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CN114657605A - Titanium aluminium titanium electrolysis copper negative plate - Google Patents

Titanium aluminium titanium electrolysis copper negative plate Download PDF

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Publication number
CN114657605A
CN114657605A CN202210252209.1A CN202210252209A CN114657605A CN 114657605 A CN114657605 A CN 114657605A CN 202210252209 A CN202210252209 A CN 202210252209A CN 114657605 A CN114657605 A CN 114657605A
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titanium
aluminum
conductive rod
plate
rod
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温方明
马明亮
尚郑平
李华清
刘茵琪
李渤渤
陶会发
王树军
周元庆
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Luoyang Sunrui Titanium Precision Casting Co Ltd
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Luoyang Sunrui Titanium Precision Casting Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02Electrodes; Connections thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/12Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper

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  • Chemical Kinetics & Catalysis (AREA)
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  • Electrolytic Production Of Metals (AREA)

Abstract

一种钛铝钛电解铜阴极板,包括极板面板和导电杆,极板面板包括芯部铝板和表层钛层,表层钛层覆盖在芯部铝板的两段平面上,表层钛层靠近导电杆一侧的边沿与导电杆之间具有条状空隙,条状空隙上涂抹有耐蚀涂料,导电杆包括芯部铝杆和外套铜层,外套铜层套设焊接在芯部铝杆的外侧,外套铜层的厚度为3~5mm,外套铜层的一侧开设有供芯部铝杆与芯部铝板贴合焊接的通槽。本发明与现有的纯钛面板相比,更多的使用铝材做为主要原材料,有更好的电效率,提高了阴极板的电效率,单个极板的重量更轻,有效的降低了工人的劳动强度,降低了能耗,提高了生产效率,同时,铝的价格相较于钛便宜很多,因此可以带来显著的经济效益,降低成本。

Figure 202210252209

A titanium-aluminum-titanium electrolytic copper cathode plate, comprising a pole plate panel and a conductive rod, the pole plate panel includes a core aluminum plate and a surface titanium layer, the surface titanium layer covers two planes of the core aluminum plate, and the surface titanium layer is close to the conductive rod There is a strip-shaped gap between the edge of one side and the conductive rod. The strip-shaped gap is coated with anti-corrosion paint. The conductive rod includes a core aluminum rod and an outer copper layer. The outer copper layer is sleeved and welded on the outside of the core aluminum rod. The thickness of the outer copper layer is 3 to 5 mm, and one side of the outer copper layer is provided with a through groove for bonding and welding the core aluminum rod and the core aluminum plate. Compared with the existing pure titanium panel, the present invention uses more aluminum as the main raw material, has better electrical efficiency, improves the electrical efficiency of the cathode plate, and the weight of a single pole plate is lighter, which effectively reduces the The labor intensity of workers reduces energy consumption and improves production efficiency. At the same time, the price of aluminum is much cheaper than titanium, so it can bring significant economic benefits and reduce costs.

Figure 202210252209

Description

一种钛铝钛电解铜阴极板A titanium-aluminum-titanium electrolytic copper cathode plate

技术领域technical field

本发明涉及电解铜阴极板领域,尤其涉及一种钛铝钛电解铜阴极板。The invention relates to the field of electrolytic copper cathode plates, in particular to a titanium-aluminum-titanium electrolytic copper cathode plate.

背景技术Background technique

电解铜工业中,目前使用的有两种形式的阴极板,分别为纯钛面板、钛包铜导电杆和316L不锈钢面板、不锈钢包铜导电杆,由于纯钛和316L不锈钢的电阻率较高,造成电解时电流效率较低,能耗较高,并且纯钛面板的造价较高,给企业造成较大的经济负担。纯钛型阴极板在使用中要人工进行操作,单片极板较重,给操作工人带来了不便。In the electrolytic copper industry, there are two forms of cathode plates currently used, namely pure titanium panels, titanium-clad copper conductive rods, 316L stainless steel panels, and stainless steel copper-clad conductive rods. Due to the high resistivity of pure titanium and 316L stainless steel, As a result, the current efficiency during electrolysis is low, the energy consumption is high, and the cost of pure titanium panels is high, causing a greater economic burden to the enterprise. The pure titanium cathode plate needs to be manually operated in use, and the monolithic plate is heavier, which brings inconvenience to the operators.

