CN114739456B - Multichannel PEM pure water electrolysis hydrogen production testing device and application method - Google Patents
Multichannel PEM pure water electrolysis hydrogen production testing device and application method Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及电解水制氢技术领域,特别涉及一种多通道PEM纯水电解制氢测试装置及使用方法。The invention relates to the technical field of hydrogen production by electrolysis of water, in particular to a multi-channel PEM pure water electrolysis hydrogen production test device and a use method.
背景技术Background technique
PEM纯水制氢具有稳定,清洁和无噪声等优点,是未来动力能源的技术制高点,也是国内外高校,科研机构和跨国企业的研究热点。在PEM电解纯水制氢中电解槽的研发和开发的各个环节中,PEM电解制氢单元的测试平台的技术水平起着至关重要的作用。然而市场现有的测试台架很少或仅能满足单个电解槽性能的测试,测试单一且不稳定。所以研发一种稳定,高效的PEM电解纯水制氢单元测试装置就十分重要。PEM pure water hydrogen production has the advantages of stability, cleanliness and no noise. It is the commanding height of future power energy technology, and it is also a research hotspot for universities, scientific research institutions and multinational companies at home and abroad. In all aspects of the R&D and development of electrolyzers in the PEM electrolysis of pure water for hydrogen production, the technical level of the test platform for the PEM electrolysis hydrogen production unit plays a vital role. However, the existing test benches in the market are seldom or only capable of testing the performance of a single electrolyzer, and the test is single and unstable. Therefore, it is very important to develop a stable and efficient PEM electrolysis pure water hydrogen production unit test device.
发明内容Contents of the invention
本发明目的在于提供一种多通道PEM纯水电解制氢测试装置及使用方法,以解决现有技术中所存在的一个或多个技术问题,至少提供一种有益的选择或创造条件。The purpose of the present invention is to provide a multi-channel PEM pure water electrolysis test device for hydrogen production and its use method to solve one or more technical problems in the prior art, and at least provide a beneficial option or create conditions.
为解决上述技术问题所采用的技术方案:The technical solution adopted for solving the above-mentioned technical problems:
首先本发明提供一种多通道PEM纯水电解制氢测试装置,其包括:机架、纯水供給机构、氢气检测组件和供电组件,机架前侧设置有测试台面、设置于测试台面后侧上部的控制面板,所述测试台面均布有多个用于装夹PEM电解槽的装夹支架,所述控制面板包括设置于上部的仪表显示区、设置于下部的操作区,所述仪表显示区设置有流量显示仪;纯水供給机构包括纯水供給管路、纯水冷却组件,所述纯水供給管路包括安装于机架内的水箱、连接于水箱上侧的补水电磁阀、设置有相互单独的多个供水通道的供水泵组、多根纯水供水管、多根纯水回水管,所述供水泵组设置有设置于仪表显示区的多通道压力控制仪,在所述水箱内设置有加热组件和第三传感器,所述纯水冷却组件的进水口与水箱相连,所述纯水冷却组件的出水口与多个供水通道的进水端连接,在所述操作区设置有分别与多个供水通道出水端连接的多个纯水供水接头、与水箱相连的多个纯水回水接头,在每个纯水供水接头与供水通道之间均设置有控制水阀,所述控制水阀设置于操作区,所述纯水供水管的一端与纯水供水接头一一对应连接,所述纯水回水管与所述纯水回水接头一一对应连接,对应的一对所述纯水供水管和纯水回水管的另一端与PEM电解槽的进、出水口可拆卸地连接;氢气检测组件包括安装于机架内的氢水分离器和干燥器、安装于仪表显示区上的智能露点仪、与流量显示仪连接的高压质量流量计、安装于操作区的多个氢气集流接头,所述氢气集流接头连接有氢气集流管,所述氢气集流管与PEM电解槽的氢气口可拆连接,多个所述氢气集流接头的内端与氢水分离器的进口连接,在每个所述氢气集流接头与氢水分离器的进气端之间依次设置有第二传感器和单向阀,所述氢水分离器的出气端与干燥器的进气端连接,在所述氢水分离器的出气端与干燥器的之间连接有设置于测试台面前侧的氢气压力表,所述干燥器的排气端通过三通接头分别与智能露点仪、高压质量流量计连接,在所述智能露点仪与干燥器之间设置有露点电磁阀,在所述高压质量流量计与干燥器之间设置有流量计电磁阀;供电组件包括安装于机架上的供电电源、与供电电源连接的电导仪、设置于操作区的多对供电接头,所述供电接头连接有供电导线,每一对所述供电接头通过两根供电导线与PEM电解槽的两电极可拆卸地连接,所述电导仪设置于仪表显示区,所述供电电源对多对供电接头供电;First of all, the present invention provides a multi-channel PEM pure water electrolysis test device for hydrogen production, which includes: a frame, a pure water supply mechanism, a hydrogen detection component and a power supply component. The upper control panel, the test bench is evenly distributed with a plurality of clamping brackets for clamping the PEM electrolyzer, the control panel includes an instrument display area arranged on the upper part and an operating area arranged on the lower part, and the instrument display The area is equipped with a flow display instrument; the pure water supply mechanism includes a pure water supply pipeline and a pure water cooling assembly, and the pure water supply pipeline includes a water tank installed in the frame, a water replenishment solenoid valve connected to the upper side of the water tank, and a set There are water supply pump sets with multiple independent water supply channels, multiple pure water supply pipes, and multiple pure water return pipes. The water supply pump set is provided with a multi-channel pressure controller arranged in the instrument display area. A heating assembly and a third sensor are arranged inside, the water inlet of the pure water cooling assembly is connected to the water tank, the water outlet of the pure water cooling assembly is connected to the water inlet ends of multiple water supply channels, and a A plurality of pure water supply joints respectively connected to the water outlets of the plurality of water supply channels, a plurality of pure water return joints connected to the water tank, and a control water valve is arranged between each pure water supply joint and the water supply channel. The control water valve is set in the operating area, one end of the pure water supply pipe is connected to the pure water supply joint in one-to-one correspondence, the pure water return pipe is connected to the pure water return joint in one-to-one correspondence, and the corresponding pair of The other end of the pure water supply pipe and the pure