CN114592946B - A Post-treatment Desulfurization System and Its Control Strategy - Google Patents
A Post-treatment Desulfurization System and Its Control Strategy Download PDFInfo
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- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
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- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
- F01N3/085—Sulfur or sulfur oxides
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
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- F01N9/00—Electrical control of exhaust gas treating apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
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- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
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- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
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Abstract
本发明涉及发动机废气处理技术领域,公开了一种后处理除硫系统及其控制策略,该后处理除硫系统包括发动机、涡轮和硫捕集器,发动机的排气口与硫捕集器的进气口连通,硫捕集器的排气口与涡轮的进气口连通。该后处理除硫系统的控制策略包括将获取的硫捕集器的运行参数信息与相应的阈值进行比较;当运行参数信息大于等于相应的阈值时,指示需更新硫捕集器。该后处理除硫系统及其控制策略,改善了现有的SCR脱硫方式造成的SCR催化剂容易水热老化的问题。
The invention relates to the technical field of engine exhaust gas treatment, and discloses a post-treatment desulfurization system and its control strategy. The post-treatment desulfurization system includes an engine, a turbine, and a sulfur trap. The air inlet is connected, and the exhaust port of the sulfur trap is connected with the air inlet of the turbine. The control strategy of the post-treatment sulfur removal system includes comparing the obtained operating parameter information of the sulfur trap with a corresponding threshold; when the operating parameter information is greater than or equal to the corresponding threshold, it is indicated that the sulfur trap needs to be updated. The post-treatment desulfurization system and its control strategy improve the problem that the SCR catalyst is prone to hydrothermal aging caused by the existing SCR desulfurization method.
Description
技术领域technical field
本发明涉及发动机废气处理技术领域,特别涉及一种后处理除硫系统及其控制策略。The invention relates to the technical field of engine exhaust gas treatment, in particular to an aftertreatment desulfurization system and a control strategy thereof.
背景技术Background technique
发动机的后处理系统中SCR(Selective Catalytic Reduction,选择性催化还原技术)系统主要采用铜分子筛催化剂,NOx转化效率较高。然而,现有柴油发动机使用的燃油含有一定量的硫,发动机涡轮后排放的废气中含有硫化物,同时,润滑剂中也含有硫,所以,SCR存在硫中毒的风险,需要对SCR定期脱硫。In the aftertreatment system of the engine, the SCR (Selective Catalytic Reduction, selective catalytic reduction technology) system mainly uses copper molecular sieve catalysts, and the NOx conversion efficiency is relatively high. However, the fuel used by existing diesel engines contains a certain amount of sulfur, and the exhaust gas discharged after the engine turbine contains sulfur compounds. At the same time, the lubricant also contains sulfur. Therefore, there is a risk of sulfur poisoning in the SCR, and the SCR needs to be regularly desulfurized.
现有技术中,是在SCR前布置DOC(氧化型催化转化器),喷入气缸中的未能充分燃烧的HC(燃油),随废气进入后处理,未燃烧的燃油在DOC催化剂的作用下氧化放热,提升后处理温度,从而在DOC中实现高温脱硫;另一种方式是,向DOC前的排气管中喷射燃油,燃油在DOC催化剂的作用下氧化放热,提升后处理温度,从而在DOC中实现高温脱硫。上述两种方式的缺点在于,容易造成SCR催化剂水热老化,并且会恶化燃油经济性。In the prior art, a DOC (Oxidation Catalytic Converter) is arranged before the SCR, and the HC (fuel oil) that is not fully burned is injected into the cylinder, and enters the post-treatment with the exhaust gas, and the unburned fuel is under the action of the DOC catalyst. Oxidation releases heat and increases the post-treatment temperature to achieve high-temperature desulfurization in the DOC; another way is to inject fuel into the exhaust pipe before the DOC, and the fuel is oxidized and released under the action of the DOC catalyst to increase the after-treatment temperature. Thereby realizing high temperature desulfurization in DOC. The disadvantages of the above two methods are that it is easy to cause hydrothermal aging of the SCR catalyst and deteriorate the fuel economy.
发明内容Contents of the invention
本发明提供了一种后处理除硫系统及其控制策略,能够改善现有的SCR脱硫方式造成的SCR催化剂容易水热老化的问题。The invention provides a post-treatment desulfurization system and its control strategy, which can improve the problem that the SCR catalyst is prone to hydrothermal aging caused by the existing SCR desulfurization method.
为达到上述目的,本发明提供以下技术方案:To achieve the above object, the present invention provides the following technical solutions:
一种后处理除硫系统,包括:发动机、涡轮和硫捕集器,所述发动机的排气口与所述硫捕集器的进气口连通,所述硫捕集器的排气口与所述涡轮的进气口连通。A post-treatment desulfurization system, comprising: an engine, a turbine and a sulfur trap, the exhaust port of the engine communicates with the intake port of the sulfur trap, the exhaust port of the sulfur trap communicates with the The air inlet of the turbine communicates.
