 mm, a crushing strength of 22.3 N, and a water loss rate of <4.0% in 6 months.
实施例4Example 4
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括巴西棕榈蜡100份和氢化松香树脂80份；所述芯液包括水100份、水溶性香精(烟草提取物)100份、防腐剂(卡松)2.5份、消泡剂(磷酸三丁酯)2.5份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of carnauba wax and 80 parts of hydrogenated rosin resin; the core liquid comprises 100 parts of water, 100 parts of water-soluble flavor (tobacco extract), 2.5 parts of a preservative (kathon), and 2.5 parts of a defoaming agent (tributyl phosphate).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、消泡剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and defoamer according to the formula to obtain core liquid.
2)将巴西棕榈蜡、氢化松香树脂按照配方比例混合均匀，搅拌条件下加热到80℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) The carnauba wax and hydrogenated rosin resin are uniformly mixed according to the formula ratio, heated to 80° C. under stirring conditions, and melted to obtain an outer wall material glue; then the outer wall material glue is repeatedly vacuumed to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在80℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 80°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue outside. Under the action of their own gravity, the droplets are dripped into a protective liquid (dimethyl silicone oil) at 25°C to cool, forming bursting beads with a certain hardness. After separation and washing by a sieve, the bursting beads for tobacco coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝1.8：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 1.8:1.
所得到包覆水溶性香精的烟用爆珠的重量为55.8mg，直径为4.3mm，抗碎强度为9.8N，6个月失水率<4.7％。The obtained tobacco explosive beads coated with water-soluble flavors have a weight of 55.8 mg, a diameter of 4.3 mm, a crushing strength of 9.8 N, and a water loss rate of <4.7% in 6 months.
实施例5Example 5
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括固体石蜡100份和甘油松香树脂50份；所述芯液包括水100份、水溶性香精(迷迭香油和紫罗兰酮的混合物)50份、防腐剂(山梨酸钾)2.5份、稳定剂(山梨醇)2.5份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of solid paraffin and 50 parts of glycerol rosin resin; the core liquid comprises 100 parts of water, 50 parts of a water-soluble flavor (a mixture of rosemary oil and ionone), 2.5 parts of a preservative (potassium sorbate), and 2.5 parts of a stabilizer (sorbitol).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、稳定剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and stabilizer according to the formula to obtain core liquid.
2)将固体石蜡、甘油松香树脂按照配方比例混合均匀，搅拌条件下加热到130℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Mix solid paraffin and glycerin rosin resin evenly according to the formula ratio, heat to 130° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在130℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 130°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue on the outer layer. Under the action of their own gravity, the droplets are dripped into a protective liquid (dimethyl silicone oil) at 25°C to cool, forming popping beads with a certain hardness. After separation and washing by a sieve, the popping beads for tobacco coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝1.6：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 1.6:1.
所得到包覆水溶性香精的烟用爆珠的重量为80.5mg，直径为6.3mm，抗碎强度为21.3N，6个月失水率<5.5％。The obtained tobacco explosive beads coated with water-soluble flavors have a weight of 80.5 mg, a diameter of 6.3 mm, a crushing strength of 21.3 N, and a water loss rate of <5.5% in 6 months.
实施例6Example 6
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括虫蜡100份和松香甲脂200份；所述芯液包括水100份、水溶性香精(烟草提取物和津巴布韦烟提取物的混合物)20份、增稠剂(海藻酸钠)1份、稳定剂(山梨醇)4份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of insect wax and 200 parts of rosin methyl ester; the core liquid comprises 100 parts of water, 20 parts of a water-soluble flavor (a mixture of tobacco extract and Zimbabwe tobacco extract), 1 part of a thickener (sodium alginate), and 4 parts of a stabilizer (sorbitol).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、增稠剂、稳定剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, thickener and stabilizer according to the formula to obtain core liquid.
2)将虫蜡、松香甲脂按照配方比例混合均匀，搅拌条件下加热到110℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the insect wax and rosin methyl ester according to the formula ratio, heat to 110° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在110℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively delivered into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 110°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue on the outer layer. Under the action of their own gravity, the droplets are dripped into a protective liquid (dimethyl silicone oil) at 25°C to cool, forming bursting bead particles with a certain hardness. After separation and washing through a sieve, the tobacco bursting beads coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝1.4：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 1.4:1.
所得到包覆水溶性香精的烟用爆珠的重量为61.2mg，直径为4.2mm，抗碎强度为9.2N，6个月失水率<6.2％。The obtained tobacco explosive beads coated with water-soluble flavors have a weight of 61.2 mg, a diameter of 4.2 mm, a crushing strength of 9.2 N, and a water loss rate of <6.2% in 6 months.
实施例7Example 7
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括巴西棕榈蜡100份和松香乙烯醇酯200份；所述芯液包括水100份、水溶性香精(烟草提取物)40份、防腐剂(苯氧乙醇)0.2份、消泡剂(磷酸三丁酯)0.3份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of carnauba wax and 200 parts of rosin vinyl alcohol ester; the core liquid comprises 100 parts of water, 40 parts of a water-soluble flavor (tobacco extract), 0.2 parts of a preservative (phenoxyethanol), and 0.3 parts of a defoaming agent (tributyl phosphate).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、消泡剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and defoamer according to the formula to obtain core liquid.