water return pipe are detachably connected to the water inlet and outlet of the PEM electrolyzer; The intelligent dew point meter on the device, the high-pressure mass flowmeter connected to the flow display instrument, and multiple hydrogen collecting joints installed in the operating area. The hydrogen collecting joints are connected with hydrogen collecting pipes, and the hydrogen collecting pipes are connected to the PEM The hydrogen port of the electrolyzer is detachably connected, and the inner ends of a plurality of the hydrogen collecting joints are connected with the inlet of the hydrogen-water separator, between each of the hydrogen collecting joints and the inlet end of the hydrogen-water separator. A second sensor and a one-way valve are provided, the outlet end of the hydrogen-water separator is connected to the inlet end of the dryer, and a test bench is connected between the outlet end of the hydrogen-water separator and the dryer. The hydrogen pressure gauge on the front side, the exhaust end of the dryer is respectively connected to the intelligent dew point meter and the high-pressure mass flow meter through a three-way joint, and a dew point solenoid valve is set between the smart dew point meter and the dryer. A flowmeter solenoid valve is set between the high-pressure mass flowmeter and the dryer; the power supply assembly includes a power supply installed on the frame, a conductivity meter connected to the power supply, and multiple pairs of power supply connectors arranged in the operating area. The joints are connected with power supply wires, and each pair of power supply joints is detachably connected to the two electrodes of the PEM electrolyzer through two power supply wires, the conductivity meter is arranged in the instrument display area, and the power supply supplies power to multiple pairs of power supply joints ;
多对供电接头、多个氢气集流接头、多个纯水供水接头、多个纯水回水接头与多个控制水阀一一对应排列设置。Multiple pairs of power supply joints, multiple hydrogen gas collecting joints, multiple pure water supply joints, multiple pure water return joints and multiple control water valves are arranged in one-to-one correspondence.
本多通道PEM纯水电解制氢测试装置的有益效果是:在使用时,可将多个PEM电解槽装夹于多个装夹支架上,然后将对应的一对所述纯水供水管和纯水回水管的另一端与PEM电解槽的进、出水口连接,对应的氢气集流管与PEM电解槽的氢气口连接,将对应的一对所述供电接头通过两根供电导线与PEM电解槽的两电极连接,水箱的纯水经过加热后再经过纯水冷却组件进行冷却,使得从纯水冷却组件出来的纯水达到工作温度,通过多通道压力控制仪来控制供水泵组中每个供水通道的纯水流量及压力,打开对应的几个控制水阀,电导仪控制供电电源对每个PEM电解槽供给不同电流、电压,使得多个PEM电解槽可在不同的工况下进行电解水,纯水从PEM电解槽出来回流至水箱,PEM电解槽出来的氢气通过第二传感器和单向阀后,进入氢水分离器和干燥器,氢水分离器将氢气和水分离,干燥器对氢气干燥,经过干燥处理的氢气分为两条支路,支路一的氢依次经过露点电磁阀、智能露点仪,智能露点仪检测氢气中含水量,达到测量氢气纯度的目的,支路二的氢气依次经过流量计电磁阀、高压质量流量计,高压质量流量计可测试产氢速率,通过控制供电电源的串并联组合和多个供水通道的供水泵组的水流量,可同时对多个PEM电解槽在不同电流、电压、流量下的测试,提高了测试效率,并且,控制面板上的仪表显示区和操作区集成了显示和操作的区域,操作起来更加方便直观。The beneficial effect of the multi-channel PEM pure water electrolysis hydrogen production test device is: when in use, multiple PEM electrolytic cells can be clamped on multiple clamping brackets, and then the corresponding pair of pure water supply pipes and The other end of the pure water return pipe is connected to the water inlet and outlet of the PEM electrolyzer, and the corresponding hydrogen manifold is connected to the hydrogen port of the PEM electrolyzer, and the corresponding pair of power supply connectors are connected to the PEM electrolyzer through two power supply wires. The two electrodes of the tank are connected, the pure water in the water tank is heated and then cooled by the pure water cooling component, so that the pure water from the pure water cooling component reaches the working temperature, and the multi-channel pressure controller is used to control each of the water supply pumps. The pure water flow and pressure of the water supply channel, open the corresponding control water valves, the conductivity meter controls the power supply to supply different currents and voltages to each PEM electrolyzer, so that multiple PEM electrolyzers can perform electrolysis under different working conditions Water, pure water flows back to the water tank from the PEM electrolyzer, the hydrogen gas from the PEM electrolyzer passes through the second sensor and the one-way valve, and then enters the hydrogen-water separator and dryer, the hydrogen-water separator separates hydrogen and water, and the dryer The hydrogen is dried, and the dried hydrogen is divided into two branches. The hydrogen in the first branch passes through the dew point solenoid valve and the intelligent dew point meter. The smart dew point meter detects the water content in the hydrogen to achieve the purpose of measuring the purity of the hydrogen. The hydrogen gas passes through the flowmeter solenoid valve and the high-pressure mass flowmeter in turn. The high-pressure mass flowmeter can test the hydrogen production rate. The testing of PEM electrolytic cells under different currents, voltages and flow rates improves the test efficiency, and the instrument display area and operation area on the control panel integrate display and operation areas, making the operation more convenient and intuitive.
