CN114633941B - A light-weight thermal insulation protection box with anti-drop impact - Google Patents
A light-weight thermal insulation protection box with anti-drop impact Download PDFInfo
- Publication number
- CN114633941B CN114633941B CN202210303991.5A CN202210303991A CN114633941B CN 114633941 B CN114633941 B CN 114633941B CN 202210303991 A CN202210303991 A CN 202210303991A CN 114633941 B CN114633941 B CN 114633941B
- Authority
- CN
- China
- Prior art keywords
- buffer
- box
- component
- lightweight
- outer layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000004224 protection Effects 0.000 title claims abstract description 49
- 238000009413 insulation Methods 0.000 title claims description 47
- 230000001681 protective effect Effects 0.000 claims abstract description 26
- 229920003225 polyurethane elastomer Polymers 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims abstract description 15
- 239000000956 alloy Substances 0.000 claims abstract description 10
- 238000010521 absorption reaction Methods 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 7
- 239000011148 porous material Substances 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 229920002748 Basalt fiber Polymers 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 3
- 230000001133 acceleration Effects 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 3
- 238000004321 preservation Methods 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 34
- 230000003139 buffering effect Effects 0.000 description 13
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical group OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 5
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 239000004970 Chain extender Substances 0.000 description 2
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- -1 polyoxypropylene Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical group CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003562 lightweight material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/20—External fittings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/14—Linings or internal coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/34—Coverings or external coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Packages (AREA)
- Laminated Bodies (AREA)
Abstract
本发明涉及一种抗跌落冲击轻质保温防护箱,属于防护箱技术领域。所述防护箱包括缓冲保温外层、轻质箱体以及缓冲防护内层,缓冲保温外层包裹在轻质箱体的外部,缓冲防护内层安装在轻质箱体的内部;其中,缓冲保温外层和缓冲防护内层均选用密度为300~400kg/m3、导热系数为0.03~0.04W/(m·K)以及单位体积吸能为60~120MJ/m3的聚氨酯弹性体,轻质箱体选用密度为1.5~2.7g/cm3、拉伸强度≥200MPa以及压缩强度≥200MPa的纤维复合材料或合金材料,缓冲保温外层上加工有半球形凸起结构,缓冲防护内层上设有限位凹槽,轻质箱体是由上箱体和下箱体通过搭扣组件形成的封闭中空箱体。本发明所述防护箱结构简单,易于制作,便于拆卸与组装,同时兼具轻质、保温以及吸能等特点,通用性强。
The invention relates to a drop-shock-resistant lightweight heat-preservation protection box, which belongs to the technical field of protection boxes. The protective box includes a buffer heat preservation outer layer, a lightweight box body and a buffer protection inner layer, the buffer heat preservation outer layer is wrapped outside the light weight box body, and the buffer protection inner layer is installed inside the light weight box body; wherein, the buffer heat preservation Both the outer layer and the buffer protection inner layer are made of polyurethane elastomer with a density of 300-400kg/m 3 , a thermal conductivity of 0.03-0.04W/(m·K), and an energy absorption per unit volume of 60-120MJ/m 3 , which is lightweight The box body is made of fiber composite or alloy materials with a density of 1.5-2.7g/cm 3 , a tensile strength of ≥200MPa, and a compressive strength of ≥200MPa. There are limited grooves, and the lightweight box is a closed hollow box formed by the upper box and the lower box through the buckle assembly. The protection box of the present invention is simple in structure, easy to manufacture, convenient to disassemble and assemble, and has the characteristics of light weight, heat preservation and energy absorption, etc., and has strong versatility.
Description
技术领域Technical Field
本发明涉及一种抗跌落冲击轻质保温防护箱,属于防护箱技术领域。The invention relates to a drop-impact resistant lightweight heat-insulating protective box, belonging to the technical field of protective boxes.
