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CN114523777B - Moisture sensitive textured fabric - Google Patents

Moisture sensitive textured fabric Download PDF

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Publication number
CN114523777B
CN114523777B CN202110021793.5A CN202110021793A CN114523777B CN 114523777 B CN114523777 B CN 114523777B CN 202110021793 A CN202110021793 A CN 202110021793A CN 114523777 B CN114523777 B CN 114523777B
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Prior art keywords
moisture
sensitive
fabric
shrinkage
ink
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CN114523777A (en
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林嘉儀
阮巽雯
蔡荣裕
林俊宏
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Taiwan Textile Research Institute
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Taiwan Textile Research Institute
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041Digital printing on surfaces other than ordinary paper
    • B41M5/0047Digital printing on surfaces other than ordinary paper by ink-jet printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Knitting Of Fabric (AREA)

Abstract

A moisture responsive deformable fabric includes a base fabric and a moisture responsive shrinkage ink. The moisture-sensitive shrinkage ink is sprayed on any surface of the base cloth by utilizing a digital spray printing process, and a hydrophilic area is formed on the surface of the base cloth by the moisture-sensitive shrinkage ink. The moisture-sensitive deformation fabric disclosed by the invention can locally generate deformation after moisture absorption, is beneficial to volatilization of sweat and reduces sticky feel of a user body, so that good wearing comfort of the user is provided.

Description

感湿变形织物Moisture sensitive deformation fabric

技术领域Technical field

本揭露内容是有关于一种感湿变形织物,且特别是有关于一种利用数码喷印制程制备而成的感湿变形织物。The present disclosure relates to a moisture-sensitive deformable fabric, and in particular, to a moisture-sensitive deformable fabric prepared using a digital jet printing process.

背景技术Background technique

随着现今社会生活水准的提升,人们对于机能性纺织品的需求越来越高,且随着各种机能性纺织品不断地问世,具有特定目的的机能性纺织品的发展亦日趋完善。With the improvement of living standards in today's society, people's demand for functional textiles is getting higher and higher, and as various functional textiles continue to come out, the development of functional textiles with specific purposes is also becoming more and more perfect.

对于穿戴型纺织品而言,其常随着使用者的汗液或环境湿度的提升而粘附在使用者皮肤,造成穿戴舒适感大幅地降低。因此,如何降低穿戴型纺织品与使用者身体间的粘附并从而提升穿戴舒适感为纺织业者积极研究的重要课题。For wearable textiles, they often adhere to the user's skin as the user's sweat or environmental humidity increases, resulting in a significant reduction in wearing comfort. Therefore, how to reduce the adhesion between wearable textiles and the user's body and thereby improve wearing comfort is an important topic that textile manufacturers are actively researching.

发明内容Contents of the invention

本揭露提供一种感湿变形织物,其可于吸湿后局部地产生变形,有助于汗水的挥发并降低使用者身体的粘腻感,从而提供使用者良好的穿戴舒适感。The present disclosure provides a moisture-sensitive deformable fabric that can locally deform after absorbing moisture, helping to evaporate sweat and reduce the stickiness of the user's body, thereby providing the user with good wearing comfort.

根据本揭露一些实施方式,感湿变形织物包括基布以及感湿收缩墨水。感湿收缩墨水利用数码喷印制程喷涂于基布的任一表面,且感湿收缩墨水于基布的表面形成亲水区。According to some embodiments of the present disclosure, the moisture-sensitive deformation fabric includes a base fabric and moisture-sensitive shrinkage ink. The moisture-sensitive shrinkable ink is sprayed on any surface of the base fabric using a digital printing process, and the moisture-sensitive shrinkable ink forms a hydrophilic area on the surface of the base fabric.

在本揭露一些实施方式中,感湿收缩墨水可具有介于2.5cP至10.0cP间的粘度以及介于22dyne/cm至32dyne/cm间的表面张力,且感湿收缩墨水包括15至35重量份的感湿收缩树脂以及65至85重量份的水。In some embodiments of the present disclosure, the moisture-sensitive shrinkage ink may have a viscosity between 2.5 cP and 10.0 cP and a surface tension between 22 dyne/cm and 32 dyne/cm, and the moisture-sensitive shrinkage ink includes 15 to 35 parts by weight. of moisture-sensitive shrinkage resin and 65 to 85 parts by weight of water.

在本揭露一些实施方式中,感湿收缩树脂可以是藉由包括以下试剂制备而成:多元醇、多元胺、第一交联剂以及第二交联剂。第一交联剂及第二交联剂各自包括异氰酸酯嵌段。In some embodiments of the present disclosure, the moisture-sensitive shrinkage resin may be prepared by including the following reagents: polyol, polyamine, first cross-linking agent and second cross-linking agent. The first cross-linking agent and the second cross-linking agent each include an isocyanate block.

在本揭露一些实施方式中,亲水区可包括多个空心圆形图案,且所述空心圆形图案呈间隔排列。In some embodiments of the present disclosure, the hydrophilic region may include a plurality of hollow circular patterns, and the hollow circular patterns are arranged at intervals.

在本揭露一些实施方式中,空心圆形图案可呈阵列排列。In some embodiments of the present disclosure, the hollow circular patterns may be arranged in an array.

在本揭露一些实施方式中,空心圆形图案可沿第一方向及第二方向排列,且第一方向与第二方向的夹角介于40度至50度间。In some embodiments of the present disclosure, the hollow circular patterns can be arranged along the first direction and the second direction, and the angle between the first direction and the second direction is between 40 degrees and 50 degrees.

在本揭露一些实施方式中,亲水区可包括多个空心六边形图案,且相邻的两空心六边形图案共用各自的其中一边。In some embodiments of the present disclosure, the hydrophilic region may include a plurality of hollow hexagonal patterns, and two adjacent hollow hexagonal patterns share one side of each.

在本揭露一些实施方式中,空心六边形图案的每一边长可皆相等。In some embodiments of the present disclosure, the lengths of each side of the hollow hexagonal pattern may be equal.

在本揭露一些实施方式中,亲水区可包括多个长条形图案,且长条形图案呈平行排列。In some embodiments of the present disclosure, the hydrophilic region may include a plurality of elongated patterns, and the elongated patterns are arranged in parallel.

在本揭露一些实施方式中,长条形图案可呈等距排列。In some embodiments of the present disclosure, the elongated patterns may be arranged equidistantly.

根据本揭露上述实施方式,本揭露的感湿变形织物具有由感湿收缩墨水喷涂而成的亲水区。透过亲水区的配置,感湿变形织物可在吸湿后局部地产生变形,以于感湿变形织物与使用者身体间产生立体空间,从而减少感湿变形织物与使用者身体间的接触。如此一来,可有助于汗水的挥发并降低使用者身体的粘腻感,从而提供使用者良好的穿戴舒适感。According to the above embodiments of the present disclosure, the moisture-sensitive deformable fabric of the present disclosure has hydrophilic areas sprayed with moisture-sensitive shrinkage ink. Through the configuration of the hydrophilic zone, the moisture-sensing deformation fabric can locally deform after absorbing moisture to create a three-dimensional space between the moisture-sensing deformation fabric and the user's body, thereby reducing the contact between the moisture-sensing deformation fabric and the user's body. In this way, it can help evaporate sweat and reduce the stickiness of the user's body, thereby providing the user with good wearing comfort.

