CN114751472A - Groundwater circulation well device and remediation method for in-situ remediation of contaminated sites - Google Patents
Groundwater circulation well device and remediation method for in-situ remediation of contaminated sites Download PDFInfo
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- 239000003673 groundwater Substances 0.000 title claims abstract description 116
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 21
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 83
- 238000007789 sealing Methods 0.000 claims abstract description 55
- 239000002101 nanobubble Substances 0.000 claims abstract description 50
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 28
- 229930182490 saponin Natural products 0.000 claims abstract description 28
- 150000007949 saponins Chemical class 0.000 claims abstract description 28
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- 239000007788 liquid Substances 0.000 claims abstract description 21
- 238000003860 storage Methods 0.000 claims abstract description 15
- 238000005086 pumping Methods 0.000 claims abstract description 12
- 239000002912 waste gas Substances 0.000 claims abstract description 7
- 239000007789 gas Substances 0.000 claims description 20
- 238000005273 aeration Methods 0.000 claims description 19
- 239000003344 environmental pollutant Substances 0.000 claims description 13
- 231100000719 pollutant Toxicity 0.000 claims description 13
- 229910001385 heavy metal Inorganic materials 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims 5
- 238000002347 injection Methods 0.000 claims 2
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- 230000000694 effects Effects 0.000 abstract description 9
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/002—Reclamation of contaminated soil involving in-situ ground water treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C2101/00—In situ
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/06—Contaminated groundwater or leachate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/78—Details relating to ozone treatment devices
- C02F2201/784—Diffusers or nozzles for ozonation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/42—Liquid level
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/04—Surfactants, used as part of a formulation or alone
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Abstract
本发明属于地下水与土壤修复技术领域,涉及污染场地原位修复的地下水循环井装置与修复方法。装置包括循环井,循环井从上到下具有透水层和封闭层;废气处理装置、臭氧发生器以及皂素溶液储存箱连通至封闭层;封闭层配置有地下水抽入管以及气泡水抽出管道。地面与地下水的水位线之间形成包气带;循环井安装有微纳米气泡水输出管道。方法包括:将地下水通过地下水抽入管抽入封闭层内;将臭氧发生器和皂素溶液储存箱的臭氧以及皂素溶液输送至封闭层内;将封闭层内的液体通过气泡水抽出管道输出至地下水中;打开微纳米气泡水抽注泵,通过微纳米气泡水输出管道将封闭层内的液体输送至包气带区域。本发明修复区域更加全面,修复效果好。
The invention belongs to the technical field of groundwater and soil restoration, and relates to a groundwater circulation well device and a restoration method for in-situ restoration of polluted sites. The device includes a circulation well, which has a permeable layer and a sealing layer from top to bottom; the waste gas treatment device, the ozone generator and the saponin solution storage tank are connected to the sealing layer; the sealing layer is equipped with a groundwater suction pipe and a bubble water extraction pipe. A vadose zone is formed between the ground and the water level line of the groundwater; the circulation well is equipped with a micro-nano bubble water output pipeline. The method includes: pumping the groundwater into the closed layer through the groundwater suction pipe; transporting the ozone and the saponin solution of the ozone generator and the saponin solution storage tank into the closed layer; outputting the liquid in the closed layer through the bubble water extraction pipeline to the closed layer. In groundwater; turn on the micro-nano bubble water pump, and transport the liquid in the closed layer to the vadose zone through the micro-nano bubble water output pipeline. The repairing area of the invention is more comprehensive and the repairing effect is good.
Description
技术领域technical field
本发明属于地下水与土壤修复技术领域,具体涉及一种污染场地原位修复的地下水循环井装置与修复方法。The invention belongs to the technical field of groundwater and soil restoration, and in particular relates to a groundwater circulation well device and a restoration method for in-situ restoration of polluted sites.
