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CN114609049B - A microsecond fast-axis adjustable photoelastic modulation ultra-high-speed generalized ellipsometric measurement device - Google Patents

A microsecond fast-axis adjustable photoelastic modulation ultra-high-speed generalized ellipsometric measurement device Download PDF

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CN114609049B
CN114609049B CN202210242500.0A CN202210242500A CN114609049B CN 114609049 B CN114609049 B CN 114609049B CN 202210242500 A CN202210242500 A CN 202210242500A CN 114609049 B CN114609049 B CN 114609049B
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axis adjustable
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CN114609049A (en
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张瑞
齐姣
薛鹏
易进
王志斌
李孟委
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North University of China
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/21Polarisation-affecting properties
    • G01N21/211Ellipsometry
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01Arrangements or apparatus for facilitating the optical investigation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/21Polarisation-affecting properties
    • G01N21/211Ellipsometry
    • G01N2021/214Variangle incidence arrangement

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Abstract

The invention belongs to the technical field of ellipsometry measuring devices, and particularly relates to a microsecond-level fast axis adjustable elasto-optical modulation ultra-high-speed generalized ellipsometry measuring device which comprises a polarization arm, a polarization detection arm and a sample table, wherein the polarization detection arm and the sample table are sequentially arranged in the light path direction of the polarization detection arm; the polarizing arm comprises a light source, a polarizer and a first fast axis adjustable circular elastic-optical modulator, wherein the polarizer and the first fast axis adjustable circular elastic-optical modulator are sequentially arranged in the light path direction of the light source, and a sample table is arranged in the light path direction of the first fast axis adjustable circular elastic-optical modulator. The ellipsometry method adopted by the invention has the advantages of single measurement, high measurement precision, simple calibration, wide spectrum range and the like. Compared with the mechanical rotation speed, the measuring device provided by the invention can be improved by 3-4 orders of magnitude, and the adopted 45-degree dual-drive fast-axis adjustable circular elasto-optical modulator has the advantages of wide spectrum range, high modulation speed, high stability and the like.

Description

一种微秒级快轴可调弹光调制超高速广义椭偏测量装置A microsecond fast-axis adjustable photoelastic modulation ultra-high-speed generalized ellipsometric measurement device

技术领域Technical Field

本发明属于椭偏测量装置技术领域,具体涉及一种微秒级快轴可调弹光调制超高速广义椭偏测量装置。The invention belongs to the technical field of ellipsometric measurement devices, and in particular relates to a microsecond-level fast-axis adjustable photoelastic modulation ultra-high-speed generalized ellipsometric measurement device.

背景技术Background Art

随着微电子、光学镀膜、平板显示,及纳米生物和新材料技术等高新技术领域的发展,高精度椭偏薄膜技术成为该领域检测的重要手段。椭偏测量技术是一种多功能光学测量技术,通过测量偏振光入射待测物前后偏振态的变化获取其光学常数(折射率n,消光系数k)、膜结构及厚度等参数。现有椭偏测量技术主要有穆勒矩阵部分元素椭偏测量和全穆勒矩阵广义椭偏测量两种方式:穆勤矩阵部分元素椭偏测量系统仅能测量部分穆勒矩阵,因不能获取完整的样品信息,可适用于非退偏或者各向同性样品的测量;全穆勒矩阵广义椭偏测量系统能测量全部的穆勒矩阵,适用于各种样品测量。With the development of high-tech fields such as microelectronics, optical coatings, flat panel displays, nano-biology and new materials technology, high-precision ellipsometric thin film technology has become an important means of detection in this field. Ellipsometry measurement technology is a multifunctional optical measurement technology that obtains its optical constants (refractive index n, extinction coefficient k), film structure and thickness parameters by measuring the change in polarization state before and after the polarized light is incident on the object to be measured. Existing ellipsometric measurement technologies mainly include Mueller matrix partial element ellipsometric measurement and full Mueller matrix generalized ellipsometric measurement. The Mueller matrix partial element ellipsometric measurement system can only measure part of the Mueller matrix. Because it cannot obtain complete sample information, it is suitable for the measurement of non-depolarized or isotropic samples; the full Mueller matrix generalized ellipsometric measurement system can measure the entire Mueller matrix and is suitable for various sample measurements.

广义椭偏测量技术每次测量可获得穆勒矩阵的所有16个元素,从而能够提供更多有用的待测信息,如结构参数、各向异性和去极化。与扫描电子显微镜和透射电子显微镜技术相比,广义椭偏测量技术可无损测得物理和结构特性,因此广义椭偏已应用于微电子、光学镀膜、平板显示和光伏太阳能电池等行业,并逐渐拓展应用于生物分子互作用、原子沉积、分子自组装、材料相变等物理过程观测,在薄膜检测、材料表征、纳米结构计量、生物医学等高新技术领域也展现出巨大应用潜力。随着微电子在线原位检测、捕捉材料物理生物瞬态机制变化过程等对高速测量要求,测量的时间分辨率需要至少在亚毫秒级,甚至微秒量级;但传统广义椭偏测量技术是基于机械旋转补偿器,时间分辨率在秒级,时间分辨率相差2~3数量级。因此,发展微秒级超高速广义椭偏技术对复杂快速过程的实时原位检测具有重要意义。Generalized ellipsometry can obtain all 16 elements of the Mueller matrix in each measurement, thus providing more useful information to be measured, such as structural parameters, anisotropy and depolarization. Compared with scanning electron microscopy and transmission electron microscopy, generalized ellipsometry can measure physical and structural properties non-destructively. Therefore, generalized ellipsometry has been applied to industries such as microelectronics, optical coating, flat panel display and photovoltaic solar cells, and has gradually expanded its application to physical process observations such as biomolecular interactions, atomic deposition, molecular self-assembly, and material phase changes. It also shows great application potential in high-tech fields such as thin film detection, material characterization, nanostructure metrology, and biomedicine. With the requirements for high-speed measurement in microelectronics online in-situ detection and capturing the physical and biological transient mechanism changes of materials, the time resolution of the measurement needs to be at least sub-millisecond level, or even microsecond level; but the traditional generalized ellipsometry measurement technology is based on a mechanical rotary compensator, with a time resolution of seconds, which is 2 to 3 orders of magnitude different. Therefore, the development of microsecond-level ultra-high-speed generalized ellipsometry technology is of great significance for real-time in-situ detection of complex and fast processes.

