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CN114517416A - PU double-layer crystal mirror surface leather and laminating method thereof - Google Patents

PU double-layer crystal mirror surface leather and laminating method thereof Download PDF

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CN114517416A
CN114517416A CN202111597867.6A CN202111597867A CN114517416A CN 114517416 A CN114517416 A CN 114517416A CN 202111597867 A CN202111597867 A CN 202111597867A CN 114517416 A CN114517416 A CN 114517416A
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曾皓
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Shengguo Dongguan New Material Technology Co ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097Release surface, e.g. separation sheets; Silicone papers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明公开一种PU双制层水晶镜面革及其贴合方法,包括以下步骤:步骤一:在基布上方涂覆湿法PU层;步骤二:将干法PU纹路层涂覆在湿法PU层上方;步骤三:在干法PU纹路层上方套印印刷层,获得第一阶段半成品;步骤四:在镜面离型纸上方涂覆透明色聚氨酯弹性体浆料后烘干形成透明色聚氨酯弹性体,在透明色聚氨酯弹性体上方涂覆聚氨酯浆料烘半干做为黏着层,获得第二阶段半成品;步骤五:在第一阶段半成品的印刷层上注入助剂后再贴合第二阶段半成品的黏着层;步骤六:将气泡排挤出第一阶段半成品和第二阶段半成品复合后的外表面,再依次通过贴合‑烘干‑冷却而制成PU双制层水晶镜面革,其主要是通过各步骤的设计,其具有水晶感强、通透性好等优点。

Figure 202111597867

The invention discloses a PU double-layer crystal mirror leather and a laminating method thereof, comprising the following steps: step 1: coating a wet-process PU layer on a base cloth; step 2: coating a dry-process PU texture layer on a wet-process PU layer Above the PU layer; Step 3: Overprint the printing layer on the dry PU texture layer to obtain the first-stage semi-finished product; Step 4: Coat the transparent color polyurethane elastomer slurry on the mirror release paper and dry to form a transparent color polyurethane elastic The second stage semi-finished product is obtained; Step 5: Inject the auxiliary agent on the printing layer of the first stage semi-finished product and then attach the second stage The adhesive layer of the semi-finished product; Step 6: Expel the air bubbles out of the composite outer surface of the first-stage semi-finished product and the second-stage semi-finished product, and then make PU double-layer crystal mirror leather by laminating-drying-cooling in sequence. It is designed through various steps, which has the advantages of strong crystal feeling and good permeability.

Figure 202111597867

Description

PU双制层水晶镜面革及其贴合方法PU double-layer crystal mirror leather and its bonding method

技术领域technical field

本发明涉及合成革制作领域技术,尤其是指一种PU双制层水晶镜面革及其贴合方法。The invention relates to the technology in the field of synthetic leather production, in particular to a PU double-layer crystal mirror leather and a bonding method thereof.

背景技术Background technique

PU合成革又称聚氨酯合成革,一般用基布与聚氨酯涂覆层构成,广泛使用于做箱包、服装、鞋、车辆和家具,其应用范围之广,数量之大,品种之多是传统的天然皮革无法满足,但现有的PU双制层水晶镜面产品却无法广泛生产使用,主要是由于聚氨酯本身的原因其生产易产生气泡空白点造成通透度不佳、效率低、成本高,客户可选择的纹路较少,一般只适用于细纹路,稍深纹路容易产生异常。PU synthetic leather, also known as polyurethane synthetic leather, is generally composed of base fabric and polyurethane coating layer. It is widely used in luggage, clothing, shoes, vehicles and furniture. Its wide application range, large quantity and variety are traditional Natural leather cannot be satisfied, but the existing PU double-layer crystal mirror products cannot be widely produced and used, mainly due to the reasons of polyurethane itself, its production is prone to bubbles and blank spots, resulting in poor permeability, low efficiency and high cost. There are few selected textures, generally only suitable for fine textures, and slightly deeper textures are prone to abnormality.