2)将巴西棕榈蜡、松香乙烯醇酯按照配方比例混合均匀，搅拌条件下加热到90℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Carnauba wax and rosin vinyl alcohol ester are uniformly mixed according to a formula ratio, heated to 90° C. under stirring conditions, and melted to obtain an outer wall material glue; then the outer wall material glue is repeatedly vacuumed to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在90℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively delivered into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 90°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue on the outer layer. Under the action of their own gravity, the droplets are dripped into a protective liquid (dimethyl silicone oil) at 25°C to cool, forming bursting bead particles with a certain hardness. After separation and washing through a sieve, the bursting beads for tobacco coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝1.2：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 1.2:1.
所得到包覆水溶性香精的烟用爆珠的重量为64.3mg，直径为3.8mm，抗碎强度为7.2N，6个月失水率<6.5％。The obtained tobacco explosive beads coated with water-soluble flavor have a weight of 64.3 mg, a diameter of 3.8 mm, a crushing strength of 7.2 N, and a water loss rate of <6.5% in 6 months.
实施例8Example 8
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括虫蜡100份和松香改性酚醛树脂180份；所述芯液包括水100份、水溶性香精(津巴布韦烟提取物)15份、稳定剂(山梨醇)0.4份、消泡剂(磷酸三丁酯)0.1份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of insect wax and 180 parts of rosin-modified phenolic resin; the core liquid comprises 100 parts of water, 15 parts of a water-soluble flavor (Zimbabwe tobacco extract), 0.4 parts of a stabilizer (sorbitol), and 0.1 parts of a defoaming agent (tributyl phosphate).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、稳定剂、消泡剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, stabilizer and defoamer according to the formula to obtain core liquid.
2)将虫蜡、松香改性酚醛树脂按照配方比例混合均匀，搅拌条件下加热到105℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) The insect wax and rosin-modified phenolic resin are uniformly mixed according to the formula ratio, heated to 105° C. under stirring conditions, and melted to obtain an outer wall material glue solution; then the outer wall material glue solution is repeatedly vacuumed to remove bubbles in the glue solution.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在105℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 105°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue on the outer layer. Under the action of their own gravity, the droplets are dripped into a protective liquid (dimethyl silicone oil) at 25°C to cool, forming popping beads with a certain hardness. After separation and washing by a sieve, the popping beads for tobacco coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝1.5：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 1.5:1.
所得到包覆水溶性香精的烟用爆珠的重量为70.2mg，直径为6.7mm，抗碎强度为18.4N，6个月失水率<5.7％。The obtained tobacco explosive beads coated with water-soluble flavors have a weight of 70.2 mg, a diameter of 6.7 mm, a crushing strength of 18.4 N, and a water loss rate of <5.7% in 6 months.
实施例9Example 9
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜂蜡100份和顺丁烯二酸酐松香树脂160份；所述芯液包括水100份、水溶性香精(小茴香油与广藿香油混合物)25份、杀菌剂(苯氧乙醇)2.5份、消泡剂(磷酸三丁酯)2.5份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 160 parts of maleic anhydride rosin resin; the core liquid comprises 100 parts of water, 25 parts of a water-soluble flavor (a mixture of fennel oil and patchouli oil), 2.5 parts of a bactericide (phenoxyethanol), and 2.5 parts of a defoaming agent (tributyl phosphate).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、杀菌剂、消泡剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, bactericide and defoamer according to the formula to obtain core liquid.
2)将蜂蜡、顺丁烯二酸酐松香树脂按照配方比例混合均匀，搅拌条件下加热到115℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) beeswax and maleic anhydride rosin resin are uniformly mixed according to a formula ratio, heated to 115° C. under stirring conditions, and melted to obtain an outer wall material glue; then the outer wall material glue is repeatedly vacuumed to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液在25℃下由同轴双层针头内层孔径流出，熔融壁材胶液在115℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入25℃的保护液(二甲基硅油)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively delivered into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle at 115°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue on the outer layer. Under the action of their own gravity, the droplets are dripped into a protective liquid (dimethyl silicone oil) at 25°C to cool, forming popping beads with a certain hardness. After separation and washing by a sieve, the popping beads for tobacco coated with water-soluble flavors can be obtained.
其中：外层壁材胶液流速：内层芯液流速＝1.7：1。Among them: the flow rate of the outer wall material glue: the flow rate of the inner core liquid = 1.7:1.
所得到包覆水溶性香精的烟用爆珠的重量为51.3mg，直径为3.6mm，抗碎强度为21.7N，6个月失水率<5.5％。The obtained tobacco explosive beads coated with water-soluble flavors have a weight of 51.3 mg, a diameter of 3.6 mm, a crushing strength of 21.7 N, and a water loss rate of <5.5% in 6 months.
