CN114720404A - Soil crude oil pollutant detection device - Google Patents
Soil crude oil pollutant detection device Download PDFInfo
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- CN114720404A CN114720404A CN202110009027.7A CN202110009027A CN114720404A CN 114720404 A CN114720404 A CN 114720404A CN 202110009027 A CN202110009027 A CN 202110009027A CN 114720404 A CN114720404 A CN 114720404A
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Abstract
本发明提供了一种土壤原油污染物检测装置,包括:外壳,外壳开设有透明的光学窗口,土壤原油污染物检测装置插入待测土壤中,待测土壤遮挡在光学窗口外侧;激光准直透镜,激光准直透镜与红外激光器连接,并能够发射激光;激光接收透镜,激光接收透镜与光学分析仪器连接,并能够接收反射回来的激光,激光准直透镜发出的激光经过光学窗口照射到待测土壤上,并在待测土壤的漫反射作用下再次经过光学窗口射入激光接收透镜。本发明解决了现有技术中的土壤中原油污染物检测过程复杂、费时费力的问题。
The invention provides a soil crude oil pollutant detection device, comprising: a casing, the casing is provided with a transparent optical window, the soil crude oil pollutant detection device is inserted into the soil to be measured, and the soil to be measured is shielded outside the optical window; a laser collimating lens , the laser collimating lens is connected with the infrared laser and can emit laser light; the laser receiving lens, the laser receiving lens is connected with the optical analysis instrument, and can receive the reflected laser light, and the laser light emitted by the laser collimating lens is irradiated to the object to be measured through the optical window On the soil, and under the effect of the diffuse reflection of the soil to be tested, the laser is again injected into the laser receiving lens through the optical window. The invention solves the problems of complicated, time-consuming and labor-intensive detection process of crude oil pollutants in soil in the prior art.
Description
技术领域technical field
本发明涉及安全环保技术领域,具体而言,涉及一种土壤原油污染物检测装置。The invention relates to the technical field of safety and environmental protection, in particular to a soil crude oil pollutant detection device.
背景技术Background technique
原油是目前人类社会赖以生存和发展的主要能源之一。但由于环境腐蚀、自然灾害及人为因素等复杂原因,原油管道泄漏产生油气类污染物,导致环境污染且存在火灾、爆炸等隐患。埋地输油管道泄漏原油近场为土壤介质,当石油类污染物进入到土壤环境,其破坏程度超过土壤的自净作用的速度,长期累积过程将导致土壤环境正常功能的失调和土壤质量的下降,并通过食物链最终影响到人类健康的现象。Crude oil is one of the main energy sources for the survival and development of human society. However, due to complex reasons such as environmental corrosion, natural disasters and human factors, the leakage of crude oil pipelines produces oil and gas pollutants, resulting in environmental pollution and hidden dangers such as fire and explosion. The near-field of crude oil leaked from buried oil pipelines is the soil medium. When petroleum pollutants enter the soil environment, the damage degree exceeds the speed of the self-purification of the soil. The long-term accumulation process will lead to the imbalance of the normal function of the soil environment and the decline of soil quality. and ultimately affect human health through the food chain.
目前还没有建立完善的土壤中原油及其相关污染物的环境质量检测方法体系,对油污土壤的环境危害分析造成诸多不便。现有的能够快速、现场检测土壤中原油污染物的方法多数采取取样分析法,在现场土壤中原油污染物检测分析时,需要对土样中的油类组分进行提后再经过萃取、浓缩、清洗、皂化、过滤、层析等一系列复杂的预处理操作步骤,极大的耗费检测时间和成本。At present, there is no perfect environmental quality detection method system for crude oil and related pollutants in soil, which causes a lot of inconvenience to the environmental hazard analysis of oily soil. Most of the existing methods that can quickly and on-site detect crude oil pollutants in soil adopt the sampling analysis method. When detecting and analyzing crude oil pollutants in soil, the oil components in the soil samples need to be extracted and then extracted and concentrated. , cleaning, saponification, filtration, chromatography and a series of complex pretreatment steps, which consume a lot of detection time and cost.