发明内容SUMMARY OF THE INVENTION

本发明的目的是提供一种钛铝钛电解铜阴极板,提高阴极板电效率,降低能耗,提高生产效率,降低工人劳动强度,降低工厂采购单价,提高经济效益。The purpose of the present invention is to provide a titanium-aluminum-titanium electrolytic copper cathode plate, which improves the electrical efficiency of the cathode plate, reduces energy consumption, improves production efficiency, reduces labor intensity of workers, reduces the unit purchase price of the factory, and improves economic benefits.

本发明为解决上述技术问题所采用的技术方案是:一种钛铝钛电解铜阴极板,包括极板面板和导电杆,极板面板为矩形平板结构,导电杆为矩形长条结构,导电杆位于极板面板沿高度方向的一侧,导电杆的长度方向与极板面板的长度方向平行,导电杆的一段长×宽的侧面与极板面板的一段长×宽的侧面贴合焊接,极板面板包括芯部铝板和表层钛层,表层钛层覆盖在芯部铝板的两段长×高的平面上,表层钛层靠近导电杆一侧的边沿与导电杆之间具有条状空隙,条状空隙的长度方向与导电杆的长度方向平行,条状空隙沿极板面板高度方向的宽度为3~5mm,条状空隙上涂抹有耐蚀涂料;导电杆包括芯部铝杆和外套铜层,外套铜层套设焊接在芯部铝杆的外侧,外套铜层的厚度为3~5mm,外套铜层的一侧开设有供芯部铝杆与芯部铝板贴合焊接的通槽。The technical solution adopted by the present invention to solve the above technical problems is: a titanium-aluminum-titanium electrolytic copper cathode plate, comprising a pole plate panel and a conductive rod, the pole plate panel is a rectangular flat plate structure, the conductive rod is a rectangular long strip structure, and the conductive rod It is located on the side of the pole plate panel along the height direction, the length direction of the conductive rod is parallel to the length direction of the pole plate panel, and a length × width side of the conductive rod is welded to a length × width side of the pole plate panel. The board panel includes a core aluminum plate and a surface titanium layer. The surface titanium layer covers the two lengths × height planes of the core aluminum plate. There is a strip-shaped gap between the edge of the surface titanium layer near the conductive rod and the conductive rod. The length direction of the gap is parallel to the length direction of the conductive rod, the width of the strip gap along the height direction of the plate panel is 3-5mm, and the strip gap is coated with anti-corrosion paint; the conductive rod includes the core aluminum rod and the outer copper layer , the outer copper layer is sleeved and welded on the outside of the core aluminum rod, the thickness of the outer copper layer is 3-5mm, and one side of the outer copper layer is provided with a through slot for the core aluminum rod and the core aluminum plate to be welded together.

优选的,极板面板上开设有多个吊装孔。Preferably, a plurality of hoisting holes are opened on the plate panel.

优选的,极板面板的宽×高的两侧分别设有绝缘夹边条。Preferably, insulating edge strips are respectively provided on both sides of the width and height of the pole plate panel.