本发明提供的后处理除硫系统在发动机的排气口与涡轮之间布置捕集器,发动机的排气口与硫捕集器的进气口连通,硫捕集器的排气口与涡轮的进气口连通,从而使得废气能够由捕集器穿过。硫捕集器的高效温度窗口在250℃~550℃,硫捕集器布置在涡轮前可以利用高温废气对废气中的SOx(硫的氧化物)进行捕集,无须高温脱硫,既能够降低后处理系统SCR硫中毒的风险,并提高燃油经济性,又不会造成SCR催化剂水热老化。The post-treatment desulfurization system provided by the present invention arranges a trap between the exhaust port of the engine and the turbine, the exhaust port of the engine communicates with the intake port of the sulfur trap, and the exhaust port of the sulfur trap communicates with the turbine The intake port of the exhaust port is connected so that the exhaust gas can pass through the trap. The high-efficiency temperature window of the sulfur trap is 250°C to 550°C. The sulfur trap is arranged in front of the turbine to capture SOx (sulfur oxide) in the exhaust gas by using high-temperature exhaust gas, without high-temperature desulfurization, which can reduce Deal with the risk of system SCR sulfur poisoning and improve fuel economy without causing hydrothermal aging of the SCR catalyst.
可选地,所述硫捕集器具有多个并行的通道,各所述通道的进气口均与所述发动机的排气口连通,各所述通道的排气口均与所述涡轮的进气口连通,且各所述通道的壁面均涂覆有硫捕集层。Optionally, the sulfur trap has a plurality of parallel channels, the air inlet of each channel is connected with the exhaust port of the engine, and the exhaust port of each channel is connected with the exhaust port of the turbine. The gas inlets are connected, and the walls of each channel are coated with a sulfur trapping layer.
可选地,所述硫捕集层包括载体层和硫捕集剂。Optionally, the sulfur trapping layer includes a carrier layer and a sulfur trapping agent.
可选地,所述硫捕集剂包括碱金属氧化物和/或碱土金属氧化物。Optionally, the sulfur collector includes alkali metal oxides and/or alkaline earth metal oxides.
可选地,所述硫捕集器与所述发动机的排气口以及所述涡轮的进气口之间均为可拆卸连接。Optionally, the sulfur trap is detachably connected to the exhaust port of the engine and the intake port of the turbine.
本发明还提供了一种后处理除硫系统的控制策略,应用于上述技术方案中提供的任意一种后处理除硫系统,该控制策略包括:The present invention also provides a control strategy for a post-treatment desulfurization system, which is applied to any one of the post-treatment desulfurization systems provided in the above technical solutions. The control strategy includes:
将获取的硫捕集器的运行参数信息与相应的阈值进行比较;Comparing the obtained operating parameter information of the sulfur trap with corresponding threshold values;
当所述运行参数信息大于等于相应的所述阈值时,指示需更新硫捕集器;When the operating parameter information is greater than or equal to the corresponding threshold, it indicates that the sulfur trap needs to be updated;
其中,所述后处理除硫系统包括:Wherein, the post-treatment desulfurization system includes:
发动机、涡轮和硫捕集器,所述发动机的排气口与所述硫捕集器的进气口连通,所述硫捕集器的排气口与所述涡轮的进气口连通。An engine, a turbine and a sulfur trap, the exhaust port of the engine communicates with the intake port of the sulfur trap, and the exhaust port of the sulfur trap communicates with the intake port of the turbine.
本发明提供的后处理除硫系统的控制策略通过将获取的硫捕集器的运行参数信息与相应的阈值进行比较,在运行参数信息大于等于相应的阈值时,能够指示需更新硫捕集器,从而有利于保证硫捕集器的捕集的效率。The control strategy of the post-treatment sulfur removal system provided by the present invention compares the obtained operating parameter information of the sulfur trap with the corresponding threshold, and can indicate that the sulfur trap needs to be updated when the operating parameter information is greater than or equal to the corresponding threshold , thus helping to ensure the efficiency of the sulfur trap.
同时,在发动机的排气口与涡轮之间布置硫捕集器,且发动机的排气口与硫捕集器的进气口连通,硫捕集器的排气口与涡轮的进气口连通,从而使得废气能够由硫捕集器穿过,硫捕集器的高效温度窗口在250℃~550℃,硫捕集器布置在涡轮前可以利用高温废气对废气中的SOx进行捕集,无须高温脱硫,既能够降低后处理系统SCR硫中毒的风险,并提高燃油经济性,又不会造成SCR催化剂水热老化。At the same time, a sulfur trap is arranged between the exhaust port of the engine and the turbine, and the exhaust port of the engine communicates with the intake port of the sulfur trap, and the exhaust port of the sulfur trap communicates with the intake port of the turbine , so that the exhaust gas can pass through the sulfur trap. The high-efficiency temperature window of the sulfur trap is between 250°C and 550°C. High-temperature desulfurization can reduce the risk of SCR sulfur poisoning in the aftertreatment system and improve fuel economy without causing hydrothermal aging of the SCR catalyst.
可选地,所述将获取的硫捕集器的运行参数信息与相应的阈值进行比较,包括下述方式中的至少一种:Optionally, the comparing the acquired operating parameter information of the sulfur trap with the corresponding threshold includes at least one of the following ways:
获取硫逃逸浓度,将所述硫逃逸浓度与硫浓度阈值进行比较;Obtaining a sulfur escape concentration, and comparing the sulfur escape concentration with a sulfur concentration threshold;
获取所述硫捕集器使用以来的硫捕集总量,将所述硫捕集总量与硫捕集量阈值进行比较;Obtaining the total amount of sulfur captured since the sulfur trap was used, and comparing the total amount of sulfur captured with a threshold value of sulfur capture;
获取所述硫捕集器使用以来的总行驶里程,将所述总行驶里程与行驶里程阈值进行比较。The total mileage since the sulfur trap is used is acquired, and the total mileage is compared with a mileage threshold.