作为上述技术方案的进一步改进,在所述智能露点仪与露点电磁阀之间设置有减压阀,所述减压阀设置于测试台面的前侧,在所述氢气压力表与干燥器之间依次连接有超压开关、压力跟踪器、背压阀和输出电磁阀,所述背压阀设置于测试台面的前侧。为了保证氢气具有一定的压强,设置了超压开关,在设定的压力时,超压开关才受控打开,氢气依次流压力跟踪器、背压阀和输出电磁阀后进入干燥器。As a further improvement of the above technical solution, a decompression valve is provided between the intelligent dew point meter and the dew point solenoid valve, the decompression valve is provided on the front side of the test bench, between the hydrogen pressure gauge and the dryer An overpressure switch, a pressure tracker, a backpressure valve and an output solenoid valve are connected in sequence, and the backpressure valve is arranged on the front side of the test table. In order to ensure that the hydrogen has a certain pressure, an overpressure switch is set up. When the set pressure is reached, the overpressure switch is controlled to open, and the hydrogen flows into the dryer through the pressure tracker, back pressure valve and output solenoid valve in sequence.
作为上述技术方案的进一步改进,在所述背压阀和输出电磁阀之间连接有排空管路,所述排空管路依次连接有排空电磁阀、排空手动阀、排空传感器。As a further improvement of the above technical solution, an emptying pipeline is connected between the back pressure valve and the output electromagnetic valve, and the emptying pipeline is sequentially connected with an emptying solenoid valve, an emptying manual valve, and an emptying sensor.
如果氢气压力过于设定值或者氢气量较多时,超压开关和排空电磁阀打开,氢气通过排空管路往外排。If the hydrogen pressure exceeds the set value or the amount of hydrogen is large, the overpressure switch and the emptying solenoid valve are opened, and the hydrogen is discharged through the emptying pipeline.
作为上述技术方案的进一步改进,所述氢水分离器的排水口通过回水管路与水箱连接,所述回水管路安装有回水电磁阀。As a further improvement of the above technical solution, the drain of the hydrogen-water separator is connected to the water tank through a return water pipeline, and the return water pipeline is equipped with a return water solenoid valve.
当氢水分离器中的水达到设定的值时,回水电磁阀受控打开,水回流至水箱。When the water in the hydrogen-water separator reaches the set value, the return water solenoid valve is controlled to open, and the water returns to the water tank.
作为上述技术方案的进一步改进,所述氢水分离器为多级氢水分离器结构,所述干燥器包括多个依次连接的干燥管。As a further improvement of the above technical solution, the hydrogen-water separator is a multi-stage hydrogen-water separator structure, and the dryer includes a plurality of drying pipes connected in sequence.
本方案采用多级氢水分离器的结构,提高氢水分离的效果,以及设置了多个干燥管来提高干燥的效果。This scheme adopts the structure of multi-stage hydrogen-water separator to improve the effect of hydrogen-water separation, and sets up multiple drying pipes to improve the drying effect.
作为上述技术方案的进一步改进,所述供水泵组与纯水冷却组件之间设置有水质水温检测仪,所述供水泵组的出口连接有与多个供水通道连接的排水管路,所述排水管路安装有排水电磁阀。As a further improvement of the above technical solution, a water quality and temperature detector is provided between the water supply pump set and the pure water cooling assembly, and the outlet of the water supply pump set is connected to a drainage pipeline connected to a plurality of water supply channels. The pipeline is equipped with a drain solenoid valve.
本方案设置了水质水温检测仪来监测纯水的水质,如果水质不合格,排水电磁阀打开,供水泵组将水往排水管路排,水质合格后,才打开对应的控制水阀。In this plan, a water quality and temperature detector is set up to monitor the water quality of pure water. If the water quality is unqualified, the drainage solenoid valve is opened, and the water supply pump unit discharges the water to the drainage pipeline. After the water quality is qualified, the corresponding control water valve is opened.
作为上述技术方案的进一步改进,所述水箱的底部设置有排水口,所述排水口通过排水阀与排水管路连接,所述第三传感器包括液位传感器和温度传感器。As a further improvement of the above technical solution, a drain port is provided at the bottom of the water tank, the drain port is connected to the drain pipeline through a drain valve, and the third sensor includes a liquid level sensor and a temperature sensor.
本方案中的水箱如果水位高于设定值上限,排水阀打开,而低于设定值下限,补水电磁阀开启。If the water level of the water tank in this scheme is higher than the upper limit of the set value, the drain valve will be opened, and if it is lower than the lower limit of the set value, the replenishment solenoid valve will be opened.
作为上述技术方案的进一步改进,所述纯水冷却组件包括依次闭环连接的缓冲罐、换热器、冷水机和循环泵,所述换热器的进、出水口分别与水箱、多个供水通道的进水端相连,所述供水泵组为多通道蠕动泵。As a further improvement of the above technical solution, the pure water cooling assembly includes a buffer tank, a heat exchanger, a water chiller and a circulating pump connected sequentially in a closed loop, and the water inlet and outlet of the heat exchanger are respectively connected to the water tank and multiple water supply channels The water inlet end is connected, and the water supply pump set is a multi-channel peristaltic pump.
