CN114624959A - A kind of high-efficiency extreme ultraviolet radiation generation method and system - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及一种极紫外辐射产生方法及系统,尤其涉及一种高效率极紫外辐射产生方法及系统,属于极紫外(EUV)技术领域。The invention relates to a method and system for generating extreme ultraviolet radiation, in particular to a method and system for generating extreme ultraviolet radiation with high efficiency, and belongs to the technical field of extreme ultraviolet (EUV).
背景技术Background technique
极紫外辐射的能量适中,对应的光子能量约几十eV,正好对应于原子外层或中层电子的跃迁能级,因此可以利用极紫外辐射与外层或中层电子的耦合作用探测原子层面的电子能级结构和化学键组成,从而提供一种全新的微观物质研究手段,帮助理解宏观物质性质背后的物理原因。由于极紫外辐射波长较短,相对的衍射极限也较小,若用于显微成像,可以实现几十纳米的分辨率,更好地解析物质结构。基于同样的原因,极紫外辐射适用于纳米加工和高精度光刻。The energy of EUV radiation is moderate, and the corresponding photon energy is about tens of eV, which just corresponds to the transition energy level of the outer or middle electrons of atoms. Therefore, the coupling effect of EUV radiation and outer or middle electrons can be used to detect electrons at the atomic level. Energy level structure and chemical bond composition, thus providing a brand-new research method of microscopic matter and helping to understand the physical reasons behind the properties of macroscopic matter. Due to the short wavelength of extreme ultraviolet radiation and the relatively small diffraction limit, if it is used for microscopic imaging, a resolution of tens of nanometers can be achieved, and the material structure can be better analyzed. For the same reason, EUV radiation is suitable for nanofabrication and high-precision lithography.
现阶段产生极紫外光源的方法有电子同步辐射光源(ECR)、激光等离子光源(LPP)和放电等离子体光源(DPP),其中DPP较早前采用对高温高密度的氙(Xe)气放电的方法,后来研究发现锡(Sn)的EUV转换效率要高于Xe,但是常温状态下锡为固体,所以采用激光轰击固体Sn靶表面产生Sn蒸气后再放电,即激光诱导锡靶放电等离子体(LDP)。At present, there are electron synchrotron radiation sources (ECR), laser plasma sources (LPP) and discharge plasma sources (DPP) for generating EUV light sources. DPP earlier used high-temperature and high-density xenon (Xe) gas discharge. Method, later studies found that the EUV conversion efficiency of tin (Sn) is higher than that of Xe, but tin is solid at room temperature, so the surface of the solid Sn target is bombarded with a laser to generate Sn vapor and then discharged, that is, the laser-induced tin target discharge plasma ( LDP).
电子同步辐射光源(ECR)体积大,成本高,很难适用于制造业。Electron synchrotron radiation sources (ECR) are bulky and expensive, making them difficult to apply in manufacturing.
激光等离子体技术(LPP)是通过喷嘴喷射锡液滴,高能激光聚焦到锡液滴上使其气化、电离产生等离子体,辐射13.5nm极紫外光,由于喷嘴喷射的锡液滴不稳定,存在锡液滴在空中摆动难以定位,激光与锡液滴难以同步,以及电能首先转换为激光然后再转换为极紫外光导致效率低下等缺点。Laser plasma technology (LPP) is to spray tin droplets through a nozzle, focus a high-energy laser on the tin droplets to vaporize and ionize them to generate plasma, and radiate 13.5nm extreme ultraviolet light. Because the tin droplets sprayed by the nozzle are unstable, There are disadvantages such as difficulty in positioning the tin droplet swinging in the air, difficulty in synchronizing the laser and the tin droplet, and inefficiency caused by the conversion of electrical energy into laser light first and then into extreme ultraviolet light.
激光诱导放电等离子体技术(LDP)是采用两个圆盘部分浸在液态锡中,圆盘旋转时利用表面张力和摩擦力在其表面吸附一层锡膜,激光辐射在锡膜上产生预等离子体,两个圆盘之间加有高压,高压击穿预等离子体发电,发电产生的主等离子体辐射13.5nm极紫外光,其虽然能够直接将电能转换为极紫外光,效率更高,但是圆盘高速运转时锡液滴可能脱离其表面造成污染,并且还存在高速旋转产生的离心力导致锡膜的厚度不均、为防止锡膜凝固圆盘需要加热、激光作用在圆盘上造成损坏改变其表面特性、机械结构复杂等等弊端。Laser-induced discharge plasma technology (LDP) uses two discs partially immersed in liquid tin. When the disc rotates, surface tension and friction are used to adsorb a layer of tin film on its surface, and laser radiation generates pre-plasma on the tin film. There is a high voltage between the two discs, and the high voltage breaks down the pre-plasma to generate electricity. The main plasma generated by the power generation radiates 13.5nm extreme ultraviolet light. Although it can directly convert electrical energy into extreme ultraviolet light, the efficiency is higher, but When the disc is running at high speed, the tin droplets may separate from its surface and cause pollution, and there is also centrifugal force generated by high-speed rotation, which leads to uneven thickness of the tin film. To prevent the tin film from solidifying, the disc needs to be heated, and the laser acts on the disc to cause damage and changes. Its surface characteristics, complex mechanical structure and other disadvantages.
因此,有必要研究一种新的极紫外辐射产生方法及系统,以解决上述问题。Therefore, it is necessary to study a new method and system for generating extreme ultraviolet radiation to solve the above problems.