附图说明Description of the drawings

为让本揭露的上述和其他目的、特征、优点与实施例能更明显易懂,所附附图的说明如下:In order to make the above and other objects, features, advantages and embodiments of the present disclosure more apparent and understandable, the accompanying drawings are described as follows:

图1绘示根据本揭露一些实施方式的感湿变形织物的侧视示意图;Figure 1 is a schematic side view of a moisture-sensitive deformable fabric according to some embodiments of the present disclosure;

图2A、图2B、图2C及图2D绘示根据本揭露不同实施方式的感湿变形织物的亲水区的图案的上视示意图;以及2A, 2B, 2C and 2D are schematic top views of patterns of hydrophilic regions of moisture-sensitive deformable fabrics according to different embodiments of the present disclosure; and

图3A、图3B、图3C及图3D分别绘示具有图2A、图2B、图2C及图2D的亲水区的图案的感湿变形织物于吸湿后的侧视示意图;Figures 3A, 3B, 3C and 3D are respectively schematic side views of the moisture-sensitive deformable fabric having the patterns of the hydrophilic regions of Figures 2A, 2B, 2C and 2D after moisture absorption;

其中,符号说明:Among them, the symbol description:

100:感湿变形织物 110:基布100: Moisture-sensitive deformation fabric 110: Base fabric

111,113:表面 120:感湿收缩墨水111,113: Surface 120: Moisture sensitive shrink ink

A1:亲水区 P1:圆形图案A1: Hydrophilic area P1: Circular pattern

P2:六边形图案 P3:长条形图案P2: Hexagonal pattern P3: Long bar pattern

O1:圆心 O2:中心O1: center of circle O2: center

D1,D4:最短距离 D2,D3:距离D1, D4: shortest distance D2, D3: distance

H:直径 W1,W2,W3:线条宽度H: diameter W1, W2, W3: line width

T1~T3:平均凹凸深度 X1:第一方向T1~T3: average concave and convex depth X1: first direction

X2:第二方向 θ:夹角。X2: second direction θ: included angle.

具体实施方式Detailed ways

以下将以附图揭露本揭露的多个实施方式,为明确地说明起见,许多实务上的细节将在以下叙述中一并说明。然而,应了解到,这些实务上的细节不应用以限制本揭露。也就是说,在本揭露部分实施方式中,这些实务上的细节是非必要的,因此不应用以限制本揭露。此外,为简化图式起见,一些习知惯用的结构与元件在图式中将以简单示意的方式绘示之。另外,为了便于读者观看,图式中各元件的尺寸并非依实际比例绘示。Various embodiments of the present disclosure will be disclosed in the accompanying drawings. For clarity of explanation, many practical details will be explained in the following description. However, it should be understood that these practical details should not be used to limit the disclosure. That is to say, in some implementations of the disclosure, these practical details are not necessary and therefore should not be used to limit the disclosure. In addition, for the purpose of simplifying the drawings, some commonly used structures and components will be illustrated in a simple schematic manner in the drawings. In addition, for the convenience of readers, the dimensions of each element in the drawings are not drawn according to actual proportions.

在本文中,有时以键线式(skeleton formula)表示聚合物或基团的结构。这种表示法可省略碳原子、氢原子以及碳氢键。当然,结构式中有明确绘出原子或原子基团的,则以绘示者为准。In this article, the structure of a polymer or group is sometimes represented by a skeleton formula. This representation can omit carbon atoms, hydrogen atoms, and carbon-hydrogen bonds. Of course, if atoms or atomic groups are clearly drawn in the structural formula, the one shown shall prevail.

本揭露内容提供一种感湿变形织物,其具有由感湿收缩墨水喷涂而成的亲水区。透过亲水区的配置,感湿变形织物可在吸湿(例如,吸收汗水)后局部地产生变形,以于感湿变形织物与使用者身体间产生立体空间,从而减少感湿变形织物与使用者身体间的接触。如此一来,可有助于汗水的挥发并降低使用者身体的粘腻感,从而提供使用者良好的穿戴舒适感。The present disclosure provides a moisture-sensitive deformable fabric having hydrophilic areas sprayed with moisture-sensitive shrinkage ink. Through the configuration of the hydrophilic zone, the moisture-sensing deformation fabric can locally deform after absorbing moisture (for example, absorbing sweat) to create a three-dimensional space between the moisture-sensing deformation fabric and the user's body, thereby reducing the use of the moisture-sensing deformation fabric. body-to-body contact. In this way, it can help evaporate sweat and reduce the stickiness of the user's body, thereby providing the user with good wearing comfort.

图1绘示根据本揭露一些实施方式的感湿变形织物100的侧视示意图。感湿变形织物100包括基布110以及感湿收缩墨水120。感湿收缩墨水120利用数码喷印制程喷涂于基布110的任一表面111,以于基布110的表面111形成亲水区A1。在一些实施方式中,基布110可例如是由弹性纤维、非弹性纤维或其组合织造而成。举例而言,基布110可例如是由92%的聚酯纤维与8%的聚氨酯纤维共同织造而成的针织布或梭织布。在一些实施方式中,感湿收缩墨水120可喷涂于基布110面对外界环境的表面111,且由感湿收缩墨水120所形成的亲水区A1可具有多种图案,从而良好地达到感湿变形的效果,此将于下文中进行更详细的说明。FIG. 1 illustrates a schematic side view of a moisture-sensitive deformable fabric 100 according to some embodiments of the present disclosure. The moisture-sensitive deformable fabric 100 includes a base fabric 110 and moisture-sensitive shrinkage ink 120 . The moisture-sensitive shrinkable ink 120 is sprayed on any surface 111 of the base fabric 110 using a digital printing process to form a hydrophilic area A1 on the surface 111 of the base fabric 110 . In some embodiments, the base fabric 110 may be, for example, woven from elastic fibers, non-elastic fibers, or combinations thereof. For example, the base fabric 110 may be a knitted fabric or a woven fabric woven by 92% polyester fiber and 8% polyurethane fiber. In some embodiments, the moisture-sensitive shrinkage ink 120 can be sprayed on the surface 111 of the base fabric 110 facing the external environment, and the hydrophilic area A1 formed by the moisture-sensitive shrinkage ink 120 can have a variety of patterns, so as to achieve a good feel. The effect of wet deformation will be explained in more detail below.