本方案通过缓冲罐、换热器、冷水机和循环泵形成的冷媒冷却回路来与纯水进行冷却。This solution cools with pure water through a refrigerant cooling circuit formed by buffer tanks, heat exchangers, chillers and circulating pumps.
作为上述技术方案的进一步改进,所述机架为机箱结构,在所述机架内设置有相互连通的安装上腔室和安装下腔室,在所述机架的顶部设置有散热风扇。As a further improvement of the above technical solution, the frame is a case structure, an upper installation chamber and a lower installation chamber communicating with each other are arranged inside the frame, and a cooling fan is arranged on the top of the frame.
散热风扇主要对机架内部进行散热,避免出现过热的现象。安装上腔室和安装下腔室用来安装各个零部件。The cooling fan mainly dissipates heat inside the rack to avoid overheating. The upper chamber and the lower chamber are installed to install various components.
此外,本发明还提供一种多通道PEM纯水电解制氢测试装置的使用方法,多通道PEM纯水电解制氢测试装置还包括PLC控制单元,所述PLC控制单元与各个电元件控制连接,具体步骤如下:In addition, the present invention also provides a method for using a multi-channel PEM pure water electrolysis hydrogen production test device. The multi-channel PEM pure water electrolysis hydrogen production test device also includes a PLC control unit, and the PLC control unit is connected to each electrical component for control, Specific steps are as follows:
S1、将待测试的多个PEM电解槽一一对应地装夹于装夹支架上,将多对所述纯水供水管和纯水回水管的另一端与多个PEM电解槽的进、出水口连接好,以及将多个所述氢气集流管与多个PEM电解槽的氢气口连接好,多对所述供电接头通过供电导线与PEM电解槽的两电极连接好;S1. Clamp the multiple PEM electrolyzers to be tested on the clamping bracket one by one, and connect the other ends of the pure water supply pipes and the pure water return pipes to the inlet and outlet of the multiple PEM electrolyzers. The water outlet is connected well, and a plurality of the hydrogen gas collectors are connected with the hydrogen gas ports of the plurality of PEM electrolyzers, and many pairs of the power supply connectors are connected with the two electrodes of the PEM electrolyzer through the power supply wires;
S2、自来水通过小型纯水机与补水电磁阀连接,并对水箱进行供水,加热组件对水箱内的水进行加热,第三传感器监控水箱的水位及温度;S2. The tap water is connected to the water supply solenoid valve through a small pure water machine, and supplies water to the water tank. The heating component heats the water in the water tank, and the third sensor monitors the water level and temperature of the water tank;
S3、水箱内的纯水加热至设定的温度后,经过纯水冷却组件进行冷却,使得从纯水冷却组件出来的纯水达到工作温度;S3. After the pure water in the water tank is heated to the set temperature, it is cooled by the pure water cooling component, so that the pure water coming out of the pure water cooling component reaches the working temperature;
S4、水质水温检测仪对纯水冷却组件出来纯粹进行探测,假设探测水质不合格,则打开排水电磁阀,启动供水泵组,将不合格纯水排掉,再对水箱进行补水、加热、冷却,使得水质水温检测仪探测水质合格。S4. The water quality and temperature detector simply detects the pure water cooling components. If the detected water quality is unqualified, open the drain solenoid valve, start the water supply pump group, drain the unqualified pure water, and then replenish, heat and cool the water tank , so that the water quality and temperature detector detects the water quality is qualified.
S5、打开各个控制水阀,启动供水泵组,多通道压力控制仪控制多个供水通道的水流量和压力,水进入PEM电解槽达到电解制氢工作要求后,PLC控制单元控制供电电源的串并联组合,使得施加在每个PEM电解槽的电流电压相异,最后水流回水箱;S5. Open each control water valve, start the water supply pump group, and the multi-channel pressure controller controls the water flow and pressure of multiple water supply channels. After the water enters the PEM electrolyzer to meet the working requirements of electrolytic hydrogen production, the PLC control unit controls the power supply. Parallel combination, so that the current and voltage applied to each PEM electrolyzer are different, and finally the water flows back to the water tank;
S6、PEM电解槽电解生成的氢气通过第二传感器和单向阀后,进入氢水分离器和干燥器,氢水分离器将氢气和水分离,干燥器对氢气干燥,经过干燥处理的氢气分为两条支路,支路一的氢依次经过露点电磁阀、智能露点仪,智能露点仪检测氢气中含水量,达到测量氢气纯度的目的,支路二的氢气依次经过流量计电磁阀、高压质量流量计,高压质量流量计可测试产氢速率。S6. The hydrogen generated by the electrolysis of the PEM electrolyzer passes through the second sensor and the one-way valve, and then enters the hydrogen-water separator and the dryer. The hydrogen-water separator separates the hydrogen from water, and the dryer dries the hydrogen. There are two branches. The hydrogen in branch one passes through the dew point solenoid valve and the smart dew point meter in turn. The smart dew point meter detects the water content in the hydrogen to achieve the purpose of measuring the purity of the hydrogen. The hydrogen in the branch two goes through the flow meter solenoid valve, high pressure Mass flow meter, high pressure mass flow meter can test hydrogen production rate.
