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CN114524568A - Zero-emission sewage treatment process in nano powder industry - Google Patents

Zero-emission sewage treatment process in nano powder industry Download PDF

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Publication number
CN114524568A
CN114524568A CN202210203934.XA CN202210203934A CN114524568A CN 114524568 A CN114524568 A CN 114524568A CN 202210203934 A CN202210203934 A CN 202210203934A CN 114524568 A CN114524568 A CN 114524568A
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China
Prior art keywords
water
tank
filter
ultrafiltration
softened
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Pending
Application number
CN202210203934.XA
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Chinese (zh)
Inventor
禹磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEFEI YUWANG MEMBRANE ENGINEERING TECHNOLOGY CO LTD
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HEFEI YUWANG MEMBRANE ENGINEERING TECHNOLOGY CO LTD
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Priority to CN202210203934.XA priority Critical patent/CN114524568A/en
Publication of CN114524568A publication Critical patent/CN114524568A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses a zero-emission sewage treatment process in the nano powder industry, which comprises a flocculation tank, a sedimentation tank, an electrophoretic pool, a disc filter, a positive pressure ultrafiltration filter, a resin filter tank, an RO (reverse osmosis) membrane filter tank, a sea-fresh membrane filter and an evaporator, wherein the flocculation tank is arranged in the sedimentation tank; the flocculation tank flocculates and settles the nano-powder in the sewage; then, the sludge passes through a sedimentation tank to obtain precipitated sludge and first-grade clear water; the first-stage clear water enters an electrophoretic pool to remove most of ultrafine powder, and then is filtered by a disc filter and a positive pressure ultrafiltration filter to obtain ultrafiltration water and ultrafiltration concentrated water; the ultrafiltration clear water passes through a resin filter tank to obtain softened water; passing the softened water through an RO membrane filter tank and a sea and fresh water membrane filter to obtain purified water and concentrated water, and passing the concentrated water through an evaporator to obtain ultra-purified water; the invention relates to a zero-emission sewage treatment process in the nano powder industry, which realizes primary treatment through flocculation and sedimentation, and obtains completely separated solid waste and pure water through multi-stage filtration and concentration, thereby realizing zero emission of sewage.

Description

Zero-emission sewage treatment process in nano powder industry
Technical Field
The invention belongs to the field of sewage treatment, and particularly relates to a zero-emission sewage treatment process in the nano powder industry.
Background
The nanometer powder is ultrafine powder, which is generated in the preparation of ultrafine powder or in some other industries, the particle size and the morphology of the ultrafine powder are difficult to control, and the ultrafine powder is easy to disperse in air or water, thus causing environmental pollution. The prior art is not mature enough for the sewage treatment technology with superfine powder, and the treated sewage contains more or less superfine powder, which causes secondary pollution to water body and the like.
Disclosure of Invention
The invention aims to provide a zero-emission sewage treatment process in the nano powder industry, which realizes primary treatment through flocculation and sedimentation, and obtains completely separated solid waste and pure water through multi-stage filtration and concentration so as to realize zero emission of sewage.
The invention relates to a zero-emission sewage treatment process in the nano powder industry, which comprises a primary flocculation tank, a secondary flocculation tank, a sedimentation tank, an electrophoresis tank, a disc filter, a positive pressure ultrafiltration filter, a resin filter tank, an RO membrane filter tank, a sea-fresh membrane filter and an evaporator which are sequentially arranged; PAC and PAM flocculating agents are respectively added into the primary flocculation tank and the secondary flocculation tank to flocculate and settle the nano powder in the sewage; then standing and precipitating the sludge in a sedimentation tank to obtain precipitated sludge and first-grade clear water; the first-stage clear water enters a disc type filter for filtering to obtain ultrafiltration source water; filtering the ultrafiltration source water through a positive pressure ultrafiltration filter to obtain ultrafiltration filtered water and ultrafiltration concentrated water; passing the ultra-filtered clear water through a resin filter tank to obtain softened water; passing the softened water through an RO membrane filtration tank to obtain pure water and softened concentrated water; and (3) passing the softened concentrated water through a sea-fresh membrane filter to obtain purified water and concentrated water, and passing the concentrated water through an evaporator to further obtain ultra-purified water and solid waste.
Preferably, a water collecting tank is arranged in front of the primary flocculation tank, a grid and a front filter screen are arranged on a water inlet of the water collecting tank, and stirrers are arranged in the primary flocculation tank and the secondary flocculation tank.
Preferably, the precipitated sludge enters a plate frame to be extruded to obtain plate frame clear liquid and mud cake solid waste, and the plate frame clear liquid is refluxed into a water collecting tank.
Preferably, the sedimentation tank rear portion still is provided with the clear water tank, collect the one-level clear water, then pump the one-level clear water into the swimming pool, the swimming pool is including the positive pole swimming pool and the negative pole swimming pool that set gradually, utilize the electrophoresis to further get rid of most in the one-level clear water by the powder that the flocculation of flocculation subsides, obtain the second grade clear water, then get into disc filter with the second grade clear water according to 30 t/hour flow, set up ultrafiltration source water pitcher behind disc filter for the ultrafiltration source water that the disc filter produced keeps in, then get into malleation ultrafiltration filter with ultrafiltration source water according to 40 t/hour flow and filter, obtain the ultrafiltration clear water and get into the clear water pitcher that sets up at malleation ultrafiltration filter rear portion, the concentrated water of ultrafiltration that obtains gets into the clear water tank, get into disc filter once more.
Preferably, a booster pump is arranged in front of the resin filter tank, an inlet of the booster pump is communicated with an outlet of the ultrafiltration clear water tank, a softened water storage tank is arranged behind the resin filter tank, and an RO high-pressure pump is arranged behind the softened water storage tank, so that softened water enters the RO membrane filter tank at a flow rate of 40 t/h to obtain pure water and softened concentrated water, wherein the ratio of the pure water to the softened concentrated water is 4: 1.
Preferably, the softened concentrated water enters a sea desalination membrane filter according to the flow rate of 8 t/h to obtain purified water and concentrated water, the ratio of the purified water to the concentrated water is 3:1, wherein the concentrated water enters an evaporator according to the flow rate of 2 t/h, and ultra-purified water and solid waste are obtained through evaporation.
Preferably, the resin filtering tank is connected with a back washing device, and a water outlet of the back washing device is communicated with the evaporator.
The technical scheme of the invention has the beneficial effects that the zero-emission sewage treatment process in the nano powder industry has the following steps: the primary treatment is realized through flocculation and sedimentation, and then the solid waste and the pure water which are completely separated are obtained through multi-stage filtration and concentration, so that the zero discharge of the sewage is realized.
Drawings
FIG. 1 is a flow chart of a zero-discharge sewage treatment process in the nano powder industry according to the technical scheme of the invention.
Detailed Description
In order to facilitate the understanding of the technical solutions of the present invention for those skilled in the art, the technical solutions of the present invention will be further described with reference to the drawings attached to the specification.
The invention relates to a zero-emission sewage treatment process in the nano powder industry, which comprises a primary flocculation tank, a secondary flocculation tank, a sedimentation tank, an electrophoresis tank, a disc filter, a positive pressure ultrafiltration filter, a resin filter tank, an RO membrane filter tank, a sea-fresh membrane filter and an evaporator which are sequentially arranged. PAC and PAM flocculating agents are respectively added into the primary flocculation tank and the secondary flocculation tank to flocculate and settle the nano powder in the sewage; then the sludge is settled in a settling tank to obtain settled sludge and first-grade clear water. The first-stage clear water enters a disc type filter for filtering to obtain ultrafiltration source water; filtering the ultrafiltration source water through a positive pressure ultrafiltration filter to obtain ultrafiltration filtered water and ultrafiltration concentrated water; passing the ultra-filtered clear water through a resin filter tank to obtain softened water; passing the softened water through an RO membrane filtration tank to obtain pure water and softened concentrated water; and (3) passing the softened concentrated water through a sea-fresh membrane filter to obtain purified water and concentrated water, and passing the concentrated water through an evaporator to further obtain ultra-purified water and solid waste.
Based on above-mentioned technical scheme, the waste water that has the superfine powder that will produce in the waste water that produces or other technologies of preparation superfine powder all discharges to the catch basin, collects, gets rid of large granule solid waste wherein at first through primary filter etc. then carries out the flocculation with the waste water that contains the superfine powder through one-level flocculation basin and second grade flocculation basin for superfine powder can be held together, and the granule increases, and the increase of flocculation weight does benefit to and subsides and filters. Then with one-level clear water through the electrophoresis cell, according to the electrophoresis principle, further realize carrying out directional absorption to the powder that the aquatic is not precipitated by the flocculation, get rid of the most dispersed miropowder in one-level clear water, improve the powder and get rid of efficiency, reduce the pressure of follow-up each filter, ensure the work efficiency and the life of each filter. And then, the wastewater is subjected to multistage filtration, concentration and the like step by step to obtain pure water and solid waste, the solid waste can be further added as a raw material of other procedures or processes, the pure water can be further directly used as industrial water, the superfine powder is separated from the wastewater, and the zero-discharge rice of sewage is realized.
The water collecting tank is arranged in front of the primary flocculation tank, and a grid and a front filter screen are arranged on a water inlet of the water collecting tank, so that large particles or large-volume solids are filtered and removed. All be provided with the agitator in one-level flocculation pond and the second grade flocculation pond, ensure that the superfine powder in polyaluminium chloride and polyacrylamide and the waste water carries out abundant contact for with improve the flocculation effect.
The precipitated sludge enters the plate frame to be extruded, plate frame clear liquid and sludge cake solid waste are obtained, the plate frame clear liquid flows back to the water collecting tank, large-particle solid waste is directly removed, the filtering pressure of a subsequent filter is reduced, and the service life of the subsequent filter is prolonged.
The sedimentation tank rear portion still is provided with the clear water tank, collect the one-level clear water, then pump the one-level clear water into the swimming pool, the swimming pool is including the positive pole swimming pool and the negative pole swimming pool that set gradually, utilize the electrophoresis to further get rid of most in the one-level clear water by the powder that the flocculation sediment, obtain the second grade clear water, then get into disc filter with the second grade clear water according to 30 t/hour flow, set up ultrafiltration source water pitcher behind disc filter, be used for keeping in the ultrafiltration source water that disc filter produced, then get into malleation ultrafiltration filter with ultrafiltration source water according to 40 t/hour flow and filter, it gets into the ultrafiltration clear water pitcher that sets up at malleation ultrafiltration filter rear portion to obtain the ultrafiltration concentrated water and gets into the clear water tank, get into disc filter once more. The disc filter adopts 1um aperture, and the filter effect is good, has also kept heightened filter effect simultaneously. And a positive pressure ultrafiltration filter is adopted, so that the filtering effect and the filtering efficiency are ensured, and the sewage treatment efficiency is accelerated.
The device comprises a resin filtering tank, a booster pump, an RO high-pressure pump, an RO membrane filtering tank and a softened concentrated water tank, wherein the booster pump is arranged in front of the resin filtering tank, an inlet of the booster pump is communicated with an outlet of the ultrafiltration clear water tank, the softened water storage tank is arranged behind the resin filtering tank, and the RO high-pressure pump is arranged behind the softened water storage tank, so that the softened water enters the RO membrane filtering tank according to the flow of 40 t/h to obtain pure water and softened concentrated water, and the ratio of the pure water to the softened concentrated water is 4: 1. And further filtering the finer powder in the water body through a resin filtering tank and an RO membrane filtering tank respectively to obtain the directly used pure water.
And the softened concentrated water enters a sea-fresh membrane filter according to the flow of 8 t/h to obtain purified water and concentrated water, wherein the ratio of the purified water to the concentrated water is 3:1, the concentrated water enters an evaporator according to the flow of 2 t/h, and ultra-purified water and solid waste are obtained through evaporation. By evaporation, more advanced fine powder is separated, and solid-liquid separation is realized.
The resin filtering tank is connected with a back washing device, and the water outlet of the back washing device is communicated with the evaporator. The wastewater generated in the working procedure is synchronously treated, and the zero discharge of the wastewater is realized.
Technical solution of the invention is described above with reference to the accompanying drawings, it is obvious that the specific implementation of the invention is not limited by the above-mentioned manner, and it is within the scope of the invention to adopt various insubstantial modifications of the inventive method concept and technical solution, or to apply the inventive concept and technical solution to other occasions without modification.

