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CN114632425A - Membrane element flow passage separation net detection device and application thereof - Google Patents

Membrane element flow passage separation net detection device and application thereof Download PDF

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Publication number
CN114632425A
CN114632425A CN202011490380.3A CN202011490380A CN114632425A CN 114632425 A CN114632425 A CN 114632425A CN 202011490380 A CN202011490380 A CN 202011490380A CN 114632425 A CN114632425 A CN 114632425A
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membrane element
area
separation net
feeding
element flow
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朱丽香
林兴榕
姚萌
洪昱斌
方富林
蓝伟光
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Suntar Membrane Technology Xiamen Co Ltd
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Suntar Membrane Technology Xiamen Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/10Testing of membranes or membrane apparatus; Detecting or repairing leaks

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  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses a membrane element flow passage screen detection device and application thereof. The invention can directly and rapidly detect the indexes of a plurality of dimensions such as diffusivity, pollutant carrying property, energy saving property and the like of the membrane element flow passage separation net; the invention has simple structure and low manufacturing cost, does not need various instruments, and only needs the charging barrel, the charging pump, the separation net tank, the matched pipeline and the valve; the invention has low operation pressure and low requirement on the pressure-resistant grade of the material, can use transparent organic materials such as a subgrid plate, glass and the like, and does not need to use stainless steel with high pressure-resistant grade; the invention has low requirement on sealing and fixing, can achieve the sealing effect only by adopting a simple clamping and fixing mechanism, and has very simple and convenient operation.

Description

一种膜元件流道隔网检测装置及其应用Membrane element flow channel separator net detection device and its application

技术领域technical field

本发明属于膜检测技术领域,具体涉及一种膜元件流道隔网检测装置及其应用。The invention belongs to the technical field of membrane detection, and in particular relates to a membrane element flow channel separator detection device and its application.

背景技术Background technique

在卷式膜元件中,浓水隔网不但起到支撑流道、导流液体的作用,而且可以作为组件内的湍流促进器,在有效加强湍流的同时降低膜面上的浓差极化和污染现象。但是,隔网在提高传质效率的同时,使得流体的流动阻力增加,压力损失增大,从而加大了能耗,还会带来局部的沟流、死区等。为使膜组件进一步适应多元化的应用领域、延长膜元件使用寿命,隔网的优化设计显得尤为重要。In the roll-type membrane element, the concentrated water separator not only plays the role of supporting the flow channel and diverting the liquid, but also can be used as a turbulence promoter in the module, which can effectively strengthen the turbulence and reduce the concentration polarization on the membrane surface. pollution phenomenon. However, while improving the mass transfer efficiency, the separation net increases the flow resistance of the fluid and the pressure loss, thereby increasing the energy consumption, and also brings local channel flow, dead zone and so on. In order to further adapt the membrane module to diversified application fields and prolong the service life of the membrane element, the optimal design of the separator is particularly important.

目前对隔网的评价方法,主要集中在隔网厚度、隔网间距、入水角度以及隔网形状等几何参数,而对其抗污染性能的评价很少,多侧重采用CFD技术模拟膜元件内料液的流体分布状态,进而评价隔网对组件的抗污染作用;或者将隔网卷制到膜页中,通过膜元件的截留率、通量、压降等性能,间接评价隔网的的抗污染性性能。At present, the evaluation methods of separators mainly focus on geometric parameters such as the thickness of the separators, the spacing of the separators, the angle of water entry and the shape of the separators, while the evaluation of its anti-pollution performance is seldom, and most of them focus on the use of CFD technology to simulate the inner material of membrane elements The fluid distribution state of the liquid, and then evaluate the anti-fouling effect of the separator on the module; or roll the separator into the membrane sheet, and indirectly evaluate the anti-fouling of the separator through the retention rate, flux, pressure drop and other properties of the membrane element. polluting properties.

《平板膜组件内部流体流动状态的可视化》(王涛等,化工学报,第65卷第1期,第71-77页,2014年1月)公开了一种有机玻璃膜组件,由透明的有机玻璃制成,用于直接观察和测试不同隔网的流体力学性能。膜组件出入口处都留有“V”形槽,使得流体在膜组件表面分布均匀,消除进出口的影响。隔网安装在中间长方形区域内,流体经过蠕动泵从进水口输送进入装置,然后汇集到出水口由出水口流出装置,装置进水管路和出水管路都安装有压力表,用于检测进出水的压力,计算流体经过隔网后的压力损失。但是在实际使用过程中,该技术方案有诸多缺陷:1)短流现象,水流的分布非常不均匀,主要集中在入水口和出水口的中心线位置流动,两侧水量少、水流缓慢;2)对水平度要求非常严苛,整个流道是扁平状,在与水流垂直方向上装置稍微有倾斜,在低流速条件下水流会发生比较严重的分布不均匀情况,即低位水流集中,流速快,高位水流缓慢,扩散差;3)装置检测的参数单一,只能检测前后的流体压力,计算流道中的压力损失ΔP。但是由于检测的隔网面积相对于膜元件来说非常小,所以压力损失非常小,几乎测不出来;4)检测方法通过拍照,肉眼观察确定示踪剂产生扩散的最低流速,但是根据实际检测结果发现,隔网的结构的影响远远大于流速的影响,即菱形隔网在很低的流速下,就能产生扩散现象,但是平行隔网,在高流速下扩散效果仍然相对较差。"Visualization of Fluid Flow State in Flat Membrane Modules" (Wang Tao et al., Chinese Journal of Chemical Industry, Vol. 65, No. 1, Pages 71-77, January 2014) discloses a plexiglass membrane module consisting of transparent plexiglass Made for direct observation and testing of the hydrodynamic properties of different separators. There are "V"-shaped grooves at the inlet and outlet of the membrane module, so that the fluid is evenly distributed on the surface of the membrane module and eliminates the influence of the inlet and outlet. The partition screen is installed in the middle rectangular area. The fluid is transported into the device from the water inlet through the peristaltic pump, and then collected to the water outlet from the water outlet. pressure, and calculate the pressure loss after the fluid passes through the screen. However, in the actual use process, this technical solution has many defects: 1) short flow phenomenon, the distribution of water flow is very uneven, mainly concentrated in the centerline of the water inlet and water outlet, and the water volume on both sides is small and the water flow is slow; 2 ) The levelness requirements are very strict, the entire flow channel is flat, and the device is slightly inclined in the vertical direction to the water flow. Under the condition of low flow rate, the water flow will have a serious uneven distribution, that is, the low-level water flow is concentrated and the flow rate is fast. , the high-level water flow is slow and the diffusion is poor; 3) The parameters detected by the device are single, only the fluid pressure before and after can be detected, and the pressure loss ΔP in the flow channel is calculated. However, since the detected screen area is very small compared to the membrane element, the pressure loss is very small and can hardly be detected; 4) The detection method determines the minimum flow rate of the tracer diffusion by taking pictures and visual observation, but according to the actual detection It was found that the influence of the structure of the separator is far greater than that of the flow velocity, that is, the rhombic separator can produce diffusion at very low flow rates, but the diffusion effect of parallel separators is still relatively poor at high flow rates.