根据上述技术方案,本发明的有益效果是:According to the above-mentioned technical scheme, the beneficial effects of the present invention are:

本发明中极板面板的芯部铝板两侧分别覆盖有表层钛层,形成“钛铝钛”的多层结构,与现有的纯钛面板相比,更多的使用铝材做为主要原材料,铝的电导率要大于钛和不锈钢,因而有更好的电效率,提高了阴极板的电效率。并且铝的密度小于钛和不锈钢,因此单个极板的重量更轻,有效的降低了工人的劳动强度,降低了能耗,提高了生产效率。同时,铝的价格相较于钛便宜很多,因此可以带来显著的经济效益,降低成本。In the present invention, the two sides of the core aluminum plate of the polar plate panel are respectively covered with surface titanium layers to form a multi-layer structure of "titanium aluminum titanium". Compared with the existing pure titanium panels, more aluminum materials are used as the main raw material. , the conductivity of aluminum is greater than that of titanium and stainless steel, so it has better electrical efficiency and improves the electrical efficiency of the cathode plate. And the density of aluminum is lower than that of titanium and stainless steel, so the weight of a single plate is lighter, which effectively reduces the labor intensity of workers, reduces energy consumption, and improves production efficiency. At the same time, the price of aluminum is much cheaper than that of titanium, so it can bring significant economic benefits and reduce costs.

附图说明Description of drawings

图1为本发明的主视示意图;1 is a schematic front view of the present invention;

图2为图1沿A-A的剖视图;Fig. 2 is the sectional view along A-A of Fig. 1;

图3为图1的仰视图。FIG. 3 is a bottom view of FIG. 1 .

图中标记:1、极板面板,2、导电杆,3、吊装孔,4、绝缘夹边条,5、芯部铝板,6、表层钛层,7、芯部铝杆,8、外套铜层。Markings in the figure: 1. Plate panel, 2. Conductive rod, 3. Hoisting hole, 4. Insulating edge strip, 5. Core aluminum plate, 6. Surface titanium layer, 7. Core aluminum rod, 8. Coating copper Floor.

具体实施方式Detailed ways

参见附图,具体实施方式如下:Referring to the accompanying drawings, the specific embodiments are as follows:

一种钛铝钛电解铜阴极板,包括极板面板1和导电杆2,极板面板1为矩形平板结构,导电杆2为矩形长条结构,导电杆2位于极板面板1沿高度方向的一侧,导电杆2的长度方向与极板面板1的长度方向平行,导电杆2的一段长×宽的侧面与极板面板1的一段长×宽的侧面贴合焊接。极板面板1上开设有多个吊装孔3,极板面板1的宽×高的两侧分别设有绝缘夹边条4,绝缘夹边条4为ABS材质。A titanium-aluminum-titanium electrolytic copper cathode plate, comprising a pole plate panel 1 and a conductive rod 2, the pole plate panel 1 is a rectangular flat plate structure, the conductive rod 2 is a rectangular long strip structure, and the conductive rod 2 is located on the pole plate panel 1 along the height direction. On one side, the length direction of the conductive rod 2 is parallel to the length direction of the pole plate panel 1 , and a length × width side of the conductive rod 2 is bonded and welded to a length × width side of the electrode plate panel 1 . The pole plate panel 1 is provided with a plurality of hoisting holes 3, and the two sides of the width x height of the pole plate panel 1 are respectively provided with insulating edge strips 4, and the insulating edge strips 4 are made of ABS material.

如图2所示,极板面板1包括芯部铝板5和表层钛层6,表层钛层6覆盖在芯部铝板5的两段长×高的平面上,表层钛层6靠近导电杆2一侧的边沿与导电杆2之间具有条状空隙,条状空隙的长度方向与导电杆2的长度方向平行,条状空隙沿极板面板1高度方向的宽度为3~5mm,条状空隙上涂抹有耐蚀涂料。As shown in FIG. 2 , the electrode panel 1 includes a core aluminum plate 5 and a surface titanium layer 6 , the surface titanium layer 6 covers the two lengths×height planes of the core aluminum plate 5 , and the surface titanium layer 6 is close to the conductive rod 2-1 There is a strip-shaped gap between the edge of the side and the conductive rod 2. The length direction of the strip-shaped gap is parallel to the length direction of the conductive rod 2. The width of the strip-shaped gap along the height direction of the electrode panel 1 is 3-5 mm. Painted with anti-corrosion paint.