背景技术Background technique
目前,由人类活动如城市垃圾填埋、农业化学品使用、工业生产等所造成的土壤与地下水污染问题不容乐观。土壤与地下水中主要污染物按种类一般分为无机污染物、有机污染物等,且大多数污染区域均在一定程度上表现出多种污染物的复合污染。At present, the problem of soil and groundwater pollution caused by human activities such as urban landfill, agricultural chemical use, and industrial production is not optimistic. The main pollutants in soil and groundwater are generally divided into inorganic pollutants, organic pollutants, etc., and most polluted areas show compound pollution of multiple pollutants to a certain extent.
现有的污染土壤与地下水的修复技术按照处理位置一般可分为原位修复和异位修复。原位修复凭借其对污染区域扰动不大、工程量较小、经济效益较好等优势得到较为广泛的应用。但是针对污染土与污染地下水的原位修复通常是将两者分别作为研究主体,对二者的修复是分开进行的。Existing remediation technologies for contaminated soil and groundwater can generally be divided into in-situ remediation and ex-situ remediation according to the treatment location. In situ remediation has been widely used due to its advantages of less disturbance to polluted areas, less engineering volume, and better economic benefits. However, the in-situ remediation of polluted soil and polluted groundwater usually takes the two as the main research subjects, and the remediation of the two is carried out separately.
地下水循环井作为一种可以综合利用化学、物理、生物等过程来实现对地下水的原位修复技术,其具有与其他修复技术相结合的潜力。其通常与曝气法联合使用,通过在循环井周围区域形成三维循环流场,循环流冲刷并带动污染物进入井内,通过曝气吹脱和抽提来去除掉易挥发或者气相有机物,同时曝气过程可以提高地下水中的含氧量,强化土著微生物对有机污染物的降解作用,从而实现对地下水和土体中有机污染物的去除。As an in-situ remediation technology for groundwater that can comprehensively utilize chemical, physical, and biological processes, groundwater circulation wells have the potential to be combined with other remediation technologies. It is usually used in combination with the aeration method. By forming a three-dimensional circulating flow field around the circulating well, the circulating flow scours and drives the pollutants into the well, and removes volatile or gas-phase organics through aeration stripping and extraction. The gas process can increase the oxygen content in groundwater and strengthen the degradation of organic pollutants by indigenous microorganisms, thereby realizing the removal of organic pollutants in groundwater and soil.
但目前地下水循环井技术与曝气法联合使用过程中也存在一些问题,如针对包气带中土壤与水体污染物去除效率不高、主要针对水体中有机污染但对土壤中存在的重金属污染无法有效处理、其循环流场区域不大或无法有效循环、气泡在水中停留时间不长等问题仍然存在。However, there are still some problems in the combined use of groundwater circulation well technology and aeration method. Problems such as effective treatment, small circulating flow field area or no effective circulation, and short residence time of bubbles in water still exist.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种污染场地原位修复的地下水循环井装置与修复方法,能够对土壤和地下水进行修复且修复效果好。The purpose of the present invention is to provide a groundwater circulation well device and a repairing method for in-situ repairing of polluted sites, which can repair soil and groundwater with good repairing effect.