发明内容SUMMARY OF THE INVENTION
为了克服上述问题,本发明人进行了锐意研究,一方面,提供一种高效率极紫外辐射产生方法,通过激光打固体靶产生极紫外辐射。In order to overcome the above-mentioned problems, the inventors of the present invention have carried out keen research, and on the one hand, provide a high-efficiency method for generating extreme ultraviolet radiation, which generates extreme ultraviolet radiation by hitting a solid target with a laser.
所述极紫外辐射为宽谱极紫外辐射,其波长范围为3-50nm,极紫外辐射在波长范围内的光谱峰可调。The extreme ultraviolet radiation is broad-spectrum extreme ultraviolet radiation, the wavelength range of which is 3-50 nm, and the spectral peak of the extreme ultraviolet radiation in the wavelength range is adjustable.
具体地,对激光进行聚焦,聚焦后的激光作用在靶材上,优选地,聚焦后的激光峰值功率不低于1015W/cm2。Specifically, the laser is focused, and the focused laser acts on the target. Preferably, the focused laser peak power is not lower than 10 15 W/cm 2 .
进一步地,聚焦前的激光源为飞秒激光源,优选单发次激光能量为0.001~100焦耳、脉宽为1~100飞秒的激光源;Further, the laser source before focusing is a femtosecond laser source, preferably a laser source with a single-shot laser energy of 0.001-100 joules and a pulse width of 1-100 femtoseconds;
聚焦后的激光焦斑直径不大于10微米,聚焦后10微米内能量集中度不小于50%。The diameter of the laser focal spot after focusing is not more than 10 microns, and the energy concentration within 10 microns after focusing is not less than 50%.
根据本发明,所述靶的靶材为满足平均密度介于常规固体和常规气体之间、微米尺寸下分布均匀、边界陡峭特点的材质,优选地,所述靶材的平均密度为1~100mg/cm3。According to the present invention, the target material of the target is a material that satisfies the characteristics of an average density between conventional solids and conventional gases, uniform distribution under micron size, and steep boundary. Preferably, the average density of the target material is 1-100 mg /cm 3 .
在一个优选的实施方式中,所述靶的靶材为纳米管泡沫材料,所述纳米管泡沫材料,是指原子在空间中无序排布形成纳米级框架结构的材料,其具有大量的纳米级孔隙结构。In a preferred embodiment, the target material of the target is a nanotube foam material, and the nanotube foam material refers to a material in which atoms are randomly arranged in space to form a nanoscale framework structure, which has a large number of nanometers. grade pore structure.
更优选地,所述靶的靶材为碳纳米管泡沫材料。More preferably, the target material of the target is carbon nanotube foam material.
根据本发明,所述纳米管形成的框架结构上负载有金属原子。According to the present invention, metal atoms are loaded on the frame structure formed by the nanotubes.
在一个优选的实施方式中,在激光聚焦前,主脉冲30皮秒前激光对比度不小于1010。In a preferred embodiment, before the laser is focused, the laser contrast is not less than 10 10 before the
另一方面,本发明还提供了一种高效率极紫外辐射产生系统,包括激光源1和固体靶2,On the other hand, the present invention also provides a high-efficiency extreme ultraviolet radiation generating system, comprising a
所述激光源1为飞秒激光源;The
所述靶材为满足平均密度介于固体和气体之间、微米尺寸下分布均匀、边界陡峭的材料。The target material is a material whose average density is between solid and gas, uniform distribution in micron size, and steep boundary.
进一步地,在激光源1与固体靶2之间还设置有离轴抛物面镜聚焦装置4,Further, an off-axis parabolic mirror focusing device 4 is also arranged between the
优选地,在激光源1与离轴抛物面镜聚焦装置4之间设置有等离子体镜装置5;Preferably, a
优选地,所述系统还包括束靶耦合装置6和极紫外辐射监测装置7。Preferably, the system further comprises a beam
本发明所具有的有益效果包括:The beneficial effects of the present invention include:
(1)根据本发明所述的高效率极紫外辐射产生方法及装置,能够通过激光打靶的方式产生极紫外辐射;(1) According to the high-efficiency extreme ultraviolet radiation generating method and device of the present invention, extreme ultraviolet radiation can be generated by means of laser targeting;
(2)根据本发明所述的高效率极紫外辐射产生方法及装置,相较于激光等离子光源(LPP)和放电等离子体光源(DPP),获得的极紫外谱带更宽;(2) According to the high-efficiency EUV radiation generating method and device according to the present invention, compared with the laser plasma light source (LPP) and the discharge plasma light source (DPP), the obtained EUV spectral band is wider;
(3)根据本发明所述的高效率极紫外辐射产生方法及装置,获得的极紫外辐射效率更高;(3) According to the high-efficiency EUV radiation generating method and device of the present invention, the obtained EUV radiation efficiency is higher;
(4)根据本发明所述的高效率极紫外辐射产生方法及装置,产生的极紫外辐射的光谱可调。(4) According to the high-efficiency extreme ultraviolet radiation generating method and device of the present invention, the spectrum of the generated extreme ultraviolet radiation can be adjusted.