对比例1Comparative Example 1
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂160份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)2.5份、增稠剂(海藻酸钠)2.5份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 160 parts of rosin resin; the core liquid comprises 100 parts of water, 5 parts of a water-soluble flavor (Zimbabwe extract), 2.5 parts of a preservative (kathion), and 2.5 parts of a thickener (sodium alginate).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到150℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) beeswax and rosin resin are mixed evenly according to a formula ratio, heated to 150° C. under stirring conditions, and melted to obtain an outer wall material glue liquid; then the outer wall material glue liquid is repeatedly vacuumed to remove bubbles in the glue liquid.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液由同轴双层针头内层孔径流出，熔融壁材胶液由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为熔融的壁材胶液。液滴在自身重力作用下滴入保护液中冷却，但是无论如何调整壁材胶液和内层芯液之间的流速比，均不能形成具有一定硬度且具备同心结构的爆珠颗粒。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively delivered into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle. After the two solutions flow out from the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, with the core liquid inside the droplets and the molten wall material glue on the outer layer. The droplets drip into the protective liquid under the action of their own gravity to cool, but no matter how the flow rate ratio between the wall material glue and the inner core liquid is adjusted, it is impossible to form explosive bead particles with a certain hardness and a concentric structure.
对比例2Comparative Example 2
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂300份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)2.5份、增稠剂(海藻酸钠)2.5份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 300 parts of rosin resin; the core liquid comprises 100 parts of water, 5 parts of a water-soluble flavor (Zimbabwe extract), 2.5 parts of a preservative (kathion), and 2.5 parts of a thickener (sodium alginate).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到120℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 120° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液由同轴双层针头内层孔径流出，熔融壁材胶液由同轴双层针头外层孔径流出。壁材胶液中松香树脂含量过高，一方面导致壁材胶液黏度过高，胶液极难从外层孔径流出，另一方面胶液固化后所形成爆珠小球硬度较高，抗碎强度为40N，极难用手捏破。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively fed into the dripping hole of the coaxial double-layer needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle. The high content of rosin resin in the wall material glue leads to high viscosity of the wall material glue, which makes it very difficult for the glue to flow out from the outer aperture. On the other hand, the hardness of the beads formed after the glue solidifies is relatively high, with a crushing strength of 40N, which is very difficult to break by hand.
对比例3Comparative Example 3
一种包覆水溶性香精的烟用爆珠，所述烟用爆珠设有皮芯结构，所述皮芯结构包括外层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂160份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)2.5份、增稠剂(海藻酸钠)2.5份。A tobacco popping bead coated with a water-soluble flavor, the tobacco popping bead is provided with a skin-core structure, the skin-core structure comprises an outer wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 160 parts of rosin resin; the core liquid comprises 100 parts of water, 5 parts of a water-soluble flavor (Zimbabwe extract), 2.5 parts of a preservative (kathion), and 2.5 parts of a thickener (sodium alginate).
上述包覆水溶性香精的烟用爆珠的制备方法为：The preparation method of the above-mentioned tobacco popping beads coated with water-soluble flavor is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到120℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 120° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)如图1所示，将步骤1)配制好的芯液和步骤2)熔融的外层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中；其中，芯液由同轴双层针头内层孔径流出，熔融壁材胶液由同轴双层针头外层孔径流出。外层壁材胶液流速：内层芯液流速＝3：1。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液不能形成同心球形液滴，或形成偏心结构的球形液体。液滴内部为芯液，外层为熔融的壁材胶液。3) As shown in Figure 1, the core liquid prepared in step 1) and the molten outer wall material glue in step 2) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump; wherein, the core liquid flows out from the inner aperture of the coaxial double-layer needle, and the molten wall material glue flows out from the outer aperture of the coaxial double-layer needle. The flow rate of the outer wall material glue: the flow rate of the inner core liquid = 3:1. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue cannot form concentric spherical droplets, or form spherical liquids with eccentric structures. The inside of the droplet is the core liquid, and the outer layer is the molten wall material glue.