CN204563945U公开了一种进料流道网的选型装置,包括储料罐、输料泵、流道网的固定器、进料压力表和出料压力表。装置通过检测进料和出料的压力,计算压力损失,压力差在0.045~0.055MPa之间,则隔网选型适配,如果压力差小于0.045MPa,则说明隔网选型偏大,需要选择更窄流道的隔网,如果压力差大于0.055MPa,则说明隔网选型偏小,需要选更宽流道的隔网,直至所选隔网的进料和出料压力差在范围内。该选型装置的缺陷在于:1)检测的参数单一,只能检测装置前后的压力,计算流道中的压力损失ΔP。但是由于检测的隔网面积相对于膜元件来说非常小,所以压力损失非常小,几乎测不出来;2)功能单一,只能用于筛选隔网厚度,对于隔网的其他性能参数(如扩散性、纳污性等)不能在一个装置上检测,需要做成完成的膜元件,通过对膜元件的检测结果来评价隔网的性能。CN204563945U discloses a type selection device for a feed flow channel network, including a material storage tank, a material delivery pump, a holder for the flow channel network, a feed pressure gauge and a discharge pressure gauge. The device calculates the pressure loss by detecting the pressure of the feeding and discharging materials. If the pressure difference is between 0.045 and 0.055MPa, the screen selection is suitable. If the pressure difference is less than 0.045MPa, it means that the screen selection is too large and needs to be Select a spacer with a narrower flow channel. If the pressure difference is greater than 0.055MPa, it means that the type of the spacer is too small, and a spacer with a wider flow channel needs to be selected until the pressure difference between the feed and discharge of the selected spacer is within the range. Inside. The defects of this type selection device are: 1) The detection parameters are single, and only the pressure before and after the device can be detected, and the pressure loss ΔP in the flow channel can be calculated. However, since the area of the screen to be tested is very small compared to the membrane element, the pressure loss is very small and can hardly be measured; 2) The function is single and can only be used to screen the thickness of the screen. For other performance parameters of the screen (such as Diffusion, dirt holding capacity, etc.) cannot be tested on one device, and a completed membrane element needs to be made, and the performance of the separator is evaluated by the test results of the membrane element.

CN106731864B公开了一种用于浓网抗污染性检测的装置,包括下模板、定位滑块A、定位滑块B及上模板,所述下模板的上端面设有弧形凸台,下模板的下端面设有贯穿弧形凸台的产水出口A,所述上模板的下端面设有弧形凹槽,上端面设有连通弧形凹槽的产水出口B、上模板的两端分别设有与弧形凹槽连通的原水进口及浓水出口,所述定位滑块A和定位滑块B分别对称设置在下模板、上模板的弧形凸台和弧形凹槽两侧,并与下模板、上模板一起构成型腔,型腔内分别设置有浓网和两片位于浓网两侧面的膜片。本发明对浓网受污染程度的观察,可了解到浓网的抗污染性。若下模板和上模板用透明有机玻璃制作,可更清楚、准确地了解浓网抗污染的整个过程。但该技术方案的缺陷在于:1)模拟了真实卷式膜元件的运行过程,但是由于料液要穿透膜层才能产水,因此对装置的耐压等级要求高,微滤级别的膜片操作压力至少3bar以上,如果是反渗透膜,则操作压力至少要15bar以上,上下模板之间的固定和密封的要求都非常高,模板的材料选型如果用透明的有机玻璃,耐压等级不足,容易崩裂,用不锈钢又不能观察其污染过程,实操性差,很难实现;2)污染过程缓慢、试验周期长,由于该装置最大程度的还原了真实膜元件的运行过程,因此模拟料液的浓度配置也要接近膜元件运行条件,不能配置高悬浮颗粒物体系,否则流道都会因为污堵导致实验不能继续,膜污染需要比较长的时间,一个周期至少需要运行1天以上。CN106731864B discloses a device for detecting the anti-pollution property of thick nets, comprising a lower template, a positioning slider A, a positioning slider B and an upper template. The upper end face of the lower template is provided with an arc-shaped boss, and the The lower end face is provided with a water production outlet A that penetrates the arc-shaped boss, the lower end face of the upper template is provided with an arc-shaped groove, the upper end face is provided with a water-produced outlet B that communicates with the arc-shaped groove, and the two ends of the upper template are respectively There are raw water inlets and concentrated water outlets that communicate with the arc-shaped grooves. The positioning slider A and the positioning slider B are symmetrically arranged on both sides of the arc-shaped bosses and arc-shaped grooves of the lower template and the upper template, and are connected with the arc groove. The lower template and the upper template together form a cavity, and the cavity is respectively provided with a thick screen and two diaphragms located on both sides of the thick screen. By observing the pollution degree of the thick net in the present invention, the anti-pollution property of the thick net can be known. If the lower template and the upper template are made of transparent plexiglass, the whole process of anti-pollution of the thick net can be understood more clearly and accurately. However, the defects of this technical solution are: 1) It simulates the operation process of the real rolled membrane element, but since the feed liquid must penetrate the membrane layer to produce water, the pressure resistance level of the device is required to be high, and the microfiltration level membrane The operating pressure should be at least 3 bar or more, and if it is a reverse osmosis membrane, the operating pressure should be at least 15 bar or more, and the requirements for fixing and sealing between the upper and lower formwork are very high. , easy to crack, and the pollution process cannot be observed with stainless steel, which is difficult to achieve due to poor practicality; 2) The pollution process is slow and the test period is long. Because the device restores the operation process of the real membrane element to the greatest extent, it simulates the liquid The concentration configuration of the membrane element should also be close to the operating conditions of the membrane element, and a system with high suspended particulate matter cannot be configured, otherwise the flow channel will be blocked due to fouling and the experiment will not be able to continue.

