CN114832630A - Stacking method of electric deionized water filtering membrane - Google Patents
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- 239000012528 membrane Substances 0.000 title claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 238000001914 filtration Methods 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000008367 deionised water Substances 0.000 title 1
- 229910021641 deionized water Inorganic materials 0.000 title 1
- 239000011229 interlayer Substances 0.000 claims abstract description 20
- 150000001450 anions Chemical class 0.000 claims abstract description 14
- 238000003466 welding Methods 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 12
- 150000001768 cations Chemical class 0.000 claims abstract description 10
- 150000002500 ions Chemical class 0.000 claims abstract description 8
- 238000009296 electrodeionization Methods 0.000 claims abstract 8
- 239000003292 glue Substances 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 238000004026 adhesive bonding Methods 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 125000006850 spacer group Chemical group 0.000 description 13
- 125000002091 cationic group Chemical group 0.000 description 9
- 238000007789 sealing Methods 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000003032 molecular docking Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/08—Flat membrane modules
- B01D63/082—Flat membrane modules comprising a stack of flat membranes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
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- Environmental & Geological Engineering (AREA)
- Engineering & Computer Science (AREA)
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- General Chemical & Material Sciences (AREA)
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Abstract
Description
技术领域technical field
本发明属于净水器领域,具体涉及一种电去离子水过滤膜的堆叠方法。The invention belongs to the field of water purifiers, in particular to a stacking method of electrodeionized water filtration membranes.
背景技术Background technique
在常见的膜滤芯中,为了达到纯净程度,RO膜占据重要地位,但是RO膜在过滤水的时候容易把80%~99%的物质过滤掉,包括对人体有益的的元素也全部过滤,此现象不利于年龄小的用户的生长发育。且受限于RO膜材质和使用方式,出水流量比较小,无法达成生活用水的目的。现有的生活用水过滤方式无法有效去除水中的钙镁及重金属,导致加热器或锅炉等用水设备极易产生水垢。目前广泛应用的软水机是使用钠来转换水中的钙镁来达到软水除垢的目的的,但会往下水道中排放高钠的盐水,使土壤盐碱化,对环境造成破坏。In common membrane filters, in order to achieve the degree of purity, RO membrane occupies an important position, but when RO membrane filters water, it is easy to filter out 80% to 99% of the substances, including all elements that are beneficial to the human body. The phenomenon is not conducive to the growth and development of young users. And limited by the RO membrane material and usage, the effluent flow is relatively small, and the purpose of domestic water cannot be achieved. The existing domestic water filtration methods cannot effectively remove calcium, magnesium and heavy metals in the water, which makes the water equipment such as heaters or boilers easily produce scale. At present, the widely used water softener uses sodium to convert calcium and magnesium in water to achieve the purpose of soft water descaling, but it will discharge high-sodium salt water into the sewers, which will salinize the soil and cause damage to the environment.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种电去离子水过滤膜的堆叠方法,既能解决有效控制水流中所含离子的比例,又能满足大通量的水流要求,还能保证不会发生混水的密封效果。The object of the present invention is to provide a method for stacking electrodeionized water filtration membranes, which can not only solve the problem of effectively controlling the proportion of ions contained in the water flow, but also meet the requirements of large flux of water flow, and can also ensure that water mixing does not occur. sealing effect.
为了实现上述目的,本发明采取的方法如下:In order to achieve the above object, the method that the present invention takes is as follows:
一种电去离子水过滤膜的堆叠方法,即所有膜片、隔层依次粘合得到初始电离子水过滤膜堆的步骤包括:A method for stacking electrodeionized water filtration membranes, that is, the steps of bonding all membrane sheets and interlayers in sequence to obtain an initial ionized water filtration membrane stack include:
进一步,所有膜片和隔层的堆放顺序依次为阴离子膜、隔层、阳离子膜、隔层、阴离子膜、隔层、阳离子膜……,或为阳离子膜、隔层、阴离子膜、隔层、阳离子膜……。Further, the stacking order of all membrane sheets and spacers is anion membrane, spacer, cationic film, spacer, anion film, spacer, cationic film..., or cationic film, spacer, anion film, spacer, Cationic membrane….