背景技术Background Art
部队战士及医生,在恶劣环境地区执勤及抗震救灾地区救援时,需要向特定的地点空投物资。例如向恶劣环境地区及受灾点运送急救用医疗器械、药品、食物、弹药等物资,如遇到公路及铁路运输无法到达地区,就需要采用无人机空投方式,为了确保器械、药品、食品、弹药等物资安全无损地到达指定地点,包装箱设有缓冲装置,以减少着地瞬间对内容物的冲击。随着部队物资在运输及储存过程中对包装箱要求越来越高,传统的木箱、铁箱、滚塑箱、PP热塑材料等存在重量大、机动性差、装卸不便、耐候性差、不保温落地瞬间箱体不具备缓冲功能等因素,无法满足现有军用物资对包装载体的要求。现阶段铝蜂窝纸板、泡沫铝缓冲材料制备防护箱克服传统材料防护箱的缺点,但其制作成本较高,无法实现批量化服役。Soldiers and doctors need to airdrop supplies to specific locations when they are on duty in harsh environments and rescuing in earthquake relief areas. For example, when transporting emergency medical equipment, medicines, food, ammunition and other supplies to harsh environments and disaster areas, if roads and railways cannot reach the area, drones need to be used for airdrop. In order to ensure that equipment, medicines, food, ammunition and other supplies arrive at the designated location safely and intact, the packaging box is equipped with a buffer device to reduce the impact on the contents at the moment of landing. As the requirements for packaging boxes for military materials become higher and higher during transportation and storage, traditional wooden boxes, iron boxes, roto-molded boxes, PP thermoplastic materials, etc. have the characteristics of heavy weight, poor maneuverability, inconvenient loading and unloading, poor weather resistance, lack of insulation, and the box body does not have a buffer function at the moment of landing, which cannot meet the requirements of existing military materials for packaging carriers. At present, aluminum honeycomb paperboard and foam aluminum buffer materials are used to prepare protective boxes to overcome the shortcomings of traditional material protective boxes, but their production costs are high and cannot be put into mass service.
发明内容Summary of the invention
针对现有技术存在的不足,本发明提供一种抗跌落冲击轻质保温防护箱,采用外层缓冲保温结构、轻质骨架结构以及内层缓冲防护结构的复合结构设计,既能起到落地缓冲作用又能给防护箱带来有效的保温功能,而且各部分结构易于规模化生产,组装与拆卸方便,具有很好的应用前景。In view of the shortcomings of the prior art, the present invention provides a lightweight thermal insulation protective box that is resistant to drop impacts. It adopts a composite structure design of an outer buffering and thermal insulation structure, a lightweight skeleton structure and an inner buffering and protective structure. It can not only play a landing buffer role but also provide an effective thermal insulation function for the protective box. Moreover, each part of the structure is easy to mass produce and is convenient to assemble and disassemble, and has a good application prospect.
本发明的目的是通过以下技术方案实现的。The objectives of the present invention are achieved through the following technical solutions.
一种抗跌落冲击轻质保温防护箱,所述防护箱包括缓冲保温外层、轻质箱体以及缓冲防护内层,缓冲保温外层包裹在轻质箱体的外部,缓冲防护内层安装在轻质箱体的内部;A drop-impact resistant lightweight thermal insulation protection box, the protection box comprising a buffer thermal insulation outer layer, a lightweight box body and a buffer protection inner layer, the buffer thermal insulation outer layer is wrapped on the outside of the lightweight box body, and the buffer protection inner layer is installed inside the lightweight box body;
所述缓冲保温外层选用密度为300~400kg/m3、导热系数为0.03~0.04W/(m·K)以及单位体积吸能为60~120MJ/m3的聚氨酯弹性体;所述缓冲保温外层上加工有半球形凸起结构;The buffer and thermal insulation outer layer is made of polyurethane elastomer with a density of 300-400 kg/m 3 , a thermal conductivity of 0.03-0.04 W/(m·K) and an energy absorption per unit volume of 60-120 MJ/m 3 ; the buffer and thermal insulation outer layer is processed with a hemispherical convex structure;
所述轻质箱体选用密度为1.5~2.7g/cm3、拉伸强度≥200MPa以及压缩强度≥200MPa的纤维复合材料或合金材料;所述轻质箱体是由上箱体和下箱体通过搭扣组件形成的封闭中空箱体;The lightweight box body is made of fiber composite material or alloy material with a density of 1.5-2.7 g/cm 3 , a tensile strength of ≥200 MPa and a compressive strength of ≥200 MPa; the lightweight box body is a closed hollow box body formed by an upper box body and a lower box body through a buckle assembly;
所述缓冲防护内层选用密度为300~400kg/m3、导热系数为0.03~0.04W/(m·K)以及单位体积吸能为60~120MJ/m3的聚氨酯弹性体;所述缓冲防护内层上设有限位凹槽。The buffer protection inner layer is made of polyurethane elastomer with a density of 300-400 kg/m 3 , a thermal conductivity of 0.03-0.04 W/(m·K) and an energy absorption per unit volume of 60-120 MJ/m 3 ; and a limiting groove is provided on the buffer protection inner layer.