为达此目的,本发明采用以下技术方案:For this purpose, the present invention adopts the following technical solutions:
一种污染场地原位修复的地下水循环井装置,包括位于地面的废气处理装置、臭氧发生器、皂素溶液储存箱以及位于位于地面以下的循环井,所述循环井从上到下具有交错设置的透水层和封闭层;所述废气处理装置、所述臭氧发生器以及所述皂素溶液储存箱连通至所述封闭层;A groundwater circulation well device for in-situ remediation of polluted sites, comprising a waste gas treatment device on the ground, an ozone generator, a saponin solution storage tank, and a circulation well located below the ground, the circulation wells are staggered from top to bottom. The water-permeable layer and the sealing layer; the waste gas treatment device, the ozone generator and the saponin solution storage tank are connected to the sealing layer;
所述封闭层配置有地下水抽入管以及气泡水抽出管道,所述地下水抽入管用于将地下水输入所述封闭层内,所述气泡水抽出管道用于将所述封闭层内的液体输出至地下水中;The closed layer is equipped with a groundwater suction pipe and a bubble water extraction pipe, the groundwater suction pipe is used to input groundwater into the closed layer, and the bubble water extraction pipe is used to output the liquid in the closed layer to groundwater middle;
地面与地下水的水位线之间形成包气带;A vadose zone is formed between the ground and the water level of the groundwater;
所述循环井安装有微纳米气泡水输出管道,所述微纳米气泡水输出管道安装有微纳米气泡水抽注泵且通过连接的微纳米气泡水抽提管道伸入所述封闭层;所述微纳米气泡水输出管道用于将所述封闭层的液体输送至所述包气带区域。The circulation well is equipped with a micro-nano bubble water output pipeline, and the micro-nano bubble water output pipeline is equipped with a micro-nano bubble water pump and extends into the closed layer through the connected micro-nano bubble water extraction pipeline; the The micro-nano bubble water output pipeline is used to transport the liquid of the closed layer to the vadose zone area.
优选地,所述微纳米气泡水输出管道安装在所述透水层上且两端穿过所述透水层的侧壁伸出至所述包气带区域。Preferably, the micro-nano bubble water output pipe is installed on the water-permeable layer, and both ends extend through the sidewall of the water-permeable layer to the vadose zone region.
优选地,所述臭氧发生器上连接有臭氧运输管道,所述臭氧运输管道形成有至少两个分支管道且所述臭氧运输管道的各个分支管道分别伸入各个所述封闭层。Preferably, the ozone generator is connected with an ozone transportation pipeline, the ozone transportation pipeline is formed with at least two branch pipelines, and each branch pipeline of the ozone transportation pipeline extends into each of the closed layers respectively.
优选地,所述臭氧运输管道的各个分支管道的出口端分别安装有曝气头。Preferably, an aeration head is respectively installed at the outlet end of each branch pipe of the ozone transport pipe.
优选地,所述曝气头能够产生直径在200nm以下的微纳米气泡。Preferably, the aeration head can generate micro-nano bubbles with diameters below 200 nm.
优选地,所述污染场地原位修复的地下水循环井装置还包括地下水处理装置,所述地下水处理装置是重金属污染物处理装置。Preferably, the groundwater circulation well device for in-situ restoration of the polluted site further includes a groundwater treatment device, and the groundwater treatment device is a heavy metal pollutant treatment device.
优选地,所述污染场地原位修复的地下水循环井装置还包括双用运输管道,所述双用运输管道包括主管道,所述双用运输管道的主管道的一端形成地面的两个分支管道,所述双用运输管道的主管道的另一端形成地下的至少两个分支管道;所述双用运输管道的一个地面的分支管道上安装有管道阀和所述皂素溶液储存箱,另一个地面的分支管道上安装有所述地下水处理装置;所述双用运输管道的地下的分支管道向下伸入所述封闭层。Preferably, the groundwater circulation well device for in-situ remediation of contaminated sites further comprises a dual-purpose transportation pipeline, the dual-purpose transportation pipeline includes a main pipeline, and one end of the main pipeline of the dual-purpose transportation pipeline forms two branch pipelines on the ground , the other end of the main pipeline of the dual-purpose transportation pipeline forms at least two branch pipelines underground; a branch pipeline on the ground of the dual-purpose transportation pipeline is installed with a pipeline valve and the saponin solution storage tank, and the other The groundwater treatment device is installed on the branch pipeline on the ground; the underground branch pipeline of the dual-purpose transportation pipeline extends downward into the closed layer.
优选地,所述双用运输管道的主管道上可拆卸安装有抽注泵,所述抽注泵方向可调。Preferably, an infusion pump is detachably installed on the main pipeline of the dual-purpose transportation pipeline, and the direction of the infusion pump is adjustable.
