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CN114618271B - Intelligent graphite falling film absorber - Google Patents

Intelligent graphite falling film absorber Download PDF

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Publication number
CN114618271B
CN114618271B CN202210516674.1A CN202210516674A CN114618271B CN 114618271 B CN114618271 B CN 114618271B CN 202210516674 A CN202210516674 A CN 202210516674A CN 114618271 B CN114618271 B CN 114618271B
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pipe
box
liquid
fixedly connected
cooling
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CN114618271A (en
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吕浩
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Nantong Kexing Graphite Equipment Co ltd
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Nantong Kexing Graphite Equipment Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The invention relates to the technical field of graphite falling film absorbers, and discloses an intelligent graphite falling film absorber which comprises an absorption box, wherein a liquid inlet pipe is fixedly connected to the upper end of the absorption box, a flow dividing piece is arranged in the absorption box, an air inlet pipe matched with the flow dividing piece for use is fixedly connected to the side wall of the absorption box, an air outlet pipe matched with the air inlet pipe for use is fixedly connected to the side wall of the absorption box, a cooling pipe is arranged at the bottom of the absorption box, a flow guide piece matched with the cooling pipe for use is arranged at the bottom of the absorption box, and an exhaust box is fixedly connected to the bottom of the cooling pipe. The liquid inlet pipe is arranged on the absorption box, the liquid inlet pipe is connected with the liquid inlet pipe, the liquid outlet pipe is connected with the liquid inlet pipe, the liquid inlet pipe is connected with the liquid outlet pipe, the liquid inlet pipe is connected with the liquid inlet pipe, the liquid outlet pipe is connected with the liquid inlet pipe, the liquid inlet pipe is connected with the liquid inlet pipe, and the liquid inlet pipe is connected with the liquid outlet pipe.