现有的基于相位调制器的广义椭偏测量中,液晶相位调制器和电光相位调制器虽然相位可通过改变电压实现调节,但其快轴方向只能通过机械旋转实现,测量速度受限,且光谱适用范围很窄;由于弹光调制具有光谱范围宽(紫外到远红外)、调制速率高(数十kHz至数百kHz)、稳定性好(工作在谐振状态)等优点,使其在高精度偏振测量中广泛被应用,但现有弹光调制主要都工作在纯驻波模式下,无法实现快轴方向的高速调制。In the existing generalized ellipsometric measurement based on phase modulators, although the phase of liquid crystal phase modulators and electro-optic phase modulators can be adjusted by changing the voltage, the fast axis direction can only be achieved by mechanical rotation, the measurement speed is limited, and the spectral application range is very narrow; due to the advantages of elastic-photoelastic modulation such as wide spectral range (ultraviolet to far infrared), high modulation rate (tens of kHz to hundreds of kHz), and good stability (working in a resonant state), it is widely used in high-precision polarization measurement, but the existing elastic-photoelastic modulation mainly works in pure standing wave mode and cannot achieve high-speed modulation in the fast axis direction.

发明内容Summary of the invention

针对上述双旋转补偿器广义椭偏测量速度慢的技术问题,本发明提供了一种微秒级快轴可调弹光调制超高速广义椭偏测量装置,该装置采用一种45°双驱动快轴可调圆形弹光调制器,可在纯行波模式下实现超高速快轴可调弹光调制,较机械旋转速度可提高3-4个数量级,将极大提高广义椭偏测量的时间分辨率。In order to solve the technical problem of slow generalized ellipsometric measurement speed of the above-mentioned dual-rotation compensator, the present invention provides a microsecond-level fast-axis adjustable photoelastic modulation ultra-high-speed generalized ellipsometric measurement device. The device adopts a 45° dual-drive fast-axis adjustable circular photoelastic modulator, which can realize ultra-high-speed fast-axis adjustable photoelastic modulation in pure traveling wave mode, and can increase the speed by 3-4 orders of magnitude compared with the mechanical rotation speed, which will greatly improve the time resolution of generalized ellipsometric measurement.

为了解决上述技术问题,本发明采用的技术方案为:In order to solve the above technical problems, the technical solution adopted by the present invention is:

一种微秒级快轴可调弹光调制超高速广义椭偏测量装置,包括起偏臂、检偏臂和样本台,所述起偏臂的光路方向上依次设置有检偏臂、样本台;所述起偏臂包括光源、起偏器和第一快轴可调圆形弹光调制器,所述光源的光路方向上依次设置有起偏器、第一快轴可调圆形弹光调制器,所述第一快轴可调圆形弹光调制器的光路方向上设置有样本台。A microsecond fast-axis adjustable elastic-light modulation ultra-high-speed generalized ellipsometric measurement device comprises a polarizing arm, an analyzing arm and a sample stage, wherein the analyzing arm and the sample stage are sequentially arranged in the optical path direction of the polarizing arm; the polarizing arm comprises a light source, a polarizer and a first fast-axis adjustable circular elastic-light modulator, wherein the polarizer and the first fast-axis adjustable circular elastic-light modulator are sequentially arranged in the optical path direction of the light source, and the sample stage is arranged in the optical path direction of the first fast-axis adjustable circular elastic-light modulator.

所述检偏臂包括探测器、检偏器和第二快轴可调圆形弹光调制器,所述第二快轴可调圆形弹光调制器的光路方向上依次设置有检偏器、探测器,所述第二快轴可调圆形弹光调制器设置在样本台的光路方向上。The polarization analyzer arm includes a detector, an analyzer and a second fast-axis adjustable circular light-elastic modulator. The polarization analyzer and the detector are arranged in sequence in the light path direction of the second fast-axis adjustable circular light-elastic modulator. The second fast-axis adjustable circular light-elastic modulator is arranged in the light path direction of the sample stage.

所述第一快轴可调圆形弹光调制器和第二快轴可调圆形弹光调制器均包括通光晶体、第一压电驱动器和第二压电驱动器,所述通光晶体分别与第一压电驱动器和第二压电驱动器连接。The first fast-axis adjustable circular light-elastic modulator and the second fast-axis adjustable circular light-elastic modulator both include a light-transmitting crystal, a first piezoelectric driver and a second piezoelectric driver, and the light-transmitting crystal is connected to the first piezoelectric driver and the second piezoelectric driver, respectively.

