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CN114832630A - Stacking method of electric deionized water filtering membrane - Google Patents

Stacking method of electric deionized water filtering membrane Download PDF

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Publication number
CN114832630A
CN114832630A CN202110133969.6A CN202110133969A CN114832630A CN 114832630 A CN114832630 A CN 114832630A CN 202110133969 A CN202110133969 A CN 202110133969A CN 114832630 A CN114832630 A CN 114832630A
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membrane
interlayer
stacking method
water
water filtration
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丁飞
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Kemflo Nanjing Environmental Technology Co Ltd
Kemflo International Co Ltd
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Kemflo Nanjing Environmental Technology Co Ltd
Kemflo International Co Ltd
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Priority to CN202110133969.6A priority Critical patent/CN114832630A/en
Priority to TW110112999A priority patent/TW202231341A/en
Publication of CN114832630A publication Critical patent/CN114832630A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08Flat membrane modules
    • B01D63/082Flat membrane modules comprising a stack of flat membranes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a stacking method of an electrodeionization water filtering membrane, which comprises the steps of alternately stacking anion and cation membranes and interlayers, taking two surfaces as a group, sequentially and alternately adding welding materials, and then bonding the membranes by corresponding technology to form an isolated multilayer water channel. The stacking method solves the problems of ion content and water flow in water filtration, can effectively control the content of metal ions in domestic water, and achieves the purpose of large-flux healthy water.

Description

一种电去离子水过滤膜的堆叠方法A kind of stacking method of electrodeionized water filtration membrane

技术领域technical field

本发明属于净水器领域,具体涉及一种电去离子水过滤膜的堆叠方法。The invention belongs to the field of water purifiers, in particular to a stacking method of electrodeionized water filtration membranes.

背景技术Background technique

在常见的膜滤芯中,为了达到纯净程度,RO膜占据重要地位,但是RO膜在过滤水的时候容易把80%~99%的物质过滤掉,包括对人体有益的的元素也全部过滤,此现象不利于年龄小的用户的生长发育。且受限于RO膜材质和使用方式,出水流量比较小,无法达成生活用水的目的。现有的生活用水过滤方式无法有效去除水中的钙镁及重金属,导致加热器或锅炉等用水设备极易产生水垢。目前广泛应用的软水机是使用钠来转换水中的钙镁来达到软水除垢的目的的,但会往下水道中排放高钠的盐水,使土壤盐碱化,对环境造成破坏。In common membrane filters, in order to achieve the degree of purity, RO membrane occupies an important position, but when RO membrane filters water, it is easy to filter out 80% to 99% of the substances, including all elements that are beneficial to the human body. The phenomenon is not conducive to the growth and development of young users. And limited by the RO membrane material and usage, the effluent flow is relatively small, and the purpose of domestic water cannot be achieved. The existing domestic water filtration methods cannot effectively remove calcium, magnesium and heavy metals in the water, which makes the water equipment such as heaters or boilers easily produce scale. At present, the widely used water softener uses sodium to convert calcium and magnesium in water to achieve the purpose of soft water descaling, but it will discharge high-sodium salt water into the sewers, which will salinize the soil and cause damage to the environment.

发明内容SUMMARY OF THE INVENTION

本发明的目的在于提供一种电去离子水过滤膜的堆叠方法,既能解决有效控制水流中所含离子的比例,又能满足大通量的水流要求,还能保证不会发生混水的密封效果。The object of the present invention is to provide a method for stacking electrodeionized water filtration membranes, which can not only solve the problem of effectively controlling the proportion of ions contained in the water flow, but also meet the requirements of large flux of water flow, and can also ensure that water mixing does not occur. sealing effect.