附图说明Description of drawings
下面结合附图和实施例对本发明做进一步的说明;Below in conjunction with accompanying drawing and embodiment the present invention will be further described;
图1是本发明所提供的通道PEM纯水电解制氢测试装置,其一实施例其中一个视角下的结构示意图;Fig. 1 is a schematic structural view of an embodiment of the channel PEM pure water electrolysis hydrogen production test device provided by the present invention under one viewing angle;
图2是本发明所提供的通道PEM纯水电解制氢测试装置,其一实施例另外一个视角下的结构示意图;Fig. 2 is a structural schematic view of another perspective of an embodiment of the channel PEM pure water electrolysis hydrogen production test device provided by the present invention;
图3是本发明所提供的通道PEM纯水电解制氢测试装置,其一实施例的侧视图;Fig. 3 is the side view of an embodiment of the channel PEM pure water electrolysis hydrogen production test device provided by the present invention;
图4是本发明所提供的通道PEM纯水电解制氢测试装置,其一实施例的控制流程图。Fig. 4 is a control flow diagram of an embodiment of the channel PEM pure water electrolysis hydrogen production test device provided by the present invention.
具体实施方式Detailed ways
本部分将详细描述本发明的具体实施例,本发明之较佳实施例在附图中示出,附图的作用在于用图形补充说明书文字部分的描述,使人能够直观地、形象地理解本发明的每个技术特征和整体技术方案,但其不能理解为对本发明保护范围的限制。This part will describe the specific embodiment of the present invention in detail, and the preferred embodiment of the present invention is shown in the accompanying drawings. Each technical feature and overall technical solution of the invention, but it should not be understood as a limitation on the protection scope of the present invention.
在本发明的描述中,需要理解的是,涉及到方位描述,例如上、下、前、后、左、右等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that the orientation descriptions, such as up, down, front, back, left, right, etc. indicated orientations or positional relationships are based on the orientations or positional relationships shown in the drawings, and are only In order to facilitate the description of the present invention and simplify the description, it does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and thus should not be construed as limiting the present invention.
在本发明的描述中,如果具有“若干”之类的词汇描述,其含义是一个或者多个,多个的含义是两个以上,大于、小于、超过等理解为不包括本数,以上、以下、以内等理解为包括本数。In the description of the present invention, if there is a word description such as "several", the meaning is one or more, and the meaning of multiple is more than two. Greater than, less than, exceeding, etc. are understood as not including the original number, above and below , within, etc. are understood as including the original number.
本发明的描述中,除非另有明确的限定,设置、安装、连接等词语应做广义理解,所属技术领域技术人员可以结合技术方案的具体内容合理确定上述词语在本发明中的具体含义。In the description of the present invention, unless otherwise clearly defined, words such as setting, installation, and connection should be understood in a broad sense, and those skilled in the art can reasonably determine the specific meanings of the above words in the present invention in combination with the specific content of the technical solution.
参照图1至图4,本发明的多通道PEM纯水电解制氢测试装置作出如下实施例:Referring to Fig. 1 to Fig. 4, the multi-channel PEM pure water electrolysis hydrogen production test device of the present invention makes the following embodiments:
本实施例的多通道PEM纯水电解制氢测试装置包括机架30、纯水供給机构、氢气检测组件和供电组件。The multi-channel PEM pure water electrolysis test device for hydrogen production in this embodiment includes a frame 30, a pure water supply mechanism, a hydrogen detection component and a power supply component.
其中机架30前侧设置有测试台面32、设置于测试台面32后侧上部的控制面板33,所述测试台面32均布有多个用于装夹PEM电解槽10的装夹支架,所述控制面板33包括设置于上部的仪表显示区、设置于下部的操作区,所述仪表显示区设置有与各个流量传感器连接的流量显示仪27,并且所述机架30为机箱结构,在所述机架30内设置有相互连通的安装上腔室和安装下腔室,在所述机架30的顶部设置有散热风扇31散热风扇31主要对机架30内部进行散热,避免出现过热的现象,安装上腔室和安装下腔室用来安装各个零部件。Wherein the front side of the frame 30 is provided with a test table 32, a control panel 33 arranged on the upper part of the rear side of the test table 32, the test table 32 is evenly distributed with a plurality of clamping brackets for clamping the PEM electrolyzer 10, the The control panel 33 includes an instrument display area arranged on the upper part and an operating area arranged on the lower part. The instrument display area is provided with a flow indicator 27 connected to each flow sensor, and the frame 30 is a cabinet structure. The frame 30 is provided with an upper chamber and a lower chamber communicated with each other. A heat dissipation fan 31 is arranged on the top of the frame 30. The heat dissipation fan 31 mainly radiates heat inside the frame 30 to avoid overheating. The upper chamber and the lower chamber are installed to install various components.
