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CN114614314A - Alloy conducting ring and preparation method thereof - Google Patents

Alloy conducting ring and preparation method thereof Download PDF

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Publication number
CN114614314A
CN114614314A CN202210071456.1A CN202210071456A CN114614314A CN 114614314 A CN114614314 A CN 114614314A CN 202210071456 A CN202210071456 A CN 202210071456A CN 114614314 A CN114614314 A CN 114614314A
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Prior art keywords
conductive ring
alloy
temperature
alloy conductive
forging temperature
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Inventor
于文军
户赫龙
郝海英
付丰年
江丹平
李海滨
董亭义
吕保国
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Beijing Trillion Metals Co ltd
Grikin Advanced Material Co Ltd
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Beijing Trillion Metals Co ltd
Grikin Advanced Material Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R39/00Rotary current collectors, distributors or interrupters
    • H01R39/02Details for dynamo electric machines
    • H01R39/08Slip-rings
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C5/00Alloys based on noble metals
    • C22C5/06Alloys based on silver
    • C22C5/08Alloys based on silver with copper as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/14Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of noble metals or alloys based thereon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/026Alloys based on copper
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/0036Details
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R43/00Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors
    • H01R43/10Manufacture of slip-rings

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Forging (AREA)

Abstract

The invention provides an alloy conducting ring, which comprises 20-21 wt% of copper Cu, 1-2 wt% of nickel Ni, 0.1-1 wt% of bismuth Bi and the balance of Ag. The alloy conducting ring has the advantages of high hardness, good wear resistance and stable quality.

Description

合金导电环及其制备方法Alloy conductive ring and preparation method thereof

技术领域technical field

本发明涉及有色金属合金技术领域,具体涉及一种银铜镍铋合金导电环及其制备方法。The invention relates to the technical field of non-ferrous metal alloys, in particular to a silver-copper-nickel-bismuth alloy conductive ring and a preparation method thereof.

背景技术Background technique

雷达天线座转动部分有各种驱动元件、测量元件和控制元件,而电源和控制机柜是固定不动的,因此需要旋转连接装置在相对转动的部件之间传输信号或功率。The rotating part of the radar antenna base has various driving elements, measuring elements and control elements, while the power supply and control cabinet are fixed, so a rotating connection device is required to transmit signals or power between the relatively rotating parts.

导电环又称导电滑环、集流环、汇流环等,是实现两个相对转动机构的图像、数据信号及动力传递的精密输电装置,特别适合应用于有无限制连续旋转需求,同时又有需要从固定位置到旋转位置传送功率或者数据的场所。导电环需要传输低电平的信号、中高频的信号和大到几百安培的电流,因此,其性能直接影响信号和电流传输的稳定性和可靠性。Conductive ring, also known as conductive slip ring, collector ring, collector ring, etc., is a precision power transmission device that realizes the image, data signal and power transmission of two relative rotating mechanisms. It is especially suitable for applications with unlimited continuous rotation requirements. Locations where power or data needs to be transferred from a fixed location to a rotating location. The conductive ring needs to transmit low-level signals, medium and high-frequency signals and currents as large as several hundred amperes. Therefore, its performance directly affects the stability and reliability of signal and current transmission.

导电环包括电刷和环状导电部分两部分,通过两者配合将静止设备上的电信号或电流传输给旋转设备。目前,欧洲航天标准化合作组织(ECSS)的标准要求导电环的有效运行距离为56000转。国内,航天科技集团公司在航天器设计时,对其在轨服役设计寿命显著增加,在轨转动的周次也由几万周次提高到百万周次。大直径,硬度高,耐磨性好,质量稳定的导电环成为行业发展的必然趋势。The conductive ring includes two parts, a brush and a ring-shaped conductive part, and through the cooperation of the two parts, the electrical signal or current on the stationary equipment is transmitted to the rotating equipment. Currently, the European Space Cooperation Organization for Standardization (ECSS) standard requires an effective operating distance of 56,000 revolutions for the conductive ring. In China, when designing spacecraft, the Aerospace Science and Technology Corporation has significantly increased its on-orbit service design life, and the number of on-orbit rotation cycles has also increased from tens of thousands of cycles to millions of cycles. Conductive rings with large diameter, high hardness, good wear resistance and stable quality have become an inevitable trend in the development of the industry.

