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CN114459024B - Flame synthesis burner capable of realizing axial and tangential combined rotational flow flexible adjustment - Google Patents

Flame synthesis burner capable of realizing axial and tangential combined rotational flow flexible adjustment Download PDF

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Publication number
CN114459024B
CN114459024B CN202210129593.6A CN202210129593A CN114459024B CN 114459024 B CN114459024 B CN 114459024B CN 202210129593 A CN202210129593 A CN 202210129593A CN 114459024 B CN114459024 B CN 114459024B
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axial
tangential
air
flow
inlet pipe
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CN114459024A (en
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李水清
靳星
宋民航
张易阳
伍泽赟
雷舒婷
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Tsinghua University
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D11/00Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space
    • F23D11/10Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space the spraying being induced by a gaseous medium, e.g. water vapour
    • F23D11/101Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space the spraying being induced by a gaseous medium, e.g. water vapour medium and fuel meeting before the burner outlet
    • F23D11/102Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space the spraying being induced by a gaseous medium, e.g. water vapour medium and fuel meeting before the burner outlet in an internal mixing chamber
    • F23D11/103Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space the spraying being induced by a gaseous medium, e.g. water vapour medium and fuel meeting before the burner outlet in an internal mixing chamber with means creating a swirl inside the mixing chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D11/00Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space
    • F23D11/36Details, e.g. burner cooling means, noise reduction means
    • F23D11/38Nozzles; Cleaning devices therefor
    • F23D11/383Nozzles; Cleaning devices therefor with swirl means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D11/00Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space
    • F23D11/36Details, e.g. burner cooling means, noise reduction means
    • F23D11/40Mixing tubes or chambers; Burner heads
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)

Abstract

The invention relates to a flame synthesis burner capable of realizing flexible adjustment of axial and tangential combined rotational flow, which comprises: the fuel can be sprayed out after being atomized by the cyclone atomizer, the axial concurrent air inlet pipe and the axial countercurrent air inlet pipe are arranged on the axial air flow mixing section, the axial direction of the axial concurrent air inlet pipe and the axial direction of the axial countercurrent air inlet pipe are tangential to the outer circumferential surface of the axial air flow mixing section, the communication position of the axial concurrent air inlet pipe and the axial air flow mixing cavity and the communication position of the axial countercurrent air inlet pipe and the axial air flow mixing cavity are staggered along the axial direction of the axial air flow mixing section, the rotation directions of the axial concurrent air and the axial countercurrent air are opposite, and the flow ratio of the air flow in the axial concurrent air inlet pipe to the air flow in the axial countercurrent air inlet pipe is 100 percent: 0% to 0%: variation between 100%. The rotational flow direction and the rotational flow strength of the air flow in the axial air flow mixing cavity can be continuously and flexibly adjusted by adjusting the flow ratio of the forward air flow to the reverse air flow.

Description

可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器Flame synthesis burner that can realize flexible adjustment of axial and tangential combined swirl

技术领域technical field

本发明涉及纳米材料合成技术领域,特别是涉及可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器。The invention relates to the technical field of nanomaterial synthesis, in particular to a flame synthesis burner capable of flexibly adjusting axial and tangential combined swirl flow.

背景技术Background technique

纳米材料具有粒径小、比表面积大等特点,且其在光学和电学方面具有优异性能,故而在诸多领域取得了较为广泛的应用。目前,纳米颗粒合成主要采用化学合成和火焰合成的方法,与化学合成方法相比,采用火焰合成法所得到的纳米颗粒具有一步合成、纯度高、颗粒物粒径可控性好等特点,在纳米粉体材料的合成方面具有广阔的应用前景。Nanomaterials have the characteristics of small particle size, large specific surface area, etc., and they have excellent optical and electrical properties, so they have been widely used in many fields. At present, the synthesis of nanoparticles mainly adopts the methods of chemical synthesis and flame synthesis. Compared with the chemical synthesis method, the nanoparticles obtained by the flame synthesis method have the characteristics of one-step synthesis, high purity, and good particle size controllability. The synthesis of powder materials has broad application prospects.

在各类型火焰合成燃烧技术中,燃烧器是火焰合成的关键设备。在旋流火焰合成燃烧器中,气流的旋流特性及旋流构建方式对纳米粉体颗粒物的形态具有很大影响。然而,在目前的旋流火焰合成燃烧器中,需要通过调整旋流叶片角度来实现对入射气流旋流特性及旋流强度的调节,整个装置的结构较为复杂,需要外接执行器才能实现对旋流叶片角度的连续性调节。因此,需要开发同样具备高灵活调控性且结构较为简单的旋流火焰合成燃烧器结构。Among various flame synthesis combustion technologies, the burner is the key equipment for flame synthesis. In the swirling flame synthesis burner, the swirling characteristics of the gas flow and the swirling construction method have a great influence on the shape of the nano-powder particles. However, in the current swirling flame synthesis burner, it is necessary to adjust the angle of the swirling blades to adjust the swirling characteristics and swirling intensity of the incident airflow. Continuous adjustment of flow vane angle. Therefore, it is necessary to develop a swirl flame synthesis burner structure that also has high flexibility and controllability and a relatively simple structure.

发明内容Contents of the invention

基于此,本发明提出一种可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器,通过调整顺流气与逆流气两股气流的流量比,可以实现对轴向气流混合腔及切向气流混合腔内气流的旋流方向和旋流强度进行连续性灵活调节,提升所构建的高温回流区动态调整能力,从而实现对合成纳米颗粒物的粒径、形态和晶相的灵活调控,并提高火焰合成纳米颗粒物的产量和生产效率。此外,该可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器无需设置旋流叶片、外接执行器等较为复杂的结构,整体结构更加简单,制造成本与难度均更低。Based on this, the present invention proposes a flame synthesizing burner that can realize the flexible adjustment of axial and tangential combined swirling flow. The swirl direction and swirl intensity of the airflow in the tangential airflow mixing chamber can be continuously and flexibly adjusted to improve the dynamic adjustment ability of the high-temperature reflow zone constructed, so as to realize the flexible regulation of the particle size, shape and crystal phase of the synthesized nanoparticles. And improve the yield and production efficiency of the flame synthesis of nanoparticles. In addition, the flame synthesizing burner that can realize the flexible adjustment of axial and tangential combined swirl does not need to install more complicated structures such as swirl blades and external actuators, the overall structure is simpler, and the manufacturing cost and difficulty are lower.

可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器,包括:Flame synthesis burners that can realize flexible adjustment of axial and tangential combined swirl flow, including:

轴向气流混合段,轴向气流混合段的内部设有轴向气流混合腔,所述轴向气流混合腔内安装有旋流雾化器,燃料能够经所述旋流雾化器雾化后喷出,所述轴向气流混合段上安装有与所述轴向气流混合腔连通的轴向顺流进气管与轴向逆流进气管,所述轴向顺流进气管的轴向、所述轴向逆流进气管的轴向均与所述轴向气流混合段的外周面相切,且所述轴向顺流进气管与所述轴向气流混合腔的连通位置、所述轴向逆流进气管与所述轴向气流混合腔的连通位置沿所述轴向气流混合段的轴向错开,经所述轴向顺流进气管流入所述轴向气流混合腔的空气形成绕所述旋流雾化器螺旋前进的轴向顺流气,经所述轴向逆流进气管流入所述轴向气流混合腔的空气形成绕所述旋流雾化器螺旋前进的轴向逆流气,所述轴向顺流气与所述轴向逆流气的旋向相反,所述轴向顺流进气管内的空气流量与所述轴向逆流进气管内的空气流量的流量比在100%:0%至0%:100%之间变化。Axial airflow mixing section. An axial airflow mixing chamber is arranged inside the axial airflow mixing section. A swirl atomizer is installed in the axial airflow mixing chamber, and the fuel can be atomized by the swirl atomizer. The axial flow air inlet pipe and the axial counterflow air inlet pipe communicated with the axial air flow mixing chamber are installed on the axial air flow mixing section, the axial direction of the axial flow air inlet pipe, the The axial direction of the axial counterflow inlet pipe is tangent to the outer peripheral surface of the axial airflow mixing section, and the communication position between the axial forward flow inlet pipe and the axial airflow mixing chamber, the axial counterflow inlet pipe The communication position with the axial airflow mixing chamber is staggered along the axial direction of the axial airflow mixing section, and the air flowing into the axial airflow mixing chamber through the axial forward flow inlet pipe forms a swirling mist around the The axial co-flow air that advances spirally in the nebulizer, the air that flows into the axial air flow mixing chamber through the axial counter-flow inlet pipe forms the axial counter-flow air that advances helically around the swirl atomizer, and the axial co-flow air The direction of rotation of the flow air is opposite to that of the axial counterflow air, and the flow ratio of the air flow in the axial forward flow intake pipe to the air flow in the axial counterflow intake pipe is 100%: 0% to 0%: Varies between 100%.

在其中一个实施例中,还包括切向气流混合段,所述切向气流混合段套设于所述轴向气流混合段的开口端的外部,所述切向气流混合段包括呈环状的切向气流混合腔,所述切向气流混合段上安装有与所述切向气流混合腔连通的切向顺流进气管与切向逆流进气管,所述切向顺流进气管的轴向、所述切向逆流进气管的轴向均与所述切向气流混合段的外周面相切,且所述切向顺流进气管与所述切向气流混合腔的连通位置、所述切向逆流进气管与所述切向气流混合腔的连通位置沿所述切向气流混合段的轴向错开,经所述切向顺流进气管流入所述切向气流混合腔的空气螺旋前进形成环绕所述开口端的切向顺流气,经所述切向逆流进气管流入所述切向气流混合腔的空气螺旋前进形成环绕所述开口端的切向逆流气,所述切向顺流气与所述切向逆流气的旋向相反,且沿所述轴向气流混合段的径向,所述切向顺流气与所述切向逆流气位于所述轴向顺流气与所述轴向逆流气的外侧,所述切向顺流进气管内的空气流量与所述切向逆流进气管内的空气流量的流量比在100%:0%至0%:100%之间变化。In one of the embodiments, it further includes a tangential airflow mixing section, the tangential airflow mixing section is sleeved outside the opening end of the axial airflow mixing section, and the tangential airflow mixing section includes an annular cut To the airflow mixing chamber, the tangential airflow mixing section is equipped with a tangential forward flow inlet pipe and a tangential counterflow air inlet pipe communicating with the tangential airflow mixing chamber, the axial direction of the tangential forward flow inlet pipe, The axial direction of the tangential counterflow inlet pipe is tangent to the outer peripheral surface of the tangential airflow mixing section, and the communication position between the tangential forward flow inlet pipe and the tangential airflow mixing chamber, the tangential counterflow The communication position between the air intake pipe and the tangential air flow mixing chamber is staggered along the axial direction of the tangential air flow mixing section, and the air flowing into the tangential air flow mixing chamber through the tangential downstream air inlet pipe spirals forward to form a circle around the The tangential co-flow air at the opening end, the air flowing into the tangential air flow mixing chamber through the tangential counter-flow air inlet pipe spirals forward to form the tangential counter-flow air surrounding the opening end, the tangential co-flow air and the tangential air flow The counter-flow air has the opposite rotation direction, and along the radial direction of the axial air-flow mixing section, the tangential co-flow air and the tangential counter-flow air are located outside the axial co-flow air and the axial counter-flow air, The flow ratio of the air flow in the tangential forward flow intake pipe to the air flow in the tangential reverse flow intake pipe varies between 100%:0% and 0%:100%.