一种污染场地原位修复的地下水修复方法,包括上述的污染场地原位修复的地下水循环井装置以及步骤:A groundwater remediation method for in-situ remediation of contaminated sites, comprising the above-mentioned groundwater circulation well device for in-situ remediation of contaminated sites and the steps:
将地下水通过所述地下水抽入管抽入所述封闭层内;drawing groundwater into the sealing layer through the groundwater suction pipe;
将所述臭氧发生器和所述皂素溶液储存箱的臭氧以及皂素溶液输送至所述封闭层内;transporting the ozone and the saponin solution of the ozone generator and the saponin solution storage tank into the sealing layer;
将所述封闭层内的液体通过所述气泡水抽出管道输出至地下水中;outputting the liquid in the closed layer to the groundwater through the bubble water extraction pipeline;
打开所述微纳米气泡水抽注泵,通过所述微纳米气泡水输出管道将所述封闭层内的液体输送至所述包气带区域。The micro-nano bubble water pump is turned on, and the liquid in the sealing layer is transported to the vadose zone region through the micro-nano bubble water output pipe.
优选地,将所述封闭层内的液体抽至地下水处理装置中进行重金属污染物处理,然后将处理后的水重新输送至所述封闭层内。Preferably, the liquid in the closed layer is pumped to a groundwater treatment device for heavy metal pollutant treatment, and then the treated water is re-transported into the closed layer.
本发明的污染场地原位修复的地下水循环井装置与修复方法的有益效果在于:通过设置微纳米气泡水输出管道,用于将封闭层的液体输送至包气带区域,从而还能够对包气带区域的土壤和污水进行修复,修复区域更加全面,修复效果好。The beneficial effect of the groundwater circulation well device and the repairing method for in-situ repair of polluted sites of the present invention is that: by setting the micro-nano bubble water output pipeline, the liquid in the sealing layer is transported to the vadose zone area, so that the vadose water can also be treated. The soil and sewage in the belt area are repaired, the repair area is more comprehensive, and the repair effect is good.
附图说明Description of drawings
图1是本发明实施例污染场地原位修复的地下水循环井装置的结构示意图。FIG. 1 is a schematic structural diagram of a groundwater circulation well device for in-situ remediation of contaminated sites according to an embodiment of the present invention.
图中部件名称和标号如下:The names and labels of the parts in the figure are as follows:
废气处理装置(1);臭氧发生器(2);空气泵(3);臭氧运输管道(4);废气抽提泵(5);废气抽提管道(6);双用运输管道(7);抽注泵(8);管道阀(9);皂素溶液储存箱(10);地下水处理装置(11);微纳米气泡水抽注泵(12);第一透水层(13a);第二透水层(13b);第三透水层(13c);封隔器(14);地下水抽提泵(15);气泡水抽出泵(16);水位感应器(17);曝气头(18);第一封闭层(19);第二封闭层(20);微纳米气泡水输出管道(21);地下水抽入管(22);上短管道(22a);气泡水抽出管道(23);下短管道(23a);微纳米气泡水抽提管道(24);不透水水泥壁(25);水位线(100);包气带(200)。Exhaust gas treatment device (1); ozone generator (2); air pump (3); ozone transportation pipeline (4); exhaust gas extraction pump (5); exhaust gas extraction pipeline (6); dual-purpose transportation pipeline (7) ; Suction pump (8); Pipe valve (9); Saponin solution storage tank (10); Groundwater treatment device (11); The second permeable layer (13b); the third permeable layer (13c); the packer (14); the groundwater extraction pump (15); the bubble water extraction pump (16); the water level sensor (17); the aeration head (18) ); the first sealing layer (19); the second sealing layer (20); the micro-nano bubble water output pipe (21); the groundwater suction pipe (22); the upper short pipe (22a); the bubble water extraction pipe (23); The lower short pipe (23a); the micro-nano bubble water extraction pipe (24); the impermeable cement wall (25); the water level line (100); the vadose zone (200).