更优选地，具有内外双层壁材结构包覆水溶性香精爆珠的实施例和对比例如下：More preferably, the embodiments and comparative examples of the water-soluble flavor bursting beads coated with inner and outer double-layer wall material structures are as follows:
实施例10Example 10
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂160份；所述内层壁材包括海藻酸钠10份、明胶20份、水70份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)2.5份、增稠剂(海藻酸钠)2.5份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprises a double-layer skin-core structure, the double-layer skin-core structure comprises an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 160 parts of rosin resin; the inner wall material comprises 10 parts of sodium alginate, 20 parts of gelatin and 70 parts of water; the core liquid comprises 100 parts of water, 5 parts of water-soluble flavor (Zimbabwe extract), 2.5 parts of preservative (kathion) and 2.5 parts of thickener (sodium alginate).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到120℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 120° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)将海藻酸钠与明胶按照配方比例混合均匀，搅拌条件下加热到65℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and gelatin according to the formula ratio, heat to 65° C. under stirring, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2内外双层壁材包覆芯液的烟用爆珠制备示意图所示，图2所示的滴丸机，包括芯材注射针筒1、壁材注射针筒2、同轴双层滴头4；同轴双层滴头4内设有内芯输送通道5和外壁输送通道6，芯材注射针筒1通过注射泵3连通内芯输送通道5，壁材注射针筒2通过注射泵3连通外壁输送通道6，所述同轴双层滴头4下方设有盛装保护液7的结构。在盛装保护液7的结构下方设有上层为筛网8，下层为熔融的外层胶液9的结构。将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在65℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数10％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝2.2：1。4) As shown in the schematic diagram of preparing the explosive beads for cigarettes with inner and outer double-layer wall materials coated with the core liquid in FIG2, the pill machine shown in FIG2 comprises a core material injection syringe 1, a wall material injection syringe 2, and a coaxial double-layer dripper 4; the coaxial double-layer dripper 4 is provided with an inner core delivery channel 5 and an outer wall delivery channel 6, the core material injection syringe 1 is connected to the inner core delivery channel 5 through an injection pump 3, and the wall material injection syringe 2 is connected to the outer wall delivery channel 6 through an injection pump 3, and a structure for containing the protective liquid 7 is provided below the coaxial double-layer dripper 4. Below the structure for containing the protective liquid 7, a structure is provided with a screen 8 on the upper layer and a molten outer layer glue 9 on the lower layer. The core liquid prepared in step 1) and the inner layer wall material glue in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner layer aperture of the coaxial double-layer needle at 25°C, and the inner layer wall material glue flows out from the outer layer aperture of the coaxial double-layer needle at 65°C. After the two solutions flow out from the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue liquid form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue liquid. The droplets drip into the 25°C protective liquid (a 10% calcium chloride aqueous solution by mass) under the action of their own gravity to cool, forming bursting bead particles with a certain hardness. After separation and washing by a sieve, the inner layer structure of the tobacco bursting bead coated with water-soluble flavors can be obtained. Among them: the wall material glue liquid flow rate: the inner layer core liquid flow rate = 2.2:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为60.3mg，直径为4.5mm，抗碎强度为15.2N，6个月失水率<4.2％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 60.3 mg, a diameter of 4.5 mm, a crushing strength of 15.2 N, and a water loss rate of <4.2% in 6 months.
实施例11Embodiment 11
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂100份；所述内层壁材包括海藻酸钠10份、卡拉胶20份、水70份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)4.75份、增稠剂(卡波姆)0.25份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprises a double-layer skin-core structure, the double-layer skin-core structure comprises an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 100 parts of rosin resin; the inner wall material comprises 10 parts of sodium alginate, 20 parts of carrageenan and 70 parts of water; the core liquid comprises 100 parts of water, 5 parts of water-soluble flavor (Zimbabwe extract), 4.75 parts of preservative (carbomer) and 0.25 parts of thickener (carbomer).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到140℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 140° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到70℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 70° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在70℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数15％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝2：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 70°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets are dripped into a 25°C protective liquid (a calcium chloride aqueous solution with a mass fraction of 15%) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 2:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为50.9mg，直径为3.7mm，抗碎强度为10.7N，6个月失水率<3.7％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 50.9 mg, a diameter of 3.7 mm, a crushing strength of 10.7 N, and a water loss rate of <3.7% in 6 months.
实施例12Example 12
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂120份；所述内层壁材包括明胶10份、卡拉胶10份、水80份；所述芯液包括水100份、水溶性香精(小茴香油与广藿香油混合物)20份、防腐剂(卡松)4.75份、增稠剂(卡波姆)0.25份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprising a double-layer skin-core structure, the double-layer skin-core structure comprising an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 120 parts of rosin resin; the inner wall material comprises 10 parts of gelatin, 10 parts of carrageenan and 80 parts of water; the core liquid comprises 100 parts of water, 20 parts of water-soluble flavoring (a mixture of fennel oil and patchouli oil), 4.75 parts of a preservative (carbomer) and 0.25 parts of a thickener (carbomer).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到100℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 100° C. under stirring conditions, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)将明胶与卡拉胶按照配方比例混合均匀，搅拌条件下加热到70℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) The gelatin and carrageenan are uniformly mixed according to the formula ratio, heated to 70° C. under stirring conditions, and dissolved to obtain an inner wall material glue solution; then the inner wall material glue solution is repeatedly vacuumed to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在70℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数30％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝2：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 70°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets are dripped into a 25°C protective liquid (a calcium chloride aqueous solution with a mass fraction of 30%) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 2:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为70.3mg，直径为3.8mm，抗碎强度为13.6N，6个月失水率<4.5％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 70.3 mg, a diameter of 3.8 mm, a crushing strength of 13.6 N, and a water loss rate of <4.5% in 6 months.