具体而言,当使用者将感湿变形织物100穿戴于身体时,由于基布110相对于由感湿收缩墨水120所形成的亲水区A1具有较高的疏水性,且亲水区A1又是形成于基布110面对外界环境的表面111,因此由使用者身体所产生的汗水会受到一拉力(如图1的箭头方向)以由基布110面对使用者身体的表面113导引至基布110面对外界环境的表面111,从而有利于汗水的挥发。另一方面,导引至基布110的表面111的汗水可进入亲水区A1,使得亲水区A1因吸湿而产生变形,从而使感湿变形织物100局部地拱起或凹陷以于感湿变形织物100与使用者身体间产生立体空间。藉此,可减少感湿变形织物100与使用者身体间的接触,有助于汗水的挥发并降低使用者身体的粘腻感,从而提供使用者良好的穿戴舒适感。Specifically, when the user wears the moisture-sensitive deformable fabric 100 on the body, the base fabric 110 has higher hydrophobicity relative to the hydrophilic area A1 formed by the moisture-sensitive shrinkage ink 120, and the hydrophilic area A1 is It is formed on the surface 111 of the base fabric 110 facing the external environment. Therefore, the sweat generated by the user's body will receive a pulling force (in the direction of the arrow in Figure 1) and be guided by the surface 113 of the base fabric 110 facing the user's body. The surface 111 of the base fabric 110 faces the external environment, thereby facilitating the evaporation of sweat. On the other hand, the sweat guided to the surface 111 of the base fabric 110 can enter the hydrophilic area A1, causing the hydrophilic area A1 to deform due to moisture absorption, thereby causing the moisture-sensitive deformation fabric 100 to partially arch or dent to facilitate moisture sensing. A three-dimensional space is generated between the deformed fabric 100 and the user's body. This can reduce the contact between the moisture-sensitive deformable fabric 100 and the user's body, help evaporate sweat and reduce the stickiness of the user's body, thereby providing the user with good wearing comfort.

在一些实施方式中,感湿收缩墨水120主要包括15重量份至35重量份的感湿收缩树脂以及65重量份至85重量份的水。感湿收缩树脂具有多个胺基与羟基,并可牢固地配置于基布110上,从而赋予以其所制得的感湿收缩墨水120及感湿变形织物100良好的感湿收缩性。在一些实施方式中,感湿收缩树脂可以藉由包括以下试剂制备而成:多元醇、多元胺、第一交联剂以及第二交联剂。在一些实施方式中,多元醇的添加量可介于0.5重量份至1.5重量份间,多元胺的添加量可介于40重量份至50重量份间,第一交联剂的添加量可介于2.2重量份至2.6重量份间,且第二交联剂的添加量可介于0.4重量份至0.8重量份间。In some embodiments, the moisture-sensitive shrinkage ink 120 mainly includes 15 to 35 parts by weight of moisture-sensitive shrinkage resin and 65 to 85 parts by weight of water. The moisture-sensitive shrinkage resin has multiple amine groups and hydroxyl groups, and can be firmly disposed on the base fabric 110 , thereby imparting good moisture-sensitive shrinkage properties to the moisture-sensitive shrinkage ink 120 and the moisture-sensitive deformable fabric 100 produced therefrom. In some embodiments, the moisture-sensitive shrinkage resin can be prepared by including the following reagents: polyol, polyamine, first cross-linking agent and second cross-linking agent. In some embodiments, the amount of polyol added can range from 0.5 to 1.5 parts by weight, the amount of polyamine added can range from 40 to 50 parts by weight, and the amount of the first cross-linking agent can range from 0.5 to 1.5 parts by weight. Between 2.2 parts by weight and 2.6 parts by weight, and the amount of the second cross-linking agent can be between 0.4 parts by weight and 0.8 parts by weight.

在一些实施方式中,多元醇可提供感湿收缩树脂良好的感湿收缩性,使得感湿收缩墨水120具有良好的感湿收缩性。如此一来,以感湿收缩墨水120所制得的感湿变形织物100可具有高的单位面积收缩率。在一些实施方式中,多元醇可例如是含醚基的多元醇,包括聚乙二醇、聚丙二醇或聚四氢呋喃。在一些实施方式中,多元醇的重量平均分子量可介于200g/mole至600g/mole之间。具体而言,若多元醇的重量平均分子量小于200g/mole,可能导致所形成的感湿收缩树脂无法牢固地配置于基布110上,从而使得感湿变形织物100具有差的感湿收缩性以及水洗牢度;而若多元醇的重量平均分子量大于600g/mole,可能导致感湿收缩墨水120的粘度过高,从而不易喷涂于基布110上。In some embodiments, the polyol can provide the moisture-sensitive shrinkage resin with good moisture-sensitive shrinkage properties, so that the moisture-sensitive shrinkage ink 120 has good moisture-sensitive shrinkage properties. In this way, the moisture-sensitive deformable fabric 100 produced with the moisture-sensitive shrinkage ink 120 can have a high shrinkage rate per unit area. In some embodiments, the polyol may be, for example, an ether group-containing polyol including polyethylene glycol, polypropylene glycol, or polytetrahydrofuran. In some embodiments, the weight average molecular weight of the polyol may be between 200 g/mole and 600 g/mole. Specifically, if the weight average molecular weight of the polyol is less than 200 g/mole, the formed moisture-sensitive shrinkage resin may not be firmly disposed on the base fabric 110 , causing the moisture-sensitive deformation fabric 100 to have poor moisture-sensitive shrinkage and Washing fastness; and if the weight average molecular weight of the polyol is greater than 600g/mole, the viscosity of the moisture-sensitive shrinkage ink 120 may be too high, making it difficult to spray on the base fabric 110.

在一些实施方式中,多元胺可提供感湿收缩树脂良好的感湿收缩性,使得感湿收缩墨水120具有良好的感湿收缩性。如此一来,以感湿收缩墨水120所制得的感湿变形织物100可具有高的单位面积收缩率。在一些实施方式中,多元胺可包括聚醚胺、聚酰胺或聚酰亚胺。在另一些实施方式中,多元胺可包括脂肪族胺,以较佳地提供感湿收缩树脂良好的感湿收缩性。更具体而言,脂肪族胺可例如是己二胺、二乙基己二胺、三甲基己二胺、庚二胺、三甲基乙二胺、四乙基乙二胺、四甲基乙二胺、壬二胺、月桂胺二亚丙基二胺、二乙烯三胺、三乙烯四胺或聚乙烯亚胺。在一些实施方式中,多元胺的重量平均分子量可介于600g/mole至8000g/mole间,且较佳地可介于800g/mole至5500g/mole间。In some embodiments, the polyamine can provide the moisture-sensitive shrinkage resin with good moisture-sensitive shrinkage, so that the moisture-sensitive shrinkage ink 120 has good moisture-sensitive shrinkage. In this way, the moisture-sensitive deformable fabric 100 produced with the moisture-sensitive shrinkage ink 120 can have a high shrinkage rate per unit area. In some embodiments, the polyamine may include polyetheramine, polyamide, or polyimide. In other embodiments, the polyamine may include an aliphatic amine to preferably provide the moisture shrinkage resin with good moisture shrinkage properties. More specifically, the aliphatic amine may be, for example, hexanediamine, diethylhexanediamine, trimethylhexanediamine, heptanediamine, trimethylethylenediamine, tetraethylethylenediamine, tetramethylethylenediamine, Ethylenediamine, nonanediamine, laurylamine dipropylenediamine, diethylenetriamine, triethylenetetramine or polyethyleneimine. In some embodiments, the weight average molecular weight of the polyamine can range from 600g/mole to 8000g/mole, and preferably can range from 800g/mole to 5500g/mole.

