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CN114751472A - Groundwater circulation well device and remediation method for in-situ remediation of contaminated sites - Google Patents

Groundwater circulation well device and remediation method for in-situ remediation of contaminated sites Download PDF

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CN114751472A
CN114751472A CN202210517935.1A CN202210517935A CN114751472A CN 114751472 A CN114751472 A CN 114751472A CN 202210517935 A CN202210517935 A CN 202210517935A CN 114751472 A CN114751472 A CN 114751472A
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groundwater
pipeline
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bubble water
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刘志彬
刘朱
蔡昕辰
贺辰飞
王琨戈
王宇婷
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Southeast University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/002Reclamation of contaminated soil involving in-situ ground water treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00In situ
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/78Details relating to ozone treatment devices
    • C02F2201/784Diffusers or nozzles for ozonation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/04Surfactants, used as part of a formulation or alone

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  • Environmental & Geological Engineering (AREA)
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  • Organic Chemistry (AREA)
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  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

本发明属于地下水与土壤修复技术领域,涉及污染场地原位修复的地下水循环井装置与修复方法。装置包括循环井,循环井从上到下具有透水层和封闭层;废气处理装置、臭氧发生器以及皂素溶液储存箱连通至封闭层;封闭层配置有地下水抽入管以及气泡水抽出管道。地面与地下水的水位线之间形成包气带;循环井安装有微纳米气泡水输出管道。方法包括:将地下水通过地下水抽入管抽入封闭层内;将臭氧发生器和皂素溶液储存箱的臭氧以及皂素溶液输送至封闭层内;将封闭层内的液体通过气泡水抽出管道输出至地下水中;打开微纳米气泡水抽注泵,通过微纳米气泡水输出管道将封闭层内的液体输送至包气带区域。本发明修复区域更加全面,修复效果好。

Figure 202210517935

The invention belongs to the technical field of groundwater and soil restoration, and relates to a groundwater circulation well device and a restoration method for in-situ restoration of polluted sites. The device includes a circulation well, which has a permeable layer and a sealing layer from top to bottom; the waste gas treatment device, the ozone generator and the saponin solution storage tank are connected to the sealing layer; the sealing layer is equipped with a groundwater suction pipe and a bubble water extraction pipe. A vadose zone is formed between the ground and the water level line of the groundwater; the circulation well is equipped with a micro-nano bubble water output pipeline. The method includes: pumping the groundwater into the closed layer through the groundwater suction pipe; transporting the ozone and the saponin solution of the ozone generator and the saponin solution storage tank into the closed layer; outputting the liquid in the closed layer through the bubble water extraction pipeline to the closed layer. In groundwater; turn on the micro-nano bubble water pump, and transport the liquid in the closed layer to the vadose zone through the micro-nano bubble water output pipeline. The repairing area of the invention is more comprehensive and the repairing effect is good.

Figure 202210517935

Description

污染场地原位修复的地下水循环井装置与修复方法Groundwater circulation well device and remediation method for in-situ remediation of contaminated sites

技术领域technical field

本发明属于地下水与土壤修复技术领域,具体涉及一种污染场地原位修复的地下水循环井装置与修复方法。The invention belongs to the technical field of groundwater and soil restoration, and in particular relates to a groundwater circulation well device and a restoration method for in-situ restoration of polluted sites.

背景技术Background technique

目前,由人类活动如城市垃圾填埋、农业化学品使用、工业生产等所造成的土壤与地下水污染问题不容乐观。土壤与地下水中主要污染物按种类一般分为无机污染物、有机污染物等,且大多数污染区域均在一定程度上表现出多种污染物的复合污染。At present, the problem of soil and groundwater pollution caused by human activities such as urban landfill, agricultural chemical use, and industrial production is not optimistic. The main pollutants in soil and groundwater are generally divided into inorganic pollutants, organic pollutants, etc., and most polluted areas show compound pollution of multiple pollutants to a certain extent.

现有的污染土壤与地下水的修复技术按照处理位置一般可分为原位修复和异位修复。原位修复凭借其对污染区域扰动不大、工程量较小、经济效益较好等优势得到较为广泛的应用。但是针对污染土与污染地下水的原位修复通常是将两者分别作为研究主体,对二者的修复是分开进行的。Existing remediation technologies for contaminated soil and groundwater can generally be divided into in-situ remediation and ex-situ remediation according to the treatment location. In situ remediation has been widely used due to its advantages of less disturbance to polluted areas, less engineering volume, and better economic benefits. However, the in-situ remediation of polluted soil and polluted groundwater usually takes the two as the main research subjects, and the remediation of the two is carried out separately.

地下水循环井作为一种可以综合利用化学、物理、生物等过程来实现对地下水的原位修复技术,其具有与其他修复技术相结合的潜力。其通常与曝气法联合使用,通过在循环井周围区域形成三维循环流场,循环流冲刷并带动污染物进入井内,通过曝气吹脱和抽提来去除掉易挥发或者气相有机物,同时曝气过程可以提高地下水中的含氧量,强化土著微生物对有机污染物的降解作用,从而实现对地下水和土体中有机污染物的去除。As an in-situ remediation technology for groundwater that can comprehensively utilize chemical, physical, and biological processes, groundwater circulation wells have the potential to be combined with other remediation technologies. It is usually used in combination with the aeration method. By forming a three-dimensional circulating flow field around the circulating well, the circulating flow scours and drives the pollutants into the well, and removes volatile or gas-phase organics through aeration stripping and extraction. The gas process can increase the oxygen content in groundwater and strengthen the degradation of organic pollutants by indigenous microorganisms, thereby realizing the removal of organic pollutants in groundwater and soil.