所述通光晶体采用圆形结构,所述通光晶体采用熔融石英,所述通光晶体的通光范围为185nm-3500nm。The light-transmitting crystal adopts a circular structure, the light-transmitting crystal adopts fused quartz, and the light-transmitting range of the light-transmitting crystal is 185nm-3500nm.

所述第一压电驱动器与第二压电驱动器之间的夹角为45°。The included angle between the first piezoelectric driver and the second piezoelectric driver is 45°.

所述光源采用光谱范围宽193nm-3200nm的复色光源及单色仪。The light source adopts a complex light source and a monochromator with a wide spectrum range of 193nm-3200nm.

所述第一压电驱动器和第二压电驱动器均采用压电α-石英晶体。The first piezoelectric driver and the second piezoelectric driver both use piezoelectric α-quartz crystals.

所述探测器包括紫外高速光电倍增管、硅基高速光电探测器和InAsSb光电探测器,所述紫外高速光电倍增管探测紫外波段,所述硅基高速光电探测器探测可见近红外波段,所述InAsSb光电探测器探测近红外短波红外波段。The detector includes an ultraviolet high-speed photomultiplier tube, a silicon-based high-speed photodetector and an InAsSb photodetector. The ultraviolet high-speed photomultiplier tube detects the ultraviolet band, the silicon-based high-speed photodetector detects the visible near-infrared band, and the InAsSb photodetector detects the near-infrared and short-wave infrared band.

所述第一压电驱动器与第二压电驱动器均设置在通光晶体形成应力驻波的波节位置,所述第一压电驱动器与第二压电驱动器的工作频率一致。The first piezoelectric driver and the second piezoelectric driver are both arranged at the node position of the stress standing wave formed in the light-transmitting crystal, and the working frequency of the first piezoelectric driver and the second piezoelectric driver are consistent.

所述检偏臂和样本台的底部均固定有旋转台,每个所述旋转台均连接有步进电机。A rotating platform is fixed at the bottom of the analysis arm and the sample platform, and each rotating platform is connected to a stepping motor.

本发明与现有技术相比,具有的有益效果是:Compared with the prior art, the present invention has the following beneficial effects:

本发明旨在解决现有机械旋转补偿器速率慢、相位调制器快轴方向不可调、广义椭偏测量系统复杂等问题,最终实现新型微秒级快轴可调弹光调制型超高速广义椭偏测量,为复杂快速实时原位检测提供理论及技术支撑。本发明采用的椭偏测量方法具有单次测量、测量精度高、标定简单、光谱范围宽等优点。本发明提出的测量装置,较机械旋转速度可提高3-4个数量级,采用的45°双驱动快轴可调圆形弹光调制器具有光谱范围宽、调制速度快、稳定性高等优质的偏振调制性能。本发明可用于微电子、光学镀膜、平板显示和光伏太阳能电池等生产线的高精度实时在线检测,也可用于生物科学、材料表征等高新技术领域物理生物瞬态机制变化过程的测量。The present invention aims to solve the problems of slow speed of existing mechanical rotation compensators, unadjustable fast axis direction of phase modulators, and complex generalized ellipsometric measurement systems, and finally realize a new type of microsecond fast axis adjustable photoelastic modulation type ultra-high-speed generalized ellipsometric measurement, providing theoretical and technical support for complex and fast real-time in-situ detection. The ellipsometric measurement method adopted by the present invention has the advantages of single measurement, high measurement accuracy, simple calibration, and wide spectral range. The measuring device proposed in the present invention can increase the mechanical rotation speed by 3-4 orders of magnitude, and the 45° dual-drive fast axis adjustable circular photoelastic modulator adopted has high-quality polarization modulation performance such as wide spectral range, fast modulation speed, and high stability. The present invention can be used for high-precision real-time online detection of production lines such as microelectronics, optical coatings, flat panel displays, and photovoltaic solar cells, and can also be used for the measurement of physical and biological transient mechanism change processes in high-tech fields such as biological sciences and material characterization.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

为了更清楚地说明本发明的实施方式或现有技术中的技术方案,下面将对实施方式或现有技术描述中所需要使用的附图作简单地介绍。显而易见地,下面描述中的附图仅仅是示例性的,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据提供的附图引申获得其它的实施附图。In order to more clearly illustrate the implementation methods of the present invention or the technical solutions in the prior art, the following briefly introduces the drawings required for the implementation methods or the description of the prior art. Obviously, the drawings in the following description are only exemplary, and for ordinary technicians in this field, other implementation drawings can be derived from the provided drawings without creative work.

本说明书所绘示的结构、比例、大小等,均仅用以配合说明书所揭示的内容,以供熟悉此技术的人士了解与阅读,并非用以限定本发明可实施的限定条件,故不具技术上的实质意义,任何结构的修饰、比例关系的改变或大小的调整,在不影响本发明所能产生的功效及所能达成的目的下,均应仍落在本发明所揭示的技术内容能涵盖的范围内。The structures, proportions, sizes, etc. illustrated in this specification are only used to match the contents disclosed in the specification so as to facilitate understanding and reading by persons familiar with the technology. They are not used to limit the conditions under which the present invention can be implemented, and therefore have no substantial technical significance. Any structural modification, change in proportion or adjustment of size shall still fall within the scope of the technical contents disclosed in the present invention without affecting the effects and purposes that can be achieved by the present invention.