进一步,以上堆叠方法的最小单位为阴离子膜、隔层、阳离子膜,两个最小单位之间为隔层。Further, the minimum unit of the above stacking method is an anion membrane, a spacer, and a cationic membrane, and the spacer is between the two minimum units.
进一步,将熔接料分别添加在隔层相对两侧边缘;Further, the welding material is added to the edges of the two opposite sides of the interlayer respectively;
进一步,将熔接料分别添加在下一层隔层另一相对两侧边缘,如此交叉重复上一操作与本次操作。Further, the welding material is added to the edges of the other opposite sides of the next layer of the interlayer respectively, and the previous operation and this operation are repeated in this way.
进一步,通过热熔或超音波焊接或胶粘的方式将隔层和相邻膜片依次粘合。Further, the spacer layer and the adjacent diaphragms are sequentially bonded by means of hot melt or ultrasonic welding or gluing.
进一步,溶接料可以为PE、PP或者其他薄片塑料或胶体。Further, the welding material can be PE, PP or other thin plastics or colloids.
进一步,膜堆可以根据实际需要实现最小单位的无限堆叠。Further, the membrane stack can realize infinite stacking of the smallest unit according to actual needs.
进一步,将粘合好的膜堆放入拥有水路的密封容器中,连接正负电极可以过滤水流的电离子。Further, put the bonded membrane stack into a sealed container with a water channel, and connect the positive and negative electrodes to filter the ions of the water flow.
进一步,通过控制电流强度或电压强度可以控制过滤水流的电离子含量。Further, the ion content of the filtered water stream can be controlled by controlling the current intensity or voltage intensity.
进一步,在膜堆四角保留缺口,在膜堆放入密封容器中时将缺口用胶水完全填充Further, keep gaps at the four corners of the membrane stack, and fill the gaps completely with glue when the membrane stack is placed in a sealed container
本发明的有益效果为:通过密封电离子膜形成膜堆,可以有效增加膜的密封效果、增大通量提高过滤效率;通过控制电流来调解净化水的电离子的含量。The beneficial effects of the invention are: forming a membrane stack by sealing the ionized membrane, which can effectively increase the sealing effect of the membrane, increase the flux and improve the filtration efficiency; and adjust the content of ionized water in the purified water by controlling the current.
附图说明Description of drawings
图1为电离子水过滤膜的结构图Figure 1 is a structural diagram of an ionized water filtration membrane
1、阴离子膜,2、隔层,3、阳离子膜,4、熔接料,5、熔接料。1. Anionic membrane, 2. Interlayer, 3. Cationic membrane, 4. Welding material, 5. Welding material.
具体实施方式Detailed ways
下面将结合本发明的实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅为本发明的一部分实施例,并非全部。通常在此处附图中描述和示出的本发明实施例的组件可以以各种不同的配置来布置和设计。因此,以下对在附图中提示的本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅标识本发明的选定实施例。基于本发明的实施例,本领域技术人员在没有做出创造性劳动的前提下获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, not all of them. The components of the embodiments of the invention generally described and illustrated in the drawings herein may be arranged and designed in a variety of different configurations. Thus, the following detailed description of the embodiments of the invention that are presented in the accompanying drawings are not intended to limit the scope of the invention as claimed, but are merely to identify selected embodiments of the invention. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative work fall within the protection scope of the present invention.
首先,将膜片1、3、隔层2依次粘合,此处的膜片主要为阴离子膜1和阳离子膜3,亦可位置颠倒放置阴离子膜和阳离子膜,所述的隔层2主要为尼龙网或其他非金属材质网,膜片和隔层的形状一般为四边形,其角呈缺口状。膜片与隔层的堆放顺序依次为阴离子膜1、隔层2、阳离子膜3、隔层2,并可以循环摆放。First, the
其次,将所述的隔层2的对边边缘添加熔接料,在下一个隔层2的另一对边边缘添加熔接料。该熔接料4、5一般为PE、PP或者其他薄片塑料或胶体。Next, add a welding material to the opposite edge of the said
再次,重复上述操作。Again, repeat the above operation.
然后,通过热熔的方式将隔层2和相邻的膜片1、3依次粘合起来。Then, the
最后,其形成的膜堆可以整体放入密封固定容器中,并在对应角落里填充胶水,该胶水可以为环氧树脂。Finally, the formed film stack can be put into a sealed and fixed container as a whole, and the corresponding corners are filled with glue, and the glue can be epoxy resin.