发明内容SUMMARY OF THE INVENTION

本发明的目的提供一种银铜镍铋合金导电环,具有硬度高、耐磨性好、质量稳定的优势。The purpose of the present invention is to provide a silver-copper-nickel-bismuth alloy conductive ring, which has the advantages of high hardness, good wear resistance and stable quality.

为解决上述技术问题,本发明提供一种合金导电环,其合金组成为铜Cu为20-21wt%、镍Ni为1-2wt%、铋Bi为0.1-1wt%、余量为Ag。In order to solve the above technical problems, the present invention provides an alloy conductive ring, the alloy composition of which is copper Cu 20-21 wt %, nickel Ni 1-2 wt %, bismuth Bi 0.1-1 wt %, and the balance Ag.

其中,所述导电环厚为2~5mm,内径为190~205mm。Wherein, the thickness of the conductive ring is 2-5 mm, and the inner diameter is 190-205 mm.

本发明还提供上述银铜镍铋合金导电环的制作方法,包括:The present invention also provides a method for making the above-mentioned silver-copper-nickel-bismuth alloy conductive ring, comprising:

第一步,将银、铜、镍、和铋材料真空中频炉熔炼,获得铸锭;The first step is to smelt silver, copper, nickel, and bismuth materials in a vacuum intermediate frequency furnace to obtain an ingot;

第二步,将铸锭进行均匀化热处理;In the second step, the ingot is subjected to homogenization heat treatment;

第三步,将第二步获得的产物进行锻造处理;The third step is to forge the product obtained in the second step;

第四步,将第三步获得的产物进行扩孔处理;In the fourth step, the product obtained in the third step is subjected to hole reaming treatment;

第五步,将第四步获得的产物进行环锻处理,制成管坯;In the fifth step, the product obtained in the fourth step is subjected to ring forging treatment to make a tube blank;

第六步,将管坯经旋压处理;The sixth step is to spin the tube blank;

第七步,将第六步获得产物进行热处理,制成合金管;In the seventh step, the product obtained in the sixth step is subjected to heat treatment to make an alloy tube;

第八步,根据需要进行切割。The eighth step is to cut as needed.

其中,所述第二步中均匀化热处理的退火温度为700℃~800℃,保温时间为100-200min。Wherein, the annealing temperature of the homogenization heat treatment in the second step is 700° C.˜800° C., and the holding time is 100-200 min.

其中,所述第三步中,所述的开坯始锻温度为700℃~800℃,终锻温度为550℃~650℃,其余火次的始锻温度为650~700℃,终锻温度为600℃。Wherein, in the third step, the initial forging temperature of the blank is 700°C to 800°C, the final forging temperature is 550°C to 650°C, and the initial forging temperature of the remaining fires is 650°C to 700°C, and the final forging temperature is 650°C to 700°C. is 600°C.

其中,所述第四步中,扩孔温度为640℃~720℃,所采用的扩孔模具的直径为

Figure BDA0003482228140000021
Wherein, in the fourth step, the hole expanding temperature is 640℃~720℃, and the diameter of the hole expanding die used is
Figure BDA0003482228140000021

其中,所述第五步中,所述的环锻温度为640℃~720℃,终锻温度为560~590℃。Wherein, in the fifth step, the ring forging temperature is 640-720°C, and the final forging temperature is 560-590°C.

其中,所述第六步中,旋压工艺的热处理温度为550~600℃。Wherein, in the sixth step, the heat treatment temperature of the spinning process is 550-600°C.