附图说明Description of drawings
图1示出根据本发明一种优选实施方式的碳纳米管泡沫靶材的电镜照片;Fig. 1 shows the electron microscope photograph of the carbon nanotube foam target material according to a preferred embodiment of the present invention;
图2示出根据本发明一种优选实施方式的高效率极紫外辐射产生系统结构示意图;2 shows a schematic structural diagram of a high-efficiency EUV radiation generation system according to a preferred embodiment of the present invention;
图3示出根据本发明一种优选实施方式的高效率极紫外辐射产生系统束靶耦合装置结构示意图;3 shows a schematic structural diagram of a beam-target coupling device of a high-efficiency EUV radiation generation system according to a preferred embodiment of the present invention;
图4示出实验例1中不同靶材产生的极紫外辐射光谱;Fig. 4 shows the extreme ultraviolet radiation spectrum produced by different targets in Experimental Example 1;
图5示出实验例2中检测到的极紫外辐射光谱图;Fig. 5 shows the extreme ultraviolet radiation spectrogram detected in Experimental Example 2;
图6示出实验例3中不同靶材产生的极紫外辐射的能量角分布。FIG. 6 shows the energy angular distribution of EUV radiation generated by different targets in Experimental Example 3. FIG.
附图标号说明:Description of reference numbers:
1-激光源;1- laser source;
2-靶;2-target;
3-真空腔;3-vacuum chamber;
31-真空泵;31 - vacuum pump;
4-离轴抛物面镜聚焦装置;4- off-axis parabolic mirror focusing device;
5-离子体镜装置;5- plasma mirror device;
6-束靶耦合装置;6-beam target coupling device;
61-长工作距离显微物镜头;61-long working distance microscope objective lens;
62-分束片;62-beam splitter;
63-成像透镜;63-imaging lens;
64-CCD;64-CCD;
65-LED光源;65-LED light source;
7-极紫外辐射监测装置。7- Extreme ultraviolet radiation monitoring device.
具体实施方式Detailed ways
下面通过附图和实施例对本发明进一步详细说明。通过这些说明,本发明的特点和优点将变得更为清楚明确。The present invention will be further described in detail below through the accompanying drawings and embodiments. The features and advantages of the present invention will become more apparent from these descriptions.
在这里专用的词“示例性”意为“用作例子、实施例或说明性”。这里作为“示例性”所说明的任何实施例不必解释为优于或好于其它实施例。尽管在附图中示出了实施例的各种方面,但是除非特别指出,不必按比例绘制附图。The word "exemplary" is used exclusively herein to mean "serving as an example, embodiment, or illustration." Any embodiment described herein as "exemplary" is not necessarily to be construed as preferred or advantageous over other embodiments. While various aspects of the embodiments are shown in the drawings, the drawings are not necessarily drawn to scale unless otherwise indicated.
一方面,本发明提供了一种高效率极紫外辐射产生方法,通过激光固体靶产生极紫外辐射,在本发明中,所述激光打靶是指利用激光对靶进行轰击,所述产生极紫外辐射是指产生介于软X射线和深紫外辐射之间的辐射,辐射波长范围为3-50nm。On the one hand, the present invention provides a high-efficiency method for generating extreme ultraviolet radiation, which generates extreme ultraviolet radiation through a solid laser target. In the present invention, the laser targeting refers to bombarding the target with a laser, and generating extreme ultraviolet radiation Refers to the generation of radiation between soft X-rays and deep ultraviolet radiation, and the radiation wavelength range is 3-50nm.
优选地,在激光打固体靶的过程中,激光先经过聚焦,聚焦后的激光作用在靶材上。Preferably, in the process of laser hitting a solid target, the laser is first focused, and the focused laser acts on the target.
更优选地,通过移动靶或激光,使得激光的焦点作用在靶材的不同位置或不同的靶材上,实现连续的打靶。More preferably, by moving the target or the laser so that the focal point of the laser acts on different positions of the target or different targets, continuous target shooting is achieved.
进一步地,由于空气会影响激光的聚焦和打靶效果,且极紫外辐射(EUV)在空气中极易吸收,故光源打靶在真空中进行。在本发明中,所述激光打靶在真空环境中进行,优选地,真空度小于10-3Pa。Further, since the air will affect the focusing and targeting effects of the laser, and extreme ultraviolet radiation (EUV) is easily absorbed in the air, the light source targeting is performed in a vacuum. In the present invention, the laser targeting is performed in a vacuum environment, preferably, the degree of vacuum is less than 10 -3 Pa.
飞秒级别激光与靶材相互作用在极紫外光产生上有很大的优势。在该情况下,光电离作用占主导,可将靶材中的原子直接电离,有效提高了极紫外辐射的功率。The interaction between the femtosecond laser and the target has great advantages in the generation of extreme ultraviolet light. In this case, photoionization dominates, which can directly ionize atoms in the target, effectively increasing the power of EUV radiation.
在本发明中,聚焦后的激光峰值功率不低于1015W/cm2,更优选地,聚焦后的激光峰值功率不低于1018W/cm2,其满足碳纳米管中碳的场电离阈值,可以提高转换效率。In the present invention, the laser peak power after focusing is not lower than 10 15 W/cm 2 , more preferably, the laser peak power after focusing is not lower than 10 18 W/cm 2 , which satisfies the field of carbon in carbon nanotubes The ionization threshold can improve the conversion efficiency.
优选地,聚焦后的焦斑直径不大于10微米,聚焦后10微米内能量集中度不小于50%。Preferably, the diameter of the focal spot after focusing is not greater than 10 microns, and the energy concentration within 10 microns after focusing is not less than 50%.