在一些实施方式中,第一交联剂可包括异氰酸酯三聚体。具体而言,第一交联剂可包括如式(1)所示的结构单元,式(1)。在一些实施方式中,第一交联剂可包括脂肪族异氰酸酯(例如是HDI、TMDI或XDI)三聚体、脂环族异氰酸酯(例如是IPDI、HMDI或HTDI)三聚体、芳香族异氰酸酯(例如是TDI或MDI)三聚体或其组合。第一交联剂可包括异氰酸酯嵌段。举例而言,异氰酸酯三聚体的至少两末端可具有异氰酸酯嵌段。具体而言,在以式(1)表示的第一交联剂中,R1、R2及R3中任两者以上包括异氰酸酯嵌段。In some embodiments, the first cross-linking agent may include an isocyanate trimer. Specifically, the first cross-linking agent may include a structural unit represented by formula (1), Formula 1). In some embodiments, the first cross-linking agent may include aliphatic isocyanate (for example, HDI, TMDI or XDI) trimer, alicyclic isocyanate (for example, IPDI, HMDI or HTDI) trimer, aromatic isocyanate (for example For example, TDI or MDI) trimers or combinations thereof. The first cross-linking agent may include an isocyanate block. For example, at least two ends of the isocyanate trimer may have isocyanate blocks. Specifically, in the first cross-linking agent represented by formula (1), any two or more of R 1 , R 2 and R 3 include an isocyanate block.

在一些实施方式中,第二交联剂与第一交联剂可具有相同的分子结构。在一些实施方式中,第二交联剂的添加量与第一交联剂的添加量的比例可例如介于1:5至1:3间。在一些实施方式中,第二交联剂与第一交联剂中的异氰酸酯嵌段的总量与多元醇中羟基的总量的比值可介于1.0至2.5间。In some embodiments, the second cross-linking agent and the first cross-linking agent may have the same molecular structure. In some embodiments, the ratio of the added amount of the second cross-linking agent to the added amount of the first cross-linking agent may be, for example, between 1:5 and 1:3. In some embodiments, the ratio of the total amount of isocyanate blocks in the second cross-linking agent to the first cross-linking agent to the total amount of hydroxyl groups in the polyol can range from 1.0 to 2.5.

在一些实施方式中,感湿收缩墨水120的粘度可介于2.5cP至10.0cP间,使得喷印出的墨水液滴可具有合适的大小,并可使感湿收缩墨水120具有合适的流动性以利于数码喷印制程。另一方面,感湿收缩墨水120的表面张力可介于22dyne/cm至32dyne/cm间,有利于墨水液滴于喷头处成形,并可使感湿收缩墨水120具有良好的渗透性。在一些实施方式中,感湿收缩墨水120中的分散质的粒径(D90)可介于90nm至360nm间,以避免在进行数码喷印制程的过程中发生喷头阻塞的问题,且可以使感湿收缩墨水120具有较佳的稳定性。上述分散质的粒径(D90)会影响感湿收缩墨水120的粘度。举例而言,感湿收缩墨水120中较小的分散质粒径可使感湿收缩墨水120具有较低的粘度。在一些实施方式中,感湿收缩墨水120在25℃时的pH值可介于6.0至8.5间,从而避免腐蚀喷印装置的喷头,且可避免墨水液滴沉积于喷头处而造成堵塞,有利于数码喷印制程。In some embodiments, the viscosity of the moisture-sensitive shrinkage ink 120 can be between 2.5cP and 10.0cP, so that the printed ink droplets can have a suitable size and the moisture-sensitive shrinkage ink 120 can have suitable fluidity. To facilitate the digital printing process. On the other hand, the surface tension of the moisture-sensitive shrinkable ink 120 can be between 22 dyne/cm and 32 dyne/cm, which is beneficial to the formation of ink droplets at the nozzle and allows the moisture-sensitive shrinkable ink 120 to have good permeability. In some embodiments, the particle size (D90) of the dispersion in the moisture-sensitive shrinkage ink 120 can be between 90 nm and 360 nm to avoid the problem of nozzle clogging during the digital printing process, and can make The moisture-sensitive shrinkage ink 120 has better stability. The particle size (D90) of the above-mentioned dispersion will affect the viscosity of the moisture-sensitive shrinkage ink 120. For example, a smaller dispersion particle size in the moisture-sensitive shrinkage ink 120 can cause the moisture-sensitive shrinkage ink 120 to have a lower viscosity. In some embodiments, the pH value of the moisture-sensitive shrinkage ink 120 at 25° C. can be between 6.0 and 8.5, thereby avoiding corrosion of the nozzle of the printing device and preventing ink droplets from being deposited on the nozzle to cause clogging. Conducive to digital printing process.

在一些实施方式中,感湿收缩墨水120可更包括5重量份至10重量份的保湿剂、0.004重量份至0.060重量份的表面活性剂及/或0.002重量份至0.020重量份的消泡剂。保湿剂可确保感湿收缩墨水120在喷印的过程中不会因凝结而沉积或阻塞喷头;表面活性剂可维持感湿收缩墨水120中的粒子(例如感湿收缩树脂、保湿剂等)的尺寸安定;消泡剂则可以确保感湿收缩墨水120中不具有泡沫。在一些实施方式中,保湿剂可例如是丙三醇、二甘醇、丙二醇甲醚或其组合。在一些实施方式中,表面活性剂可例如是聚二甲基硅氧烷、聚醚改性硅氧烷、聚醚改性聚二甲基硅氧烷或其组合。在一些实施方式中,消泡剂可例如是聚醚改性聚二甲基硅氧烷、破泡聚硅氧烷、溶于聚乙二醇中的破泡聚硅氧烷与憎水颗粒混合物或其组合。In some embodiments, the moisture-sensitive shrinkage ink 120 may further include 5 to 10 parts by weight of a humectant, 0.004 to 0.060 parts by weight of a surfactant, and/or 0.002 to 0.020 parts by weight of a defoaming agent. . The humectant can ensure that the moisture-sensitive shrinkage ink 120 will not be deposited or clog the nozzle due to condensation during the printing process; the surfactant can maintain the stability of the particles in the moisture-sensitive shrinkage ink 120 (such as moisture-sensitive shrinkage resin, humectant, etc.) The size is stable; the defoaming agent can ensure that there is no foam in the moisture-sensitive shrinkage ink 120. In some embodiments, the humectant may be, for example, glycerol, diethylene glycol, propylene glycol methyl ether, or combinations thereof. In some embodiments, the surfactant may be, for example, polydimethylsiloxane, polyether-modified siloxane, polyether-modified polydimethylsiloxane, or combinations thereof. In some embodiments, the antifoaming agent may be, for example, a polyether-modified polydimethylsiloxane, a foam-breaking polysiloxane, a mixture of foam-breaking polysiloxane and hydrophobic particles dissolved in polyethylene glycol. or combination thereof.

在一些实施方式中,感湿收缩墨水120可更包括适量的分散剂、适量的酸碱调整剂以及适量的抑菌剂。分散剂可确保感湿收缩墨水120中的分散质完全地分散,避免产生沉淀物或凝聚物而阻塞喷头;酸碱调整剂可确保感湿收缩墨水120的pH值介于6.0至8.5间,以避免感湿收缩墨水120因过度偏酸性或偏碱性而影响感湿收缩墨水中各成份的溶解性,从而容易形成沉淀物使得喷头阻塞或造成喷头腐蚀;抑菌剂可有效地抑制细菌生长。In some embodiments, the moisture-sensitive shrinkage ink 120 may further include an appropriate amount of dispersant, an appropriate amount of acid-base adjuster, and an appropriate amount of bacteriostatic agent. The dispersant can ensure that the dispersion in the moisture-sensitive shrinkage ink 120 is completely dispersed to avoid the generation of sediments or aggregations that will block the nozzle; the acid-base adjuster can ensure that the pH value of the moisture-sensitive shrinkage ink 120 is between 6.0 and 8.5. Prevent the moisture-sensitive shrinkage ink 120 from being excessively acidic or alkaline, which may affect the solubility of the components in the moisture-sensitive shrinkage ink, thereby easily forming sediments that may clog the nozzle or cause corrosion of the nozzle; bacteriostatic agents can effectively inhibit bacterial growth.

在一些实施方式中,感湿收缩墨水120可更包括适量的色料,以使欲喷印的织物呈现出合适的色彩。在一些实施方式中,感湿收缩墨水120中的色料的粒径(D90)可小于或等于250nm,以使色料有效地渗入至欲喷印的织物中,从而提升色牢度。在一些实施方式中,色料可例如是颜料或染料,且染料可例如是分散染料、高温型分散性染料、反应性染料或酸性染料。当感湿收缩墨水120中含有色料时,感湿收缩墨水120可藉由数码喷印制程一次性地赋予织物局部或全面的色彩及感湿收缩性能,有效地解决传统二次加工时因染料迁徙所导致的色牢度下降的问题。In some embodiments, the moisture-sensitive shrinkage ink 120 may further include an appropriate amount of colorant so that the fabric to be printed exhibits a suitable color. In some embodiments, the particle size (D90) of the color material in the moisture-sensitive shrinkage ink 120 can be less than or equal to 250 nm, so that the color material can effectively penetrate into the fabric to be printed, thereby improving color fastness. In some embodiments, the colorant may be, for example, a pigment or a dye, and the dye may be, for example, a disperse dye, a high-temperature disperse dye, a reactive dye, or an acid dye. When the moisture-sensitive shrinkage ink 120 contains colorants, the moisture-sensitive shrinkage ink 120 can impart partial or comprehensive color and moisture-sensitive shrinkage properties to the fabric at one time through the digital printing process, effectively solving the problems caused by traditional secondary processing. The problem of reduced color fastness caused by dye migration.

如前所述,由感湿收缩墨水120所形成的亲水区A1可具有多种图案,以良好地达到感湿变形的效果。请参阅图2A、图2B、图2C以及图2D,其绘示根据本揭露不同实施方式的感湿变形织物100的亲水区A1的图案的上视示意图。在以下叙述中,将针对亲水区A1的各种图案进行更详细的说明。As mentioned above, the hydrophilic area A1 formed by the moisture-sensitive shrinkage ink 120 can have various patterns to achieve a good effect of moisture-sensitive deformation. Please refer to FIGS. 2A, 2B, 2C and 2D, which illustrate schematic top views of the patterns of the hydrophilic areas A1 of the moisture-sensitive deformable fabric 100 according to different embodiments of the present disclosure. In the following description, various patterns of the hydrophilic region A1 will be described in more detail.

首先,请同时参阅图1及图2A。在一些实施方式中,亲水区A1可包括多个空心圆形图案P1。换句话说,感湿收缩墨水120经喷涂以于基布110的表面111形成多个空心圆形图案P1。在一些实施方式中,多个空心圆形图案P1可呈间隔排列,从而预留空间以供感湿变形织物100产生变形。在一些实施方式中,相邻的两空心圆形图案P1间的最短距离D1可介于4mm至12mm间,且相邻的两空心圆形图案P1各自的圆心O1间的距离D2可介于10mm至14mm间。如此一来,可确保感湿变形织物100整体具有足够的变形量,并预留足够的空间以供感湿变形织物100产生变形。详细而言,若相邻的两空心圆形图案P1间的最短距离D1小于4mm或者两空心圆形图案P1各自的圆心O1间的距离D2小于10mm,可能导致两空心圆形图案P1间不具有足够的空间供感湿变形织物100产生变形,易使感湿变形织物100因变形而过度地扭曲,影响使用者的穿戴舒适感;若相邻的两空心圆形图案P1间的最短距离D1大于12mm或者两空心圆形图案P1各自的圆心O1间的距离D2大于14mm,可能导致空心圆形图案P1分布的密度过低,使得感湿变形织物100整体的变形量不足。First, please refer to both Figure 1 and Figure 2A. In some embodiments, the hydrophilic area A1 may include a plurality of hollow circular patterns P1. In other words, the moisture-sensitive shrinkage ink 120 is sprayed to form a plurality of hollow circular patterns P1 on the surface 111 of the base fabric 110 . In some embodiments, a plurality of hollow circular patterns P1 may be arranged at intervals, thereby leaving space for the moisture-sensitive deformation fabric 100 to deform. In some embodiments, the shortest distance D1 between two adjacent hollow circular patterns P1 may be between 4 mm and 12 mm, and the distance D2 between the center O1 of each of the two adjacent hollow circular patterns P1 may be between 10 mm. to 14mm. In this way, it is ensured that the moisture-sensitive deformation fabric 100 has a sufficient deformation amount as a whole, and enough space is reserved for the moisture-sensitive deformation fabric 100 to deform. Specifically, if the shortest distance D1 between two adjacent hollow circular patterns P1 is less than 4mm or the distance D2 between the centers O1 of the two hollow circular patterns P1 is less than 10mm, it may result in that there is no space between the two hollow circular patterns P1. There is enough space for the moisture-sensitive deformation fabric 100 to deform, which may easily cause the moisture-sensitive deformation fabric 100 to be excessively distorted due to deformation, affecting the user's wearing comfort; if the shortest distance D1 between two adjacent hollow circular patterns P1 is greater than 12mm or the distance D2 between the centers O1 of the two hollow circular patterns P1 is greater than 14mm, which may cause the distribution density of the hollow circular patterns P1 to be too low, resulting in insufficient deformation of the moisture-sensitive deformation fabric 100 as a whole.

在一些实施方式中,空心圆形图案P1的直径H可介于5mm至8mm间,且空心圆形图案P1的线条宽度W可介于1.5mm至3.0mm间。空心圆形图案P1的直径H及空心圆形图案P1的线条宽度W1可影响空心圆形图案P1的面积,以影响感湿变形织物100整体于吸湿后的变形量。详细而言,若空心圆形图案P1的直径H小于5mm且空心圆形图案P1的线条宽度W1大于3.0mm,可能导致感湿变形织物100整体的变形面积太大,影响使用者的穿戴舒适感;若空心圆形图案P1的直径H大于8mm且空心圆形图案P1的线条宽度W1小于1.5mm,则可能导致感湿变形织物100整体的变形面积太小,使得感湿变形织物100整体的变形量不足。在一些实施方式中,多个空心圆形图案P1可进一步呈阵列排列,从而提升感湿变形织物100的变形均匀度。In some embodiments, the diameter H of the hollow circular pattern P1 may range from 5 mm to 8 mm, and the line width W of the hollow circular pattern P1 may range from 1.5 mm to 3.0 mm. The diameter H of the hollow circular pattern P1 and the line width W1 of the hollow circular pattern P1 can affect the area of the hollow circular pattern P1, thereby affecting the overall deformation amount of the moisture-sensitive deformation fabric 100 after absorbing moisture. Specifically, if the diameter H of the hollow circular pattern P1 is less than 5 mm and the line width W1 of the hollow circular pattern P1 is greater than 3.0 mm, the overall deformation area of the moisture-sensitive deformation fabric 100 may be too large, affecting the user's wearing comfort. ; If the diameter H of the hollow circular pattern P1 is greater than 8mm and the line width W1 of the hollow circular pattern P1 is less than 1.5mm, it may cause the overall deformation area of the moisture-sensitive deformation fabric 100 to be too small, causing the overall deformation of the moisture-sensitive deformation fabric 100 Insufficient quantity. In some embodiments, the plurality of hollow circular patterns P1 can be further arranged in an array, thereby improving the deformation uniformity of the moisture-sensitive deformation fabric 100 .

接着,请同时参阅图1及图2B。在一些实施方式中,多个空心圆形图案P1可例如呈交错排列。具体而言,多个空心圆形图案P1可沿第一方向X1以及第二方向X2排列,且第一方向X1与第二方向X2的夹角θ介于40度至50度间。在一些实施方式中,多个空心圆形图案P1可沿第一方向X1及第二方向X2等距地排列。基于上述配置,可使多个空心圆形图案P1以合适的密度分布于基布110的表面111,以确保感湿变形织物100于吸湿后具有一定程度的变形量。应了解到,相邻的两空心圆形图案P1间的最短距离D1、相邻的两空心圆形图案P1各自的圆心O1间的距离D2以及空心圆形图案P1的直径H与线条宽度W1皆可参照图2A的实施方式,于此便不再赘述。Next, please refer to Figure 1 and Figure 2B at the same time. In some embodiments, the plurality of hollow circular patterns P1 may be arranged in a staggered manner, for example. Specifically, the plurality of hollow circular patterns P1 may be arranged along the first direction X1 and the second direction X2, and the angle θ between the first direction X1 and the second direction X2 is between 40 degrees and 50 degrees. In some embodiments, the plurality of hollow circular patterns P1 may be equidistantly arranged along the first direction X1 and the second direction X2. Based on the above configuration, a plurality of hollow circular patterns P1 can be distributed on the surface 111 of the base fabric 110 at an appropriate density to ensure that the moisture-sensitive deformation fabric 100 has a certain degree of deformation after absorbing moisture. It should be understood that the shortest distance D1 between two adjacent hollow circular patterns P1, the distance D2 between the respective center O1 of two adjacent hollow circular patterns P1, and the diameter H and line width W1 of the hollow circular patterns P1 are all Reference may be made to the implementation of FIG. 2A , which will not be described again here.

随后,请同时参阅图1及图2C。在一些实施方式中,亲水区A1可包括多个空心六边形图案P2,且相邻的两空心六边形图案P2共用各自的其中一个边。换句话说,多个空心六边形图案P2于基布110的表面111形成蜂巢状的图案。在一些实施方式中,相邻的两空心六边形图案P2各自的中心O2间的距离D3可介于8mm至16mm间。如此一来,可确保感湿变形织物100整体具有足够的变形量,并预留足够的空间以供感湿变形织物100产生变形。在一些实施方式中,空心六边形图案P2的线条宽度W2可介于1.5mm至3.0mm间。详细而言,若空心六边形图案P2的线条宽度W1大于3.0mm,可能导致感湿变形织物100整体的变形面积太大,影响使用者的穿戴舒适感;若空心六边形图案P2的线条宽度W2小于1.5mm,则可能导致感湿变形织物100整体的变形面积太小,使得感湿变形织物100整体的变形量不足。在一些实施方式中,空心六边形图案P2的每一个边长皆相等,亦即空心六边形图案P2是空心正六边形,从而提升感湿变形织物100的变形均匀度。Then, please refer to Figure 1 and Figure 2C at the same time. In some embodiments, the hydrophilic area A1 may include a plurality of hollow hexagonal patterns P2, and two adjacent hollow hexagonal patterns P2 share one of their respective sides. In other words, the plurality of hollow hexagonal patterns P2 form a honeycomb pattern on the surface 111 of the base fabric 110 . In some embodiments, the distance D3 between the respective centers O2 of two adjacent hollow hexagonal patterns P2 may range from 8 mm to 16 mm. In this way, it is ensured that the moisture-sensitive deformation fabric 100 has a sufficient deformation amount as a whole, and enough space is reserved for the moisture-sensitive deformation fabric 100 to deform. In some embodiments, the line width W2 of the hollow hexagonal pattern P2 may range from 1.5 mm to 3.0 mm. Specifically, if the line width W1 of the hollow hexagonal pattern P2 is greater than 3.0mm, the overall deformation area of the moisture-sensitive deformable fabric 100 may be too large, affecting the user's wearing comfort; if the line width W1 of the hollow hexagonal pattern P2 If the width W2 is less than 1.5 mm, the overall deformation area of the moisture-sensitive deformation fabric 100 may be too small, causing the overall deformation amount of the moisture-sensitive deformation fabric 100 to be insufficient. In some embodiments, each side length of the hollow hexagon pattern P2 is equal, that is, the hollow hexagon pattern P2 is a hollow regular hexagon, thereby improving the deformation uniformity of the moisture-sensitive deformation fabric 100 .

最后,请同时参阅图1及图2D。在一些实施方式中,亲水区A1可包括多个长条形图案P3,且多个长条形图案P3呈平行且间隔排列。在一些实施方式中,长条形图案P3的线条宽度W3可介于5mm至20mm间,且相邻的两长条形图案P3间的最短距离D4可介于5mm至20mm间。在上述范围内,可使感湿变形织物100整体具有足够的变形量以及良好的变形均匀度。在一些实施方式中,长条形图案P3的线条宽度W3可与相邻的两长条形图案P3间的最短距离D4实质上相近或相同,且长条形图案P3可呈等距排列,从而提供感湿变形织物100较佳的变形均匀度。Finally, please refer to both Figure 1 and Figure 2D. In some embodiments, the hydrophilic region A1 may include a plurality of elongated patterns P3, and the plurality of elongated patterns P3 are arranged in parallel and at intervals. In some embodiments, the line width W3 of the strip pattern P3 may range from 5 mm to 20 mm, and the shortest distance D4 between two adjacent strip patterns P3 may range from 5 mm to 20 mm. Within the above range, the entire moisture-sensitive deformation fabric 100 can have sufficient deformation amount and good deformation uniformity. In some embodiments, the line width W3 of the strip pattern P3 may be substantially similar or the same as the shortest distance D4 between two adjacent strip patterns P3, and the strip patterns P3 may be arranged equidistantly, so that The moisture-sensitive deformation fabric 100 is provided with better deformation uniformity.