但目前地下水循环井技术与曝气法联合使用过程中也存在一些问题,如针对包气带中土壤与水体污染物去除效率不高、主要针对水体中有机污染但对土壤中存在的重金属污染无法有效处理、其循环流场区域不大或无法有效循环、气泡在水中停留时间不长等问题仍然存在。However, there are still some problems in the combined use of groundwater circulation well technology and aeration method. Problems such as effective treatment, small circulating flow field area or no effective circulation, and short residence time of bubbles in water still exist.

发明内容SUMMARY OF THE INVENTION

本发明的目的在于提供一种污染场地原位修复的地下水循环井装置与修复方法,能够对土壤和地下水进行修复且修复效果好。The purpose of the present invention is to provide a groundwater circulation well device and a repairing method for in-situ repairing of polluted sites, which can repair soil and groundwater with good repairing effect.

为达此目的,本发明采用以下技术方案:For this purpose, the present invention adopts the following technical solutions:

一种污染场地原位修复的地下水循环井装置,包括位于地面的废气处理装置、臭氧发生器、皂素溶液储存箱以及位于位于地面以下的循环井,所述循环井从上到下具有交错设置的透水层和封闭层;所述废气处理装置、所述臭氧发生器以及所述皂素溶液储存箱连通至所述封闭层;A groundwater circulation well device for in-situ remediation of polluted sites, comprising a waste gas treatment device on the ground, an ozone generator, a saponin solution storage tank, and a circulation well located below the ground, the circulation wells are staggered from top to bottom. The water-permeable layer and the sealing layer; the waste gas treatment device, the ozone generator and the saponin solution storage tank are connected to the sealing layer;

所述封闭层配置有地下水抽入管以及气泡水抽出管道,所述地下水抽入管用于将地下水输入所述封闭层内,所述气泡水抽出管道用于将所述封闭层内的液体输出至地下水中;The closed layer is equipped with a groundwater suction pipe and a bubble water extraction pipe, the groundwater suction pipe is used to input groundwater into the closed layer, and the bubble water extraction pipe is used to output the liquid in the closed layer to groundwater middle;

地面与地下水的水位线之间形成包气带;A vadose zone is formed between the ground and the water level of the groundwater;

所述循环井安装有微纳米气泡水输出管道,所述微纳米气泡水输出管道安装有微纳米气泡水抽注泵且通过连接的微纳米气泡水抽提管道伸入所述封闭层;所述微纳米气泡水输出管道用于将所述封闭层的液体输送至所述包气带区域。The circulation well is equipped with a micro-nano bubble water output pipeline, and the micro-nano bubble water output pipeline is equipped with a micro-nano bubble water pump and extends into the closed layer through the connected micro-nano bubble water extraction pipeline; the The micro-nano bubble water output pipeline is used to transport the liquid of the closed layer to the vadose zone area.

优选地,所述微纳米气泡水输出管道安装在所述透水层上且两端穿过所述透水层的侧壁伸出至所述包气带区域。Preferably, the micro-nano bubble water output pipe is installed on the water-permeable layer, and both ends extend through the sidewall of the water-permeable layer to the vadose zone region.

优选地,所述臭氧发生器上连接有臭氧运输管道,所述臭氧运输管道形成有至少两个分支管道且所述臭氧运输管道的各个分支管道分别伸入各个所述封闭层。Preferably, the ozone generator is connected with an ozone transportation pipeline, the ozone transportation pipeline is formed with at least two branch pipelines, and each branch pipeline of the ozone transportation pipeline extends into each of the closed layers respectively.

优选地,所述臭氧运输管道的各个分支管道的出口端分别安装有曝气头。Preferably, an aeration head is respectively installed at the outlet end of each branch pipe of the ozone transport pipe.

优选地,所述曝气头能够产生直径在200nm以下的微纳米气泡。Preferably, the aeration head can generate micro-nano bubbles with diameters below 200 nm.

优选地,所述污染场地原位修复的地下水循环井装置还包括地下水处理装置,所述地下水处理装置是重金属污染物处理装置。Preferably, the groundwater circulation well device for in-situ restoration of the polluted site further includes a groundwater treatment device, and the groundwater treatment device is a heavy metal pollutant treatment device.

优选地,所述污染场地原位修复的地下水循环井装置还包括双用运输管道,所述双用运输管道包括主管道,所述双用运输管道的主管道的一端形成地面的两个分支管道,所述双用运输管道的主管道的另一端形成地下的至少两个分支管道;所述双用运输管道的一个地面的分支管道上安装有管道阀和所述皂素溶液储存箱,另一个地面的分支管道上安装有所述地下水处理装置;所述双用运输管道的地下的分支管道向下伸入所述封闭层。Preferably, the groundwater circulation well device for in-situ remediation of contaminated sites further comprises a dual-purpose transportation pipeline, the dual-purpose transportation pipeline includes a main pipeline, and one end of the main pipeline of the dual-purpose transportation pipeline forms two branch pipelines on the ground , the other end of the main pipeline of the dual-purpose transportation pipeline forms at least two branch pipelines underground; a branch pipeline on the ground of the dual-purpose transportation pipeline is installed with a pipeline valve and the saponin solution storage tank, and the other The groundwater treatment device is installed on the branch pipeline on the ground; the underground branch pipeline of the dual-purpose transportation pipeline extends downward into the closed layer.

优选地,所述双用运输管道的主管道上可拆卸安装有抽注泵,所述抽注泵方向可调。Preferably, an infusion pump is detachably installed on the main pipeline of the dual-purpose transportation pipeline, and the direction of the infusion pump is adjustable.