实施例13Embodiment 13
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括巴西棕榈蜡100份和氢化松香树脂80份；所述内层壁材包括明胶20份、水80份；所述芯液包括水100份、水溶性香精(烟草提取物)100份、防腐剂(卡松)2.5份、消泡剂(磷酸三丁酯)2.5份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprises a double-layer skin-core structure, the double-layer skin-core structure comprises an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of carnauba wax and 80 parts of hydrogenated rosin resin; the inner wall material comprises 20 parts of gelatin and 80 parts of water; the core liquid comprises 100 parts of water, 100 parts of water-soluble flavor (tobacco extract), 2.5 parts of preservative (kathion), and 2.5 parts of defoaming agent (tributyl phosphate).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、消泡剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and defoamer according to the formula to obtain core liquid.
2)将巴西棕榈蜡、氢化松香树脂按照配方比例混合均匀，搅拌条件下加热到80℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) The carnauba wax and hydrogenated rosin resin are uniformly mixed according to the formula ratio, heated to 80° C. under stirring conditions, and melted to obtain an outer wall material glue; then the outer wall material glue is repeatedly vacuumed to remove bubbles in the glue.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到70℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 70° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在70℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数15％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.8：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 70°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets are dripped into a 25°C protective liquid (a calcium chloride aqueous solution with a mass fraction of 15%) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.8:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为60.3mg，直径为4.3mm，抗碎强度为15.4N，6个月失水率<4.5％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 60.3 mg, a diameter of 4.3 mm, a crushing strength of 15.4 N, and a water loss rate of <4.5% in 6 months.
实施例14Embodiment 14
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括固体石蜡100份和甘油松香树脂50份；所述内层壁材包括海藻酸钠20份、水80份；所述芯液包括水100份、水溶性香精(迷迭香油和紫罗兰酮的混合物)50份、防腐剂(山梨酸钾)2.5份、稳定剂(山梨醇)2.5份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprising a double-layer skin-core structure, the double-layer skin-core structure comprising an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of solid paraffin and 50 parts of glycerol rosin resin; the inner wall material comprises 20 parts of sodium alginate and 80 parts of water; the core liquid comprises 100 parts of water, 50 parts of water-soluble flavoring (a mixture of rosemary oil and ionone), 2.5 parts of a preservative (potassium sorbate) and 2.5 parts of a stabilizer (sorbitol).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、稳定剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and stabilizer according to the formula to obtain core liquid.
2)将固体石蜡、甘油松香树脂按照配方比例混合均匀，搅拌条件下加热到130℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Mix solid paraffin and glycerin rosin resin evenly according to the formula ratio, heat to 130° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到70℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 70° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在70℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数20％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.6：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 70°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets drip into a 25°C protective liquid (a calcium chloride aqueous solution with a mass fraction of 20%) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.6:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为70.5mg，直径为4.3mm，抗碎强度为13.2N，6个月失水率<4.2％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 70.5 mg, a diameter of 4.3 mm, a crushing strength of 13.2 N, and a water loss rate of <4.2% in 6 months.
实施例15Embodiment 15
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括虫蜡100份和松香甲脂200份；所述内层壁材包括卡拉胶10份、水90份；所述芯液包括水100份、水溶性香精(烟草提取物和津巴布韦烟提取物的混合物)20份、增稠剂(海藻酸钠)1份、稳定剂(山梨醇)4份。A water-soluble flavor popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprising a double-layer skin-core structure, the double-layer skin-core structure comprising an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of insect wax and 200 parts of rosin methyl ester; the inner wall material comprises 10 parts of carrageenan and 90 parts of water; the core liquid comprises 100 parts of water, 20 parts of water-soluble flavor (a mixture of tobacco extract and Zimbabwe tobacco extract), 1 part of thickener (sodium alginate) and 4 parts of stabilizer (sorbitol).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、增稠剂、稳定剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, thickener and stabilizer according to the formula to obtain core liquid.
2)将虫蜡、松香甲脂按照配方比例混合均匀，搅拌条件下加热到110℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the insect wax and rosin methyl ester according to the formula ratio, heat to 110° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到70℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 70° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在70℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数20％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.4：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 70°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets drip into a 25°C protective liquid (a calcium chloride aqueous solution with a mass fraction of 20%) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.4:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为55.4mg，直径为4.3mm，抗碎强度为12.8N，6个月失水率<4.5％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 55.4 mg, a diameter of 4.3 mm, a crushing strength of 12.8 N, and a water loss rate of <4.5% in 6 months.
实施例16Example 16
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括巴西棕榈蜡100份和松香乙烯醇酯200份；所述内层壁材包括明胶15份、卡拉胶5份、水80份；所述芯液包括水100份、水溶性香精(烟草提取物)40份、防腐剂(苯氧乙醇)0.2份、消泡剂(磷酸三丁酯)0.3份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprising a double-layer skin-core structure, the double-layer skin-core structure comprising an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of carnauba wax and 200 parts of rosin vinyl alcohol ester; the inner wall material comprises 15 parts of gelatin, 5 parts of carrageenan and 80 parts of water; the core liquid comprises 100 parts of water, 40 parts of water-soluble flavor (tobacco extract), 0.2 parts of preservative (phenoxyethanol) and 0.3 parts of defoaming agent (tributyl phosphate).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、消泡剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and defoamer according to the formula to obtain core liquid.