为了实现上述目的,本发明采取的方法如下:In order to achieve the above object, the method that the present invention takes is as follows:

一种电去离子水过滤膜的堆叠方法,即所有膜片、隔层依次粘合得到初始电离子水过滤膜堆的步骤包括:A method for stacking electrodeionized water filtration membranes, that is, the steps of bonding all membrane sheets and interlayers in sequence to obtain an initial ionized water filtration membrane stack include:

进一步,所有膜片和隔层的堆放顺序依次为阴离子膜、隔层、阳离子膜、隔层、阴离子膜、隔层、阳离子膜……,或为阳离子膜、隔层、阴离子膜、隔层、阳离子膜……。Further, the stacking order of all membrane sheets and spacers is anion membrane, spacer, cationic film, spacer, anion film, spacer, cationic film..., or cationic film, spacer, anion film, spacer, Cationic membrane….

进一步,以上堆叠方法的最小单位为阴离子膜、隔层、阳离子膜,两个最小单位之间为隔层。Further, the minimum unit of the above stacking method is an anion membrane, a spacer, and a cationic membrane, and the spacer is between the two minimum units.

进一步,将熔接料分别添加在隔层相对两侧边缘;Further, the welding material is added to the edges of the two opposite sides of the interlayer respectively;

进一步,将熔接料分别添加在下一层隔层另一相对两侧边缘,如此交叉重复上一操作与本次操作。Further, the welding material is added to the edges of the other opposite sides of the next layer of the interlayer respectively, and the previous operation and this operation are repeated in this way.

进一步,通过热熔或超音波焊接或胶粘的方式将隔层和相邻膜片依次粘合。Further, the spacer layer and the adjacent diaphragms are sequentially bonded by means of hot melt or ultrasonic welding or gluing.

进一步,溶接料可以为PE、PP或者其他薄片塑料或胶体。Further, the welding material can be PE, PP or other thin plastics or colloids.

进一步,膜堆可以根据实际需要实现最小单位的无限堆叠。Further, the membrane stack can realize infinite stacking of the smallest unit according to actual needs.

进一步,将粘合好的膜堆放入拥有水路的密封容器中,连接正负电极可以过滤水流的电离子。Further, put the bonded membrane stack into a sealed container with a water channel, and connect the positive and negative electrodes to filter the ions of the water flow.

进一步,通过控制电流强度或电压强度可以控制过滤水流的电离子含量。Further, the ion content of the filtered water stream can be controlled by controlling the current intensity or voltage intensity.

进一步,在膜堆四角保留缺口,在膜堆放入密封容器中时将缺口用胶水完全填充Further, keep gaps at the four corners of the membrane stack, and fill the gaps completely with glue when the membrane stack is placed in a sealed container

本发明的有益效果为:通过密封电离子膜形成膜堆,可以有效增加膜的密封效果、增大通量提高过滤效率;通过控制电流来调解净化水的电离子的含量。The beneficial effects of the invention are: forming a membrane stack by sealing the ionized membrane, which can effectively increase the sealing effect of the membrane, increase the flux and improve the filtration efficiency; and adjust the content of ionized water in the purified water by controlling the current.

附图说明Description of drawings

图1为电离子水过滤膜的结构图Figure 1 is a structural diagram of an ionized water filtration membrane

1、阴离子膜,2、隔层,3、阳离子膜,4、熔接料,5、熔接料。1. Anionic membrane, 2. Interlayer, 3. Cationic membrane, 4. Welding material, 5. Welding material.

具体实施方式Detailed ways

下面将结合本发明的实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅为本发明的一部分实施例,并非全部。通常在此处附图中描述和示出的本发明实施例的组件可以以各种不同的配置来布置和设计。因此,以下对在附图中提示的本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅标识本发明的选定实施例。基于本发明的实施例,本领域技术人员在没有做出创造性劳动的前提下获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, not all of them. The components of the embodiments of the invention generally described and illustrated in the drawings herein may be arranged and designed in a variety of different configurations. Thus, the following detailed description of the embodiments of the invention that are presented in the accompanying drawings are not intended to limit the scope of the invention as claimed, but are merely to identify selected embodiments of the invention. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative work fall within the protection scope of the present invention.