在其中一个实施例中,所述切向气流混合段包括呈环状的侧板以及与所述侧板的端部连接的端板,所述侧板内部中空以形成所述切向气流混合腔,所述端板内部中空以形成与所述切向气流混合腔连通的切向气流出口环,所述端板上设有与所述切向气流出口环连通的缺口,所述切向顺流气与所述切向逆流气沿所述切向气流出口环的周向流动并经所述缺口流出所述可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器。In one of the embodiments, the tangential airflow mixing section includes an annular side plate and an end plate connected to the end of the side plate, and the inside of the side plate is hollow to form the tangential airflow mixing chamber , the inside of the end plate is hollow to form a tangential air flow outlet ring communicating with the tangential air flow mixing chamber, the end plate is provided with a gap communicating with the tangential air flow outlet ring, the tangential co-flow air The tangential counterflow gas flows along the circumference of the tangential gas flow outlet ring and flows out of the flame synthesis burner that can realize flexible adjustment of axial and tangential combined swirl through the gap.

在其中一个实施例中,还包括呈环状且两端开口的气流分隔段,所述侧板与所述端板限定出第一安装腔,所述气流分隔段安装于所述第一安装腔的腔壁,所述气流分隔段包括第二安装腔,所述开口端伸入所述第二安装腔,经所述开口端喷出的气流与燃料穿过所述缺口朝外喷出。In one of the embodiments, it further includes a ring-shaped air flow separation section with two ends open, the side plate and the end plate define a first installation cavity, and the air flow separation section is installed in the first installation cavity The wall of the chamber, the air flow partition section includes a second installation chamber, the opening end extends into the second installation chamber, and the air flow and fuel ejected through the opening end are ejected outward through the gap.

在其中一个实施例中,沿所述轴向气流混合段的轴向,所述气流分隔段的外端与所述轴向气流混合段的外端之间存在高度差。In one embodiment, along the axial direction of the axial airflow mixing section, there is a height difference between the outer end of the airflow dividing section and the outer end of the axial airflow mixing section.

在其中一个实施例中,沿所述轴向气流混合段的径向,所述轴向顺流进气管与所述轴向气流混合腔的连通位置、所述轴向逆流进气管与所述轴向气流混合腔的连通位置分别位于所述轴向气流混合段的两端;以及/或者,In one of the embodiments, along the radial direction of the axial airflow mixing section, the communication position between the axial forward flow inlet pipe and the axial airflow mixing chamber, the axial reverse flow inlet pipe and the shaft The communication positions to the airflow mixing chamber are respectively located at both ends of the axial airflow mixing section; and/or,

沿所述切向气流混合段的径向,所述切向顺流进气管与所述切向气流混合腔的连通位置、所述切向逆流进气管与所述切向气流混合腔的连通位置分别位于所述切向气流混合段的两端。Along the radial direction of the tangential airflow mixing section, the communication position between the tangential forward flow inlet pipe and the tangential airflow mixing chamber, and the communication position between the tangential counterflow air inlet pipe and the tangential airflow mixing chamber They are respectively located at both ends of the tangential airflow mixing section.

在其中一个实施例中,还包括镂空旋流盘,所述镂空旋流盘安装于所述开口端,所述旋流雾化器穿过所述镂空旋流盘的中心孔朝外伸出,所述旋流雾化器上设有多个沿自身周向间隔排布的通孔,沿所述镂空旋流盘的径向,所述通孔位于所述中心孔的外侧,所述轴向顺流气与所述轴向逆流气经所述通孔喷出。In one of the embodiments, it further includes a hollow swirl disk, the hollow swirl disk is installed on the opening end, and the swirl atomizer protrudes outward through the central hole of the hollow swirl disk, The swirl atomizer is provided with a plurality of through holes arranged at intervals along its circumferential direction. Along the radial direction of the hollow swirl disc, the through holes are located outside the central hole, and the axial The co-current air and the axially counter-current air are ejected through the through holes.

在其中一个实施例中,所述旋流雾化器包括雾化喷嘴与主体部,所述轴向气流混合段包括位于所述开口端的对侧的封闭端,所述主体部穿过所述封闭端伸入所述轴向气流混合腔并插入所述中心孔,且所述主体部固定连接于所述封闭端,所述雾化喷嘴抵持于所述镂空旋流盘上背离所述轴向气流混合腔的一侧,所述雾化喷嘴与所述主体部固定连接,燃料能够经所述主体部流入,并经所述雾化喷嘴喷出。In one of the embodiments, the swirl atomizer includes an atomizing nozzle and a main body, the axial air flow mixing section includes a closed end opposite to the open end, and the main body passes through the closed end. The end extends into the axial air flow mixing chamber and is inserted into the central hole, and the main body part is fixedly connected to the closed end, and the atomizing nozzle is supported on the hollow swirl disc away from the axial direction. On one side of the airflow mixing chamber, the atomizing nozzle is fixedly connected with the main body, fuel can flow in through the main body, and be sprayed out through the atomizing nozzle.

在其中一个实施例中,所述轴向顺流进气管的轴向、所述轴向逆流进气管的轴向均相对于所述轴向气流混合段的端面倾斜,沿所述轴向顺流进气管内的气流流向,所述轴向顺流进气管与所述轴向气流混合段的气流流出口的间距逐渐减小,沿所述轴向逆流进气管内的气流流向,所述轴向逆流进气管与所述气流流出口的间距逐渐减小。In one of the embodiments, the axial direction of the axial forward flow inlet pipe and the axial direction of the axial reverse flow inlet pipe are both inclined relative to the end face of the axial air flow mixing section, and the axial direction along the axial direction The air flow direction in the air intake pipe, the distance between the axial flow air intake pipe and the air flow outlet of the axial air flow mixing section gradually decreases, and the air flow direction in the axial counterflow air intake pipe, the axial direction The distance between the reverse flow inlet pipe and the airflow outlet gradually decreases.

在其中一个实施例中,所述旋流雾化器的内部设有沿所述轴向气流混合段的轴向延伸的前驱物中心管与外层剪切气管,所述前驱物中心管的出口与所述外层剪切气管的出口均与所述雾化喷嘴连通,所述外层剪切气管套设于所述前驱物中心管的外部,经所述雾化喷嘴喷出的空气包裹于燃料的外部。In one of the embodiments, the interior of the swirl atomizer is provided with a precursor central tube and an outer layer shear gas tube extending axially along the axial flow mixing section, and the outlet of the precursor central tube The outlet of the outer layer shearing air pipe is connected with the atomizing nozzle, the outer layer shearing air pipe is sleeved outside the central tube of the precursor, and the air ejected through the atomizing nozzle is wrapped in the Fuel outside.

上述可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器,经轴向顺流进气管流入轴向气流混合腔的空气形成绕旋流雾化器螺旋前进的轴向顺流气,经轴向逆流进气管流入轴向气流混合腔的空气形成绕旋流雾化器螺旋前进的轴向逆流气,轴向顺流气与轴向逆流气的旋向相反,当轴向顺流进气管内的空气流量与轴向逆流进气管内的空气流量的流量比在100%:0%至0%:100%之间变化时,轴向气流混合腔内轴向顺流气与轴向逆流气的流量占比随之发生变化。当轴向顺流气的流量较大而占主导时,轴向气流混合腔内的气流呈顺时针螺旋前进,且轴向顺流气的流量越大,轴向气流混合腔内的顺时针气流的旋流强度越大;当轴向逆流气的流量较大而占主导时,轴向气流混合腔内的气流呈逆时针螺旋前进,且轴向逆流气的流量越大,轴向气流混合腔内的逆时针气流的旋流强度越大。当轴向逆流气流量与轴向顺流气流量间的流量比在100%:0%至0%:100%间逐渐增大过程中,将使轴向气流混合段100内部的逆时针旋转气流旋流强度逐渐减小,逐渐转变为沿着轴向直流气流流动,而后产生顺时针的旋转气流,并且其旋流强度逐渐增大。通过调整顺流气与逆流气两股气流的流量比,可以对轴向气流混合腔及切向气流混合腔内气流的旋流方向和旋流强度进行连续性灵活调节,从而较为灵活的调节纳米粉体颗粒物合成过程。此外,该可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器在进行调节时,无需设置旋流叶片、外接执行器等较为复杂的结构,整体结构更加简单,制造成本与难度均更低。The above-mentioned flame synthesis burner that can realize the flexible adjustment of axial and tangential combined swirl flow, the air flowing into the axial flow mixing chamber through the axial flow inlet pipe forms the axial flow air that spirals around the swirl atomizer, The air flowing into the axial airflow mixing chamber through the axial counterflow air inlet pipe forms the axial counterflow air that spirals around the swirl atomizer. When the flow ratio of the air flow in the air flow and the air flow in the axial counterflow intake pipe changes between 100%:0% and 0%:100%, the ratio of the axial forward flow air and the axial counterflow air in the axial airflow mixing chamber The proportion of traffic changes accordingly. When the flow rate of axially downstream air is large and dominant, the airflow in the axial airflow mixing chamber advances in a clockwise spiral, and the greater the flow rate of axially downstream air, the greater the flow rate of the clockwise airflow in the axial airflow mixing chamber. The greater the flow intensity is; when the flow rate of the axial counterflow air is large and dominant, the airflow in the axial airflow mixing chamber advances in a counterclockwise spiral, and the greater the flow rate of the axial counterflow air, the greater the flow rate in the axial airflow mixing chamber. The swirl strength of the counterclockwise airflow is greater. When the flow ratio between the axial counter-flow air flow and the axial co-flow air flow gradually increases from 100%:0% to 0%:100%, the counterclockwise rotating air flow inside the axial air flow mixing section 100 will be swirled. The flow intensity gradually decreases, and gradually transforms into a direct flow along the axial direction, and then generates a clockwise swirling airflow, and its swirl intensity gradually increases. By adjusting the flow ratio of the two streams of forward flow air and counterflow air, the swirl direction and swirl intensity of the airflow in the axial flow mixing chamber and tangential flow mixing chamber can be continuously and flexibly adjusted, so that the nano powder can be adjusted more flexibly Body particle synthesis process. In addition, the flame synthesizing burner, which can realize the flexible adjustment of axial and tangential combined swirl flow, does not need to set more complicated structures such as swirl blades and external actuators when adjusting, the overall structure is simpler, and the manufacturing cost and difficulty are lower.