可选地,当所述将获取的硫捕集器的运行参数信息与相应的阈值进行比较,包括获取所述硫捕集器使用以来的硫捕集总量,将所述硫捕集总量与硫捕集量阈值进行比较时,所述控制策略具体包括:Optionally, when comparing the obtained operating parameter information of the sulfur trap with the corresponding threshold value, including obtaining the total amount of sulfur captured by the sulfur trap since it is used, the total amount of sulfur captured When compared with the sulfur capture threshold, the control strategy specifically includes:
计算所述硫捕集器的实时硫捕集质量;calculating the real-time sulfur capture mass of the sulfur trap;
将所述实时硫捕集质量与所述硫捕集器使用以来的各历史驾驶循环的硫捕集质量进行累加,得到所述硫捕集总量;Accumulating the real-time sulfur capture mass with the sulfur capture mass of each historical driving cycle since the sulfur trap is used, to obtain the total sulfur capture amount;
将所述硫捕集总量与所述硫捕集量阈值进行比较,当所述硫捕集总量大于等于所述硫捕集量阈值时,指示需更新硫捕集器。The total amount of captured sulfur is compared with the threshold value of the captured amount of sulfur, and when the total amount of captured sulfur is greater than or equal to the threshold value of the captured amount of sulfur, it is indicated that the sulfur trap needs to be updated.
可选地,所述计算所述硫捕集器的实时硫捕集质量,具体包括:Optionally, the calculating the real-time sulfur capture quality of the sulfur trap specifically includes:
将当前驾驶循环中,废气中的硫质量流量进行积分,得到当前驾驶循环中硫质量流量的积分值;Integrating the sulfur mass flow in the exhaust gas in the current driving cycle to obtain the integral value of the sulfur mass flow in the current driving cycle;
将所述积分值与所述硫捕集器的转化效率进行乘积,得到所述实时硫捕集质量。The real-time sulfur capture quality is obtained by multiplying the integral value by the conversion efficiency of the sulfur trap.
可选地,所述将当前驾驶循环中,废气中的硫质量流量进行积分,得到当前驾驶循环中硫质量流量的积分值之前,包括:Optionally, before integrating the sulfur mass flow in the exhaust gas in the current driving cycle to obtain the integral value of the sulfur mass flow in the current driving cycle, it includes:
通过发动机转速与燃油喷射量以及燃油中的硫浓度,得到废气中硫质量流量初始值;The initial value of the sulfur mass flow rate in the exhaust gas is obtained through the engine speed, the fuel injection quantity and the sulfur concentration in the fuel;
对所述硫质量流量初始值进行修正得到所述废气中的硫质量流量。The sulfur mass flow in the exhaust gas is obtained by correcting the initial value of the sulfur mass flow.
可选地,对所述硫质量流量初始值进行修正的方式,包括下述方式中的至少一种:Optionally, the way of correcting the initial value of the sulfur mass flow rate includes at least one of the following ways:
通过空气过量影响系数对所述硫质量流量初始值进行修正;The initial value of the sulfur mass flow rate is corrected by the air excess influence coefficient;
通过环境温度影响系数对所述硫质量流量初始值进行修正;The initial value of the sulfur mass flow rate is corrected by the ambient temperature influence coefficient;
通过环境压力影响系数对所述硫质量流量初始值进行修正。The initial value of the sulfur mass flow rate is corrected by the environmental pressure influence coefficient.
可选地,所述将所述实时硫捕集质量与所述硫捕集器使用以来的各历史驾驶循环的硫捕集质量进行累加,具体包括:Optionally, the accumulating the real-time sulfur capture quality and the sulfur capture quality of each historical driving cycle since the use of the sulfur trap specifically includes:
获取各历史驾驶循环的硫捕集质量或各历史驾驶循环的硫捕集质量之和;Obtain the sulfur capture mass of each historical driving cycle or the sum of the sulfur capture mass of each historical driving cycle;
将所述实时硫捕集质量与对应的所述各历史驾驶循环的硫捕集质量或各历史驾驶循环的硫捕集质量之和进行累加。Accumulate the real-time sulfur trapping mass and the corresponding sulfur trapping mass of each historical driving cycle or the sum of the sulfur trapping mass of each historical driving cycle.
可选地,当前驾驶循环结束后,对所述实时硫捕集质量进行存储,以在下一驾驶循环中计算硫捕集器的硫捕集总量。Optionally, after the end of the current driving cycle, the real-time sulfur capture quality is stored, so as to calculate the total amount of sulfur captured by the sulfur trap in the next driving cycle.
可选地,当所述将获取的硫捕集器的运行参数信息与相应的阈值进行比较,包括获取所述硫捕集器使用以来的总行驶里程,将所述总行驶里程与行驶里程阈值进行比较时,所述控制策略包括:Optionally, when comparing the obtained operating parameter information of the sulfur trap with the corresponding threshold value, it includes obtaining the total mileage since the sulfur trap is used, and comparing the total mileage with the mileage threshold When compared, the control strategies include:
将当前驾驶循环的实时行驶里程与硫捕集器使用以来的各历史驾驶循环的行驶里程进行累加,得到所述总行驶里程;Accumulate the real-time mileage of the current driving cycle and the mileage of each historical driving cycle since the use of the sulfur trap to obtain the total mileage;
将所述总行驶里程与行驶里程阈值进行比较,当所述总行驶里程大于等于所述行驶里程阈值时,指示需更新硫捕集器。The total mileage is compared with a mileage threshold, and when the total mileage is greater than or equal to the mileage threshold, it is indicated that the sulfur trap needs to be updated.