首先,将膜片1、3、隔层2依次粘合,此处的膜片主要为阴离子膜1和阳离子膜3,亦可位置颠倒放置阴离子膜和阳离子膜,所述的隔层2主要为尼龙网或其他非金属材质网,膜片和隔层的形状一般为四边形,其角呈缺口状。膜片与隔层的堆放顺序依次为阴离子膜1、隔层2、阳离子膜3、隔层2,并可以循环摆放。First, the diaphragms 1, 3 and the interlayer 2 are bonded in sequence. The diaphragms here are mainly the anionic membrane 1 and the cationic membrane 3, and the anionic membrane and the cationic membrane can also be placed upside down. The interlayer 2 is mainly composed of Nylon mesh or other non-metal mesh, the shape of the diaphragm and the spacer is generally quadrilateral, and its corners are notched. The stacking sequence of membranes and spacers is anion membrane 1, spacer 2, cationic film 3, spacer 2, and can be placed cyclically.

其次,将所述的隔层2的对边边缘添加熔接料,在下一个隔层2的另一对边边缘添加熔接料。该熔接料4、5一般为PE、PP或者其他薄片塑料或胶体。Next, add a welding material to the opposite edge of the said partition 2, and add a welding material to the other opposite edge of the next partition 2. The welding materials 4 and 5 are generally PE, PP or other thin plastics or colloids.

再次,重复上述操作。Again, repeat the above operation.

然后,通过热熔的方式将隔层2和相邻的膜片1、3依次粘合起来。Then, the interlayer 2 and the adjacent membrane sheets 1 and 3 are sequentially bonded together by means of thermal fusion.

最后,其形成的膜堆可以整体放入密封固定容器中,并在对应角落里填充胶水,该胶水可以为环氧树脂。Finally, the formed film stack can be put into a sealed and fixed container as a whole, and the corresponding corners are filled with glue, and the glue can be epoxy resin.

在具体操作中,最小单位的阴阳离子膜1、3之间形成水路,水流从阴离子膜1和阳离子膜3之间通过,水流中的正负离子分别穿透阴阳离子膜去往相邻水道,但是水流不会穿透阴阳离子膜去往相邻水道,实现了净化水流的密封效果。In the specific operation, a water channel is formed between the smallest unit of anion and cation membranes 1 and 3, the water flow passes between the anion membrane 1 and the cation membrane 3, and the positive and negative ions in the water flow penetrate the anion and cation membranes to the adjacent water channels respectively, but The water flow will not penetrate the anion and cation membranes to the adjacent water channels, and the sealing effect of the purified water flow is realized.

在具体操作中,通过热熔或超音波粘合的方式,在膜堆中形成完全隔绝的十字形上下两层水路,通过最小单位的叠加,既提高了过滤的水量,也保证横向水路和纵向水路在膜堆中不会发生混水现象。In the specific operation, a completely isolated cross-shaped upper and lower water channel is formed in the membrane stack by means of thermal fusion or ultrasonic bonding. There will be no water mixing phenomenon in the waterway in the membrane stack.

在具体操作中,通过膜堆和密封容器中水路匹配对接,实现通过膜堆的水流按照净水和废水去往不同的排水口,保证水流在通过膜堆后不会发生混水现象。In the specific operation, through the matching and docking of the water channels in the membrane stack and the sealed container, the water flow through the membrane stack can go to different drains according to the purified water and waste water, so as to ensure that the water flow will not be mixed with water after passing through the membrane stack.

在具体操作中,可通过控制密封容器连接的正负两极的通过电流大小/或电压大小控制通过膜堆的水中电离子的含量。In the specific operation, the content of the electric ions in the water passing through the membrane stack can be controlled by controlling the magnitude of the passing current/or the magnitude of the voltage of the positive and negative electrodes connected to the sealed container.

在具体操作中,膜堆四角的缺口填充胶水,可以提高膜堆固定在密封容器中的牢固性,还可以保证通过的水流不会在膜堆四角发生混水现象。In the specific operation, the gaps at the four corners of the membrane stack are filled with glue, which can improve the firmness of the membrane stack in the sealed container, and can also ensure that the passing water flow will not mix water at the four corners of the membrane stack.