目前缺乏可以实现对土壤原油污染物原位、快速检测的装置,而土壤中石油类有机污染物是一类可以严重威胁人类生存和社会可持续发展的污染问题,对土壤原油污染物原位检测装置研发的重视程度也日益趋升。At present, there is a lack of devices that can realize in-situ and rapid detection of soil crude oil pollutants, and petroleum organic pollutants in soil are a kind of pollution problem that can seriously threaten human survival and sustainable social development. The emphasis on research and development is also increasing.
发明内容SUMMARY OF THE INVENTION
本发明的主要目的在于提供一种土壤原油污染物检测装置,以解决现有技术中的土壤中原油污染物检测过程复杂、费时费力的问题。The main purpose of the present invention is to provide a device for detecting crude oil pollutants in soil, so as to solve the problems in the prior art that the detection process of crude oil pollutants in soil is complicated, time-consuming and labor-intensive.
为了实现上述目的,本发明提供了一种土壤原油污染物检测装置,包括:外壳,外壳开设有透明的光学窗口,土壤原油污染物检测装置插入待测土壤中,待测土壤遮挡在光学窗口外侧;激光准直透镜,激光准直透镜与红外激光器连接,并能够发射激光;激光接收透镜,激光接收透镜与光学分析仪器连接,并能够接收反射回来的激光,激光准直透镜发出的激光经过光学窗口照射到待测土壤上,并在待测土壤的漫反射作用下再次经过光学窗口射入激光接收透镜。In order to achieve the above purpose, the present invention provides a soil crude oil contaminant detection device, comprising: a casing, the casing is provided with a transparent optical window, the soil crude oil pollution detection device is inserted into the soil to be measured, and the soil to be measured is shielded outside the optical window ; Laser collimating lens, the laser collimating lens is connected with the infrared laser, and can emit laser light; the laser receiving lens, the laser receiving lens is connected with the optical analysis instrument, and can receive the reflected laser light, and the laser light emitted by the laser collimating lens passes through the optical The window is irradiated on the soil to be tested, and under the action of the diffuse reflection of the soil to be tested, the laser is injected into the laser receiving lens through the optical window again.
进一步地,土壤原油污染物检测装置还包括聚焦透镜,聚焦透镜固定设置在外壳内,并且激光准直透镜安装在聚焦透镜的中心处,经由待测土壤的漫反射反射回的至少部分激光经过聚焦透镜的汇聚作用下照射在激光接收透镜上。Further, the device for detecting soil crude oil pollutants further includes a focusing lens, the focusing lens is fixedly arranged in the housing, and the laser collimating lens is installed at the center of the focusing lens, and at least part of the laser light reflected by the diffuse reflection of the soil to be tested is focused. The light is irradiated on the laser receiving lens under the converging action of the lens.
进一步地,外壳的内壁具有固定卡槽,聚焦透镜的外边缘处固定在固定卡槽上。Further, the inner wall of the casing is provided with a fixing slot, and the outer edge of the focusing lens is fixed on the fixing slot.
进一步地,土壤原油污染物检测装置还包括用于滤除颗粒散射和杂散辐射的陷波滤光片,陷波滤光片设置在聚焦透镜与激光接收透镜之间。Further, the device for detecting soil and crude oil pollutants further includes a notch filter for filtering particle scattering and stray radiation, and the notch filter is arranged between the focusing lens and the laser receiving lens.
进一步地,外壳具有隔断,隔断将外壳分隔成第一腔体和第二腔体,且第一腔体密闭设置,激光准直透镜设置在第一腔体内,光学窗口开设在第一腔体的侧壁,激光接收透镜穿设在隔断的中心处。Further, the housing has a partition, the partition divides the housing into a first cavity and a second cavity, and the first cavity is sealed and arranged, the laser collimating lens is arranged in the first cavity, and the optical window is opened in the first cavity. On the side wall, the laser receiving lens is penetrated at the center of the partition.
进一步地,激光准直透镜通过发射光纤与红外激光器连接,隔断开设有供发射光纤穿过的过孔,激光接收透镜通过接收光纤与光学分析仪器连接。Further, the laser collimating lens is connected with the infrared laser through the transmitting fiber, and the partition is provided with a via hole for the transmitting fiber to pass through, and the laser receiving lens is connected with the optical analysis instrument through the receiving fiber.