进一步地,所述缓冲保温外层的厚度为σ,所述缓冲保温外层上半球形凸起结构的半径为r,所述缓冲保温外层上均匀分布的半球形凸起结构个数为n,则Furthermore, the thickness of the buffer and thermal insulation outer layer is σ, the radius of the hemispherical convex structure on the buffer and thermal insulation outer layer is r, and the number of hemispherical convex structures evenly distributed on the buffer and thermal insulation outer layer is n, then
6h1≤r≤8h1 6h 1 ≤r ≤8h 1
其中,c1代表内装物比热容,m1代表内装物的质量,c2代表聚氨酯弹性体的比热容,T2代表起始防护箱内环境温度,T’1代表起始内装物温度,T’2最终防护箱内(或者内装物)温度,负号代表传热方向与温度梯度方向相反,λ代表导热系数,t代表保温时间,g代表重力加速度,W代表防护箱的宽度,H代表防护箱坠落高度,A代表防护箱的表面积,M代表防护箱中内装物的总质量,V代表防护箱的体积,ρ代表聚氨酯弹性体的密度,V台为缓冲保温外层上所有半球形凸起结构的总体积,h1为所有半球形凸起结构平均分配至外表面缓冲保温外层上堆积高度。Among them, c1 represents the specific heat capacity of the contents, m1 represents the mass of the contents, c2 represents the specific heat capacity of the polyurethane elastomer, T2 represents the initial ambient temperature in the protective box, T'1 represents the initial temperature of the contents, T'2 represents the final temperature in the protective box (or the contents), the negative sign represents that the heat transfer direction is opposite to the direction of the temperature gradient, λ represents the thermal conductivity, t represents the insulation time, g represents the acceleration of gravity, W represents the width of the protective box, H represents the falling height of the protective box, A represents the surface area of the protective box, M represents the total mass of the contents in the protective box, V represents the volume of the protective box, ρ represents the density of the polyurethane elastomer, V台is the total volume of all hemispherical convex structures on the buffer and thermal insulation outer layer, and h1 is the stacking height of all hemispherical convex structures evenly distributed to the outer surface of the buffer and thermal insulation outer layer.
进一步地,所述缓冲保温外层以及缓冲防护内层选用的聚氨酯弹性体材料是由A组分与B组分反应固化成型得到的;Furthermore, the polyurethane elastomer material selected for the buffering and heat-insulating outer layer and the buffering and protective inner layer is obtained by curing and molding component A and component B;
所述A组分由聚醚多元醇、扩链剂、发泡剂、催化剂、开孔剂和填料混合均匀配制而成;所述聚醚多元醇为3官能度5000分子量的聚氧化丙烯三醇(EP-330N)和2官能度8000分子量的聚氧化丙烯二醇(ED-14),所述扩链剂为1,4-丁二醇(BDO),所述发泡剂为H2O,所述催化剂为双(二甲氨基乙基)醚(BDMAEE)和二月桂酸二丁基锡(T12),所述开孔剂为开孔硅油(优选上海晔兴实业有限公司牌号为ECOADD-019C的开孔硅油),所述填料为活性碳纤维;A组分的原料中各组分的质量份数如下:EP-330N 15~25份,ED-14 65~75份,BDO 3~10份,H2O 0.40~0.48份,BDMAEE 0.10~0.15份,T12 0.01~0.02份,开孔硅油0.85~0.95份,活性碳纤维2~6份;The component A is prepared by uniformly mixing polyether polyol, chain extender, foaming agent, catalyst, pore opening agent and filler; the polyether polyol is polyoxypropylene triol (EP-330N) with a functionality of 3 and a molecular weight of 5000 and polyoxypropylene diol (ED-14) with a functionality of 2 and a molecular weight of 8000, the chain extender is 1,4-butanediol (BDO), the foaming agent is H 2 O, the catalyst is bis(dimethylaminoethyl) ether (BDMAEE) and dibutyltin dilaurate (T12), the pore opening agent is pore opening silicone oil (preferably the pore opening silicone oil with the brand name ECOADD-019C produced by Shanghai Yexing Industrial Co., Ltd.), and the filler is activated carbon fiber; the mass fractions of each component in the raw materials of component A are as follows: EP-330N 15-25 parts, ED-14 65-75 parts, BDO 3-10 parts, H 2 O 0.40-0.48 parts, BDMAEE 0.10-0.15 parts, T12 0.01-0.02 parts, open-pore silicone oil 0.85-0.95 parts, activated carbon fiber 2-6 parts;