2)将巴西棕榈蜡、松香乙烯醇酯按照配方比例混合均匀，搅拌条件下加热到90℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Carnauba wax and rosin vinyl alcohol ester are uniformly mixed according to a formula ratio, heated to 90° C. under stirring conditions, and melted to obtain an outer wall material glue; then the outer wall material glue is repeatedly vacuumed to remove bubbles in the glue.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到75℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 75° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在75℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数10％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.2：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 75°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets drip into a 25°C protective liquid (a 10% calcium chloride aqueous solution) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.2:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为90.2mg，直径为6.2mm，抗碎强度为15.8N，6个月失水率<4.5％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 90.2 mg, a diameter of 6.2 mm, a crushing strength of 15.8 N, and a water loss rate of <4.5% in 6 months.
实施例17Embodiment 17
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括虫蜡100份和松香改性酚醛树脂180份；所述内层壁材包括明胶15份、水85份；所述芯液包括水100份、水溶性香精(津巴布韦烟提取物)15份、稳定剂(山梨醇)0.4份、消泡剂(磷酸三丁酯)0.1份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprising a double-layer skin-core structure, the double-layer skin-core structure comprising an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of insect wax and 180 parts of rosin-modified phenolic resin; the inner wall material comprises 15 parts of gelatin and 85 parts of water; the core liquid comprises 100 parts of water, 15 parts of water-soluble flavor (Zimbabwe tobacco extract), 0.4 parts of a stabilizer (sorbitol) and 0.1 parts of a defoaming agent (tributyl phosphate).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、稳定剂、消泡剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, stabilizer and defoamer according to the formula to obtain core liquid.
2)将虫蜡、松香改性酚醛树脂按照配方比例混合均匀，搅拌条件下加热到105℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) The insect wax and rosin-modified phenolic resin are uniformly mixed according to the formula ratio, heated to 105° C. under stirring conditions, and melted to obtain an outer wall material glue solution; then the outer wall material glue solution is repeatedly vacuumed to remove bubbles in the glue solution.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到75℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 75° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在75℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数5％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.5：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 75°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. The droplets drip into a 25°C protective liquid (a 5% calcium chloride aqueous solution by mass) under the action of their own gravity to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.5:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为60.2mg，直径为3.9mm，抗碎强度为10.6N，6个月失水率<4.0％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 60.2 mg, a diameter of 3.9 mm, a crushing strength of 10.6 N, and a water loss rate of <4.0% in 6 months.
实施例18Embodiment 18
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括蜂蜡100份和顺丁烯二酸酐松香树脂160份；所述内层壁材包括明胶20份、海藻酸钠5份、水75份；所述芯液包括水100份、水溶性香精(小茴香油与广藿香油混合物)25份、杀菌剂(苯氧乙醇)2.5份、消泡剂(磷酸三丁酯)2.5份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprises a double-layer skin-core structure, the double-layer skin-core structure comprises an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 160 parts of maleic anhydride rosin resin; the inner wall material comprises 20 parts of gelatin, 5 parts of sodium alginate and 75 parts of water; the core liquid comprises 100 parts of water, 25 parts of water-soluble flavoring (a mixture of fennel oil and patchouli oil), 2.5 parts of a bactericide (phenoxyethanol) and 2.5 parts of a defoaming agent (tributyl phosphate).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、杀菌剂、消泡剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, bactericide and defoamer according to the formula to obtain core liquid.
2)将蜂蜡、顺丁烯二酸酐松香树脂按照配方比例混合均匀，搅拌条件下加热到115℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) beeswax and maleic anhydride rosin resin are uniformly mixed according to a formula ratio, heated to 115° C. under stirring conditions, and melted to obtain an outer wall material glue; then the outer wall material glue is repeatedly vacuumed to remove bubbles in the glue.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到75℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 75° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在75℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数10％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.7：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 75°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets are dripped into a 25°C protective liquid (a calcium chloride aqueous solution with a mass fraction of 10%) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.7:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors.
所得到内外双层壁材包覆水溶性香精的烟用爆珠的重量为70.3mg，直径为3.8mm，抗碎强度为12.9N，6个月失水率<4.0％。The obtained tobacco explosive beads with inner and outer double-layer wall materials coated with water-soluble flavors have a weight of 70.3 mg, a diameter of 3.8 mm, a crushing strength of 12.9 N, and a water loss rate of <4.0% in 6 months.