其中,所述第六步中,所述的旋压工艺道次变形量为10%~30%,总变形量为40~70%。Wherein, in the sixth step, the deformation amount of the spinning process is 10%-30%, and the total deformation amount is 40-70%.

本发明的有益效果The beneficial effects of the present invention

本发明提供的导电环通过增加铋元素提高了合金的耐磨性,电阻率满足要求,并且节约了生产成本,满足导电环的使用。The conductive ring provided by the invention improves the wear resistance of the alloy by adding bismuth element, and the resistivity meets the requirements, saves the production cost, and satisfies the use of the conductive ring.

具体实施方式Detailed ways

本发明提供一种合金导电环,其合金组成为铜Cu为20-21wt%、镍Ni为1-2wt%、铋Bi为0.1-1wt%、余量为Ag。The invention provides an alloy conductive ring, the alloy composition of which is copper Cu 20-21wt%, nickel Ni 1-2wt%, bismuth Bi 0.1-1wt%, and the balance Ag.

其中,所述导电环厚为2~5mm,优选2~4mm,内径为190~205mm,优选为192~198mm。Wherein, the thickness of the conductive ring is 2-5 mm, preferably 2-4 mm, and the inner diameter is 190-205 mm, preferably 192-198 mm.

该合金导电环通过增加铋元素提高了合金的耐磨性,电阻率满足要求,并且节约了生产成本,满足导电环的使用。The alloy conductive ring improves the wear resistance of the alloy by adding bismuth element, and the electrical resistivity meets the requirements, saves the production cost, and satisfies the use of the conductive ring.

本发明还提供上述银铜镍铋合金导电环的制作方法,包括:The present invention also provides a method for making the above-mentioned silver-copper-nickel-bismuth alloy conductive ring, comprising:

第一步,将银、铜、镍、和铋材料真空中频炉熔炼,获得铸锭;The first step is to smelt silver, copper, nickel, and bismuth materials in a vacuum intermediate frequency furnace to obtain an ingot;

第二步,将铸锭进行均匀化热处理;In the second step, the ingot is subjected to homogenization heat treatment;

第三步,将第二步获得的产物进行锻造处理;The third step is to forge the product obtained in the second step;

第四步,将第三步获得的产物进行扩孔处理;In the fourth step, the product obtained in the third step is subjected to hole reaming treatment;

第五步,将第四步获得的产物进行环锻处理,制成管坯;In the fifth step, the product obtained in the fourth step is subjected to ring forging treatment to make a tube blank;

第六步,将管坯经旋压处理;The sixth step is to spin the tube blank;

第七步,将第六步获得产物进行热处理,制成合金管;In the seventh step, the product obtained in the sixth step is subjected to heat treatment to make an alloy tube;

第八步,根据需要进行切割。The eighth step is to cut as needed.

其中,所述第二步中均匀化热处理的退火温度为700℃~800℃,保温时间为100-200min。Wherein, the annealing temperature of the homogenization heat treatment in the second step is 700° C.˜800° C., and the holding time is 100-200 min.

其中,所述第三步中,所述的开坯始锻温度为700℃~800℃,终锻温度为550℃~650℃,其余火次的始锻温度为650~700℃,终锻温度为600℃。Wherein, in the third step, the initial forging temperature of the blank is 700°C to 800°C, the final forging temperature is 550°C to 650°C, and the initial forging temperature of the remaining fires is 650°C to 700°C, and the final forging temperature is 650°C to 700°C. is 600°C.

其中,所述第四步中,扩孔温度为640℃~720℃,所采用的扩孔模具的直径为

Figure BDA0003482228140000041
Wherein, in the fourth step, the hole expanding temperature is 640℃~720℃, and the diameter of the hole expanding die used is
Figure BDA0003482228140000041

其中,所述第五步中,所述的环锻温度为640℃~720℃,终锻温度优选为560~590℃。芯模直径为85mm。Wherein, in the fifth step, the ring forging temperature is 640°C to 720°C, and the final forging temperature is preferably 560°C to 590°C. The mandrel diameter is 85mm.