(1)相比于常规在雾化前驱物的周围布置值班火焰的技术方案(通常使用CH4或天然气燃烧构建值班火焰),本发明通过结构及配风设计,可在完全依靠雾化液体燃料的自身燃烧放热及合理耦合周围环形旋流风的燃烧组织方式下,实现旋流火焰合成燃烧器的自维持燃烧;(1) Compared with the conventional technical scheme of arranging duty flames around the atomized precursor (usually using CH4 or natural gas combustion to build duty flames), the present invention can completely rely on atomized liquid fuels through structure and air distribution design. The self-sustaining combustion of the swirling flame synthesis burner is realized under the self-combustion heat release and the reasonable coupling of the surrounding annular swirl wind combustion organization;

(2)在中心雾化前驱物的周向,由内至外,依次布置了轴向旋流风和切向旋流风,且轴向旋流风与切向旋流风中间间隔有气流分隔段,确保对高温火焰场的轴向分布及径向分布尺寸及位置的灵活调节,达到对纳米粉体颗粒物成核、聚并及烧结过程的快速有效调节,实现有效控制合成纳米颗粒物的粒径、形态和晶相;(2) In the circumferential direction of the central atomized precursor, from the inside to the outside, the axial swirl wind and the tangential swirl wind are arranged in sequence, and there is an air separation section between the axial swirl wind and the tangential swirl wind to ensure the The flexible adjustment of the axial distribution and radial distribution size and position of the high-temperature flame field can achieve rapid and effective adjustment of the nucleation, coalescence and sintering process of nano-powder particles, and realize effective control of the particle size, shape and crystallinity of the synthesized nanoparticles. Mutually;

(3)本发明中所构建的轴向旋流风和切向旋流风,均可通过调整顺流气与逆流气两股气流间的风量比来对气流的旋流方向和旋流强度进行连续性在线灵活调节,增加了对纳米粉体颗粒物合成过程的灵活调节措施;(3) The axial swirl wind and the tangential swirl wind constructed in the present invention can continuously carry out on-line swirl direction and swirl intensity of the airflow by adjusting the air volume ratio between the two streams of downstream air and countercurrent air. Flexible adjustment, adding flexible adjustment measures to the synthesis process of nano-powder particles;

(4)本发明所述的雾化火焰合成燃烧器结构简单,便于设计加工、制造成本低,有利于提高单只雾化火焰合成燃烧器的粉体材料合成产量,促进雾化旋流火焰合成技术的规模化推广应用。(4) The atomized flame synthesis burner of the present invention has a simple structure, is convenient for design and processing, and has low manufacturing cost, which is conducive to improving the powder material synthesis output of a single atomization flame synthesis burner and promoting atomization swirl flame synthesis Large-scale promotion and application of technology.

附图说明Description of drawings

图1为本发明一实施例中的可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器的整体结构示意图;Figure 1 is a schematic diagram of the overall structure of a flame-combining burner capable of flexibly adjusting axial and tangential combined swirls in an embodiment of the present invention;

图2为图1中可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器的俯视图;Figure 2 is a top view of the flame synthesis burner that can realize the flexible adjustment of axial and tangential combined swirl in Figure 1;

图3为图2中B-B处的剖视图;Fig. 3 is the sectional view of B-B place among Fig. 2;

图4为图1中A-A处的剖视图;Fig. 4 is the sectional view of A-A place among Fig. 1;

图5为图1中可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器的镂空旋流盘的结构示意图;Fig. 5 is a structural schematic diagram of the hollow swirl disc of the flame synthesis burner that can realize the flexible adjustment of axial and tangential combined swirl in Fig. 1;

图6为构建逆时针旋流气流时的气流流动示意图;Fig. 6 is the airflow flow schematic diagram when constructing counterclockwise swirl airflow;

图7为构建顺时针旋流气流时的气流流动示意图;Fig. 7 is the airflow flow schematic diagram when constructing the clockwise swirling airflow;

图8为图1中可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器的气流流向与火焰分布示意图;Fig. 8 is a schematic diagram of the airflow direction and flame distribution of the flame synthesis burner that can realize the flexible adjustment of axial and tangential combined swirl in Fig. 1;

图9为图1中可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器的尺寸示意图。Fig. 9 is a schematic diagram of the size of the flame synthesis burner in Fig. 1 that can realize the flexible adjustment of axial and tangential combined swirl.

附图标记:Reference signs:

轴向气流混合段100、轴向气流混合腔110;Axial airflow mixing section 100, axial airflow mixing chamber 110;

切向气流混合段200、切向气流混合腔210、切向气流出口环220、侧板230、端板240、缺口241;Tangential airflow mixing section 200, tangential airflow mixing chamber 210, tangential airflow outlet ring 220, side plate 230, end plate 240, gap 241;

轴向顺流进气管310、轴向逆流进气管320、切向顺流进气管330、切向逆流进气管340;Axial forward flow air intake pipe 310, axial reverse flow air intake pipe 320, tangential forward flow air intake pipe 330, tangential reverse flow air intake pipe 340;

旋流雾化器400、雾化喷嘴410、主体部420、前驱物中心管421、外层剪切气管422;Swirl atomizer 400, atomizing nozzle 410, main body 420, precursor central tube 421, outer shear gas tube 422;

气流分隔段500、第二安装腔510;The airflow separation section 500, the second installation chamber 510;

镂空旋流盘600、通孔610、中心孔620;Hollow swirl disc 600, through hole 610, center hole 620;

前驱物入口管710、剪切气入口管720。Precursor inlet pipe 710, shear gas inlet pipe 720.

具体实施方式Detailed ways

为使本发明的上述目的、特征和优点能够更加明显易懂,下面结合附图对本发明的具体实施方式做详细的说明。在下面的描述中阐述了很多具体细节以便于充分理解本发明。但是本发明能够以很多不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本发明内涵的情况下做类似改进,因此本发明不受下面公开的具体实施例的限制。In order to make the above objects, features and advantages of the present invention more comprehensible, specific implementations of the present invention will be described in detail below in conjunction with the accompanying drawings. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. However, the present invention can be implemented in many other ways different from those described here, and those skilled in the art can make similar improvements without departing from the connotation of the present invention, so the present invention is not limited by the specific embodiments disclosed below.

在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In describing the present invention, it should be understood that the terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", " Back", "Left", "Right", "Vertical", "Horizontal", "Top", "Bottom", "Inner", "Outer", "Clockwise", "Counterclockwise", "Axial" , "radial", "circumferential" and other indicated orientations or positional relationships are based on the orientations or positional relationships shown in the drawings, which are only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying the referred device or Elements must have certain orientations, be constructed and operate in certain orientations, and therefore should not be construed as limitations on the invention.

此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。在本发明的描述中,“多个”的含义是至少两个,例如两个,三个等,除非另有明确具体的限定。In addition, the terms "first" and "second" are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features. Thus, the features defined as "first" and "second" may explicitly or implicitly include at least one of these features. In the description of the present invention, "plurality" means at least two, such as two, three, etc., unless otherwise specifically defined.

在本发明中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the present invention, unless otherwise clearly specified and limited, terms such as "installation", "connection", "connection" and "fixation" should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection , or integrated; it may be mechanically connected or electrically connected; it may be directly connected or indirectly connected through an intermediary, and it may be the internal communication of two components or the interaction relationship between two components, unless otherwise specified limit. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present invention according to specific situations.

在本发明中,除非另有明确的规定和限定,第一特征在第二特征“上”或“下”可以是第一和第二特征直接接触,或第一和第二特征通过中间媒介间接接触。而且,第一特征在第二特征“之上”、“上方”和“上面”可是第一特征在第二特征正上方或斜上方,或仅仅表示第一特征水平高度高于第二特征。第一特征在第二特征“之下”、“下方”和“下面”可以是第一特征在第二特征正下方或斜下方,或仅仅表示第一特征水平高度小于第二特征。In the present invention, unless otherwise clearly specified and limited, the first feature may be in direct contact with the first feature or the first and second feature may be in direct contact with the second feature through an intermediary. touch. Moreover, "above", "above" and "above" the first feature on the second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is higher in level than the second feature. "Below", "beneath" and "beneath" the first feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is less horizontally than the second feature.

需要说明的是,当元件被称为“固定于”或“设置于”另一个元件,它可以直接在另一个元件上或者也可以存在居中的元件。当一个元件被认为是“连接”另一个元件,它可以是直接连接到另一个元件或者可能同时存在居中元件。本文所使用的术语“垂直的”、“水平的”、“上”、“下”、“左”、“右”以及类似的表述只是为了说明的目的,并不表示是唯一的实施方式。It should be noted that when an element is referred to as being “fixed on” or “disposed on” another element, it may be directly on the other element or there may be an intervening element. When an element is referred to as being "connected to" another element, it can be directly connected to the other element or intervening elements may also be present. As used herein, the terms "vertical", "horizontal", "upper", "lower", "left", "right" and similar expressions are for the purpose of illustration only and are not intended to represent the only embodiments.