在以下叙述中,将针对本揭露多个实施例的感湿变形织物进行各种测试与评估,以进一步验证本揭露的功效。In the following description, various tests and evaluations will be conducted on the moisture-sensitive deformation fabrics of multiple embodiments of the present disclosure to further verify the efficacy of the present disclosure.

<实验例1:感湿变形织物的感湿收缩性评估><Experimental Example 1: Evaluation of moisture-sensitive shrinkage of moisture-sensitive deformation fabric>

在本实验例中,利用数码喷印制程将感湿收缩墨水喷涂于基布的表面,以形成具有亲水区的图案的感湿变形织物。接着,将感湿变形织物于水中浸湿,并量测与计算感湿变形织物于变形后所产生的平均凹凸深度。在各实施例的感湿变形织物中,基布是由92%的聚酯(PET)纤维与8%的聚氨酯(OP)纤维共同织造而成的针织布,且基布重是180gsm。各实施例的感湿变形织物的其他详细说明以及量测结果如表一所示。In this experimental example, a digital jet printing process is used to spray moisture-sensitive shrinkage ink on the surface of the base fabric to form a moisture-sensitive deformable fabric with a pattern of hydrophilic areas. Next, the moisture-sensitive deformable fabric is soaked in water, and the average depth of unevenness produced by the moisture-sensitive deformable fabric after deformation is measured and calculated. In the moisture-sensitive deformable fabrics of each embodiment, the base fabric is a knitted fabric woven from 92% polyester (PET) fiber and 8% polyurethane (OP) fiber, and the base fabric weight is 180 gsm. Other detailed descriptions and measurement results of the moisture-sensitive deformation fabrics of each embodiment are shown in Table 1.

表一Table I

图3A、图3B、图3C及图3D分别绘示具有图2A、图2B、图2C及图2D的亲水区的图案的感湿变形织物于吸湿后的侧视示意图。由表一可知,各实施例的感湿变形织物于吸湿后的平均凹凸深度可介于0.37mm至4.26mm间,其中实施例1至16的感湿变形织物的亲水区的图案是空心圆形图案,且其平均凹凸深度T1介于0.72mm至1.34mm间(如图3A以及图3B所示);实施例17至22的感湿变形织物的亲水区的图案是空心六边形图案,且其平均凹凸深度T2介于0.37mm至1.10mm间(如图3C所示);实施例23至32的感湿变形织物的亲水区的图案是长条形图案,且其平均凹凸深度T3介于1.18mm至4.26mm间(如图3D所示),显示各实施例的感湿变形织物于吸湿后皆具有一定程度的变形量,具有良好的感湿收缩性。整体而言,当亲水区的图案是长条形图案时,感湿变形织物具有较佳的感湿收缩性。Figures 3A, 3B, 3C and 3D are respectively schematic side views of the moisture-sensitive deformable fabric having the patterns of the hydrophilic regions of Figures 2A, 2B, 2C and 2D after moisture absorption. It can be seen from Table 1 that the average depth of the concavities and convexities of the moisture-sensitive deformation fabrics of each embodiment after moisture absorption can range from 0.37mm to 4.26mm. The pattern of the hydrophilic zone of the moisture-sensitive deformation fabrics of Examples 1 to 16 is a hollow circle. shaped pattern, and its average concave-convex depth T1 is between 0.72mm and 1.34mm (as shown in Figure 3A and Figure 3B); the pattern of the hydrophilic area of the moisture-sensitive deformation fabrics of Examples 17 to 22 is a hollow hexagonal pattern , and its average concave-convex depth T2 is between 0.37mm and 1.10mm (as shown in Figure 3C); the pattern of the hydrophilic area of the moisture-sensitive deformable fabric of Examples 23 to 32 is a long strip pattern, and its average concave-convex depth T3 ranges from 1.18mm to 4.26mm (as shown in Figure 3D), which shows that the moisture-sensitive deformable fabrics of each embodiment have a certain degree of deformation after moisture absorption and have good moisture-sensitive shrinkage. Overall, when the pattern of the hydrophilic area is a long strip pattern, the moisture-sensitive deformation fabric has better moisture-sensitive shrinkage.

<实验例2:不同织物规格的感湿变形织物的感湿收缩性评估><Experimental Example 2: Evaluation of moisture-sensitive shrinkage of moisture-sensitive deformation fabrics with different fabric specifications>

在本实验例中,利用数码喷印制程将感湿收缩墨水喷涂于不同规格的基布的表面,以形成具有亲水区的图案的感湿变形织物。接着,将感湿变形织物于水中浸湿,并量测以及计算感湿变形织物于变形后所产生的平均凹凸深度。各实施例的感湿变形织物的详细说明以及量测结果如表二所示。In this experimental example, a digital jet printing process is used to spray moisture-sensitive shrinkage ink on the surface of base fabrics of different specifications to form a moisture-sensitive deformable fabric with a pattern of hydrophilic areas. Next, the moisture-sensitive deformable fabric is soaked in water, and the average depth of unevenness produced by the moisture-sensitive deformable fabric after deformation is measured and calculated. The detailed description and measurement results of the moisture-sensitive deformation fabrics of each embodiment are shown in Table 2.

表二Table II

由表二可知,实施例33至41的感湿变形织物于吸湿后所产生的平均凹凸深度可介于0.34至5.65间,显示具有一定程度的变形量。换句话说,本揭露的感湿收缩墨水可利用数码喷印制程喷涂于不同规格的基布上,且所制得的感湿变形织物皆可具有良好的感湿收缩性。As can be seen from Table 2, the average depth of unevenness produced by the moisture-sensitive deformable fabrics of Examples 33 to 41 after absorbing moisture can range from 0.34 to 5.65, indicating a certain degree of deformation. In other words, the moisture-sensitive shrinkage ink of the present disclosure can be sprayed on base fabrics of different specifications using a digital printing process, and the resulting moisture-sensitive deformable fabrics can all have good moisture-sensitive shrinkage properties.

<实验例3:感湿变形织物的粘腻性评估><Experimental Example 3: Evaluation of stickiness of moisture-sensitive deformation fabric>

在本实验例中,分别对比较例1的织物及表一中部分的实施例的感湿变形织物进行拉伸粘滞力测试,其中比较例1的织物是由92%的聚酯纤维与8%的聚氨酯纤维共同织造而成的针织布。测试方法是将比较例的织物以及各实施例的感湿变形织物于水中浸湿,并分别将比较例的织物及各实施例的感湿变形织物放置于人工皮肤上,接着对比较例的织物及各实施例的感湿变形织物进行拉伸,其中拉伸的方向平行于织物的罗纹(rib)方向。测试结果如表三所示。In this experimental example, tensile viscosity tests were conducted on the fabric of Comparative Example 1 and the moisture-sensitive deformation fabrics of some of the examples in Table 1. The fabric of Comparative Example 1 is made of 92% polyester fiber and 8% polyester fiber. Knitted fabric woven with % polyurethane fiber. The test method is to soak the fabrics of the comparative example and the moisture-sensitive deformation fabrics of each embodiment in water, and place the fabrics of the comparative example and the moisture-sensitive deformation fabrics of each embodiment on the artificial skin, and then compare the fabrics of the comparative examples. The moisture-sensitive deformable fabrics of each embodiment are stretched, wherein the stretching direction is parallel to the rib direction of the fabric. The test results are shown in Table 3.