如图2所示,导电杆2包括芯部铝杆7和外套铜层8,外套铜层8套设焊接在芯部铝杆7的外侧,外套铜层8的厚度为3~5mm,外套铜层8的一侧开设有供芯部铝杆7与芯部铝板5贴合焊接的通槽。As shown in FIG. 2, the conductive rod 2 includes a core aluminum rod 7 and an outer copper layer 8. The outer copper layer 8 is sleeved and welded on the outer side of the core aluminum rod 7. The thickness of the outer copper layer 8 is 3-5 mm, and the outer copper layer 8 One side of the layer 8 is provided with a through groove for the core aluminum rod 7 and the core aluminum plate 5 to be bonded and welded.

本发明的新型钛铝钛电解铜阴极板的制作方法为:The manufacturing method of the novel titanium-aluminum-titanium electrolytic copper cathode plate of the present invention is:

步骤一,将热轧后的钛铝钛复合板校平,不平度小于等于3mm,按照图纸加工到规定尺寸,加工出吊装孔和底部V型槽。Step 1: Level the hot-rolled titanium-aluminum-titanium composite plate with an unevenness of less than or equal to 3mm, process it to the specified size according to the drawing, and process the hoisting hole and the bottom V-shaped groove.

步骤二,将模具拉拔后的铜包铝导电杆加工到设计尺寸,在导电杆的两端使用氩弧焊焊上铜层,根据图纸在导电杆上加工出焊接开槽,露出芯部铝层。Step 2: Process the copper-clad aluminum conductive rod drawn by the mold to the design size, use argon arc welding to weld the copper layer on both ends of the conductive rod, and process the welding slot on the conductive rod according to the drawing to expose the core aluminum. Floor.

步骤三,将极板面板和导电杆装配到焊接工装上,相应位置进行对齐,进行手工TIG焊或MIG焊接,双面满焊。Step 3: Assemble the pole plate panel and the conductive rod on the welding tool, align the corresponding positions, perform manual TIG welding or MIG welding, and fully weld on both sides.

步骤四,安装绝缘夹边条。在极板上方露出铝层位置刷涂耐蚀涂料。Step 4, install the insulating clip edge strip. Brush corrosion-resistant paint on the exposed aluminum layer above the plate.

步骤五,检查极板焊后平整度和悬挂垂直度。Step 5: Check the flatness and verticality of the pole plate after welding.

Claims (3)