参阅图1至图3,以及图8,本发明一实施例提供的可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器包括轴向气流混合段100,轴向气流混合段100的内部设有轴向气流混合腔110,轴向气流混合腔110内安装有旋流雾化器400,燃料能够经旋流雾化器400雾化后喷出,轴向气流混合段100上安装有与轴向气流混合腔110连通的轴向顺流进气管310与轴向逆流进气管320,轴向顺流进气管310的轴向、轴向逆流进气管320的轴向均与轴向气流混合段100的外周面相切,且轴向顺流进气管310与轴向气流混合腔110的连通位置、轴向逆流进气管320与轴向气流混合腔110的连通位置沿轴向气流混合段100的轴向错开,经轴向顺流进气管310流入轴向气流混合腔110的空气形成绕旋流雾化器400螺旋前进的轴向顺流气,经轴向逆流进气管320流入轴向气流混合腔110的空气形成绕旋流雾化器400螺旋前进的轴向逆流气,轴向顺流气与轴向逆流气的旋向相反,轴向顺流进气管310内的空气流量与轴向逆流进气管320内的空气流量的流量比在100%:0%至0%:100%之间变化。Referring to Fig. 1 to Fig. 3, and Fig. 8, the flame synthesis burner that can realize the flexible adjustment of axial and tangential combined swirl provided by an embodiment of the present invention includes an axial airflow mixing section 100, and an axial airflow mixing section 100 Axial airflow mixing chamber 110 is arranged inside the axial airflow mixing chamber 110. A swirl atomizer 400 is installed in the axial airflow mixing chamber 110. The fuel can be atomized by the swirl atomizer 400 and sprayed out. There is an axial forward flow inlet pipe 310 and an axial counterflow inlet pipe 320 communicating with the axial airflow mixing chamber 110. The outer peripheral surface of the mixing section 100 is tangent, and the communication position between the axial forward flow inlet pipe 310 and the axial airflow mixing chamber 110 and the communication position between the axial counterflow inlet pipe 320 and the axial airflow mixing chamber 110 are along the direction of the axial airflow mixing section 100 Axially staggered, the air flowing into the axial airflow mixing chamber 110 through the axial forward flow inlet pipe 310 forms axially forward flow air spirally advancing around the swirl atomizer 400, and flows into the axial airflow mixing chamber through the axial counterflow inlet pipe 320 The air in the chamber 110 forms an axially countercurrent air that spirals forward around the swirl atomizer 400. The direction of the axially forward air is opposite to that of the axially counterflow air. The flow ratio of the air flow in the air duct 320 varies from 100%:0% to 0%:100%.

具体地,轴向气流混合段100的外形呈圆柱状,轴向气流混合段100的内部中空以形成轴向气流混合腔110,轴向气流混合段100的一端为封闭端,另一端为开口端。在附图所示视角下,上下方向即为轴向气流混合段100的轴向,轴向气流混合段100的底端为封闭端,顶端为开口端。旋流雾化器400同轴安装于轴向气流混合腔110的中心位置。液体燃料(例如醇基液体燃料)经旋流雾化器400雾化形成小液滴状并朝上喷出。轴向顺流进气管310与轴向逆流进气管320安装于轴向气流混合段100上靠近封闭端的位置。轴向顺流进气管310与轴向逆流进气管320可以呈空心圆柱状,也可以呈空心长方体等形状。当为空心长方体状时,其轴向即为长方体的长度方向。轴向顺流进气管310与轴向气流混合腔110的连通位置、轴向逆流进气管320与轴向气流混合腔110的连通位置沿轴向气流混合段100的轴向错开,以防止轴向顺流气与轴向逆流气相撞而无法按预期方向与速度流动。在附图所示实施例中,轴向顺流进气管310位于轴向逆流进气管320的上方,在其他实施例中,也可以将轴向逆流进气管320设置于轴向顺流进气管310的上方。空气经轴向顺流进气管310与轴向逆流进气管320流入轴向气流混合腔110后,将形成两股环绕旋流雾化器400的螺旋状朝上前进的旋流风,其中一股为顺时针螺旋前进的轴向顺流气,另一股为逆时针螺旋前进的轴向逆流气。Specifically, the shape of the axial air mixing section 100 is cylindrical, and the inside of the axial air mixing section 100 is hollow to form an axial air mixing chamber 110. One end of the axial air mixing section 100 is a closed end, and the other end is an open end. . From the perspective shown in the drawings, the up and down direction is the axial direction of the axial air mixing section 100 , the bottom end of the axial air mixing section 100 is a closed end, and the top end is an open end. The swirl atomizer 400 is coaxially installed at the center of the axial airflow mixing chamber 110 . The liquid fuel (such as alcohol-based liquid fuel) is atomized by the swirl atomizer 400 to form small droplets and sprayed upward. The axial forward flow inlet pipe 310 and the axial counterflow inlet pipe 320 are installed on the axial airflow mixing section 100 near the closed end. The axial forward-flow intake pipe 310 and the axial counter-flow intake pipe 320 may be in the shape of a hollow cylinder, or may be in the shape of a hollow cuboid or the like. When it is a hollow cuboid, its axial direction is the length direction of the cuboid. The communication position of the axial forward flow inlet pipe 310 and the axial air flow mixing chamber 110, and the communication position of the axial counterflow inlet pipe 320 and the axial air flow mixing chamber 110 are staggered along the axial direction of the axial air flow mixing section 100 to prevent the axial The co-flow air collides with the axial counter-flow air and cannot flow in the expected direction and speed. In the embodiment shown in the drawings, the axial forward flow intake pipe 310 is located above the axial reverse flow intake pipe 320 , in other embodiments, the axial reverse flow intake pipe 320 can also be arranged on the axial forward flow intake pipe 310 above. After the air flows into the axial airflow mixing chamber 110 through the axial forward flow air inlet pipe 310 and the axial counterflow air inlet pipe 320, two swirl winds will be formed which surround the swirl atomizer 400 and advance spirally upwards, one of which is Axial flow air that advances in a clockwise spiral, and another axial counterflow air that advances in a counterclockwise spiral.

当轴向顺流进气管310内的空气流量与轴向逆流进气管320内的空气流量的流量比在100%:0%至0%:100%之间变化时,轴向气流混合腔110内轴向顺流气与轴向逆流气的流量占比随之发生变化。当轴向顺流气的流量较大而占主导时,轴向气流混合腔110内的气流呈顺时针螺旋前进,且轴向顺流气的流量越大,轴向气流混合腔110内的顺时针气流的旋流强度越大;当轴向逆流气的流量较大而占主导时,轴向气流混合腔110内的气流呈逆时针螺旋前进,且轴向逆流气的流量越大,轴向气流混合腔110内的逆时针气流的旋流强度越大。当轴向逆流气流量与轴向顺流气的流量比在100%:0%至0%:100%间逐渐增大过程中,将使轴向气流混合段100内部的逆时针旋转气流旋流强度逐渐减小,逐渐转变为沿着轴向直流气流流动,而后产生顺时针的旋转气流,并且其旋流强度逐渐增大。通过调整顺流气与逆流气两股气流的流量比,可以对轴向气流混合腔110内气流的旋流方向和旋流强度进行连续性灵活调节,从而较为灵活的调节纳米粉体颗粒物合成过程。此外,该可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器在进行调节时,无需设置旋流叶片、外接执行器等较为复杂的结构,整体结构更加简单,制造成本与难度均更低。When the flow ratio of the air flow in the axial forward flow intake pipe 310 to the air flow in the axial counterflow intake pipe 320 changes between 100%:0% and 0%:100%, the axial airflow mixing chamber 110 The flow ratio of axial co-flow air and axial counter-flow air changes accordingly. When the flow rate of the axially downstream air is large and dominant, the airflow in the axial airflow mixing chamber 110 advances in a clockwise spiral, and the greater the flow rate of the axially downstream air, the more clockwise airflow in the axial airflow mixing chamber 110 The greater the swirl intensity; when the flow rate of the axial counterflow air is large and dominant, the airflow in the axial airflow mixing chamber 110 advances in a counterclockwise spiral, and the greater the flow rate of the axial counterflow air, the axial airflow mixing The swirl strength of the counterclockwise airflow in the chamber 110 is greater. When the flow ratio of the axial counter-flow air flow to the axial co-flow air flow gradually increases from 100%:0% to 0%:100%, the swirl intensity of the counterclockwise airflow inside the axial airflow mixing section 100 will be increased. Gradually decreases, and gradually transforms into a direct flow along the axial direction, and then generates a clockwise swirling airflow, and its swirl intensity gradually increases. By adjusting the flow ratio of the forward flow air and the counterflow air flow, the swirl direction and swirl intensity of the air flow in the axial flow mixing chamber 110 can be continuously and flexibly adjusted, thereby more flexibly adjusting the synthesis process of nanopowder particles. In addition, the flame synthesizing burner, which can realize the flexible adjustment of axial and tangential combined swirl flow, does not need to set more complicated structures such as swirl blades and external actuators when adjusting, the overall structure is simpler, and the manufacturing cost and difficulty are lower.

旋流风螺旋前进到达轴向气流混合段100的顶端,并朝外喷出。旋流风环绕旋流雾化器400外圈,经旋流雾化器400喷出的燃料将位于旋流风的内部。在高温点火热源的作用下,燃料(例如醇基液体燃料)将会发生燃烧放热,并使得溶解于燃料中的前驱物盐(硝酸盐或醋酸盐等盐类)发生热解,从而生成氧化物纳米颗粒。在雾化前驱物的周围形成的旋流风一方面可以为燃料的持续燃烧补充氧量,一方面旋流风的内圈形成的低压区将会促进燃料燃烧时产生的高温烟气的回流,从而在旋流风的内圈也即燃料燃烧区域形成高温回流区,有助于保持燃料燃烧区域的高温状态,提高火焰温度,稳定燃烧火焰及高温区的分布,从而促进燃烧过程中所形成的纳米氧化物颗粒的成核、聚并和烧结长大过程,使纳米粉体颗粒物的合成产量与质量有所提高。The swirling wind spirally advances to the top of the axial airflow mixing section 100, and is ejected outward. The swirl wind surrounds the outer ring of the swirl atomizer 400, and the fuel sprayed by the swirl atomizer 400 will be located inside the swirl wind. Under the action of a high-temperature ignition heat source, the fuel (such as alcohol-based liquid fuel) will burn and release heat, which will cause the precursor salt (nitrate or acetate and other salts) dissolved in the fuel to undergo pyrolysis, thereby forming oxide nanoparticles. On the one hand, the swirling wind formed around the atomized precursor can supplement the oxygen for the continuous combustion of the fuel; The inner ring of the swirling wind, that is, the fuel combustion area, forms a high-temperature recirculation area, which helps to maintain the high-temperature state of the fuel combustion area, increase the flame temperature, stabilize the distribution of the combustion flame and the high-temperature area, and promote the formation of nano-oxides during the combustion process. The process of particle nucleation, coalescence and sintering growth improves the synthesis yield and quality of nano powder particles.