所述B组分为多亚甲基多苯基异氰酸酯(PM-200);B组分含有的-NCO基团与A组分含有的活泼-H的摩尔比为(0.98~1.03):1.00,其中A组分中的活泼-H为多元醇-OH中的活泼-H和H2O中活泼-H之和。The B component is polymethylene polyphenyl isocyanate (PM-200); the molar ratio of -NCO groups contained in the B component to active -H contained in the A component is (0.98-1.03):1.00, wherein the active -H in the A component is the sum of the active -H in the polyol -OH and the active -H in H2O .
进一步地,A组分与B组分反应的具体操作如下:先将A组分预热至35±2℃、B组分预热至45±2℃,然后将预热后的A组分和预热后的B组分浇注到预热至65±5℃的模具中,在60~70℃下固化成型,得到聚氨酯弹性体。Furthermore, the specific operation of the reaction of component A and component B is as follows: first preheat component A to 35±2°C and component B to 45±2°C, then pour the preheated component A and the preheated component B into a mold preheated to 65±5°C, and cure at 60-70°C to obtain a polyurethane elastomer.
进一步地,所述轻质箱体的材料选用玻璃纤维复合材料、碳纤维复合材料、玄武岩纤维复合材料、铝合金材料或钛合金材料。Furthermore, the lightweight box body is made of glass fiber composite material, carbon fiber composite material, basalt fiber composite material, aluminum alloy material or titanium alloy material.
有益效果:Beneficial effects:
(1)本发明采用外层缓冲保温结构、轻质骨架结构以及内层缓冲防护结构的复合结构设计,既能起到落地缓冲作用又能给防护箱带来有效的保温功能,还能够抵抗风沙、酷热、严寒、高空坠落的袭击,具有抗强冲击、耐高低温、缓冲减震、防水防潮、防紫外线、防尘抗腐作用,在丛林、沙漠、航空、航海、高原等各种恶劣环境下可保证内部装载物资的完整性、使用性和可靠性。(1) The present invention adopts a composite structure design of an outer buffer insulation structure, a lightweight skeleton structure and an inner buffer protection structure, which can not only play a role in cushioning the impact of falling but also provide an effective thermal insulation function for the protective box. It can also resist attacks from wind and sand, extreme heat, severe cold, and falling from a high altitude. It has the functions of strong impact resistance, high and low temperature resistance, buffering and shock absorption, waterproof and moisture-proof, UV protection, dustproof and corrosion resistance. It can ensure the integrity, usability and reliability of the internally loaded materials in various harsh environments such as jungles, deserts, aviation, navigation, and plateaus.
(2)本发明在轻质箱体外设置的缓冲保温外层,其表面的半球形凸起结构会最先接触地面,通过聚氨酯弹性体内的泡孔溃缩,吸收大量冲击能量,减少冲击能对防护箱内装物的损伤;同时,缓冲保温外层的导热系数极低,具有良好的保温效果。(2) The buffering and heat-insulating outer layer of the present invention is arranged outside the lightweight box. The hemispherical convex structure on its surface will first contact the ground, and absorb a large amount of impact energy through the collapse of the bubbles in the polyurethane elastomer, thereby reducing the damage of the impact energy to the contents of the protective box. At the same time, the thermal conductivity of the buffering and heat-insulating outer layer is extremely low, and has a good thermal insulation effect.
(3)本发明在轻质箱体内设置缓冲防护内层,内防护层可保证内装物之间不发生接触,而且还可以起到一定的缓冲以及保温效果。(3) The present invention provides a buffering protective inner layer in the lightweight box. The inner protective layer can ensure that the contents do not come into contact with each other and can also provide a certain buffering and heat preservation effect.