发明内容SUMMARY OF THE INVENTION

本发明的目的在于克服现有技术缺陷,提供一种膜元件流道隔网检测装置。The purpose of the present invention is to overcome the defects of the prior art, and to provide a membrane element flow channel separator net detection device.

本发明的另一目的在于提供一种膜元件流道隔网检测方法。Another object of the present invention is to provide a method for detecting a membrane element flow channel separator.

本发明的技术方案如下:The technical scheme of the present invention is as follows:

一种膜元件流道隔网检测装置,包括一架台、一料桶、一进料泵和若干隔网池组件;A membrane element flow channel separation net detection device, comprising a stand, a material bucket, a feed pump and several separation net pool components;

每一隔网池组件包括一本体、一密封圈、一上盖和若干夹持机构,上盖通过密封圈盖设于本体上,且若干夹持机构夹紧本体和上盖,本体和上盖均为透明,其中Each net-separating pool assembly includes a main body, a sealing ring, an upper cover and several clamping mechanisms. The upper cover is covered on the main body through the sealing ring, and several clamping mechanisms clamp the main body and the upper cover, the main body and the upper cover. are transparent, with

本体上凹设一槽体,该槽体沿其长度方向从一端到另一端依次分为一进料区、一隔网放置区和一出料区,进料区的形状为半圆形,出料区的形状为等腰三角形,进料区的深度大于隔网放置区的深度,出料区的深度与隔网放置区的深度一致,该槽体的一端的底壁设有一进料口,进料口的下游的进料区的底壁凸设一导流挡板,该槽体的另一端的底壁设有一出料口;A groove body is recessed on the main body, and the groove body is divided into a feeding area, a mesh placing area and a discharging area in turn from one end to the other along its length direction. The shape of the feeding area is an isosceles triangle, the depth of the feeding area is greater than the depth of the screen placing area, the depth of the discharging area is consistent with the depth of the dividing screen placing area, the bottom wall of one end of the tank body is provided with a feeding port, A guide baffle is protruded from the bottom wall of the feed zone downstream of the feed port, and a discharge port is provided on the bottom wall of the other end of the tank body;

上盖具有一示踪剂入口,该示踪剂入口对应本体的进料区并插设一硅胶毛细管,该硅胶毛细管的一端连通注射示踪剂的注射装置,另一端插入上盖之下并正对本体的隔网放置区的与进料区相接的边缘;The upper cover has a tracer inlet, the tracer inlet corresponds to the feeding area of the body and a silica gel capillary is inserted, one end of the silica gel capillary is connected to the injection device for injecting the tracer, and the other end is inserted under the upper cover and is To the edge of the screen placement area of the body that is connected to the feeding area;

若干隔网池组件设于架台上且并联设置,料桶通过进料泵连通若干隔网池组件的进料口,若干隔网池组件的出料口连通料桶,料桶内装有检测料液。A plurality of net-separation pool components are arranged on the stand and are arranged in parallel, the material barrel is connected to the feed ports of the plurality of net-separation pool components through the feeding pump, and the discharge ports of the plurality of net-separation pool components are connected to the material barrel, and the material barrel is equipped with a detection material liquid. .

在本发明的一个优选实施方案中,所述本体设有至少二定位凹槽,所述上盖设有于该二定位凹槽适配的至少二定位凸起。In a preferred embodiment of the present invention, the body is provided with at least two positioning grooves, and the upper cover is provided with at least two positioning protrusions that fit in the two positioning grooves.

在本发明的一个优选实施方案中,所述若干夹持机构为G型夹。In a preferred embodiment of the present invention, the plurality of clamping mechanisms are G-clamps.

在本发明的一个优选实施方案中,所述进料区与所述隔网放置区的交界处设有过渡斜坡。In a preferred embodiment of the present invention, a transition slope is provided at the junction of the feeding zone and the separating net placement zone.

在本发明的一个优选实施方案中,所述进料区的深度为5-15mm,所述隔网放置区的深度为2-5mm。In a preferred embodiment of the present invention, the depth of the feeding zone is 5-15mm, and the depth of the screen placement zone is 2-5mm.

进一步优选的,所述进料区的深度为10mm,所述隔网放置区的深度为6.5mm。Further preferably, the depth of the feeding zone is 10 mm, and the depth of the screen placement zone is 6.5 mm.