优选地,聚焦前的激光源为飞秒激光源,优选单发次激光能量为0.001~100焦耳、脉宽为1~100飞秒的激光源进行聚焦后轰击靶材。Preferably, the laser source before focusing is a femtosecond laser source, preferably a laser source with a single-shot laser energy of 0.001-100 joules and a pulse width of 1-100 femtoseconds is focused and then bombards the target.
激光源参数和聚焦后焦斑的参数保证了聚焦之后的光强大于1018W/cm2,使得碳原子能被光场直接快速电离到五价和六价,场电离机制占主导地位,可以迅速电离靶材,产生高强度短脉宽的极紫外辐射;若焦斑的参数和光强参数较低,则碰撞电离机制占主导,产生的极紫外辐射强度会较弱。The parameters of the laser source and the focal spot after focusing ensure that the light intensity after focusing is greater than 10 18 W/cm 2 , so that carbon atoms can be directly and rapidly ionized to pentavalent and hexavalent by the optical field, and the field ionization mechanism is dominant, which can quickly The target is ionized to produce EUV radiation with high intensity and short pulse width; if the parameters of the focal spot and light intensity are low, the collision ionization mechanism is dominant, and the resulting EUV radiation intensity will be weak.
由于飞秒激光具有预脉冲,预脉冲会对靶材产生破坏,在一个优选的实施方式中,在激光聚焦之前,提高激光的对比度,起到保护靶材的效果。Since the femtosecond laser has a pre-pulse, the pre-pulse will damage the target. In a preferred embodiment, before the laser is focused, the contrast of the laser is improved to protect the target.
所述对比度是指激光主脉冲与激光预脉冲光强的比值,进一步地,激光聚焦前,主脉冲30皮秒前激光对比度不小于1010,在本发明中,可以通过等离子体镜系统实现激光对比度的提高。The contrast refers to the ratio of the light intensity of the main laser pulse and the laser pre-pulse. Further, before the laser is focused, the laser contrast is not less than 10 10 30 picoseconds before the main pulse. In the present invention, the laser can be realized by a plasma mirror system. Contrast improvement.
常规靶的靶材在激光条件下将主要实现粒子加速和产生X射线辐射,何种靶材能够实现极紫外辐射的激发是本发明的关键所在。The target material of the conventional target will mainly achieve particle acceleration and generate X-ray radiation under laser conditions, and what kind of target material can realize the excitation of extreme ultraviolet radiation is the key of the present invention.
根据本发明,所述固体靶材为满足平均密度低、微米尺寸下分布均匀且边界陡峭特点的材料。According to the present invention, the solid target material is a material that satisfies the characteristics of low average density, uniform distribution in micron size, and steep boundary.
进一步地,所述平均密度低是指固体靶材的平均密度介于常规固体和常规气体之间,优选为1~100mg/cm3;Further, the low average density means that the average density of the solid target material is between conventional solids and conventional gases, preferably 1-100 mg/cm 3 ;
飞秒激光与这种低密度的靶材相互作用可以得到临界密度等离子体,而在临界密度等离子体中激光与等离子体的强耦合可以显著提高激光吸收率,从而提高最后极紫外辐射的产生效率。The interaction of the femtosecond laser with this low-density target can obtain a critical density plasma, and the strong coupling of the laser to the plasma in the critical density plasma can significantly increase the laser absorption rate, thereby improving the generation efficiency of the final EUV radiation .
所述边界陡峭性高是指材料在形成等离子体状态与激光相互作用时,这个等离子体的密度梯度非常大,存在锐利的边界,从而抑制激光在密度缓慢变化的等离子体中传播所带来的成丝等不稳定性。The high steepness of the boundary means that when the material forms a plasma state and interacts with the laser, the density gradient of the plasma is very large, and there is a sharp boundary, thereby inhibiting the propagation of the laser in the plasma whose density changes slowly. Instability such as filament formation.
在一个优选的实施方式中,所述靶材为纳米管泡沫材料,其是通过原子在空间中无序排布形成纳米级框架结构形成,具有大量的纳米级孔隙结构,故称之为泡沫材料。In a preferred embodiment, the target material is a nanotube foam material, which is formed by the disordered arrangement of atoms in space to form a nanoscale frame structure, and has a large number of nanoscale pore structures, so it is called a foam material .
泡沫形状的材料,极大提高了靶材对激光的吸收效率,其对激光的吸收效率远大于普通的结构的靶材。The foam-shaped material greatly improves the laser absorption efficiency of the target material, and its absorption efficiency to the laser light is much higher than that of the target material of ordinary structure.
更优选地,所述靶材为碳纳米管泡沫材料,如图1所示,相比于其他临界密度靶体,碳纳米管泡沫具有比较陡峭的边界,并且碳纳米管丝的直径在几十纳米,因此在焦斑对应的微米尺度上看是比较均匀的,并且容易形成管状结构、制造难度低、成本低等诸多优点,尤其适合作为产生极紫外辐射的靶材。More preferably, the target material is a carbon nanotube foam material. As shown in FIG. 1 , compared with other critical density targets, the carbon nanotube foam has a relatively steep boundary, and the diameter of the carbon nanotube filaments is in the tens of tens. Therefore, it is relatively uniform on the micrometer scale corresponding to the focal spot, and has many advantages such as easy formation of a tubular structure, low manufacturing difficulty, and low cost, and is especially suitable as a target for generating extreme ultraviolet radiation.
所述碳纳米管泡沫材料可以是单壁或多壁碳纳米管,优选为单壁碳纳米管材料。The carbon nanotube foam material can be single-walled or multi-walled carbon nanotubes, preferably a single-walled carbon nanotube material.