Description

Intelligent graphite falling film absorber
Technical Field
The invention relates to the technical field of graphite falling film absorbers, in particular to an intelligent graphite falling film absorber.
Background
The graphite falling film absorber is a falling film type gas absorption device mainly made of impermeable graphite. By impervious graphite is meant a graphite article that is impervious to fluid media such as gases, vapors, liquids, and the like. The graphite material is a special non-metallic material, not only has good physical and mechanical properties and processability, but also has excellent corrosion resistance and high thermal conductivity, so that the graphite material is an ideal material for manufacturing chemical anti-corrosion equipment. The graphite product as a structural material also contains some high molecular materials or other components to adapt to different use conditions.
The graphite falling film absorber consists of three parts, including gas-liquid distributor comprising gas and liquid inlet pipes, pressure stabilizing ring, liquid distributing pipe and other impervious graphite parts, absorbing and cooling section and gas-liquid separator. Graphite falling film absorbers are essentially in which the heat extracted and concurrent downward flow of the two gas absorbed and liquid absorbed streams is effected by a shell and tube heat exchanger circulating cooling water within the shell. The liquid is circulated through the tank until the desired concentration is achieved. At such a rate, the tube is not flowing sufficiently, but not liquid, to fall down the tube as gravity on the inner wall of the membrane. A graphite falling film absorption reactor is an absorption reactor in which liquid falls down a wall under the action of gravity to form a thin film and is in counter-current or co-current contact with gas. The liquid film descending along the wall surface can be formed on the flat surface or on the inner and outer walls of a round tube, generally a round tube, and has the following characteristics: 1. the gas film and the liquid film are not penetrated, the pressure drop of the equipment is small, and higher gas load is allowed; 2. The falling film is very thin and can generate special fluctuation on the surface of the film, the back mixing of a gas phase and a liquid film is small, the heat and mass transfer efficiency is high, and the total fluid transfer amount generated by unit energy consumption is large; 3. the liquid film descending along the wall can be cooled by the partition walls, which is suitable for absorption processes with high thermal effect and can make the process run at near-isothermal temperature.
However, in the actual use process of the existing intelligent graphite falling film absorber, the absorption efficiency of the final absorption liquid is not high due to too fast liquid flow rate or too small actual contact area between the liquid and the gas, so that the yield of the subsequent product is affected, meanwhile, in the cooling stage, the heat transfer efficiency of the liquid may be affected due to too short contact time of the liquid in the cooling pipe, and the cost may be too high if the cooling pipe is lengthened.
Disclosure of Invention
The invention aims to solve the problems that in the actual use process of the existing intelligent graphite falling film absorber in the prior art, the final absorption efficiency of absorption liquid is not high due to too high liquid flow rate or too small actual contact area between liquid and gas, so that the yield of subsequent products is influenced, meanwhile, in the cooling stage, the heat transfer efficiency of liquid is possibly influenced due to too short contact time of the liquid in a cooling pipe, and the cost is possibly too high if the cooling pipe is lengthened.
In order to achieve the purpose, the invention adopts the following technical scheme:
the utility model provides an intelligence graphite falling liquid film absorber, includes the absorption box, absorption box upper end fixedly connected with feed liquor pipe, the inside reposition of redundant personnel that is provided with of absorption box, the reposition of redundant personnel setting is at the feed liquor pipe, the intake pipe that fixedly connected with cooperation reposition of redundant personnel used on the absorption box lateral wall, the outlet duct that fixedly connected with cooperation intake pipe used on the absorption box lateral wall, absorption box bottom is provided with the cooling tube, absorption box bottom is provided with the water conservancy diversion piece that cooperation cooling tube used, cooling tube bottom fixedly connected with exhaust box, the inside spiral pipe that is provided with vertical setting of exhaust box, the blast pipe that fixedly connected with cooperation spiral pipe used on the exhaust box lateral wall, exhaust box bottom fixedly connected with goes out the workbin, go out workbin bottom fixedly connected with discharging pipe, be provided with the valve on the discharging pipe.
In foretell intelligence graphite falling liquid film absorber, the reposition of redundant personnel piece comprises flow distribution box, liquid outlet and flow distribution plate, flow distribution box fixed connection is in feed liquor socle portion, and is a plurality of the liquid outlet evenly sets up on the flow distribution box lateral wall, the flow distribution plate cup joints on the flow distribution box lateral wall, the flow distribution plate adopts the setting of toper structure.
In foretell intelligence graphite falling liquid film absorber, the ring channel has been cup jointed on the absorption box lateral wall, intake pipe fixed connection is on the ring channel, the inside venthole that offers cooperation intake pipe and use of ring channel, the venthole passes the setting of absorption box inner wall.
In foretell intelligence graphite falling liquid film absorber, the water conservancy diversion spare comprises guide plate, water conservancy diversion hole and opening, guide plate fixed connection is in the absorption tank bottom, the water conservancy diversion hole is seted up on guide plate bottom fixed block, the water conservancy diversion hole adopts the setting of V type structure, the opening is seted up in the guide plate upper end, water conservancy diversion hole cooperation opening sets up.
In the above-mentioned intelligent graphite falling film absorber, the flow guide holes are arranged in parallel with the inner wall of the cooling pipe, and the upper end of the cooling pipe is arranged in an inclined structure in cooperation with the flow guide holes.
In the above intelligent graphite falling film absorber, the inner wall of the cooling pipe is provided with a spiral groove used in cooperation with the flow guide hole, and the spiral groove is arranged in close contact with the inner wall of the cooling pipe.
In the above intelligent graphite falling film absorber, a cooling pipe groove is formed in the inner wall of the cooling pipe, and a cooling water pipe is arranged in the cooling pipe groove.
In the above-mentioned intelligent graphite falling film absorber, the drainage groove that cooperation spiral pipe used is seted up at the exhaust case top, the last separation hole of having seted up of spiral pipe.
In the above intelligent graphite falling film absorber, the side wall of the bottom of the absorber tank extends outwards to form a fixed edge, the side wall of the cooling pipe extends outwards to form a fixed edge, and a fixing bolt is connected between the two fixed edges through a bolt.
In foretell intelligence graphite falling liquid film absorber, the spiral pipe upper end is seted up on the drainage groove inner wall, the one end that the drainage groove was kept away from to the spiral pipe is seted up on the play workbin inner wall.
Compared with the prior art, the invention has the following advantages:
1. the liquid inlet pipe is connected with the liquid outlet, the liquid outlet pipe is connected with the liquid inlet pipe, the liquid inlet pipe is connected with the liquid outlet, and the liquid outlet pipe is connected with the liquid inlet pipe.
2. The cooling pipe is provided with the flow guide piece and the spiral groove, so that liquid can flow on the inner wall of the cooling pipe through the flow guide hole when entering the cooling pipe, the flowing speed of the liquid is slowed down, meanwhile, the spiral groove can increase the contact area between the liquid and the inner wall of the cooling pipe, the cooling time of the liquid is prolonged, and the cooling efficiency is improved.
3. The invention is provided with the fixed edge and the fixed bolt, so that certain impurities can be accumulated in the device to influence the liquid absorption efficiency in the long-time use process of the device, and the device can be separated by rotating the fixed bolt, so that the inside of the device can be conveniently cleaned.