具体实施方式Detailed ways
下面结合附图和实施例对本发明作进一步的详细说明。可以理解的是,此处所描述的具体实施例仅仅用于解释本发明,而非对本发明的限定。另外还需要说明的是,为了便于描述,附图中仅示出了与本发明相关的部分而非全部结构。The present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention, but not to limit the present invention. In addition, it should be noted that, for the convenience of description, the drawings only show some but not all structures related to the present invention.
如图1所示,本实施例公开了一种污染场地原位修复的地下水循环井装置。该污染场地原位修复的地下水循环井装置包括地面部分和地面以下部分。地面与地下水的水位线100之间形成包气带200。As shown in FIG. 1 , this embodiment discloses a groundwater circulation well device for in-situ repair of a polluted site. The groundwater circulation well device for in-situ remediation of the polluted site includes a ground part and a part below the ground. A
地面部分包括废气处理装置1、臭氧发生器2、空气泵3、臭氧运输管道4、废气抽提泵5、废气抽提管道6、双用运输管道7、抽注泵8、管道阀9、皂素溶液储存箱10以及地下水处理装置11。The ground part includes exhaust
地面以下部分设置有循环井。循环井包括微纳米气泡水抽注泵12、微纳米气泡水抽提管道24、微纳米气泡水输出管道21、地下水抽入管22、地下水抽提泵15、气泡水抽出管道23、气泡水抽出泵16、水位感应器17。The part below the ground is provided with a circulation well. The circulating well includes a micro-nano
该循环井从上到下具有透水层和封闭层。本实施例以三个透水层和两个封闭层来说明本实施例的污染场地原位修复的地下水循环井装置。在其它的实施例中,透水层和封闭层的数量以及布置方式可以根据需要进行设定。The circulation well has a permeable layer and a sealing layer from top to bottom. In this embodiment, three permeable layers and two closed layers are used to illustrate the groundwater circulation well device for in-situ restoration of contaminated sites in this embodiment. In other embodiments, the number and arrangement of the water-permeable layer and the sealing layer can be set as required.
如图1所示,本实施例的封闭层分为第一封闭层19和第二封闭层20。透水层分别是第一透水层13a、第二透水层13b、第三透水层13c。循环井从上到下依次是第一透水层13a、第一封闭层19、第二透水层13b、第二封闭层20、第三透水层13c。第一透水层13a自地面向下延伸,经过包气带200延伸至水位线100以下。第一封闭层19、第二透水层13b、第二封闭层20、第三透水层13c均位于水位线100以下。As shown in FIG. 1 , the sealing layer in this embodiment is divided into a
本实施例的第一透水层13a、第二透水层13b、第三透水层13c的侧壁为石英砂材质。本实施例设置第一透水层13a、第二透水层13b、第三透水层13c能够使得地下水在循环井的作用下更好地循环流动,以提高修复效果。The side walls of the first water-
第一封闭层19和第二封闭层20的侧壁分别为不透水水泥壁25。第一封闭层19和第二封闭层20的上下分别设置封隔器14。具体地,第一封闭层19是由上下两个封隔器14和不透水水泥壁25围成的封闭腔体。第二封闭层20是由上下两个封隔器14和不透水水泥壁25围成的封闭腔体。第一封闭层19和第二封闭层20分别能够隔断水,以为循环修复过程的控制提供基础。The side walls of the
本实施例的废气处理装置1上连接有废气抽提管道6。具体地,该废气抽提管道6包括主管道,废气抽提管道6的主管道的一端与废气处理装置1连接,废气抽提管道6的主管道的另一端形成有两个分支管道。废气抽提泵5安装在废气抽提管道6的主管道上。废气抽提管道6的一个分支管道向下伸入第一封闭层19,废气抽提管道6的另一个分支管道向下伸入第二封闭层20。An exhaust
本实施例的臭氧发生器2上连接有臭氧运输管道4。具体地,臭氧运输管道4包括主管道,臭氧运输管道4的主管道的一端与臭氧发生器2连接,且臭氧运输管道4的主管道上安装有空气泵3。臭氧运输管道4的主管道的另一端形成有两个分支管道。臭氧运输管道4的一个分支管道向下伸入第一封闭层19且该分支管道末端安装有曝气头18。臭氧运输管道4的另一个分支管道向下伸入第二封闭层20且该分支管道末端安装有曝气头18。The
本实施例的双用运输管道7包括主管道,双用运输管道7的主管道的一端形成地面的两个分支管道,双用运输管道7的主管道的另一端形成地下的两个分支管道。The dual-purpose transportation pipeline 7 in this embodiment includes a main pipeline. One end of the main pipeline of the dual-purpose transportation pipeline 7 forms two branch pipelines on the ground, and the other end of the main pipeline for the dual-purpose transportation pipeline 7 forms two underground branch pipelines.