(4)本发明所述防护箱各结构部分均可采用模块化生产,且各部分之间便于组装、拆卸,同时各部分都可以根据防护箱的实际使用工况环境进行单独设计,从而赋予防护箱适应各种外部工况及不同的内部结构匹配相应的内装物资,通用性强,具有很好的应用前景。(4) All structural parts of the protective box described in the present invention can be produced in a modular manner, and the parts can be easily assembled and disassembled. At the same time, each part can be individually designed according to the actual working conditions of the protective box, thereby enabling the protective box to adapt to various external working conditions and different internal structures to match the corresponding internal materials. It has strong versatility and good application prospects.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为实施例1中所述抗跌落冲击轻质保温防护箱的主视图;图中,1-半球形凸起结构,2-搭扣组件。Fig. 1 is a front view of the drop-impact-resistant lightweight thermal insulation protective box described in Example 1; in the figure, 1 is a hemispherical protrusion structure, and 2 is a buckle assembly.
具体实施方式DETAILED DESCRIPTION
下面结合具体实施方式对本发明作进一步阐述,其中,所述方法如无特别说明均为常规方法,所述原材料如无特别说明均能从公开商业途径获得。The present invention is further described below in conjunction with specific embodiments, wherein the methods are conventional methods unless otherwise specified, and the raw materials can be obtained from public commercial channels unless otherwise specified.
实施例1Example 1
一种抗跌落冲击轻质保温防护箱,所述防护箱包括缓冲保温外层、轻质箱体以及缓冲防护内层,缓冲保温外层包裹在轻质箱体的外部,缓冲防护内层安装在轻质箱体的内部;A drop-impact resistant lightweight thermal insulation protection box, the protection box comprising a buffer thermal insulation outer layer, a lightweight box body and a buffer protection inner layer, the buffer thermal insulation outer layer is wrapped on the outside of the lightweight box body, and the buffer protection inner layer is installed inside the lightweight box body;
所述缓冲保温外层以及缓冲防护内层均选用密度为300~400kg/m3、导热系数为0.03~0.04W/(m·K)以及单位体积吸能为60~120MJ/m3的聚氨酯弹性体,该聚氨酯弹性体的具体制备步骤如下:先将A组分预热至35±2℃、B组分预热至45±2℃,然后将预热后的A组分和预热后的B组分浇注到预热至65±5℃的模具中,在60~70℃下固化成型,得到聚氨酯弹性体;其中,A组分由EP-330N15~25份、ED-14 65~75份、BDO 3~10份、H2O 0.40~0.48份、BDMAEE 0.10~0.15份、T12 0.01~0.02份、上海晔兴实业有限公司牌号为ECOADD-019C开孔硅油0.85~0.95份以及活性碳纤维2~6份混合均匀配制而成,B组分为PM-200,B组分含有的-NCO基团与A组分含有的活泼-H的摩尔比为(0.98~1.03):1.00;The buffer thermal insulation outer layer and the buffer protection inner layer are both made of polyurethane elastomer with a density of 300-400 kg/m 3 , a thermal conductivity of 0.03-0.04 W/(m·K) and an energy absorption per unit volume of 60-120 MJ/m 3 . The specific preparation steps of the polyurethane elastomer are as follows: firstly preheating component A to 35±2°C and component B to 45±2°C, then pouring the preheated component A and component B into a mold preheated to 65±5°C, and curing and molding at 60-70°C to obtain a polyurethane elastomer; wherein component A is composed of 15-25 parts of EP-330N, 65-75 parts of ED-14, 3-10 parts of BDO, 0.40-0.48 parts of H 2 O, 0.10-0.15 parts of BDMAEE, and T12 0.01-0.02 parts, 0.85-0.95 parts of open-pore silicone oil ECOADD-019C produced by Shanghai Yexing Industrial Co., Ltd. and 2-6 parts of activated carbon fiber are uniformly mixed and prepared, component B is PM-200, and the molar ratio of -NCO group contained in component B to active -H contained in component A is (0.98-1.03):1.00;
所述缓冲保温外层上加工有均匀分布的半球形凸起结构1,如图1所示;所述缓冲保温外层的厚度为σ,所述缓冲保温外层上半球形凸起结构1的半径为r,所述缓冲保温外层上均匀分布的半球形凸起结构1个数为n,则:The buffer thermal insulation outer layer is processed with uniformly distributed