Drawings
Fig. 1 is a schematic structural diagram of an intelligent graphite falling film absorber according to the present invention;
fig. 2 is a schematic diagram of the internal structure of an intelligent graphite falling film absorber according to the present invention;
fig. 3 is a schematic view of a vent box structure of an intelligent graphite falling film absorber according to the present invention;
fig. 4 is a schematic structural view of a flow divider of an intelligent graphite falling film absorber according to the present invention;
fig. 5 is a schematic structural view of a flow guide part of an intelligent graphite falling film absorber according to the present invention.
In the figure: 1 absorption box, 2 liquid inlet pipes, 3 flow dividing parts, 31 flow dividing box, 32 liquid outlet, 33 flow dividing plate, 4 air inlet pipes, 5 annular grooves, 6 air outlet holes, 7 air outlet pipes, 8 cooling pipes, 9 flow dividing parts, 91 flow dividing plates, 92 flow dividing holes, 93 flow dividing holes, 10 spiral grooves, 11 cooling pipe grooves, 12 cooling water pipes, 13 air exhaust boxes, 14 flow dividing grooves, 15 spiral pipes, 16 separating holes, 17 air exhaust pipes, 18 discharge boxes, 19 discharge pipes, 20 valves, 21 fixing edges, 22 fixing bolts, 23 fixing edges, 31 flow dividing box, 32 liquid outlet, 33 flow dividing plate, 91 flow dividing plate, 92 flow dividing holes and 93 flow dividing holes.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
Referring to fig. 1 and 2, an intelligent graphite falling film absorber comprises an absorption box 1, a liquid inlet pipe 2 is fixedly connected to the upper end of the absorption box 1, a shunt member 3 is arranged inside the absorption box 1, the shunt member 3 is arranged on the liquid inlet pipe 2, an air inlet pipe 4 matched with the shunt member 3 for use is fixedly connected to the side wall of the absorption box 1, an annular groove 5 is sleeved on the side wall of the absorption box 1, the air inlet pipe 4 is fixedly connected to the annular groove 5, an air outlet hole 6 matched with the air inlet pipe 4 for use is arranged inside the annular groove 5, the air outlet hole 6 penetrates through the inner wall of the absorption box 1, gas is introduced through the air inlet pipe 4, the gas passes through the annular groove 5 and is introduced into the absorption box 1 through the air outlet hole 6, the gas is uniformly diffused inside the absorption box 1 under the action of a plurality of the air outlet holes 6, an air outlet pipe 7 matched with the air inlet pipe 4 for use is fixedly connected to the side wall of the absorption box 1, a cooling pipe 8 is arranged at the bottom of the absorption box 1, the bottom of absorption box 1 is provided with water conservancy diversion spare 9 that cooperation cooling tube 8 used, be provided with the helicla flute 10 that cooperation water conservancy diversion hole 92 used on the 8 inner walls of cooling tube, cooling tube groove 11 has been seted up in the 8 inner walls of cooling tube, cooling tube groove 11 inside is provided with condenser tube 12, condenser tube 12 is inside lets in cold water, the heat of liquid can be taken away to condenser tube 12, helicla flute 10 hugs closely 8 inner walls of cooling tube and sets up 8 bottom fixedly connected with exhaust boxes 13 of cooling tube, 1 bottom lateral wall of absorption box outwards extends and forms fixed limit 21, 8 lateral walls of condenser tube outwards extend and form fixed limit 23, bolted connection has fixing bolt 22 between fixed limit 21 and the fixed limit 23, can fix and dismantle absorption box 1 and cooling tube 8 through fixing bolt 22, the washing of later stage to the device has been made things convenient for.
Referring to fig. 3, a vertically arranged spiral tube 15 is arranged inside an exhaust box 13, the upper end of the spiral tube 15 is arranged on the inner wall of a drainage groove 14, one end of the spiral tube 15, which is far away from the drainage groove 14, is arranged on the inner wall of a discharge box 18, a drainage groove 14 matched with the spiral tube 15 for use is arranged at the top end of the exhaust box 13, a separation hole 16 is arranged on the spiral tube 15, when liquid flows to the bottom of the spiral tube 10, the liquid flows into the spiral tube 15 inside an exhaust pipe 13 through the drainage groove 14, residual gas inside the device can flow out through the separation hole 16 while flowing inside the spiral tube 15, so as to avoid impurity gas existing in a final product, an exhaust pipe 17 matched with the spiral tube 15 for use is fixedly connected to the side wall of the exhaust box 13, the bottom of the exhaust box 13 is fixedly connected with the discharge box 18, a discharge pipe 19 is fixedly connected to the bottom of the discharge box 18, a valve 20 is arranged on the discharge pipe 19, and the liquid flows into the discharge box 18 through the spiral tube 15 for storage, when it is desired to discharge the product liquid, valve 20 is opened and the product liquid can be discharged through discharge pipe 19.
Referring to fig. 4, reposition of redundant personnel 3 comprises flow distribution box 31, liquid outlet 32 and flow distribution plate 33, and flow distribution box 31 fixed connection is in 2 bottoms of feed liquor pipe, and a plurality of liquid outlets 32 evenly set up on flow distribution box 31 lateral wall, and flow distribution plate 33 cup joints on flow distribution box 31 lateral wall, and flow distribution plate 33 adopts the toper structure to set up, and when liquid passed through flow distribution 3, liquid passed through liquid outlet 32 to take place the diffusion through flow distribution plate 33, make the area of contact increase of liquid.
Referring to fig. 2 and 5, the flow guiding member 9 is composed of a flow guiding plate 91, flow guiding holes 92 and flow holes 93, the flow guiding plate 91 is fixedly connected to the bottom of the absorption box 1, the flow guiding holes 92 are formed in a fixed block at the bottom of the flow guiding plate 91, the flow guiding holes 92 are arranged in a V-shaped structure, the flow holes 93 are formed in the upper end of the flow guiding plate 91, the flow guiding holes 92 are arranged in cooperation with the flow holes 93, the flow guiding holes 92 are arranged in parallel with the inner wall of the cooling pipe 8, the upper end of the cooling pipe 8 is arranged in an inclined structure in cooperation with the flow guiding holes 92, liquid passes through the flow guiding member 9, the liquid flows into the flow guiding holes 92 through the flow holes 93 on the flow guiding plate 91, the liquid flows onto the inner wall of the cooling pipe 8 through the flow guiding holes 92, and slowly flows through the spiral grooves 10, so that the cooling time of the liquid is prolonged.
The working principle is as follows:
at first fix absorption box 1 and cooling tube 8 through fixing bolt 22, let in liquid through feed liquor pipe 2 after that, liquid is when passing through reposition of redundant personnel piece 3, liquid passes through liquid outlet 32, and take place the diffusion through flow distribution plate 33, make the area of contact of liquid increase, let in gas through intake pipe 4 after that, gas is through ring channel 5, and let in absorption box 1 inside through venthole 6, make gaseous even diffusion inside absorption box 1 under the effect of a plurality of ventholes 6, gaseous and liquid take place intensive mixing in absorption box 1, useless gas is discharged through outlet duct 7 again.
The liquid that has absorbed gas passes through water conservancy diversion spare 9, and liquid flows into water conservancy diversion hole 92 through circulation hole 93 on guide plate 91 in, and liquid flows to cooling tube 9 inner wall through water conservancy diversion hole 92 on, and liquid passes through helicla flute 10 slow flow for liquid cooling time increases, and toward the inside cold water that lets in of cooling tube 12 simultaneously, cooling tube 12 can take away the heat of liquid.
When liquid flows to spiral groove 10 bottom, inside spiral pipe 15 in the blast pipe 13 flows in through drainage groove 14, in the inside flow of spiral pipe 15 simultaneously, the inside remaining gas of device can flow out through separation hole 16, avoid final finished product to have impurity gas, impurity gas passes through blast pipe 17 at exhaust box 13 and discharges, liquid finally flows into out 18 inside storages of workbin through spiral pipe 15, when the finished product liquid of needs discharge, open valve 20, alright discharge in order to pass through discharging pipe 19.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (5)