图1为本发明在透射状态下的结构示意图;FIG1 is a schematic diagram of the structure of the present invention in a transmission state;

图2为本发明在反射状态下的结构示意图;FIG2 is a schematic diagram of the structure of the present invention in a reflection state;

图3为本发明快轴可调圆形弹光调制器的结构示意图。FIG. 3 is a schematic structural diagram of a fast-axis adjustable circular elastic light modulator according to the present invention.

其中:1为起偏臂,1-1为光源,1-2为起偏器,1-3为第一快轴可调圆形弹光调制器,2为检偏臂,2-1为探测器,2-2为检偏器,2-3为第二快轴可调圆形弹光调制器,3为样品台,4为通光晶体,5-1为第一压电驱动器,5-2为第一压电驱动器。Among them: 1 is the polarizing arm, 1-1 is the light source, 1-2 is the polarizer, 1-3 is the first fast-axis adjustable circular elastic modulator, 2 is the analyzer arm, 2-1 is the detector, 2-2 is the analyzer, 2-3 is the second fast-axis adjustable circular elastic modulator, 3 is the sample stage, 4 is the light-transmitting crystal, 5-1 is the first piezoelectric driver, and 5-2 is the first piezoelectric driver.

具体实施方式DETAILED DESCRIPTION

为使本发明实施例的目的、技术方案和优点更加清楚,下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例,这些描述只是为进一步说明本发明的特征和优点,而不是对本发明权利要求的限制;基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purpose, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. Obviously, the described embodiments are only part of the embodiments of the present application, rather than all the embodiments. These descriptions are only to further illustrate the features and advantages of the present invention, rather than to limit the claims of the present invention. Based on the embodiments in the present application, all other embodiments obtained by ordinary technicians in this field without making creative work are within the scope of protection of this application.

下面结合附图和实施例,对本发明的具体实施方式做进一步详细描述。以下实施例用于说明本发明,但不用来限制本发明的范围。The specific implementation of the present invention is further described in detail below in conjunction with the accompanying drawings and examples. The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention.

术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本申请的描述中,除非另有说明,“多个”的含义是两个或两个以上。The terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of the features. In the description of this application, unless otherwise specified, "plurality" means two or more.

在本申请的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体的连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本申请中的具体含义。In the description of this application, it should be noted that, unless otherwise clearly specified and limited, the terms "installed", "connected", and "connected" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or it can be indirectly connected through an intermediate medium, or it can be the internal communication of two components. For ordinary technicians in this field, the specific meanings of the above terms in this application can be understood according to specific circumstances.

实施例一Embodiment 1

本发明装置的整体结构如图1、图2所示,分别为椭偏测量的透射式、反射式装置。该结构主要由三部分组成:一条起偏臂1和一条检偏臂2以及样本台3。其中起偏臂1包含了光源1-1、起偏器1-2、第一快轴可调圆形弹光调制器1-3。检偏臂2包含了探测器2-1、检偏器2-2、第二快轴可调圆形弹光调制器2-3。中间位置处的样本台3是样品放置区域,用来放置待测薄膜及纳米结构。本装置中光源1-1发出的光束通过各个光学元件的顺序为起偏器1-2到第一快轴可调圆形弹光调制器1-3到样本台3到第二快轴可调圆形弹光调制器2-3到检偏器2-2,最终被探测器2-1接收并进行数据处理,从而获取得到待测样品的信息。The overall structure of the device of the present invention is shown in Figures 1 and 2, which are respectively transmission and reflection devices for ellipsometric measurement. The structure is mainly composed of three parts: a polarizing arm 1, an analyzing arm 2 and a sample stage 3. The polarizing arm 1 includes a light source 1-1, a polarizer 1-2, and a first fast-axis adjustable circular elastic light modulator 1-3. The analyzing arm 2 includes a detector 2-1, an analyzer 2-2, and a second fast-axis adjustable circular elastic light modulator 2-3. The sample stage 3 at the middle position is a sample placement area for placing the film and nanostructure to be tested. In this device, the light beam emitted by the light source 1-1 passes through the various optical elements in the order of the polarizer 1-2 to the first fast-axis adjustable circular elastic light modulator 1-3 to the sample stage 3 to the second fast-axis adjustable circular elastic light modulator 2-3 to the analyzer 2-2, and is finally received by the detector 2-1 and data processing is performed, thereby obtaining the information of the sample to be tested.