一种污染场地原位修复的地下水修复方法,包括上述的污染场地原位修复的地下水循环井装置以及步骤:A groundwater remediation method for in-situ remediation of contaminated sites, comprising the above-mentioned groundwater circulation well device for in-situ remediation of contaminated sites and the steps:

将地下水通过所述地下水抽入管抽入所述封闭层内;drawing groundwater into the sealing layer through the groundwater suction pipe;

将所述臭氧发生器和所述皂素溶液储存箱的臭氧以及皂素溶液输送至所述封闭层内;transporting the ozone and the saponin solution of the ozone generator and the saponin solution storage tank into the sealing layer;

将所述封闭层内的液体通过所述气泡水抽出管道输出至地下水中;outputting the liquid in the closed layer to the groundwater through the bubble water extraction pipeline;

打开所述微纳米气泡水抽注泵,通过所述微纳米气泡水输出管道将所述封闭层内的液体输送至所述包气带区域。The micro-nano bubble water pump is turned on, and the liquid in the sealing layer is transported to the vadose zone region through the micro-nano bubble water output pipe.

优选地,将所述封闭层内的液体抽至地下水处理装置中进行重金属污染物处理,然后将处理后的水重新输送至所述封闭层内。Preferably, the liquid in the closed layer is pumped to a groundwater treatment device for heavy metal pollutant treatment, and then the treated water is re-transported into the closed layer.

本发明的污染场地原位修复的地下水循环井装置与修复方法的有益效果在于:通过设置微纳米气泡水输出管道,用于将封闭层的液体输送至包气带区域,从而还能够对包气带区域的土壤和污水进行修复,修复区域更加全面,修复效果好。The beneficial effect of the groundwater circulation well device and the repairing method for in-situ repair of polluted sites of the present invention is that: by setting the micro-nano bubble water output pipeline, the liquid in the sealing layer is transported to the vadose zone area, so that the vadose water can also be treated. The soil and sewage in the belt area are repaired, the repair area is more comprehensive, and the repair effect is good.

附图说明Description of drawings

图1是本发明实施例污染场地原位修复的地下水循环井装置的结构示意图。FIG. 1 is a schematic structural diagram of a groundwater circulation well device for in-situ remediation of contaminated sites according to an embodiment of the present invention.

图中部件名称和标号如下:The names and labels of the parts in the figure are as follows:

废气处理装置(1);臭氧发生器(2);空气泵(3);臭氧运输管道(4);废气抽提泵(5);废气抽提管道(6);双用运输管道(7);抽注泵(8);管道阀(9);皂素溶液储存箱(10);地下水处理装置(11);微纳米气泡水抽注泵(12);第一透水层(13a);第二透水层(13b);第三透水层(13c);封隔器(14);地下水抽提泵(15);气泡水抽出泵(16);水位感应器(17);曝气头(18);第一封闭层(19);第二封闭层(20);微纳米气泡水输出管道(21);地下水抽入管(22);上短管道(22a);气泡水抽出管道(23);下短管道(23a);微纳米气泡水抽提管道(24);不透水水泥壁(25);水位线(100);包气带(200)。Exhaust gas treatment device (1); ozone generator (2); air pump (3); ozone transportation pipeline (4); exhaust gas extraction pump (5); exhaust gas extraction pipeline (6); dual-purpose transportation pipeline (7) ; Suction pump (8); Pipe valve (9); Saponin solution storage tank (10); Groundwater treatment device (11); The second permeable layer (13b); the third permeable layer (13c); the packer (14); the groundwater extraction pump (15); the bubble water extraction pump (16); the water level sensor (17); the aeration head (18) ); the first sealing layer (19); the second sealing layer (20); the micro-nano bubble water output pipe (21); the groundwater suction pipe (22); the upper short pipe (22a); the bubble water extraction pipe (23); The lower short pipe (23a); the micro-nano bubble water extraction pipe (24); the impermeable cement wall (25); the water level line (100); the vadose zone (200).

具体实施方式Detailed ways

下面结合附图和实施例对本发明作进一步的详细说明。可以理解的是,此处所描述的具体实施例仅仅用于解释本发明,而非对本发明的限定。另外还需要说明的是,为了便于描述,附图中仅示出了与本发明相关的部分而非全部结构。The present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention, but not to limit the present invention. In addition, it should be noted that, for the convenience of description, the drawings only show some but not all structures related to the present invention.

如图1所示,本实施例公开了一种污染场地原位修复的地下水循环井装置。该污染场地原位修复的地下水循环井装置包括地面部分和地面以下部分。地面与地下水的水位线100之间形成包气带200。As shown in FIG. 1 , this embodiment discloses a groundwater circulation well device for in-situ repair of a polluted site. The groundwater circulation well device for in-situ remediation of the polluted site includes a ground part and a part below the ground. A vadose zone 200 is formed between the ground and the water level line 100 of the groundwater.

地面部分包括废气处理装置1、臭氧发生器2、空气泵3、臭氧运输管道4、废气抽提泵5、废气抽提管道6、双用运输管道7、抽注泵8、管道阀9、皂素溶液储存箱10以及地下水处理装置11。The ground part includes exhaust gas treatment device 1, ozone generator 2, air pump 3, ozone transportation pipeline 4, exhaust gas extraction pump 5, exhaust gas extraction pipeline 6, dual-purpose transportation pipeline 7, suction pump 8, pipeline valve 9, soap Elemental solution storage tank 10 and groundwater treatment device 11.

地面以下部分设置有循环井。循环井包括微纳米气泡水抽注泵12、微纳米气泡水抽提管道24、微纳米气泡水输出管道21、地下水抽入管22、地下水抽提泵15、气泡水抽出管道23、气泡水抽出泵16、水位感应器17。The part below the ground is provided with a circulation well. The circulating well includes a micro-nano bubble water pump 12, a micro-nano bubble water extraction pipeline 24, a micro-nano bubble water output pipeline 21, a groundwater suction pipe 22, a groundwater extraction pump 15, a bubble water extraction pipeline 23, and a bubble water extraction pump 16. Water level sensor 17.