双用运输管道7的一个地面的分支管道上安装有管道阀9和皂素溶液储存箱10,另一个地面的分支管道上安装有地下水处理装置11。本实施例的抽注泵8的方向可调,且抽注泵8可拆卸安装于双用运输管道7上。具体地,抽注泵8可拆卸安装于双用运输管道7的主管道上。A pipeline valve 9 and a saponin
双用运输管道7的一个地下的分支管道向下伸入第一封闭层19,双用运输管道7的另一个地下的分支管道向下伸入第二封闭层20。One underground branch pipe of the dual-purpose transport pipeline 7 protrudes downward into the first
本实施例的地下水处理装置11是重金属等污染物处理装置,能够处理重金属以及其它的污染物。The
本实施例的第一透水层13a上安装有水平的微纳米气泡水输出管道21。微纳米气泡水输出管道21位于地面以下且位于水位线100以上。微纳米气泡水输出管道21的两端伸出第一透水层13a的侧壁,以进入包气带200。微纳米气泡水输出管道21的中部安装有微纳米气泡水抽注泵12。微纳米气泡水抽注泵12为潜水泵。微纳米气泡水输出管道21的中部还连接有微纳米气泡水抽提管道24。微纳米气泡水抽提管道24自微纳米气泡水输出管道21向下延伸至封闭层。本实施例的封闭层为第一封闭层19。在其它的实施例中,微纳米气泡水抽提管道24还可以向下延伸至其它的封闭层。A horizontal micro-nano bubble
现有对包气带200部分的土壤没有进行修复处理,处理区域不全面。本实施例还能够对包气带200部分的土壤进行修复处理,污染处理区域更加全面。At present, the soil in the 200 part of the vadose zone has not been repaired, and the treatment area is not comprehensive. In this embodiment, the soil in the
水位线100以下的第一透水层13a的侧壁上安装有水平的地下水抽入管22。地下水抽入管22的两端分别伸出第一透水层13a的侧壁,以进入地下水。地下水抽入管22中部安装有地下水抽提泵15和上短管道22a,该上短管道22a自地下水抽入管22向下延伸至第一封闭层19的顶部内腔。上短管道22a安装有水位感应器17,用于检测第一封闭层19内腔的水是否处于高水位。A horizontal
第二透水层13b的侧壁安装有水平的气泡水抽出管道23。气泡水抽出管道23的两端分别伸出第一透水层13a的侧壁,以进入地下水。气泡水抽出管道23的中部安装有气泡水抽出泵16和下短管道23a。下短管道23a自气泡水抽出管道23向上延伸至第一封闭层19的底部内腔。下短管道23a安装有水位感应器17,用于检测第一封闭层19内腔的水是否处于低水位。A horizontal bubble
同理,第二封闭层20也配置有地下水抽入管22、地下水抽提泵15、气泡水抽出管道23、气泡水抽出泵16、水位感应器17。第二封闭层20配置的地下水抽入管22安装在第二透水层13b的底部。第二封闭层20配置的气泡水抽出管道23位于第三透水层13c。Similarly, the second
本实施例的污染场地原位修复的地下水修复方法基于上述的污染场地原位修复的地下水循环井装置。方法如下:The groundwater remediation method for in-situ remediation of contaminated sites in this embodiment is based on the above-mentioned groundwater circulation well device for in-situ remediation of contaminated sites. Methods as below:
将地下水通过地下水抽入管22抽入封闭层内;The groundwater is pumped into the closed layer through the
将臭氧发生器2和皂素溶液储存箱10的臭氧以及皂素溶液输送至封闭层内;The ozone and the saponin solution of the
将封闭层内的液体通过气泡水抽出管道23输出至地下水中;The liquid in the closed layer is output to the groundwater through the bubble