而纯水供給机构包括纯水供給管路、纯水冷却组件,所述纯水供給管路包括安装于机架30内的水箱1、连接于水箱1上侧的补水电磁阀2、设置有相互单独的多个供水通道的供水泵组、多根纯水供水管34、多根纯水回水管35,所述供水泵组设置有设置于仪表显示区的多通道压力控制仪29,所述供水泵组为多通道蠕动泵8,多通道压力控制仪29用于控制每个供水通道的泵头驱动力,在所述水箱1内设置有加热组件和第三传感器,所述供水泵组与纯水冷却组件之间设置有水质水温检测仪44,所述供水泵组的出口连接有与多个供水通道连接的排水管路,所述排水管路安装有排水电磁阀3,所述水箱1的底部设置有排水口,所述排水口通过排水阀45与排水管路连接,所述第三传感器包括液位传感器和温度传感器,本实施例设置了水质水温检测仪44来监测纯水的水质,如果水质不合格,排水电磁阀3打开,供水泵组将水往排水管路排,水质合格后,才打开对应的控制水阀9,水箱1如果水位高于设定值上限,排水阀45打开,而低于设定值下限,补水电磁阀2开启,其中补水电磁阀2连接过小型纯水机。The pure water supply mechanism includes a pure water supply pipeline and a pure water cooling assembly. Separate water supply pumps for multiple water supply channels, multiple pure water supply pipes 34, and multiple pure water return pipes 35, the water supply pumps are provided with a multi-channel pressure controller 29 arranged in the instrument display area, and the water supply The water pump group is a multi-channel peristaltic pump 8, and the multi-channel pressure controller 29 is used to control the driving force of the pump head of each water supply channel. A heating assembly and a third sensor are arranged in the water tank 1. A water quality and temperature detector 44 is arranged between the water cooling components. The outlet of the water supply pump group is connected with a drainage pipeline connected with a plurality of water supply channels. The drainage pipeline is equipped with a drainage solenoid valve 3. The water tank 1 The bottom is provided with a drain, and the drain is connected to the drain pipeline through a drain valve 45. The third sensor includes a liquid level sensor and a temperature sensor. In this embodiment, a water quality and temperature detector 44 is provided to monitor the water quality of pure water. If the water quality is unqualified, the drain solenoid valve 3 is opened, and the water supply pump group drains the water to the drain pipeline. After the water quality is qualified, the corresponding control water valve 9 is opened. If the water level of the water tank 1 is higher than the upper limit of the set value, the drain valve 45 is opened. , and is lower than the lower limit of the set value, the water replenishment solenoid valve 2 is opened, wherein the water replenishment solenoid valve 2 is connected to a small pure water machine.
本实施例的所述纯水冷却组件包括依次闭环连接的缓冲罐5、换热器4、冷水机7和循环泵6,所述换热器4的进、出水口分别与水箱1、多个供水通道的进水端相连,通过缓冲罐5、换热器4、冷水机7和循环泵6形成的冷媒冷却回路来与纯水进行冷却。The pure water cooling assembly of the present embodiment comprises a buffer tank 5, a heat exchanger 4, a water chiller 7 and a circulating pump 6 which are sequentially connected in a closed loop. The water inlet end of the water supply channel is connected, and is cooled with pure water through a refrigerant cooling circuit formed by a buffer tank 5 , a heat exchanger 4 , a water chiller 7 and a circulation pump 6 .
在所述操作区设置有分别与多个供水通道出水端连接的多个纯水供水接头、与水箱1相连的多个纯水回水接头,在每个纯水供水接头与供水通道之间均设置有控制水阀9,所述控制水阀9设置于操作区,所述纯水供水管34的一端与纯水供水接头一一对应连接,所述纯水回水管35与所述纯水回水接头一一对应连接,对应的一对所述纯水供水管34和纯水回水管35的另一端与PEM电解槽10的进、出水口可拆卸地连接。A plurality of pure water supply joints respectively connected to the water outlets of a plurality of water supply channels and a plurality of pure water return joints connected to the water tank 1 are arranged in the operation area, and each pure water supply joint and the water supply channel are connected to each other. A control water valve 9 is provided, and the control water valve 9 is set in the operating area, one end of the pure water supply pipe 34 is connected to the pure water supply joint one by one, and the pure water return pipe 35 is connected to the pure water return pipe. The water connectors are connected one by one, and the other ends of the corresponding pair of pure water supply pipes 34 and pure water return pipes 35 are detachably connected to the water inlet and outlet of the PEM electrolytic cell 10 .
在使用时,将多个PEM电解槽10装夹于多个装夹支架上,然后将对应的一对所述纯水供水管34和纯水回水管35的另一端与PEM电解槽10的进、出水口连接。When in use, a plurality of PEM electrolyzers 10 are clamped on a plurality of clamping brackets, and then the corresponding pair of pure water supply pipes 34 and the other end of the pure water return pipe 35 are connected to the inlet of the PEM electrolyzer 10 , Outlet connection.
氢气检测组件包括安装于机架30内的氢水分离器13和干燥器、安装于仪表显示区上的智能露点仪24、与流量显示仪27连接的高压质量流量计26、安装于操作区的多个氢气集流接头,所述氢气集流接头连接有氢气集流管36,所述氢气集流管36与PEM电解槽10的氢气口可拆连接,多个所述氢气集流接头的内端与氢水分离器13的进口连接,在每个所述氢气集流接头与氢水分离器13的进气端之间依次设置有第二传感器11和单向阀12,所述氢水分离器13的出气端与干燥器的进气端连接,在所述氢水分离器13的出气端与干燥器的之间连接有设置于测试台面32前侧的氢气压力表15,所述干燥器的排气端通过三通接头分别与智能露点仪24、高压质量流量计26连接,在所述智能露点仪24与干燥器之间设置有露点电磁阀22,在所述高压质量流量计26与干燥器之间设置有流量计电磁阀25。The hydrogen detection assembly includes a hydrogen-water separator 13 and a dryer installed in the frame 30, an intelligent dew point meter 24 installed on the instrument display area, a high-pressure mass flow meter 26 connected to the flow display instrument 27, and a A plurality of hydrogen gas collecting joints, the hydrogen gas collecting joints are connected with a hydrogen gas collecting pipe 36, and the hydrogen gas collecting pipe 36 is detachably connected with the hydrogen port of the PEM electrolyzer 10, and the interior of a plurality of the hydrogen gas collecting joints end is connected with the inlet of the hydrogen-water separator 13, and a second sensor 11 and a one-way valve 12 are sequentially arranged between each hydrogen gas collecting joint and the inlet end of the hydrogen-water separator 13, and the hydrogen-water separator The outlet end of device 13 is connected with the inlet end of drier, is connected with the hydrogen pressure gauge 15 that is arranged on the front side of test bench 32 between the outlet end of described hydrogen-water separator 13 and drier, and described drier The exhaust end of the exhaust port is respectively connected with the smart dew point meter 24 and the high-pressure mass flow meter 26 through a tee joint, and a dew point electromagnetic valve 22 is arranged between the smart dew point meter 24 and the drier, and between the high-pressure mass flow meter 26 and the dryer. A flow meter solenoid valve 25 is arranged between the dryers.
