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CN114575176A - Method for manufacturing low-cost pure meta-aramid insulating composite paper - Google Patents

Method for manufacturing low-cost pure meta-aramid insulating composite paper Download PDF

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CN114575176A
CN114575176A CN202210360540.5A CN202210360540A CN114575176A CN 114575176 A CN114575176 A CN 114575176A CN 202210360540 A CN202210360540 A CN 202210360540A CN 114575176 A CN114575176 A CN 114575176A
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aramid
paper
fibrids
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meta
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尹盛东
常小斌
李永锋
蒋少波
丁见兴
蒋泉洪
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Ganzhou Longbang Material Technology Co ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/30Defibrating by other means
    • D21B1/34Kneading or mixing; Pulpers
    • D21B1/345Pulpers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21DTREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00Methods of beating or refining; Beaters of the Hollander type
    • D21D1/20Methods of refining
    • D21D1/30Disc mills
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F5/00Dryer section of machines for making continuous webs of paper
    • D21F5/02Drying on cylinders
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/26Polyamides; Polyimides

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  • Chemical & Material Sciences (AREA)
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Abstract

本发明公开了一种低成本纯间位芳纶绝缘复合纸的制造方法,属于芳纶纸制备技术领域,包括如下步骤:原料的制备,包括5‑40重量份的芳纶短切纤维,以及60‑95重量份的芳纶沉析纤维;两层斜网抄造;采用去离子水进行网纹辊涂水;依次通过平轧和背辊轧的方式进行热轧。本发明中,沉析纤维选用丝状沉析纤维,其比表面积相对片膜状沉析纤维较小,在抄造时滤水快,抄造车速也较快,能够大大提高抄造速度;且本发明采用超低浓度浆液,这就要求成型网部脱水量大,采用双叠网,在0.01%‑0.02%的上浆浓度下,2层斜网纸机来抄造复合纸也能保证脱水量足够,保证了复合纸的质量;采用湿轧的方法进行热轧,将毛胚纸用去离子水增湿,再将湿胚纸热轧,使得纸面强度高,且较光滑。

Figure 202210360540

The invention discloses a manufacturing method of low-cost pure meta-aramid fiber insulating composite paper, which belongs to the technical field of aramid paper preparation. 60-95 parts by weight of aramid fibrids; two-layer oblique wire lamination; deionized water is used for anilox roll water coating; hot rolling is carried out by means of flat rolling and back rolling in turn. In the present invention, fibrous fibrids are selected as fibrids, and their specific surface area is smaller than that of sheet-membrane fibrids, the water filtration is fast during papermaking, and the speed of papermaking is also faster, which can greatly improve the speed of papermaking; and the present invention adopts Ultra-low concentration slurry, which requires a large amount of dewatering in the forming wire, using a double-stacked wire, and at a sizing concentration of 0.01%-0.02%, a 2-layer inclined wire machine can also ensure sufficient dewatering capacity to make composite paper. The quality of the composite paper; the method of wet rolling is used for hot rolling, the rough paper is humidified with deionized water, and then the wet green paper is hot rolled to make the paper surface high in strength and smooth.

Figure 202210360540

Description

一种低成本纯间位芳纶绝缘复合纸的制造方法A kind of manufacturing method of low-cost pure meta-aramid fiber insulating composite paper

技术领域technical field

本发明涉及芳纶纸制备技术领域,尤其是涉及一种低成本纯间位芳纶绝缘复合纸的制造方法。The invention relates to the technical field of aramid paper preparation, in particular to a manufacturing method of low-cost pure meta-aramid insulating composite paper.

背景技术Background technique

间位芳纶纸是以间位芳纶短切纤维和间位芳纶沉析纤维为原料,采用湿法抄造和热轧成型制造的纸状耐高温材料,其中短切纤维提供机械强度,沉析纤维提供粘结,同时在绝缘应用中提供介电性能。Meta-aramid paper is a paper-like high-temperature resistant material made of meta-aramid chopped fibers and meta-aramid fibrids as raw materials, which are produced by wet lamination and hot rolling. The analyte fibers provide bonding while providing dielectric properties in insulation applications.

间位芳纶纸因其具备轻质高强、耐高温、阻燃、抗腐蚀以及优异介电性能,可作为绝缘材料和蜂窝芯材而广泛应用于航空航天、轨道交通、电气电子绝缘等领域。其中应用在绝缘领域的间位芳纶纸分为两大类:复合纸(A)和纯纸。复合纸一般是将其与聚酯薄膜(简称M)、聚酰亚胺薄膜(简称H或K)或者聚苯硫醚(简称P)复合后使用,形成结构AM二层结构或AMA三层结构复合材料。应用于电机的槽绝缘、匝间绝缘、衬垫绝缘和变压器线圈包扎绝缘等,目前已有完整的柔软复合材料标准规范JB/4061.1-1995。美国杜邦公司在该领域的典型产品型号为T464。Because of its light weight and high strength, high temperature resistance, flame retardant, corrosion resistance and excellent dielectric properties, meta-aramid paper can be widely used as insulating material and honeycomb core material in aerospace, rail transit, electrical and electronic insulation and other fields. Among them, the meta-aramid paper used in the insulation field is divided into two categories: composite paper (A) and pure paper. Composite paper is generally used after compounding it with polyester film (referred to as M), polyimide film (referred to as H or K) or polyphenylene sulfide (referred to as P) to form a structure AM two-layer structure or AMA three-layer structure composite material. It is used in slot insulation, inter-turn insulation, gasket insulation and transformer coil wrapping insulation of motors. At present, there is a complete standard specification for flexible composite materials JB/4061.1-1995. The typical product model of DuPont in this field is T464.

在柔软复合材料应用中,芳纶复合纸主要承担耐高温、抗撕、耐磨和增加挺度等作用,而对其绝缘作用的要求相对较低,T464/0.05mm介电强度10Kv/mm-12Kv/mm已经基本满足使用要求,相比较纯纸T410/0.05mm介电强度17.3Kv/mm,差距也比较大。同时,柔软复合材料的应用很广,需求量比较大,为了在激烈的市场竞争中立足,将此类产品定位为中性能和低成本,因此在保持一定性能的基础上,进行降本增效成为研发的重点。In the application of soft composite materials, aramid composite paper mainly bears the functions of high temperature resistance, tear resistance, wear resistance and increased stiffness, while the requirements for its insulation are relatively low, T464/0.05mm dielectric strength 10Kv/mm- 12Kv/mm has basically met the requirements for use. Compared with the dielectric strength of pure paper T410/0.05mm, which is 17.3Kv/mm, the gap is also relatively large. At the same time, the application of soft composite materials is very wide and the demand is relatively large. In order to gain a foothold in the fierce market competition, such products are positioned as medium-performance and low-cost, so on the basis of maintaining certain performance, cost reduction and efficiency increase become the focus of research and development.

在芳纶纸制造过程中,一般是通过将短切纤维和沉析纤维按一定比例混合在水介质中,然后在网上沉积,抄造形成原纸;再利用芳纶材料玻璃化转变原理,将原纸经过高温热轧,形成成品纸。因此抄造速度和热轧速度是降低复合纸成本的关键。In the manufacturing process of aramid paper, the base paper is generally formed by mixing chopped fibers and precipitating fibers in a certain proportion in an aqueous medium, and then depositing them on the web to form base paper; High temperature hot rolling to form finished paper. Therefore, the speed of papermaking and hot rolling is the key to reducing the cost of composite paper.

发明内容SUMMARY OF THE INVENTION

本发明的目的在于提供一种低成本纯间位芳纶绝缘复合纸的制造方法,以解决现有技术中芳纶复合纸成本高的技术问题。The purpose of the present invention is to provide a low-cost manufacturing method of pure meta-aramid fiber insulating composite paper, so as to solve the technical problem of high cost of aramid fiber composite paper in the prior art.

本发明提供一种低成本纯间位芳纶绝缘复合纸的制造方法,包括如下步骤:The invention provides a manufacturing method of low-cost pure meta-aramid fiber insulating composite paper, comprising the following steps:

Sp1:原料的制备,包括5-40重量份的芳纶短切纤维,以及60-95重量份的芳纶沉析纤维;Sp1: preparation of raw materials, including 5-40 parts by weight of aramid chopped fibers, and 60-95 parts by weight of aramid fibrids;

Sp1-1:所述芳纶短切纤维是长度为6-10mm、细度为1-3旦的间位芳纶纤维;Sp1-1: the aramid chopped fiber is a meta-aramid fiber with a length of 6-10mm and a fineness of 1-3 deniers;

Sp1-2:所述芳纶沉析纤维的制备包括如下步骤:Sp1-2: the preparation of the aramid fibrids comprises the following steps:

Sp1-2-1:准备低温间位芳纶聚合物;Sp1-2-1: Prepare low temperature meta-aramid polymer;

Sp1-2-2:配制凝固液;Sp1-2-2: prepare coagulation liquid;

Sp1-2-3:将所述间位芳纶聚合物通过喷嘴进入沉析机与所述凝固液混合,进行高速剪切搅拌,混合均匀,获得沉析纤维产物;Sp1-2-3: The meta-aramid fiber polymer is mixed with the coagulation liquid by entering the precipitator through a nozzle, and subjected to high-speed shearing and stirring, and the mixture is uniform to obtain a precipitating fiber product;

Sp1-2-4:对所述产物进行固化处理,再进行洗浆,获得所述芳纶沉析纤维;Sp1-2-4: curing the product, and then washing the pulp to obtain the aramid fibrid;

Sp2:两层斜网抄造;Sp2: Two-layer slanted net copying;

Sp2-1:将上述芳纶短切纤维原料在水中分散疏解,制成质量浓度为0.3-0.8%的芳纶短切纤维浆料;Sp2-1: Disperse and decompose the above-mentioned aramid chopped fiber raw material in water to prepare a aramid chopped fiber slurry with a mass concentration of 0.3-0.8%;

Sp2-2:将上述芳纶沉析纤维原料在水中分散疏解,盘磨直至叩解度为50-650SR,制成质量浓度为1-2%的芳纶沉析纤维浆料;Sp2-2: Disperse the above-mentioned aramid precipitation fiber raw materials in water, grind until the beating degree is 50-650SR, and prepare the aramid precipitation fiber slurry with a mass concentration of 1-2%;

Sp2-3:将芳纶短切纤维浆液和芳纶沉析纤维浆液在配料池中混合均匀后,使其浓度为0.01-0.02%,经调节浆液上网压头,通过中心布浆器横向布浆、匀整浆流.将速度一致、纤维分散的浆料上网进入斜网流浆箱,浆液被均匀分布到两层成型网上,多余浆液经溢流至白水池,当浆液沿成形网运行时,借助脱水压差的作用,水从纸浆中滤出,形成湿纸页,再经过纸机烘缸得到毛纸;Sp2-3: After mixing the aramid chopped fiber slurry and the aramid fibrid fibrous slurry uniformly in the batching tank, the concentration is 0.01-0.02%, and the slurry is adjusted horizontally through the central sizing device. , Homogenizing flow. The slurry with the same speed and fiber dispersion is fed into the inclined wire headbox, and the slurry is evenly distributed on the two-layer forming wire. The excess slurry overflows to the white pool. When the slurry runs along the forming wire, the Under the action of the dewatering pressure difference, the water is filtered out from the pulp to form a wet paper sheet, and then the wool paper is obtained through the drying cylinder of the paper machine;

Sp3:网纹辊涂水;Sp3: Anilox roller coating water;

Sp3-1:准备去离子水;Sp3-1: Prepare deionized water;

Sp3-2:选择适配的网纹辊,网纹辊一面与去离子水充分接触,保证辊面能吸附去离子水;Sp3-2: Select an appropriate anilox roller, one side of the anilox roller is fully in contact with deionized water to ensure that the roller surface can absorb deionized water;

Sp3-3:将毛纸贴在网纹辊另一面,在移动中涂水;Sp3-3: Stick the wool paper on the other side of the anilox roller and apply water while moving;

Sp4:热轧;Sp4: hot rolling;

Sp4-1:将涂水后的毛纸通过平轧的方式进行热轧:Sp4-1: Hot rolling the water-coated wool paper by flat rolling:

Sp4-2:通过平轧的毛纸再进行背辊压。Sp4-2: Back rolling through the flat rolled wool paper.

进一步,所述芳纶沉析纤维的制备中,所述喷嘴设置为方形,所述喷嘴的孔型设置为两种,制备丝状芳纶沉析纤维时,在所述喷嘴表面开设细圆孔;制备片膜状芳纶沉析纤维时,在所述喷嘴表面开设狭缝孔。现有技术下,国内外各生产厂家均有各自的沉析纤维生产方法,但从技术路径来看,由于其沉析机均采用大口径圆形喷嘴,在剪切作用下,生产出来的沉析纤维均为丝状纤维和片膜状沉析的混合物,并且粗细不均,而片膜状沉析纤维又比较影响抄造速度,本发明中,通过改进喷嘴的孔型,将圆形树脂喷嘴改为方型,并在方型喷嘴上再次细化,制作丝状沉析纤维时用细圆孔,数量较多,保证抄造速度,若将细圆孔改为狭缝孔,则能固定产出片膜状沉析纤维,即使在沉析机中有湍流存在,仍然可以保证绝大多数沉析纤维的膜状特性。Further, in the preparation of the aramid fibrids, the nozzles are set in a square shape, and the nozzles have two types of holes. When preparing the filamentous aramid fibrids, fine circular holes are opened on the surface of the nozzles. ; When the sheet-like aramid fibrid is prepared, slit holes are provided on the surface of the nozzle. Under the existing technology, various domestic and foreign manufacturers have their own methods for producing fibrid The precipitation fibers are a mixture of filamentous fibers and flake-like precipitation, and the thickness is uneven, and the flake-like precipitation fibers affect the papermaking speed. In the present invention, by improving the hole type of the nozzle, the circular resin nozzle is Change it to a square shape, and refine it again on the square nozzle. When making filamentous precipitating fibers, use fine round holes. The number is large to ensure the speed of copying. If the fine round holes are changed to slit holes, the production can be fixed. Film-like precipitating fibers are produced, even if there is turbulent flow in the precipitating machine, the film-like properties of most precipitating fibers can still be guaranteed.

进一步,所述芳纶沉析纤维的制备中,所述低温间位芳纶聚合物浓度为4-8%,相对粘度为0.8-1.3,温度控制在0-20℃。Further, in the preparation of the aramid fibrids, the low temperature meta-aramid polymer concentration is 4-8%, the relative viscosity is 0.8-1.3, and the temperature is controlled at 0-20°C.

进一步,所述芳纶沉析纤维的制备中,配制的凝固液为酰胺类溶剂与水的混合物,其中,酰胺类溶剂为二甲基乙酰胺,所述凝固液中所述酰胺类溶剂的含量为20-35%,所述凝固液的温度为0-20℃,所述低温间位芳纶聚合物与所述凝固液的质量比为1:10-30。Further, in the preparation of the aramid fiber, the prepared coagulation liquid is a mixture of an amide solvent and water, wherein the amide solvent is dimethylacetamide, and the content of the amide solvent in the coagulation liquid is is 20-35%, the temperature of the coagulation liquid is 0-20° C., and the mass ratio of the low-temperature meta-aramid polymer to the coagulation liquid is 1:10-30.

进一步,所述芳纶沉析纤维的制备中,高速搅拌的转速为4000-7000rpm。Further, in the preparation of the aramid fibrids, the rotating speed of the high-speed stirring is 4000-7000 rpm.

进一步,所述芳纶沉析纤维的制备中,所述固化处理为将所述产物进行盘磨机处理。经过盘磨机处理的沉析纤维,能够使得所述产物进一步舒展、固化。Further, in the preparation of the aramid fibrids, the curing treatment is to subject the product to a disc mill treatment. The fibrids processed by the disc mill can further stretch and solidify the product.

进一步,所述网纹辊涂水中,网纹辊涂水速度为80-100m/min,且湿度范围为10-30%。Further, in the anilox roller coating water, the anilox roller coating water speed is 80-100 m/min, and the humidity range is 10-30%.

进一步,所述热轧中,平轧工步下,热轧线压力为1-5MPa,轧辊表面温度为180-230℃,轧速为15-20m/min。Further, in the hot rolling, in the flat rolling step, the pressure of the hot rolling line is 1-5 MPa, the surface temperature of the roll is 180-230° C., and the rolling speed is 15-20 m/min.

进一步,所述热轧中,背辊轧工步下,辊间压力为0-4MPa,辊面温度为170-220℃,轧速为20-30m/min。本发明的热轧工艺采用平轧+背辊轧的双温双压区工,在平轧过程中,沉析纤维在高温下受热熔融软化,压区中的水促使柔软的沉析纤维有效地铺张和包裹在短切纤维表面,热应力迫使纤维分子间的距离变短,无定形区沿着一定的取向规整排列而进入结晶区,致使芳纶纸的结晶度提高;而背辊轧的目的是将平轧后的芳纶纸在略低的温度进行进一步的规整修复,使得其内部结构更加紧密,纸面更加光滑平整。Further, in the hot rolling, in the back rolling step, the pressure between the rolls is 0-4MPa, the roll surface temperature is 170-220°C, and the rolling speed is 20-30m/min. The hot rolling process of the present invention adopts the double temperature and double nip process of flat rolling and back rolling. During the flat rolling process, the precipitating fibers are melted and softened by heating at a high temperature, and the water in the nip promotes the soft precipitating fibers to effectively When stretched and wrapped on the surface of chopped fibers, thermal stress forces the distance between fiber molecules to shorten, and the amorphous area is regularly arranged along a certain orientation and enters the crystalline area, resulting in an increase in the crystallinity of the aramid paper; the purpose of back rolling It is to further repair the flat-rolled aramid paper at a slightly lower temperature, so that its internal structure is tighter and the paper surface is smoother and flatter.

与现有技术相比较,本发明的有益效果在于:Compared with the prior art, the beneficial effects of the present invention are:

其一,现有技术下,在保证芳纶复合纸的基本性能达标的情况下,由于其市场定位为中性能和低成本,因此,进行降本增效成为研发的重点,而抄造速度和热轧速度是降低复合纸成本的有效方法,针对此类问题,本发明设计了一种低成本纯间位芳纶绝缘复合纸的制造方法,依次通过原料的制备,两层斜网抄造,网纹辊涂水和热轧,得到成品芳纶复合纸,进行原料的制备时,短切纤维纤度一般为2D、1.5D和1D,长度一般为6mm,其比表面积较小,对抄速影响较小,而沉析纤维则选用丝状沉析纤维,尽管用丝状沉析纤维生产的的芳纶纸的结构较为疏松,介电强度也相对较低,一般在9-12Kv/mm,但是该档次介电强度已基本能达到复合用芳纶纸的应用需求,且其比表面积相对片膜状沉析纤维较小,在抄造时滤水快,抄造车速也较快,能够大大提高抄造速度;而为了保证纸页的匀度,本发明采用超低浓度浆液,这就要求成型网部脱水量大,传统工艺中,一般采用增设真空脱水箱或增加成型区间的总长度的方式来实现,一般选择多圆网、多斜网和多长网进行抄造,但网数增加后,会给操作控制带来难度,且成本也会增加,而本发明选择双叠网,在0.01%-0.02%的上浆浓度下,2层斜网纸机来抄造复合纸也能保证脱水量足够,保证了复合纸的质量,通过两层成形网的设计,使得斜网成形器具备低浓度大流量脱水成形能力,极大的提高了斜网抄造速度,也为纸页良好匀度及横幅定量创造了良好的工艺条件保证;另一方面,传统的热轧工艺中,多采用干轧的方法,由于芳纶纸热传导系数较低,热轧辊的温度设置较高,一般在275℃-295℃,虽然在高温区间情况下,沉析纤维熔融较好,但宽幅纸面的边沿收缩较大,会产生边沿起皱,同时白度下降,影响产品外观,若分切除去起皱纸边,则损耗增加,成本增加,而在相对低温区间情况下,虽然产品白度增加,但沉析纤维熔融不充分,纸面容易起毛,而本发明采用湿轧的方法进行热轧,将毛胚纸用去离子水增湿,然后将该湿胚纸进行热轧,水份作为一种塑化剂,可以降低芳纶纸的玻璃化转变温度Tg,在热轧时,沉析纤维熔融充分,纸面强度高,并且较为光滑。First, under the existing technology, under the condition that the basic performance of aramid composite paper is guaranteed to meet the standard, due to its market positioning as medium performance and low cost, cost reduction and efficiency increase have become the focus of research and development, while the speed of papermaking and heat Rolling speed is an effective method to reduce the cost of composite paper. In view of such problems, the present invention designs a manufacturing method of low-cost pure meta-aramid fiber insulating composite paper. Roll coating with water and hot rolling to obtain the finished aramid composite paper. When preparing the raw materials, the fineness of the chopped fibers is generally 2D, 1.5D and 1D, and the length is generally 6mm. , and fibrids use filamentous fibrids, although the structure of aramid paper produced with filamentous fibrids is relatively loose, and the dielectric strength is relatively low, generally 9-12Kv/mm, but this grade The dielectric strength can basically meet the application requirements of composite aramid paper, and its specific surface area is smaller than that of the film-like precipitating fiber, the water filtration is fast during papermaking, and the papermaking speed is also faster, which can greatly improve the papermaking speed; In order to ensure the evenness of the paper sheet, the present invention adopts ultra-low concentration slurry, which requires a large amount of dewatering in the forming wire. Multi-circle, multi-inclined and multi-long nets are used for copying, but when the number of nets increases, it will bring difficulty to operation control and increase the cost. In the present invention, double-stacked nets are selected, and the sizing is 0.01%-0.02%. Concentration, 2-layer slanted wire paper machine to make composite paper can also ensure sufficient dewatering capacity and ensure the quality of composite paper. Through the design of 2-layer forming wire, the slant wire forming machine has the ability of low-concentration and large-flow dewatering and forming. It greatly improves the speed of oblique wire making, and also creates a good process condition guarantee for the good evenness of the paper sheet and the quantification of the width of the paper. The coefficient is low, and the temperature setting of the hot roll is high, generally 275℃-295℃. Although the precipitating fiber melts better in the high temperature range, the edge of the wide paper surface shrinks greatly, which will cause edge wrinkling. At the same time, the whiteness decreases, which affects the appearance of the product. If the wrinkled paper edge is cut off, the loss will increase and the cost will increase. In the relatively low temperature range, although the whiteness of the product increases, the precipitating fiber is not fully melted, and the paper surface is not fully melted. It is easy to fluff, and the present invention adopts the method of wet rolling for hot rolling, moistens the rough paper with deionized water, and then hot-rolls the wet green paper. The glass transition temperature Tg is high. During hot rolling, the precipitation fibers are fully melted, and the paper surface has high strength and is relatively smooth.

其二,现有技术下,国内外各生产厂家均有各自的沉析纤维生产方法,但从技术路径来看,由于其沉析机均采用大口径圆形喷嘴,在剪切作用下,生产出来的沉析纤维均为丝状纤维和片膜状沉析的混合物,并且粗细不均,而片膜状沉析纤维又比较影响抄造速度,本发明中,通过改进喷嘴的孔型,将圆形树脂喷嘴改为方型,并在方型喷嘴上再次细化,制作丝状沉析纤维时用细圆孔,数量较多,保证抄造速度,若将细圆孔改为狭缝孔,则能固定产出片膜状沉析纤维,即使在沉析机中有湍流存在,仍然可以保证绝大多数沉析纤维的膜状特性。Second, under the existing technology, various domestic and foreign manufacturers have their own production methods for fibrid The precipitating fibers that come out are all mixtures of filamentous fibers and sheet-like precipitating fibers, and the thickness is uneven, and the sheet-like precipitating fibers relatively affect the speed of papermaking. In the present invention, by improving the hole type of the nozzle, the circular The resin nozzle is changed to a square type, and it is refined again on the square nozzle. When making filamentous fibrids, fine round holes are used, and the number is large to ensure the speed of copying. If the fine round holes are changed to slit holes, the The film-like precipitating fibers can be produced in a fixed manner. Even if there is turbulent flow in the precipitating machine, the film-like properties of most of the precipitating fibers can still be guaranteed.

其三,本发明中,热轧工艺采用平轧+背辊轧的双温双压区工,在平轧过程中,沉析纤维在高温下受热熔融软化,压区中的水促使柔软的沉析纤维有效地铺张和包裹在短切纤维表面,热应力迫使纤维分子间的距离变短,无定形区沿着一定的取向规整排列而进入结晶区,致使芳纶纸的结晶度提高;而背辊轧的目的是将平轧后的芳纶纸在略低的温度进行进一步的规整修复,使得其内部结构更加紧密,纸面更加光滑平整。Thirdly, in the present invention, the hot rolling process adopts the double temperature and double nip process of flat rolling and back rolling. During the flat rolling process, the precipitant fibers are melted and softened by heating at high temperature, and the water in the nip promotes the soft sinking. The analyte fibers are effectively stretched and wrapped on the surface of the chopped fibers, the thermal stress forces the distance between the fiber molecules to shorten, and the amorphous region is regularly arranged along a certain orientation and enters the crystalline region, resulting in an increase in the crystallinity of the aramid paper; The purpose of rolling is to further repair the flat-rolled aramid paper at a slightly lower temperature, so that its internal structure is tighter and the paper surface is smoother and flatter.

附图说明Description of drawings

为了更清楚地说明本发明具体实施方式或现有技术中的技术方案,下面将对具体实施方式或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施方式,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to illustrate the specific embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings that need to be used in the description of the specific embodiments or the prior art. Obviously, the accompanying drawings in the following description The drawings are some embodiments of the present invention. For those of ordinary skill in the art, other drawings can also be obtained based on these drawings without creative efforts.

图1为本发明的流程示意图;Fig. 1 is the schematic flow chart of the present invention;

图2为本发明中丝状沉析纤维喷嘴结构示意图;Fig. 2 is the structure schematic diagram of filamentous precipitating fiber nozzle in the present invention;

图3为本发明中热轧工艺的示意图。FIG. 3 is a schematic diagram of the hot rolling process in the present invention.

附图标记:Reference number:

1、细圆孔;2、狭缝孔;3、剪切刀。1. Thin round hole; 2. Slit hole; 3. Shearing knife.

具体实施方式Detailed ways

下面将结合附图对本发明的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。The technical solutions of the present invention will be clearly and completely described below with reference to the accompanying drawings. Obviously, the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments.

通常在此处附图中描述和显示出的本发明实施例的组件可以以各种不同的配置来布置和设计。因此,以下对在附图中提供的本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅表示本发明的选定实施例。The components of the embodiments of the invention generally described and shown in the drawings herein may be arranged and designed in a variety of different configurations. Thus, the following detailed description of the embodiments of the invention provided in the accompanying drawings is not intended to limit the scope of the invention as claimed, but is merely representative of selected embodiments of the invention.

基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

在本发明的描述中,需要说明的是,术语“中心”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”、“第三”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. The indicated orientation or positional relationship is based on the orientation or positional relationship shown in the accompanying drawings, which is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the indicated device or element must have a specific orientation or a specific orientation. construction and operation, and therefore should not be construed as limiting the invention. Furthermore, the terms "first", "second", and "third" are used for descriptive purposes only and should not be construed to indicate or imply relative importance.

在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that the terms "installed", "connected" and "connected" should be understood in a broad sense, unless otherwise expressly specified and limited, for example, it may be a fixed connection or a detachable connection Connection, or integral connection; can be mechanical connection, can also be electrical connection; can be directly connected, can also be indirectly connected through an intermediate medium, can be internal communication between two elements. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood in specific situations.

下面结合图1至图3所示,本发明实施例提供了一种低成本纯间位芳纶绝缘复合纸的制造方法,包括如下步骤:1 to 3, an embodiment of the present invention provides a method for manufacturing a low-cost pure meta-aramid fiber insulating composite paper, including the following steps:

Sp1:原料的制备,包括5-40重量份的芳纶短切纤维,以及60-95重量份的芳纶沉析纤维;Sp1: preparation of raw materials, including 5-40 parts by weight of aramid chopped fibers, and 60-95 parts by weight of aramid fibrids;

Sp1-1:芳纶短切纤维是长度为6-10mm、细度为1-3旦的间位芳纶纤维;Sp1-1: Aramid chopped fiber is a meta-aramid fiber with a length of 6-10mm and a fineness of 1-3 denier;

Sp1-2:芳纶沉析纤维的制备包括如下步骤:Sp1-2: The preparation of aramid fibrids includes the following steps:

Sp1-2-1:准备低温间位芳纶聚合物;Sp1-2-1: Prepare low temperature meta-aramid polymer;

Sp1-2-2:配制凝固液;Sp1-2-2: prepare coagulation liquid;

Sp1-2-3:将间位芳纶聚合物通过喷嘴进入沉析机与凝固液混合,进行高速剪切搅拌,混合均匀,获得沉析纤维产物;Sp1-2-3: The meta-aramid fiber polymer enters the precipitator through the nozzle and mixes with the coagulation liquid, performs high-speed shearing and stirring, and mixes evenly to obtain the fibrous product;

Sp1-2-4:对产物进行固化处理,再进行洗浆,获得芳纶沉析纤维;Sp1-2-4: solidify the product, and then wash the pulp to obtain aramid fibrids;

Sp2:两层斜网抄造;Sp2: Two-layer slanted net copying;

Sp2-1:将上述芳纶短切纤维原料在水中分散疏解,制成质量浓度为0.3-0.8%的芳纶短切纤维浆料;Sp2-1: Disperse and decompose the above-mentioned aramid chopped fiber raw material in water to prepare a aramid chopped fiber slurry with a mass concentration of 0.3-0.8%;

Sp2-2:将上述芳纶沉析纤维原料在水中分散疏解,盘磨直至叩解度为50-650SR,制成质量浓度为1-2%的芳纶沉析纤维浆料;Sp2-2: Disperse the above-mentioned aramid precipitation fiber raw materials in water, grind until the beating degree is 50-650SR, and prepare the aramid precipitation fiber slurry with a mass concentration of 1-2%;

Sp2-3:将芳纶短切纤维浆液和芳纶沉析纤维浆液在配料池中混合均匀后,使其浓度为0.01-0.02%,经调节浆液上网压头,通过中心布浆器横向布浆、匀整浆流.将速度一致、纤维分散的浆料上网进入斜网流浆箱,浆液被均匀分布到两层成型网上,多余浆液经溢流至白水池,当浆液沿成形网运行时,借助脱水压差的作用,水从纸浆中滤出,形成湿纸页,再经过纸机烘缸得到毛纸;Sp2-3: After mixing the aramid chopped fiber slurry and the aramid fibrid fibrous slurry uniformly in the batching tank, the concentration is 0.01-0.02%, and the slurry is adjusted horizontally through the central sizing device. , Homogenizing flow. The slurry with the same speed and fiber dispersion is fed into the inclined wire headbox, and the slurry is evenly distributed on the two-layer forming wire. The excess slurry overflows to the white pool. When the slurry runs along the forming wire, the Under the action of the dewatering pressure difference, the water is filtered out from the pulp to form a wet paper sheet, and then the wool paper is obtained through the drying cylinder of the paper machine;

Sp3:网纹辊涂水;Sp3: Anilox roller coating water;

Sp3-1:准备去离子水;Sp3-1: Prepare deionized water;

Sp3-2:选择适配的网纹辊,网纹辊一面与去离子水充分接触,保证辊面能吸附去离子水;Sp3-2: Select an appropriate anilox roller, one side of the anilox roller is fully in contact with deionized water to ensure that the roller surface can absorb deionized water;

Sp3-3:将毛纸贴在网纹辊另一面,在移动中涂水;Sp3-3: Stick the wool paper on the other side of the anilox roller and apply water while moving;

Sp4:热轧;Sp4: hot rolling;

Sp4-1:将涂水后的毛纸通过平轧的方式进行热轧:Sp4-1: Hot rolling the water-coated wool paper by flat rolling:

Sp4-2:通过平轧的毛纸再进行背辊压。Sp4-2: Back rolling through the flat rolled wool paper.

现有技术下,在保证芳纶复合纸的基本性能达标的情况下,由于其市场定位为中性能和低成本,因此,进行降本增效成为研发的重点,而抄造速度和热轧速度是降低复合纸成本的有效方法,针对此类问题,本发明设计了一种低成本纯间位芳纶绝缘复合纸的制造方法,依次通过原料的制备,两层斜网抄造,网纹辊涂水和热轧,得到成品芳纶复合纸,进行原料的制备时,短切纤维纤度一般为2D、1.5D和1D,长度一般为6mm,其比表面积较小,对抄速影响较小,而沉析纤维则选用丝状沉析纤维,尽管用丝状沉析纤维生产的的芳纶纸的结构较为疏松,介电强度也相对较低,一般在9-12Kv/mm,但是该档次介电强度已基本能达到复合用芳纶纸的应用需求,且其比表面积相对片膜状沉析纤维较小,在抄造时滤水快,抄造车速也较快,能够大大提高抄造速度;而为了保证纸页的匀度,本发明采用超低浓度浆液,这就要求成型网部脱水量大,传统工艺中,一般采用增设真空脱水箱或增加成型区间的总长度的方式来实现,一般选择多圆网、多斜网和多长网进行抄造,但网数增加后,会给操作控制带来难度,且成本也会增加,而本发明选择双叠网,在0.01%-0.02%的上浆浓度下,2层斜网纸机来抄造复合纸也能保证脱水量足够,保证了复合纸的质量,通过两层成形网的设计,使得斜网成形器具备低浓度大流量脱水成形能力,极大的提高了斜网抄造速度,也为纸页良好匀度及横幅定量创造了良好的工艺条件保证;另一方面,传统的热轧工艺中,多采用干轧的方法,由于芳纶纸热传导系数较低,热轧辊的温度设置较高,一般在275℃-295℃,虽然在高温区间情况下,沉析纤维熔融较好,但宽幅纸面的边沿收缩较大,会产生边沿起皱,同时白度下降,影响产品外观,若分切除去起皱纸边,则损耗增加,成本增加,而在相对低温区间情况下,虽然产品白度增加,但沉析纤维熔融不充分,纸面容易起毛,而本发明采用湿轧的方法进行热轧,将毛胚纸用去离子水增湿,然后将该湿胚纸进行热轧,水份作为一种塑化剂,可以降低芳纶纸的玻璃化转变温度Tg,在热轧时,沉析纤维熔融充分,纸面强度高,并且较为光滑。Under the existing technology, under the condition that the basic performance of aramid composite paper is guaranteed to meet the standard, due to its market positioning as medium performance and low cost, cost reduction and efficiency increase have become the focus of research and development, while the speed of papermaking and hot rolling are the highest. An effective method for reducing the cost of composite paper, in view of such problems, the present invention designs a low-cost manufacturing method of pure meta-aramid fiber insulating composite paper, which comprises the following steps: preparation of raw materials, two-layer oblique wire making, and anilox roller coating with water. and hot rolling to obtain the finished aramid composite paper. When preparing the raw materials, the fineness of the chopped fibers is generally 2D, 1.5D and 1D, and the length is generally 6mm. Filamentous fibrids are used for fibrillar fibers. Although the aramid paper produced with filamentous fibrids has a looser structure and a relatively low dielectric strength, generally 9-12Kv/mm, the dielectric strength of this grade is relatively low. It can basically meet the application requirements of composite aramid paper, and its specific surface area is smaller than that of sheet-like precipitating fibers, and it can filter water quickly during papermaking, and the speed of papermaking is also faster, which can greatly improve the papermaking speed. The evenness of the page, the ultra-low concentration slurry is used in the present invention, which requires a large amount of dehydration in the forming wire part. In the traditional process, it is generally achieved by adding a vacuum dewatering box or increasing the total length of the forming section. Generally, a multi-circle wire mesh is selected. , multi-slanted nets and multi-long nets are copied, but when the number of nets increases, it will bring difficulty to the operation control, and the cost will also increase, and the present invention selects double-stacked nets, under the sizing concentration of 0.01%-0.02%, The use of a 2-layer slanted wire machine to make composite paper can also ensure sufficient dewatering and ensure the quality of composite paper. Through the design of the 2-layer forming wire, the slant wire former has the ability to form low-concentration and high-flow dewatering, which greatly improves the It also improves the speed of oblique wire making, and also creates a good process condition guarantee for the good evenness of the paper and the quantification of the profile. On the other hand, in the traditional hot rolling process, the dry rolling method is mostly used, because the thermal conductivity of the aramid paper is low. , The temperature setting of the hot roll is relatively high, generally 275℃-295℃. Although the precipitation fiber melts better in the high temperature range, the edge of the wide paper surface shrinks greatly, which will cause edge wrinkling and whitening. The quality of the product decreases, which affects the appearance of the product. If the wrinkled paper edge is cut off, the loss will increase and the cost will increase. In the relatively low temperature range, although the whiteness of the product increases, the precipitating fiber is not fully melted, and the paper surface is prone to fluff. In the present invention, the wet rolling method is used for hot rolling, the blank paper is humidified with deionized water, and then the wet green paper is hot rolled, and the water content is used as a plasticizer, which can reduce the vitrification of the aramid paper. Transition temperature Tg, during hot rolling, the precipitating fibers are fully melted, the paper surface strength is high, and it is relatively smooth.

具体的,芳纶沉析纤维的制备中,喷嘴设置为方形,喷嘴的孔型设置为两种,制备丝状芳纶沉析纤维时,在喷嘴表面开设细圆孔1;制备片膜状芳纶沉析纤维时,在喷嘴表面开设狭缝孔2。现有技术下,国内外各生产厂家均有各自的沉析纤维生产方法,但从技术路径来看,由于其沉析机均采用大口径圆形喷嘴,在剪切作用下,生产出来的沉析纤维均为丝状纤维和片膜状沉析的混合物,并且粗细不均,而片膜状沉析纤维又比较影响抄造速度,本发明中,通过改进喷嘴的孔型,将圆形树脂喷嘴改为方型,并在方型喷嘴上再次细化,制作丝状沉析纤维时用细圆孔1,数量较多,保证抄造速度,若将细圆孔1改为狭缝孔2,则能固定产出片膜状沉析纤维,即使在沉析机中有湍流存在,仍然可以保证绝大多数沉析纤维的膜状特性。Specifically, in the preparation of aramid fibrids, the nozzles are set to be square, and the hole types of the nozzles are set to two. When preparing filamentous aramid fibrids, fine circular holes 1 are opened on the surface of the nozzles; When the fiber is fibrous, a slit hole 2 is opened on the surface of the nozzle. Under the existing technology, various domestic and foreign manufacturers have their own methods for producing fibrid The precipitation fibers are a mixture of filamentous fibers and flake-like precipitation, and the thickness is uneven, and the flake-like precipitation fibers affect the papermaking speed. In the present invention, by improving the hole type of the nozzle, the circular resin nozzle is Change it to a square type, and refine it again on the square nozzle. When making filamentous precipitating fibers, use thin round holes 1, and the number is large to ensure the speed of copying. If the thin round holes 1 are changed to slit holes 2, then The film-like precipitating fibers can be produced in a fixed manner. Even if there is turbulent flow in the precipitating machine, the film-like properties of most of the precipitating fibers can still be guaranteed.

具体的,芳纶沉析纤维的制备中,低温间位芳纶聚合物浓度为4-8%,相对粘度为0.8-1.3,温度控制在0-20℃。Specifically, in the preparation of aramid fibrids, the low temperature meta-aramid polymer concentration is 4-8%, the relative viscosity is 0.8-1.3, and the temperature is controlled at 0-20°C.

具体的,芳纶沉析纤维的制备中,配制的凝固液为酰胺类溶剂与水的混合物,其中,酰胺类溶剂为二甲基乙酰胺,凝固液中酰胺类溶剂的含量为20-35%,凝固液的温度为0-20℃,低温间位芳纶聚合物与凝固液的质量比为1:10-30。Specifically, in the preparation of aramid fibrids, the prepared coagulation liquid is a mixture of an amide solvent and water, wherein the amide solvent is dimethylacetamide, and the content of the amide solvent in the coagulation liquid is 20-35% , the temperature of the coagulation liquid is 0-20℃, and the mass ratio of the low temperature meta-aramid fiber polymer to the coagulation liquid is 1:10-30.

具体的,芳纶沉析纤维的制备中,高速搅拌的转速为4000-7000rpm。Specifically, in the preparation of aramid fibrids, the rotating speed of high-speed stirring is 4000-7000 rpm.

具体的,芳纶沉析纤维的制备中,固化处理为将产物进行盘磨机处理。经过盘磨机处理的沉析纤维,能够使得产物进一步舒展、固化。Specifically, in the preparation of the aramid fibrids, the curing treatment is to subject the product to a disc mill treatment. The precipitation fiber treated by the disc mill can further stretch and solidify the product.

具体的,网纹辊涂水中,网纹辊涂水速度为80-100m/min,且湿度范围为10-30%。Specifically, the anilox roller is coated with water, the speed of the anilox roller is 80-100 m/min, and the humidity range is 10-30%.

具体的,热轧中,平轧工步下,热轧线压力为1-5MPa,轧辊表面温度为180-230℃,轧速为15-20m/min。Specifically, in the hot rolling, in the flat rolling step, the hot rolling line pressure is 1-5MPa, the surface temperature of the roll is 180-230°C, and the rolling speed is 15-20m/min.

具体的,热轧中,背辊轧工步下,辊间压力为0-4MPa,辊面温度为170-220℃,轧速为20-30m/min。本发明的热轧工艺采用平轧+背辊轧的双温双压区工,在平轧过程中,沉析纤维在高温下受热熔融软化,压区中的水促使柔软的沉析纤维有效地铺张和包裹在短切纤维表面,热应力迫使纤维分子间的距离变短,无定形区沿着一定的取向规整排列而进入结晶区,致使芳纶纸的结晶度提高;而背辊轧的目的是将平轧后的芳纶纸在略低的温度进行进一步的规整修复,使得其内部结构更加紧密,纸面更加光滑平整。Specifically, in the hot rolling, under the back rolling step, the pressure between the rolls is 0-4MPa, the roll surface temperature is 170-220°C, and the rolling speed is 20-30m/min. The hot rolling process of the present invention adopts the double temperature and double nip process of flat rolling and back rolling. During the flat rolling process, the precipitating fibers are melted and softened by heating at a high temperature, and the water in the nip promotes the soft precipitating fibers to effectively When stretched and wrapped on the surface of chopped fibers, thermal stress forces the distance between fiber molecules to shorten, and the amorphous area is regularly arranged along a certain orientation and enters the crystalline area, resulting in an increase in the crystallinity of the aramid paper; the purpose of back rolling It is to further repair the flat-rolled aramid paper at a slightly lower temperature, so that its internal structure is tighter and the paper surface is smoother and flatter.

最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, but not to limit them; although the present invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: The technical solutions described in the foregoing embodiments can still be modified, or some or all of the technical features thereof can be equivalently replaced; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the technical solutions of the embodiments of the present invention. scope.

Claims (9)

1.一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:包括如下步骤:1. a manufacture method of low-cost pure meta-aramid fiber insulating composite paper, is characterized in that: comprise the steps: Sp1:原料的制备,包括5-40重量份的芳纶短切纤维,以及60-95重量份的芳纶沉析纤维;Sp1: preparation of raw materials, including 5-40 parts by weight of aramid chopped fibers, and 60-95 parts by weight of aramid fibrids; Sp1-1:所述芳纶短切纤维是长度为6-10mm、细度为1-3旦的间位芳纶纤维;Sp1-1: the aramid chopped fiber is a meta-aramid fiber with a length of 6-10mm and a fineness of 1-3 deniers; Sp1-2:所述芳纶沉析纤维的制备包括如下步骤:Sp1-2: the preparation of the aramid fibrids comprises the following steps: Sp1-2-1:准备低温间位芳纶聚合物;Sp1-2-1: Prepare low temperature meta-aramid polymer; Sp1-2-2:配制凝固液;Sp1-2-2: prepare coagulation liquid; Sp1-2-3:将所述间位芳纶聚合物通过喷嘴进入沉析机与所述凝固液混合,进行高速剪切搅拌,混合均匀,获得沉析纤维产物;Sp1-2-3: The meta-aramid fiber polymer is mixed with the coagulation liquid by entering the precipitator through a nozzle, and subjected to high-speed shearing and stirring, and the mixture is uniform to obtain a precipitating fiber product; Sp1-2-4:对所述产物进行固化处理,再进行洗浆,获得所述芳纶沉析纤维;Sp1-2-4: curing the product, and then washing the pulp to obtain the aramid fibrid; Sp2:两层斜网抄造;Sp2: Two-layer slanted net copying; Sp2-1:将上述芳纶短切纤维原料在水中分散疏解,制成质量浓度为0.3-0.8%的芳纶短切纤维浆料;Sp2-1: Disperse and decompose the above-mentioned aramid chopped fiber raw material in water to prepare a aramid chopped fiber slurry with a mass concentration of 0.3-0.8%; Sp2-2:将上述芳纶沉析纤维原料在水中分散疏解,盘磨直至叩解度为50-650SR,制成质量浓度为1-2%的芳纶沉析纤维浆料;Sp2-2: Disperse the above-mentioned aramid precipitation fiber raw materials in water, grind until the beating degree is 50-650SR, and prepare the aramid precipitation fiber slurry with a mass concentration of 1-2%; Sp2-3:将芳纶短切纤维浆液和芳纶沉析纤维浆液在配料池中混合均匀后,使其浓度为0.01-0.02%,经调节浆液上网压头,通过中心布浆器横向布浆、匀整浆流.将速度一致、纤维分散的浆料上网进入斜网流浆箱,浆液被均匀分布到两层成型网上,多余浆液经溢流至白水池,当浆液沿成形网运行时,借助脱水压差的作用,水从纸浆中滤出,形成湿纸页,再经过纸机烘缸得到毛纸;Sp2-3: After mixing the aramid chopped fiber slurry and the aramid fibrid fibrous slurry uniformly in the batching tank, the concentration is 0.01-0.02%, and the slurry is adjusted horizontally through the central sizing device. , Homogenizing flow. The slurry with the same speed and fiber dispersion is fed into the inclined wire headbox, and the slurry is evenly distributed on the two-layer forming wire. The excess slurry overflows to the white pool. When the slurry runs along the forming wire, the Under the action of the dewatering pressure difference, the water is filtered out from the pulp to form a wet paper sheet, and then the wool paper is obtained through the drying cylinder of the paper machine; Sp3:网纹辊涂水;Sp3: Anilox roller coating water; Sp3-1:准备去离子水;Sp3-1: Prepare deionized water; Sp3-2:选择适配的网纹辊,网纹辊一面与去离子水充分接触,保证辊面能吸附去离子水;Sp3-2: Select an appropriate anilox roller, one side of the anilox roller is fully in contact with deionized water to ensure that the roller surface can absorb deionized water; Sp3-3:将毛纸贴在网纹辊另一面,在移动中涂水;Sp3-3: Stick the wool paper on the other side of the anilox roller and apply water while moving; Sp4:热轧;Sp4: hot rolling; Sp4-1:将涂水后的毛纸通过平轧的方式进行热轧:Sp4-1: Hot rolling the water-coated wool paper by flat rolling: Sp4-2:通过平轧的毛纸再进行背辊压。Sp4-2: Back rolling through the flat rolled wool paper. 2.根据权利要求1所述的一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:所述芳纶沉析纤维的制备中,所述喷嘴设置为方形,所述喷嘴的孔型设置为两种,制备丝状芳纶沉析纤维时,在所述喷嘴表面开设细圆孔(1);制备片膜状芳纶沉析纤维时,在所述喷嘴表面开设狭缝孔(2)。2. The method for manufacturing a low-cost pure meta-aramid fiber insulating composite paper according to claim 1, characterized in that: in the preparation of the aramid fibrids, the nozzle is set to be square, and the nozzle is There are two kinds of hole types, when preparing filamentous aramid fibrids, open fine circular holes (1) on the surface of the nozzle; when preparing sheet-like aramid fibrids, open slits on the surface of the nozzle hole (2). 3.根据权利要求1所述的一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:所述芳纶沉析纤维的制备中,所述低温间位芳纶聚合物浓度为4-8%,相对粘度为0.8-1.3,温度控制在0-20℃。3. The manufacturing method of a kind of low-cost pure meta-aramid fiber insulating composite paper according to claim 1, characterized in that: in the preparation of the aramid fibrids, the low-temperature meta-aramid polymer concentration It is 4-8%, the relative viscosity is 0.8-1.3, and the temperature is controlled at 0-20 °C. 4.根据权利要求1所述的一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:所述芳纶沉析纤维的制备中,配制的凝固液为酰胺类溶剂与水的混合物,其中,酰胺类溶剂为二甲基乙酰胺,所述凝固液中所述酰胺类溶剂的含量为20-35%,所述凝固液的温度为0-20℃,所述低温间位芳纶聚合物与所述凝固液的质量比为1:10-30。4. The manufacturing method of a kind of low-cost pure meta-aramid fiber insulating composite paper according to claim 1, characterized in that: in the preparation of the aramid fibrids, the prepared coagulation liquid is an amide solvent and water mixture, wherein the amide solvent is dimethylacetamide, the content of the amide solvent in the coagulation liquid is 20-35%, the temperature of the coagulation liquid is 0-20 ℃, the low temperature meta The mass ratio of the aramid polymer to the coagulation liquid is 1:10-30. 5.根据权利要求1所述的一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:所述芳纶沉析纤维的制备中,高速搅拌的转速为4000-7000rpm。5 . The method for manufacturing a low-cost pure meta-aramid fiber insulating composite paper according to claim 1 , wherein: in the preparation of the aramid fibrids, the rotating speed of high-speed stirring is 4000-7000 rpm. 6 . 6.根据权利要求1所述的一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:所述芳纶沉析纤维的制备中,所述固化处理为将所述产物进行盘磨机处理。6 . The method for manufacturing a low-cost pure meta-aramid fiber insulating composite paper according to claim 1 , wherein: in the preparation of the aramid fibrids, the curing treatment is to perform the curing process on the product. 7 . Disc grinder processing. 7.根据权利要求1所述的一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:所述网纹辊涂水中,网纹辊涂水速度为80-100m/min,且湿度范围为10-30%。7. The manufacturing method of a low-cost pure meta-aramid fiber insulating composite paper according to claim 1, wherein the anilox roller is coated in water, and the anilox roller is coated with water at a speed of 80-100 m/min, And the humidity range is 10-30%. 8.根据权利要求1所述的一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:所述热轧中,平轧工步下,热轧线压力为1-5MPa,轧辊表面温度为180-230℃,轧速为15-20m/min。8. The manufacturing method of a low-cost pure meta-aramid fiber insulating composite paper according to claim 1, characterized in that: in the hot rolling, under the flat rolling step, the hot rolling line pressure is 1-5MPa, The surface temperature of the roll is 180-230℃, and the rolling speed is 15-20m/min. 9.根据权利要求1所述的一种低成本纯间位芳纶绝缘复合纸的制造方法,其特征在于:所述热轧中,背辊轧工步下,辊间压力为0-4MPa,辊面温度为170-220℃,轧速为20-30m/min。9 . The method for manufacturing a low-cost pure meta-aramid insulating composite paper according to claim 1 , wherein in the hot rolling, under the back rolling step, the pressure between the rolls is 0-4MPa, 10 . The roll surface temperature is 170-220℃, and the rolling speed is 20-30m/min.
CN202210360540.5A 2022-04-07 2022-04-07 Method for manufacturing low-cost pure meta-aramid insulating composite paper Pending CN114575176A (en)

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CN115075045A (en) * 2022-06-16 2022-09-20 赣州龙邦材料科技有限公司 Preparation method of uniform and flat aramid fiber honeycomb paper
CN115125765A (en) * 2022-06-14 2022-09-30 株洲时代华先材料科技有限公司 Preparation method of low-air permeability and low-quantitative meta-aramid honeycomb paper
CN115198567A (en) * 2022-06-28 2022-10-18 陈克复 High-performance aramid laminated board and preparation method and application thereof
CN115897292A (en) * 2022-10-28 2023-04-04 株洲时代华先材料科技有限公司 Aramid crepe paper and preparation method thereof
CN116905272A (en) * 2023-08-29 2023-10-20 赣州龙邦材料科技有限公司 A method for manufacturing high stiffness and wear-resistant aramid paper
CN116905271A (en) * 2023-07-14 2023-10-20 赣州龙邦材料科技有限公司 Aramid and airgel composite paper and preparation method thereof
WO2025015741A1 (en) * 2023-07-14 2025-01-23 赣州龙邦材料科技有限公司 Preparation method for spreading and smoothing paper surface after hot rolling of high-performance aramid paper

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CN115125765A (en) * 2022-06-14 2022-09-30 株洲时代华先材料科技有限公司 Preparation method of low-air permeability and low-quantitative meta-aramid honeycomb paper
CN115075045A (en) * 2022-06-16 2022-09-20 赣州龙邦材料科技有限公司 Preparation method of uniform and flat aramid fiber honeycomb paper
CN115198567A (en) * 2022-06-28 2022-10-18 陈克复 High-performance aramid laminated board and preparation method and application thereof
CN115198567B (en) * 2022-06-28 2023-10-13 陈克复 High-performance aramid laminate and preparation method and application thereof
CN115897292A (en) * 2022-10-28 2023-04-04 株洲时代华先材料科技有限公司 Aramid crepe paper and preparation method thereof
CN116905271A (en) * 2023-07-14 2023-10-20 赣州龙邦材料科技有限公司 Aramid and airgel composite paper and preparation method thereof
WO2025015741A1 (en) * 2023-07-14 2025-01-23 赣州龙邦材料科技有限公司 Preparation method for spreading and smoothing paper surface after hot rolling of high-performance aramid paper
CN116905272A (en) * 2023-08-29 2023-10-20 赣州龙邦材料科技有限公司 A method for manufacturing high stiffness and wear-resistant aramid paper

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