传统二维弹光调制器的快轴方向不可调节,弹光晶体采用八角结构;但本发明中需要对弹光调制器的快轴方向进行高速调制,由于圆形比八角结构对称性更好,因此采用圆形结构有助于快轴方向的调节。本发明中使用的45°双驱动的第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3结构如图3所示,主要包含通光晶体4和两个空间角度相隔45°的第一压电驱动器5-1、第二压电驱动器5-2。当第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3的第一压电驱动器5-1、第二压电驱动器5-2施加与弹光调制器谐振频率一致的正弦交流驱动电压时,第一压电驱动器5-1、第二压电驱动器5-2作长度伸缩振动,并驱动通光晶体4振动实现谐振工作。弹光调制器1-3/2-3谐振时,在通光晶体4中形成应力驻波,由于弹光效应,使其相位、快轴方向发生改变。压电驱动器5-1在通光晶体4中形成应力驻波的波节位置,即与压电驱动器5-1相距45°的空间位置上引入与第一压电驱动器5-1工作频率一致的压电驱动器5-2,使第一压电驱动器5-1、第二压电驱动器5-2在通光晶体4上呈对称分布,构成由第一压电驱动器5-1、第二压电驱动器5-2空间分布成45°的第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3结构。这样便能够使第一压电驱动器5-1、第二压电驱动器5-2均连接在彼此驱动通光晶体4工作的波节位置处,对彼此的通光晶体4中的应力驻波干扰最小,从而实现稳定的调制工作。The fast axis direction of the traditional two-dimensional elastic light modulator cannot be adjusted, and the elastic light crystal adopts an octagonal structure; however, in the present invention, the fast axis direction of the elastic light modulator needs to be modulated at high speed. Since the circular structure has better symmetry than the octagonal structure, the circular structure is helpful for adjusting the fast axis direction. The structure of the 45° dual-driven first fast-axis adjustable circular elastic light modulator 1-3 and the second fast-axis adjustable circular elastic light modulator 2-3 used in the present invention is shown in Figure 3, and mainly includes a light-transmitting crystal 4 and two first piezoelectric drivers 5-1 and second piezoelectric drivers 5-2 separated by 45° in space angle. When the first piezoelectric driver 5-1 and the second piezoelectric driver 5-2 of the first fast-axis adjustable circular elastic light modulator 1-3 and the second fast-axis adjustable circular elastic light modulator 2-3 apply a sinusoidal AC driving voltage consistent with the resonant frequency of the elastic light modulator, the first piezoelectric driver 5-1 and the second piezoelectric driver 5-2 perform length expansion and contraction vibrations, and drive the light-transmitting crystal 4 to vibrate to achieve resonance. When the elastic light modulator 1-3/2-3 resonates, a stress standing wave is formed in the transparent crystal 4, and its phase and fast axis direction are changed due to the elastic light effect. The piezoelectric driver 5-1 introduces a piezoelectric driver 5-2 with the same working frequency as the first piezoelectric driver 5-1 at the node position where the stress standing wave is formed in the transparent crystal 4, that is, at a spatial position 45° away from the piezoelectric driver 5-1, so that the first piezoelectric driver 5-1 and the second piezoelectric driver 5-2 are symmetrically distributed on the transparent crystal 4, forming a first fast-axis adjustable circular elastic light modulator 1-3 and a second fast-axis adjustable circular elastic light modulator 2-3 structure composed of the first piezoelectric driver 5-1 and the second piezoelectric driver 5-2 spatially distributed at 45°. In this way, the first piezoelectric driver 5-1 and the second piezoelectric driver 5-2 can be connected to each other at the node position where they drive the transparent crystal 4 to work, and the interference of the stress standing waves in each other's transparent crystal 4 is minimized, thereby achieving stable modulation work.

为了实现不同角度、透射/反射测量要求,检测臂2和样本台3可以旋转。起偏臂1和检偏臂2中第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3的快轴以恒定的转速比连续旋转,可实现纯驻波和纯行波两种工作模式:其中纯驻波工作模式下弹光调制在固定驱动电压幅值和相位时的快轴方向是固定的,但快轴方向可通过驱动幅值和相位进行任意方向调节;纯行波工作模式下可实现快轴方向高速调制(数十kHz),且可通过驱动电压调节实现任意相位延迟调制。In order to achieve different angles and transmission/reflection measurement requirements, the detection arm 2 and the sample stage 3 can rotate. The fast axes of the first fast-axis adjustable circular photoelastic modulator 1-3 and the second fast-axis adjustable circular photoelastic modulator 2-3 in the polarizing arm 1 and the analyzing arm 2 rotate continuously at a constant speed ratio, and two working modes of pure standing wave and pure traveling wave can be realized: in the pure standing wave working mode, the fast axis direction of the photoelastic modulation is fixed when the driving voltage amplitude and phase are fixed, but the fast axis direction can be adjusted in any direction through the driving amplitude and phase; in the pure traveling wave working mode, high-speed modulation (tens of kHz) in the fast axis direction can be achieved, and arbitrary phase delay modulation can be achieved through driving voltage adjustment.

实施例二Embodiment 2

本发明的装置用于测量薄膜厚度、光学常数等信息。具体实施如下:The device of the present invention is used to measure information such as film thickness and optical constants. The specific implementation is as follows:

本发明装置的主要结构包括起偏臂1、检偏臂2、样品台3。起偏臂1主要是对经过单色仪后的不同波长入射光进行偏振态调制,其中光源1-1选择光谱范围宽193nm-3200nm的复色光源及单色仪。检偏臂2主要是对不同波长偏振态调制后经过样品的光偏振态进行探测分析,其中探测器2-1可通过分三段来实现宽光谱探测:紫外波段采用紫外高速光电倍增管,可见近红外波段采用硅基高速光电探测器,近红外短波红外波段采用InAsSb光电探测器。The main structure of the device of the present invention includes a polarizing arm 1, an analyzing arm 2, and a sample stage 3. The polarizing arm 1 is mainly used to modulate the polarization state of incident light of different wavelengths after passing through a monochromator, wherein the light source 1-1 selects a polychromatic light source and a monochromator with a wide spectral range of 193nm-3200nm. The analyzing arm 2 is mainly used to detect and analyze the polarization state of light passing through the sample after polarization state modulation of different wavelengths, wherein the detector 2-1 can realize wide spectrum detection by dividing into three sections: ultraviolet high-speed photomultiplier tubes are used in the ultraviolet band, silicon-based high-speed photodetectors are used in the visible near-infrared band, and InAsSb photodetectors are used in the near-infrared and short-wave infrared bands.