参阅图1至图3,以及图8,在一些实施例中,还包括切向气流混合段200,切向气流混合段200套设于轴向气流混合段100的开口端的外部,切向气流混合段200包括呈环状的切向气流混合腔210,切向气流混合段200上安装有与切向气流混合腔210连通的切向顺流进气管330与切向逆流进气管340,切向顺流进气管330的轴向、切向逆流进气管340的轴向均与切向气流混合段200的外周面相切,且切向顺流进气管330与切向气流混合腔210的连通位置、切向逆流进气管340与切向气流混合腔210的连通位置沿切向气流混合段200的轴向错开,经切向顺流进气管330流入切向气流混合腔210的空气螺旋前进形成环绕开口端的切向顺流气,经切向逆流进气管340流入切向气流混合腔210的空气螺旋前进形成环绕开口端的切向逆流气,切向顺流气与切向逆流气的旋向相反,且沿轴向气流混合段100的径向,切向顺流气与切向逆流气位于轴向顺流气与轴向逆流气的外侧,切向顺流进气管330内的空气流量与切向逆流进气管340内的空气流量的流量比在100%:0%至0%:100%之间变化。Referring to Figures 1 to 3, and Figure 8, in some embodiments, a tangential airflow mixing section 200 is also included, and the tangential airflow mixing section 200 is sleeved outside the opening end of the axial airflow mixing section 100, and the tangential airflow mixing section The section 200 includes a ring-shaped tangential airflow mixing chamber 210. A tangential forward flow air inlet pipe 330 and a tangential counterflow air inlet pipe 340 communicating with the tangential airflow mixing chamber 210 are installed on the tangential airflow mixing chamber 200. The axial direction of the airflow inlet pipe 330 and the axial direction of the tangential counterflow air inlet pipe 340 are all tangent to the outer peripheral surface of the tangential airflow mixing section 200, and the communication position, tangential The communication position between the counterflow air inlet pipe 340 and the tangential airflow mixing chamber 210 is staggered along the axial direction of the tangential airflow mixing section 200, and the air flowing into the tangential airflow mixing chamber 210 through the tangential forward flow air inlet pipe 330 spirals forward to form a circle around the opening end. Tangential downstream air, the air flowing into the tangential airflow mixing chamber 210 through the tangential reverse flow inlet pipe 340 spirals forward to form tangential countercurrent air around the opening end, the tangential downstream air and the tangential countercurrent air have the opposite rotation direction, and along the axial direction The radial direction of the airflow mixing section 100, the tangential forward flow air and the tangential reverse flow air are located outside the axial forward flow air and the axial reverse flow air, and the air flow rate in the tangential forward flow inlet pipe 330 is the same as that in the tangential reverse flow inlet pipe 340. The flow ratio of the air flow varies from 100%:0% to 0%:100%.

具体地,切向气流混合段200呈一端开口另一端封闭的空心圆柱状,且切向气流混合段200的内部中空。切向顺流进气管330与切向逆流进气管340安装于切向气流混合段200上靠近底端的位置。切向顺流进气管330与切向逆流进气管340可以呈空心圆柱状,也可以呈空心长方体等形状。当为空心长方体状时,其切向即为长方体的长度方向。切向顺流进气管330与切向气流混合腔210的连通位置、切向逆流进气管340与切向气流混合腔210的连通位置沿切向气流混合段200的轴向错开,以防止切向顺流气与切向逆流气相撞而无法按预期方向与速度流动。在附图所示实施例中,切向顺流进气管330位于切向逆流进气管340的上方,在其他实施例中,也可以将切向逆流进气管340设置于切向顺流进气管330的上方。空气经切向顺流进气管330与切向逆流进气管340流入切向气流混合腔210后,将形成两股螺旋状朝上前进的旋流风,其中一股为顺时针螺旋前进的切向顺流气,另一股为逆时针螺旋前进的切向逆流气。Specifically, the tangential airflow mixing section 200 is in the shape of a hollow cylinder with one end open and the other end closed, and the inside of the tangential airflow mixing section 200 is hollow. The tangential forward flow inlet pipe 330 and the tangential reverse flow inlet pipe 340 are installed on the tangential airflow mixing section 200 near the bottom. The tangential forward flow inlet pipe 330 and the tangential counterflow inlet pipe 340 may be in the shape of a hollow cylinder, or may be in the shape of a hollow cuboid or the like. When it is a hollow cuboid, its tangential direction is the length direction of the cuboid. The communication position of the tangential forward flow inlet pipe 330 and the tangential airflow mixing chamber 210, and the communication position of the tangential counterflow inlet pipe 340 and the tangential airflow mixing chamber 210 are staggered along the axial direction of the tangential airflow mixing section 200 to prevent tangential The co-current gas collides with the tangential counter-current gas and cannot flow in the expected direction and speed. In the embodiment shown in the drawings, the tangential forward flow inlet pipe 330 is located above the tangential reverse flow inlet pipe 340 , in other embodiments, the tangential reverse flow inlet pipe 340 can also be arranged on the tangential forward flow inlet pipe 330 above. After the air flows into the tangential airflow mixing chamber 210 through the tangential forward flow air inlet pipe 330 and the tangential counterflow air inlet pipe 340, two swirling air flows spirally upward, one of which is a tangential forward airflow spirally advancing clockwise. The other is a tangential countercurrent air that spirals forward in a counterclockwise direction.

当切向顺流进气管330内的空气流量与切向逆流进气管340内的空气流量的流量比在100%:0%至0%:100%之间变化时,切向气流混合腔210内切向顺流气与切向逆流气的流量占比随之发生变化。当切向顺流气的流量较大而占主导时,切向气流混合腔210内的气流呈顺时针螺旋前进,且切向顺流气的流量越大,切向气流混合腔210内的顺时针气流的旋流强度越大;当切向逆流气的流量较大而占主导时,切向气流混合腔210内的气流呈逆时针螺旋前进,且切向逆流气的流量越大,切向气流混合腔210内的逆时针气流的旋流强度越大。当切向逆流气流量与切向顺流气的流量比在100%:0%至0%:100%间逐渐增大过程中,将使切向气流混合段200内部的逆时针旋转气流旋流强度逐渐减小,逐渐转变为沿着轴向直流气流流动,而后产生顺时针的旋转气流,并且其旋流强度逐渐增大。通过调整顺流气与逆流气两股气流的流量比,可以对切向气流混合腔210内气流的旋流方向和旋流强度进行连续性灵活调节,从而较为灵活的调节纳米粉体颗粒物合成过程。切向旋流风环绕于从轴向气流混合腔110的顶端喷出的轴向旋流风的外侧,从而形成双层旋流风,对燃烧区的氧量分级补充,且更易于形成中心的低压区,从而有利于提高整体周向旋流风构建高温回流区的能力,提高雾化合成火焰的自维持燃烧能力,并提高火焰的稳定性。When the flow ratio of the air flow in the tangential forward flow inlet pipe 330 to the air flow in the tangential counterflow air inlet pipe 340 changes between 100%:0% to 0%:100%, the tangential airflow mixing chamber 210 The flow ratio of tangential co-flow gas and tangential counter-flow gas changes accordingly. When the flow rate of tangential downstream air is large and dominant, the airflow in the tangential airflow mixing chamber 210 advances in a clockwise spiral, and the larger the flow rate of tangential downstream air is, the clockwise airflow in the tangential airflow mixing chamber 210 The greater the swirl intensity; when the flow rate of the tangential counterflow air is larger and dominant, the airflow in the tangential airflow mixing chamber 210 advances in a counterclockwise spiral, and the greater the flow rate of the tangential counterflow air, the tangential airflow mixing The swirl strength of the counterclockwise airflow in the chamber 210 is greater. When the flow ratio of the tangential counter-flow air flow to the tangential co-flow air flow gradually increases between 100%:0% and 0%:100%, the swirl intensity of the counterclockwise airflow inside the tangential airflow mixing section 200 will be increased. Gradually decreases, and gradually transforms into a direct flow along the axial direction, and then generates a clockwise swirling airflow, and its swirl intensity gradually increases. By adjusting the flow ratio of the forward flow gas and the counterflow gas flow, the swirl direction and swirl intensity of the gas flow in the tangential flow mixing chamber 210 can be continuously and flexibly adjusted, thereby more flexibly adjusting the synthesis process of nanopowder particles. The tangential swirling wind surrounds the outer side of the axial swirling wind ejected from the top of the axial airflow mixing chamber 110, thereby forming a double-layer swirling wind, which supplements the oxygen in the combustion zone in stages, and is more likely to form a central low-pressure zone. Therefore, it is beneficial to improve the ability of the overall circumferential swirling air to build a high-temperature recirculation zone, improve the self-sustaining combustion ability of the atomized synthesis flame, and improve the stability of the flame.

参阅图3与图8,在一些实施例中,切向气流混合段200包括呈环状的侧板230以及与侧板230的端部连接的端板240,侧板230内部中空以形成切向气流混合腔210,端板240内部中空以形成与切向气流混合腔210连通的切向气流出口环220,端板240上设有与切向气流出口环220连通的缺口241,切向顺流气与切向逆流气沿切向气流出口环220的周向流动并经缺口241流出可实现轴向、切向组合性旋流灵活调节的火焰合成燃烧器。具体地,切向顺流进气管330、切向逆流进气管340均安装于侧板230的外周面。端板240连接于侧板230的顶端,端板240的中心位置设有沿自身轴向贯通的缺口241,以使得端板240的内腔呈环形,以形成切向气流出口环220。流入切向气流混合腔210的切向顺流气与切向逆流气混合后,将形成以流量占比更高的气流为主导的切向旋流风。切向旋流风自切向气流混合腔210流入切向气流出口环220,并从切向气流出口环220的内圈处的缺口241处朝外喷出。当切向旋流风在切向气流出口环220内流动时,将会环绕于从轴向气流混合段100顶端喷出的轴向旋流风的外侧,从而构建双层旋流风。3 and 8, in some embodiments, the tangential airflow mixing section 200 includes an annular side plate 230 and an end plate 240 connected to the end of the side plate 230, the side plate 230 is hollow inside to form a tangential The airflow mixing chamber 210, the end plate 240 is hollow inside to form a tangential airflow outlet ring 220 communicating with the tangential airflow mixing chamber 210, the end plate 240 is provided with a gap 241 communicating with the tangential airflow outlet ring 220, and the tangential airflow The tangential counterflow gas flows along the circumferential direction of the tangential gas flow outlet ring 220 and flows out through the gap 241, which can realize the flexible adjustment of axial and tangential combined swirl flow. Specifically, both the tangential forward flow air intake pipe 330 and the tangential reverse flow air intake pipe 340 are installed on the outer peripheral surface of the side plate 230 . The end plate 240 is connected to the top of the side plate 230 , and the center of the end plate 240 is provided with a notch 241 axially penetrating through itself, so that the inner cavity of the end plate 240 is annular to form a tangential airflow outlet ring 220 . After the tangential forward flow air flowing into the tangential air flow mixing chamber 210 is mixed with the tangential counter flow air, a tangential swirling air flow dominated by the air flow with a higher flow rate will be formed. The tangential swirling air flows into the tangential airflow outlet ring 220 from the tangential airflow mixing chamber 210 , and is sprayed out from the gap 241 at the inner circle of the tangential airflow outlet ring 220 . When the tangential swirling air flows in the tangential airflow outlet ring 220 , it will surround the outside of the axial swirling air ejected from the top of the axial airflow mixing section 100 , thereby forming a double-layer swirling air.