作为碳纳米管泡沫材料靶的典型示例为通过中国专利申请2020107630093获得的自支撑碳纳米管薄膜靶。A typical example of a carbon nanotube foam target is a self-supporting carbon nanotube thin film target obtained through Chinese Patent Application No. 2020107630093.
在一个优选的实施方式中,所述靶材的厚度在5~200微米,更优选为10~100微米,发明人发现,此厚度的靶材,其机械强度即可支持在毫米直径的孔洞上形成自支撑,经过激光离化后形成等离子体,电子密度在1021/cm3量级。In a preferred embodiment, the thickness of the target material is 5-200 microns, more preferably 10-100 microns. The inventor found that the target material with this thickness can support the mechanical strength of the millimeter-diameter hole. It is self-supporting, and after laser ionization, a plasma is formed, and the electron density is in the order of 10 21 /cm 3 .
在一个更优选的实施方式中,所述纳米管形成的框架结构上可以负载不同的金属原子,使得激光打靶后形成的极紫外辐射在波长范围内的光谱峰可调,例如,光刻时需要产生能量峰值在13.5nm的极紫外辐射,可以采用金属锡修饰碳纳米管,形成负载有锡的碳纳米管泡沫材料;又例如,可以采用金(Au)修饰碳纳米管,获得的极紫外辐射的峰值在4~5nm。In a more preferred embodiment, the frame structure formed by the nanotubes can be loaded with different metal atoms, so that the extreme ultraviolet radiation formed after laser targeting has an adjustable spectral peak in the wavelength range. For example, when photolithography requires To generate extreme ultraviolet radiation with an energy peak of 13.5nm, metal tin can be used to modify carbon nanotubes to form tin-loaded carbon nanotube foam materials; for example, gold (Au) can be used to modify carbon nanotubes, and the obtained extreme ultraviolet radiation The peak is at 4-5 nm.
优选地,所述金属原子为通过气相沉积法负载在碳纳米管形成的框架上的,可以采用浮动催化法或对碳纳米管进行改性实现,在本发明中不再赘述。Preferably, the metal atoms are supported on the frame formed by carbon nanotubes by vapor deposition method, which can be realized by floating catalysis method or modification of carbon nanotubes, which will not be repeated in the present invention.
在一个优选的实施方式中,在激光打靶前,对激光的焦点和靶材的位置进行监控,确保激光焦点位于靶材上。In a preferred embodiment, before the laser hits the target, the focus of the laser and the position of the target are monitored to ensure that the focus of the laser is on the target.
在一个优选的实施方式中,在激光打靶后,对产生的极紫外辐射的光谱和能量进行检测,以监控激光打靶过程。In a preferred embodiment, after laser targeting, the spectrum and energy of the generated EUV radiation are detected to monitor the laser targeting process.
另一方面,本发明还提供了一种高效率极紫外辐射产生系统,包括激光源1和固体靶2。On the other hand, the present invention also provides a high-efficiency extreme ultraviolet radiation generating system, comprising a
所述激光源1为能够提供激光的装置,激光源产生的激光作用在靶上,进而产生极紫外辐射。The
进一步地,所述激光源1为飞秒激光源,优选地,为能够提供单发次能量为0.001~100焦耳、脉宽为1~100飞秒激光束的装置。Further, the
所述固体靶2具有靶材,所述固体靶的靶材为满足平均密度介于常规固体和常规气体之间、微米尺寸下分布均匀、边界陡峭的材料。The
优选地,所述靶材的平均密度为1~100mg/cm3。Preferably, the average density of the target material is 1-100 mg/cm 3 .
在一个优选的实施方式中,所述靶材为纳米管泡沫材料。In a preferred embodiment, the target material is a nanotube foam material.
更优选地,所述靶材为碳纳米管泡沫材料,所述碳纳米管泡沫材料可以是单壁或多壁碳纳米管,优选为单壁碳纳米管材料。More preferably, the target material is a carbon nanotube foam material, and the carbon nanotube foam material can be a single-walled or multi-walled carbon nanotube, preferably a single-walled carbon nanotube material.
由于碳纳米管泡沫材料具有自支撑的特性,其作为靶材时,无需为靶材设置其它的支撑结构,不仅简化了靶2的结构复杂度,并且减少了靶材支撑结构对打靶的影响,提高了系统的稳定性。Due to the self-supporting characteristics of the carbon nanotube foam material, when it is used as a target material, there is no need to provide other support structures for the target material, which not only simplifies the structural complexity of the
在一个优选的实施方式中,所述纳米管泡沫材料上负载有不同的金属原子,使得激光打靶后形成的极紫外辐射的光谱可调。In a preferred embodiment, the nanotube foam material is loaded with different metal atoms, so that the spectrum of the extreme ultraviolet radiation formed after laser targeting is adjustable.
优选地,所述靶2还包括靶体移动装置,所述靶体移动装置具有平移台,平移台与电机连接,在平移台上安装有多个靶材,通过电机驱动平移台的移动,实现靶体移动装置对靶材的移动,进而使得激光能够作用在不同的靶材上,从而连续地产生极紫外辐射。Preferably, the
在一个更优选的实施方式中,所述靶体移动装置的平移台为六维平移台,可在上下、左右、前后分别移动和旋转,从而使得靶材的位置可精确调整,进而实现将不同位置的靶材精确移动到激光打靶位置。In a more preferred embodiment, the translation stage of the target moving device is a six-dimensional translation stage, which can be moved and rotated up and down, left and right, and front and rear respectively, so that the position of the target can be precisely adjusted, thereby realizing the different The position of the target material is precisely moved to the laser target position.