Claims (7)

1. A zero-discharge sewage treatment process in the nano powder industry is characterized by comprising a primary flocculation tank, a secondary flocculation tank, a sedimentation tank, an electrophoresis tank, a disc filter, a positive pressure ultrafiltration filter, a resin filter tank, an RO membrane filter tank, a sea-fresh membrane filter and an evaporator which are sequentially arranged; PAC and PAM flocculating agents are respectively added into the primary flocculation tank and the secondary flocculation tank to flocculate and settle the nano powder in the sewage; then standing and precipitating the sludge in a sedimentation tank to obtain precipitated sludge and first-grade clear water; the first-stage clear water enters a disc type filter for filtering to obtain ultrafiltration source water; filtering the ultrafiltration source water through a positive pressure ultrafiltration filter to obtain ultrafiltration filtered water and ultrafiltration concentrated water; passing the ultra-filtered clear water through a resin filter tank to obtain softened water; passing the softened water through an RO membrane filtration tank to obtain pure water and softened concentrated water; and (3) passing the softened concentrated water through a sea-fresh membrane filter to obtain purified water and concentrated water, and passing the concentrated water through an evaporator to further obtain ultra-purified water and solid waste.
2. The process of claim 1, wherein a water collecting tank is arranged in front of the primary flocculation tank, a grid and a pre-filter screen are arranged at a water inlet of the water collecting tank, and stirrers are arranged in the primary flocculation tank and the secondary flocculation tank.
3. The nano powder industry zero-emission sewage treatment process as claimed in claim 1, wherein the precipitated sludge enters a plate frame to be extruded to obtain plate frame clear liquid and sludge cake solid waste, and the plate frame clear liquid is refluxed into a water collection tank.
4. The process of claim 1, wherein a clear water tank is further disposed at the rear of the settling tank to collect the first-stage clear water, the first-stage clear water is pumped into the swimming pool, the swimming pool comprises an anode swimming pool and a cathode swimming pool, most of the powder which is not flocculated and precipitated in the first-stage clear water is further removed by electrophoresis to obtain second-stage clear water, the second-stage clear water enters the disc filter at a flow rate of 30 t/hr, an ultrafiltration source water tank is disposed behind the disc filter for temporarily storing ultrafiltration source water generated by the disc filter, the ultrafiltration source water enters the positive pressure ultrafiltration filter at a flow rate of 40 t/hr for filtration, the obtained ultrafiltration clear water enters the ultrafiltration clear water tank disposed at the rear of the positive pressure ultrafiltration filter, and the obtained ultrafiltration concentrated water enters the clear water tank, and enters the disc filter again.
5. The nano-powder industry zero-emission sewage treatment process as claimed in claim 1, wherein a booster pump is arranged in front of the resin filter tank, an inlet of the booster pump is communicated with an outlet of the ultrafiltration clear water tank, a softened water storage tank is arranged behind the resin filter tank, and an RO high-pressure pump is arranged behind the softened water storage tank, so that softened water enters the RO membrane filter tank at a flow rate of 40 t/h to obtain pure water and softened concentrated water, wherein the ratio of the pure water to the softened concentrated water is 4: 1.
6. The nano powder industry zero-emission sewage treatment process as claimed in claim 1, wherein the softened concentrated water enters a sea-freshwater membrane filter at a flow rate of 8 t/h to obtain purified water and concentrated water, the ratio of the purified water to the concentrated water is 3:1, wherein the concentrated water enters an evaporator at a flow rate of 2 t/h, and ultra-purified water and solid waste are obtained through evaporation.
7. The nano-powder industry zero-emission sewage treatment process as claimed in claim 1, wherein the resin filtration tank is connected with a backwashing device, and a water outlet of the backwashing device is communicated with the evaporator.
CN202210203934.XA 2022-03-02 2022-03-02 Zero-emission sewage treatment process in nano powder industry Pending CN114524568A (en)

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CN202210203934.XA CN114524568A (en) 2022-03-02 2022-03-02 Zero-emission sewage treatment process in nano powder industry

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Application Number Priority Date Filing Date Title
CN202210203934.XA CN114524568A (en) 2022-03-02 2022-03-02 Zero-emission sewage treatment process in nano powder industry

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CN114524568A true CN114524568A (en) 2022-05-24

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS634893A (en) * 1986-06-25 1988-01-09 Daicel Chem Ind Ltd Fine particle removing device from ultrapure water
CN101156996A (en) * 2007-08-03 2008-04-09 中国铝业股份有限公司 A method for the sedimentation of bauxite cradling tailings
CN102101710A (en) * 2010-12-09 2011-06-22 安徽理工大学 Method for precipitating and clarifying coal slime water assisted by extra electric field
JP2014128777A (en) * 2012-12-28 2014-07-10 Yamada Katsuhiko Apparatus and method for flocculating, separating and recovering particle
CN205773883U (en) * 2016-07-21 2016-12-07 何吾斌 A kind of oil field compression fracture returns sewer processing means
CN111875142A (en) * 2020-07-27 2020-11-03 煤炭工业太原设计研究院集团有限公司 A zero-discharge system and process for salty wastewater in a power plant

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS634893A (en) * 1986-06-25 1988-01-09 Daicel Chem Ind Ltd Fine particle removing device from ultrapure water
CN101156996A (en) * 2007-08-03 2008-04-09 中国铝业股份有限公司 A method for the sedimentation of bauxite cradling tailings
CN102101710A (en) * 2010-12-09 2011-06-22 安徽理工大学 Method for precipitating and clarifying coal slime water assisted by extra electric field
JP2014128777A (en) * 2012-12-28 2014-07-10 Yamada Katsuhiko Apparatus and method for flocculating, separating and recovering particle
CN205773883U (en) * 2016-07-21 2016-12-07 何吾斌 A kind of oil field compression fracture returns sewer processing means
CN111875142A (en) * 2020-07-27 2020-11-03 煤炭工业太原设计研究院集团有限公司 A zero-discharge system and process for salty wastewater in a power plant

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Application publication date: 20220524

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