进一步地,土壤原油污染物检测装置还包括棱镜反射镜,棱镜反射镜设置在外壳内,并且具有反射斜面,光学窗口开设在外壳的侧面,激光准直透镜发出的激光照射在反射斜面上,并经反射斜面反射后照射到光学窗口外的待测土壤上,待测土壤的漫反射回的激光照射在反射斜面上,并经反射斜面反射后照射到激光接收透镜上。Further, the soil and crude oil pollutant detection device also includes a prismatic reflector, the prismatic reflector is arranged in the casing and has a reflecting slope, the optical window is opened on the side of the casing, and the laser light emitted by the laser collimating lens is irradiated on the reflecting slope, and After being reflected by the reflective slope, it is irradiated on the soil to be tested outside the optical window. The diffusely reflected laser light of the soil to be tested is irradiated on the reflective slope, and reflected on the reflective slope and then irradiated on the laser receiving lens.
进一步地,反射斜面的表面镀有二氧化硅保护层金膜。Further, the surface of the reflective slope is coated with a silicon dioxide protective layer gold film.
进一步地,外壳具有活动设置的挡板,外壳的侧面设置有容纳槽,挡板活动设置在容纳槽内,并能够伸出容纳槽以关闭光学窗口或者缩回容纳槽以打开光学窗口。Further, the housing has a movably arranged baffle, a side surface of the housing is provided with an accommodating slot, the baffle is movably arranged in the accommodating slot, and can extend out of the accommodating slot to close the optical window or retract the accommodating slot to open the optical window.
进一步地,挡板伸出容纳槽的一端具有倾斜设置的刀口切面,挡板朝向光学窗口的表面具有用于擦拭光学窗口的土渍擦拭棉。Further, one end of the baffle protruding from the accommodating groove has an obliquely arranged knife-edge cut surface, and the surface of the baffle facing the optical window has soil-stained wiping cotton for wiping the optical window.
进一步地,光学窗口为光学玻璃件,光学窗口的外侧镀有耐磨层,光学窗口的内侧镀有红外增透膜。Further, the optical window is an optical glass piece, the outer side of the optical window is coated with a wear-resistant layer, and the inner side of the optical window is coated with an infrared antireflection film.
进一步地,土壤原油污染物检测装置还包括:电动机箱,电动机箱设置在外壳伸入待测土壤的一端,电动机箱内设置有电动机;推进钻头,推进钻头设置在电动机箱上,并与电动机电连接。Further, the soil crude oil pollutant detection device also includes: an electric motor box, the electric motor box is arranged at one end of the outer casing extending into the soil to be tested, and a motor is arranged in the electric motor box; the pushing drill bit is arranged on the electric motor box, and is electrically connected with the motor. connect.
进一步地,外壳远离伸入待测土壤的一端具有连接部,土壤原油污染物检测装置还包括连接杆,连接杆与连接部可拆卸连接。Further, the end of the casing away from the soil to be tested has a connecting portion, and the soil crude oil pollutant detection device further includes a connecting rod, and the connecting rod is detachably connected to the connecting portion.