其中,所述第六步中,旋压工艺的热处理温度为550~600℃。Wherein, in the sixth step, the heat treatment temperature of the spinning process is 550-600°C.

其中,所述第六步中,所述的旋压工艺道次变形量为10%~30%,优选10%~20%,总变形量为40~70%。Wherein, in the sixth step, the deformation amount of the spinning process is 10%-30%, preferably 10%-20%, and the total deformation amount is 40-70%.

以下采用实施例来详细说明本发明的实施方式,借此对本发明如何应用技术手段来解决技术问题,并达成技术效果的实现过程能充分理解并据以实施。Embodiments of the present invention are described in detail below by using examples, so as to fully understand and implement the implementation process of how to apply technical means to solve technical problems and achieve technical effects in the present invention.

实施例1Example 1

AgCuNiBi的银铜镍合金,按照AgCuNiBia合金成分要求配料,采用对开式纯铜铸模,在真空中频炉中熔炼成

Figure BDA0003482228140000042
圆锭。将铸锭在700℃均匀化热处理。热处理后的铸锭开坯锻造温度为750℃,终锻温度为600℃,其余火次锻造温度为670℃,终锻温度600℃,铸锭进行两次镦粗,滚圆,最终锻至高度150mm。AgCuNiBi's silver-copper-nickel alloy is prepared according to the requirements of the AgCuNiBia alloy composition. It adopts a split pure copper mold and is smelted in a vacuum intermediate frequency furnace.
Figure BDA0003482228140000042
round ingot. The ingot was homogenized and heat-treated at 700°C. The forging temperature of the ingot after heat treatment is 750°C, the final forging temperature is 600°C, the other forging temperature is 670°C, and the final forging temperature is 600°C. .

采用

Figure BDA0003482228140000043
的带锥度冲孔模具对镦粗后的铸锭进行冲孔,上下两次完成冲孔,然后依次采用
Figure BDA0003482228140000044
的带锥度模具进行扩孔,扩孔温度650℃。use
Figure BDA0003482228140000043
The taper punching die punches the upsetting ingot, completes the punching twice up and down, and then uses
Figure BDA0003482228140000044
The taper mold is expanded, and the expansion temperature is 650 ℃.

将环坯穿在直径85mm的芯模上进行环锻,道次变形量30%,每道次锻造后回炉退火。环锻温度为650℃,低于600℃时回炉退火,退火工艺:650℃保温30min。The ring blank is worn on a mandrel with a diameter of 85 mm for ring forging, and the deformation amount of each pass is 30%. After each pass of forging, it is returned to the furnace for annealing. Ring forging temperature is 650 ℃, when it is lower than 600 ℃, it is returned to furnace for annealing. Annealing process: 650 ℃ for 30 minutes.

开坯旋压采用低应变量开坯旋压,芯模直径为195.8mm,道次变形量为10%,每两道次旋压后,退火处理再旋压,累计变形量55%,退火热处理制度为550℃/1h,制成内径为196mm,外径为203mm的汇流环管。The billet spinning adopts low-strain billet spinning, the diameter of the mandrel is 195.8mm, and the deformation amount of each pass is 10%. After every two passes of spinning, annealing treatment and then spinning, the cumulative deformation amount is 55%, and the annealing heat treatment The temperature is 550℃/1h, and the inner diameter is 196mm and the outer diameter is 203mm.

去除旋压后的合金管的压余,按照240mm长度线切割,制成汇流环管。所长制备的银铜镍合金环椭圆度小于0.5mm,不直度小于0.1mm,显微硬度大于150HV,电阻率2.7μΩ·cm,符合雷达系统对汇流环的要求。Remove the excess pressure of the alloy tube after spinning, and cut it according to the length of 240mm to make a confluence ring tube. The ellipticity of the silver-copper-nickel alloy ring prepared by the director is less than 0.5mm, the non-straightness is less than 0.1mm, the microhardness is more than 150HV, and the resistivity is 2.7μΩ·cm, which meets the requirements of the radar system for the bus ring.