第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3的结构如图3所示,通光晶体4采用熔融石英,其最佳通光范围为185nm-3500nm,可覆盖光谱范围;第一压电驱动器5-1和第二压电驱动器5-2选择压电α-石英晶体,其具有频带很窄、高纯度、特定切型的振动模态单一、热效应可通过切型选择有效降低等特点。当给第一压电驱动器5-1和第二压电驱动器5-2施加电压V=V0sin2πft时(V0为驱动电压幅值,f为压电驱动频率),第一压电驱动器5-1和第二压电驱动器5-2在通光晶体4中引入的应力满足驻波解,因此可将驱动器5-1和5-2引入的应力驻波分解为顺时针和逆时针方向的两个行波叠加。在纯行波模式下,第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3能够实现快轴方位角作圆周运动的偏振调制,旋转方向由两驱动之间相位差决定。其中,相位延迟量为一常量,并且与驱动电压幅值成正比。因此纯行波模式下,第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3实现了类似旋转补偿器的偏振调制,但是该偏振调制模式下无机械旋转,快轴方向调制频率远高于机械旋转频率,并且相位延迟量能够通过给第一压电驱动器5-1和第二压电驱动器5-2施加的驱动电压幅值灵活调节。The structures of the first fast-axis adjustable circular elastic modulator 1-3 and the second fast-axis adjustable circular elastic modulator 2-3 are shown in FIG3 . The transparent crystal 4 is made of fused quartz, and its optimal transparent range is 185nm-3500nm, which can cover the spectral range. The first piezoelectric driver 5-1 and the second piezoelectric driver 5-2 are selected from piezoelectric α-quartz crystals, which have the characteristics of very narrow frequency band, high purity, single vibration mode of specific cut type, and thermal effect can be effectively reduced by cutting type selection. When the voltage V=V 0 sin2πft is applied to the first piezoelectric driver 5-1 and the second piezoelectric driver 5-2 (V 0 is the driving voltage amplitude, and f is the piezoelectric driving frequency), the stress introduced by the first piezoelectric driver 5-1 and the second piezoelectric driver 5-2 in the transparent crystal 4 satisfies the standing wave solution, so the stress standing wave introduced by the drivers 5-1 and 5-2 can be decomposed into two traveling waves superimposed in the clockwise and counterclockwise directions. In the pure traveling wave mode, the first fast-axis adjustable circular light-elastic modulator 1-3 and the second fast-axis adjustable circular light-elastic modulator 2-3 can realize polarization modulation of the fast-axis azimuth in circular motion, and the rotation direction is determined by the phase difference between the two drives. Among them, the phase delay amount is a constant and is proportional to the driving voltage amplitude. Therefore, in the pure traveling wave mode, the first fast-axis adjustable circular light-elastic modulator 1-3 and the second fast-axis adjustable circular light-elastic modulator 2-3 realize polarization modulation similar to the rotation compensator, but in this polarization modulation mode, there is no mechanical rotation, the fast-axis direction modulation frequency is much higher than the mechanical rotation frequency, and the phase delay amount can be flexibly adjusted by the driving voltage amplitude applied to the first piezoelectric driver 5-1 and the second piezoelectric driver 5-2.

整个装置系统需要协同控制,光源1-1发出的光束通过各个光学元件的顺序为起偏器1-2到快轴可调圆形弹光调制器1-3到样本台3到快轴可调圆形弹光调制器2-3到检偏器2-2,最终被探测器2-1接收,并且根据测得数据进行处理,获得被测膜厚、光学参数等信息。若以斯托克斯向量描述偏振光束,穆勒矩阵描述光学元件和被测薄膜及微纳结构,则离开检偏器2-2光束的斯托克斯向量Sout可表示为穆勒矩阵相乘的形式:The entire device system needs to be controlled in a coordinated manner. The order of the light beam emitted by the light source 1-1 passing through each optical element is polarizer 1-2 to fast-axis adjustable circular elastic light modulator 1-3 to sample stage 3 to fast-axis adjustable circular elastic light modulator 2-3 to analyzer 2-2, and finally received by detector 2-1. The measured data is processed to obtain information such as the measured film thickness and optical parameters. If the Stokes vector is used to describe the polarized light beam, and the Mueller matrix is used to describe the optical element and the measured film and micro-nano structure, the Stokes vector S out of the light beam leaving the analyzer 2-2 can be expressed as the multiplication of the Mueller matrix:

其中,MP、MPEM1、MS、MPEM2和MA分别表示起偏器1-2、第一快轴可调圆形弹光调制器1-3、样品、第二快轴可调圆形弹光调制器2-3和检偏器2-2的穆勒矩阵,δ1和δ2分别表示第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3的相位延迟量。由于各个光学元件的光轴方向都不相同,方程(1)中使用了穆勒旋转矩阵R(θ)将它们统一到入射面所在的参考系中,角度θ=P、A、PEM1、PEM2分别对应起偏器1-2、检偏器2-2、第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3的光轴方位角。Wherein, MP , MPEM1 , MS , MPEM2 and MA respectively represent the Mueller matrices of the polarizer 1-2, the first fast-axis adjustable circular elastic light modulator 1-3, the sample, the second fast-axis adjustable circular elastic light modulator 2-3 and the analyzer 2-2, δ1 and δ2 respectively represent the phase delay of the first fast-axis adjustable circular elastic light modulator 1-3 and the second fast-axis adjustable circular elastic light modulator 2-3. Since the optical axis directions of each optical element are different, the Mueller rotation matrix R(θ) is used in equation (1) to unify them into the reference system where the incident surface is located, and the angle θ=P, A, PEM1, PEM2 respectively correspond to the optical axis azimuth angles of the polarizer 1-2, the analyzer 2-2, the first fast-axis adjustable circular elastic light modulator 1-3 and the second fast-axis adjustable circular elastic light modulator 2-3.