附图说明Description of drawings
图1为本发明实施例提供的一种后处理除硫系统中硫捕集器的结构示意图(上方的空心箭头表示废气流的流动方向);Fig. 1 is a structural schematic diagram of a sulfur trap in a post-treatment desulfurization system provided by an embodiment of the present invention (the hollow arrow above indicates the flow direction of the exhaust gas flow);
图2为本发明实施例提供的一种后处理除硫系统的控制策略的流程示意图;Fig. 2 is a schematic flow chart of a control strategy of a post-treatment desulfurization system provided by an embodiment of the present invention;
图3为本发明实施例提供的一种后处理除硫系统的控制策略中部分环节的流程示意图;3 is a schematic flow diagram of some links in the control strategy of a post-treatment desulfurization system provided by an embodiment of the present invention;
图4为本发明实施例提供的一种后处理除硫系统的控制策略中部分环节的流程示意图;Fig. 4 is a schematic flow diagram of some links in the control strategy of a post-treatment desulfurization system provided by an embodiment of the present invention;
图5为本发明实施例提供的一种后处理除硫系统的控制策略中部分环节的流程示意图;Fig. 5 is a schematic flow diagram of some links in the control strategy of a post-treatment desulfurization system provided by an embodiment of the present invention;
图6为本发明实施例提供的一种后处理除硫系统的控制策略的逻辑图;Fig. 6 is a logic diagram of a control strategy of a post-treatment desulfurization system provided by an embodiment of the present invention;
图7为本发明实施例提供的一种后处理除硫系统的控制策略的流程示意图;Fig. 7 is a schematic flowchart of a control strategy of a post-treatment desulfurization system provided by an embodiment of the present invention;
图8为一种设置有本发明实施例提供的后处理除硫系统的发动机系统的结构示意图。Fig. 8 is a schematic structural diagram of an engine system provided with an aftertreatment desulfurization system provided by an embodiment of the present invention.
图标:1-硫捕集层;11-载体层;12-硫捕集剂;2-基底层;3-滤清器;4-压气机;5-进气节流阀;6-发动机;7-涡轮;8-DOC;9-DPF;10-SCR;13-ASC;14-催化剂;100-硫捕集器。Icons: 1-sulfur trapping layer; 11-carrier layer; 12-sulfur trapping agent; 2-base layer; 3-filter; 4-compressor; 5-intake throttle valve; 6-engine; 7 8-DOC; 9-DPF; 10-SCR; 13-ASC; 14-catalyst; 100-sulfur trap.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
如图8所示,本实施例提供的一种后处理除硫系统包括发动机6、涡轮7和硫捕集器100,其中,发动机6的排气口与硫捕集器100的进气口连通,硫捕集器100的排气口与涡轮7的进气口连通。As shown in Figure 8, a post-treatment desulfurization system provided in this embodiment includes an
本实施例提供的后处理除硫系统在发动机的排气口与涡轮之间布置捕集器,发动机的排气口与硫捕集器的进气口连通,硫捕集器的排气口与涡轮的进气口连通,从而使得废气能够由捕集器穿过。硫捕集器100的高效温度窗口在250℃~550℃,硫捕集器100布置在涡轮前可以利用高温废气对废气中的SOx(硫的氧化物)进行捕集,无须高温脱硫,既能够降低后处理系统SCR硫中毒的风险,并提高燃油经济性,又不会造成SCR催化剂水热老化。In the post-treatment desulfurization system provided in this embodiment, a trap is arranged between the exhaust port of the engine and the turbine, the exhaust port of the engine communicates with the intake port of the sulfur trap, and the exhaust port of the sulfur trap communicates with the intake port of the sulfur trap. The intake port of the turbine communicates so that the exhaust gases can pass through the trap. The high-efficiency temperature window of the
具体设置上述硫捕集器时,一种可选的实现方式中,硫捕集器具有多个并行的通道,各通道的进气口均与发动机的排气口连通,各通道的排气口均与涡轮的进气口连通,且各通道的壁面均涂覆有硫捕集层1。When the above-mentioned sulfur trap is specifically set, in an optional implementation mode, the sulfur trap has a plurality of parallel channels, the air inlets of each channel are connected with the exhaust port of the engine, and the exhaust ports of each channel All communicate with the air inlet of the turbine, and the wall surface of each channel is coated with a sulfur trapping layer 1 .