进一步地,在所述智能露点仪24与露点电磁阀22之间设置有减压阀23,所述减压阀23设置于测试台面32的前侧,在所述氢气压力表15与干燥器之间依次连接有超压开关16、压力跟踪器17、背压阀18和输出电磁阀19,所述背压阀18设置于测试台面32的前侧,为了保证氢气具有一定的压强,设置了超压开关16,在设定的压力时,超压开关16才受控打开,氢气依次流压力跟踪器17、背压阀18和输出电磁阀19后进入干燥器。Further, a decompression valve 23 is provided between the intelligent dew point meter 24 and the dew point solenoid valve 22, and the decompression valve 23 is provided on the front side of the test table 32, between the hydrogen pressure gauge 15 and the dryer. An overpressure switch 16, a pressure tracker 17, a backpressure valve 18 and an output solenoid valve 19 are sequentially connected in between. When the pressure switch 16 is set, the overpressure switch 16 is controlled to open, and the hydrogen gas flows through the pressure tracker 17, the back pressure valve 18 and the output solenoid valve 19 and then enters the dryer.
并且,在所述背压阀18和输出电磁阀19之间连接有排空管路39,所述排空管路39依次连接有排空电磁阀21、排空手动阀40、排空传感器41,如果氢气压力过于设定值或者氢气量较多时,超压开关16和排空电磁阀21打开,氢气通过排空管路39往外排。Moreover, an emptying pipeline 39 is connected between the back pressure valve 18 and the output solenoid valve 19, and the emptying pipeline 39 is sequentially connected with an emptying solenoid valve 21, an emptying manual valve 40, and an emptying sensor 41. , if the hydrogen pressure exceeds the set value or the amount of hydrogen is large, the overpressure switch 16 and the emptying solenoid valve 21 are opened, and the hydrogen is discharged through the emptying pipeline 39 .
此外,所述氢水分离器13的排水口通过回水管路42与水箱1连接,所述回水管路42安装有回水电磁阀43,当氢水分离器13中的水达到设定的值时,回水电磁阀43受控打开,水回流至水箱1。In addition, the drain outlet of the hydrogen-water separator 13 is connected to the water tank 1 through the water return pipeline 42, and the water return pipeline 42 is equipped with a return water solenoid valve 43. When the water in the hydrogen-water separator 13 reaches the set value , the return water solenoid valve 43 is controlled to open, and the water returns to the water tank 1.
本实施例中的所述氢水分离器13为多级氢水分离器结构,所述干燥器包括多个依次连接的干燥管20,采用多级氢水分离器的结构,提高氢水分离的效果,以及设置了多个干燥管20来提高干燥的效果。The hydrogen-water separator 13 in this embodiment is a multi-stage hydrogen-water separator structure, and the dryer includes a plurality of drying pipes 20 connected in sequence, and adopts the structure of a multi-stage hydrogen-water separator to improve the efficiency of hydrogen-water separation. effect, and a plurality of drying pipes 20 are provided to improve the drying effect.
在使用时,对应的氢气集流管36与PEM电解槽10的氢气口连接。In use, the corresponding hydrogen gas header 36 is connected to the hydrogen gas port of the PEM electrolyzer 10 .
供电组件包括安装于机架30上的供电电源37、与供电电源37连接的电导仪28、设置于操作区的多对供电接头38,所述供电接头38连接有供电导线,每一对所述供电接头38通过两根供电导线与PEM电解槽10的两电极可拆卸地连接,所述电导仪28设置于仪表显示区,所述供电电源37对多对供电接头38供电,在使用时,将对应的一对所述供电接头38通过两根供电导线与PEM电解槽10的两电极连接。The power supply assembly includes a power supply 37 installed on the frame 30, a conductivity meter 28 connected to the power supply 37, a plurality of pairs of power supply joints 38 arranged in the operating area, and the power supply joints 38 are connected with power supply wires, and each pair of the power supply The power supply connector 38 is detachably connected to the two electrodes of the PEM electrolyzer 10 by two power supply wires, the conductivity meter 28 is arranged in the instrument display area, and the power supply 37 supplies power to many pairs of power supply connectors 38. When in use, the The corresponding pair of power supply connectors 38 are connected to the two electrodes of the PEM electrolyzer 10 through two power supply wires.