第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3以恒定的转速比f1:f2=pf0:qf0连续转动,其中f0为基频(f0=20kHz),第一快轴可调圆形弹光调制器1-3光轴方位角可表示为和第二快轴可调圆形弹光调制器2-3光轴方位角可表示其中分别表示快轴可调圆形弹光调制器1-3和2-3的初始快轴方位角。第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3的转速比取pf0:qf0=5:3。The first fast-axis adjustable circular light elastic modulator 1-3 and the second fast-axis adjustable circular light elastic modulator 2-3 rotate continuously at a constant speed ratio f 1 :f 2 =pf 0 :qf 0 , where f 0 is the base frequency (f 0 =20kHz). The optical axis azimuth of the first fast-axis adjustable circular light elastic modulator 1-3 can be expressed as The azimuth angle of the optical axis of the second fast-axis adjustable circular elastic light modulator 2-3 can be expressed as in and They represent the initial fast axis azimuths of the fast axis adjustable circular light elastic modulators 1-3 and 2-3 respectively. The rotation speed ratio of the first fast axis adjustable circular light elastic modulator 1-3 and the second fast axis adjustable circular light elastic modulator 2-3 is pf 0 :qf 0 =5:3.

一般来说,入射起偏器1-2的光线为非偏振光,其斯托克斯向量可表示为Sin=(I0,0,0,0)T,其中T表示矩阵的转置。出射检偏器2-2的光束的斯托克斯向量Sout=(I,Q,U,V)T,由于探测器2-1仅能检测到光束的强度信息,即斯托克斯向量的第一项I,方程(1)整理展开,可以得出射检偏器2-2的光束斯托克斯向量Sout第一项表达式:Generally speaking, the light incident on the polarizer 1-2 is non-polarized light, and its Stokes vector can be expressed as S in =(I 0 ,0,0,0) T , where T represents the transpose of the matrix. The Stokes vector of the light beam exiting the analyzer 2-2 is S out =(I,Q,U,V) T . Since the detector 2-1 can only detect the intensity information of the light beam, that is, the first term I of the Stokes vector, equation (1) can be rearranged and expanded to obtain the first term expression of the Stokes vector S out of the light beam exiting the analyzer 2-2:

其中,in,

其中,mjk(j=1,...,4;k=1,...,4)为被测薄膜或纳米结构的穆勒矩阵元素。对探测器2-1采集的光强信号进行傅里叶分析,结合上述分析,通过锁相不同2nf0系统获得被测薄膜或纳米结构穆勒矩阵Ms中16个元素mij,进一步处理后可获得被测膜厚、光学参数等信息。in, m jk (j=1,...,4;k=1,...,4) is the Mueller matrix element of the film or nanostructure under test. The light intensity signal collected by the detector 2-1 is subjected to Fourier analysis. Combined with the above analysis, the 16 elements m ij in the Mueller matrix Ms of the film or nanostructure under test are obtained by phase-locking different 2nf 0 systems. After further processing, the film thickness, optical parameters and other information under test can be obtained.

为实现多角度、透反射薄膜厚度测量,需要通过旋转检偏臂2和样品台3实现测量,旋转都采用旋转台加步进电机方式,步进电机的驱动控制是样品扫描控制的核心。控制电路输出电脉冲信号来驱动步进电机完成指定转速和方向控制。基于FPGA输出电机驱动控制源信号,经驱动控制器放大和细分后驱动步进电机工作,进而实现各转台精确控制。In order to achieve multi-angle and transflective film thickness measurement, it is necessary to rotate the analyzer arm 2 and the sample stage 3 to achieve measurement. The rotation adopts the rotating stage plus stepper motor method. The drive control of the stepper motor is the core of the sample scanning control. The control circuit outputs an electrical pulse signal to drive the stepper motor to complete the specified speed and direction control. Based on the FPGA output motor drive control source signal, the drive controller amplifies and subdivides it to drive the stepper motor to work, thereby realizing precise control of each turntable.

上述第一快轴可调圆形弹光调制器1-3和第二快轴可调圆形弹光调制器2-3施加的交流高电压信号是基于FPGA产生弹光调制工作所需的方波交流源信号,输出给电容电感(LC)谐振电路放大后驱动弹光调制工作。通过FPGA调节方波交流源信号的频率、相位和占空比能够分别实现弹光调制器的交流高电压驱动信号的频率、相位和幅值调节,进而实现快轴可调弹光调制器的调制频率、相位延迟量的控制。The AC high voltage signal applied by the first fast-axis adjustable circular elastic light modulator 1-3 and the second fast-axis adjustable circular elastic light modulator 2-3 is a square wave AC source signal required for the elastic light modulation work generated by the FPGA, which is output to the capacitor-inductor (LC) resonant circuit for amplification and then drives the elastic light modulation work. By adjusting the frequency, phase and duty cycle of the square wave AC source signal through the FPGA, the frequency, phase and amplitude of the AC high voltage driving signal of the elastic light modulator can be adjusted respectively, thereby realizing the control of the modulation frequency and phase delay of the fast-axis adjustable elastic light modulator.