具体设置上述硫捕集层1时,如图1所示,一种可选的实现方式中,硫捕集层包括载体层11和硫捕集剂12。When specifically setting the above-mentioned sulfur trapping layer 1 , as shown in FIG. 1 , in an optional implementation manner, the sulfur trapping layer includes a
一种可选的实现方式中,硫捕集剂12包括碱金属氧化物和/或碱土金属氧化物,例如:硫捕集剂12可以包括钾的氧化物、钡的氧化物以及铈的氧化物三者中的至少一个。In an optional implementation, the
硫捕集层1包括载体层11和硫捕集剂12,一种可选的实现方式中,载体层11设置于通道的壁面,硫捕集剂12层设置于载体层11上。示例性地,载体层11可以涂覆于通道的壁面,硫捕集剂12层可以涂覆于载体层11上。The sulfur trapping layer 1 includes a
另一种可选地实现方式中,硫捕集剂12混合于载体层11中,与载体层11一并涂覆于通道的壁面。In another optional implementation manner, the
具体设置上述载体层11时,载体层11可以包括三氧化二铝层。Specifically, when the above-mentioned
一种可选的实现方式中,硫捕集器包括基底层2(例如:堇青石层),载体层11涂覆于基底层2。In an optional implementation manner, the sulfur trap includes a base layer 2 (for example: a cordierite layer), and the
为了提到硫捕集器100的捕集效率,一种可选的实现方式中,硫捕集层1上设有催化剂14。示例性地,催化剂14包括铂(Pt)。In order to improve the trapping efficiency of the
一种可选的实现方式中,硫捕集器与发动机的排气口以及涡轮的进气口之间均为可拆卸连接。例如:硫捕集器与发动机排气口通过法兰连接,硫捕集器与涡轮进气口也通过法兰连接。In an optional implementation manner, the sulfur trap is detachably connected to the exhaust port of the engine and the intake port of the turbine. For example: the sulfur trap is connected to the exhaust port of the engine through a flange, and the sulfur trap is also connected to the turbine inlet through a flange.
硫捕集器与发动机的排气口以及涡轮的进气口之间均为可拆卸连接,硫捕集器需要更新时,可以直接更换新的硫捕集器,操作较为便捷。The sulfur trap is detachably connected to the exhaust port of the engine and the intake port of the turbine. When the sulfur trap needs to be updated, a new sulfur trap can be directly replaced, and the operation is more convenient.
本实施例中在硫捕集器的各通道内布置硫捕集剂12,以碱金属氧化物和/或碱土金属氧化物作为SOx捕集剂,以三氧化二铝为载体层11,对废气中的SOx进行捕集,发挥硫捕集的作用。同时,硫捕集器100相当于一个“滤芯”,成本较低,且可以定期更换,能够减轻后处理SCR硫中毒的风险。通过下文提及的后处理除硫系统的控制策略,对硫捕集器100进行更新,也有利于提高后处理系统中SCR催化剂的可靠性,提高燃油经济性。In this embodiment, a
发动机系统采用本实施例提供的后处理除硫系统时,废气中的SOx通过与硫捕集剂12反应生成硫酸盐而被捕获,但生成的硫酸盐很难通过高温进行脱硫,因而,硫捕集器100使用一段时间后需要更新,以免因硫捕集器100吸附能力下降而造成硫逃逸,对下游SCR产生不利影响。因此,对硫捕集器100的控制及更新维护也尤为重要。When the engine system adopts the post-treatment desulfurization system provided in this embodiment, the SOx in the exhaust gas is captured by reacting with the
如图2所示,本实施例提供的一种后处理除硫系统的控制策略,应用于上述技术方案中提供的任意一种后处理除硫系统,该控制策略包括:As shown in Figure 2, a control strategy for a post-treatment desulfurization system provided in this embodiment is applied to any post-treatment desulfurization system provided in the above technical solution, and the control strategy includes:
步骤S1、将获取的硫捕集器100的运行参数信息与相应的阈值进行比较;Step S1, comparing the acquired operating parameter information of the
当运行参数信息大于等于相应的阈值时,指示需更新硫捕集器100。When the operating parameter information is greater than or equal to the corresponding threshold, it indicates that the
本实施例提供的后处理除硫系统的控制策略通过将获取的硫捕集器100的运行参数信息与相应的阈值进行比较,在运行参数信息大于等于相应的阈值时,能够指示需更新硫捕集器100,从而有利于保证硫捕集器的捕集的效率。The control strategy of the post-processing sulfur removal system provided in this embodiment compares the obtained operating parameter information of the
同时,在发动机的排气口与涡轮之间布置硫捕集器,且发动机的排气口与硫捕集器的进气口连通,硫捕集器的排气口与涡轮的进气口连通,从而使得废气能够由硫捕集器穿过,硫捕集器100的高效温度窗口在250℃~550℃,硫捕集器100布置在涡轮前可以利用高温废气对废气中的SOx进行捕集,无须高温脱硫,既能够降低后处理系统SCR硫中毒的风险,并提高燃油经济性,又不会造成SCR催化剂水热老化。At the same time, a sulfur trap is arranged between the exhaust port of the engine and the turbine, and the exhaust port of the engine communicates with the intake port of the sulfur trap, and the exhaust port of the sulfur trap communicates with the intake port of the turbine , so that the exhaust gas can pass through the sulfur trap. The high-efficiency temperature window of the
当运行参数信息大于等于相应的阈值时,指示需更新硫捕集器100,示例性地,当硫捕集器与发动机的排气口以及涡轮的进气口之间均为可拆卸连接时,可以将现有的硫捕集器100拆除,更换新的硫捕集器100。When the operating parameter information is greater than or equal to the corresponding threshold, it indicates that the