Claims (6)

1. The stacking method of the electrodeionization water filtration membrane is characterized in that the step of sequentially bonding all membranes and interlayers to obtain an initial electrodeionization water filtration membrane stack comprises the following steps:
s1: all the membrane sheets and the interlayer are stacked in sequence to form an anion membrane, an interlayer, a cation membrane, an interlayer, an anion membrane, an interlayer and a cation membrane … …, or form a cation membrane, an interlayer, an anion membrane, an interlayer and a cation membrane … ….
S2: the minimum units of the stacking method are an anion membrane (1), an interlayer (2) and a cation membrane (3), and the interlayer (2) is arranged between the two minimum units;
s3: adding welding materials (4) on the edges of the two opposite sides of the interlayer respectively;
s3: respectively adding welding materials (5) to the edges of the other two opposite sides of the next interlayer, and repeating the previous operation and the current operation in a crossed manner;
s4: the interlayer and the adjacent membranes are sequentially bonded by hot melting or ultrasonic welding or gluing.
2. The stacking method of electrodeionization water filtration membranes as claimed in claim 1, wherein the frit is PE, PP or other thin plastic or gel.
3. The stacking method of electrodeionization water filtration membranes according to claim 1, wherein infinite stacking of the smallest unit can be achieved according to practical needs.
4. The stacking method of electrodeionization water filtration membranes according to claim 1, wherein the bonded membrane stack is placed in a sealed container having water paths, and the positive and negative electrodes are connected to filter the electric ions of the water flow.
5. The stacking method of electrodeionization water filtration membranes according to claim 1, wherein the ion content of the filtered water stream is controlled by controlling the current/voltage intensity.
6. The stacking method of electrodeionization water filtration membranes according to claim 1, wherein notches are reserved at four corners of the membrane stack, and the notches are completely filled with the glue when the membrane stack is placed in the sealed container.
CN202110133969.6A 2021-02-01 2021-02-01 Stacking method of electric deionized water filtering membrane Pending CN114832630A (en)

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CN202110133969.6A CN114832630A (en) 2021-02-01 2021-02-01 Stacking method of electric deionized water filtering membrane
TW110112999A TW202231341A (en) 2021-02-01 2021-04-09 Stacking method of electrodeionized water filtering membranes, manufacturing method of electrodeionized water filter element, and making method of electrodeionized water for effectively controlling ion ratio contained in water flow and meeting requirement of large water flow volume

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120145547A1 (en) * 2010-12-14 2012-06-14 General Electric Company Electrical deionization apparatus
CN103282112A (en) * 2010-11-12 2013-09-04 西门子私人有限公司 Methods of making a cell stack for an electrical purification apparatus
CZ2013504A3 (en) * 2013-06-27 2015-01-07 Membrain S.R.O. Asymmetric ion-exchange membrane and method of using thereof
US20180093030A1 (en) * 2016-09-30 2018-04-05 Curion Research Corporation Dialysate free artificial kidney device
CN212151724U (en) * 2020-03-16 2020-12-15 佛山市云米电器科技有限公司 Asymmetric bipolar membrane, membrane stack and electrodeionization device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103282112A (en) * 2010-11-12 2013-09-04 西门子私人有限公司 Methods of making a cell stack for an electrical purification apparatus
US20120145547A1 (en) * 2010-12-14 2012-06-14 General Electric Company Electrical deionization apparatus
CZ2013504A3 (en) * 2013-06-27 2015-01-07 Membrain S.R.O. Asymmetric ion-exchange membrane and method of using thereof
US20180093030A1 (en) * 2016-09-30 2018-04-05 Curion Research Corporation Dialysate free artificial kidney device
CN212151724U (en) * 2020-03-16 2020-12-15 佛山市云米电器科技有限公司 Asymmetric bipolar membrane, membrane stack and electrodeionization device

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Application publication date: 20220802