本发明上述实施所示的方法制备银铜镍铋合金汇流环,与原有的银铜镍合金汇流环相比,如表1所示,耐磨性有明显提高。增加导电环使用时间,通过增加铋元素的含量,减少贵金属银的使用,节约原材料成本。The silver-copper-nickel-bismuth alloy bus ring is prepared by the method shown in the above implementation of the present invention, and compared with the original silver-copper-nickel alloy bus ring, as shown in Table 1, the wear resistance is significantly improved. Increase the use time of the conductive ring, reduce the use of precious metal silver by increasing the content of bismuth element, and save the cost of raw materials.

表1Table 1

相对磨损率(W)Relative wear rate (W) 银铜镍silver copper nickel 0.07-0.150.07-0.15 银铜镍铝Silver Copper Nickel Aluminum 0.05-0.100.05-0.10

所有上述的首要实施这一知识产权,并没有设定限制其他形式的实施这种新产品和/或新方法。本领域技术人员将利用这一重要信息,上述内容修改,以实现类似的执行情况。但是,所有修改或改造基于本发明新产品属于保留的权利。All of the aforementioned primary implementations of this intellectual property do not set limits to other forms of implementation of this new product and/or new method. Those skilled in the art will use this important information to modify the above to achieve a similar implementation. However, all modifications or alterations to new products based on the present invention are reserved.

以上所述,仅是本发明的较佳实施例而已,并非是对本发明作其它形式的限制,任何熟悉本专业的技术人员可能利用上述揭示的技术内容加以变更或改型为等同变化的等效实施例。但是凡是未脱离本发明技术方案内容,依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与改型,仍属于本发明技术方案的保护范围。The above are only preferred embodiments of the present invention, and are not intended to limit the present invention in other forms. Any person skilled in the art may use the technical content disclosed above to make changes or modifications to equivalent changes. Example. However, any simple modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention without departing from the content of the technical solutions of the present invention still belong to the protection scope of the technical solutions of the present invention.

Claims (9)