对比例4Comparative Example 4
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂160份；所述内层壁材包括明胶20份、海藻酸钠5份、水75份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)2.5份、增稠剂(海藻酸钠)2.5份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprises a double-layer skin-core structure, the double-layer skin-core structure comprises an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 160 parts of rosin resin; the inner wall material comprises 20 parts of gelatin, 5 parts of sodium alginate and 75 parts of water; the core liquid comprises 100 parts of water, 5 parts of water-soluble flavoring (Zimbabwe extract), 2.5 parts of preservative (kathion) and 2.5 parts of thickener (sodium alginate).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到150℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) beeswax and rosin resin are mixed evenly according to a formula ratio, heated to 150° C. under stirring conditions, and melted to obtain an outer wall material glue liquid; then the outer wall material glue liquid is repeatedly vacuumed to remove bubbles in the glue liquid.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到75℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 75° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在75℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数10％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.7：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 75°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets are dripped into a 25°C protective liquid (a calcium chloride aqueous solution with a mass fraction of 10%) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.7:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，无论烟用爆珠内层结构在外层胶液中停留多长时间，取出室温冷却后均不能得到具有一定硬度且具备同心结构的爆珠颗粒。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2). No matter how long the inner layer structure of the tobacco popping beads stays in the outer layer glue solution, after being taken out and cooled at room temperature, popping beads particles with a certain hardness and a concentric structure cannot be obtained.
对比例5Comparative Example 5
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂300份；所述内层壁材包括明胶15份、水85份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)2.5份、增稠剂(海藻酸钠)2.5份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprises a double-layer skin-core structure, the double-layer skin-core structure comprises an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 300 parts of rosin resin; the inner wall material comprises 15 parts of gelatin and 85 parts of water; the core liquid comprises 100 parts of water, 5 parts of water-soluble flavor (Zimbabwe extract), 2.5 parts of preservative (kathion) and 2.5 parts of thickener (sodium alginate).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到120℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 120° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到75℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 75° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在75℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数5％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.5：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 75°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets drip into a 25°C protective liquid (a 5% calcium chloride aqueous solution) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.5:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠。由于壁材胶液中松香树脂含量过高，一方面导致壁材胶液黏度过高，另一方面使胶液固化后所形成爆珠小球硬度较高，抗碎强度为45N，极难用手捏破。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue prepared in step 2), and after staying for 2-5 seconds, it is taken out and cooled at room temperature to obtain the tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors. Due to the high content of rosin resin in the wall material glue, on the one hand, the viscosity of the wall material glue is too high, and on the other hand, the hardness of the popping beads formed after the glue is solidified is relatively high, and the crushing strength is 45N, which is extremely difficult to be broken by hand.
对比例6Comparative Example 6
一种内外双层壁材包覆水溶性香精爆珠，所述烟用爆珠包括双层皮芯结构，所述双层皮芯结构包括外层壁材、内层壁材和芯液；所述外层壁材包括蜂蜡100份和松香树脂40份；所述内层壁材包括海藻酸钠20份、水80份；所述芯液包括水100份、水溶性香精(津巴布韦提取物)5份、防腐剂(卡松)2.5份、增稠剂(海藻酸钠)2.5份。A water-soluble flavoring popping bead coated with inner and outer double-layer wall materials, the popping bead for tobacco comprises a double-layer skin-core structure, the double-layer skin-core structure comprises an outer wall material, an inner wall material and a core liquid; the outer wall material comprises 100 parts of beeswax and 40 parts of rosin resin; the inner wall material comprises 20 parts of sodium alginate and 80 parts of water; the core liquid comprises 100 parts of water, 5 parts of water-soluble flavor (Zimbabwe extract), 2.5 parts of preservative (kathion) and 2.5 parts of thickener (sodium alginate).
上述内外双层壁材包覆水溶性香精爆珠的制备方法为：The preparation method of the water-soluble essence bursting beads coated with the inner and outer double-layer wall materials is as follows:
1)将水、水溶性香精、防腐剂、增稠剂按照配方混合均匀得到芯液。1) Mix water, water-soluble flavor, preservative and thickener according to the formula to obtain core liquid.
2)将蜂蜡、松香树脂按照配方比例混合均匀，搅拌条件下加热到120℃，熔融得到外层壁材胶液；然后对外层壁材胶液进行反复抽真空，去除胶液中气泡。2) Evenly mix the beeswax and rosin resin according to the formula ratio, heat to 120° C. under stirring, and melt to obtain the outer wall material glue; then repeatedly evacuate the outer wall material glue to remove bubbles in the glue.
3)将海藻酸钠与卡拉胶按照配方比例混合均匀，搅拌条件下加热到70℃，溶解得到内层壁材胶液；然后对内层壁材胶液进行反复抽真空，去除胶液中的气泡。3) Evenly mix sodium alginate and carrageenan according to the formula ratio, heat to 70° C. under stirring conditions, and dissolve to obtain an inner wall material glue solution; then repeatedly evacuate the inner wall material glue solution to remove bubbles in the glue solution.