该循环井从上到下具有透水层和封闭层。本实施例以三个透水层和两个封闭层来说明本实施例的污染场地原位修复的地下水循环井装置。在其它的实施例中,透水层和封闭层的数量以及布置方式可以根据需要进行设定。The circulation well has a permeable layer and a sealing layer from top to bottom. In this embodiment, three permeable layers and two closed layers are used to illustrate the groundwater circulation well device for in-situ restoration of contaminated sites in this embodiment. In other embodiments, the number and arrangement of the water-permeable layer and the sealing layer can be set as required.

如图1所示,本实施例的封闭层分为第一封闭层19和第二封闭层20。透水层分别是第一透水层13a、第二透水层13b、第三透水层13c。循环井从上到下依次是第一透水层13a、第一封闭层19、第二透水层13b、第二封闭层20、第三透水层13c。第一透水层13a自地面向下延伸,经过包气带200延伸至水位线100以下。第一封闭层19、第二透水层13b、第二封闭层20、第三透水层13c均位于水位线100以下。As shown in FIG. 1 , the sealing layer in this embodiment is divided into a first sealing layer 19 and a second sealing layer 20 . The water-permeable layers are the first water-permeable layer 13a, the second water-permeable layer 13b, and the third water-permeable layer 13c, respectively. From top to bottom, the circulation well is a first permeable layer 13a, a first closed layer 19, a second permeable layer 13b, a second closed layer 20, and a third permeable layer 13c. The first water permeable layer 13a extends downward from the ground, and extends below the water level 100 through the vadose zone 200 . The first sealing layer 19 , the second water-permeable layer 13 b , the second sealing layer 20 , and the third water-permeable layer 13 c are all located below the water level 100 .

本实施例的第一透水层13a、第二透水层13b、第三透水层13c的侧壁为石英砂材质。本实施例设置第一透水层13a、第二透水层13b、第三透水层13c能够使得地下水在循环井的作用下更好地循环流动,以提高修复效果。The side walls of the first water-permeable layer 13a, the second water-permeable layer 13b, and the third water-permeable layer 13c in this embodiment are made of quartz sand. In this embodiment, the first permeable layer 13a, the second permeable layer 13b, and the third permeable layer 13c can make the groundwater circulate better under the action of the circulation well, so as to improve the repair effect.

第一封闭层19和第二封闭层20的侧壁分别为不透水水泥壁25。第一封闭层19和第二封闭层20的上下分别设置封隔器14。具体地,第一封闭层19是由上下两个封隔器14和不透水水泥壁25围成的封闭腔体。第二封闭层20是由上下两个封隔器14和不透水水泥壁25围成的封闭腔体。第一封闭层19和第二封闭层20分别能够隔断水,以为循环修复过程的控制提供基础。The side walls of the first sealing layer 19 and the second sealing layer 20 are respectively impermeable cement walls 25 . Packers 14 are respectively provided above and below the first sealing layer 19 and the second sealing layer 20 . Specifically, the first sealing layer 19 is a closed cavity surrounded by the upper and lower packers 14 and the impermeable cement wall 25 . The second sealing layer 20 is a closed cavity surrounded by two upper and lower packers 14 and an impermeable cement wall 25 . The first sealing layer 19 and the second sealing layer 20 are respectively capable of blocking water, so as to provide a basis for the control of the cyclic repairing process.

本实施例的废气处理装置1上连接有废气抽提管道6。具体地,该废气抽提管道6包括主管道,废气抽提管道6的主管道的一端与废气处理装置1连接,废气抽提管道6的主管道的另一端形成有两个分支管道。废气抽提泵5安装在废气抽提管道6的主管道上。废气抽提管道6的一个分支管道向下伸入第一封闭层19,废气抽提管道6的另一个分支管道向下伸入第二封闭层20。An exhaust gas extraction pipe 6 is connected to the exhaust gas treatment device 1 of this embodiment. Specifically, the exhaust gas extraction pipeline 6 includes a main pipeline, one end of the main pipeline of the exhaust gas extraction pipeline 6 is connected to the exhaust gas treatment device 1, and the other end of the main pipeline of the exhaust gas extraction pipeline 6 is formed with two branch pipelines. The exhaust gas extraction pump 5 is installed on the main pipe of the exhaust gas extraction pipe 6 . One branch pipe of the exhaust gas extraction pipe 6 extends downward into the first closed layer 19 , and another branch pipe of the exhaust gas extraction pipe 6 extends downward into the second closed layer 20 .

本实施例的臭氧发生器2上连接有臭氧运输管道4。具体地,臭氧运输管道4包括主管道,臭氧运输管道4的主管道的一端与臭氧发生器2连接,且臭氧运输管道4的主管道上安装有空气泵3。臭氧运输管道4的主管道的另一端形成有两个分支管道。臭氧运输管道4的一个分支管道向下伸入第一封闭层19且该分支管道末端安装有曝气头18。臭氧运输管道4的另一个分支管道向下伸入第二封闭层20且该分支管道末端安装有曝气头18。The ozone generator 2 in this embodiment is connected with an ozone transport pipeline 4 . Specifically, the ozone transportation pipeline 4 includes a main pipeline, one end of the main pipeline of the ozone transportation pipeline 4 is connected to the ozone generator 2 , and an air pump 3 is installed on the main pipeline of the ozone transportation pipeline 4 . The other end of the main pipe of the ozone transport pipe 4 is formed with two branch pipes. A branch pipe of the ozone transport pipe 4 extends downward into the first sealing layer 19 and an aeration head 18 is installed at the end of the branch pipe. Another branch pipe of the ozone transport pipe 4 extends downward into the second sealing layer 20 and an aeration head 18 is installed at the end of the branch pipe.