在本发明的一个优选实施方案中,所述隔网放置区内还设有至少一垫片,以适应不同厚度的隔网。In a preferred embodiment of the present invention, at least one spacer is further provided in the spacer net placement area to adapt to different thicknesses of the spacer nets.

进一步优选的,所述至少一垫片的厚度为0.2-3mm。Further preferably, the thickness of the at least one gasket is 0.2-3 mm.

本发明的另一技术方案如下:Another technical scheme of the present invention is as follows:

一种膜元件流道隔网检测方法,使用权利要求1至8中任一权利要求所述的膜元件流道隔网检测装置以检测待测膜元件流道隔网的纳污性能、扩散性能和节能性能。A membrane element flow channel partition detection method, using the membrane element flow channel partition detection device according to any one of claims 1 to 8 to detect the dirt holding performance and diffusion performance of the membrane element flow channel partition to be tested. and energy saving performance.

在本发明的一个优选实施方案中,当检测膜元件流道隔网的纳污性能时,通过测试检测料液的前后浊度差异来表征;当检测膜元件流道隔网的扩散性能时,通过测试经示踪剂染色的检测料液的扩散程度来表征;当检测膜元件流道隔网的节能性能时,通过测试隔网对检测料液的过流量差异来表征。In a preferred embodiment of the present invention, when testing the dirt-holding performance of the membrane element flow channel separator, it is characterized by the difference in turbidity before and after testing the material liquid; when testing the diffusion performance of the membrane element flow channel separator, It is characterized by testing the diffusion degree of the test material dyed with the tracer; when testing the energy-saving performance of the membrane element flow channel separator, it is characterized by testing the difference in the flow rate of the test material liquid by the separator.

本发明的有益效果是:The beneficial effects of the present invention are:

1、本发明可以直接、快速检测膜元件流道隔网的扩散性、纳污性和节能性等多个维度的指标。1. The present invention can directly and quickly detect indicators of multiple dimensions such as the diffusivity, dirt-holding capacity, and energy-saving performance of the membrane element flow channel separator.

2、本发明的结构简单,制作成本低,无需各种仪表,只需要进料桶、进料泵、隔网池和配套管路、阀门即可。2. The structure of the present invention is simple, the production cost is low, and all kinds of instruments are not needed, only the feeding barrel, the feeding pump, the separation net pool, the supporting pipeline and the valve are required.

3、本发明的操作压力低,对材料的耐压等级要求低,可以用亚格力板、玻璃等透明有机材料,不需要用高耐压等级的不锈钢。3. The operating pressure of the present invention is low, and the pressure resistance level of the material is low, and transparent organic materials such as sub-grid and glass can be used, and stainless steel with a high pressure resistance level is not required.

4、本发明对密封固定的要求也低,只需要采用简单的夹持固定机构就可达到密封效果,操作十分简便。4. The present invention also has low requirements for sealing and fixing, and only needs to adopt a simple clamping and fixing mechanism to achieve the sealing effect, and the operation is very simple.

附图说明Description of drawings

图1为本发明实施例1的膜元件流道隔网检测装置的结构示意图。FIG. 1 is a schematic structural diagram of a membrane element flow channel separator detection device according to Embodiment 1 of the present invention.

图2为本发明实施例1的膜元件流道隔网检测装置的立体结构示意图。FIG. 2 is a schematic three-dimensional structural diagram of the membrane element flow channel separator screen detection device according to Embodiment 1 of the present invention.

图3为本发明实施例1中的隔网池组件的立体结构示意图。FIG. 3 is a schematic three-dimensional structure diagram of a net-separating pool assembly in Example 1 of the present invention.

图4为本发明实施例1中的隔网池组件的本体的结构示意图。FIG. 4 is a schematic structural diagram of the body of the net-separating pool assembly in Embodiment 1 of the present invention.

图5为本发明实施例1中的上盖的结构示意图。FIG. 5 is a schematic structural diagram of the upper cover in Embodiment 1 of the present invention.

图6为本发明实施例2的实验结果图之一。FIG. 6 is one of the experimental result diagrams of Example 2 of the present invention.

图7为本发明实施例2的实验结果图之二。FIG. 7 is the second diagram of the experimental results of Example 2 of the present invention.

图8为本发明实施例2的实验结果图之三。FIG. 8 is the third diagram of the experimental results of Example 2 of the present invention.

图9为本发明实施例2的实验结果图之四。FIG. 9 is the fourth diagram of the experimental results of Example 2 of the present invention.

图10为本发明实施例3的实验结果图之一。FIG. 10 is one of the experimental result diagrams of Example 3 of the present invention.

图11为本发明实施例3的实验结果图之二。FIG. 11 is the second diagram of the experimental results of Example 3 of the present invention.

图12为本发明实施例4中的隔网样品的照片。Figure 12 is a photograph of a sample of the separator in Example 4 of the present invention.

图13为本发明实施例4的实验结果图。FIG. 13 is an experimental result diagram of Example 4 of the present invention.

具体实施方式Detailed ways

以下通过具体实施方式结合附图对本发明的技术方案进行进一步的说明和描述。The technical solutions of the present invention will be further illustrated and described below through specific embodiments in conjunction with the accompanying drawings.

实施例1Example 1

如图1和2所示,一种膜元件流道隔网检测装置,包括一架台2、一料桶3、一进料泵4和二隔网池组件1。As shown in Figures 1 and 2, a membrane element flow channel separation net detection device includes a stand 2, a material barrel 3, a feed pump 4 and two separation net pool assemblies 1.

如图3和4所示,每一隔网池组件1包括一本体10、一密封圈11、一上盖13和四G型夹14,上盖13通过密封圈11盖设于本体10上,且四G型夹14夹紧本体10和上盖13,本体10和上盖13均为透明。As shown in FIGS. 3 and 4 , each net-separating pool assembly 1 includes a main body 10 , a sealing ring 11 , an upper cover 13 and four G-type clips 14 , and the upper cover 13 is covered on the main body 10 through the sealing ring 11 , In addition, the four G-type clips 14 clamp the main body 10 and the upper cover 13, and both the main body 10 and the upper cover 13 are transparent.