在本发明中,对平移台的具体结构不做特别限定,只要能够满足上述功能即可,例如武汉红星杨科技有限公司、北京卓立汉光仪器有限公司等生产的六维平移台。In the present invention, the specific structure of the translation stage is not particularly limited, as long as it can meet the above functions, such as the six-dimensional translation stage produced by Wuhan Hongxingyang Technology Co., Ltd., Beijing Zhuoli Hanguang Instrument Co., Ltd., etc.
根据本发明,所述靶2安装在真空腔3中,所述真空腔3上设置有真空泵31。According to the present invention, the
在一个优选的实施方式中,在激光源1与靶2之间还设置有离轴抛物面镜聚焦装置4,对激光源1提供的激光束进行聚焦,进一步地,所述离轴抛物面镜聚焦装置4也设置在真空腔3中。In a preferred embodiment, an off-axis parabolic mirror focusing device 4 is further arranged between the
进一步地,所述离轴抛物面镜聚焦装置4聚焦后的激光光斑直径不大于10微米,10微米内能量集中度不小于50%。Further, the diameter of the laser spot after being focused by the off-axis parabolic mirror focusing device 4 is not greater than 10 microns, and the energy concentration within 10 microns is not less than 50%.
更进一步地,所述离轴抛物面镜聚焦装置4聚焦后的激光峰值功率不低于1015W/cm2,优选地,聚焦后的激光峰值功率不低于1018W/cm2,其满足碳纳米管中碳的场电离阈值,可以提高转换效率。Further, the laser peak power after focusing by the off-axis parabolic mirror focusing device 4 is not lower than 10 15 W/cm 2 , preferably, the laser peak power after focusing is not lower than 10 18 W/cm 2 , which satisfies The field ionization threshold of carbon in carbon nanotubes can improve the conversion efficiency.
在本发明中,对离轴抛物面镜聚焦装置4的具体结构不做特别限定,只要能够满足上述要求即可,例如美国Thorlabs的离轴抛物面反射镜。In the present invention, the specific structure of the off-axis parabolic mirror focusing device 4 is not particularly limited, as long as the above requirements can be met, such as an off-axis parabolic mirror from Thorlabs in the United States.
在一个优选的实施方式中,在激光源1与离轴抛物面镜聚焦装置4之间还设置有等离子体镜装置5,以去除飞秒激光中的预脉冲,提高激光对比度,优选地,所述离子体镜装置5设置在真空腔3中。In a preferred embodiment, a
在本发明中,不对等离子体镜装置5的具体厂家、型号做特别限制,只要能够对激光源1进行处理后,获得的激光主脉冲30ps前激光对比度不小于1010即可。In the present invention, the specific manufacturer and model of the
在一个优选的实施方式中,所述等离子体镜装置包括一个等离子体镜,等离子体镜(PM)是表面镀了增透膜的透明材料,当主激光的预脉冲到达等离子体镜表面时,高透射率膜层材料会使得只有千分之一的预脉冲被反射,大部分预脉冲被透射;而当主脉冲即将达到时,激光强度随时间增强,脉冲前沿会在等离子体镜表面不断产生等离子体,当这些等离子体的密度超过临界密度时,等离子体镜将不再透明,主激光大部分被反射。在时域上最后结果是激光的预脉冲强度减小三个量级,而主脉冲强度变化不大,因此激光的对比度有两个量级以上的提升。In a preferred embodiment, the plasma mirror device includes a plasma mirror, and the plasma mirror (PM) is a transparent material coated with an antireflection coating. When the pre-pulse of the main laser reaches the surface of the plasma mirror, the high The transmittance film material will make only one thousandth of the pre-pulse reflected, and most of the pre-pulse will be transmitted; and when the main pulse is about to arrive, the laser intensity increases with time, and the pulse front will continuously generate plasma on the surface of the plasma mirror , when the density of these plasmas exceeds the critical density, the plasma mirror will no longer be transparent and the main laser light will be mostly reflected. The final result in the time domain is that the pre-pulse intensity of the laser decreases by three orders of magnitude, while the main pulse intensity does not change much, so the contrast of the laser is improved by more than two orders of magnitude.
等离子体镜系统的采用会损失部分激光能量,而且其反射率与入射激光的能量有关,发明人发现,s偏振的激光在等离子体表面的吸收较弱,反射率一般较高。The use of the plasma mirror system will lose part of the laser energy, and its reflectivity is related to the energy of the incident laser. The inventors found that the absorption of the s-polarized laser on the plasma surface is weak, and the reflectivity is generally higher.
在一个更优选的实施方式中,在等离子体镜前还设置有二分之一波片以改变主激光偏振实现等离子体镜的s偏振入射。In a more preferred embodiment, a half-wave plate is further arranged in front of the plasmonic mirror to change the polarization of the main laser to realize the s-polarized incidence of the plasmonic mirror.