本实施例的双用运输管道7包括主管道,双用运输管道7的主管道的一端形成地面的两个分支管道,双用运输管道7的主管道的另一端形成地下的两个分支管道。The dual-purpose transportation pipeline 7 in this embodiment includes a main pipeline. One end of the main pipeline of the dual-purpose transportation pipeline 7 forms two branch pipelines on the ground, and the other end of the main pipeline for the dual-purpose transportation pipeline 7 forms two underground branch pipelines.

双用运输管道7的一个地面的分支管道上安装有管道阀9和皂素溶液储存箱10,另一个地面的分支管道上安装有地下水处理装置11。本实施例的抽注泵8的方向可调,且抽注泵8可拆卸安装于双用运输管道7上。具体地,抽注泵8可拆卸安装于双用运输管道7的主管道上。A pipeline valve 9 and a saponin solution storage tank 10 are installed on one ground branch pipe of the dual-purpose transportation pipeline 7 , and a groundwater treatment device 11 is installed on the other ground branch pipe. The direction of the infusion pump 8 in this embodiment is adjustable, and the infusion pump 8 can be detachably installed on the dual-purpose transportation pipeline 7 . Specifically, the infusion pump 8 is detachably installed on the main pipeline of the dual-purpose transportation pipeline 7 .

双用运输管道7的一个地下的分支管道向下伸入第一封闭层19,双用运输管道7的另一个地下的分支管道向下伸入第二封闭层20。One underground branch pipe of the dual-purpose transport pipeline 7 protrudes downward into the first closed layer 19 , and another underground branch pipeline of the dual-purpose transport pipeline 7 extends downward into the second closed layer 20 .

本实施例的地下水处理装置11是重金属等污染物处理装置,能够处理重金属以及其它的污染物。The groundwater treatment device 11 of this embodiment is a pollutant treatment device such as heavy metals, and can treat heavy metals and other pollutants.

本实施例的第一透水层13a上安装有水平的微纳米气泡水输出管道21。微纳米气泡水输出管道21位于地面以下且位于水位线100以上。微纳米气泡水输出管道21的两端伸出第一透水层13a的侧壁,以进入包气带200。微纳米气泡水输出管道21的中部安装有微纳米气泡水抽注泵12。微纳米气泡水抽注泵12为潜水泵。微纳米气泡水输出管道21的中部还连接有微纳米气泡水抽提管道24。微纳米气泡水抽提管道24自微纳米气泡水输出管道21向下延伸至封闭层。本实施例的封闭层为第一封闭层19。在其它的实施例中,微纳米气泡水抽提管道24还可以向下延伸至其它的封闭层。A horizontal micro-nano bubble water output pipe 21 is installed on the first water-permeable layer 13a in this embodiment. The micro-nano bubble water output pipe 21 is located below the ground and above the water level 100 . Both ends of the micro-nano bubble water output pipe 21 protrude from the side wall of the first water permeable layer 13 a to enter the vadose zone 200 . The micro-nano bubble water pump 12 is installed in the middle of the micro-nano bubble water output pipe 21 . The micro-nano bubble water pump 12 is a submersible pump. The middle of the micro-nano bubble water output pipe 21 is also connected with a micro-nano bubble water extraction pipe 24 . The micro-nano bubble water extraction pipe 24 extends downward from the micro-nano bubble water output pipe 21 to the closed layer. The sealing layer in this embodiment is the first sealing layer 19 . In other embodiments, the micro-nano bubble water extraction pipeline 24 may also extend downward to other closed layers.

现有对包气带200部分的土壤没有进行修复处理,处理区域不全面。本实施例还能够对包气带200部分的土壤进行修复处理,污染处理区域更加全面。At present, the soil in the 200 part of the vadose zone has not been repaired, and the treatment area is not comprehensive. In this embodiment, the soil in the vadose zone 200 can also be repaired, and the pollution treatment area is more comprehensive.

水位线100以下的第一透水层13a的侧壁上安装有水平的地下水抽入管22。地下水抽入管22的两端分别伸出第一透水层13a的侧壁,以进入地下水。地下水抽入管22中部安装有地下水抽提泵15和上短管道22a,该上短管道22a自地下水抽入管22向下延伸至第一封闭层19的顶部内腔。上短管道22a安装有水位感应器17,用于检测第一封闭层19内腔的水是否处于高水位。A horizontal groundwater suction pipe 22 is attached to the side wall of the first permeable layer 13a below the water level 100 . The two ends of the groundwater suction pipe 22 respectively protrude from the side wall of the first permeable layer 13a to enter the groundwater. A groundwater extraction pump 15 and an upper short pipe 22 a are installed in the middle of the groundwater suction pipe 22 , and the upper short pipe 22a extends downward from the groundwater suction pipe 22 to the top inner cavity of the first sealing layer 19 . A water level sensor 17 is installed on the upper short pipe 22a to detect whether the water in the inner cavity of the first sealing layer 19 is at a high water level.

第二透水层13b的侧壁安装有水平的气泡水抽出管道23。气泡水抽出管道23的两端分别伸出第一透水层13a的侧壁,以进入地下水。气泡水抽出管道23的中部安装有气泡水抽出泵16和下短管道23a。下短管道23a自气泡水抽出管道23向上延伸至第一封闭层19的底部内腔。下短管道23a安装有水位感应器17,用于检测第一封闭层19内腔的水是否处于低水位。A horizontal bubble water extraction pipe 23 is installed on the side wall of the second water permeable layer 13b. Both ends of the bubble water extraction pipe 23 respectively protrude from the side wall of the first permeable layer 13a to enter the groundwater. The bubble water extraction pump 16 and the lower short pipeline 23a are installed in the middle of the bubble water extraction pipe 23 . The lower short pipe 23a extends upward from the sparkling water extraction pipe 23 to the bottom inner cavity of the first sealing layer 19 . A water level sensor 17 is installed on the lower short pipe 23a to detect whether the water in the inner cavity of the first sealing layer 19 is at a low water level.