在具体操作中,最小单位的阴阳离子膜1、3之间形成水路,水流从阴离子膜1和阳离子膜3之间通过,水流中的正负离子分别穿透阴阳离子膜去往相邻水道,但是水流不会穿透阴阳离子膜去往相邻水道,实现了净化水流的密封效果。In the specific operation, a water channel is formed between the smallest unit of anion and
在具体操作中,通过热熔或超音波粘合的方式,在膜堆中形成完全隔绝的十字形上下两层水路,通过最小单位的叠加,既提高了过滤的水量,也保证横向水路和纵向水路在膜堆中不会发生混水现象。In the specific operation, a completely isolated cross-shaped upper and lower water channel is formed in the membrane stack by means of thermal fusion or ultrasonic bonding. There will be no water mixing phenomenon in the waterway in the membrane stack.
在具体操作中,通过膜堆和密封容器中水路匹配对接,实现通过膜堆的水流按照净水和废水去往不同的排水口,保证水流在通过膜堆后不会发生混水现象。In the specific operation, through the matching and docking of the water channels in the membrane stack and the sealed container, the water flow through the membrane stack can go to different drains according to the purified water and waste water, so as to ensure that the water flow will not be mixed with water after passing through the membrane stack.
在具体操作中,可通过控制密封容器连接的正负两极的通过电流大小/或电压大小控制通过膜堆的水中电离子的含量。In the specific operation, the content of the electric ions in the water passing through the membrane stack can be controlled by controlling the magnitude of the passing current/or the magnitude of the voltage of the positive and negative electrodes connected to the sealed container.
在具体操作中,膜堆四角的缺口填充胶水,可以提高膜堆固定在密封容器中的牢固性,还可以保证通过的水流不会在膜堆四角发生混水现象。In the specific operation, the gaps at the four corners of the membrane stack are filled with glue, which can improve the firmness of the membrane stack in the sealed container, and can also ensure that the passing water flow will not mix water at the four corners of the membrane stack.
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CN202110133969.6A CN114832630A (en) | 2021-02-01 | 2021-02-01 | Stacking method of electric deionized water filtering membrane |
TW110112999A TW202231341A (en) | 2021-02-01 | 2021-04-09 | Stacking method of electrodeionized water filtering membranes, manufacturing method of electrodeionized water filter element, and making method of electrodeionized water for effectively controlling ion ratio contained in water flow and meeting requirement of large water flow volume |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US20120145547A1 (en) * | 2010-12-14 | 2012-06-14 | General Electric Company | Electrical deionization apparatus |
CN103282112A (en) * | 2010-11-12 | 2013-09-04 | 西门子私人有限公司 | Methods of making a cell stack for an electrical purification apparatus |
CZ2013504A3 (en) * | 2013-06-27 | 2015-01-07 | Membrain S.R.O. | Asymmetric ion-exchange membrane and method of using thereof |
US20180093030A1 (en) * | 2016-09-30 | 2018-04-05 | Curion Research Corporation | Dialysate free artificial kidney device |
CN212151724U (en) * | 2020-03-16 | 2020-12-15 | 佛山市云米电器科技有限公司 | Asymmetric bipolar membrane, membrane stack and electrodeionization device |
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- 2021-02-01 CN CN202110133969.6A patent/CN114832630A/en active Pending
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Publication number | Priority date | Publication date | Assignee | Title |
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CN103282112A (en) * | 2010-11-12 | 2013-09-04 | 西门子私人有限公司 | Methods of making a cell stack for an electrical purification apparatus |
US20120145547A1 (en) * | 2010-12-14 | 2012-06-14 | General Electric Company | Electrical deionization apparatus |
CZ2013504A3 (en) * | 2013-06-27 | 2015-01-07 | Membrain S.R.O. | Asymmetric ion-exchange membrane and method of using thereof |
US20180093030A1 (en) * | 2016-09-30 | 2018-04-05 | Curion Research Corporation | Dialysate free artificial kidney device |
CN212151724U (en) * | 2020-03-16 | 2020-12-15 | 佛山市云米电器科技有限公司 | Asymmetric bipolar membrane, membrane stack and electrodeionization device |
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