如图4所示,所述本体10上凹设一槽体101,该槽体101沿其长度方向从一端到另一端依次分为一进料区1011、一隔网放置区1012和一出料区1013,进料区1011的形状为半圆形,出料区1013的形状为等腰三角形(其顶角为90°-150°)。隔网放置区1012的形状为矩形,进料区1011的深度为10mm,隔网放置区1012的深度为3.5mm(最高可以测试厚度120mil厚度的膜元件流道隔网,如有更大厚度的膜元件流道隔网可根据需要加大槽体101的深度,当测不同厚度的膜元件流道隔网时,可通过在隔网放置区1012增加或减少垫片数量(厚垫片2-3mm厚度,薄垫片0.2-1mm厚度)并根据需要选择合对应种类来调整合适的高度),进料区1011和隔网放置区1012的落差为6.5mm,出料区1013的深度与隔网放置区1012的深度一致,该槽体101的一端的底壁设有一进料口102,进料口102的下游的进料区1011的底壁凸设一导流挡板1014,该槽体101的另一端的底壁设有一出料口103,进料区1011与隔网放置区1012的交界处设有过渡斜坡1015。检测料液中若有悬浮颗粒物,则该悬浮颗粒在进入隔网放置区1012的时候会碰壁掉落来,造成悬浮颗粒物在进料区1011富集的现象,设置该过渡斜坡1015后可以消除这种影响。As shown in FIG. 4 , a groove body 101 is recessed on the main body 10 , and the groove body 101 is divided into a feeding area 1011 , a mesh placing area 1012 and a discharging area in turn from one end to the other end along the length direction of the groove body 101 . The shape of the zone 1013, the feed zone 1011 is a semicircle, and the shape of the discharge zone 1013 is an isosceles triangle (its apex angle is 90°-150°). The shape of the spacer placement area 1012 is a rectangle, the depth of the feeding area 1011 is 10mm, and the depth of the spacer placement area 1012 is 3.5mm (the membrane element flow channel spacer with a thickness of up to 120mil can be tested, if there is a larger thickness The membrane element flow channel separator can increase the depth of the tank body 101 as required. When measuring membrane element flow channel separators with different thicknesses, the number of gaskets can be increased or decreased in the separator placement area 1012 (thick gaskets 2- 3mm thickness, thin gasket 0.2-1mm thickness) and adjust the appropriate height according to the corresponding type), the drop between the feeding area 1011 and the screen placement area 1012 is 6.5mm, the depth of the discharge area 1013 and the screen The depth of the placement area 1012 is the same. The bottom wall of one end of the tank body 101 is provided with a feeding port 102, and the bottom wall of the feeding area 1011 downstream of the feeding port 102 is protruded with a guide baffle 1014. The tank body 101 The bottom wall of the other end is provided with a discharge port 103, and a transition slope 1015 is provided at the junction of the feeding area 1011 and the screen placing area 1012. If there are suspended particles in the detected feed liquid, the suspended particles will fall off the wall when entering the screen placement area 1012, resulting in the phenomenon that suspended particles are enriched in the feeding area 1011. After setting the transition slope 1015, this can be eliminated. an impact.

上述进料区1011的功能在于调节检测料液的浓度和流速的均匀性,因此进水区1011越大越有利于调匀浓度和流速,但是又要避免做成多边形的形状会有流动死区,因此将其形状设置成为半圆形。上述导流挡板1014的功能在于避免检测料液在进料口102和出料口103的连线形成短流,而使待测隔网的中间区域走料,两侧不走料的现象。The function of the above-mentioned feeding area 1011 is to adjust the uniformity of the concentration and flow rate of the detected feed liquid. Therefore, the larger the water inlet area 1011, the more favorable it is to mix the concentration and flow rate. Set its shape to a semicircle. The function of the above-mentioned deflector baffle 1014 is to avoid the phenomenon that the detection material liquid forms a short flow in the connection line between the feed port 102 and the discharge port 103, so that the material is fed in the middle area of the separator to be tested, and the material is not fed on both sides.

如图5所示,上盖13具有一示踪剂入口130,该示踪剂入口130对应本体10的进料区1011并插设一硅胶毛细管132,该硅胶毛细管132的一端连通注射示踪剂的注射装置5,另一端插入上盖13之下并正对本体10的隔网放置区1012的与进料区1011相接的边缘;As shown in FIG. 5 , the upper cover 13 has a tracer inlet 130 , the tracer inlet 130 corresponds to the feeding area 1011 of the main body 10 and a silica gel capillary 132 is inserted, and one end of the silica gel capillary 132 is connected to inject the tracer The other end of the injection device 5 is inserted under the upper cover 13 and faces the edge of the screen placement area 1012 of the main body 10 that is connected to the feeding area 1011;

所述本体10的对角线两端设有二定位凹槽104,所述上盖13设有于该二定位凹槽104适配的二定位凸起131。Two locating grooves 104 are provided at two diagonal ends of the main body 10 , and two locating protrusions 131 are provided on the upper cover 13 that fit into the two locating grooves 104 .

如图1和2所示,二隔网池组件1设于架台2上且并联设置,料桶3通过进料泵4连通二隔网池组件1的进料口102,二隔网池组件1的出料口103连通料桶3,料桶3内装有检测料液。As shown in FIGS. 1 and 2 , the two-separation net pool assembly 1 is arranged on the stand 2 and is arranged in parallel, the material barrel 3 is connected to the feed port 102 of the second-separation net pool assembly 1 through the feed pump 4 , and the second net-separation pool assembly 1 The discharge port 103 is connected to the material barrel 3, and the material barrel 3 is equipped with a detection material liquid.