6h1≤r≤8h1 6h 1 ≤r ≤8h 1
其中,c1代表内装物比热容,m1代表内装物的质量,c2代表聚氨酯弹性体的比热容,T2代表起始防护箱内环境温度,T’1代表起始内装物温度,T’2最终防护箱内(或者内装物)温度,负号代表传热方向与温度梯度方向相反,λ代表导热系数,t代表保温时间,g代表重力加速度,W代表防护箱的宽度,H代表防护箱坠落高度,A代表防护箱的表面积,M代表防护箱中内装物的总质量,V代表防护箱的体积,ρ代表聚氨酯弹性体的密度,V台为缓冲保温外层上所有半球形凸起结构1的总体积,h1为所有半球形凸起结构1平均分配至外表面缓冲保温外层上堆积高度;Wherein, c1 represents the specific heat capacity of the contents, m1 represents the mass of the contents, c2 represents the specific heat capacity of the polyurethane elastomer, T2 represents the initial ambient temperature in the protection box, T'1 represents the initial temperature of the contents, T'2 represents the final temperature in the protection box (or the contents), the negative sign represents that the heat transfer direction is opposite to the temperature gradient direction, λ represents the thermal conductivity, t represents the insulation time, g represents the acceleration of gravity, W represents the width of the protection box, H represents the falling height of the protection box, A represents the surface area of the protection box, M represents the total mass of the contents in the protection box, V represents the volume of the protection box, ρ represents the density of the polyurethane elastomer, V台is the total volume of all
所述轻质箱体选用密度为1.5~2.7g/cm3、拉伸强度≥200MPa以及压缩强度≥200MPa的纤维复合材料或合金材料(如玻璃纤维复合材料、碳纤维复合材料、玄武岩纤维复合材料、铝合金材料或钛合金材料);所述轻质箱体是由上箱体和下箱体通过搭扣组件2形成的封闭中空箱体,如图1所示;The lightweight box is made of a fiber composite material or alloy material (such as glass fiber composite material, carbon fiber composite material, basalt fiber composite material, aluminum alloy material or titanium alloy material) with a density of 1.5-2.7 g/cm 3 , a tensile strength of ≥200 MPa and a compressive strength of ≥200 MPa; the lightweight box is a closed hollow box formed by an upper box and a lower box through a
所述缓冲防护内层上设有限位凹槽,限位凹槽具体结构根据所装的具体内装物进行设计,用于固定内装物且避免内装物之间发生接触而造成内装物破损;The buffer protection inner layer is provided with a limiting groove, the specific structure of which is designed according to the specific contents to be loaded, and is used to fix the contents and prevent the contents from contacting each other and causing damage to the contents;
本实施例所述防护箱的缓冲保温外层和缓冲防护内层均选用兼具低密度、低导热系数、优异缓冲吸能性能以及优异力学性能的聚氨酯弹性体,轻质箱体选用力学性能优异的轻质材料,并在缓冲保温外层的表面上加工半球形凸起结构,确保防护箱在轻质的基础上具有良好的抗缓冲性能以及保温性能;另外,所述防护箱的各部分结构易于规模化生产,组装与拆卸方便,而且各部分都可以根据防护箱的实际使用工况环境进行单独设计,从而使防护箱能够满足各种外部工况及不同内装物资的应用需求。The buffering and heat-insulating outer layer and the buffering and protective inner layer of the protection box described in this embodiment are both made of polyurethane elastomer with low density, low thermal conductivity, excellent buffering and energy absorption performance and excellent mechanical properties. The lightweight box body is made of lightweight materials with excellent mechanical properties, and a hemispherical protrusion structure is processed on the surface of the buffering and heat-insulating outer layer to ensure that the protection box has good anti-buffering and thermal insulation properties on the basis of light weight. In addition, the various structural parts of the protection box are easy to mass produce and easy to assemble and disassemble, and each part can be individually designed according to the actual operating conditions of the protection box, so that the protection box can meet the application requirements of various external working conditions and different internal materials.