因此,需要研究一种新的技术方案来解决上述问题。Therefore, it is necessary to study a new technical solution to solve the above problems.

发明内容SUMMARY OF THE INVENTION

有鉴于此,本发明针对现有技术存在之缺失,其主要目的是提供一种PU双制层水晶镜面革及其贴合方法,其通过各层结构及制作步骤的设计,来增加产品的水晶感通透度及舒软感,减少原有气泡异常提高通透度及效率,贴合后的PU双制层革其具有水晶感强、通透性好、极少产生气泡、手感佳、生产效率高、成本低等优点。In view of this, the present invention is aimed at the deficiencies existing in the prior art, and its main purpose is to provide a PU double-layer crystal mirror leather and a bonding method thereof, which increase the crystal of the product through the design of each layer structure and manufacturing steps. Feel the permeability and softness, reduce the abnormality of the original bubbles, improve the permeability and efficiency, the laminated PU double-layer leather has strong crystal feeling, good permeability, very few bubbles, good hand feeling, production High efficiency and low cost.

为实现上述目的,本发明采用如下之技术方案:To achieve the above object, the present invention adopts the following technical scheme:

一种PU双制层水晶镜面革,包括有由下而上依次复合设置的基布、湿法PU层、干法PU纹路层、印刷层、黏着层、透明色聚氨酯弹性体。The utility model relates to a PU double-layer crystal mirror leather, which comprises a base cloth, a wet-process PU layer, a dry-process PU texture layer, a printing layer, an adhesive layer, and a transparent-colored polyurethane elastomer which are compounded sequentially from bottom to top.

一种如上述PU双制层水晶镜面革的贴合方法,包括以下步骤:A method for laminating the above-mentioned PU double-layer crystal mirror leather, comprising the following steps:

步骤一:在基布上方涂覆湿法PU层;Step 1: Coat the wet PU layer on the base cloth;

步骤二:将干法PU纹路层涂覆在湿法PU层上方;Step 2: coating the dry PU texture layer on the wet PU layer;

步骤三:在干法PU纹路层上方套印印刷层,获得第一阶段半成品;Step 3: Overprint the printing layer on the dry PU texture layer to obtain the first-stage semi-finished product;

步骤四:在镜面离型纸上方涂覆透明色聚氨酯弹性体浆料后烘干形成透明色聚氨酯弹性体,在透明色聚氨酯弹性体上方涂覆聚氨酯浆料烘半干做为黏着层,获得第二阶段半成品;Step 4: Coating the transparent color polyurethane elastomer slurry on the mirror surface release paper and drying to form a transparent color polyurethane elastomer, coating the polyurethane slurry on the transparent color polyurethane elastomer and drying it semi-dry as an adhesive layer to obtain the first step. Second-stage semi-finished products;

步骤五:在第一阶段半成品的印刷层上注入助剂后再贴合第二阶段半成品的黏着层;Step 5: Inject the auxiliary agent on the printing layer of the first-stage semi-finished product and then attach the adhesive layer of the second-stage semi-finished product;

步骤六:将气泡排挤出第一阶段半成品和第二阶段半成品复合后的外表面,再依次通过贴合-烘干-冷却而制成PU双制层水晶镜面革。Step 6: Expel the air bubbles out of the composite outer surface of the first-stage semi-finished product and the second-stage semi-finished product, and then make PU double-layer crystal mirror leather by laminating-drying-cooling in sequence.

作为一种优选方案,在步骤一中:首先,将基布预湿,预湿后,挤干-烫平使基布含湿量保持在80%-95%;接着,在浸湿后的基布上涂覆PU湿法浆料,再依次通过凝固-水洗-烘干,制成PU湿基材。As a preferred solution, in step 1: first, pre-wet the base cloth, after pre-wetting, squeeze dry-ironing to keep the moisture content of the base cloth at 80%-95%; The cloth is coated with PU wet-process slurry, and then successively passes through coagulation-washing-drying to prepare a PU wet substrate.