1.一种合金导电环,其特征在于:合金组成为铜Cu为20-21wt%、镍Ni为1-2wt%、铋Bi为0.1-1wt%、余量为Ag。1. An alloy conductive ring, characterized in that: the alloy composition is that copper Cu is 20-21 wt %, nickel Ni is 1-2 wt %, bismuth Bi is 0.1-1 wt %, and the balance is Ag. 2.如权利要求1所述合金导电环,其特征在于:所述导电环厚为2~5mm,内径为190~205mm。2 . The alloy conductive ring according to claim 1 , wherein the conductive ring has a thickness of 2-5 mm and an inner diameter of 190-205 mm. 3 . 3.权利要求1或2所述合金导电环的制作方法,其特征在于,包括:3. the manufacture method of the described alloy conductive ring of claim 1 or 2, is characterized in that, comprises: 第一步,将银、铜、镍、和铋材料真空中频炉熔炼,获得铸锭;The first step is to smelt silver, copper, nickel, and bismuth materials in a vacuum intermediate frequency furnace to obtain an ingot; 第二步,将铸锭进行均匀化热处理;In the second step, the ingot is subjected to homogenization heat treatment; 第三步,将第二步获得的产物进行锻造处理;The third step is to forge the product obtained in the second step; 第四步,将第三步获得的产物进行扩孔处理;In the fourth step, the product obtained in the third step is subjected to hole reaming treatment; 第五步,将第四步获得的产物进行环锻处理,制成管坯;In the fifth step, the product obtained in the fourth step is subjected to ring forging treatment to make a tube blank; 第六步,将管坯经旋压处理;The sixth step is to spin the tube blank; 第七步,将第六步获得产物进行热处理,制成合金管;In the seventh step, the product obtained in the sixth step is subjected to heat treatment to make an alloy tube; 第八步,根据需要进行切割。The eighth step is to cut as needed. 4.如权利要求3所述合金导电环的制作方法,其特征在于:所述第二步中均匀化热处理的退火温度为700℃~800℃,保温时间为100-200min。4 . The method for manufacturing an alloy conductive ring according to claim 3 , wherein the annealing temperature of the homogenizing heat treatment in the second step is 700° C. to 800° C., and the holding time is 100-200 min. 5 . 5.如权利要求3或4所述合金导电环的制作方法,其特征在于:所述第三步中,所述的开坯始锻温度为700℃~800℃,终锻温度为550℃~650℃,其余火次的始锻温度为650~700℃,终锻温度为600℃。5. The method for making an alloy conductive ring according to claim 3 or 4, wherein in the third step, the initial forging temperature of the blank is 700°C to 800°C, and the final forging temperature is 550°C to 550°C. 650°C, the initial forging temperature of the remaining fires is 650-700°C, and the final forging temperature is 600°C. 6.如权利要求3或4所述合金导电环的制作方法,其特征在于:所述第四步中,扩孔温度为640℃~720℃,所采用的扩孔模具的直径为
Figure FDA0003482228130000011
Figure FDA0003482228130000012
6. The method for making an alloy conductive ring according to claim 3 or 4, wherein in the fourth step, the hole expanding temperature is 640°C to 720°C, and the diameter of the hole expanding die used is
Figure FDA0003482228130000011
Figure FDA0003482228130000012
7.如权利要求3或4所述合金导电环的制作方法,其特征在于:所述第五步中,所述的环锻温度为640℃~720℃,终锻温度为560~590℃。7 . The method for manufacturing an alloy conductive ring according to claim 3 , wherein in the fifth step, the ring forging temperature is 640°C to 720°C, and the final forging temperature is 560°C to 590°C. 8 . 8.如权利要求3或4所述合金导电环的制作方法,其特征在于:所述第六步中,旋压工艺的热处理温度为550~600℃。8 . The manufacturing method of the alloy conductive ring according to claim 3 or 4 , wherein in the sixth step, the heat treatment temperature of the spinning process is 550-600° C. 9 . 9.如权利要求3或4所述合金导电环的制作方法,其特征在于:所述第六步中,所述的旋压工艺道次变形量为10%~30%,总变形量为40~70%。9. The manufacturing method of the alloy conductive ring according to claim 3 or 4, wherein in the sixth step, the deformation amount of the spinning process is 10% to 30%, and the total deformation amount is 40%. ~70%.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5171643A (en) * 1989-08-02 1992-12-15 The Furukawa Electric Co., Ltd. Electric contact material and electric contact using said material
US20100263769A1 (en) * 2004-06-02 2010-10-21 Middlesex Silver Co. Limited Process for making finished or semi-finished articles of silver alloy
CN109396761A (en) * 2018-11-05 2019-03-01 北京翠铂林有色金属技术开发中心有限公司 A kind of production method of major diameter silver-bearing copper nickel alloy conducting ring
CN111069497A (en) * 2019-12-31 2020-04-28 有研亿金新材料有限公司 Preparation method of high-hardness silver-copper-nickel alloy conducting ring

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5171643A (en) * 1989-08-02 1992-12-15 The Furukawa Electric Co., Ltd. Electric contact material and electric contact using said material
US20100263769A1 (en) * 2004-06-02 2010-10-21 Middlesex Silver Co. Limited Process for making finished or semi-finished articles of silver alloy
CN109396761A (en) * 2018-11-05 2019-03-01 北京翠铂林有色金属技术开发中心有限公司 A kind of production method of major diameter silver-bearing copper nickel alloy conducting ring
CN111069497A (en) * 2019-12-31 2020-04-28 有研亿金新材料有限公司 Preparation method of high-hardness silver-copper-nickel alloy conducting ring

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