1. The utility model provides an intelligence graphite falling liquid film absorber, includes absorption tank (1), its characterized in that, absorption tank (1) upper end fixedly connected with feed liquor pipe (2), inside reposition of redundant personnel piece (3) that is provided with of absorption tank (1), reposition of redundant personnel piece (3) set up in feed liquor pipe (2) bottom, intake pipe (4) that fixedly connected with cooperation reposition of redundant personnel piece (3) used on the absorption tank (1) lateral wall, fixedly connected with outlet duct (7) that cooperation intake pipe (4) used on absorption tank (1) lateral wall, absorption tank (1) bottom is provided with cooling tube (8), absorption tank (1) bottom is provided with water conservancy diversion piece (9) that cooperation cooling tube (8) used, cooling tube (8) bottom fixedly connected with exhaust box (13), inside spiral pipe (15) that are provided with vertical setting of exhaust box (13), an exhaust pipe (17) matched with the spiral pipe (15) for use is fixedly connected to the side wall of the exhaust box (13), a discharge box (18) is fixedly connected to the bottom of the exhaust box (13), a discharge pipe (19) is fixedly connected to the bottom of the discharge box (18), and a valve (20) is arranged on the discharge pipe (19);
the flow dividing piece (3) is composed of a flow dividing box (31), liquid outlets (32) and a flow dividing plate (33), the flow dividing box (31) is fixedly connected to the bottom of the liquid inlet pipe (2), the liquid outlets (32) are uniformly arranged on the side wall of the flow dividing box (31), the flow dividing plate (33) is sleeved on the side wall of the flow dividing box (31), and the flow dividing plate (33) is arranged in a conical structure;
the side wall of the absorption box (1) is sleeved with an annular groove (5), the air inlet pipe (4) is fixedly connected to the annular groove (5), an air outlet hole (6) matched with the air inlet pipe (4) is formed in the annular groove (5), and the air outlet hole (6) penetrates through the inner wall of the absorption box (1);
the utility model discloses a set up the spiral pipe (15) on the absorption case, water conservancy diversion spare (9) comprises guide plate (91), water conservancy diversion hole (92) and opening (93), guide plate (91) fixed connection is in absorption case (1) bottom, water conservancy diversion hole (92) are seted up on guide plate (91) bottom fixed block, water conservancy diversion hole (92) adopt V type structure to set up, opening (93) are seted up in guide plate (91) upper end, water conservancy diversion hole (92) cooperation opening (93) set up, drainage groove (14) that cooperation spiral pipe (15) used have been seted up on exhaust case (13) top, separation hole (16) have been seted up on spiral pipe (15).
2. An intelligent graphite falling film absorber according to claim 1, wherein the inner wall of the cooling pipe (8) is provided with a spiral groove (10) used for matching with the diversion hole (92), and the spiral groove (10) is closely attached to the inner wall of the cooling pipe (8).
3. An intelligent graphite falling film absorber according to claim 1, wherein a cooling pipe groove (11) is formed in the inner wall of the cooling pipe (8), and a cooling water pipe (12) is arranged in the cooling pipe groove (11).
4. An intelligent graphite falling film absorber according to claim 1, wherein the side wall of the bottom of the absorption box (1) extends outwards to form a fixed edge (21), the side wall of the cooling pipe (8) extends outwards to form a fixed edge (23), and a fixed bolt (22) is bolted between the fixed edge (21) formed by the side wall of the bottom of the absorption box (1) and the fixed edge (23) formed by the side wall of the cooling pipe (8).
5. An intelligent graphite falling film absorber according to claim 1, wherein the upper end of the spiral pipe (15) is arranged on the inner wall of the drainage groove (14), and the end of the spiral pipe (15) far away from the drainage groove (14) is arranged on the inner wall of the discharge box (18).
CN202210516674.1A 2022-05-13 2022-05-13 Intelligent graphite falling film absorber Active CN114618271B (en)