打开微纳米气泡水抽注泵12,通过微纳米气泡水输出管道21将封闭层内的液体输送至包气带200区域。The micro-nano
将封闭层内的液体抽至地下水处理装置11中进行重金属污染物处理,然后将处理后的水重新输送至封闭层内。The liquid in the closed layer is pumped to the
具体方法为:The specific method is:
步骤一:地下水抽提泵15开始工作,将地下水通过地下水抽入管22和上短管道22a抽入第一封闭层19和第二封闭层20。当水位感应器17感应到水位快达到预设的高度时,也就是快达到封闭层的容量时,地下水抽提泵15停止工作。Step 1: The groundwater extraction pump 15 starts to work, and the groundwater is pumped into the
步骤二:管道阀9打开,抽注泵8、臭氧发生器2和空气泵3开始运行。将臭氧和高浓度的皂素溶液输送至第一封闭层19和第二封闭层20。曝气头18开始工作,对第一封闭层19和第二封闭层20的地下水进行持续曝气,产生粒径在200nm以下的微纳米气泡,同时废气抽提泵5开始工作,抽出曝气过程中产生的废气,抽至废气处理装置1中进行处理,一段时间后,停止向第一封闭层19和第二封闭层20中输入臭氧和高浓度的皂素溶液。Step 2: The pipeline valve 9 is opened, and the
步骤三:打开微纳米气泡水抽注泵12,通过微纳米气泡水输出管道21将封闭层内的液体输送至包气带200区域。打开气泡水抽出泵16,将第一封闭层19和第二封闭层20的液体输送至地下水中。当水位感应器17检测到第一封闭层19和第二封闭层20的液体水位快到底部时,微纳米气泡水抽注泵12以及气泡水抽出泵16均停止工作。至此,一个循环结束。Step 3: Turn on the micro-nano
重复步骤一到步骤三进行下一次的循环。Repeat steps 1 to 3 for the next cycle.
当地下水的循环工作结束后,需要对土壤洗出的重金属等污染物进行处理。需要将地下水抽至地下水处理装置11中。具体地,将抽注泵8反装,将管道阀9关闭,运行抽注泵8,打开地下水抽提泵15,持续将地下水抽至地下水处理装置11。处理后,将处理后的液体重新输送至循环井。When the circulation of groundwater is completed, pollutants such as heavy metals washed out from the soil need to be treated. The groundwater needs to be pumped into the
本实施例通过微纳米气泡水输出管道21将封闭层内的液体输送至包气带200区域。该液体为含有皂素及臭氧这两种成分的微纳米气泡水,能够对包气带200区域的土壤与地下水进行修复。在多次的循环过程中,能够对包气带200区域的土壤与地下水进行充分修复。In this embodiment, the liquid in the sealing layer is transported to the area of the
本实施例可以根据需要设定皂素溶液储存箱10中的皂素溶液的浓度。可适当配置较高浓度、较小体积的皂素溶液,主要是由于皂素溶液注入地下水后会自动稀释。皂素溶液是生物友好型表面活性剂,实现对无机污染物、有机污染物的去除效果。本实施例所使用的皂素溶液的浓度为125mg/L。In this embodiment, the concentration of the saponin solution in the saponin
本实施例将地下水循环井技术、曝气技术、原位淋洗技术三者联合使用,对地下水与土壤均存在污染的场地进行原位修复。仅需通过单井即可实现较好的修复功能,节省成本。In this embodiment, groundwater circulation well technology, aeration technology, and in-situ leaching technology are combined to perform in-situ restoration of a site where both groundwater and soil are polluted. Only a single well can achieve better repair function and save costs.