同理,第二封闭层20也配置有地下水抽入管22、地下水抽提泵15、气泡水抽出管道23、气泡水抽出泵16、水位感应器17。第二封闭层20配置的地下水抽入管22安装在第二透水层13b的底部。第二封闭层20配置的气泡水抽出管道23位于第三透水层13c。Similarly, the second closed layer 20 is also provided with a groundwater suction pipe 22 , a groundwater extraction pump 15 , a bubble water extraction pipe 23 , a bubble water extraction pump 16 , and a water level sensor 17 . The groundwater suction pipe 22 disposed in the second sealing layer 20 is installed at the bottom of the second permeable layer 13b. The bubble water extraction pipe 23 disposed in the second sealing layer 20 is located in the third water permeable layer 13c.

本实施例的污染场地原位修复的地下水修复方法基于上述的污染场地原位修复的地下水循环井装置。方法如下:The groundwater remediation method for in-situ remediation of contaminated sites in this embodiment is based on the above-mentioned groundwater circulation well device for in-situ remediation of contaminated sites. Methods as below:

将地下水通过地下水抽入管22抽入封闭层内;The groundwater is pumped into the closed layer through the groundwater suction pipe 22;

将臭氧发生器2和皂素溶液储存箱10的臭氧以及皂素溶液输送至封闭层内;The ozone and the saponin solution of the ozone generator 2 and the saponin solution storage tank 10 are transported into the sealing layer;

将封闭层内的液体通过气泡水抽出管道23输出至地下水中;The liquid in the closed layer is output to the groundwater through the bubble water extraction pipeline 23;

打开微纳米气泡水抽注泵12,通过微纳米气泡水输出管道21将封闭层内的液体输送至包气带200区域。The micro-nano bubble water pump 12 is turned on, and the liquid in the closed layer is transported to the area of the vadose zone 200 through the micro-nano bubble water output pipe 21 .

将封闭层内的液体抽至地下水处理装置11中进行重金属污染物处理,然后将处理后的水重新输送至封闭层内。The liquid in the closed layer is pumped to the groundwater treatment device 11 for heavy metal pollutant treatment, and then the treated water is re-transported into the closed layer.

具体方法为:The specific method is:

步骤一:地下水抽提泵15开始工作,将地下水通过地下水抽入管22和上短管道22a抽入第一封闭层19和第二封闭层20。当水位感应器17感应到水位快达到预设的高度时,也就是快达到封闭层的容量时,地下水抽提泵15停止工作。Step 1: The groundwater extraction pump 15 starts to work, and the groundwater is pumped into the first sealing layer 19 and the second sealing layer 20 through the groundwater suction pipe 22 and the upper short pipe 22a. When the water level sensor 17 senses that the water level is about to reach a preset height, that is, when the water level is about to reach the capacity of the sealing layer, the groundwater extraction pump 15 stops working.

步骤二:管道阀9打开,抽注泵8、臭氧发生器2和空气泵3开始运行。将臭氧和高浓度的皂素溶液输送至第一封闭层19和第二封闭层20。曝气头18开始工作,对第一封闭层19和第二封闭层20的地下水进行持续曝气,产生粒径在200nm以下的微纳米气泡,同时废气抽提泵5开始工作,抽出曝气过程中产生的废气,抽至废气处理装置1中进行处理,一段时间后,停止向第一封闭层19和第二封闭层20中输入臭氧和高浓度的皂素溶液。Step 2: The pipeline valve 9 is opened, and the infusion pump 8, the ozone generator 2 and the air pump 3 start to operate. The ozone and high-concentration saponin solution are delivered to the first sealing layer 19 and the second sealing layer 20 . The aeration head 18 starts to work, continuously aerates the groundwater in the first closed layer 19 and the second closed layer 20, and generates micro-nano bubbles with a particle size below 200 nm. At the same time, the exhaust gas extraction pump 5 starts to work to extract the aeration process. The waste gas generated in the waste gas is pumped to the waste gas treatment device 1 for treatment. After a period of time, the input of ozone and high-concentration saponin solution to the first sealing layer 19 and the second sealing layer 20 is stopped.

步骤三:打开微纳米气泡水抽注泵12,通过微纳米气泡水输出管道21将封闭层内的液体输送至包气带200区域。打开气泡水抽出泵16,将第一封闭层19和第二封闭层20的液体输送至地下水中。当水位感应器17检测到第一封闭层19和第二封闭层20的液体水位快到底部时,微纳米气泡水抽注泵12以及气泡水抽出泵16均停止工作。至此,一个循环结束。Step 3: Turn on the micro-nano bubble water pump 12 , and transport the liquid in the closed layer to the area of the vadose zone 200 through the micro-nano bubble water output pipe 21 . The sparkling water pump 16 is turned on, and the liquids in the first sealing layer 19 and the second sealing layer 20 are transported into the groundwater. When the water level sensor 17 detects that the liquid level of the first sealing layer 19 and the second sealing layer 20 is approaching the bottom, both the micro-nano bubble water pump 12 and the bubble water pump 16 stop working. At this point, a cycle ends.

重复步骤一到步骤三进行下一次的循环。Repeat steps 1 to 3 for the next cycle.