应用本发明的技术方案,通过设置的激光准直透镜和激光接收透镜,使用时,将土壤原油污染物检测装置插入到待测土壤中,激光准直透镜对红外激光器的激光进行准直和扩束,使得检测面积随着激光光斑面积增大而扩大,激光准直透镜将激光发射出去,射出的激光穿过透明的光学窗口照射到外侧的待测土壤上,在激光照射作用下,待测土壤表面中的原油污染物分子将吸收红外激光能量,激光能量发生衰减,由于土壤表面粗糙度较大,激光会发生漫反射作用,其中近似垂直光学窗口的部分激光在漫反射作用下反向再次经过光学窗口射入到外壳内,并被激光接收透镜接收,传输到微型光栅光谱仪或光电探测器等光学分析仪器,进行相应分析。探测到的油污土壤吸收光谱信号与已建立的不同浓度油污土壤吸收光谱图谱数据库进行比对分析,根据吸收光谱峰值与土壤含油浓度成正比关系,建立标定拟合方程,利用光谱信息处理系统将探测到的吸收光谱峰值代入标定拟合方程,实现待测土壤中原油污染物浓度的检测。上述设置方式利用激光吸收光谱技术对油污土壤进行检测并传输至数据分析系统,获得反射光中土壤中原油污染物的浓度信息,从而不需要对样品进行复杂的处理,可以快速、无损伤、准确地对土壤原油污染物进行原位检测,能够为石油化工和油气储运场地污染检测及后期土壤修复质量评价提供原油污染物的特征识别与浓度检测功能。By applying the technical scheme of the present invention, through the provided laser collimating lens and laser receiving lens, when in use, the soil crude oil pollutant detection device is inserted into the soil to be measured, and the laser collimating lens collimates and expands the laser light of the infrared laser. beam, so that the detection area expands with the increase of the laser spot area. The laser collimator lens emits the laser light, and the emitted laser light passes through the transparent optical window and irradiates the soil to be tested on the outside. The crude oil pollutant molecules in the soil surface will absorb the infrared laser energy, and the laser energy will be attenuated. Due to the large roughness of the soil surface, the laser will undergo diffuse reflection, and part of the laser near the vertical optical window will reverse again under the diffuse reflection. It is injected into the casing through the optical window, received by the laser receiving lens, and transmitted to optical analysis instruments such as micro-grating spectrometers or photodetectors for corresponding analysis. The detected oily soil absorption spectrum signal is compared and analyzed with the established oily soil absorption spectrum map database with different concentrations. The obtained absorption spectrum peak is substituted into the calibration fitting equation to realize the detection of the concentration of crude oil pollutants in the soil to be measured. The above setting method uses laser absorption spectroscopy technology to detect oily soil and transmit it to the data analysis system to obtain the concentration information of crude oil pollutants in the soil in the reflected light, which does not require complex sample processing, and can be fast, non-destructive and accurate. The in-situ detection of soil crude oil pollutants can provide the feature identification and concentration detection functions of crude oil pollutants for the pollution detection of petrochemical and oil and gas storage and transportation sites and the later soil remediation quality evaluation.
附图说明Description of drawings
构成本申请的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings forming a part of the present application are used to provide further understanding of the present invention, and the exemplary embodiments of the present invention and their descriptions are used to explain the present invention and do not constitute an improper limitation of the present invention. In the attached image:
图1示出了本发明的土壤原油污染物检测装置的结构示意图;Fig. 1 shows the structural schematic diagram of the soil crude oil pollutant detection device of the present invention;
图2示出了图1中的土壤原油污染物检测装置的剖视图。FIG. 2 shows a cross-sectional view of the soil crude oil contaminant detection device in FIG. 1 .
其中,上述附图包括以下附图标记:Wherein, the above-mentioned drawings include the following reference signs:
10、外壳;11、光学窗口;12、隔断;13、挡板;14、容纳槽;20、激光准直透镜;30、激光接收透镜;40、聚焦透镜;50、发射光纤;60、接收光纤;70、棱镜反射镜;80、电动机箱;90、推进钻头;100、连接部。10, housing; 11, optical window; 12, partition; 13, baffle; 14, accommodating groove; 20, laser collimating lens; 30, laser receiving lens; 40, focusing lens; 50, transmitting fiber; 60, receiving fiber ; 70, prism mirror; 80, motor box; 90, advancing drill; 100, connecting part.
具体实施方式Detailed ways
需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本发明。It should be noted that the embodiments in the present application and the features of the embodiments may be combined with each other in the case of no conflict. The present invention will be described in detail below with reference to the accompanying drawings and in conjunction with the embodiments.
需要指出的是,除非另有指明,本申请使用的所有技术和科学术语具有与本申请所属技术领域的普通技术人员通常理解的相同含义。It should be noted that, unless otherwise specified, all technical and scientific terms used in this application have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.
在本发明中,在未作相反说明的情况下,使用的方位词如“上、下、顶、底”通常是针对附图所示的方向而言的,或者是针对部件本身在竖直、垂直或重力方向上而言的;同样地,为便于理解和描述,“内、外”是指相对于各部件本身的轮廓的内、外,但上述方位词并不用于限制本发明。In the present invention, unless otherwise stated, the directional words used such as "upper, lower, top, bottom" are usually for the directions shown in the drawings, or for the components themselves in vertical, In terms of vertical or gravitational direction; similarly, for the convenience of understanding and description, "inner and outer" refers to the inner and outer relative to the contour of each component itself, but the above-mentioned orientation words are not used to limit the present invention.