作为一种优选方案,通过预湿液将基布预湿。As a preferred solution, the base fabric is pre-wetted with a pre-wetting liquid.

作为一种优选方案,所述预湿液为10%-25%的DMF水溶液。As a preferred solution, the pre-wetting liquid is a 10%-25% DMF aqueous solution.

作为一种优选方案,所述印刷层为双色印刷层。As a preferred solution, the printing layer is a two-color printing layer.

本发明与现有技术相比具有明显的优点和有益效果,具体而言,由上述技术方案可知,其主要是通过各层结构及制作步骤的设计,采用透明色聚氨酯弹性体树脂,来增加产品的水晶感通透度及舒软感,且在干法层纹路表面上注入助剂再贴合透明色聚氨酯弹性体,将气泡排挤出PU革表面,减少原有气泡异常提高通透度及效率,同时,贴合后的PU双制层革其具有水晶感强、通透性好、极少产生气泡、手感佳、生产效率高、成本低等优点。Compared with the prior art, the present invention has obvious advantages and beneficial effects. Specifically, it can be seen from the above technical solutions that it mainly adopts transparent color polyurethane elastomer resin to increase the number of products through the design of each layer structure and production steps. The crystal-like permeability and soft feeling are improved, and additives are injected on the surface of the dry-laid texture, and then the transparent-colored polyurethane elastomer is pasted to expel the air bubbles from the surface of the PU leather, reducing the abnormality of the original air bubbles and improving the permeability and efficiency. , At the same time, the laminated PU double-layer leather has the advantages of strong crystal feeling, good permeability, little bubble generation, good hand feeling, high production efficiency and low cost.

为更清楚地阐述本发明的结构特征和功效,下面结合附图与具体实施例来对本发明进行详细说明。In order to illustrate the structural features and effects of the present invention more clearly, the present invention will be described in detail below with reference to the accompanying drawings and specific embodiments.

附图说明Description of drawings

图1是本发明之实施例的第一阶段半成品截面图;1 is a cross-sectional view of a first-stage semi-finished product according to an embodiment of the present invention;

图2是本发明之实施例的第二阶段半成品截面图(贴合离型纸);FIG. 2 is a cross-sectional view of the second-stage semi-finished product according to the embodiment of the present invention (laminating the release paper);

图3是本发明之实施例的成品截面图(贴合离型纸);FIG. 3 is a sectional view of the finished product (laminated release paper) according to an embodiment of the present invention;

图4是本发明之实施例的成品截面图(离型纸撕开示意);4 is a sectional view of a finished product of an embodiment of the present invention (removal of release paper);

图5是本发明之实施例的成品截面图(撕掉离型纸后)。FIG. 5 is a sectional view of the finished product (after tearing off the release paper) according to an embodiment of the present invention.

附图标识说明:Description of drawings:

10、基布 20、湿法PU层10. Base fabric 20. Wet PU layer

30、干法PU纹路层 40、印刷层30. Dry PU texture layer 40. Printing layer

50、黏着层 60、透明色聚氨酯弹性体50. Adhesive layer 60. Transparent color polyurethane elastomer

70、离型纸。70. Release paper.

具体实施方式Detailed ways

请参照图1至图5所示,其显示出了本发明之实施例的具体结构。Please refer to FIG. 1 to FIG. 5 , which show the specific structure of the embodiment of the present invention.

一种PU双制层水晶镜面革,包括有由下而上依次复合设置的基布10、湿法PU层20、干法PU纹路层30、印刷层40、黏着层50、透明色聚氨酯弹性体60,采用透明色聚氨酯弹性体树脂,来增加产品的水晶感通透度及舒软感,且在干法层纹路表面上注入助剂再贴合透明色聚氨酯弹性体60,将气泡排挤出PU革表面,减少原有气泡异常提高通透度及效率。A PU double-layer crystal mirror leather, comprising a base cloth 10, a wet-process PU layer 20, a dry-process PU texture layer 30, a printing layer 40, an adhesive layer 50, and a transparent-colored polyurethane elastomer, which are sequentially compounded from bottom to top. 60. Use transparent color polyurethane elastomer resin to increase the crystal transparency and softness of the product, and inject additives on the surface of the dry layer texture and then paste the transparent color polyurethane elastomer 60 to expel the air bubbles out of the PU Leather surface, reduce the abnormality of original bubbles and improve the permeability and efficiency.