参阅图3与图8,在一些实施例中,还包括呈环状且两端开口的气流分隔段500,侧板230与端板240限定出第一安装腔,气流分隔段500安装于第一安装腔的腔壁,气流分隔段500包括第二安装腔510,开口端伸入第二安装腔510,经开口端喷出的气流与燃料穿过缺口241朝外喷出。具体地,侧板230与端板240的内侧形成柱状的第一安装腔,气流分隔段500的外侧壁贴合于侧板230的内侧壁,气流分隔段500的端壁贴合于端板240的内壁。气流分隔段500的顶端与底端均呈开口状,内部中空以形成第二安装腔510。轴向气流混合段100的顶端从下朝上伸入第二安装腔510内,轴向气流混合段100的外侧壁贴合于气流分隔段500的内侧壁。气流分隔段500可以通过卡接、螺纹紧固件连接等方式固定于轴向气流混合段100与切向气流混合段200之间。通过设置在轴向气流混合段100与切向气流混合段200之间设置气流分隔段500,可以增大内外两层旋流风的径向间距,尽量将内外两层旋流风隔开,使两层旋流风不易混在一起相互干扰。Referring to FIG. 3 and FIG. 8 , in some embodiments, it also includes an annular airflow partition section 500 with openings at both ends, the side plate 230 and the end plate 240 define a first installation cavity, and the airflow partition section 500 is installed in the first The cavity wall of the installation cavity, the air flow partition section 500 includes a second installation cavity 510 , the opening end extends into the second installation cavity 510 , and the air flow and fuel ejected through the opening end are ejected outward through the gap 241 . Specifically, the side plate 230 and the inner side of the end plate 240 form a columnar first installation cavity, the outer wall of the air flow partition section 500 is attached to the inner wall of the side plate 230, and the end wall of the air flow partition section 500 is attached to the end plate 240 the inner wall. Both the top end and the bottom end of the air separation section 500 are open, and the inside is hollow to form a second installation cavity 510 . The top end of the axial airflow mixing section 100 protrudes into the second installation cavity 510 from bottom to top, and the outer sidewall of the axial airflow mixing section 100 is attached to the inner sidewall of the airflow partition section 500 . The airflow separation section 500 can be fixed between the axial airflow mixing section 100 and the tangential airflow mixing section 200 by clamping, threaded fastener connection and the like. By being arranged between the axial airflow mixing section 100 and the tangential airflow mixing section 200, the airflow separation section 500 can increase the radial distance between the inner and outer two-layer swirl wind, and separate the inner and outer two-layer swirl wind as far as possible, so that the two layers The swirling winds are not easy to mix together and interfere with each other.

参阅图3、图8与图9,在一些实施例中,沿轴向气流混合段100的轴向,气流分隔段500的外端与轴向气流混合段100的外端之间存在高度差。具体地,气流分隔段500的顶端与轴向气流混合段100的顶端之间存在高度差H1。燃料从旋流雾化器400的顶端朝上喷出后被点燃形成火焰,在该高度差范围内,从轴向气流混合段100的顶端朝上喷出的轴向旋流风可以稳定的环绕于火焰外圈,待到达缺口241处,切向旋流风再加入,形成两层旋流风,以免两层旋流风相互之间相互干扰而无法按照预期速度与流向流动。优选地,在一些实施例中,0.2H≤H1≤0.6H,其中H为切向气流混合段200的轴向长度,满足该数值范围时,可以尽量保证装置具有较小的轴向尺寸,同时使从轴向气流混合段100的顶端朝上喷出的轴向旋流风可以稳定的环绕于火焰外圈。Referring to FIG. 3 , FIG. 8 and FIG. 9 , in some embodiments, along the axial direction of the axial airflow mixing section 100 , there is a height difference between the outer end of the airflow dividing section 500 and the outer end of the axial airflow mixing section 100 . Specifically, there is a height difference H 1 between the top end of the airflow separation section 500 and the top end of the axial airflow mixing section 100 . After the fuel is sprayed upward from the top of the swirl atomizer 400, it is ignited to form a flame. Within the height difference range, the axial swirl air sprayed upward from the top of the axial air flow mixing section 100 can stably surround the When the flame outer circle reaches the gap 241, the tangential swirl wind is added to form two layers of swirl wind, so as to prevent the two layers of swirl wind from interfering with each other and unable to flow according to the expected speed and flow direction. Preferably, in some embodiments, 0.2H≤H 1 ≤0.6H, where H is the axial length of the tangential airflow mixing section 200, and when this value range is met, the device can be guaranteed to have a smaller axial dimension, At the same time, the axial swirling air jetted upward from the top of the axial air flow mixing section 100 can stably surround the outer circle of the flame.

参阅图2与图4、图6与图7,在一些实施例中,沿轴向气流混合段100的径向,轴向顺流进气管310与轴向气流混合腔110的连通位置、轴向逆流进气管320与轴向气流混合腔110的连通位置分别位于轴向气流混合段100的两端;以及/或者,Referring to FIG. 2 and FIG. 4 , FIG. 6 and FIG. 7 , in some embodiments, along the radial direction of the axial airflow mixing section 100 , the communication position of the axial downstream air intake pipe 310 and the axial airflow mixing chamber 110 The communication positions between the reverse flow inlet pipe 320 and the axial airflow mixing chamber 110 are respectively located at both ends of the axial airflow mixing section 100; and/or,

沿切向气流混合段200的径向,切向顺流进气管330与切向气流混合腔210的连通位置、切向逆流进气管340与切向气流混合腔210的连通位置分别位于切向气流混合段200的两端。Along the radial direction of the tangential airflow mixing section 200, the communication position between the tangential forward flow inlet pipe 330 and the tangential airflow mixing chamber 210, and the communication position between the tangential counterflow air inlet pipe 340 and the tangential airflow mixing chamber 210 are respectively located in the tangential airflow mixing chamber 210. both ends of the mixing section 200.

具体地,轴向顺流进气管310位于轴向逆流进气管320的正对一侧。轴向顺流进气管310与轴向气流混合腔110的连通位置位于图4视角下的下端,轴向逆流进气管320与轴向气流混合腔110的连通位置位于图4视角下的上端。将两个连通位置分别设置于沿径向的两端时,两个连通位置之间的间距最大,各自流入的气流不易相互干扰。类似地,在图2视角下,切向顺流进气管330位于切向逆流进气管340的正对一侧。切向顺流进气管330与切向气流混合腔210的连通位置位于下端,切向逆流进气管340与切向气流混合腔210的连通位置位于上端。当然,除了图示位置,也可以是其他位置,例如分别位于左端和右端。Specifically, the axial forward flow intake pipe 310 is located on the side opposite to the axial reverse flow intake pipe 320 . The communication position between the axial forward flow inlet pipe 310 and the axial airflow mixing chamber 110 is located at the lower end from the perspective of FIG. When the two communication positions are respectively arranged at two ends along the radial direction, the distance between the two communication positions is the largest, and the respective inflowing airflows are less likely to interfere with each other. Similarly, from the perspective of FIG. 2 , the tangential forward flow intake pipe 330 is located on the opposite side of the tangential reverse flow intake pipe 340 . The communication position between the tangential forward flow inlet pipe 330 and the tangential airflow mixing chamber 210 is located at the lower end, and the communication position between the tangential counterflow air inlet pipe 340 and the tangential airflow mixing chamber 210 is located at the upper end. Of course, in addition to the illustrated positions, other positions are also possible, for example, respectively located at the left end and the right end.

参阅图2、图3、图5与图8,在一些实施例中,还包括镂空旋流盘600,镂空旋流盘600安装于开口端,旋流雾化器400穿过镂空旋流盘600的中心孔620朝外伸出,旋流雾化器400上设有多个沿自身周向间隔排布的通孔610,沿镂空旋流盘600的径向,通孔610位于中心孔620的外侧,轴向顺流气与轴向逆流气经通孔610喷出。具体地,镂空旋流盘600安装于轴向气流混合段100的顶端开口处,且其外径与轴向气流混合段100的内径相等,镂空旋流盘600将轴向气流混合段100的顶端开口封堵,镂空旋流盘600外侧壁抵持于轴向气流混合腔110的腔体侧壁以实现对镂空旋流盘600的径向限位。镂空旋流盘600的中心位置设置有沿自身轴向贯通的中心孔620,旋流雾化器400自下朝上经中心孔620朝外伸出。多个通孔610环绕于中心孔620设置,且多个通孔均匀间隔排布。到达轴向气流混合段100顶端的轴向旋流风可以经各个通孔610朝上喷出。附图所示实施例中,通孔610呈扇形,沿旋流雾化器400的径向且朝外的方向上,通孔610的周向尺寸逐渐增大。当然,在另一些实施例中,通孔610也可以设置为其他形状,例如圆形、椭圆形、长方形等。由于通孔610处无遮挡部件,可以使轴向旋流气顺利流通,减少对旋转气流的阻挡。Referring to Fig. 2, Fig. 3, Fig. 5 and Fig. 8, in some embodiments, a hollow swirl disk 600 is also included, the hollow swirl disk 600 is installed at the open end, and the swirl atomizer 400 passes through the hollow swirl disk 600 The central hole 620 protrudes outward, and the swirl atomizer 400 is provided with a plurality of through holes 610 arranged at intervals along its circumferential direction. Along the radial direction of the hollow swirl disk 600, the through holes 610 are located On the outside, the axial co-current air and the axial counter-current air are ejected through the through hole 610 . Specifically, the hollow swirl disk 600 is installed at the top opening of the axial airflow mixing section 100, and its outer diameter is equal to the inner diameter of the axial airflow mixing section 100. The opening is blocked, and the outer wall of the hollowed out swirl disk 600 bears against the sidewall of the axial airflow mixing chamber 110 to realize the radial limit of the hollowed out swirl disk 600 . A center hole 620 is provided at the center of the hollow swirl disk 600 along its axial direction, and the swirl atomizer 400 protrudes outward through the center hole 620 from bottom to top. A plurality of through holes 610 are disposed around the central hole 620 , and the plurality of through holes are evenly spaced. The axial swirling air reaching the top of the axial air mixing section 100 can be ejected upward through each through hole 610 . In the embodiment shown in the drawings, the through hole 610 is fan-shaped, and the circumferential dimension of the through hole 610 gradually increases along the radial and outward direction of the swirl atomizer 400 . Certainly, in some other embodiments, the through hole 610 may also be set in other shapes, such as circular, elliptical, rectangular and so on. Since there is no shielding part at the through hole 610, the axial swirling air can be smoothly circulated and the obstruction to the swirling air flow can be reduced.