一种可选的实现方式中,步骤S1、将获取的硫捕集器100的运行参数信息与相应的阈值进行比较,包括下述方式中的至少一种(即,可以包括下列方式中的一种、两种或者三种):In an optional implementation manner, step S1, comparing the obtained operating parameter information of the
方式一、获取硫逃逸浓度,将硫逃逸浓度与硫浓度阈值进行比较;Method 1: Obtain the sulfur escape concentration, and compare the sulfur escape concentration with the sulfur concentration threshold;
方式二、获取硫捕集器100使用以来的硫捕集总量,将硫捕集总量与硫捕集量阈值进行比较;Method 2: Obtain the total amount of sulfur captured since the
方式三、获取硫捕集器100使用以来的总行驶里程,将总行驶里程与行驶里程阈值进行比较。Way 3: Obtain the total mileage since the use of the
示例性地,可以在硫捕集器100的下游布置SO2浓度传感器,通过SO2浓度传感器来检测硫逃逸浓度。Exemplarily, an SO 2 concentration sensor may be arranged downstream of the
同时,也可以在硫捕集器100上游布置SO2浓度传感器,以精确判定燃油中的硫浓度,使硫累积量算法更加准确。At the same time, an SO 2 concentration sensor can also be arranged upstream of the
需要说明的是,当步骤S1、将获取的硫捕集器100的运行参数信息与相应的阈值进行比较,包括上述方式中的两种或者三种时,其中一种方式对应的硫捕集器100的运行参数信息大于等于相应的阈值时,则指示需更新硫捕集器100。It should be noted that when step S1 compares the obtained operating parameter information of the
当步骤S1、将获取的硫捕集器100的运行参数信息与相应的阈值进行比较,包括获取硫捕集器100使用以来的硫捕集总量,将硫捕集总量与硫捕集量阈值进行比较时,如图3所示,一种可选的实现方式中,该控制策略具体包括:In step S1, comparing the obtained operating parameter information of the
步骤S11、计算硫捕集器100的实时硫捕集质量;Step S11, calculating the real-time sulfur capture quality of the
步骤S12、将实时硫捕集质量与硫捕集器100使用以来的各历史驾驶循环的硫捕集质量进行累加,得到硫捕集总量;Step S12, adding up the real-time sulfur capture mass and the sulfur capture mass of each historical driving cycle since the use of the
步骤S13、将硫捕集总量与硫捕集量阈值进行比较,当硫捕集总量大于等于硫捕集量阈值时,指示需更新硫捕集器100。Step S13 , comparing the total amount of captured sulfur with the threshold value of sulfur capture amount, and when the total amount of sulfur capture is greater than or equal to the threshold value of sulfur capture amount, it is indicated that the
如图4所示,一种可选的实现方式中,步骤S11、计算硫捕集器100的实时硫捕集质量,具体包括:As shown in Figure 4, in an optional implementation, step S11, calculating the real-time sulfur capture quality of the
步骤S21、将当前驾驶循环中,废气中的硫质量流量进行积分,得到当前驾驶循环中硫质量流量的积分值;Step S21, integrating the mass flow rate of sulfur in the exhaust gas in the current driving cycle to obtain the integral value of the mass flow rate of sulfur in the current driving cycle;
步骤S22、将积分值与硫捕集器100的转化效率进行乘积,得到实时硫捕集质量。Step S22 , multiplying the integral value by the conversion efficiency of the
此种方式时,更新硫捕集器100后,需将ECU(Electronic Control Unit,电子控制单元)内计算的积分值、硫捕集器100使用以来的硫捕集总量等均重置为0。In this way, after updating the
如图5所示,一种可选的实现方式中,步骤S21、将当前驾驶循环中,废气中的硫质量流量进行积分,得到当前驾驶循环中硫质量流量的积分值之前,包括:As shown in Figure 5, in an optional implementation, before step S21, integrating the sulfur mass flow in the exhaust gas in the current driving cycle to obtain the integral value of the sulfur mass flow in the current driving cycle, includes:
步骤S31、通过发动机转速与燃油喷射量以及燃油中的硫浓度,得到废气中硫质量流量初始值;Step S31, obtain the initial value of sulfur mass flow rate in exhaust gas according to engine speed, fuel injection quantity and sulfur concentration in fuel;
步骤S32、对硫质量流量初始值进行修正得到废气中的硫质量流量。Step S32, correcting the initial value of the sulfur mass flow rate to obtain the sulfur mass flow rate in the exhaust gas.
一种可选的实现方式中,步骤S32、对硫质量流量初始值进行修正的方式,包括下述方式中的至少一种:In an optional implementation manner, step S32, the manner of correcting the initial value of the sulfur mass flow rate includes at least one of the following manners:
方式一、通过空气过量影响系数对硫质量流量初始值进行修正;Method 1. Correct the initial value of the sulfur mass flow rate through the influence coefficient of excess air;
方式二、通过环境温度影响系数对硫质量流量初始值进行修正;Method 2: Correct the initial value of the sulfur mass flow rate through the influence coefficient of the ambient temperature;
方式三、通过环境压力影响系数对硫质量流量初始值进行修正。Method 3: The initial value of the sulfur mass flow rate is corrected by the environmental pressure influence coefficient.