所述的PU双制层水晶镜面革的贴合方法,包括以下步骤:The method for laminating the PU double-layer crystal mirror leather comprises the following steps:

步骤一:在基布10上方涂覆湿法PU层20;Step 1: coating the wet PU layer 20 on the base cloth 10;

步骤二:将干法PU纹路层30涂覆在湿法PU层20上方;Step 2: coating the dry PU texture layer 30 on the wet PU layer 20;

步骤三:在干法PU纹路层30上方套印印刷层40,获得第一阶段半成品;Step 3: Overprint the printing layer 40 on the dry PU texture layer 30 to obtain the first-stage semi-finished product;

步骤四:在镜面离型纸70上方涂覆透明色聚氨酯弹性体浆料后烘干形成透明色聚氨酯弹性体60,在透明色聚氨酯弹性体60上方涂覆聚氨酯浆料烘半干做为黏着层50,获得第二阶段半成品;Step 4: Coating transparent color polyurethane elastomer slurry on the mirror surface release paper 70 and drying to form a transparent color polyurethane elastomer 60, coating polyurethane slurry on top of the transparent color polyurethane elastomer 60 and drying semi-dry as an adhesive layer 50. Obtain the second-stage semi-finished product;

步骤五:在第一阶段半成品的印刷层40上注入助剂后再贴合第二阶段半成品的黏着层50;Step 5: injecting the auxiliary agent on the printing layer 40 of the first-stage semi-finished product, and then attaching the adhesive layer 50 of the second-stage semi-finished product;

步骤六:将气泡排挤出第一阶段半成品和第二阶段半成品复合后的外表面,再依次通过贴合-烘干-冷却而制成PU双制层水晶镜面革,贴合后的PU双制层革其具有水晶感强、通透性好、极少产生气泡、手感佳、生产效率高、成本低等优点。Step 6: Expel the air bubbles out of the composite outer surface of the first-stage semi-finished product and the second-stage semi-finished product, and then sequentially pass lamination-drying-cooling to make PU double-layer crystal mirror leather, and the laminated PU double-made Layer leather has the advantages of strong crystal feeling, good permeability, very few bubbles, good hand feeling, high production efficiency and low cost.

优选地,所述印刷层为双色印刷层。Preferably, the printing layer is a two-color printing layer.

在本实施例中,在步骤一中:首先,将基布10预湿,通过预湿液将基布10预湿,所述预湿液为10%-25%的DMF水溶液,预湿后,挤干-烫平使基布含湿量保持在80%-95%;接着,在浸湿后的基布10上涂覆PU湿法浆料,再依次通过凝固-水洗-烘干,制成PU湿基材。In this embodiment, in step 1: first, the base fabric 10 is pre-wetted, and the base fabric 10 is pre-wetted with a pre-wet solution, the pre-wet solution is a 10%-25% DMF aqueous solution. Squeeze dry-ironing to keep the moisture content of the base cloth at 80%-95%; then, coat the wet PU slurry on the soaked base cloth 10, and then sequentially pass through coagulation-washing-drying to make PU wet substrate.