参阅图3与图8,在一些实施例中,旋流雾化器400包括雾化喷嘴410与主体部420,轴向气流混合段100包括位于开口端的对侧的封闭端,主体部420穿过封闭端伸入轴向气流混合腔110并插入中心孔620,且主体部420固定连接于封闭端,雾化喷嘴410抵持于镂空旋流盘600上背离轴向气流混合腔110的一侧,雾化喷嘴410与主体部420固定连接,燃料能够经主体部420流入,并经雾化喷嘴410喷出。具体地,轴向气流混合段100的封闭端的中心位置设置有安装孔,主体部420呈杆状,自下朝上穿过该安装孔,并固定于封闭端。具体地,可以在主体部420露出于轴向气流混合段100以外的部分的外周面设置外螺纹,螺母旋紧于外螺纹直至螺母抵持于轴向气流混合段100的封闭端的外端面,从而将主体部420固定安装于轴向气流混合段100的封闭端。当然,在其他实施例中,也可以通过卡接等方式实现固定安装。主体部420的顶端穿过中心孔620,并与位于镂空旋流盘600的上方的雾化喷嘴410固定连接,例如,可以通过螺钉实现固定,或者,也可以通过卡接固定。燃料流经主体部420的内部,朝上流动而流入雾化喷嘴410,并经雾化喷嘴410朝上喷出。3 and 8, in some embodiments, the swirl atomizer 400 includes an atomizing nozzle 410 and a main body 420, the axial flow mixing section 100 includes a closed end opposite to the open end, and the main body 420 passes through The closed end extends into the axial air mixing chamber 110 and is inserted into the central hole 620, and the main body 420 is fixedly connected to the closed end, and the atomizing nozzle 410 is held against the side of the hollow swirl disk 600 facing away from the axial air mixing chamber 110, The atomizing nozzle 410 is fixedly connected with the main body 420 , fuel can flow in through the main body 420 and be sprayed out through the atomizing nozzle 410 . Specifically, an installation hole is provided at the center of the closed end of the axial airflow mixing section 100 , and the main body 420 is rod-shaped, passes through the installation hole from bottom to top, and is fixed on the closed end. Specifically, an external thread can be provided on the outer peripheral surface of the part of the main body 420 exposed outside the axial air flow mixing section 100, and the nut is screwed on the external thread until the nut is against the outer end surface of the closed end of the axial air flow mixing section 100, thereby The main body part 420 is fixedly mounted on the closed end of the axial flow mixing section 100 . Certainly, in other embodiments, the fixed installation may also be implemented by clamping or the like. The top end of the main body part 420 passes through the central hole 620 and is fixedly connected with the atomizing nozzle 410 located above the hollow swirl disk 600 , for example, can be fixed by screws, or can also be fixed by clamping. The fuel flows through the inside of the main body part 420 , flows upward, flows into the atomizing nozzle 410 , and is sprayed upward through the atomizing nozzle 410 .

参阅图1与图3,在一些实施例中,轴向顺流进气管310的轴向、轴向逆流进气管320的轴向均相对于轴向气流混合段100的端面倾斜,沿轴向顺流进气管310内的气流流向,轴向顺流进气管310与轴向气流混合段100的气流流出口的间距逐渐减小,沿轴向逆流进气管320内的气流流向,轴向逆流进气管320与气流流出口的间距逐渐减小。具体地,沿气流在轴向顺流进气管310内的流动方向,轴向顺流进气管310朝上倾斜。沿气流在轴向逆流进气管320内的流动方向,轴向逆流进气管320朝上倾斜。如此设置可以使轴向顺流气与轴向逆流气在初始阶段即具有朝上的流动速度,从而更易于朝上流动。优选地,在一些实施例中,5°≤α≤20°,其中α为轴向顺流进气管310的轴向与轴向气流混合段100端面(也就是水平方向)的夹角,也为轴向逆流进气管320的轴向与轴向气流混合段100端面(也就是水平方向)的夹角。类似地,沿气流在切向顺流进气管330内的流动方向,切向顺流进气管330朝上倾斜。沿气流在切向逆流进气管340内的流动方向,切向逆流进气管340朝上倾斜。当然,在一些实施例中,也可以将轴向顺流进气管310、轴向逆流进气管320、切向顺流进气管330、切向逆流进气管340均设置为水平。Referring to FIG. 1 and FIG. 3 , in some embodiments, the axial direction of the axial forward flow inlet pipe 310 and the axial direction of the axial counterflow inlet pipe 320 are both inclined relative to the end surface of the axial airflow mixing section 100 , The air flow direction in the air inlet pipe 310 is axially forward, and the distance between the air flow outlet of the air inlet pipe 310 and the axial air flow mixing section 100 is gradually reduced, and the air flow direction in the air inlet pipe 320 is axially reversed, and the axial direction of the air flow in the air inlet pipe is reversed. The distance between 320 and the airflow outlet gradually decreases. Specifically, along the flow direction of the airflow in the axial downstream intake pipe 310 , the axial downstream intake pipe 310 is inclined upward. Along the flow direction of the airflow in the axial reverse flow intake pipe 320 , the axial reverse flow intake pipe 320 is inclined upward. Such setting can make the axial co-current air and the axial counter-current air have an upward flow velocity at the initial stage, so that it is easier to flow upward. Preferably, in some embodiments, 5°≤α≤20°, where α is the angle between the axial direction and the end surface (that is, the horizontal direction) of the axial flow mixing section 100 of the axial co-flow inlet pipe 310, and is also The included angle between the axial direction of the axial reverse flow inlet pipe 320 and the end surface (ie, the horizontal direction) of the axial airflow mixing section 100 . Similarly, along the flow direction of the airflow in the tangential co-flow intake duct 330 , the tangential co-flow intake duct 330 is inclined upward. Along the flow direction of the airflow in the tangential counterflow intake duct 340 , the tangential counterflow intake duct 340 is inclined upward. Of course, in some embodiments, the axial forward flow inlet pipe 310 , the axial reverse flow inlet pipe 320 , the tangential forward flow inlet pipe 330 , and the tangential reverse flow inlet pipe 340 can all be set horizontally.

参阅图,在一些实施例中,旋流雾化器400的内部设有沿轴向气流混合段100的轴向延伸的前驱物中心管421与外层剪切气管422,前驱物中心管421的出口与外层剪切气管422的出口均与雾化喷嘴410连通,外层剪切气管422套设于前驱物中心管421的外部,经雾化喷嘴410喷出的空气包裹于燃料的外部。具体地,外层剪切气管422与剪切气入口管720连通,前驱物中心管421与前驱物入口管710连通。前驱物入口管710与剪切气入口管720均穿过轴向气流混合段100的侧壁伸入轴向气流混合腔110内,并各自连接于主体部420上对应位置。空气经剪切气入口管720流入外层剪切气管422,并流入雾化喷嘴410。前驱物经前驱物入口管710流入前驱物中心管421,并流入雾化喷嘴410。在雾化喷嘴410内,前驱物被空气包裹而高速喷出。在喷出过程中,空气将会对前驱物进行剪切破碎,使前驱物发生雾化,液态的前驱物破碎成粒径更小的液滴,从而更易于燃烧充分。优选地,雾化喷嘴410呈空心锥形,其内腔的径向尺寸从下至上逐渐减小,燃料经前驱物中心管421流入雾化喷嘴410的锥形内腔,同时空气也经外层剪切气管422流入雾化喷嘴410的锥形内腔。通过限定雾化喷嘴410的内腔为锥形,可以使空气喷出时的角度能尽量朝向位于中心位置的燃料,从而加剧对液体燃料的剪切破碎,使其雾化效果更好。Referring to the figure, in some embodiments, the interior of the swirl atomizer 400 is provided with a precursor central tube 421 extending axially along the axial flow mixing section 100 and an outer layer shear gas tube 422. The precursor central tube 421 Both the outlet and the outlet of the outer layer shearing air pipe 422 are in communication with the atomizing nozzle 410, the outer layer shearing air pipe 422 is sleeved outside the precursor central pipe 421, and the air ejected from the atomizing nozzle 410 is wrapped around the outside of the fuel. Specifically, the outer shear gas pipe 422 communicates with the shear gas inlet pipe 720 , and the precursor central pipe 421 communicates with the precursor inlet pipe 710 . Both the precursor inlet pipe 710 and the shear gas inlet pipe 720 extend into the axial flow mixing chamber 110 through the sidewall of the axial flow mixing section 100 , and are respectively connected to corresponding positions on the main body 420 . The air flows into the outer shear gas pipe 422 through the shear gas inlet pipe 720 , and then flows into the atomizing nozzle 410 . The precursor flows into the precursor central pipe 421 through the precursor inlet pipe 710 , and flows into the atomizing nozzle 410 . In the atomizing nozzle 410, the precursor is surrounded by air and ejected at high speed. During the ejection process, the air will shear and break the precursor to atomize the precursor, and the liquid precursor is broken into smaller droplets, which are easier to burn fully. Preferably, the atomizing nozzle 410 is in the shape of a hollow cone, and the radial dimension of the inner cavity gradually decreases from bottom to top. The fuel flows into the conical inner cavity of the atomizing nozzle 410 through the precursor central tube 421, and the air also passes through the outer layer The shear air tube 422 flows into the conical inner cavity of the atomizing nozzle 410 . By limiting the inner cavity of the atomizing nozzle 410 to be conical, the angle of air spraying can be directed toward the fuel at the center as much as possible, thereby intensifying the shearing and breaking of the liquid fuel and making the atomization effect better.