本实施例的循环水流动通畅,还能提高微纳米气泡在污染区域停留时间,增强对污染物去除效果。The circulating water in this embodiment flows smoothly, and the residence time of the micro-nano bubbles in the polluted area can be increased, thereby enhancing the removal effect of pollutants.
本实施例对包气带200污染土壤通过循环井实现循环淋洗,提升淋洗液渗流速度,并不必再建造单独的抽提井。In this embodiment, the polluted soil in the
本实施例通过多层位的曝气头18能够扩大地下水循环井的循环流场区域,从而实现扩大地下水与地下水位以下土壤污染区域的修复范围,并能在提升地下水中强氧化物质含量,提升污染物去除效果。通过引入生物友好型表面活性剂皂素,直接将对地下水位以下污染土所进行的原位淋洗流程嵌套进地下水循环井,不但可以减少用水量、皂素使用量、对环境污染程度,彻底将与原位淋洗工艺直接关联的抽提井舍弃,更能够同步实现对土壤与地下水的同步修复,也可以提升淋洗剂在土壤中总停留时间,提升淋洗效果。除此之外,通过加入臭氧气源,并产生粒径在200nm以下的微纳米气泡,更能增加强氧化物质在地下水中停留时间,从而提升对地下水和土壤中有机污染物的去除率。In this embodiment, the
本实施例曝气头18对不同层位地下水直接曝气,节约用水量、减少传输距离,并其能产生直径小于200nm的微纳米气泡,使得含有强氧化剂的小气泡能够在地下水中存在更长时间,从而对污染物能有更好的去除效果。In this embodiment, the
本实施例曝气头18能够在单位时间内产生更多的微纳米气泡,从而提高整个地下水区域中强化剂在单位时间单位体积中的含量。The
本实施例通过多个独立地封闭层,通过多层位地抽入、泵出,能为地下水循环流场区域提供更强的循环动力,构建更通畅的地下水循环流场。This embodiment can provide stronger circulation power for the groundwater circulation flow field area through multiple independent closed layers and multi-level pumping and pumping, and build a smoother groundwater circulation flow field.
显然,本发明的上述实施例仅仅是为了清楚说明本发明所作的举例,而并非是对本发明的实施方式的限定。对于所属领域的普通技术人员来说,能够进行各种明显的变化、重新调整和替代而不会脱离本发明的保护范围。这里无需也无法对所有的实施方式予以穷举。凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明权利要求的保护范围之内。Obviously, the above-mentioned embodiments of the present invention are only examples for clearly illustrating the present invention, rather than limiting the embodiments of the present invention. For those of ordinary skill in the art, various obvious changes, readjustments and substitutions can be made without departing from the protection scope of the present invention. There is no need and cannot be exhaustive of all implementations here. Any modifications, equivalent replacements and improvements made within the spirit and principle of the present invention shall be included within the protection scope of the claims of the present invention.
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席北斗等: "《地下水污染源强评价、分类与防控技术研究》", 30 June 2016, 中国环境出版社 * |
Cited By (3)
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CN115784420A (en) * | 2022-09-07 | 2023-03-14 | 河北工程大学 | Device for removing pollutants in underground water in situ |
CN115784420B (en) * | 2022-09-07 | 2024-05-10 | 河北工程大学 | A device for removing pollutants from groundwater in situ |
CN115889432A (en) * | 2022-12-20 | 2023-04-04 | 煜环环境科技有限公司 | Soil and underground water pollution cooperative remediation system and remediation method thereof |
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