为了解决现有技术中的土壤中原油污染物检测过程复杂、费时费力的问题,本发明提供了一种土壤原油污染物检测装置。In order to solve the problems in the prior art that the detection process of crude oil pollutants in soil is complex, time-consuming and labor-intensive, the present invention provides a soil crude oil pollutant detection device.
如图1和图2所示的一种土壤原油污染物检测装置,包括外壳10、激光准直透镜20和激光接收透镜30,外壳10开设有透明的光学窗口11,土壤原油污染物检测装置插入待测土壤中,待测土壤遮挡在光学窗口11外侧;激光准直透镜20与红外激光器连接,并能够发射激光;激光接收透镜30与光学分析仪器连接,并能够接收反射回来的激光,激光准直透镜20发出的激光经过光学窗口11照射到待测土壤上,并在待测土壤的漫反射作用下再次经过光学窗口11射入激光接收透镜30。As shown in Figures 1 and 2, a soil and crude oil pollutant detection device includes a
本实施例通过设置的激光准直透镜20和激光接收透镜30,使用时,将土壤原油污染物检测装置插入到待测土壤中,激光准直透镜20对红外激光器的激光进行准直和扩束,使得检测面积随着激光光斑面积增大而扩大,激光准直透镜20将激光发射出去,射出的激光穿过透明的光学窗口11照射到外侧的待测土壤上,在激光照射作用下,待测土壤表面中的原油污染物分子将吸收红外激光能量,激光能量发生衰减,由于土壤表面粗糙度较大,激光会发生漫反射作用,其中近似垂直光学窗口11的部分激光在漫反射作用下反向再次经过光学窗口11射入到外壳10内,并被激光接收透镜30接收,传输到微型光栅光谱仪或光电探测器等光学分析仪器,进行相应分析。探测到的油污土壤吸收光谱信号与已建立的不同浓度油污土壤吸收光谱图谱数据库进行比对分析,根据吸收光谱峰值与土壤含油浓度成正比关系,建立标定拟合方程,利用光谱信息处理系统将探测到的吸收光谱峰值代入标定拟合方程,实现待测土壤中原油污染物浓度的检测。上述设置方式利用激光吸收光谱技术对油污土壤进行检测并传输至数据分析系统,获得反射光中土壤中原油污染物的浓度信息,从而不需要对样品进行复杂的处理,可以快速、无损伤、准确地对土壤原油污染物进行原位检测,能够为石油化工和油气储运场地污染检测及后期土壤修复质量评价提供原油污染物的特征识别与浓度检测功能。In this embodiment, the laser collimating
在本实施例中,土壤原油污染物检测装置还包括聚焦透镜40,聚焦透镜40固定设置在外壳10内,并且激光准直透镜20安装在聚焦透镜40的中心处,这样,激光准直透镜20发出的激光能够准确照射在预定的位置,并且经由待测土壤的漫反射反射回的至少部分激光则会经过聚焦透镜40,并且在聚焦透镜40的汇聚作用下照射在激光接收透镜30上,从而提高了激光接收透镜30接收到的激光量,有利于后续的数据分析处理。In this embodiment, the soil and crude oil pollutant detection device further includes a focusing
可选地,本实施例在外壳10的内壁上固定设置有四个固定卡槽,固定卡槽沿外壳10的内壁周向排布,聚焦透镜40的外边缘处固定在固定卡槽上,从而完成聚焦透镜40及其上的激光准直透镜20的安装。Optionally, in this embodiment, four fixing slots are fixed on the inner wall of the
可选地,土壤原油污染物检测装置还包括陷波滤光片,陷波滤光片设置在聚焦透镜40与激光接收透镜30之间,陷波滤光片用于滤除颗粒散射和杂散辐射,从而保证检测结果的可靠性和准确性。Optionally, the soil and crude oil pollutant detection device further includes a notch filter, the notch filter is arranged between the focusing
在本实施例中,外壳10具有隔断12,隔断12将外壳10内的空腔分隔成第一腔体和第二腔体,且第一腔体密闭设置,第二腔体可以根据需要密闭或者不密闭,激光准直透镜20设置在第一腔体内,光学窗口11开设在第一腔体的侧壁上,激光接收透镜30穿设在隔断12的中心处并伸入至第一腔体内。In this embodiment, the
本实施例的激光准直透镜20通过发射光纤50与红外激光器连接,隔断12开设有供发射光纤50穿过的过孔。相似地,激光接收透镜30通过接收光纤60与光学分析仪器连接。发射光纤50和接收光纤60均采用FC接口单模单芯光纤。The
在本实施例中,外壳10呈圆柱形,激光准直透镜20和激光接收透镜30均沿外壳10的轴线设置,激光准直透镜20发射出的激光以及激光接收透镜30接收到的激光均与外壳10的轴线平行,而光学窗口11设置在外壳10的圆周侧壁上,这样,激光准直透镜20发出的激光需要转向才能够照射到光学窗口11。基于此,本实施例的土壤原油污染物检测装置还包括棱镜反射镜70,本实施例采用直角棱镜反射镜,棱镜反射镜70设置在外壳10内,其直角面通过粘接等方式与外壳10内壁连接,其斜面作为反射斜面,当激光照射到反射斜面上时在反射斜面的作用下即会改变方向。具体而言,激光准直透镜20发出的激光沿外壳10的轴线照射在反射斜面上,并经反射斜面反射后转90度,照射到光学窗口11外的待测土壤上,待测土壤的漫反射回的激光由于近似垂直光学窗口11,因而照射在反射斜面上,并经反射斜面反射后反向转90度,照射到聚焦透镜40上,在聚焦透镜40的作用下汇聚到激光接收透镜30上。并且由于激光准直透镜20安装在聚焦透镜40的中心处,因而可以保证激光照射于棱镜反射镜70的反射斜面的中心。In this embodiment, the