本发明的设计重点在于,其主要是通过各层结构及制作步骤的设计,采用透明色聚氨酯弹性体树脂,来增加产品的水晶感通透度及舒软感,且在干法层纹路表面上注入助剂再贴合透明色聚氨酯弹性体,将气泡排挤出PU革表面,减少原有气泡异常提高通透度及效率,同时,贴合后的PU双制层革其具有水晶感强、通透性好、极少产生气泡、手感佳、生产效率高、成本低等优点。The key point of the design of the present invention is that it mainly adopts the transparent color polyurethane elastomer resin through the design of the structure of each layer and the production steps to increase the crystal permeability and soft feeling of the product, and on the surface of the dry layer texture Injecting additives and then laminating the transparent polyurethane elastomer to expel the air bubbles out of the surface of the PU leather, reducing the abnormality of the original air bubbles and improving the permeability and efficiency. It has the advantages of good permeability, little bubble generation, good hand feeling, high production efficiency and low cost.

以上所述,仅是本发明的较佳实施例而已,并非对本发明的技术范围作任何限制,故凡是依据本发明的技术实质对以上实施例所作的任何细微修改、等同变化与修饰,均仍属于本发明技术方案的范围内。The above are only preferred embodiments of the present invention, and do not limit the technical scope of the present invention. Therefore, any minor modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention are still It belongs to the scope of the technical solution of the present invention.

Claims (6)

1. The utility model provides a two system layer crystal mirror surface leathers of PU which characterized in that: comprises a base cloth, a wet PU layer, a dry PU grain layer, a printing layer, an adhesion layer and a transparent polyurethane elastomer which are sequentially and compositely arranged from bottom to top.
2. The method for bonding the PU double-layer crystal mirror leather according to claim 1, wherein the method comprises the following steps: the method comprises the following steps:
the method comprises the following steps: coating a wet PU layer on the base cloth;
step two: coating the dry-method PU texture layer on the wet-method PU layer;
step three: overprinting a printing layer on the dry-method PU grain layer to obtain a first-stage semi-finished product;
step four: coating transparent polyurethane elastomer slurry on the mirror release paper, drying to form a transparent polyurethane elastomer, coating polyurethane slurry on the transparent polyurethane elastomer, and drying to be semi-dry to be used as an adhesive layer to obtain a second-stage semi-finished product;
step five: injecting an auxiliary agent on the printing layer of the first-stage semi-finished product and then attaching the adhesive layer of the second-stage semi-finished product;
step six: and extruding the bubbles out of the outer surface of the first-stage semi-finished product and the second-stage semi-finished product after compounding, and sequentially laminating, drying and cooling to prepare the PU double-layer crystal mirror surface leather.
3. The method for bonding PU double-layer crystal mirror leather according to claim 2, wherein: in the first step: firstly, pre-wetting a base cloth, and after pre-wetting, squeezing and ironing to keep the moisture content of the base cloth at 80% -95%; and then, coating the wet PU slurry on the soaked base fabric, and sequentially performing solidification, washing and drying to prepare the wet PU base material.
4. The method for bonding PU double-layer crystal mirror leather according to claim 3, wherein: and pre-wetting the base cloth by using a pre-wetting liquid.
5. The method for bonding PU double-layer crystal mirror leather according to claim 4, wherein: the pre-wetting solution is 10-25% of DMF aqueous solution.
6. The method for bonding PU double-layer crystal mirror leather according to claim 1, wherein: the printing layer is a double-color printing layer.
CN202111597867.6A 2021-12-24 2021-12-24 PU double-layer crystal mirror surface leather and laminating method thereof Pending CN114517416A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0073389A1 (en) * 1981-08-28 1983-03-09 Bayer Ag Coating and finishing agent for leather, and leather substitute based on a polyurethane-polyurea coating composition
CN205804016U (en) * 2016-05-30 2016-12-14 东莞市盛国仿真皮革技术有限公司 A PU crystal mirror bonding structure

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0073389A1 (en) * 1981-08-28 1983-03-09 Bayer Ag Coating and finishing agent for leather, and leather substitute based on a polyurethane-polyurea coating composition
CN205804016U (en) * 2016-05-30 2016-12-14 东莞市盛国仿真皮革技术有限公司 A PU crystal mirror bonding structure

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