1.一种钛铝钛电解铜阴极板,其特征在于:包括极板面板(1)和导电杆(2),极板面板(1)为矩形平板结构,导电杆(2)为矩形长条结构,导电杆(2)位于极板面板(1)沿高度方向的一侧,导电杆(2)的长度方向与极板面板(1)的长度方向平行,导电杆(2)的一段长×宽的侧面与极板面板(1)的一段长×宽的侧面贴合焊接,极板面板(1)包括芯部铝板(5)和表层钛层(6),表层钛层(6)覆盖在芯部铝板(5)的两段长×高的平面上,表层钛层(6)靠近导电杆(2)一侧的边沿与导电杆(2)之间具有条状空隙,条状空隙的长度方向与导电杆(2)的长度方向平行,条状空隙沿极板面板(1)高度方向的宽度为3~5mm,条状空隙上涂抹有耐蚀涂料;导电杆(2)包括芯部铝杆(7)和外套铜层(8),外套铜层(8)套设焊接在芯部铝杆(7)的外侧,外套铜层(8)的厚度为3~5mm,外套铜层(8)的一侧开设有供芯部铝杆(7)与芯部铝板(5)贴合焊接的通槽。1. A titanium-aluminum-titanium electrolytic copper cathode plate, characterized in that: it comprises a pole plate panel (1) and a conductive rod (2), the pole plate panel (1) is a rectangular flat plate structure, and the conductive rod (2) is a rectangular strip Structure, the conductive rod (2) is located on one side of the pole plate panel (1) along the height direction, the length direction of the conductive rod (2) is parallel to the length direction of the pole plate panel (1), the length of a section of the conductive rod (2) × The wide side is welded with a length x width side of the pole plate panel (1), and the pole plate panel (1) includes a core aluminum plate (5) and a surface titanium layer (6), and the surface titanium layer (6) is covered on the On the plane of the two lengths × height of the core aluminum plate (5), there is a strip-shaped gap between the edge of the surface layer titanium layer (6) near the conductive rod (2) and the conductive rod (2), and the length of the strip-shaped gap is The direction is parallel to the length direction of the conductive rod (2), the width of the strip-shaped gap along the height direction of the pole plate panel (1) is 3 to 5 mm, and the strip-shaped gap is coated with anti-corrosion paint; the conductive rod (2) includes the core aluminum The rod (7) and the outer copper layer (8), the outer copper layer (8) is sleeved and welded on the outside of the core aluminum rod (7), the thickness of the outer copper layer (8) is 3-5 mm, and the outer copper layer (8) ) is provided with a through groove for welding the core aluminum rod (7) and the core aluminum plate (5). 2.根据权利要求1所述的一种钛铝钛电解铜阴极板,其特征在于:极板面板(1)上开设有多个吊装孔(3)。2 . The titanium-aluminum-titanium electrolytic copper cathode plate according to claim 1 , wherein a plurality of hoisting holes ( 3 ) are opened on the plate face plate ( 1 ). 3 . 3.根据权利要求1所述的一种钛铝钛电解铜阴极板,其特征在于:极板面板(1)的宽×高的两侧分别设有绝缘夹边条(4)。3 . The titanium-aluminum-titanium electrolytic copper cathode plate according to claim 1 , wherein the width and height of the plate panel ( 1 ) are respectively provided with insulating edge strips ( 4 ). 4 .
CN202210252209.1A 2022-03-15 2022-03-15 Titanium aluminium titanium electrolysis copper negative plate Pending CN114657605A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009114475A (en) * 2007-11-02 2009-05-28 Mitsui Mining & Smelting Co Ltd Electrode for producing electrolytic copper powder and anode for producing electrolytic copper powder
CN102766887A (en) * 2012-08-16 2012-11-07 张家港市江城冶化科技有限公司 Method for manufacturing stainless steel negative plate
CN105274579A (en) * 2014-05-26 2016-01-27 江西瑞林装备有限公司 Electrolytic negative plate
CN213896019U (en) * 2020-12-10 2021-08-06 无锡灵惠材料科技有限公司 Titanium-aluminum-titanium composite cathode plate
CN214088695U (en) * 2020-12-10 2021-08-31 江苏中色复合材料有限公司 Connection structure of titanium-aluminum-titanium composite polar plate
CN214088696U (en) * 2020-12-10 2021-08-31 江苏中色复合材料有限公司 Hanger of titanium-aluminum composite electrode plate
CN113897643A (en) * 2021-10-11 2022-01-07 兰州理工大学 A sandwich composite metal electrolysis and deposition cathode plate

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009114475A (en) * 2007-11-02 2009-05-28 Mitsui Mining & Smelting Co Ltd Electrode for producing electrolytic copper powder and anode for producing electrolytic copper powder
CN102766887A (en) * 2012-08-16 2012-11-07 张家港市江城冶化科技有限公司 Method for manufacturing stainless steel negative plate
CN105274579A (en) * 2014-05-26 2016-01-27 江西瑞林装备有限公司 Electrolytic negative plate
CN213896019U (en) * 2020-12-10 2021-08-06 无锡灵惠材料科技有限公司 Titanium-aluminum-titanium composite cathode plate
CN214088695U (en) * 2020-12-10 2021-08-31 江苏中色复合材料有限公司 Connection structure of titanium-aluminum-titanium composite polar plate
CN214088696U (en) * 2020-12-10 2021-08-31 江苏中色复合材料有限公司 Hanger of titanium-aluminum composite electrode plate
CN113897643A (en) * 2021-10-11 2022-01-07 兰州理工大学 A sandwich composite metal electrolysis and deposition cathode plate

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Application publication date: 20220624