一种可选的实现方式中,步骤S12、将实时硫捕集质量与硫捕集器100使用以来的各历史驾驶循环的硫捕集质量进行累加,具体包括:In an optional implementation, step S12 is to accumulate the real-time sulfur capture quality and the sulfur capture quality of each historical driving cycle since the use of the
获取各历史驾驶循环的硫捕集质量或各历史驾驶循环的硫捕集质量之和;Obtain the sulfur capture mass of each historical driving cycle or the sum of the sulfur capture mass of each historical driving cycle;
将实时硫捕集质量与对应的各历史驾驶循环的硫捕集质量或各历史驾驶循环的硫捕集质量之和进行累加,即,当获取的为各历史驾驶循环的硫捕集质量时,将实时硫捕集质量与各历史驾驶循环的硫捕集质量进行累加;当获取的为各历史驾驶循环的硫捕集质量之和时,将实时硫捕集质量与各历史驾驶循环的硫捕集质量之和进行累加。Accumulate the real-time sulfur capture mass with the corresponding sulfur capture mass of each historical driving cycle or the sum of the sulfur capture mass of each historical driving cycle, that is, when the sulfur capture mass of each historical driving cycle is obtained, Accumulate the real-time sulfur capture mass and the sulfur capture mass of each historical driving cycle; when the obtained sulfur capture mass is the sum of each historical driving cycle, the real-time sulfur The sum of the set masses is accumulated.
一种可选的实现方式中,当前驾驶循环结束后,对实时硫捕集质量进行存储,以在下一驾驶循环中计算硫捕集器100的硫捕集总量。In an optional implementation manner, after the current driving cycle ends, the real-time sulfur capture quality is stored, so as to calculate the total amount of sulfur captured by the
示例性地,当前驾驶循环结束后,ECU下电时(即T15下电时),实时硫捕集质量更新到存储器中;新的驾驶循环开始后,即ECU上电(即T15上电)后从存储器中读取相应的各历史驾驶循环的硫捕集质量或各历史驾驶循环的硫捕集质量之和。Exemplarily, after the end of the current driving cycle, when the ECU is powered off (that is, when T15 is powered off), the real-time sulfur capture quality is updated to the memory; after a new driving cycle starts, that is, after the ECU is powered on (that is, when T15 is powered on) The corresponding sulfur trapping mass of each historical driving cycle or the sum of the sulfur trapping mass of each historical driving cycle is read from the memory.
当步骤S1、将获取的硫捕集器100的运行参数信息与相应的阈值进行比较,包括获取硫捕集器100使用以来的总行驶里程,将总行驶里程与行驶里程阈值进行比较时,一种可选的实现方式中,该控制策略包括:When step S1 compares the obtained operating parameter information of the
将当前驾驶循环的实时行驶里程与硫捕集器100使用以来的各历史驾驶循环的行驶里程进行累加,得到总行驶里程;Accumulate the real-time mileage of the current driving cycle and the mileage of each historical driving cycle since the use of the
将总行驶里程与行驶里程阈值进行比较,当总行驶里程大于等于行驶里程阈值时,指示需更新硫捕集器100。The total driving mileage is compared with the driving mileage threshold, and when the total driving mileage is greater than or equal to the driving mileage threshold, it indicates that the
此种方式时,更新硫捕集器100后,需将硫捕集器100使用以来的总行驶里程重置为0。In this way, after the
本实施例提供了一种后处理除硫系统及后处理除硫系统的控制策略,将本实施例提供的后处理除硫系统布置在柴油机后处理上,通过定期更新硫捕集器100,即能够减轻后处理中SCR硫中毒的风险,而且无须高温脱硫,从而降低了SCR水热老化的风险,提高了后处理系统中SCR催化剂的可靠性以及燃油经济性。This embodiment provides a post-processing desulfurization system and a control strategy for the post-processing desulfurization system. The post-processing desulfurization system provided in this embodiment is arranged on the post-treatment of diesel engines, and the
下面结合图6和图7对本实施例提供的一种后处理除硫系统的控制策略进行简要说明。A control strategy of a post-treatment desulfurization system provided in this embodiment will be briefly described below with reference to FIG. 6 and FIG. 7 .
步骤S41、通过发动机转速与燃油喷射量以及燃油中的硫浓度,得到废气中硫质量流量初始值;Step S41, obtain the initial value of sulfur mass flow rate in exhaust gas according to engine speed, fuel injection quantity and sulfur concentration in fuel;
具体的,可以是通过发动机转速以及燃油喷射量这二者与燃油含硫量的关系图,经计算得到废气中硫质量流量初始值。Specifically, the initial value of the mass flow rate of sulfur in the exhaust gas may be obtained through calculation based on a relationship diagram between the engine speed and the fuel injection amount and the fuel sulfur content.
步骤S42、通过空气过量影响系数对上述硫质量流量初始值进行修正,得到瞬态工况下的硫质量流量;Step S42, correcting the initial value of the above-mentioned sulfur mass flow rate by using the influence coefficient of excess air to obtain the sulfur mass flow rate under transient working conditions;
具体地,可以是根据空气吸入量与空气过量影响系数的关系图确定空气过量影响系数,将空气过量影响系数与硫质量流量初始值进行乘积,得到上述瞬态工况下的硫质量流量。Specifically, the air excess influence coefficient may be determined according to the relationship diagram between the air intake amount and the excess air influence coefficient, and the excess air influence coefficient is multiplied by the initial value of the sulfur mass flow rate to obtain the sulfur mass flow rate under the above transient conditions.