表三Table 3

由表三可知,相较于比较例的织物,各实施例的感湿变形织物皆可透过较小的拉伸粘滞力以与人工皮肤彼此分离。也就是说,各实施例的感湿变形织物于感湿变形后不易粘滞于使用者身体,有助于汗水的挥发并降低使用者身体的粘腻感,从而提供使用者良好的穿戴舒适感。It can be seen from Table 3 that compared with the fabric of the comparative example, the moisture-sensitive deformation fabrics of each embodiment can be separated from the artificial skin through smaller tensile viscosity. That is to say, the moisture-sensitive deformation fabrics of various embodiments are not easy to stick to the user's body after moisture-sensitive deformation, which helps to evaporate sweat and reduce the stickiness of the user's body, thereby providing the user with good wearing comfort. .

根据本揭露上述实施方式,本揭露的感湿变形织物具有由感湿收缩墨水喷涂而成的亲水区。透过亲水区的配置,感湿变形织物可在吸湿后局部地产生变形,以于感湿变形织物与使用者身体间产生立体空间,从而减少感湿变形织物与使用者身体间的接触。如此一来,可有助于汗水的挥发并降低使用者身体的粘腻感,从而提供使用者良好的穿戴舒适感。另一方面,透过亲水区的图案的设计,可进一步提升感湿变形织物的感湿收缩性。According to the above embodiments of the present disclosure, the moisture-sensitive deformable fabric of the present disclosure has hydrophilic areas sprayed with moisture-sensitive shrinkage ink. Through the configuration of the hydrophilic zone, the moisture-sensing deformation fabric can locally deform after absorbing moisture to create a three-dimensional space between the moisture-sensing deformation fabric and the user's body, thereby reducing the contact between the moisture-sensing deformation fabric and the user's body. In this way, it can help evaporate sweat and reduce the stickiness of the user's body, thereby providing the user with good wearing comfort. On the other hand, through the design of the pattern of the hydrophilic area, the moisture-sensitive shrinkage of the moisture-sensitive deformation fabric can be further improved.

虽然本揭露已以实施方式揭露如上,然其并非用以限定本揭露,任何熟习此技艺者,在不脱离本揭露的精神和范围内,当可作各种的更动与润饰,因此本揭露的保护范围当视后附的申请专利范围所界定者为准。Although the disclosure has been disclosed in the above embodiments, it is not intended to limit the disclosure. Anyone skilled in the art can make various changes and modifications without departing from the spirit and scope of the disclosure. Therefore, the disclosure The scope of protection shall be determined by the scope of the patent application attached.

Claims (9)

1.一种感湿变形织物,其特征在于,包括:1. A moisture-sensitive deformable fabric, characterized in that it includes: 基布;以及base cloth; and 感湿收缩墨水,利用数码喷印制程喷涂于所述基布的任一表面,其中所述感湿收缩墨水于所述基布的所述表面形成亲水区,所述感湿收缩墨水包括感湿收缩树脂,且所述感湿收缩树脂是藉由包括以下成分的试剂制备而成:The moisture-sensitive shrinkage ink is sprayed on any surface of the base fabric using a digital jet printing process, wherein the moisture-sensitive shrinkage ink forms a hydrophilic area on the surface of the base fabric, and the moisture-sensitive shrinkage ink includes Moisture-sensitive shrinkage resin, and the moisture-sensitive shrinkage resin is prepared by a reagent including the following components: 0.5重量份至1.5重量份的多元醇;0.5 parts by weight to 1.5 parts by weight of polyol; 40重量份至50重量份的多元胺;40 to 50 parts by weight of polyamine; 2.2重量份至2.6重量份的第一交联剂,包括异氰酸酯嵌段;以及2.2 to 2.6 parts by weight of the first crosslinking agent, including the isocyanate block; and 0.4重量份至0.8重量份第二交联剂,包括异氰酸酯嵌段。0.4 parts by weight to 0.8 parts by weight of the second cross-linking agent, including an isocyanate block. 2.如权利要求1所述的感湿变形织物,其中所述感湿收缩墨水具有介于2.5cP至10.0cP间的粘度以及介于22dyne/cm至32dyne/cm间的表面张力,且所述感湿收缩墨水包括15重量份至35重量份的感湿收缩树脂以及65重量份至85重量份的水。2. The moisture-sensitive deformable fabric of claim 1, wherein the moisture-sensitive shrinkage ink has a viscosity between 2.5cP and 10.0cP and a surface tension between 22dyne/cm and 32dyne/cm, and the The moisture-sensitive shrinkage ink includes 15 to 35 parts by weight of moisture-sensitive shrinkage resin and 65 to 85 parts by weight of water. 3.如权利要求1所述的感湿变形织物,其中所述亲水区包括多个空心圆形图案,且所述空心圆形图案呈间隔排列。3. The moisture-sensitive deformable fabric of claim 1, wherein the hydrophilic area includes a plurality of hollow circular patterns, and the hollow circular patterns are arranged at intervals. 4.如权利要求3所述的感湿变形织物,其中所述空心圆形图案呈阵列排列。4. The moisture-sensitive deformable fabric according to claim 3, wherein the hollow circular patterns are arranged in an array. 5.如权利要求3所述的感湿变形织物,其中所述空心圆形图案沿第一方向及第二方向排列,且所述第一方向与所述第二方向的夹角介于40度至50度间。5. The moisture-sensitive deformable fabric of claim 3, wherein the hollow circular patterns are arranged along the first direction and the second direction, and the angle between the first direction and the second direction is between 40 degrees. to 50 degrees. 6.如权利要求1所述的感湿变形织物,其中所述亲水区包括多个空心六边形图案,且相邻的两所述空心六边形图案共用各自的其中一边。6. The moisture-sensitive deformable fabric of claim 1, wherein the hydrophilic area includes a plurality of hollow hexagonal patterns, and two adjacent hollow hexagonal patterns share one side of each. 7.如权利要求6所述的感湿变形织物,其中所述空心六边形图案的每一边长皆相等。7. The moisture-sensitive deformable fabric of claim 6, wherein each side of the hollow hexagonal pattern is equal in length. 8.如权利要求1所述的感湿变形织物,其中所述亲水区包括多个长条形图案,且所述长条形图案呈平行排列。8. The moisture-sensitive deformable fabric of claim 1, wherein the hydrophilic area includes a plurality of strip-shaped patterns, and the strip-shaped patterns are arranged in parallel. 9.如权利要求8所述的感湿变形织物,其中所述长条形图案呈等距排列。9. The moisture-sensitive deformable fabric according to claim 8, wherein the strip patterns are arranged equidistantly.
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