在一个优选的实施方式中,所述系统还包括束靶耦合装置6,所述束靶耦合装置6为一种显微成像系统,可用于观测激光和靶材。In a preferred embodiment, the system further includes a beam-
进一步地,束靶耦合装置6的景深不大于10微米,以清晰的观测激光和靶材。Further, the depth of field of the beam-
在本发明中,可以采用现有的任意一种束靶耦合装置,优选地,所述束靶耦合装置包括长工作距离显微物镜头61、分束片62、成像透镜63、两个CCD64和LED光源65,如图3所示,LED光源65设置在靶2前,通过LED光源65发出的光线提供靶体透射成像的照明,长工作距离显微物镜头65和分束片62依次设置在靶2后,两个CCD64分别设置在分束片62的反射光路和透射光路上,以提供不同放大倍速的打靶点图像,所述成像透镜63设置在分束片62透射光路上,位于分束片62与CCD64之间。In the present invention, any existing beam-target coupling device can be used, preferably, the beam-target coupling device includes a long working distance
通过上述的设置,两个CCD可同时实现50倍和10倍的放大成像,其中,50倍放大成像用于激光光斑和靶材的精确定位,10倍放大成像用于靶体角度的调整和中心点的确定。Through the above settings, the two CCDs can achieve 50x and 10x magnification imaging at the same time. Among them, the 50x magnification imaging is used for the precise positioning of the laser spot and the target, and the 10x magnification imaging is used for the adjustment and centering of the target angle. point OK.
进一步地,所述长工作距离显微物镜头61、分束片62、成像透镜63和CCD64安装在三维电动平移台,通过其对靶2进行调节,可实现靶材0.5μm的重复定位精度。Further, the long working distance
在一个优选的实施方式中,所述系统还具有极紫外辐射监测装置7,其包括平场光栅谱仪和AXUV二极管,平场光栅谱仪用于测量极紫外辐射光谱,AXUV二极管配合特定的极紫外滤片来测量极紫外辐射的绝对能量,并将测量获得的回馈信号传递给靶体移动装置,以对靶材位置进行调节。In a preferred embodiment, the system also has an EUV
所述平场光栅可以具有多块,分别测量不同波段的极紫外辐射,优选具有两块,其线对数分别是1200和300,对应测量光谱范围为3.3-30nm和20-80nm。The flat-field grating may have multiple pieces to measure EUV radiation in different wavelength bands respectively, and preferably has two pieces, whose line pairs are 1200 and 300 respectively, and the corresponding measurement spectral ranges are 3.3-30nm and 20-80nm.
所述AXUV二极管是IRD公司开发的针对极紫外辐射波段的光电二极管,也是NIST推荐的标准测量元件之一,被广泛应用在激光等离子体光源和同步辐射装置中。The AXUV diode is a photodiode developed by IRD for the extreme ultraviolet radiation band, and is also one of the standard measurement components recommended by NIST, and is widely used in laser plasma light sources and synchrotron radiation devices.
实施例Example
实施例1Example 1
进行实验,使用激光源对靶材进行打靶产生极紫外辐射。Experiments were conducted using a laser source to target the target to generate extreme ultraviolet radiation.
实验过程中通过束靶耦合装置调整靶材位置,使得激光源产生的激光依次经过等离子体镜和离轴抛物面镜聚焦装置后打在靶上,采用极紫外辐射监测装置对产生的极紫外辐射进行检测,离子体镜、离轴抛物面镜聚焦装置、靶和束靶耦合装置均设置在真空腔体中,真空腔的真空环境低于10-3pa。During the experiment, the position of the target is adjusted by the beam-target coupling device, so that the laser generated by the laser source passes through the plasma mirror and the off-axis parabolic mirror focusing device in turn and hits the target, and the extreme ultraviolet radiation monitoring device is used to monitor the generated extreme ultraviolet radiation. For detection, the plasma mirror, the off-axis parabolic mirror focusing device, the target and the beam-target coupling device are all set in a vacuum chamber, and the vacuum environment of the vacuum chamber is lower than 10 -3 Pa.
其中,激光源为法国THALES公司生产的200TW商用激光器,可产生30飞秒脉冲的激光,输出能量为单发次5焦耳,由束靶耦合装置测得激光焦斑的半高全宽为5.5μm,1/e2能量集中度为60%,估算可得激光的功率密度为6.6×1019W/cm2,对应的归一化光强为a0=5.5;Among them, the laser source is a 200TW commercial laser produced by French company THALES, which can generate a 30 femtosecond pulse laser, and the output energy is 5 joules per shot. The energy concentration of /e 2 is 60%, the estimated power density of the available laser is 6.6×10 19 W/cm 2 , and the corresponding normalized light intensity is a 0 =5.5;
使用靶材为碳纳米管泡沫,通过化学气相沉积(CVD)方法制备,其厚度为40微米,密度为4mg/cm3,其电镜照片如图1所示;The target material is carbon nanotube foam, prepared by chemical vapor deposition (CVD) method, its thickness is 40 microns, and the density is 4 mg/cm 3 , and its electron microscope photo is shown in Figure 1;
靶体移动装置为具有六维平移台的装置,其重复定位精度不低于10微米,调节靶体移动平台,使得激光入射靶体角度在1°之内;The target moving device is a device with a six-dimensional translation stage, and its repeated positioning accuracy is not less than 10 microns, and the target moving platform is adjusted so that the angle of the laser incident on the target is within 1°;
极紫外辐射监测装置包括两块平场光栅谱仪和AXUV二极管,两块平场光栅谱仪线对数分别是1200和300,AXUV二极管型号为AXUV100AL。The EUV radiation monitoring device includes two flat-field grating spectrometers and AXUV diodes. The line logarithms of the two flat-field grating spectrometers are 1200 and 300 respectively. The AXUV diode model is AXUV100AL.