本实施例还提供一种多通道PEM纯水电解制氢测试装置的使用方法,多通道PEM纯水电解制氢测试装置还包括PLC控制单元,所述PLC控制单元与各个电元件控制连接,具体步骤如下:This embodiment also provides a method for using a multi-channel PEM pure water electrolysis hydrogen production test device. The multi-channel PEM pure water electrolysis hydrogen production test device also includes a PLC control unit, and the PLC control unit is connected to each electrical component for control, specifically Proceed as follows:
S1、将待测试的多个PEM电解槽10一一对应地装夹于装夹支架上,将多对所述纯水供水管34和纯水回水管35的另一端与多个PEM电解槽10的进、出水口连接好,以及将多个所述氢气集流管36与多个PEM电解槽10的氢气口连接好,多对所述供电接头38通过供电导线与PEM电解槽10的两电极连接好;S1, a plurality of PEM electrolytic cells 10 to be tested are clamped on the clamping bracket one by one, and the other ends of the multiple pairs of pure water supply pipes 34 and pure water return pipes 35 are connected to a plurality of PEM electrolytic cells 10 The water inlet and outlet are connected well, and a plurality of hydrogen gas collectors 36 are connected with the hydrogen gas ports of a plurality of PEM electrolyzers 10, and many pairs of the power supply joints 38 are connected to the two electrodes of the PEM electrolyzer 10 through power supply wires. connected;
S2、自来水通过小型纯水机与补水电磁阀2连接,并对水箱1进行供水,加热组件对水箱1内的水进行加热,第三传感器监控水箱1的水位及温度;S2. The tap water is connected to the water supply solenoid valve 2 through a small pure water machine, and supplies water to the water tank 1. The heating component heats the water in the water tank 1, and the third sensor monitors the water level and temperature of the water tank 1;
S3、水箱1内的纯水加热至设定的温度后,经过纯水冷却组件进行冷却,使得从纯水冷却组件出来的纯水达到工作温度;S3. After the pure water in the water tank 1 is heated to the set temperature, it is cooled by the pure water cooling assembly, so that the pure water coming out of the pure water cooling assembly reaches the working temperature;
S4、水质水温检测仪44对纯水冷却组件出来纯粹进行探测,假设探测水质不合格,则打开排水电磁阀3,启动供水泵组,将不合格纯水排掉,再对水箱1进行补水、加热、冷却,使得水质水温检测仪44探测水质合格。S4. The water quality and temperature detector 44 simply detects the pure water cooling assembly. If the detected water quality is unqualified, then open the drain solenoid valve 3, start the water supply pump group, drain the unqualified pure water, and then replenish water to the water tank 1. Heating and cooling make the water quality and temperature detector 44 detect that the water quality is qualified.
S5、打开各个控制水阀9,启动供水泵组,多通道压力控制仪29控制多个供水通道的水流量和压力,水进入PEM电解槽10达到电解制氢工作要求后,PLC控制单元控制供电电源37的串并联组合,使得施加在每个PEM电解槽10的电流电压相异,最后水流回水箱1;S5, open each control water valve 9, start the water supply pump group, the multi-channel pressure controller 29 controls the water flow and pressure of multiple water supply channels, after the water enters the PEM electrolyzer 10 to meet the working requirements of electrolytic hydrogen production, the PLC control unit controls the power supply The series-parallel combination of the power supply 37 makes the current and voltage applied to each PEM electrolyzer 10 different, and finally the water flows back to the water tank 1;
S6、PEM电解槽10电解生成的氢气通过第二传感器11和单向阀12后,进入氢水分离器13和干燥器,氢水分离器13将氢气和水分离,干燥器对氢气干燥,经过干燥处理的氢气分为两条支路,支路一的氢依次经过露点电磁阀22、智能露点仪24,智能露点仪24检测氢气中含水量,达到测量氢气纯度的目的,支路二的氢气依次经过流量计电磁阀25、高压质量流量计26,高压质量流量计26可测试产氢速率。S6, the hydrogen generated by the electrolysis of the PEM electrolyzer 10 passes through the second sensor 11 and the one-way valve 12, then enters the hydrogen-water separator 13 and the drier, the hydrogen-water separator 13 separates the hydrogen from water, and the drier dries the hydrogen, and passes through The hydrogen in the drying process is divided into two branches. The hydrogen in the branch one passes through the dew point solenoid valve 22 and the intelligent dew point meter 24 in turn. The intelligent dew point meter 24 detects the water content in the hydrogen to achieve the purpose of measuring the purity of the hydrogen gas. The hydrogen in the branch two Pass through the flowmeter solenoid valve 25 and the high-pressure mass flowmeter 26 in turn, and the high-pressure mass flowmeter 26 can test the hydrogen production rate.
本实施例通过控制供电电源37的串并联组合和多个供水通道的供水泵组的水流量,可同时对多个PEM电解槽10在不同电流、电压、流量下的测试,提高了测试效率,并且,控制面板33上的仪表显示区和操作区集成了显示和操作的区域,操作起来更加方便直观。In this embodiment, by controlling the series-parallel combination of the power supply 37 and the water flow of the water supply pump group of multiple water supply channels, multiple PEM electrolytic cells 10 can be tested under different currents, voltages, and flow rates at the same time, which improves the test efficiency. Moreover, the instrument display area and the operation area on the control panel 33 integrate display and operation areas, making the operation more convenient and intuitive.
以上对本发明的较佳实施方式进行了具体说明,但本发明创造并不限于所述实施例,熟悉本领域的技术人员在不违背本发明精神的前提下还可作出种种的等同变型或替换,这些等同的变型或替换均包含在本申请权利要求所限定的范围内。The preferred embodiments of the present invention have been described in detail above, but the invention is not limited to the described embodiments, and those skilled in the art can also make various equivalent modifications or replacements without violating the spirit of the present invention. These equivalent modifications or replacements are all within the scope defined by the claims of the present application.
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