可选地,为了保证良好的反射效果,本实施例在反射斜面的表面镀有二氧化硅保护层金膜。Optionally, in order to ensure a good reflection effect, in this embodiment, a silicon dioxide protective layer gold film is plated on the surface of the reflection slope.
在本实施例中,外壳10具有活动设置的挡板13,外壳10的侧面设置有容纳槽14,挡板13活动设置在容纳槽14内,并能够伸出容纳槽14以关闭光学窗口11或者缩回容纳槽14以打开光学窗口11,从而实现土壤原油污染物检测装置的关闭收纳和正常使用。本实施例将挡板13与单片机等控制件电连接,通过控制件控制挡板13的动作。In this embodiment, the
可选地,挡板13伸出容纳槽14的一端具有倾斜设置的刀口切面,挡板13朝向光学窗口11的表面具有用于擦拭光学窗口11的土渍擦拭棉,起到对光学窗口11的清洁功能。Optionally, one end of the
在本实施例中,光学窗口11为光学玻璃件,光学窗口11的外侧镀有耐磨层,减小土壤颗粒对光学窗口11表面的磨损,光学窗口11的内侧镀有红外增透膜,提高激光的透过率。In this embodiment, the
在本实施例中,土壤原油污染物检测装置还包括电动机箱80和推进钻头90,电动机箱80设置在外壳10伸入待测土壤的一端,电动机箱80内设置有电动机,并铺设有减震垫,以减小对其他光学器件的震动损伤和位置错动;推进钻头90设置在电动机箱80上,并与电动机电连接,推进钻头90具有304不锈钢螺旋叶片,提高土壤原油污染物检测装置在土层中的检测速率。In this embodiment, the soil and crude oil pollutant detection device further includes a
可选地,外壳10远离伸入待测土壤的一端具有凸出的呈圆柱状的连接部100,土壤原油污染物检测装置还包括可供操作人员手持的连接杆,连接杆可以根据需要设置有多个,且分别为不同长度,也可以设置可伸缩的连接杆,通过连接杆与连接部100可拆卸连接,使得土壤原油污染物检测装置可以根据需要伸入到不同深度的待测土壤中,从而实现不同深度范围土壤原油污染物的检测,提高可检测的范围。Optionally, the end of the
本实施例的土壤原油污染物检测装置使用过程如下:The use process of the soil crude oil pollutant detection device of the present embodiment is as follows:
在测量时,开启红外激光器,红外激光器的波长为2.4μm,激光经发射光纤50传输至激光准直透镜20,完成激光的准直和扩束,检测面积随着激光光斑面积增大而扩大,竖直的激光光束经棱镜反射镜70的反射斜面反射作用转折射入光学窗口11。待测土壤附着于光学窗口11的外侧,在激光照射作用下,待测土壤表面中的原油污染物分子将吸收红外激光能量,激光能量发生衰减。由于待测土壤表面粗糙度较大,激光回波信号以漫反射形式再次经过光学窗口11到达棱镜反射镜70,棱镜反射镜70将其中近似垂直光学窗口11的回波光线反射到达聚焦透镜40,回波光线经过汇聚作用被激光接收透镜30接收,回波光线经接收光纤60传至微型光栅光谱仪或光电探测器。During the measurement, the infrared laser is turned on. The wavelength of the infrared laser is 2.4 μm. The laser is transmitted to the
探测到的油污土壤吸收光谱信号与已建立的不同浓度油污土壤吸收光谱图谱数据库进行比对分析,根据吸收光谱峰值与土壤含油浓度成正比关系,建立标定拟合方程。利用光谱信息处理系统将探测到的吸收光谱峰值代入标定拟合方程,实现土壤中原油污染物浓度的检测。The detected oily soil absorption spectrum signal is compared with the established database of oily soil absorption spectrum of different concentrations. According to the proportional relationship between the absorption spectrum peak and the soil oil concentration, a calibration fitting equation is established. Using the spectral information processing system, the detected absorption spectrum peaks are substituted into the calibration fitting equation to realize the detection of the concentration of crude oil pollutants in the soil.
检测结束或变换检测位置时,通过单片机控制挡板13降下,实现对光学窗口11的关闭,降低土壤颗粒对光学窗口11的损耗。When the detection is finished or the detection position is changed, the
需要说明的是,上述实施例中的多个指的是至少两个。It should be noted that a plurality in the above-mentioned embodiments refers to at least two.