步骤S43、通过环境温度影响系数对上述瞬态工况下的硫质量流量进行进一步修正;Step S43, further correcting the sulfur mass flow rate under the above-mentioned transient working conditions by using the ambient temperature influence coefficient;
具体地,可以是根据环境温度与环境温度影响系数的关系图确定环境温度影响系数,将环境温度影响系数与上述瞬态工况下的硫质量流量进行乘积,以实现对上述瞬态工况下的硫质量流量进行进一步修正。Specifically, the ambient temperature influence coefficient can be determined according to the relationship diagram between the ambient temperature and the ambient temperature influence coefficient, and the ambient temperature influence coefficient can be multiplied by the sulfur mass flow rate under the above-mentioned transient conditions, so as to realize the calculation of the above-mentioned transient conditions. The sulfur mass flow rate is further corrected.
步骤S44、通过环境压力影响系数对步骤S43得出的结果进行进一步修正,得到废气中的硫质量流量;Step S44, further correcting the result obtained in step S43 by using the environmental pressure influence coefficient to obtain the mass flow rate of sulfur in the exhaust gas;
具体地,可以是根据环境压力与环境压力影响系数的关系图确定环境压力影响系数,将环境压力影响系数与步骤S43得出的结果进行乘积,以得到废气中的硫质量流量。Specifically, the environmental pressure influence coefficient may be determined according to the relationship diagram between the environmental pressure and the environmental pressure influence coefficient, and the environmental pressure influence coefficient is multiplied by the result obtained in step S43 to obtain the mass flow rate of sulfur in the exhaust gas.
步骤S45、将当前驾驶循环中,废气中的硫质量流量进行积分,得到当前驾驶循环中硫质量流量的积分值;Step S45, integrating the mass flow rate of sulfur in the exhaust gas in the current driving cycle to obtain the integral value of the mass flow rate of sulfur in the current driving cycle;
步骤S46、将积分值与硫捕集器100的转化效率进行乘积,得到实时硫捕集质量。Step S46 , multiplying the integral value by the conversion efficiency of the
步骤S47、获取硫捕集器100使用以来的各历史驾驶循环的硫捕集质量;Step S47, obtaining the sulfur capture quality of each historical driving cycle since the use of the
步骤S48、将实时硫捕集质量与硫捕集器100使用以来的各历史驾驶循环的硫捕集质量进行累加,得到硫捕集总量;Step S48, adding up the real-time sulfur capture mass and the sulfur capture mass of each historical driving cycle since the use of the
步骤S49、将硫捕集总量与硫捕集量阈值进行比较,当硫捕集总量大于等于硫捕集量阈值时,指示需更新硫捕集器100。Step S49 , comparing the total amount of captured sulfur with the threshold value of sulfur capture amount, and when the total amount of sulfur capture is greater than or equal to the threshold value of sulfur capture amount, it is indicated that the
步骤S50、更新硫捕集器100后,将ECU内计算的积分值、硫捕集器100使用以来的硫捕集总量等均重置为0。Step S50 , after updating the
当将获取的硫捕集器100的运行参数信息与相应的阈值进行比较,包括获取硫捕集器100使用以来的总行驶里程,将总行驶里程与行驶里程阈值进行比较时,一种可选的实现方式中,本实施例提供的后处理除硫系统的控制策略包括以下步骤:When comparing the obtained operating parameter information of the
将当前驾驶循环的行驶里程与硫捕集器100使用以来的各历史驾驶循环的行驶里程进行累加,得到总行驶里程;The mileage of the current driving cycle and the mileage of each historical driving cycle since the use of the
将总行驶里程与行驶里程阈值进行比较,当总行驶里程大于等于行驶里程阈值时,指示需更新硫捕集器100。The total driving mileage is compared with the driving mileage threshold, and when the total driving mileage is greater than or equal to the driving mileage threshold, it indicates that the
一种可选的实现方式中,将当前驾驶循环的行驶里程与硫捕集器100使用以来的各历史驾驶循环的行驶里程进行累加,得到总行驶里程,具体包括以下步骤:In an optional implementation, the mileage of the current driving cycle is accumulated with the mileage of each historical driving cycle since the use of the
获取当前驾驶循环的实时行驶里程以及硫捕集器100使用以来的各历史驾驶循环的行驶里程;Obtain the real-time driving mileage of the current driving cycle and the driving mileage of each historical driving cycle since the use of the
将当前驾驶循环的实时行驶里程与硫捕集器100使用以来的各历史驾驶循环的行驶里程进行累加,得到总行驶里程。The real-time driving mileage of the current driving cycle and the driving mileage of each historical driving cycle since the use of the
更新硫捕集器100后,将硫捕集器100使用以来的总行驶里程重置为0。After updating the
下面结合图8对柴油机后处理布置有本实施例提供的后处理除硫系统时的情况进行简要说明:The situation when the post-treatment desulfurization system provided by this embodiment is arranged for the post-treatment of the diesel engine is briefly described below in conjunction with FIG. 8 :
空气经滤清器3后进入压气机4,然后经进气节流阀5进入发动机6,发动机排出的废气经硫捕集器100后进入涡轮7,从涡轮排出后,又依次经DOC(Diesel OxidationCatalysis,氧化型催化转化器)8、DPF(Diesel Particulate Filter,颗粒物捕集器)9、SCR10、以及ASC(氨气氧化催化器)13后排出,其中,在DPF和SCR之间会有尿素喷射。The air enters the compressor 4 after passing through the
显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. Thus, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalent technologies, the present invention also intends to include these modifications and variations.
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