此外,本发明中的快轴可调圆形弹光调制器1-3/2-3可实现宽光谱范围的偏振调制,熔融石英型弹光调制器可实现紫外到短波红外的偏振调制,硒化锌型弹光调制器可实现可见到中远红外的偏振调制;该快轴调制频率较机械旋转可提高3-4个数量级,从而实现微秒级快轴可调弹光调制超高速广义椭偏测量。In addition, the fast-axis adjustable circular photoelastic modulator 1-3/2-3 in the present invention can realize polarization modulation in a wide spectral range, the fused quartz photoelastic modulator can realize polarization modulation from ultraviolet to short-wave infrared, and the zinc selenide photoelastic modulator can realize polarization modulation from visible to mid- and far-infrared; the fast-axis modulation frequency can be increased by 3-4 orders of magnitude compared with mechanical rotation, thereby realizing microsecond-level fast-axis adjustable photoelastic modulation ultra-high-speed generalized ellipsometric measurement.

上面仅对本发明的较佳实施例作了详细说明,但是本发明并不限于上述实施例,在本领域普通技术人员所具备的知识范围内,还可以在不脱离本发明宗旨的前提下作出各种变化,各种变化均应包含在本发明的保护范围之内。Only the preferred embodiments of the present invention are described in detail above, but the present invention is not limited to the above embodiments. Various changes can be made within the knowledge scope of ordinary technicians in this field without departing from the purpose of the present invention, and various changes should be included in the protection scope of the present invention.

Claims (6)

1. The utility model provides a microsecond level fast axis adjustable elasto-optical modulation superspeed generalized ellipsometry measuring device which characterized in that: the device comprises a polarizing arm (1), a polarization-detecting arm (2) and a sample table (3), wherein the polarization-detecting arm (2) and the sample table (3) are sequentially arranged in the light path direction of the polarizing arm (1); the light source (1-1) comprises a light source (1-1), a polarizer (1-2) and a first fast axis adjustable circular light-emitting modulator (1-3), wherein the polarizer (1-2) and the first fast axis adjustable circular light-emitting modulator (1-3) are sequentially arranged in the light path direction of the light source (1-1), and a sample table (3) is arranged in the light path direction of the first fast axis adjustable circular light-emitting modulator (1-3); the polarization analyzer comprises a polarization analyzer (2), a polarization analyzer (2-1) and a second fast axis adjustable circular elastic-optical modulator (2-3), wherein the polarization analyzer (2-2) and the detector (2-1) are sequentially arranged in the optical path direction of the second fast axis adjustable circular elastic-optical modulator (2-3), and the second fast axis adjustable circular elastic-optical modulator (2-3) is arranged in the optical path direction of a sample table (3); the first fast axis adjustable circular elastic light modulator (1-3) and the second fast axis adjustable circular elastic light modulator (2-3) comprise light passing crystals (4), a first piezoelectric driver (5-1) and a second piezoelectric driver (5-2), and the light passing crystals (4) are respectively connected with the first piezoelectric driver (5-1) and the second piezoelectric driver (5-2); the detector (2-1) comprises an ultraviolet high-speed photomultiplier, a silicon-based high-speed photoelectric detector and an InAsSb photoelectric detector, wherein the ultraviolet high-speed photomultiplier detects ultraviolet bands, the silicon-based high-speed photoelectric detector detects visible near infrared bands, and the InAsSb photoelectric detector detects near infrared short wave infrared bands; the first piezoelectric driver (5-1) and the second piezoelectric driver (5-2) are arranged at the node positions of the light-transmitting crystal (4) for forming stress standing waves, and the working frequencies of the first piezoelectric driver (5-1) and the second piezoelectric driver (5-2) are consistent.
2. The microsecond-level fast axis adjustable elasto-optical modulation ultra-high-speed generalized ellipsometry measurement device according to claim 1, wherein the device is characterized in that: the light passing crystal (4) adopts a circular structure, the light passing crystal (4) adopts fused quartz, and the light passing range of the light passing crystal (4) is 185nm-3500nm.
3. The microsecond-level fast axis adjustable elasto-optical modulation ultra-high-speed generalized ellipsometry measurement device according to claim 1, wherein the device is characterized in that: the included angle between the first piezoelectric driver (5-1) and the second piezoelectric driver (5-2) is 45 degrees.
4. The microsecond-level fast axis adjustable elasto-optical modulation ultra-high-speed generalized ellipsometry measurement device according to claim 1, wherein the device is characterized in that: the light source (1-1) adopts a multi-color light source with a spectrum range of 193nm-3200nm and a monochromator.
5. The microsecond-level fast axis adjustable elasto-optical modulation ultra-high-speed generalized ellipsometry measurement device according to claim 1, wherein the device is characterized in that: the first piezoelectric driver (5-1) and the second piezoelectric driver (5-2) are both piezoelectric alpha-quartz crystals.
6. The microsecond-level fast axis adjustable elasto-optical modulation ultra-high-speed generalized ellipsometry measurement device according to claim 1, wherein the device is characterized in that: the bottoms of the analyzer arm (2) and the sample table (3) are respectively fixed with a rotary table, and each rotary table is connected with a stepping motor.
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