从以上的描述中,可以看出,本发明上述的实施例实现了如下技术效果:From the above description, it can be seen that the above-mentioned embodiments of the present invention achieve the following technical effects:
1、解决了现有技术中的土壤中原油污染物检测过程复杂、费时费力的问题;1. Solve the problems in the prior art that the detection process of crude oil pollutants in soil is complex, time-consuming and labor-intensive;
2、利用激光吸收光谱技术对油污土壤进行检测,不需要对样品进行复杂的处理,可以快速、无损伤、准确地对土壤原油污染物进行原位检测;2. The use of laser absorption spectroscopy to detect oily soil does not require complex sample processing, and can quickly, non-damage and accurately detect soil crude oil pollutants in situ;
3、能够为石油化工和油气储运场地污染检测及后期土壤修复质量评价提供原油污染物的特征识别与浓度检测功能;3. It can provide feature identification and concentration detection functions of crude oil pollutants for pollution detection of petrochemical and oil and gas storage and transportation sites and later soil remediation quality evaluation;
4、整体结构简单,使用方便,检测结果准确可靠。4. The overall structure is simple, easy to use, and the detection results are accurate and reliable.
显然,上述所描述的实施例仅仅是本发明一部分的实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。Obviously, the above-described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本申请的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、工作、器件、组件和/或它们的组合。It should be noted that the terminology used herein is for the purpose of describing specific embodiments only, and is not intended to limit the exemplary embodiments according to the present application. As used herein, unless the context clearly dictates otherwise, the singular is intended to include the plural as well, furthermore, it is to be understood that when the terms "comprising" and/or "including" are used in this specification, it indicates that There are features, steps, acts, devices, components, and/or combinations thereof.
需要说明的是,本申请的说明书和权利要求书及上述附图中的术语“第一”、“第二”等是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的本申请的实施方式能够以除了在这里图示或描述的那些以外的顺序实施。It should be noted that the terms "first", "second", etc. in the description and claims of the present application and the above drawings are used to distinguish similar objects, and are not necessarily used to describe a specific sequence or sequence. It is to be understood that data so used may be interchanged under appropriate circumstances so that the embodiments of the application described herein can be practiced in sequences other than those illustrated or described herein.
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.
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