实施例2Example 2

本实施例用实施例1的膜元件流道隔网检测装置检测隔网的纳污性能,具体如下:This embodiment uses the membrane element flow channel separator screen detection device of Example 1 to detect the dirt-holding performance of the separator screen, which is as follows:

(1)裁切隔网样品,大小与所述隔网放置区1012尺寸适配,放在隔网放置区1012内,放好密封圈11,盖上上盖13,用G型夹14密封固定,连接好进料桶3、进料泵4、二隔网池组件1之间的管路,形成闭合的循环系统;(1) Cut the sample of the partition mesh, the size is suitable for the size of the partition mesh placement area 1012, put it in the partition mesh placement area 1012, place the sealing ring 11, cover the upper cover 13, and seal and fix it with the G-clamp 14 , connect the pipelines between the feeding barrel 3, the feeding pump 4, and the two-separation net pool assembly 1 to form a closed circulation system;

(2)配制检测料液:以25nm的TiO2配制成检测料液,检测料液体积1L,测浊度T0(2) Preparation of detection feed liquid: the detection feed liquid is prepared with 25nm TiO 2 , the volume of the detection feed liquid is 1L, and the turbidity T 0 is measured;

(3)开启进料泵4,调整流速,记录运行时间,关闭进料泵4,测进料桶3内悬浮液的浊度Ti(3) open feed pump 4, adjust flow rate, record running time, close feed pump 4, measure the turbidity T i of the suspension in feed barrel 3;

(4)计算截留率R=(T0-Ti)/T0(4) Calculate the retention rate R=(T 0 -T i )/T 0 .

最佳操作条件筛选:Best Operating Conditions Screening:

A、检测料液浓度筛选A. Screening of liquid concentration detection

对比两款相同厚度不同形状的隔网的截留率,当其他条件相同,而检测料液的浓度不同的情况下,截留率的差异性最大,则该浓度的检测料液最有利于评价隔网的纳污性能。Comparing the retention rates of the two types of separators with the same thickness and different shapes, when other conditions are the same and the concentrations of the detected feed liquid are different, the difference in the retention rates is the largest, and the detection feed liquid of this concentration is most conducive to evaluating the separators. dirt holding performance.

表1Table 1

项目project 100ppm100ppm 50ppm50ppm 20ppm20ppm 46mil-方形截留率46mil-square rejection rate 60.26%60.26% 56.47%56.47% 66.25%66.25% 46mil-菱形截留率46mil-diamond rejection 67.16%67.16% 77.07%77.07% 73.40%73.40% 46mil-方形节流浊度46mil-square throttling turbidity 323323 131131 6464 46mil-菱形截留浊度46mil-rhombus retention turbidity 360360 178.8178.8 70.970.9 不同隔网的浊度截留差值(NTU)Turbidity retention difference (NTU) of different separators 3737 47.847.8 6.96.9

如下表1和图6所示,当检测料液中的TiO2的浓度为50ppm时,两种隔网对浊度的截留率的差异性最大,浊度截留差值47.8NTU,20ppm时,浊度截留差值才6.9NTU。因此确定最佳的检测料液的浓度为50ppm。As shown in Table 1 and Figure 6 below, when the concentration of TiO 2 in the detected feed liquid is 50ppm, the difference in the turbidity retention rate of the two separators is the largest, and the turbidity retention difference is 47.8NTU. When 20ppm, the turbidity The degree of rejection difference is only 6.9NTU. Therefore, it is determined that the concentration of the best detection feed liquid is 50 ppm.

B、走料流速筛选B. Screening of feeding flow rate

对比两款相同厚度不同形状的隔网的截留率,当其他条件相同,而走料流速不同的情况下,截留率的差异性稳定,且不再有大幅度变化时,则该运行时间最有利于评价隔网的纳污性能。Comparing the retention rates of the two types of separators with the same thickness and different shapes, when other conditions are the same and the feed flow rates are different, the difference in retention rates is stable and there is no significant change, then the operating time is the most efficient. It is helpful to evaluate the dirt holding performance of the separator.

如图7所示,低流速情况下,悬浮颗粒物容易卡在隔网内,不容易被冲出来,因此两款隔网的截留率差异小;高流速情况下水流的湍动性好,悬浮颗粒物不易沉降,部分颗粒物会被带出隔网,两款隔网的截留率差异大,更有利于评价隔网的纳污性能。走料流速可以选择比1.0LPM更大的流速,但是在1.0LPM条件下已经有明显的差异性,而且考虑节能和高流速对装置的要求,因此确定1.0LPM为最佳操作流速。As shown in Figure 7, in the case of low flow rate, suspended particles are easily stuck in the separator and are not easily flushed out, so the difference in retention rate between the two separators is small. It is not easy to settle, and part of the particles will be taken out of the separator. The interception rate of the two separators is very different, which is more conducive to evaluating the dirt-holding performance of the separator. The feed flow rate can be selected to be larger than 1.0LPM, but there are obvious differences under the condition of 1.0LPM, and considering the requirements of energy saving and high flow rate for the device, 1.0LPM is determined as the optimal operating flow rate.

C、走料时间筛选C. Screening of feeding time

对比两款相同厚度不同形状的隔网的截留率,当其他条件相同,而循环运行时间不同的情况下,截留率的差异性稳定,且不再有大幅度变化时,则该运行时间最有利于评价隔网的纳污性能。Comparing the retention rates of the two types of separators with the same thickness and different shapes, when other conditions are the same and the cycle running time is different, the difference in the retention rate is stable and there is no significant change, then the running time is the most efficient. It is helpful to evaluate the dirt holding performance of the separator.