当地下水的循环工作结束后,需要对土壤洗出的重金属等污染物进行处理。需要将地下水抽至地下水处理装置11中。具体地,将抽注泵8反装,将管道阀9关闭,运行抽注泵8,打开地下水抽提泵15,持续将地下水抽至地下水处理装置11。处理后,将处理后的液体重新输送至循环井。When the circulation of groundwater is completed, pollutants such as heavy metals washed out from the soil need to be treated. The groundwater needs to be pumped into the groundwater treatment device 11 . Specifically, the suction pump 8 is reversely installed, the pipeline valve 9 is closed, the suction pump 8 is operated, the groundwater extraction pump 15 is turned on, and the groundwater is continuously pumped to the groundwater treatment device 11 . After treatment, the treated fluid is re-delivered to the circulation well.

本实施例通过微纳米气泡水输出管道21将封闭层内的液体输送至包气带200区域。该液体为含有皂素及臭氧这两种成分的微纳米气泡水,能够对包气带200区域的土壤与地下水进行修复。在多次的循环过程中,能够对包气带200区域的土壤与地下水进行充分修复。In this embodiment, the liquid in the sealing layer is transported to the area of the vadose zone 200 through the micro-nano bubble water output pipe 21 . The liquid is micro-nano bubble water containing two components, saponin and ozone, and can remediate soil and groundwater in the vadose zone 200 area. In the process of multiple cycles, the soil and groundwater in the vadose zone 200 area can be fully repaired.

本实施例可以根据需要设定皂素溶液储存箱10中的皂素溶液的浓度。可适当配置较高浓度、较小体积的皂素溶液,主要是由于皂素溶液注入地下水后会自动稀释。皂素溶液是生物友好型表面活性剂,实现对无机污染物、有机污染物的去除效果。本实施例所使用的皂素溶液的浓度为125mg/L。In this embodiment, the concentration of the saponin solution in the saponin solution storage tank 10 can be set as required. A higher concentration and smaller volume of saponin solution can be appropriately configured, mainly because the saponin solution will be automatically diluted after being injected into the groundwater. Saponin solution is a bio-friendly surfactant, which can remove inorganic pollutants and organic pollutants. The concentration of the saponin solution used in this example was 125 mg/L.

本实施例将地下水循环井技术、曝气技术、原位淋洗技术三者联合使用,对地下水与土壤均存在污染的场地进行原位修复。仅需通过单井即可实现较好的修复功能,节省成本。In this embodiment, groundwater circulation well technology, aeration technology, and in-situ leaching technology are combined to perform in-situ restoration of a site where both groundwater and soil are polluted. Only a single well can achieve better repair function and save costs.

本实施例的循环水流动通畅,还能提高微纳米气泡在污染区域停留时间,增强对污染物去除效果。The circulating water in this embodiment flows smoothly, and the residence time of the micro-nano bubbles in the polluted area can be increased, thereby enhancing the removal effect of pollutants.

本实施例对包气带200污染土壤通过循环井实现循环淋洗,提升淋洗液渗流速度,并不必再建造单独的抽提井。In this embodiment, the polluted soil in the vadose zone 200 can be rinsed through the circulation well to realize the circulatory rinsing, so as to increase the seepage velocity of the eluent, and it is not necessary to build a separate extraction well.

本实施例通过多层位的曝气头18能够扩大地下水循环井的循环流场区域,从而实现扩大地下水与地下水位以下土壤污染区域的修复范围,并能在提升地下水中强氧化物质含量,提升污染物去除效果。通过引入生物友好型表面活性剂皂素,直接将对地下水位以下污染土所进行的原位淋洗流程嵌套进地下水循环井,不但可以减少用水量、皂素使用量、对环境污染程度,彻底将与原位淋洗工艺直接关联的抽提井舍弃,更能够同步实现对土壤与地下水的同步修复,也可以提升淋洗剂在土壤中总停留时间,提升淋洗效果。除此之外,通过加入臭氧气源,并产生粒径在200nm以下的微纳米气泡,更能增加强氧化物质在地下水中停留时间,从而提升对地下水和土壤中有机污染物的去除率。In this embodiment, the multi-level aeration head 18 can expand the circulating flow field area of the groundwater circulating well, so as to expand the remediation scope of groundwater and soil pollution areas below the groundwater level, and can increase the content of strong oxidizing substances in groundwater, improve Contaminant removal effect. By introducing the bio-friendly surfactant saponin, the in-situ rinsing process for polluted soil below the groundwater level is directly nested into the groundwater circulation well, which can not only reduce water consumption, saponin consumption, and environmental pollution, but also Completely abandoning the extraction wells directly related to the in-situ leaching process can achieve simultaneous restoration of soil and groundwater, and can also increase the total residence time of the leaching agent in the soil and improve the leaching effect. In addition, by adding ozone gas source and generating micro-nano bubbles with a particle size below 200nm, the residence time of strong oxidizing substances in groundwater can be increased, thereby improving the removal rate of organic pollutants in groundwater and soil.

本实施例曝气头18对不同层位地下水直接曝气,节约用水量、减少传输距离,并其能产生直径小于200nm的微纳米气泡,使得含有强氧化剂的小气泡能够在地下水中存在更长时间,从而对污染物能有更好的去除效果。In this embodiment, the aeration head 18 directly aerates groundwater at different levels, saves water consumption, reduces transmission distance, and can generate micro-nano bubbles with a diameter of less than 200 nm, so that small bubbles containing strong oxidants can exist in groundwater for a longer time time, so as to have a better removal effect on pollutants.

本实施例曝气头18能够在单位时间内产生更多的微纳米气泡,从而提高整个地下水区域中强化剂在单位时间单位体积中的含量。The aeration head 18 of this embodiment can generate more micro-nano bubbles per unit time, thereby increasing the content of the fortifier per unit time and unit volume in the entire groundwater area.