4)如图2所示，将步骤1)配制好的芯液和步骤3)的内层壁材胶液分别通过计量泵送入同轴双层共针头的滴孔中，其中芯液在25℃下由同轴双层针头内层孔径流出，内层壁材胶液在70℃下由同轴双层针头外层孔径流出。两种溶液在针头处流出后，在表面张力作用下，滴出的芯液液滴和滴出的壁材胶液形成同心球形液滴，液滴内部为芯液，外层为壁材胶液。液滴在自身重力作用下滴入25℃的保护液(质量分数20％的氯化钙水溶液)中冷却，形成具有一定硬度的爆珠颗粒，经筛网分离并洗涤后即可得到包覆水溶性香精的烟用爆珠内层结构。其中：壁材胶液流速：内层芯液流速＝1.6：1。4) As shown in FIG. 2, the core liquid prepared in step 1) and the inner wall material glue prepared in step 3) are respectively fed into the dripping hole of the coaxial double-layer common needle through a metering pump, wherein the core liquid flows out from the inner aperture of the coaxial double-layer needle at 25°C, and the inner wall material glue flows out from the outer aperture of the coaxial double-layer needle at 70°C. After the two solutions flow out of the needle, under the action of surface tension, the dripping core liquid droplets and the dripping wall material glue form concentric spherical droplets, the inside of the droplets is the core liquid, and the outer layer is the wall material glue. Under the action of its own gravity, the droplets drip into a 25°C protective liquid (a calcium chloride aqueous solution with a mass fraction of 20%) to cool, forming bursting bead particles with a certain hardness. After separation and washing by a screen, the inner layer structure of the tobacco bursting bead coated with a water-soluble flavor can be obtained. Among them: the wall material glue flow rate: the inner layer core liquid flow rate = 1.6:1.
5)将步骤4)中所得烟用爆珠内层结构快速浸没于步骤2)所配胶液中，停留2-5s之后取出，室温冷却得到内外双层壁材包覆水溶性香精的烟用爆珠，但所得爆珠无脆性。5) The inner layer structure of the tobacco popping beads obtained in step 4) is quickly immersed in the glue solution prepared in step 2), and taken out after staying for 2-5 seconds, and cooled at room temperature to obtain tobacco popping beads with inner and outer double-layer wall materials coated with water-soluble flavors, but the obtained popping beads are not brittle.
最后所应当说明的是，以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制，尽管参照较佳实施例对本发明作了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的实质和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention rather than to limit the scope of protection of the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that the technical solution of the present invention can be modified or replaced by equivalents without departing from the essence and scope of the technical solution of the present invention.
Claims (9)
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0510761A1 (en) * | 1991-04-24 | 1992-10-28 | Unilever N.V. | Wax-encapsulated particles and method for making same |
| US5230822A (en) * | 1989-11-15 | 1993-07-27 | Lever Brothers Company, Division Of Conopco, Inc. | Wax-encapsulated particles |
| US5258132A (en) * | 1989-11-15 | 1993-11-02 | Lever Brothers Company, Division Of Conopco, Inc. | Wax-encapsulated particles |
| CN103815541A (en) * | 2014-02-21 | 2014-05-28 | 湖北中烟工业有限责任公司 | Water capsule for three-layer cigarette and preparation method of water capsule |
| CN104305521A (en) * | 2014-08-28 | 2015-01-28 | 上海华宝生物科技有限公司 | Cigarette water capsule with water and hydrotropic substance as core materials and manufacturing method of cigarette water capsule with water and hydrotropic substance as core materials |
| CN109222223A (en) * | 2018-08-28 | 2019-01-18 | 中国烟草总公司郑州烟草研究院 | A kind of wax water-in type cigarette is with quick-fried pearl and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10744476B2 (en) * | 2007-05-31 | 2020-08-18 | Philip Morris Usa Inc. | Production of wax capsules containing liquid hydrophilic cores |
| CN109043644B (en) * | 2018-08-28 | 2022-02-08 | 中国烟草总公司郑州烟草研究院 | Three-layer structure cigarette capsule simultaneously coated with lipid solution and water and preparation method thereof |
-
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- 2022-04-02 CN CN202210353874.XA patent/CN114847516B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5230822A (en) * | 1989-11-15 | 1993-07-27 | Lever Brothers Company, Division Of Conopco, Inc. | Wax-encapsulated particles |
| US5258132A (en) * | 1989-11-15 | 1993-11-02 | Lever Brothers Company, Division Of Conopco, Inc. | Wax-encapsulated particles |
| EP0510761A1 (en) * | 1991-04-24 | 1992-10-28 | Unilever N.V. | Wax-encapsulated particles and method for making same |
| CN103815541A (en) * | 2014-02-21 | 2014-05-28 | 湖北中烟工业有限责任公司 | Water capsule for three-layer cigarette and preparation method of water capsule |
| CN104305521A (en) * | 2014-08-28 | 2015-01-28 | 上海华宝生物科技有限公司 | Cigarette water capsule with water and hydrotropic substance as core materials and manufacturing method of cigarette water capsule with water and hydrotropic substance as core materials |
| CN109222223A (en) * | 2018-08-28 | 2019-01-18 | 中国烟草总公司郑州烟草研究院 | A kind of wax water-in type cigarette is with quick-fried pearl and preparation method thereof |
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