如图8所示,运行10min时截留率差异不大,当运行30min时,截留率的差值相对较大,且随着运行时间的延长,截留率差值没有显著变化,则判定30min为最佳运行时长,更有利于评价隔网的纳污性能。As shown in Figure 8, the difference in retention rate is not significant when running for 10 minutes. When running for 30 minutes, the difference in retention rate is relatively large, and with the extension of running time, the difference in retention rate does not change significantly, so 30 minutes is determined as the most The optimal operating time is more conducive to evaluating the dirt-holding performance of the separator.

几种隔网的纳污性测试:以上述确定的最佳的检测料液的浓度、最佳操作流速和最佳运行时长为确定参数对几种隔网的纳污性进行测试。Contamination-holding test of several kinds of separators: Test the dirt-holding capacity of several separators with the above-determined optimal concentration of the detection material, the best operating flow rate and the best operating time as the parameters.

如图9所示,测试了部分隔网对悬浮颗粒物的截留情况,得出隔网的纳污性评价结果:大波浪板的隔网对污染物的截留最小。同等厚度情况下菱形隔网对悬浮颗粒物的截留率比斜形、方形的隔网截留率大。As shown in Figure 9, the interception of suspended particulates by some of the separators was tested, and the evaluation result of the pollution holding capacity of the separators was obtained: the separators with large wave plates have the least interception of pollutants. Under the condition of the same thickness, the interception rate of the suspended particles by the diamond-shaped screen is larger than that of the oblique and square screen.

实施例3Example 3

本实施例用实施例1的膜元件流道隔网检测装置检测隔网的扩散性能,具体如下:This embodiment uses the membrane element flow channel separator screen detection device of Example 1 to detect the diffusion performance of the separator screen, as follows:

(1)裁切隔网样品和膜片样品,大小与所述隔网放置区1012的尺寸一致,先把膜片放置在隔网放置区1012,膜面朝上,然后将待测的隔网放置在膜片的上方,放好密封圈11,盖上上盖13,用G型夹14密封固定,连接好进料桶3、进料泵4、二隔网池组件1之间的管路,形成闭合的循环系统;(1) Cut the sample of the partition screen and the sample of the film, the size is the same as the size of the spacer screen placement area 1012, first place the film sheet in the spacer screen placement area 1012 with the film surface facing up, and then place the spacer screen to be tested. Put it on the top of the diaphragm, put the sealing ring 11, cover the upper cover 13, seal and fix it with the G-clamp 14, and connect the pipeline between the feeding barrel 3, the feeding pump 4, and the two-separator pool assembly 1. , forming a closed circulatory system;

(2)用纯水作为检测料液,开启进料泵4,调整流速,让系统稳定运行;(2) Use pure water as the detection feed liquid, turn on the feed pump 4, adjust the flow rate, and let the system run stably;

(3)准备好录像相机,调好焦距视角,开启录像;(3) Prepare the video camera, adjust the focal length and angle of view, and start the video recording;

(4)用注射装置将红墨水示踪剂注入硅胶毛细管132,观察扩散情况;(4) inject the red ink tracer into the silica gel capillary 132 with the injection device, and observe the diffusion;

(5)回放录像,截出扩散到最款距离的图片,计算跨越的网格数量N,测量扩散宽度D。(5) Play back the video, cut out the picture that spreads to the maximum distance, calculate the number N of grids spanned, and measure the spread width D.

检测结果如下表2和图10至11所示,方形隔网的扩散性相对较差,相同雷诺数下跨越网格数少,扩散宽度小;菱形隔网扩散性好,无论在高低雷诺数下其扩散的效果都非常好而且相对接近。扩散的特性和隔网的构型相关:方形隔网纵向荆条粗横向细,流体的流向会相对集中横向荆条跨越,较难发生纵向荆条跃迁;菱形隔网横纵荆条同粗细,入水角度90°,且横纵荆条节点粗流道细,水流扩散各方向都相对均匀,但是相对的阻力也会比较大。The test results are shown in Table 2 below and Figures 10 to 11. The diffusivity of the square separator is relatively poor. Under the same Reynolds number, the number of spanning grids is small, and the diffusion width is small; the rhombic separator has good diffusivity, regardless of the high and low Reynolds numbers. The diffusion effects are all very good and relatively close. The characteristics of diffusion are related to the configuration of the separator: the vertical vitex of the square separator is thick and horizontal, and the flow direction of the fluid will be relatively concentrated. , and the horizontal and vertical vitex nodes are thick and thin, and the water flow is relatively uniform in all directions, but the relative resistance will also be relatively large.

表2Table 2

Figure BDA0002839319640000081
Figure BDA0002839319640000081

实施例4Example 4

本实施例用实施例1的膜元件流道隔网检测装置检测隔网的节能性能,具体如下:This embodiment uses the membrane element flow channel separator screen detection device of Example 1 to detect the energy-saving performance of the separator screen, as follows:

(1)裁切不同隔网样品(如图12所示)和膜片样品,大小与所述隔网放置区1012的尺寸一致,先把膜片放置在隔网放置区1012,膜面朝上,然后将待测的隔网放置在膜片的上方,放好密封圈11,盖上上盖13,用G型夹14密封固定,连接好进料桶3、进料泵4、二隔网池组件1之间的管路,形成闭合的循环系统;(1) Cut different separator mesh samples (as shown in Figure 12) and film samples, the size is the same as the size of the separator screen placement area 1012, first place the membrane sheet in the separator screen placement area 1012, with the film side up , and then place the screen to be tested on the top of the diaphragm, put the sealing ring 11, cover the upper cover 13, seal and fix it with the G-clamp 14, and connect the feeding barrel 3, the feeding pump 4, and the second separator. The pipeline between the pool components 1 forms a closed circulation system;

(2)用纯水作为检测料液,开启进料泵4,调整到最大流速,让系统稳定运行;(2) Use pure water as the detection feed liquid, turn on the feed pump 4, adjust to the maximum flow rate, and let the system run stably;

(3)用量筒和秒表测算每组隔网池组件1的1min的产水量Qi;当测试隔网阻力接近时,可适当延长产水时间,差异性更明显。(3) Measure the water production Q i in 1 min of each group of separator pool components 1 with a measuring cylinder and a stopwatch; when the resistance of the test separator is close, the water production time can be appropriately extended, and the difference is more obvious.