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CN114618271B true CN114618271B (en) 2022-09-13

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2842344Y (en) * 2005-11-09 2006-11-29 南化集团研究院 Falling-film cooler
CN202724976U (en) * 2012-08-16 2013-02-13 建德市欣正环保设备有限公司 Graphite modified polypropylene falling film absorber
CN202844835U (en) * 2012-10-22 2013-04-03 杭州新安江工业泵有限公司 Falling film absorber
CN108722132A (en) * 2017-11-24 2018-11-02 羿太环保科技(上海)有限公司 A kind of falling film type absorption condensation device and method
CN213408174U (en) * 2020-06-11 2021-06-11 新郑市永兴工贸有限公司 Graphite falling film absorption tower for benzoyl chloride production

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2842344Y (en) * 2005-11-09 2006-11-29 南化集团研究院 Falling-film cooler
CN202724976U (en) * 2012-08-16 2013-02-13 建德市欣正环保设备有限公司 Graphite modified polypropylene falling film absorber
CN202844835U (en) * 2012-10-22 2013-04-03 杭州新安江工业泵有限公司 Falling film absorber
CN108722132A (en) * 2017-11-24 2018-11-02 羿太环保科技(上海)有限公司 A kind of falling film type absorption condensation device and method
CN213408174U (en) * 2020-06-11 2021-06-11 新郑市永兴工贸有限公司 Graphite falling film absorption tower for benzoyl chloride production

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