综上所述,以上仅为本发明的较佳实施例而已,并非用于限定本发明的保护范围。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。In summary, the above are only preferred embodiments of the present invention and are not intended to limit the protection scope of the present invention. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention should be included in the protection scope of the present invention.
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210303991.5A CN114633941B (en) | 2022-03-25 | 2022-03-25 | A light-weight thermal insulation protection box with anti-drop impact |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210303991.5A CN114633941B (en) | 2022-03-25 | 2022-03-25 | A light-weight thermal insulation protection box with anti-drop impact |
Publications (2)
Publication Number | Publication Date |
---|---|
CN114633941A CN114633941A (en) | 2022-06-17 |
CN114633941B true CN114633941B (en) | 2023-03-24 |
Family
ID=81950574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210303991.5A Active CN114633941B (en) | 2022-03-25 | 2022-03-25 | A light-weight thermal insulation protection box with anti-drop impact |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114633941B (en) |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN202115883U (en) * | 2011-07-01 | 2012-01-18 | 中国人民解放军军事医学科学院卫生装备研究所 | Heat-insulation box for field operations |
CN204750820U (en) * | 2015-05-24 | 2015-11-11 | 亳州师范高等专科学校 | Fast dismouting packing box |
JP6551087B2 (en) * | 2015-09-10 | 2019-07-31 | 三菱ケミカル株式会社 | Polylactic acid-based laminate film, heat-shrinkable laminate film using the laminate film, molded article using the heat-shrinkable laminate film, heat-shrinkable label, and using the molded article or the label container |
CN206798204U (en) * | 2016-10-27 | 2017-12-26 | 杭州沛文科技有限公司 | A kind of box for material circulation |
CN109018621A (en) * | 2018-09-12 | 2018-12-18 | 张家港精工包装彩印有限公司 | Multi-functional shock-proof keeps the temperature packing case |
CN215044565U (en) * | 2021-03-25 | 2021-12-07 | 深圳圆满智能电子有限公司 | Heat insulation box |
-
2022
- 2022-03-25 CN CN202210303991.5A patent/CN114633941B/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN114633941A (en) | 2022-06-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2021120567A1 (en) | Anti-collision device combining chiral structure having negative poisson's ratio with honeycomb structure | |
JP3193107B2 (en) | Missile canister and its manufacturing method | |
CN101227029B (en) | Composite material satellite antenna reflection surface and manufacturing process thereof | |
ES2642198T3 (en) | Composite construction items and methods to manufacture them | |
US10132597B2 (en) | Ballistic-resistant structural insulated panels | |
US12091150B2 (en) | Low-density structured materials and methods of making and using same | |
CN112757740B (en) | High-strength lightweight carriage plate and preparation method thereof | |
KR102676307B1 (en) | Liquid hydrogen Hydrogen storage container | |
CN112303481A (en) | A type A land storage tank for LNG storage | |
US9027782B1 (en) | Composite material based insulated shipping container | |
CN114633941B (en) | A light-weight thermal insulation protection box with anti-drop impact | |
KR0148557B1 (en) | Element having a multi-directional cellular sturucture and the manufacture method thereof | |
Wang et al. | Mechanical properties of rigid and flexible polyurethane foam in-situ foamed Nomex honeycomb | |
CN203881216U (en) | High-rigidity light launching box | |
CN114183685B (en) | Bearing type heat insulation supporting structure of low-temperature storage box | |
KR102676297B1 (en) | Liquid hydrogen storage container | |
CN104071313B (en) | Elastically bendable anti-impact energy-absorbing cover layer | |
KR101865673B1 (en) | Non-foam polyurethane type insulation and structural components, and insulation cargo tank of low temperature using the same | |
CN113414998A (en) | High-strength heat-insulation composite board and preparation method thereof | |
CN207105805U (en) | A kind of pearl cotton for protection, heat insulation and shock absorption | |
CN100385194C (en) | Composite material box structure of missile storage and launch box | |
KR102676293B1 (en) | Liquid hydrogen storage container | |
CN108799813A (en) | Honeycomb structure | |
RU2497716C2 (en) | Structural element and method of its fabrication | |
CN1359827A (en) | Hard-shell balloon or airship using hydrogen safety and able to control its lifting |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |