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CN114551450A - Semiconductor structure and method of making the same - Google Patents

Semiconductor structure and method of making the same Download PDF

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Publication number
CN114551450A
CN114551450A CN202210174057.8A CN202210174057A CN114551450A CN 114551450 A CN114551450 A CN 114551450A CN 202210174057 A CN202210174057 A CN 202210174057A CN 114551450 A CN114551450 A CN 114551450A
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electrode
layer
dielectric layer
hole
substrate
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邵光速
吴敏敏
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Changxin Memory Technologies Inc
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/30DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
    • H10B12/33DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells the capacitor extending under the transistor
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/01Manufacture or treatment
    • H10B12/02Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
    • H10B12/03Making the capacitor or connections thereto
    • H10B12/036Making the capacitor or connections thereto the capacitor extending under the transistor
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/30DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
    • H10B12/48Data lines or contacts therefor
    • H10B12/482Bit lines

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Semiconductor Memories (AREA)
  • Semiconductor Integrated Circuits (AREA)

Abstract

The embodiment of the present disclosure provides a semiconductor structure and a manufacturing method thereof, wherein the semiconductor structure comprises: a substrate; the first electrode is positioned on the substrate and surrounds a through hole extending towards the direction far away from the substrate; the second electrode is at least positioned in the through hole; the capacitor dielectric layer is positioned between the first electrode and the second electrode, the capacitor dielectric layer and the first electrode form a capacitor structure; the transistor is positioned on the capacitor structure and comprises a first doping area and a second doping area which are arranged at intervals along the direction vertical to the surface of the substrate, the first doping area is electrically connected with the second electrode, the doping type of the first doping area and the doping type of the second doping area are one of N type or P type, and the doping types of the first doping area and the second doping area are the same; and the bit line is positioned on the transistor and is electrically connected with the second doped region. The embodiment of the disclosure is at least beneficial to improving the performance of the semiconductor device and reducing the difficulty of the manufacturing process.

Description

半导体结构及其制造方法Semiconductor structure and method of making the same

技术领域technical field

本公开实施例涉及半导体技术领域,特别涉及一种半导体结构及其制造方法。Embodiments of the present disclosure relate to the field of semiconductor technology, and in particular, to a semiconductor structure and a method for manufacturing the same.

背景技术Background technique

随着半导体技术的发展,制造出性能更优、集成度更高的半导体器件已成为了半导体加工过程中追求的主要方向。With the development of semiconductor technology, the manufacture of semiconductor devices with better performance and higher integration has become the main direction pursued in the semiconductor processing process.

然而,尺寸更小的半导体器件的制造工艺复杂,对加工设备的性能要求极高,并且,通过改进加工设备的性能从而提高加工精度的方式实现难度较大。However, the manufacturing process of the smaller-sized semiconductor device is complex, and the performance of the processing equipment is extremely required, and it is difficult to realize the method of improving the processing accuracy by improving the performance of the processing equipment.

所以,对半导体器件结构的布局以及形成方式进行改进,是使半导体器件满足性能更优、尺寸更小的同时降低半导体器件加工难度的有效方式。Therefore, improving the layout and formation method of the semiconductor device structure is an effective way to make the semiconductor device meet the requirements of better performance and smaller size while reducing the processing difficulty of the semiconductor device.

发明内容SUMMARY OF THE INVENTION

本公开实施例提供一种半导体结构及其制造方法,至少有利于提高半导体器件的性能并降低制造工艺难度。Embodiments of the present disclosure provide a semiconductor structure and a manufacturing method thereof, which are at least beneficial to improve the performance of the semiconductor device and reduce the difficulty of the manufacturing process.

本公开实施例一方面提供一种半导体结构,包括:基底;第一电极,第一电极位于基底上,第一电极围成朝向远离基底方向延伸的通孔;第二电极,第二电极至少位于通孔内;电容介质层,电容介质层位于第一电极与第二电极之间,第二电极、电容介质层以及第一电极构成电容结构;晶体管,晶体管位于电容结构上,且晶体管包括沿垂直于基底表面方向间隔排布的第一掺杂区和第二掺杂区,第一掺杂区与第二电极电连接,第一掺杂区和第二掺杂区的掺杂类型为N型或者P型中的一者,且第一掺杂区和第二掺杂区的掺杂类型相同;位线,位线位于晶体管上,且与第二掺杂区电连接。In one aspect, an embodiment of the present disclosure provides a semiconductor structure, comprising: a substrate; a first electrode, the first electrode is located on the substrate, the first electrode encloses a through hole extending in a direction away from the substrate; a second electrode, the second electrode is at least located on the substrate In the through hole; the capacitor dielectric layer, the capacitor dielectric layer is located between the first electrode and the second electrode, the second electrode, the capacitor dielectric layer and the first electrode form a capacitor structure; the transistor, the transistor is located on the capacitor structure, and the transistor includes a vertical The first doping region and the second doping region are arranged at intervals in the direction of the surface of the substrate, the first doping region is electrically connected to the second electrode, and the doping type of the first doping region and the second doping region is N-type Or one of the P-type, and the doping types of the first doping region and the second doping region are the same; the bit line is located on the transistor and is electrically connected to the second doping region.

在一些实施例中,还包括:绝缘层,电容结构位于绝缘层内,且绝缘层暴露出第二电极顶面;通孔远离第二电极的外侧壁与绝缘层相接触;通孔被第二电极和电容介质层共同填满,且第二电极顶面与电容介质层顶面齐平。In some embodiments, the method further includes: an insulating layer, the capacitor structure is located in the insulating layer, and the insulating layer exposes the top surface of the second electrode; the outer sidewall of the through hole away from the second electrode is in contact with the insulating layer; the through hole is surrounded by the second electrode. The electrodes and the capacitive dielectric layer are filled together, and the top surface of the second electrode is flush with the top surface of the capacitive dielectric layer.

在一些实施例中,电容介质层还位于第一电极顶面以及绝缘层顶面,且第二电极顶面与电容介质层顶面齐平。In some embodiments, the capacitive dielectric layer is further located on the top surface of the first electrode and the top surface of the insulating layer, and the top surface of the second electrode is flush with the top surface of the capacitive dielectric layer.

在一些实施例中,第二电极还位于通孔的外侧壁以及第一电极顶面,且第二电极包括:第一主体部,第一主体部位于通孔内;第二主体部,第二主体部位于通孔的外侧壁,第二主体部的材料与第一主体部的材料相同,且在平行于基底表面方向上,第一主体部的厚度大于第二主体部的厚度;电连接部,电连接部横跨第一主体部以及第二主体部,且与第一主体部顶面和第二主体部顶面相接触。In some embodiments, the second electrode is further located on the outer sidewall of the through hole and the top surface of the first electrode, and the second electrode includes: a first main body part, the first main body part is located in the through hole; The main body part is located on the outer side wall of the through hole, the material of the second main body part is the same as the material of the first main body part, and in the direction parallel to the surface of the substrate, the thickness of the first main body part is greater than the thickness of the second main body part; the electrical connection part , the electrical connection part spans the first main body part and the second main body part, and is in contact with the top surface of the first main body part and the top surface of the second main body part.

在一些实施例中,对于同一电容结构,第二电极为一体成型结构。In some embodiments, for the same capacitor structure, the second electrode is an integrally formed structure.

在一些实施例中,第一电极包括:侧边部,侧边部为通孔的侧壁部分;底连接部,底连接部为通孔平行于基底的底面部分;半导体结构还包括:电连接层,电连接层位于基底上,且电连接相邻的底连接部。In some embodiments, the first electrode includes: a side portion, where the side portion is a side wall portion of the through hole; a bottom connection portion, where the bottom connection portion is a bottom surface portion of the through hole parallel to the substrate; the semiconductor structure further includes: an electrical connection layer, and the electrical connection layer is located on the substrate and electrically connects the adjacent bottom connection parts.

在一些实施例中,电连接层与底连接部为一体成型膜层,且电容介质层还位于电连接层表面。In some embodiments, the electrical connection layer and the bottom connection portion are integrally formed as a film layer, and the capacitive dielectric layer is also located on the surface of the electrical connection layer.

在一些实施例中,侧边部与底连接部为一体成型膜层,且电连接层还位于底连接部与基底之间。In some embodiments, the side portion and the bottom connecting portion are integrally formed into a film layer, and the electrical connecting layer is also located between the bottom connecting portion and the substrate.

在一些实施例中,晶体管还包括:沟道区,沟道区位于第一掺杂区与第二掺杂区之间,且沟道区、第一掺杂区以及第二掺杂区的材料至少包括IGZO、IWO或者ITO中的一种或多种;栅介质层,栅介质层环绕沟道区设置,且位于沟道区的侧壁表面;栅导电层,栅导电层环绕沟道区设置,且位于沟道区对应的栅介质层的侧壁表面。In some embodiments, the transistor further includes: a channel region, the channel region is located between the first doping region and the second doping region, and the material of the channel region, the first doping region and the second doping region is At least one or more of IGZO, IWO or ITO is included; a gate dielectric layer, the gate dielectric layer is arranged around the channel region, and is located on the sidewall surface of the channel region; the gate conductive layer, the gate conductive layer is arranged around the channel region , and is located on the sidewall surface of the gate dielectric layer corresponding to the channel region.

本公开实施例另一方面还提供一种半导体结构的制造方法,包括:提供基底;在基底上形成第一电极,第一电极围成朝向远离基底方向延伸的通孔;形成第二电极,第二电极至少位于通孔内;形成电容介质层,电容介质层位于第一电极与第二电极之间,第二电极、电容介质层以及第一电极构成电容结构;形成晶体管,晶体管位于电容结构上,且晶体管包括沿垂直于基底表面方向间隔排布的第一掺杂区和第二掺杂区,第一掺杂区与第二电极电连接,第一掺杂区和第二掺杂区的掺杂类型为N型或者P型中的一者,且第一掺杂区和第二掺杂区的掺杂类型相同;形成位线,位线位于晶体管上,且与第二掺杂区电连接。Another aspect of the embodiments of the present disclosure further provides a method for fabricating a semiconductor structure, including: providing a substrate; forming a first electrode on the substrate, the first electrode enclosing a through hole extending in a direction away from the substrate; forming a second electrode, the first electrode Two electrodes are located at least in the through holes; a capacitor dielectric layer is formed, the capacitor dielectric layer is located between the first electrode and the second electrode, and the second electrode, the capacitor dielectric layer and the first electrode form a capacitor structure; a transistor is formed, and the transistor is located on the capacitor structure , and the transistor includes a first doping region and a second doping region spaced along a direction perpendicular to the surface of the substrate, the first doping region is electrically connected to the second electrode, and the first doping region and the second doping region are The doping type is one of N-type or P-type, and the doping types of the first doping region and the second doping region are the same; a bit line is formed, and the bit line is located on the transistor and electrically connected to the second doping region. connect.

在一些实施例中,形成第一电极的步骤包括:在基底上形成绝缘膜,且绝缘膜内具有贯穿绝缘膜厚度的凹槽;形成第一电极,第一电极位于凹槽的底部和侧壁。In some embodiments, the step of forming the first electrode includes: forming an insulating film on the substrate, and the insulating film has a groove through the thickness of the insulating film; forming a first electrode, the first electrode is located on the bottom and sidewalls of the groove .

在一些实施例中,剩余绝缘膜作为绝缘层;形成电容介质层以及第二电极的步骤包括:形成电容介质层,电容介质层位于通孔底部和侧壁;形成第二电极层,第二电极层位于电容介质层表面且填充通孔。In some embodiments, the remaining insulating film is used as an insulating layer; the steps of forming a capacitor dielectric layer and the second electrode include: forming a capacitor dielectric layer, and the capacitor dielectric layer is located at the bottom and sidewalls of the through hole; forming a second electrode layer, the second electrode The layer is on the surface of the capacitive dielectric layer and fills the via.

在一些实施例中,形成电容介质层以及第二电极的步骤包括:去除剩余绝缘膜,露出通孔的外侧壁;形成电容介质层,电容介质层位于通孔的底部、内侧壁以及外侧壁;形成第二电极,第二电极位于电容介质层表面,且还位于通孔内以及通孔外侧壁上。In some embodiments, the steps of forming the capacitor dielectric layer and the second electrode include: removing the remaining insulating film to expose the outer sidewall of the through hole; forming a capacitor dielectric layer, the capacitor dielectric layer is located on the bottom, inner sidewall and outer sidewall of the through hole; A second electrode is formed, and the second electrode is located on the surface of the capacitor dielectric layer, and also located in the through hole and on the outer sidewall of the through hole.

在一些实施例中,还包括:形成绝缘层,绝缘层位于基底上;形成绝缘层以及第二电极的工艺步骤包括:形成第一主体部和第二主体部,第一主体部位于通孔内,第二主体部位于通孔的外侧壁,第二主体部的材料与第一主体部的材料相同;在基底上形成绝缘层,绝缘层位于第二主体部侧壁;形成电连接部,电连接部横跨第一主体部以及第二主体部,且与第一主体部顶面和第二主体部顶面相接触,电连接部、第一主体部以及第二主体部共同构成第二电极。In some embodiments, the method further includes: forming an insulating layer, and the insulating layer is located on the substrate; the process step of forming the insulating layer and the second electrode includes: forming a first main body part and a second main body part, and the first main body part is located in the through hole , the second body part is located on the outer sidewall of the through hole, and the material of the second body part is the same as that of the first body part; an insulating layer is formed on the substrate, and the insulating layer is located on the sidewall of the second body part; The connection part spans the first main body part and the second main body part and is in contact with the top surface of the first main body part and the top surface of the second main body part, and the electrical connection part, the first main body part and the second main body part together constitute the second electrode.

在一些实施例中,在形成第一电极之前,还包括:在基底上形成电连接层,电连接层与第一电极电连接。In some embodiments, before forming the first electrode, the method further includes: forming an electrical connection layer on the substrate, and the electrical connection layer is electrically connected to the first electrode.

本公开实施例提供的技术方案至少具有以下优点:半导体结构的电容结构位于晶体管的下方,这种排布方式主要有以下两方面的优势:一方面,在形成晶体管后,可直接在露出的第二掺杂区上形成位线结构,相较于传统的埋入式位线,这种形成位线的工艺更加简单;另一方面,这种排布方式的电容结构克服了制造产线上对后道工艺的限制,那么即可实现电容结构与晶体结构的多层堆叠,增大存储容量,并且,在多层堆叠的情况下,降低了对单层结构缩小尺寸的要求,可适当增大单层结构的尺寸,降低工艺难度。此外,电容结构为柱状电容,在有限的空间内,第一电极与第二电极的相对面积更大,增大存储容量。The technical solutions provided by the embodiments of the present disclosure have at least the following advantages: the capacitor structure of the semiconductor structure is located below the transistor, and this arrangement has the following advantages: The bit line structure is formed on the two-doped region. Compared with the traditional buried bit line, the process of forming the bit line is simpler; The limitation of the back-end process, then the multi-layer stacking of the capacitor structure and the crystal structure can be realized, and the storage capacity can be increased. The size of the single-layer structure reduces the difficulty of the process. In addition, the capacitor structure is a columnar capacitor, and in a limited space, the opposing area of the first electrode and the second electrode is larger, thereby increasing the storage capacity.

附图说明Description of drawings

一个或多个实施例通过与之对应的附图中的图片进行示例性说明,这些示例性说明并不构成对实施例的限定,除非有特别申明,附图中的图不构成比例限制;为了更清楚地说明本公开实施例或传统技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本公开的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。One or more embodiments are exemplified by the pictures in the corresponding accompanying drawings, and these exemplary descriptions do not constitute limitations on the embodiments, unless otherwise stated, the drawings in the accompanying drawings do not constitute a scale limitation; In order to more clearly illustrate the technical solutions in the embodiments of the present disclosure or in the traditional technology, the accompanying drawings required in the embodiments will be briefly introduced below. Obviously, the accompanying drawings in the following description are only some embodiments of the present disclosure. , for those of ordinary skill in the art, other drawings can also be obtained based on these drawings without any creative effort.

图1为本公开一实施例提供的半导体结构的竖直方向剖面结构示意图;FIG. 1 is a schematic cross-sectional structural diagram of a semiconductor structure in a vertical direction according to an embodiment of the present disclosure;

图2为图1所示实施例的电容结构的水平方向剖面结构图;FIG. 2 is a horizontal cross-sectional structural view of the capacitor structure of the embodiment shown in FIG. 1;

图3为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;3 is a schematic cross-sectional structural diagram of a semiconductor structure in a vertical direction according to another embodiment of the present disclosure;

图4为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;4 is a schematic cross-sectional structural diagram of a semiconductor structure in a vertical direction according to another embodiment of the present disclosure;

图5为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;5 is a schematic cross-sectional structural diagram of a semiconductor structure in a vertical direction according to another embodiment of the present disclosure;

图6为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;6 is a schematic cross-sectional structural diagram of a semiconductor structure in a vertical direction according to another embodiment of the present disclosure;

图7为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;7 is a schematic cross-sectional structural schematic diagram of a semiconductor structure in a vertical direction according to another embodiment of the present disclosure;

图8为图7所示实施例的晶体管的水平方向剖面结构图;FIG. 8 is a horizontal cross-sectional structural view of the transistor of the embodiment shown in FIG. 7;

图9为图7所示实施例不包括隔离层的俯视图;FIG. 9 is a top view of the embodiment shown in FIG. 7 without an isolation layer;

图10至图25为本公开实施例提供的半导体结构的制备方法各步骤对应的结构示意图。10 to FIG. 25 are schematic structural diagrams corresponding to each step of a method for fabricating a semiconductor structure according to an embodiment of the present disclosure.

具体实施方式Detailed ways

由背景技术可知,通过改进加工设备的性能从而提高加工精度的方式实现难度较大,对半导体器件结构的布局以及形成方式进行改进,是使半导体器件满足性能更优的同时降低尺寸集成的有效方式。It can be seen from the background art that it is more difficult to improve the processing accuracy by improving the performance of the processing equipment. Improving the layout and formation of the semiconductor device structure is an effective way to make the semiconductor device meet the requirements of better performance and reduce the size of the integration. .

为解决上述问题,本公开实施例提供了一种半导体结构及其制造方法,通过对电容结构和晶体管的位置关系的调整,使半导体结构的位线的加工工艺更加简单,并且,有利于实现存储器的3D(3Dimensions)堆叠,增加半导体结构的集成密度。此外,通过增大第一电极与第二电极的相对面积,增大了电容容量,进而增大了存储容量。In order to solve the above problems, the embodiments of the present disclosure provide a semiconductor structure and a manufacturing method thereof. By adjusting the positional relationship between the capacitor structure and the transistor, the processing technology of the bit line of the semiconductor structure is simpler, and it is beneficial to realize the memory The 3D (3Dimensions) stacking increases the integration density of semiconductor structures. In addition, by increasing the opposing area of the first electrode and the second electrode, the capacitance capacity is increased, thereby increasing the storage capacity.

下面将结合附图对本公开各实施例进行详细的阐述。然而,本领域的普通技术人员可以理解,在本公开各实施例中,为了使读者更好地理解本公开实施例而提出了许多技术细节。但是,即使没有这些技术细节和基于以下各实施例的种种变化和修改,也可以实现本公开实施例所要求保护的技术方案。The embodiments of the present disclosure will be described in detail below with reference to the accompanying drawings. However, those of ordinary skill in the art can appreciate that, in the various embodiments of the present disclosure, many technical details are provided for the reader to better understand the embodiments of the present disclosure. However, even without these technical details and various changes and modifications based on the following embodiments, the technical solutions claimed in the embodiments of the present disclosure can be implemented.

图1为本公开一实施例提供的半导体结构的竖直方向剖面结构示意图;图2为图1所示实施例的电容结构的水平方向剖面结构图;图3为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;图4为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;图5为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;图6为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;图7为本公开另一实施例提供的半导体结构的竖直方向剖面结构示意图;图8为图7所示实施例的晶体管的水平方向剖面结构图;图9为图7所示实施例不包括隔离层的俯视图。1 is a schematic diagram of a vertical cross-sectional structure of a semiconductor structure provided by an embodiment of the present disclosure; FIG. 2 is a horizontal cross-sectional structural diagram of a capacitor structure of the embodiment shown in FIG. 1 ; FIG. 3 is provided by another embodiment of the present disclosure. A schematic view of a vertical cross-sectional structure of a semiconductor structure; FIG. 4 is a schematic view of a vertical cross-sectional structure of a semiconductor structure provided by another embodiment of the present disclosure; FIG. 5 is a vertical cross-sectional structure of a semiconductor structure provided by another embodiment of the present disclosure 6 is a schematic view of a vertical cross-sectional structure of a semiconductor structure provided by another embodiment of the present disclosure; FIG. 7 is a schematic view of a vertical cross-sectional structure of a semiconductor structure provided by another embodiment of the present disclosure; FIG. 9 is a top view of the embodiment shown in FIG. 7 without an isolation layer.

参考图1至图9,半导体结构包括:基底100;第一电极102,第一电极102位于基底100上,第一电极102围成朝向远离基底100方向延伸的通孔;第二电极104,第二电极104至少位于通孔内;电容介质层103,电容介质层103位于第一电极102与第二电极104之间,第二电极104、电容介质层103以及第一电极102构成电容结构110;晶体管111,晶体管111位于电容结构110上,且晶体管111包括沿垂直于基底100表面方向间隔排布的第一掺杂区I和第二掺杂区III,第一掺杂区I与第二电极104电连接,第一掺杂区I和第二掺杂区III的掺杂类型为N型或者P型中的一者,且第一掺杂区I和第二掺杂区III的掺杂类型相同;位线112,位线112位于晶体管111上,且与第二掺杂区III电连接。1 to 9, the semiconductor structure includes: a substrate 100; a first electrode 102, the first electrode 102 is located on the substrate 100, the first electrode 102 encloses a through hole extending away from the substrate 100; The two electrodes 104 are at least located in the through holes; the capacitor dielectric layer 103 is located between the first electrode 102 and the second electrode 104, and the second electrode 104, the capacitor dielectric layer 103 and the first electrode 102 constitute the capacitor structure 110; Transistor 111, the transistor 111 is located on the capacitor structure 110, and the transistor 111 includes a first doped region I and a second doped region III spaced along a direction perpendicular to the surface of the substrate 100, the first doped region I and the second electrode 104 is electrically connected, the doping type of the first doping region I and the second doping region III is one of N-type or P-type, and the doping type of the first doping region I and the second doping region III The same; the bit line 112, the bit line 112 is located on the transistor 111, and is electrically connected to the second doped region III.

由于半导体结构包括垂直的全环绕栅极(GAA,Gate-All-Around)晶体管111,且晶体111管的制造工艺温度与电容结构110中的导电材料以及位线112的导电材料相兼容,使晶体管111可堆叠在电容结构110上或者位线112上,因而可构成3D堆叠的存储器件,有利于提高半导体结构的集成密度。此外,在3D堆叠的基础上,适当增大单层存储器件的尺寸,有利于降低制造难度。位线112位于晶体管111上,那么,相对于埋入式位线112,本实施例中叠加在晶体管111上的位线112形成方式更加简单。并且,由于第二电极104位于第一电极102围成的通孔内,对比于平面电容,朝向通孔内壁的第二电极104的外侧壁表面与第一电极102的通孔的内侧壁的相对面积更大,具有更大的电容容量。Since the semiconductor structure includes a vertical gate-all-around (GAA, Gate-All-Around) transistor 111, and the manufacturing process temperature of the transistor 111 is compatible with the conductive material in the capacitor structure 110 and the conductive material in the bit line 112, the transistor The 111 can be stacked on the capacitor structure 110 or on the bit line 112, so that a 3D stacked memory device can be formed, which is beneficial to improve the integration density of the semiconductor structure. In addition, on the basis of 3D stacking, appropriately increasing the size of the single-layer memory device is beneficial to reduce the manufacturing difficulty. The bit line 112 is located on the transistor 111 , then, compared with the buried bit line 112 , the formation of the bit line 112 superimposed on the transistor 111 in this embodiment is simpler. Moreover, since the second electrode 104 is located in the through hole surrounded by the first electrode 102 , compared with the planar capacitor, the surface of the outer side wall of the second electrode 104 facing the inner wall of the through hole is opposite to the inner side wall of the through hole of the first electrode 102 . Larger area and larger capacitance.

参考图1,本实施例中,由于位于基底100上的第一电极102与基底100接触,为了提高第一电极102的电位稳定性,基底100可以为绝缘材料,例如,二氧化硅,氮氧化硅等,且基底100内可以具有导电层(图中未示出)。导电层与第一电极102电连接,用于引出第一电极102,并且,多个第一电极102可与同一导线层电连接,有利于节省走线空间,缩小半导体结构的尺寸。Referring to FIG. 1, in this embodiment, since the first electrode 102 on the substrate 100 is in contact with the substrate 100, in order to improve the potential stability of the first electrode 102, the substrate 100 may be an insulating material, such as silicon dioxide, oxynitride Silicon, etc., and the substrate 100 may have a conductive layer (not shown in the figure). The conductive layer is electrically connected to the first electrode 102 for drawing out the first electrode 102, and a plurality of first electrodes 102 can be electrically connected to the same wire layer, which is beneficial to save wiring space and reduce the size of the semiconductor structure.

在一些实施例中,基底100还可以为第一基底层114和第二基底层115构成的叠层结构,以与第一电极102接触的基底100为第二基底层115为例,第二基底层115层可以为绝缘材料,例如,氧化硅。且第二基底层115内可以具有用于引出第一电极102的导电层(图中未示出)。第一基底层114层为可直接进入制造环节生产半导体器件的材料,例如第一基底层114层可以为绝缘衬底上的硅(SOI)、硅、锗、锗化硅、碳化硅、砷化镓或者蓝宝石等。In some embodiments, the substrate 100 may also be a stacked structure composed of the first substrate layer 114 and the second substrate layer 115 . Taking the substrate 100 in contact with the first electrode 102 as the second substrate layer 115 as an example, the second substrate The bottom layer 115 may be an insulating material such as silicon oxide. And the second base layer 115 may have a conductive layer (not shown in the figure) for drawing out the first electrode 102 . The first base layer 114 is a material that can directly enter the manufacturing process to produce semiconductor devices. For example, the first base layer 114 can be silicon (SOI), silicon, germanium, silicon germanium, silicon carbide, arsenide on an insulating substrate Gallium or sapphire, etc.

参考图1和图2,在一些实施例中,基底100上电容结构110的第一电极102围成的通孔为圆柱形通孔,即电容结构110为圆柱状电容,这种电容结构110具有平滑的侧面,有利于避免尖端放电现象。电容介质层103位于第一电极102的通孔的内侧表面以及底部,即电容介质层103也围成朝向远离基底100方向延伸的通孔。第二电极104填充电容介质层103围成的通孔,且第二电极104接近基底100的下表面与电容介质层103接触。在另一些实施例中,第一电极102围成的通孔可以为方形通孔或者其他形状的柱状孔,相对于平面电容,也具有较大的极板相对面积,可增大电容容量。Referring to FIG. 1 and FIG. 2 , in some embodiments, the through hole surrounded by the first electrode 102 of the capacitor structure 110 on the substrate 100 is a cylindrical through hole, that is, the capacitor structure 110 is a cylindrical capacitor, and the capacitor structure 110 has Smooth sides help avoid tip discharge. The capacitor dielectric layer 103 is located on the inner surface and bottom of the through hole of the first electrode 102 , that is, the capacitor dielectric layer 103 also surrounds the through hole extending away from the substrate 100 . The second electrode 104 fills the through hole surrounded by the capacitor dielectric layer 103 , and the second electrode 104 is in contact with the capacitor dielectric layer 103 close to the lower surface of the substrate 100 . In some other embodiments, the through hole enclosed by the first electrode 102 may be a square through hole or a columnar hole of other shapes, which also has a larger relative area of the plates compared to a planar capacitor, which can increase the capacitance.

在一些实施例中,第一电极102与第二电极104为导电材料,例如氮化钛。在另一些实施例中,第一电极102与第二电极104的材料还可以为镍化铂、钛、钽、钴、铜、钨、氮化钽等导电材料中的至少一种。电容介质层103为绝缘的介电材料,例如,电容介质层103的材料为氧化硅、氧化钽、氧化铪、氧化锆、氧化铌、氧化钛、氧化钡、氧化锶、氧化钇、氧化镧、氧化镨或者钛酸锶钡等高介电常数材料中的至少一种。In some embodiments, the first electrode 102 and the second electrode 104 are conductive materials, such as titanium nitride. In other embodiments, the material of the first electrode 102 and the second electrode 104 may also be at least one of conductive materials such as platinum nickel oxide, titanium, tantalum, cobalt, copper, tungsten, and tantalum nitride. The capacitor dielectric layer 103 is an insulating dielectric material, for example, the capacitor dielectric layer 103 is made of silicon oxide, tantalum oxide, hafnium oxide, zirconium oxide, niobium oxide, titanium oxide, barium oxide, strontium oxide, yttrium oxide, lanthanum oxide, At least one of high dielectric constant materials such as praseodymium oxide or barium strontium titanate.

此外,半导体结构包括多个沿平行于基底100顶面方向间隔排布的电容结构110,不同电容结构110相互分立。In addition, the semiconductor structure includes a plurality of capacitor structures 110 spaced along a direction parallel to the top surface of the substrate 100 , and different capacitor structures 110 are separated from each other.

继续参考图1,在一些实施例中,半导体结构还可以包括:绝缘层101,电容结构110位于绝缘层101内,且绝缘层101暴露出第二电极104顶面;通孔远离第二电极104的外侧壁与绝缘层101相接触;通孔被第二电极104和电容介质层103共同填满,且第二电极104顶面与电容介质层103顶面齐平。Continuing to refer to FIG. 1 , in some embodiments, the semiconductor structure may further include: an insulating layer 101 , the capacitor structure 110 is located in the insulating layer 101 , and the insulating layer 101 exposes the top surface of the second electrode 104 ; the through hole is away from the second electrode 104 The outer sidewall of the electrode is in contact with the insulating layer 101 ; the through hole is filled with the second electrode 104 and the capacitive dielectric layer 103 , and the top surface of the second electrode 104 is flush with the top surface of the capacitive dielectric layer 103 .

绝缘层101位于电容结构110之间,用于支撑电容结构110,并隔离相邻的电容结构110的第二电极102。其中,绝缘层101的材料包括氮化硅、氮氧化硅或者氧化硅中的至少一种。在一些实施例中,绝缘层101也可以为堆叠膜层结构,只要保证绝缘层101能够起到支撑和隔离目的即可,本公开实施例不对绝缘层101的结构具体限制。The insulating layer 101 is located between the capacitor structures 110 for supporting the capacitor structures 110 and isolating the second electrodes 102 of the adjacent capacitor structures 110 . The material of the insulating layer 101 includes at least one of silicon nitride, silicon oxynitride or silicon oxide. In some embodiments, the insulating layer 101 may also be a stacked film structure, as long as the insulating layer 101 can serve the purpose of support and isolation, and the embodiments of the present disclosure do not specifically limit the structure of the insulating layer 101 .

在一些实施例中,电容介质层103还可以位于第一电极102的顶面,以使绝缘层101的顶面仅露出第二电极104,有利于避免出现后续加工工艺误差导致的第一电极102与晶体管111的第一掺杂区I产生电连接的情况。此外,第二电极104顶面与电容介质层103顶面平齐,保证了第一电极102与第二电极104的相对面积更大,有利于增大电容容量。可以理解的是,在另一些实施例中,第一电极102的顶面也可高于电容介质层103的顶面。In some embodiments, the capacitive dielectric layer 103 may also be located on the top surface of the first electrode 102 , so that only the second electrode 104 is exposed on the top surface of the insulating layer 101 , which is beneficial to avoid the occurrence of the first electrode 102 caused by subsequent processing errors. A case of electrical connection with the first doped region I of the transistor 111 . In addition, the top surface of the second electrode 104 is flush with the top surface of the capacitor dielectric layer 103, which ensures that the opposing area of the first electrode 102 and the second electrode 104 is larger, which is beneficial to increase the capacitance. It can be understood that, in other embodiments, the top surface of the first electrode 102 may also be higher than the top surface of the capacitive dielectric layer 103 .

参考图3,在一些实施例中,电容介质层103还位于第一电极102顶面以及绝缘层101顶面,且第二电极104顶面与电容介质层103顶面齐平。Referring to FIG. 3 , in some embodiments, the capacitive dielectric layer 103 is also located on the top surface of the first electrode 102 and the top surface of the insulating layer 101 , and the top surface of the second electrode 104 is flush with the top surface of the capacitive dielectric layer 103 .

具体的,位于第一电极102顶面和绝缘层101顶面的电容介质层103可作为第二电极104的平坦化停止层,第二电极104仅位于电容介质层103的通孔内,且与电容介质层103顶面平齐,这不仅有利于简化加工工艺,还保证了电容结构110具有较大的电容容量。Specifically, the capacitive dielectric layer 103 located on the top surface of the first electrode 102 and the top surface of the insulating layer 101 can be used as a planarization stop layer for the second electrode 104, and the second electrode 104 is only located in the through hole of the capacitive dielectric layer 103, and is different from that of the capacitor dielectric layer 103. The top surface of the capacitor dielectric layer 103 is flush, which not only facilitates the simplification of the manufacturing process, but also ensures that the capacitor structure 110 has a larger capacitance capacity.

参考图4,在一些实施例中,第二电极104还位于通孔的外侧壁以及第一电极102顶面,且第二电极104包括:第一主体部120,第一主体部120位于通孔内;第二主体部121,第二主体部121位于通孔的外侧壁,第二主体部121的材料与第一主体部120的材料相同,且在平行于基底100表面方向上,第一主体部120的厚度大于第二主体部121的厚度;电连接部122,电连接部122横跨第一主体部120以及第二主体部121,且与第一主体部120顶面和第二主体部121顶面相接触。电连接部122用于电连接通孔内侧壁的第一主体部120与通孔外侧壁的第二主体部121,使得在单个电容当中,共用第二电极104。此外,通孔的外侧壁、内侧壁均具有相对的第二电极104,相比于平面电容,通过设置第一主体部120和第二主体部121可以极大的增加电容容量,有效的改善了半导体结构的性能。Referring to FIG. 4 , in some embodiments, the second electrode 104 is also located on the outer sidewall of the through hole and the top surface of the first electrode 102 , and the second electrode 104 includes: a first main body part 120 , and the first main body part 120 is located in the through hole inside; the second body portion 121, the second body portion 121 is located on the outer sidewall of the through hole, the material of the second body portion 121 is the same as the material of the first body portion 120, and in the direction parallel to the surface of the substrate 100, the first body portion The thickness of the part 120 is greater than the thickness of the second main body part 121; the electrical connection part 122, the electrical connection part 122 spans the first main body part 120 and the second main body part 121, and is connected with the top surface of the first main body part 120 and the second main body part 121 The top surfaces are in contact. The electrical connection portion 122 is used to electrically connect the first body portion 120 of the inner sidewall of the through hole and the second body portion 121 of the outer sidewall of the through hole, so that the second electrode 104 is shared among a single capacitor. In addition, the outer sidewall and inner sidewall of the through hole have opposite second electrodes 104. Compared with the planar capacitor, by arranging the first main body portion 120 and the second main body portion 121, the capacitance capacity can be greatly increased, effectively improving the performance of semiconductor structures.

具体的,第二电极104的外侧壁也具有绝缘层101,起到隔离第二电极104和支撑电容结构110的作用,使得电容和电容之间相互独立,每个电容对应连接一个晶体管111。第一主体部120、第二主体部121为同时形成的结构,即构成第一主体部120、第二主体部121的材料为相同的导电材料。并且,第一主体部120的厚度是指,第一主体部120在平行于基底100表面方向上的最大厚度。此外,电容介质层103也位于基底100的表面,电容介质层103可以选择性去除或者保留,以保留电容介质层103为例,保留电容介质层103可以减少整个半导体制造过程的工艺时长,提高半导体结构的制造效率。可以理解的是,在另一些实施例中,电容介质层103也可以仅位于第一电极102表面,也可以达到隔离第一电极102与第二电极104的效果。Specifically, the outer sidewall of the second electrode 104 also has an insulating layer 101 to isolate the second electrode 104 from the supporting capacitor structure 110 , so that the capacitors are independent of each other, and each capacitor is connected to a transistor 111 correspondingly. The first main body portion 120 and the second main body portion 121 are structures formed at the same time, that is, the materials constituting the first main body portion 120 and the second main body portion 121 are the same conductive material. Also, the thickness of the first main body portion 120 refers to the maximum thickness of the first main body portion 120 in a direction parallel to the surface of the substrate 100 . In addition, the capacitor dielectric layer 103 is also located on the surface of the substrate 100, and the capacitor dielectric layer 103 can be selectively removed or retained. Taking the capacitor dielectric layer 103 as an example, retaining the capacitor dielectric layer 103 can reduce the process time of the entire semiconductor manufacturing process and improve the semiconductor performance. Fabrication efficiency of the structure. It can be understood that, in other embodiments, the capacitive dielectric layer 103 may also be located only on the surface of the first electrode 102 , and may also achieve the effect of isolating the first electrode 102 and the second electrode 104 .

继续参考图4,在一些实施例中,对于同一电容结构110,第二电极104为一体成型结构。也就是说,电连接部122与第一主体部120、第二主体部121为同时形成的材料相同的结构,这种一体成型结构使第二电极104的加工工艺更加简单。可以理解的是,在另一些实施例中,电连接部122和第一主体部120、第二主体部121的材料也可以不同。Continuing to refer to FIG. 4 , in some embodiments, for the same capacitor structure 110 , the second electrode 104 is an integrally formed structure. That is to say, the electrical connection portion 122 , the first main body portion 120 and the second main body portion 121 are formed of the same material at the same time, and this integrally formed structure makes the processing process of the second electrode 104 simpler. It can be understood that, in other embodiments, the materials of the electrical connection part 122 and the first main body part 120 and the second main body part 121 may also be different.

参考图5和图6,在一些实施例中,第一电极102可以包括:侧边部123,侧边部123为通孔的侧壁部分;底连接部124,底连接部124为通孔平行于基底100的底面部分;半导体结构还可以包括:电连接层108,电连接层108位于基底100上,且电连接相邻的底连接部124。Referring to FIGS. 5 and 6 , in some embodiments, the first electrode 102 may include: a side portion 123 , the side portion 123 is a side wall portion of the through hole; a bottom connecting portion 124 , the bottom connecting portion 124 is parallel to the through holes On the bottom surface portion of the substrate 100 ; the semiconductor structure may further include: an electrical connection layer 108 , the electrical connection layer 108 is located on the substrate 100 and is electrically connected to the adjacent bottom connection portions 124 .

需要说明的是,由于基底100上具有电连接层108,那么基底100内可以不包含导电层。电连接层108使每个电容结构110的第一电极102均与电连接层108电连接。具有电连接层108的半导体结构既保证了每个电容结构110的相互独立,还使第一电极102经电连接层108电连接至外部电路,实现半导体结构的电容结构110具有共用的第一电极102,简化工艺,有利于改善增加导电层导致的空间浪费。It should be noted that, since the substrate 100 has the electrical connection layer 108, the substrate 100 may not include a conductive layer. The electrical connection layer 108 electrically connects the first electrodes 102 of each capacitive structure 110 to the electrical connection layer 108 . The semiconductor structure with the electrical connection layer 108 not only ensures the independence of each capacitor structure 110 from each other, but also enables the first electrode 102 to be electrically connected to an external circuit through the electrical connection layer 108, so that the capacitor structure 110 of the semiconductor structure has a common first electrode. 102 , simplifying the process, which is beneficial to improve the space waste caused by adding the conductive layer.

在一些实施例中,电连接层108的材料与第一电极102层的材料相同,有利于避免界面态缺陷,提高导电效果。可以理解的是,在另一些实施例中,电连接层108的材料与第一电极102的材料也可以不同,只需保证电连接第一电极102即可。In some embodiments, the material of the electrical connection layer 108 is the same as the material of the first electrode 102 layer, which is beneficial to avoid interface state defects and improve the conduction effect. It can be understood that, in other embodiments, the material of the electrical connection layer 108 and the material of the first electrode 102 may also be different, as long as it is only necessary to ensure that the first electrode 102 is electrically connected.

参考图5和图6,在一些实施例中,电连接层108与底连接部124可以为一体成型膜层,且电容介质层103还位于电连接层108表面。Referring to FIGS. 5 and 6 , in some embodiments, the electrical connection layer 108 and the bottom connection portion 124 may be integrally formed as a film layer, and the capacitive dielectric layer 103 is also located on the surface of the electrical connection layer 108 .

具体的,位于通孔底部的电连接层108直接作为第一电极102的底连接部124,有利于简化第一电极102的加工工艺。并且,位于电连接层108表面的电容介质层103避免了第二电极104与电连接层108相接触。Specifically, the electrical connection layer 108 located at the bottom of the through hole directly serves as the bottom connection portion 124 of the first electrode 102 , which is beneficial to simplify the processing technology of the first electrode 102 . In addition, the capacitive dielectric layer 103 located on the surface of the electrical connection layer 108 prevents the second electrode 104 from being in contact with the electrical connection layer 108 .

参考图7,在一些实施例中,侧边部123与底连接部124可以为一体成型膜层,且电连接层108还位于底连接部124与基底100之间。Referring to FIG. 7 , in some embodiments, the side portion 123 and the bottom connecting portion 124 may be integrally formed as a film layer, and the electrical connecting layer 108 is also located between the bottom connecting portion 124 and the substrate 100 .

具体的,电连接层108和底连接部124为不同的结构,电连接层108远离基底100的部分表面与第一电极102的底连接部124相接触,通过电连接层108直接引出第一电极102,避免增加其他电连接结构引出第一电极103,从而避免增加其他电连接结构对空间的浪费。Specifically, the electrical connection layer 108 and the bottom connection portion 124 have different structures. A part of the surface of the electrical connection layer 108 away from the substrate 100 is in contact with the bottom connection portion 124 of the first electrode 102 , and the first electrode is directly drawn out through the electrical connection layer 108 . 102, to avoid adding other electrical connection structures to lead out the first electrode 103, thereby avoiding the waste of space by adding other electrical connection structures.

参考图7和图8,半导体结构的每一电容结构110的第二电极104顶部均与一个晶体管111的第一掺杂区I相接触。第一掺杂区I构成晶体管111的源极或者漏极中的一者,第二掺杂区III构成晶体管111的源极或者漏极中的另一者。第一掺杂区I和第二掺杂区III可以是N型掺杂区或P型掺杂区,N型掺杂区的离子包括砷离子、磷离子、锑离子等,P型掺杂区的离子包括硼离子、铝离子、镓离子等。Referring to FIGS. 7 and 8 , the top of the second electrode 104 of each capacitor structure 110 of the semiconductor structure is in contact with the first doped region I of one transistor 111 . The first doped region I constitutes one of the source or the drain of the transistor 111 , and the second doped region III constitutes the other of the source or the drain of the transistor 111 . The first doping region I and the second doping region III can be N-type doping regions or P-type doping regions, the ions of the N-type doping regions include arsenic ions, phosphorus ions, antimony ions, etc., and the P-type doping regions The ions include boron ions, aluminum ions, gallium ions, etc.

在一些实施例中,晶体管111还可以包括:沟道区II,沟道区II位于第一掺杂区I与所述第二掺杂区III之间,且沟道区II、第一掺杂区I以及第二掺杂区III的材料至少包括IGZO(铟镓锌氧化物,Indium Gallium Zinc Oxide)、IWO(掺钨氧化铟,Indium TungstenOxide)或者ITO(氧化铟锡,Indium Tin Oxide)中的一种或多种,上述材料具有较高的载流子迁移率,有利于降低半导体结构工作时的漏电流,改善半导体结构的性能。In some embodiments, the transistor 111 may further include: a channel region II, the channel region II is located between the first doping region I and the second doping region III, and the channel region II, the first doping region The materials of the region I and the second doped region III at least include IGZO (Indium Gallium Zinc Oxide), IWO (Indium Tungsten Oxide) or ITO (Indium Tin Oxide). One or more, the above-mentioned materials have higher carrier mobility, which is beneficial to reduce the leakage current of the semiconductor structure during operation and improve the performance of the semiconductor structure.

晶体管111的沟道区II和第一掺杂区I、第二掺杂区III构成晶体管111的半导体通道105,在一些实施例中,半导体通道105的材料为IGZO,IGZO的载流子迁移率是多晶硅的载流子迁移率的20~50倍,有利于提高沟道区II的载流子迁移率,以降低半导体结构的功耗和提高半导体结构的工作效率。此外,IGZO半导体通道105的形成温度较低,便于形成在金属结构上,有利于形成3D堆叠的存储结构,从而增大半导体结构的集成密度,在有限的空间内集成更多的半导体结构。The channel region II, the first doping region I, and the second doping region III of the transistor 111 constitute the semiconductor channel 105 of the transistor 111. In some embodiments, the material of the semiconductor channel 105 is IGZO, and the carrier mobility of IGZO is It is 20 to 50 times of the carrier mobility of polysilicon, which is beneficial to improve the carrier mobility of the channel region II, so as to reduce the power consumption of the semiconductor structure and improve the working efficiency of the semiconductor structure. In addition, the formation temperature of the IGZO semiconductor channel 105 is relatively low, which is convenient for forming on the metal structure, which is favorable for forming a 3D stacked memory structure, thereby increasing the integration density of the semiconductor structure and integrating more semiconductor structures in a limited space.

在一些实施例中,构成半导体通道105的第一掺杂区I、沟道区II以及第二掺杂区III为一体结构,有利于改善第一掺杂区I和沟道区II之间的界面态缺陷,和改善沟道区II和第二掺杂区III之间的界面态缺陷,以改善半导体结构的性能。可以理解的是,在另一些实施例中,半导体通道105也可以为三层结构,且每一层结构相应作为第一掺杂区I、沟道区II以及第二掺杂区III。In some embodiments, the first doping region I, the channel region II, and the second doping region III constituting the semiconductor channel 105 are of an integrated structure, which is beneficial to improve the contact between the first doping region I and the channel region II. interface state defects, and improving the interface state defects between the channel region II and the second doped region III to improve the performance of the semiconductor structure. It can be understood that, in other embodiments, the semiconductor channel 105 may also have a three-layer structure, and each layer structure corresponds to the first doping region I, the channel region II, and the second doping region III.

此外,参考图8,在一些实施例中,半导体通道105为圆柱状结构,使半导体通道105的侧面为平滑过渡表面,有利于避免半导体通道105发生尖端放电或者漏电的现象,进一步改善半导体结构的电学性能。需要说明的是,在另一些实施例中,半导体通道105也可以为方柱状结构或者其他不规则结构。可以理解的是,半导体通道105结构为方柱状结构时,方柱状结构的侧壁相邻面构成的拐角可以为圆滑化的拐角,同样能够避免尖端放电问题,方柱状结构可以为正方体柱状结构或者长方体柱状结构。In addition, referring to FIG. 8 , in some embodiments, the semiconductor channel 105 is a cylindrical structure, so that the side surface of the semiconductor channel 105 is a smooth transition surface, which is beneficial to avoid the phenomenon of tip discharge or leakage of the semiconductor channel 105, and further improves the semiconductor structure. electrical properties. It should be noted that, in other embodiments, the semiconductor channel 105 may also be a square column structure or other irregular structure. It can be understood that when the structure of the semiconductor channel 105 is a square columnar structure, the corners formed by the adjacent surfaces of the sidewalls of the square columnar structure can be rounded corners, which can also avoid the problem of tip discharge, and the square columnar structure can be a square columnar structure or Cuboid columnar structure.

继续参考图7和图8,晶体管111结构还可以包括:栅介质层106,栅介质层106环绕沟道区II设置,且位于沟道区II的侧壁表面;栅导电层107,栅导电层107环绕沟道区II设置,且位于沟道区II对应的栅介质层106的侧壁表面。7 and 8, the structure of the transistor 111 may further include: a gate dielectric layer 106, the gate dielectric layer 106 is disposed around the channel region II, and is located on the sidewall surface of the channel region II; a gate conductive layer 107, a gate conductive layer 107 is disposed around the channel region II, and is located on the sidewall surface of the gate dielectric layer 106 corresponding to the channel region II.

在一些实施例中,栅介质层106位于沟道区II的半导体通道105的侧壁表面和第二掺杂区III的半导体通道105的侧壁表面,用于将栅导电层107与半导体通道105隔离开。并且,位于第二掺杂区III的半导体通道105的侧壁表面的栅介质层106能够对第二掺杂区III表面起到保护作用,避免在形成栅导电层107的过程中对第二掺杂区III表面造成的工艺损伤,从而有利于进一步改善半导体结构的性能。可以理解的是,在另一些实施例中,栅介质层106也可以仅位于沟道区II的半导体通道105的侧壁表面。In some embodiments, the gate dielectric layer 106 is located on the sidewall surface of the semiconductor channel 105 in the channel region II and the sidewall surface of the semiconductor channel 105 in the second doping region III, for connecting the gate conductive layer 107 with the semiconductor channel 105 isolated. In addition, the gate dielectric layer 106 located on the sidewall surface of the semiconductor channel 105 in the second doped region III can protect the surface of the second doped region III, so as to avoid the second doped region during the formation of the gate conductive layer 107. The process damage caused by the surface of the impurity region III is beneficial to further improve the performance of the semiconductor structure. It can be understood that, in other embodiments, the gate dielectric layer 106 may only be located on the sidewall surface of the semiconductor channel 105 in the channel region II.

栅介质层106的材料包括氧化硅、氮化硅、氮氧化硅或其他高介电常数介质材料中的至少一种。栅导电层107的材料包括多晶硅、氮化钛、氮化钽、铜、钨或者铝中的至少一种。The material of the gate dielectric layer 106 includes at least one of silicon oxide, silicon nitride, silicon oxynitride or other high dielectric constant dielectric materials. The material of the gate conductive layer 107 includes at least one of polysilicon, titanium nitride, tantalum nitride, copper, tungsten or aluminum.

继续参考图7,在一些实施例中,晶体管111还可以包括层间介质层113,层间介质层113位于晶体管111之间,露出晶体管111的第二掺杂区III的顶面,起到隔离相邻的晶体管111以及支撑的作用。且层间介质层113包括第一层间介质125、第二层间介质126和第三层间介质127。第一层间介质125位于第一掺杂区I所在的半导体通道105的侧壁表面、栅介质层106朝向基底100方向的底面和栅导电层107朝向基底100方向的底面。第二层间介质126位于第二掺杂区III侧壁的栅介质层106侧壁表面和栅导电层107远离基底100方向的顶面。第三层间介质127位于栅导电层107的侧壁表面、不同的第一层间介质125侧壁之间以及不同的第二层间介质126侧壁之间。其中,第一层间介质125、第二层间介质126以及第三层间介质127可以为分开形成的结构,第一层间介质125、第二层间介质126以及第三层间介质127可以为相同的绝缘材料,例如氧化硅、氮化硅、碳氮化硅或者碳氮氧化硅中的至少一种,相同的材料有利于形成良好的接触界面,提高半导体结构的可靠性。可以理解的是,在另一些实施例中,第一层间介质125、第二层间介质126以及第三层间介质127也可以为不相同的绝缘材料。Continuing to refer to FIG. 7 , in some embodiments, the transistor 111 may further include an interlayer dielectric layer 113 . The interlayer dielectric layer 113 is located between the transistors 111 and exposes the top surface of the second doped region III of the transistor 111 for isolation. Adjacent transistors 111 and the role of support. And the interlayer dielectric layer 113 includes a first interlayer dielectric 125 , a second interlayer dielectric 126 and a third interlayer dielectric 127 . The first interlayer dielectric 125 is located on the sidewall surface of the semiconductor channel 105 where the first doped region I is located, the bottom surface of the gate dielectric layer 106 facing the substrate 100 and the bottom surface of the gate conductive layer 107 facing the substrate 100 . The second interlayer dielectric 126 is located on the sidewall surface of the gate dielectric layer 106 of the sidewall of the second doped region III and the top surface of the gate conductive layer 107 in the direction away from the substrate 100 . The third interlayer dielectric 127 is located on the sidewall surface of the gate conductive layer 107 , between the sidewalls of the different first interlayer dielectrics 125 and between the sidewalls of the different second interlayer dielectrics 126 . The first interlayer medium 125 , the second interlayer medium 126 and the third interlayer medium 127 may be separately formed structures, and the first interlayer medium 125 , the second interlayer medium 126 and the third interlayer medium 127 may The same insulating material, such as at least one of silicon oxide, silicon nitride, silicon carbonitride or silicon oxycarbonitride, is beneficial to form a good contact interface and improve the reliability of the semiconductor structure. It can be understood that, in other embodiments, the first interlayer dielectric 125 , the second interlayer dielectric 126 and the third interlayer dielectric 127 may also be different insulating materials.

参考图7,在一些实施例中,半导体结构还可以包括位线112以及隔离层109,位线112位于部分的层间介质层113表面且与晶体管111的第二掺杂区III、栅介质层106远离基底100的部分顶面相接触,隔离层109覆盖位线112的表面,以将不同的位线112进行隔离以及支撑位线112上的堆叠的其他半导体结构。其中,隔离层109的材料可以包括氧化硅、氮化硅或者氮氧化硅中的至少一种。此外,层间介质层113与隔离层109的材料相同,有利于改善层间介质层113与隔离层109之间的界面态缺陷,改善半导体结构的性能,并且,有利于减少半导体结构的加工步骤,降低半导体结构的制造成本和复杂度。可以理解的是,在另一些实施中,层间介质层113的材料与隔离层109的材料可以不同。Referring to FIG. 7 , in some embodiments, the semiconductor structure may further include a bit line 112 and an isolation layer 109 . The bit line 112 is located on a part of the surface of the interlayer dielectric layer 113 and is connected to the second doped region III of the transistor 111 and the gate dielectric layer. A portion of the top surface 106 away from the substrate 100 is in contact, and an isolation layer 109 covers the surface of the bit lines 112 to isolate the different bit lines 112 and to support other semiconductor structures stacked on the bit lines 112 . The material of the isolation layer 109 may include at least one of silicon oxide, silicon nitride or silicon oxynitride. In addition, the material of the interlayer dielectric layer 113 and the isolation layer 109 is the same, which is beneficial to improve the interface state defects between the interlayer dielectric layer 113 and the isolation layer 109, improve the performance of the semiconductor structure, and is beneficial to reduce the processing steps of the semiconductor structure , reducing the manufacturing cost and complexity of semiconductor structures. It can be understood that, in other implementations, the material of the interlayer dielectric layer 113 and the material of the isolation layer 109 may be different.

具体的,层间介质层113的部分表面可以具有多个间隔排布的位线112,每一位线112可与至少一个第二掺杂区III相接触电连接。例如,参考图9,每一位线112与2个第二掺杂区III相接触。可根据实际电学需求,合理设置与每一位线112相接触电连接的第二掺杂区III的数量。Specifically, a part of the surface of the interlayer dielectric layer 113 may have a plurality of bit lines 112 arranged at intervals, and each bit line 112 may be in electrical contact with at least one second doped region III. For example, referring to FIG. 9 , each bit line 112 is in contact with two second doped regions III. The number of the second doped regions III that are in contact and electrically connected to each bit line 112 can be reasonably set according to actual electrical requirements.

上述实施例提供的半导体结构,电容结构110为柱状结构的基础上,第一电极102围成的通孔内以及通孔外侧边均具有相对的第二电极104,极大的增加了电容结构110的相对极板面积,增大了电容容量。电连接层108既使半导体结构具有相互独立的电容结构110,还使第一电极102经电连接层108电连接至外部电路,实现半导体结构具有共用的第一电极102,有利于简化工艺,避免空间浪费。通过对晶体管111和电容结构110的位置关系进行调整,使半导体结构满足多层堆叠的条件,在相同的体积下,增大了半导体结构的集成密度。此外,晶体管111在电容结构110上的排布方式,不仅使位线112的形成工艺更加简单,还可适当增大单层半导体结构的尺寸,有利于降低制造的复杂程度。In the semiconductor structure provided by the above embodiment, on the basis that the capacitor structure 110 is a columnar structure, the through hole enclosed by the first electrode 102 and the outer side of the through hole have opposite second electrodes 104, which greatly increases the capacitance structure. The relative plate area of 110 increases the capacitance. The electrical connection layer 108 enables the semiconductor structure to have independent capacitance structures 110, and also enables the first electrode 102 to be electrically connected to an external circuit through the electrical connection layer 108, so that the semiconductor structure has a common first electrode 102, which is beneficial to simplify the process and avoid Waste of space. By adjusting the positional relationship between the transistor 111 and the capacitor structure 110 , the semiconductor structure satisfies the multi-layer stacking condition, and under the same volume, the integration density of the semiconductor structure is increased. In addition, the arrangement of the transistors 111 on the capacitor structure 110 not only makes the formation process of the bit line 112 simpler, but also appropriately increases the size of the single-layer semiconductor structure, which is beneficial to reduce the complexity of manufacturing.

相应的,本公开实施例另一方面还提供一种半导体结构的制造方法,用于形成上述半导体结构。需要说明的是,与前述实施例相同或者相应的部分,可参考前述实施例的详细说明,以下将不做赘述。Correspondingly, another aspect of the embodiments of the present disclosure further provides a method for fabricating a semiconductor structure for forming the above-mentioned semiconductor structure. It should be noted that, for the parts that are the same as or corresponding to the foregoing embodiments, reference may be made to the detailed descriptions of the foregoing embodiments, which will not be repeated below.

图10至图25为本公开实施例提供的半导体结构的制备方法各步骤对应的结构示意图。10 to FIG. 25 are schematic structural diagrams corresponding to each step of a method for fabricating a semiconductor structure according to an embodiment of the present disclosure.

参考图10,半导体结构的制造方法包括:提供基底100。Referring to FIG. 10 , a method of fabricating a semiconductor structure includes: providing a substrate 100 .

其中,基底100的表面形成有绝缘材料或者基底100本身为绝缘材料,如此,可避免与基底100相接触的半导体结构受到不稳定的电信号影响,影响半导体结构的电学性能。The surface of the substrate 100 is formed with an insulating material or the substrate 100 itself is an insulating material, so that the semiconductor structure in contact with the substrate 100 can be prevented from being affected by unstable electrical signals and affect the electrical performance of the semiconductor structure.

参考图11,在一些实施例中,可以在基底100上形成电连接层108。电连接层108是位于基底100的顶面的导电膜层,与后续形成的第一电极102电连接。此外,电连接层108可通过物理气相沉积、蒸发、溅射等方式形成。有关基底100、电连接层108的材料可参考前述实施例的相应说明,在此不再赘述。Referring to FIG. 11 , in some embodiments, an electrical connection layer 108 may be formed on the substrate 100 . The electrical connection layer 108 is a conductive film layer located on the top surface of the substrate 100 and is electrically connected to the first electrode 102 formed subsequently. In addition, the electrical connection layer 108 may be formed by physical vapor deposition, evaporation, sputtering, or the like. For the materials of the substrate 100 and the electrical connection layer 108 , reference may be made to the corresponding descriptions of the foregoing embodiments, which will not be repeated here.

参考图12至图14,在基底100上形成第一电极102,第一电极102围成朝向远离基底100方向延伸的通孔。12 to 14 , a first electrode 102 is formed on the substrate 100 , and the first electrode 102 surrounds a through hole extending in a direction away from the substrate 100 .

具体的,参考图14,可在基底100的电连接层108上形成相互独立的第一电极102,第一电极102朝向基底100的底面与电连接层108相接触。如此,无需增加其他引线层,直接通过电连接层108引出第一电极102,可节省空间,有利于缩小半导体结构的尺寸。此外,有关通孔的形状可参考前述实施例的相应说明,在此不再赘述。Specifically, referring to FIG. 14 , mutually independent first electrodes 102 may be formed on the electrical connection layer 108 of the substrate 100 , and the first electrodes 102 are in contact with the electrical connection layer 108 toward the bottom surface of the substrate 100 . In this way, there is no need to add other lead layers, and the first electrode 102 can be directly led out through the electrical connection layer 108 , which can save space and help reduce the size of the semiconductor structure. In addition, for the shape of the through hole, reference may be made to the corresponding descriptions of the foregoing embodiments, which will not be repeated here.

继续参考图12至图14,在一些实施例中,形成第一电极102的步骤还可以包括:在基底100上形成绝缘膜,且绝缘膜内具有贯穿绝缘膜厚度的凹槽;形成第一电极102,第一电极102位于凹槽的底部和侧壁。绝缘膜内的凹槽,定义了第一电极102的位置,在绝缘膜的辅助和支撑下,通过在凹槽的侧壁及底部形成导电材料,得到电容容量更大的柱状电容的第一电极102。并且,绝缘膜的材料可以为氧化硅。12 to 14, in some embodiments, the step of forming the first electrode 102 may further include: forming an insulating film on the substrate 100, and the insulating film has a groove through the thickness of the insulating film; forming the first electrode 102, the first electrode 102 is located at the bottom and sidewalls of the groove. The groove in the insulating film defines the position of the first electrode 102. With the assistance and support of the insulating film, conductive materials are formed on the sidewall and bottom of the groove to obtain the first electrode of the columnar capacitor with larger capacitance. 102. Also, the material of the insulating film may be silicon oxide.

具体的,首先可通过沉积的方式在基底100的电连接层108上形成绝缘膜,并根据所需柱状电容的高度确定绝缘膜的厚度。再采用光刻、刻蚀等工艺在绝缘膜上形成凹槽,且凹槽的底部露出部分电连接层108的顶面。并且,此处形成的凹槽可为向基底100方向延伸的圆孔形凹槽。可以理解的是,在另一些实施例中,凹槽也可为方孔型凹槽或其他形状的凹槽。然后,在凹槽的底部露出的电连接层108表面、凹槽的侧壁、绝缘膜的顶面形成一层导电材料作为第一电极102,并采用无掩膜刻蚀的方式去除绝缘膜顶面的导电材料,进而形成相互独立的第一电极102。此外,形成第一电极102的方式可为原子层沉积工艺。Specifically, firstly, an insulating film may be formed on the electrical connection layer 108 of the substrate 100 by means of deposition, and the thickness of the insulating film may be determined according to the required height of the columnar capacitance. Then, a groove is formed on the insulating film by means of photolithography, etching and other processes, and a part of the top surface of the electrical connection layer 108 is exposed at the bottom of the groove. Moreover, the groove formed here may be a circular hole-shaped groove extending toward the direction of the substrate 100 . It can be understood that, in other embodiments, the grooves can also be square-hole grooves or grooves of other shapes. Then, a layer of conductive material is formed as the first electrode 102 on the surface of the electrical connection layer 108 exposed at the bottom of the groove, the sidewall of the groove, and the top surface of the insulating film, and the top of the insulating film is removed by maskless etching. The conductive material of the surface is formed, thereby forming the first electrodes 102 independent of each other. In addition, the manner of forming the first electrode 102 may be an atomic layer deposition process.

在一些实施例中,也可采用光刻胶覆盖通孔,再去除绝缘膜的顶面的第一电极102,也可以得到第一电极102。需要说明的是,此时,位于通孔底部的第一电极102在光刻胶的覆盖下不会受到刻蚀消耗,从而被保留在了通孔内的电连接层108上。In some embodiments, photoresist can also be used to cover the through hole, and then the first electrode 102 on the top surface of the insulating film can be removed, and the first electrode 102 can also be obtained. It should be noted that, at this time, the first electrode 102 located at the bottom of the through hole will not be etched and consumed under the coverage of the photoresist, and thus remains on the electrical connection layer 108 in the through hole.

参考图15至图20,形成第一电极102后,还包括形成第二电极104和电容介质层103。第二电极104至少位于通孔内,电容介质层103位于第一电极102与第二电极104之间,第二电极104、电容介质层103以及第一电极102构成电容结构110。并且,形成第二电极104的方式可以为原子层沉积工艺。Referring to FIG. 15 to FIG. 20 , after forming the first electrode 102 , it also includes forming the second electrode 104 and the capacitor dielectric layer 103 . The second electrode 104 is located at least in the through hole, the capacitor dielectric layer 103 is located between the first electrode 102 and the second electrode 104 , and the second electrode 104 , the capacitor dielectric layer 103 and the first electrode 102 constitute the capacitor structure 110 . Also, the method of forming the second electrode 104 may be an atomic layer deposition process.

形成电容介质层103和第二电极104的方法通过以下实施例具体描述。The method of forming the capacitive dielectric layer 103 and the second electrode 104 is specifically described by the following embodiments.

参考图15至图16,在一些实施例中,剩余绝缘膜可以作为绝缘层101,之后,形成电容介质层103,电容介质层103位于通孔底部和侧壁;形成第二电极104层,第二电极104层位于电容介质层103表面且填充通孔。将剩余的绝缘膜保留作为绝缘层101,可在形成通孔内侧壁相对的第二电极104时起到支撑的作用。Referring to FIGS. 15 to 16 , in some embodiments, the remaining insulating film can be used as the insulating layer 101 , and then, the capacitive dielectric layer 103 is formed, and the capacitive dielectric layer 103 is located at the bottom and sidewalls of the through hole; the second electrode 104 layer is formed, and the first The second electrode 104 layer is located on the surface of the capacitor dielectric layer 103 and fills the through hole. Remaining the remaining insulating film as the insulating layer 101 can play a supporting role when forming the second electrode 104 opposite to the inner sidewall of the through hole.

具体的,在绝缘层101远离基底100的顶面、第一电极102形成的通孔侧壁、顶面及底部形成电容介质层103。然后,在电容介质层103上形成第二电极104,且第二电极104填充电容介质层103形成的通孔。采用平坦化的工艺,以电容介质层103为平坦化停止层,去除位于绝缘层101顶面和第一电极102顶面的电容介质层103上的第二电极104,得到与电容介质层103顶面平齐的第二电极104。如此,可简化工艺流程,降低制造的复杂度。在另一些实施例中,除去位于绝缘层101顶面和第一电极102顶面的电容介质层103上的第二电极104的方式也可以采用掩膜刻蚀法,即用光刻胶覆盖通孔内的第二电极104顶面,再去除剩余的第二电极104。Specifically, the capacitor dielectric layer 103 is formed on the top surface of the insulating layer 101 away from the substrate 100 , the sidewalls, the top surface and the bottom of the through hole formed by the first electrode 102 . Then, a second electrode 104 is formed on the capacitor dielectric layer 103 , and the second electrode 104 fills the through hole formed in the capacitor dielectric layer 103 . Using the planarization process, the capacitor dielectric layer 103 is used as a planarization stop layer, and the second electrode 104 on the capacitor dielectric layer 103 located on the top surface of the insulating layer 101 and the top surface of the first electrode 102 is removed to obtain the top surface of the capacitor dielectric layer 103 The second electrode 104 with a flush surface. In this way, the process flow can be simplified and the manufacturing complexity can be reduced. In other embodiments, the method of removing the second electrode 104 located on the top surface of the insulating layer 101 and the capacitor dielectric layer 103 on the top surface of the first electrode 102 may also be a mask etching method, that is, covering the pass-through with photoresist The top surface of the second electrode 104 in the hole is removed, and the remaining second electrode 104 is removed.

参考图17和图18,在一些实施例中,形成电容介质层103以及第二电极104的步骤还可以包括:去除剩余绝缘膜,露出通孔的外侧壁;形成电容介质层103,电容介质层103位于通孔的底部、内侧壁以及外侧壁;形成第二电极104,第二电极104位于电容介质层103表面,且还位于通孔内以及通孔外侧壁上。如此,可在第一电极102通孔的内侧壁、外侧壁均形成第二电极104,进一步增大极板相对面积,从而增大电容容量。17 and 18 , in some embodiments, the steps of forming the capacitor dielectric layer 103 and the second electrode 104 may further include: removing the remaining insulating film to expose the outer sidewalls of the through holes; forming the capacitor dielectric layer 103 , the capacitor dielectric layer 103 is located at the bottom, inner sidewall and outer sidewall of the through hole; a second electrode 104 is formed, and the second electrode 104 is located on the surface of the capacitor dielectric layer 103 and also located in the through hole and on the outer sidewall of the through hole. In this way, the second electrode 104 can be formed on both the inner sidewall and the outer sidewall of the through hole of the first electrode 102 to further increase the relative area of the electrode plates, thereby increasing the capacitance.

具体的,去除在基底100的电连接层108上的和通孔外侧壁的绝缘膜,并且在电连接层108上和第一电极102上通过沉积功能工艺形成电容介质层103,进而在电容介质层103上形成第二电极104。其中,形成第二电极104方式为原子层沉积工艺。Specifically, the insulating films on the electrical connection layer 108 of the substrate 100 and the outer sidewalls of the through holes are removed, and the capacitor dielectric layer 103 is formed on the electrical connection layer 108 and the first electrode 102 by a functional deposition process, and then the capacitor dielectric layer 103 is formed on the electrical connection layer 108 and the first electrode 102 by a functional deposition process A second electrode 104 is formed on the layer 103 . The method for forming the second electrode 104 is an atomic layer deposition process.

参考图19至图20,在一些实施例中,形成第二电极104的步骤中,还可以包括:形成绝缘层101,绝缘层101位于基底100上;形成绝缘层101以及第二电极104的工艺步骤包括:形成第一主体部120和第二主体部121,第一主体部120位于通孔内,第二主体部121位于通孔的外侧壁,第二主体部121的材料与第一主体部120的材料相同;在基底100上形成绝缘层101,绝缘层101位于第二主体部121侧壁;形成电连接部122,电连接部122横跨第一主体部120以及第二主体部121,且与第一主体部120顶面和第二主体部121顶面相接触,电连接部122、第一主体部120以及第二主体部121共同构成第二电极104。19 to 20 , in some embodiments, the step of forming the second electrode 104 may further include: forming an insulating layer 101 on the substrate 100 ; and forming the insulating layer 101 and the second electrode 104 The steps include: forming a first main body part 120 and a second main body part 121, the first main body part 120 is located in the through hole, the second main body part 121 is located in the outer side wall of the through hole, the material of the second main body part 121 is the same as that of the first main body part The material of 120 is the same; an insulating layer 101 is formed on the substrate 100, and the insulating layer 101 is located on the sidewall of the second main body part 121; And in contact with the top surface of the first main body part 120 and the top surface of the second main body part 121 , the electrical connection part 122 , the first main body part 120 and the second main body part 121 together constitute the second electrode 104 .

具体的,形成了电容介质层103上的第二电极104后,采用无掩膜刻蚀的方式,去除电容介质层103通孔顶部、以及电连接层108上电容介质层103表面的第二电极104,得到第二电极104的第一主体部120和第二主体部121。在第二主体部121的外侧壁形成绝缘层101,使相互独立的第二电极104之间绝缘隔离,并对后续的半导体结构起到支撑作用。其中,绝缘层101露出第一主体部120的顶面、第二主体部121的顶面以及电容介质层103远离基底100的顶面。在绝缘层101远离基底100的顶面、第一主体部120的顶面、第二主体部121的顶面以及电容介质层103远离基底100的顶面上形成电连接部122材料,并去除绝缘层101远离基底100的顶面上的电连接部122,使第二电极104的第一主体部120与第二主体部121电连接,并形成相互独立的第二电极104。Specifically, after the second electrode 104 on the capacitor dielectric layer 103 is formed, maskless etching is used to remove the top of the through hole in the capacitor dielectric layer 103 and the second electrode on the surface of the capacitor dielectric layer 103 on the electrical connection layer 108 Step 104 , the first main body part 120 and the second main body part 121 of the second electrode 104 are obtained. An insulating layer 101 is formed on the outer sidewall of the second body portion 121 to insulate and isolate the second electrodes 104 independent of each other, and play a supporting role for subsequent semiconductor structures. The insulating layer 101 exposes the top surface of the first body portion 120 , the top surface of the second body portion 121 , and the top surface of the capacitor dielectric layer 103 away from the substrate 100 . The material of the electrical connection portion 122 is formed on the top surface of the insulating layer 101 away from the substrate 100 , the top surface of the first body portion 120 , the top surface of the second body portion 121 , and the top surface of the capacitive dielectric layer 103 away from the substrate 100 , and the insulation is removed. The layer 101 is away from the electrical connection portion 122 on the top surface of the substrate 100 , electrically connecting the first body portion 120 and the second body portion 121 of the second electrode 104 and forming the second electrode 104 independent of each other.

在一些实施例中,形成电连接部122的方式为:在绝缘层101远离基底100的顶面、第一主体部120的顶面、第二主体部121的顶面以及电容介质层103远离基底100的顶面上形成一层,例如导电材料和掩膜层,采用SADP(Self-aligned Double Patterning自对准双重成像技术)工艺,在一个方向形成多条凸起的第一掩膜图形,在另一个方向上通过SADP工艺形成多条凸起的第二掩膜图形。选择性地对第一掩膜图形和第二掩膜图形交叉的区域进行刻蚀,去除掩膜层以及掩膜层下的导电材料,直至暴露出绝缘层101,再去除剩余的掩膜层,保留剩余的电连接部122材料,形成电连接部122。本公开实施例可以精准地控制电连接部122的位置和形状,以形成相互独立的电连接部122,进而实现第一主体部120与第二主体部121通过电连接部122相连接,形成相互独立且为一体结构的第二电极104。在另一些实施例中,形成电连接部122的方式还可以为:采用SAQP(Self-aligned Quadruple Patterning自对准四重成像技术)工艺形成电连接部122。In some embodiments, the electrical connection portion 122 is formed as follows: the top surface of the insulating layer 101 away from the substrate 100 , the top surface of the first body portion 120 , the top surface of the second body portion 121 , and the capacitor dielectric layer 103 away from the substrate A layer is formed on the top surface of 100, such as a conductive material and a mask layer, and a SADP (Self-aligned Double Patterning) process is used to form a plurality of raised first mask patterns in one direction, In the other direction, a plurality of raised second mask patterns are formed by the SADP process. Selectively etch the area where the first mask pattern and the second mask pattern intersect, remove the mask layer and the conductive material under the mask layer until the insulating layer 101 is exposed, and then remove the remaining mask layer, Remaining material of the electrical connection portion 122 is retained to form the electrical connection portion 122 . The embodiment of the present disclosure can precisely control the position and shape of the electrical connection portion 122 to form mutually independent electrical connection portions 122 , thereby realizing that the first main body portion 120 and the second main body portion 121 are connected through the electrical connection portion 122 to form a mutually independent electrical connection portion 122 . The second electrode 104 is an independent and one-piece structure. In other embodiments, the electrical connection portion 122 may also be formed by using a SAQP (Self-aligned Quadruple Patterning) process to form the electrical connection portion 122 .

在一些实施例中,使用光刻胶将电容介质层103围成的通孔外侧壁、内侧壁、底部以及顶部上的第二电极104覆盖,刻蚀去除通孔外电连接层108上电容介质层103表面的第二电极104,从而直接得到相互独立的包括第一主体部120、第二主体部121以及电连接部122的第二电极104。并且,在去除光刻胶后形成绝缘层101,采用平坦化工艺使绝缘层101露出第二电极104的顶面,以使后续形成的晶体管111的第一掺杂区I与第二电极104相接触。In some embodiments, photoresist is used to cover the outer sidewall, inner sidewall, bottom and second electrode 104 on the top of the through hole surrounded by the capacitor dielectric layer 103 , and the capacitor dielectric layer on the outer electrical connection layer 108 of the through hole is removed by etching. The second electrode 104 on the surface of 103 is directly obtained, and the second electrode 104 including the first main body part 120 , the second main body part 121 and the electrical connection part 122 is directly obtained. In addition, after removing the photoresist, an insulating layer 101 is formed, and a planarization process is used to expose the insulating layer 101 to the top surface of the second electrode 104, so that the first doped region I of the transistor 111 and the second electrode 104 to be formed subsequently touch.

参考图21至图23,形成晶体管111,晶体管111位于电容结构110上,且晶体管111包括沿垂直于基底100表面方向间隔排布的第一掺杂区I和第二掺杂区III,第一掺杂区I与第二电极104电连接,第一掺杂区I和第二掺杂区III的掺杂类型为N型或者P型中的一者,且第一掺杂区I和第二掺杂区III的掺杂类型相同。需要说明的是,形成晶体管111还可以包括:形成沟道区II,沟道区II位于第一掺杂区I与所述第二掺杂区III之间,沟道区II和第一掺杂区I、第二掺杂区III构成晶体管111的半导体通道105;形成栅介质层106,栅介质层106环绕沟道区II设置,且位于沟道区II的侧壁表面;形成栅导电层107,栅导电层107环绕沟道区II设置,且位于沟道区II对应的栅介质层106的侧壁表面。Referring to FIGS. 21 to 23 , a transistor 111 is formed, the transistor 111 is located on the capacitor structure 110 , and the transistor 111 includes a first doped region I and a second doped region III spaced along a direction perpendicular to the surface of the substrate 100 . The doping region I is electrically connected to the second electrode 104, the doping type of the first doping region I and the second doping region III is one of N-type or P-type, and the first doping region I and the second doping region The doping type of the doped region III is the same. It should be noted that, forming the transistor 111 may further include: forming a channel region II, the channel region II is located between the first doping region I and the second doping region III, and the channel region II and the first doping region II The region I and the second doped region III constitute the semiconductor channel 105 of the transistor 111; the gate dielectric layer 106 is formed, and the gate dielectric layer 106 is arranged around the channel region II and is located on the sidewall surface of the channel region II; the gate conductive layer 107 is formed , the gate conductive layer 107 is disposed around the channel region II, and is located on the sidewall surface of the gate dielectric layer 106 corresponding to the channel region II.

并且,形成晶体管111之前,还可以包括形成第一层间介质125,参考图21,第一层间介质125在第二电极104的部分表面以及绝缘层101表面,并且第一层间介质125内形成有向第二电极104顶面延伸的凹槽,凹槽的底部露出第二电极104的部分顶面。其中,凹槽可以为圆孔形凹槽。参考图22,在凹槽内形成半导体通道105,再去除部分厚度的第一层间介质125,形成栅介质层106、栅导电层107以及第二层间介质126。由于此时不同晶体管111的栅导电层107都是相互连接的状态,所以,参考图23,通过选择性刻蚀打断栅导电层107,从而形成相互独立或者具有指定连接方式的栅导电层107。并在相互独立的栅导电层107之间形成第三层间介质127。第一层间介质125、第二层间介质126以及第三层间介质127构成层间介质层113,层间介质层113有利于使晶体管达到更好的绝缘隔离效果,并为后续的半导体结构提供支撑。In addition, before forming the transistor 111 , it may further include forming a first interlayer dielectric 125 . Referring to FIG. 21 , the first interlayer dielectric 125 is on a part of the surface of the second electrode 104 and the surface of the insulating layer 101 , and inside the first interlayer dielectric 125 A groove extending toward the top surface of the second electrode 104 is formed, and a part of the top surface of the second electrode 104 is exposed at the bottom of the groove. Wherein, the groove may be a circular hole-shaped groove. Referring to FIG. 22 , a semiconductor channel 105 is formed in the groove, and then a partial thickness of the first interlayer dielectric 125 is removed to form a gate dielectric layer 106 , a gate conductive layer 107 and a second interlayer dielectric 126 . Since the gate conductive layers 107 of different transistors 111 are all connected to each other at this time, referring to FIG. 23 , the gate conductive layers 107 are interrupted by selective etching, thereby forming the gate conductive layers 107 that are independent of each other or have a specified connection mode. . And a third interlayer dielectric 127 is formed between the mutually independent gate conductive layers 107 . The first interlayer dielectric 125 , the second interlayer dielectric 126 and the third interlayer dielectric 127 constitute the interlayer dielectric layer 113 , and the interlayer dielectric layer 113 is conducive to achieving better insulation and isolation effect of the transistor, and is a subsequent semiconductor structure Provide support.

参考图24,形成位线112,位线112位于晶体管111上,且与第二掺杂区III电连接。Referring to FIG. 24, a bit line 112 is formed, and the bit line 112 is located on the transistor 111 and is electrically connected to the second doped region III.

具体的,在层间介质层113表面、晶体管111的第二掺杂区III、栅介质层106远离基底100的顶面上形成位线112,并图形化,形成相互独立或具有指定连接方式的位线112。此外,在位线112表面形成隔离层109,使相互独立的位线112之间具有较好的绝缘隔离效果,并为后续位线112上形成的堆叠的半导体结构提供支撑。Specifically, the bit line 112 is formed on the surface of the interlayer dielectric layer 113, the second doped region III of the transistor 111, and the top surface of the gate dielectric layer 106 away from the substrate 100, and patterned to form independent or specified connection modes. bit line 112 . In addition, an isolation layer 109 is formed on the surface of the bit lines 112 , so that the independent bit lines 112 have better insulation and isolation effect, and provide support for the stacked semiconductor structure formed on the subsequent bit lines 112 .

参考图25,邻近基底100的电容结构110、晶体管111以及位线112构成存储单元阵列130,在隔离层109上形成至少一个存储单元阵列130,且多个存储单元阵列130向远离于基底100顶面的方向延伸。Referring to FIG. 25 , the capacitor structure 110 , the transistor 111 and the bit line 112 adjacent to the substrate 100 constitute a memory cell array 130 , at least one memory cell array 130 is formed on the isolation layer 109 , and a plurality of memory cell arrays 130 are far from the top of the substrate 100 direction of the face.

上述实施例提供的半导体结构的制造方法,可形成共用第一电极102的柱状电容结构110、排布于电容结构110上的晶体管111结构以及非埋入式位线112。共用第一电极102可节省空间,排布于电容结构110上的晶体管111结构可实现存储单元阵列的多层堆叠,如此,有利于在保证半导体结构具有较优性能的前提下,进一步实现尺寸微缩。此外,非埋入式位线112降低的制造的复杂程度,柱状电容结构110具有较大的相对电极面积,提升了半导体结构的性能。The manufacturing method of the semiconductor structure provided by the above embodiments can form the columnar capacitor structure 110 sharing the first electrode 102 , the transistor 111 structure arranged on the capacitor structure 110 and the non-buried bit line 112 . Sharing the first electrode 102 can save space, and the transistor 111 structure arranged on the capacitor structure 110 can realize the multi-layer stacking of the memory cell array, which is beneficial to further realize the size reduction on the premise of ensuring the semiconductor structure has better performance . In addition, the manufacturing complexity of the non-buried bit line 112 is reduced, and the columnar capacitor structure 110 has a larger opposing electrode area, which improves the performance of the semiconductor structure.

本领域的普通技术人员可以理解,上述各实施方式是实现本公开的具体实施例,而在实际应用中,可以在形式上和细节上对其作各种改变,而不偏离本公开的精神和范围。任何本领域技术人员,在不脱离本公开的精神和范围内,均可作各自变动与修改,因此本公开的保护范围应当以权利要求限定的范围为准。Those of ordinary skill in the art can understand that the above embodiments are specific examples for realizing the present disclosure, and in practical applications, various changes in form and details can be made without departing from the spirit and the spirit of the present disclosure. scope. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present disclosure. Therefore, the protection scope of the present disclosure should be based on the scope defined by the claims.

Claims (15)

1.一种半导体结构,其特征在于,包括:1. a semiconductor structure, is characterized in that, comprises: 基底;base; 第一电极,所述第一电极位于所述基底上,所述第一电极围成朝向远离所述基底方向延伸的通孔;a first electrode, the first electrode is located on the substrate, and the first electrode surrounds a through hole extending in a direction away from the substrate; 第二电极,所述第二电极至少位于所述通孔内;a second electrode, the second electrode is at least located in the through hole; 电容介质层,所述电容介质层位于所述第一电极与所述第二电极之间,所述第二电极、所述电容介质层以及所述第一电极构成电容结构;a capacitor dielectric layer, the capacitor dielectric layer is located between the first electrode and the second electrode, and the second electrode, the capacitor dielectric layer and the first electrode constitute a capacitor structure; 晶体管,所述晶体管位于所述电容结构上,且所述晶体管包括沿垂直于所述基底表面方向间隔排布的第一掺杂区和第二掺杂区,所述第一掺杂区与所述第二电极电连接,所述第一掺杂区和所述第二掺杂区的掺杂类型为N型或者P型中的一者,且所述第一掺杂区和所述第二掺杂区的掺杂类型相同;a transistor, the transistor is located on the capacitor structure, and the transistor includes a first doped region and a second doped region spaced along a direction perpendicular to the surface of the substrate, the first doped region and the The second electrode is electrically connected, the doping type of the first doping region and the second doping region is one of N-type or P-type, and the first doping region and the second doping region are The doping types of the doped regions are the same; 位线,所述位线位于所述晶体管上,且与所述第二掺杂区电连接。a bit line, which is located on the transistor and is electrically connected to the second doped region. 2.如权利要求1所述的半导体结构,其特征在于,还包括:绝缘层,所述电容结构位于所述绝缘层内,且所述绝缘层暴露出所述第二电极顶面;所述通孔远离所述第二电极的外侧壁与所述绝缘层相接触;所述通孔被所述第二电极和所述电容介质层共同填满,且所述第二电极顶面与所述电容介质层顶面齐平。2 . The semiconductor structure of claim 1 , further comprising: an insulating layer, the capacitor structure is located in the insulating layer, and the insulating layer exposes the top surface of the second electrode; the The outer sidewall of the through hole away from the second electrode is in contact with the insulating layer; the through hole is jointly filled by the second electrode and the capacitor dielectric layer, and the top surface of the second electrode is in contact with the insulating layer. The top surface of the capacitor dielectric layer is flush. 3.如权利要求2所述的半导体结构,其特征在于,所述电容介质层还位于所述第一电极顶面以及所述绝缘层顶面,且所述第二电极顶面与所述电容介质层顶面齐平。3 . The semiconductor structure of claim 2 , wherein the capacitor dielectric layer is further located on the top surface of the first electrode and the top surface of the insulating layer, and the second electrode top surface is connected to the capacitor 3 . The top surface of the dielectric layer is flush. 4.如权利要求1所述的半导体结构,其特征在于,所述第二电极还位于所述通孔的外侧壁以及所述第一电极顶面,且所述第二电极包括:4. The semiconductor structure of claim 1, wherein the second electrode is further located on the outer sidewall of the through hole and the top surface of the first electrode, and the second electrode comprises: 第一主体部,所述第一主体部位于所述通孔内;a first main body part, the first main body part is located in the through hole; 第二主体部,所述第二主体部位于所述通孔的外侧壁,所述第二主体部的材料与所述第一主体部的材料相同,且在平行于所述基底表面方向上,所述第一主体部的厚度大于所述第二主体部的厚度;a second main body part, the second main body part is located on the outer side wall of the through hole, the material of the second main body part is the same as the material of the first main body part, and in a direction parallel to the surface of the base, The thickness of the first body portion is greater than the thickness of the second body portion; 电连接部,所述电连接部横跨所述第一主体部以及所述第二主体部,且与所述第一主体部顶面和所述第二主体部顶面相接触。an electrical connection part, the electrical connection part spans the first main body part and the second main body part, and is in contact with the top surface of the first main body part and the top surface of the second main body part. 5.如权利要求4所述的半导体结构,其特征在于,对于同一所述电容结构,所述第二电极为一体成型结构。5 . The semiconductor structure of claim 4 , wherein for the same capacitor structure, the second electrode is an integrally formed structure. 6 . 6.如权利要求1所述的半导体结构,其特征在于,所述第一电极包括:6. The semiconductor structure of claim 1, wherein the first electrode comprises: 侧边部,所述侧边部为所述通孔的侧壁部分;a side part, the side part is the side wall part of the through hole; 底连接部,所述底连接部为所述通孔平行于所述基底的底面部分;a bottom connecting part, the bottom connecting part is a bottom surface part of the through hole parallel to the base; 所述半导体结构还包括:电连接层,所述电连接层位于所述基底上,且电连接相邻的所述底连接部。The semiconductor structure further includes: an electrical connection layer located on the substrate and electrically connected to the adjacent bottom connection parts. 7.如权利要求6所述半导体结构,其特征在于,所述电连接层与所述底连接部为一体成型膜层,且所述电容介质层还位于所述电连接层表面。7 . The semiconductor structure of claim 6 , wherein the electrical connection layer and the bottom connection portion are integrally formed as a film layer, and the capacitive dielectric layer is also located on the surface of the electrical connection layer. 8 . 8.如权利要求6所述的半导体结构,其特征在于,所述侧边部与所述底连接部为一体成型膜层,且所述电连接层还位于所述底连接部与所述基底之间。8 . The semiconductor structure of claim 6 , wherein the side portion and the bottom connecting portion are integrally formed into a film layer, and the electrical connecting layer is also located between the bottom connecting portion and the substrate. 9 . between. 9.如权利要求1所述的半导体结构,其特征在于,所述晶体管还包括:9. The semiconductor structure of claim 1, wherein the transistor further comprises: 沟道区,所述沟道区位于所述第一掺杂区与所述第二掺杂区之间,且所述沟道区、所述第一掺杂区以及所述第二掺杂区的材料至少包括IGZO、IWO或者ITO中的一种或多种;a channel region, the channel region is located between the first doping region and the second doping region, and the channel region, the first doping region and the second doping region The material includes at least one or more of IGZO, IWO or ITO; 栅介质层,所述栅介质层环绕所述沟道区设置,且位于所述沟道区的侧壁表面;a gate dielectric layer, the gate dielectric layer is disposed around the channel region and is located on the sidewall surface of the channel region; 栅导电层,所述栅导电层环绕所述沟道区设置,且位于所述沟道区对应的所述栅介质层的侧壁表面。A gate conductive layer, the gate conductive layer is disposed around the channel region and is located on the sidewall surface of the gate dielectric layer corresponding to the channel region. 10.一种半导体结构的制造方法,其特征在于,包括:10. A method for manufacturing a semiconductor structure, comprising: 提供基底;provide a base; 在所述基底上形成第一电极,所述第一电极围成朝向远离所述基底方向延伸的通孔;forming a first electrode on the substrate, the first electrode enclosing a through hole extending away from the substrate; 形成第二电极,所述第二电极至少位于所述通孔内;forming a second electrode, the second electrode is located at least in the through hole; 形成电容介质层,所述电容介质层位于所述第一电极与所述第二电极之间,所述第二电极、所述电容介质层以及所述第一电极构成电容结构;forming a capacitor dielectric layer, the capacitor dielectric layer is located between the first electrode and the second electrode, and the second electrode, the capacitor dielectric layer and the first electrode constitute a capacitor structure; 形成晶体管,所述晶体管位于所述电容结构上,且所述晶体管包括沿垂直于所述基底表面方向间隔排布的第一掺杂区和第二掺杂区,所述第一掺杂区与所述第二电极电连接,所述第一掺杂区和所述第二掺杂区的掺杂类型为N型或者P型中的一者,且所述第一掺杂区和所述第二掺杂区的掺杂类型相同;A transistor is formed, the transistor is located on the capacitor structure, and the transistor includes a first doped region and a second doped region spaced along a direction perpendicular to the surface of the substrate, the first doped region and the The second electrode is electrically connected, the doping type of the first doping region and the second doping region is one of N-type or P-type, and the first doping region and the first doping region are The doping types of the two doped regions are the same; 形成位线,所述位线位于所述晶体管上,且与所述第二掺杂区电连接。A bit line is formed, the bit line is located on the transistor and is electrically connected to the second doped region. 11.如权利要求10所述的半导体结构的制造方法,其特征在于,形成所述第一电极的步骤包括:11. The method of manufacturing a semiconductor structure according to claim 10, wherein the step of forming the first electrode comprises: 在所述基底上形成绝缘膜,且所述绝缘膜内具有贯穿所述绝缘膜厚度的凹槽;forming an insulating film on the substrate, and the insulating film has a groove through the thickness of the insulating film; 形成所述第一电极,所述第一电极位于所述凹槽的底部和侧壁。The first electrode is formed, and the first electrode is located at the bottom and sidewalls of the groove. 12.如权利要求11所述的半导体结构的制造方法,其特征在于,剩余所述绝缘膜作为绝缘层;形成所述电容介质层以及所述第二电极的步骤包括:12. The method for manufacturing a semiconductor structure according to claim 11, wherein the insulating film is left as an insulating layer; the step of forming the capacitor dielectric layer and the second electrode comprises: 形成所述电容介质层,所述电容介质层位于所述通孔底部和侧壁;forming the capacitive dielectric layer, where the capacitive dielectric layer is located at the bottom and sidewalls of the through hole; 形成第二电极层,所述第二电极层位于所述电容介质层表面且填充所述通孔。A second electrode layer is formed, the second electrode layer is located on the surface of the capacitor dielectric layer and fills the through hole. 13.如权利要求11所述的半导体结构的制造方法,其特征在于,形成所述电容介质层以及所述第二电极的步骤包括:13. The method for manufacturing a semiconductor structure according to claim 11, wherein the step of forming the capacitor dielectric layer and the second electrode comprises: 去除剩余所述绝缘膜,露出所述通孔的外侧壁;removing the remaining insulating film to expose the outer sidewall of the through hole; 形成所述电容介质层,所述电容介质层位于所述通孔的底部、内侧壁以及外侧壁;forming the capacitive dielectric layer, the capacitive dielectric layer is located at the bottom, inner sidewall and outer sidewall of the through hole; 形成所述第二电极,所述第二电极位于所述电容介质层表面,且还位于所述通孔内以及所述通孔外侧壁上。The second electrode is formed, and the second electrode is located on the surface of the capacitor dielectric layer, and is also located in the through hole and on the outer sidewall of the through hole. 14.如权利要求13所述的半导体结构的制造方法,其特征在于,还包括:形成绝缘层,所述绝缘层位于所述基底上;形成所述绝缘层以及所述第二电极的工艺步骤包括:14. The method for fabricating a semiconductor structure according to claim 13, further comprising: forming an insulating layer, the insulating layer being located on the substrate; the process steps of forming the insulating layer and the second electrode include: 形成第一主体部和第二主体部,所述第一主体部位于所述通孔内,所述第二主体部位于所述通孔的外侧壁,所述第二主体部的材料与所述第一主体部的材料相同;A first main body part and a second main body part are formed, the first main body part is located in the through hole, the second main body part is located in the outer side wall of the through hole, and the material of the second main body part is the same as the material of the through hole. The material of the first body part is the same; 在所述基底上形成所述绝缘层,所述绝缘层位于所述第二主体部侧壁;forming the insulating layer on the substrate, the insulating layer being located on the sidewall of the second body portion; 形成电连接部,所述电连接部横跨所述第一主体部以及所述第二主体部,且与所述第一主体部顶面和所述第二主体部顶面相接触,所述电连接部、所述第一主体部以及所述第二主体部共同构成所述第二电极。An electrical connection portion is formed, the electrical connection portion spans the first body portion and the second body portion, and is in contact with the top surface of the first body portion and the top surface of the second body portion, the electrical connection portion The connection part, the first main body part and the second main body part together constitute the second electrode. 15.如权利要求10所述的半导体结构的制造方法,其特征在于,在形成所述第一电极之前,还包括:在所述基底上形成电连接层,所述电连接层与所述第一电极电连接。15 . The method for manufacturing a semiconductor structure according to claim 10 , wherein before forming the first electrode, further comprising: forming an electrical connection layer on the substrate, the electrical connection layer and the first electrode 15 . An electrode is electrically connected.
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