本实施例通过多个独立地封闭层,通过多层位地抽入、泵出,能为地下水循环流场区域提供更强的循环动力,构建更通畅的地下水循环流场。This embodiment can provide stronger circulation power for the groundwater circulation flow field area through multiple independent closed layers and multi-level pumping and pumping, and build a smoother groundwater circulation flow field.

显然,本发明的上述实施例仅仅是为了清楚说明本发明所作的举例,而并非是对本发明的实施方式的限定。对于所属领域的普通技术人员来说,能够进行各种明显的变化、重新调整和替代而不会脱离本发明的保护范围。这里无需也无法对所有的实施方式予以穷举。凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明权利要求的保护范围之内。Obviously, the above-mentioned embodiments of the present invention are only examples for clearly illustrating the present invention, rather than limiting the embodiments of the present invention. For those of ordinary skill in the art, various obvious changes, readjustments and substitutions can be made without departing from the protection scope of the present invention. There is no need and cannot be exhaustive of all implementations here. Any modifications, equivalent replacements and improvements made within the spirit and principle of the present invention shall be included within the protection scope of the claims of the present invention.

Claims (10)

1. The underground water circulating well device for in-situ remediation of the polluted site is characterized by comprising an exhaust gas treatment device (1) positioned on the ground, an ozone generator (2), a saponin solution storage tank (10) and a circulating well positioned below the ground, wherein the circulating well is provided with a permeable layer and a sealing layer which are arranged in a staggered mode from top to bottom; the waste gas treatment device (1), the ozone generator (2) and the saponin solution storage tank (10) are communicated to the sealing layer;
the closed layer is provided with a groundwater suction pipe (22) and a bubble water pumping pipeline (23), the groundwater suction pipe (22) is used for inputting groundwater into the closed layer, and the bubble water pumping pipeline (23) is used for outputting liquid in the closed layer to groundwater;
an aeration zone (200) is formed between the ground and a water level line (100) of the underground water;
the circulation well is provided with a micro-nano bubble water output pipeline (21), the micro-nano bubble water output pipeline (21) is provided with a micro-nano bubble water pumping and injecting pump (12) and extends into the sealing layer through a connected micro-nano bubble water extraction pipeline (24); the micro-nano bubble water output pipeline (21) is used for conveying the liquid of the closed layer to the area of the aeration zone (200).
2. A groundwater circulating well device for in-situ remediation of a contaminated site as claimed in claim 1, wherein: micro-nano bubble water output pipeline (21) are installed on the permeable layer and both ends pass the lateral wall on permeable layer stretches out to it is regional to bordure area (200).
3. A groundwater circulating well device for in situ remediation of a contaminated site as claimed in claim 1, wherein: ozone transport pipe way (4) are connected with on ozone generator (2), ozone transport pipe way (4) are formed with two at least branch pipelines just each branch pipeline of ozone transport pipe way (4) stretches into each respectively the seal coat.
4. A groundwater circulating well device for in situ remediation of a contaminated site as claimed in claim 3, wherein: and the outlet ends of all branch pipelines of the ozone conveying pipeline (4) are respectively provided with an aeration head (18).
5. A groundwater circulating well device for in-situ remediation of a contaminated site as claimed in claim 4, wherein: the aeration head (18) can generate micro-nano bubbles with the diameter of less than 200 nm.
6. A groundwater circulating well device for in situ remediation of a contaminated site as claimed in claim 1, wherein: the underground water circulating well device for in-situ remediation of the polluted site further comprises an underground water treatment device (11), wherein the underground water treatment device (11) is a heavy metal pollutant treatment device.
7. A groundwater circulating well device for in-situ remediation of a contaminated site as claimed in claim 6, wherein: the underground water circulating well device for in-situ remediation of the polluted site further comprises a dual-purpose conveying pipeline (7), wherein the dual-purpose conveying pipeline (7) comprises a main pipeline, one end of the main pipeline of the dual-purpose conveying pipeline (7) forms two branch pipelines on the ground, and the other end of the main pipeline of the dual-purpose conveying pipeline (7) forms at least two branch pipelines underground; a pipeline valve (9) and the saponin solution storage tank (10) are arranged on a branch pipeline on one ground of the dual-purpose transport pipeline (7), and the underground water treatment device (11) is arranged on a branch pipeline on the other ground; and underground branch pipelines of the double-purpose transport pipeline (7) extend downwards into the closed layer.
8. A groundwater circulating well device for in-situ remediation of a contaminated site as claimed in claim 7, wherein: the main pipeline of the double-purpose transport pipeline (7) is detachably provided with a pumping and injection pump (8), and the direction of the pumping and injection pump (8) is adjustable.
9. A groundwater remediation method for in-situ remediation of a contaminated site, comprising the groundwater circulation well device for in-situ remediation of a contaminated site according to any one of claims 1 to 8 and the steps of:
pumping groundwater into the enclosure through the groundwater pumping pipe (22);
conveying the ozone of the ozone generator (2) and the saponin solution storage tank (10) and the saponin solution into the sealing layer;
outputting the liquid in the closed layer to underground water through the bubble water extraction pipeline (23);
and (3) opening the micro-nano bubble water pumping and injecting pump (12), and conveying the liquid in the closed layer to the area of the aeration zone (200) through the micro-nano bubble water output pipeline (21).
10. A groundwater remediation method of in situ remediation of a contaminated site as claimed in claim 9, wherein: pumping the liquid in the sealing layer into a groundwater treatment device (11) for heavy metal pollutant treatment, and then delivering the treated water into the sealing layer again.
CN202210517935.1A 2022-05-12 2022-05-12 Groundwater circulation well device and remediation method for in-situ remediation of contaminated sites Pending CN114751472A (en)

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