(4)对比产水量的大小,确定隔网的阻力大小,最终判定隔网的节能性。(4) Compare the size of water production, determine the resistance of the screen, and finally determine the energy-saving performance of the screen.

检测结果图13所示,相同厚度不同结构的隔网其阻力差异较大,当过流压力相等的条件下,并联的二隔网池组件1,阻力小的一侧过流量大,阻力大的一侧过流量小。通过这种简易的装置和快速的定性测试方法,当一侧隔网的产水量大的情况下,可以定性的判定该侧隔网的阻力小,制备成的组件对流体的阻力小,压降小,因而更加节能。The test results are shown in Figure 13. The resistances of the meshes with the same thickness and different structures are quite different. When the overcurrent pressure is equal, the two meshes in parallel pool 1, the side with the smaller resistance has the larger overflow and the larger resistance. One side overflow is small. Through this simple device and rapid qualitative test method, when the water production of one side screen is large, it can be qualitatively determined that the resistance of the side screen is small, the prepared component has low resistance to fluid, and pressure drop Smaller and therefore more energy efficient.

以上所述,仅为本发明的较佳实施例而已,故不能依此限定本发明实施的范围,即依本发明专利范围及说明书内容所作的等效变化与修饰,皆应仍属本发明涵盖的范围内。The above descriptions are only preferred embodiments of the present invention, so the scope of implementation of the present invention cannot be limited accordingly. That is, equivalent changes and modifications made according to the patent scope of the present invention and the contents of the description should still be covered by the present invention. In the range.

Claims (10)

1. The utility model provides a membrane element runner separates net detection device which characterized in that: comprises a stand, a charging bucket, a feeding pump and a plurality of screen pool components;
each screen cell component comprises a body, a sealing ring, an upper cover and a plurality of clamping mechanisms, the upper cover is arranged on the body through the sealing ring cover, the plurality of clamping mechanisms clamp the body and the upper cover, the body and the upper cover are transparent, wherein,
the groove body is concavely provided with a groove body, the groove body is sequentially divided into a feeding area, a separation net placing area and a discharging area from one end to the other end along the length direction of the groove body, the feeding area is semicircular, the discharging area is isosceles triangle-shaped, the depth of the feeding area is greater than that of the separation net placing area, the depth of the discharging area is consistent with that of the separation net placing area, the bottom wall of one end of the groove body is provided with a feeding hole, the bottom wall of the feeding area at the downstream of the feeding hole is convexly provided with a flow guide baffle, and the bottom wall of the other end of the groove body is provided with a discharging hole;
the upper cover is provided with a tracer inlet, the tracer inlet corresponds to the feeding area of the body, a silica gel capillary is inserted in the feeding area, one end of the silica gel capillary is communicated with an injection device for injecting tracer, and the other end of the silica gel capillary is inserted below the upper cover and is opposite to the edge of the separation net placing area of the body, which is connected with the feeding area;
the plurality of screen pool components are arranged on the stand and are arranged in parallel, the charging bucket is communicated with the feeding holes of the plurality of screen pool components through a feeding pump, the discharging holes of the plurality of screen pool components are communicated with the charging bucket, and the charging bucket is internally provided with a detection feed liquid.
2. The membrane element flow channel spacer mesh detection device of claim 1, wherein: the body is provided with at least two positioning grooves, and the upper cover is provided with at least two positioning bulges matched with the two positioning grooves.
3. The membrane element flow channel spacer mesh detection device of claim 1, wherein: the clamping mechanisms are G-shaped clamps.
4. The membrane element flow channel spacer mesh detection device of claim 1, wherein: and a transition slope is arranged at the junction of the feeding area and the partition net placing area.
5. The membrane element flow channel spacer mesh detection device of claim 1, wherein: the depth of the feeding area is 5-15mm, and the depth of the mesh separation placing area is 2-5 mm.
6. The membrane element flow channel spacer mesh detection device of claim 5, wherein: the depth of the feeding area is 10mm, and the depth of the separation net placing area is 6.5 mm.
7. The membrane element flow channel spacer mesh detection device of claim 1, wherein: at least one gasket is arranged in the separation net placing area to adapt to separation nets with different thicknesses.
8. The membrane element flow channel spacer mesh detection device of claim 7, wherein: the thickness of the at least one gasket is 0.2-3 mm.
9. A membrane element flow passage separation net detection method is characterized in that: the membrane element flow channel barrier detection device as claimed in any one of claims 1 to 8 is used for detecting the dirt receiving performance, the diffusion performance and the energy saving performance of the membrane element flow channel barrier to be detected.
10. The method for detecting a membrane element flow passage screen of claim 9, wherein: when the dirt containing performance of the flow passage separation net of the membrane element is detected, the detection is characterized by testing the front and back turbidity difference of the detection liquid; when the diffusion performance of the membrane element flow passage separation net is detected, the diffusion performance is characterized by testing the diffusion degree of detection feed liquid dyed by a tracer; when the energy-saving performance of the membrane element flow channel separation net is detected, the representation is carried out by testing the over-flow difference of the separation net to the detection feed liquid.
CN202011490380.3A 2020-12-16 2020-12-16 Membrane element flow passage separation net detection device and application thereof Pending CN114632425A (en)

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