实施例2Example 2
进行与实施例1相同的实验,区别在于,靶材的厚度为60微米。The same experiment as in Example 1 was carried out, except that the thickness of the target was 60 microns.
实施例3Example 3
进行与实施例1相同的实验,区别在于,靶材的厚度为80微米。The same experiment as in Example 1 was carried out, except that the thickness of the target was 80 microns.
对比例1Comparative Example 1
进行与实施例1相同的实验,区别在于,靶材为厚度为120微米的塑料靶。The same experiment as in Example 1 was carried out, except that the target material was a plastic target with a thickness of 120 microns.
实验例1Experimental example 1
检测对比例1和实施例1、2产生的极紫外辐射光谱,如图4所示,可以明显看到,激光与塑料靶作用没有观测到极紫外辐射,如图中a)所示;Detecting the extreme ultraviolet radiation spectrum produced by Comparative Example 1 and Examples 1 and 2, as shown in Figure 4, it can be clearly seen that no extreme ultraviolet radiation is observed when the laser interacts with the plastic target, as shown in a) in the figure;
激光与碳纳米管泡沫靶相互作用过程中可以产生宽谱的极紫外辐射,图中b)和c)的极紫外辐射表现为很多条分立的线辐射以及一个准连续的本底辐射,值得注意的是,由于1200线和300线光栅的衍射效率以及光谱分辨率不同,在拼接光谱的25nm处会有不连续。During the interaction between the laser and the carbon nanotube foam target, a broad spectrum of EUV radiation can be generated. The EUV radiation in b) and c) in the figure appears as many discrete line radiations and a quasi-continuous background radiation. It is worth noting However, due to the different diffraction efficiencies and spectral resolutions of the 1200-line and 300-line gratings, there will be a discontinuity at 25 nm of the stitched spectrum.
实验例2Experimental example 2
从实施例2中平场光栅谱仪采集到的数据中反解出光谱,结果如图5所示,其中,左上角的插入图是实验中AXUV二极管在15度方向上测到的辐射能量信号。The spectrum is reversely solved from the data collected by the flat-field grating spectrometer in Example 2, and the result is shown in Figure 5, where the insert in the upper left corner is the radiation energy signal measured by the AXUV diode in the 15-degree direction in the experiment .
从解出的光谱可以看到在波长小于10nm的辐射段,线辐射的特征很明显,而在波长大于10nm的辐射段,则以较为平坦的准连续辐射为主。From the solved spectrum, it can be seen that in the radiation section with wavelength less than 10nm, the characteristics of line radiation are obvious, while in the radiation section with wavelength greater than 10nm, relatively flat quasi-continuous radiation is dominant.
实验例3Experimental example 3
观察实施例1~3中AXUV二极管测量到的极紫外辐射的能量角分布,结果如图6所示,其中带*的点代表AXUV二极管的实际测量值,其他角度的辐射能量通过线性插值和对称性估计得到,径向数值代表辐射产额,单位为mJ/Sr。Observe the energy angular distribution of the extreme ultraviolet radiation measured by the AXUV diode in Examples 1 to 3. The results are shown in Figure 6, where the point with * represents the actual measured value of the AXUV diode, and the radiation energy of other angles is obtained by linear interpolation and symmetry. The radial value represents the radiation yield in mJ/Sr.
可以看出实施例1~3激光与碳纳米管泡沫靶相互作用均能产生极紫外辐射,且产生的极紫外辐射具有一定的前向性。考虑辐射分布后,估计辐射总立体角为3π,相应的极紫外辐射总产额为240mJ,对应的转换效率为22%。It can be seen that the interaction of the lasers in Examples 1 to 3 with the carbon nanotube foam target can generate extreme ultraviolet radiation, and the generated extreme ultraviolet radiation has a certain forward direction. After considering the radiation distribution, the total solid angle of radiation is estimated to be 3π, the corresponding total EUV radiation yield is 240 mJ, and the corresponding conversion efficiency is 22%.
在本发明的描述中,需要说明的是,术语“上”、“下”、“内”、“外”、“前”、“后”等指示的方位或位置关系为基于本发明工作状态下的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”、“第三”、“第四”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of the present invention, it should be noted that the orientation or positional relationship indicated by the terms "upper", "lower", "inner", "outer", "front", "rear", etc. is based on the working state of the present invention The orientation or positional relationship is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the indicated device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be construed as a limitation of the present invention . Furthermore, the terms "first," "second," "third," and "fourth" are used for descriptive purposes only and should not be construed to indicate or imply relative importance.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”“相连”“连接”应作广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体的连接普通;可以是机械连接,也可以是电连接;可以是直接连接,也可以通过中间媒介间接连接,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that, unless otherwise expressly specified and limited, the terms "installed", "connected" and "connected" should be understood in a broad sense, for example, it may be a fixed connection or a detachable connection, Or an integral connection is common; it can be a mechanical connection or an electrical connection; it can be a direct connection, or an indirect connection through an intermediate medium, and it can be internal communication between two components. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood in specific situations.
以上结合了优选的实施方式对本发明进行了说明,不过这些实施方式仅是范例性的,仅起到说明性的作用。在此基础上,可以对本发明进行多种替换和改进,这些均落入本发明的保护范围内。The present invention has been described above with reference to the preferred embodiments, but these embodiments are merely exemplary and serve only for illustrative purposes. On this basis, various substitutions and improvements can be made to the present invention, which all fall within the protection scope of the present invention.
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