参阅图3、图8与图9,在一些实施例中,5°≤α≤20°;1.5d≤h≤3d;1.1d≤D2≤1.5d;1.1D2≤D1≤1.2D2;0.5D2≤H≤0.9D2;0.2H≤H1≤0.6H。其中,α为轴向顺流进气管310的轴向与轴向气流混合段100端面的夹角,也为轴向逆流进气管320的轴向与轴向气流混合段100端面的夹角。H1为端板240与轴向气流混合段100的顶端之间存在的高度差,H为切向气流混合段200的轴向长度。d为轴向气流混合段100的内径,h为轴向气流混合段100内轴向气流混合腔110的轴向长度。D1为切向气流混合段200的内径,D2为气流分隔段500的外径。当满足上述数值范围时,燃烧器能够实现较优的合成效果,有利于纳米氧化物颗粒的成核、聚并和烧结长大过程。Referring to FIG. 3 , FIG. 8 and FIG. 9 , in some embodiments, 5°≤α≤20°; 1.5d≤h≤3d; 1.1d≤D 2 ≤1.5d; 1.1D 2 ≤D 1 ≤1.2D 2 ; 0.5D 2 ≤ H ≤ 0.9D 2 ; 0.2H ≤ H 1 ≤ 0.6H. Wherein, α is the angle between the axial direction of the axial forward flow inlet pipe 310 and the end surface of the axial airflow mixing section 100 , and is also the angle between the axial direction and the end surface of the axial airflow mixing section 100 of the axial counterflow inlet pipe 320 . H 1 is the height difference between the end plate 240 and the top end of the axial airflow mixing section 100 , and H is the axial length of the tangential airflow mixing section 200 . d is the inner diameter of the axial air flow mixing section 100 , and h is the axial length of the axial air flow mixing chamber 110 in the axial air flow mixing section 100 . D 1 is the inner diameter of the tangential airflow mixing section 200 , and D2 is the outer diameter of the airflow separation section 500 . When the above numerical range is satisfied, the burner can achieve a better synthesis effect, which is beneficial to the nucleation, coalescence and sintering growth process of nano-oxide particles.

参阅图3与图8,本发明的液体燃料自维持燃烧火焰合成燃烧器在燃烧过程中主要有4股气流和液流参与火焰合成纳米粉体颗粒物的过程,具体包括:轴向旋流风、切向旋流风、前驱物、剪切气。其中,轴向旋流风同时由轴向逆流气和轴向顺流气两股气流耦合组成,切向旋流风同时由切向逆流气和切向顺流气两股气流耦合组成,具体为:Referring to Fig. 3 and Fig. 8, the liquid fuel self-sustaining combustion flame synthesis burner of the present invention mainly has 4 streams of air flow and liquid flow to participate in the process of flame synthesis of nano-powder particles in the combustion process, specifically including: axial swirling wind, cutting Swirl wind, precursor, shear gas. Among them, the axial swirl wind is composed of two airflow couplings of axial counterflow air and axial downflow air, and the tangential swirl wind is composed of two airflow couplings of tangential counterflow air and tangential downflow air at the same time, specifically:

轴向旋流风,包括轴向逆流气由轴向逆流进气管320喷入,同时,轴向顺流气由轴向顺流进气管310喷入,而后两股气流共同沿着不同的高度和位置高速喷入到轴向气流混合段100的内部,由于二者之间产生的旋转气流方向不同,当轴向顺流气的入射动量大于轴向逆流气的入射动量时,轴向顺流气在轴向气流混合段100的顺时针旋转将占据主导作用,并在轴向气流混合段100的上端产生顺时针旋流气流流动,而当轴向顺流气的入射动量小于轴向逆流气的入射动量时,此时,轴向逆流气在轴向气流混合段100的逆时针旋转将占据主导作用,并在轴向气流混合段100的上端产生逆时针旋流气流流动。在这个过程中,当轴向逆流气流量与轴向顺流气的流量比在100%:0%至0%:100%间逐渐增大过程中,将使轴向气流混合段100内部的逆时针旋转气流旋流强度逐渐减小,逐渐转变为沿着轴向直流气流流动,而后产生顺时针的旋转气流,并且其旋流强度逐渐增大。而后具有一定旋流强度的气流由位于上部的通孔610喷出。Axial swirling air, including axial counterflow air, is injected through the axial counterflow inlet pipe 320, while axial downflow air is injected through the axial downflow inlet pipe 310, and then the two airflows jointly travel along different heights and positions at high speeds. It is sprayed into the axial airflow mixing section 100. Since the direction of the rotating airflow generated between the two is different, when the incident momentum of the axially forward flow air is greater than that of the axially counterflow air, the axially forward flow air will The clockwise rotation of the mixing section 100 will play a dominant role, and generate a clockwise swirling airflow at the upper end of the axial airflow mixing section 100, and when the incident momentum of the axially forward flow air is smaller than the incident momentum of the axially counterflow air, this , the counterclockwise rotation of the axial counterflow air in the axial airflow mixing section 100 will play a dominant role, and a counterclockwise swirling airflow will be generated at the upper end of the axial airflow mixing section 100 . In this process, when the flow ratio of the axial counter-flow air flow and the axial co-flow air flow gradually increases from 100%:0% to 0%:100%, the counterclockwise flow inside the axial air flow mixing section 100 will be made The swirl intensity of the swirling airflow decreases gradually, and gradually transforms into a direct flow along the axial direction, and then generates a clockwise swirling airflow, and its swirl intensity gradually increases. Then the airflow with a certain swirl intensity is ejected from the upper through hole 610 .

切向旋流风,包括切向逆流气由切向逆流进气管340喷入,同时,切向顺流气由切向顺流进气管330喷入,而后两股气流共同沿着不同的高度和位置高速喷入到切向气流混合段200的内部,由于二者之间产生的旋转气流方向不同,当切向顺流气的入射动量大于切向逆流气的入射动量时,切向顺流气在切向气流混合段200内部的顺时针旋转将占据主导作用,并在切向气流混合段200的上端产生顺时针旋流气流流动,而当切向顺流气的入射动量小于切向逆流气的入射动量时,此时,切向逆流气在切向气流混合段200内部的逆时针旋转将占据主导作用,并在切向气流混合段200的上端产生逆时针旋流气流流动。在这个过程中,当切向逆流气流量与切向顺流气的流量比在100%:0%至0%:100%间逐渐增大过程中,将使切向气流混合段200内部的逆时针旋转气流旋流强度逐渐减小,逐渐转变为沿着轴向直流气流流动,而后产生顺时针的旋转气流,并且其旋流强度逐渐增大。而后具有一定旋流强度的切向气流由切向气流出口环220的内侧出口高速喷出。The tangential swirling wind, including the tangential counter-flow air, is injected through the tangential counter-flow air intake pipe 340, while the tangential downstream air is injected through the tangential downstream air intake pipe 330. It is sprayed into the inside of the tangential airflow mixing section 200. Since the direction of the swirling airflow generated between the two is different, when the incident momentum of the tangential forward flow air is greater than that of the tangential counterflow air, the tangential forward flow air will The clockwise rotation inside the mixing section 200 will play a dominant role, and generate a clockwise swirling airflow flow at the upper end of the tangential airflow mixing section 200, and when the incident momentum of the tangential forward flow air is smaller than the incident momentum of the tangential counterflow air, At this time, the counterclockwise rotation of the tangential counterflow gas inside the tangential airflow mixing section 200 will play a dominant role, and a counterclockwise swirling airflow will be generated at the upper end of the tangential airflow mixing section 200 . In this process, when the flow ratio of the tangential counter-flow air flow to the tangential co-flow air flow gradually increases from 100%:0% to 0%:100%, the counterclockwise movement inside the tangential air flow mixing section 200 will be made The swirl intensity of the swirling airflow decreases gradually, and gradually transforms into a direct flow along the axial direction, and then generates a clockwise swirling airflow, and its swirl intensity gradually increases. Then the tangential airflow with a certain swirl intensity is ejected at high speed from the inner outlet of the tangential airflow outlet ring 220 .

前驱物,主要为液体燃料(例如醇基液体燃料)和前驱物盐(硝酸盐或醋酸盐等盐类)的混合液,在外接增压泵的作用下,经由前驱物入口管710进入前驱物中心管421,并由雾化喷嘴410喷出。The precursor is mainly a mixture of liquid fuel (such as alcohol-based liquid fuel) and precursor salt (salts such as nitrate or acetate), and enters the precursor through the precursor inlet pipe 710 under the action of an external booster pump. The center tube 421 of the object is sprayed out by the atomizing nozzle 410.

剪切气,主要为空气流,在外接增压风机的作用下,经由剪切气入口管720进入外层剪切气管422,并由雾化喷嘴410高速喷出。The shearing gas, mainly air flow, enters the outer layer shearing air pipe 422 through the shearing gas inlet pipe 720 under the action of an external booster fan, and is ejected from the atomizing nozzle 410 at high speed.

首先,相比于常规在雾化前驱物的周围布置值班火焰的技术方案(通常使用CH4或天然气燃烧构建值班火焰),本发明通过结构及配风设计,可在完全依靠雾化液体燃料的自身燃烧放热及合理耦合周围环形旋流风的燃烧组织方式下,实现旋流火焰合成燃烧器的自维持燃烧;First of all, compared with the conventional technical scheme of arranging duty flames around atomized precursors (usually using CH4 or natural gas to burn to build duty flames), the present invention can be used in the environment completely relying on atomized liquid fuels through structure and air distribution design. The self-sustaining combustion of the swirl flame synthesis burner is realized under the combustion organization mode of self-combustion heat release and reasonable coupling with the surrounding annular swirl wind;

其次,在中心雾化前驱物的周向,由内至外,依次布置了轴向旋流风和切向旋流风,且轴向旋流风与切向旋流风中间间隔有气流分隔段,确保对高温火焰场的轴向分布及径向分布尺寸及位置的灵活调节,达到对纳米粉体颗粒物成核、聚并及烧结过程的快速有效调节,实现有效控制合成纳米颗粒物的粒径、形态和晶相;Secondly, in the circumferential direction of the central atomized precursor, from the inside to the outside, the axial swirl wind and the tangential swirl wind are arranged in sequence, and there is an air separation section between the axial swirl wind and the tangential swirl wind to ensure the high temperature The axial distribution of the flame field and the flexible adjustment of the size and position of the radial distribution can achieve rapid and effective adjustment of the nucleation, coalescence and sintering process of nano-powder particles, and realize effective control of the particle size, shape and crystal phase of the synthesized nanoparticles ;

再次,本发明中所构建的轴向旋流风和切向旋流风,均可通过调整顺流气与逆流气两股气流间的风量比来对气流的旋流方向和旋流强度进行连续性在线灵活调节,增加了对纳米粉体颗粒物合成过程的灵活调节措施;Again, both the axial swirl wind and the tangential swirl wind constructed in the present invention can continuously and flexibly adjust the swirl direction and swirl intensity of the airflow by adjusting the air volume ratio between the forward flow air and the counterflow air flow. Adjustment, adding flexible adjustment measures to the synthesis process of nano-powder particles;

再次,本发明所述的雾化火焰合成燃烧器结构简单,便于设计加工、制造成本低,有利于提高单只雾化火焰合成燃烧器的粉体材料合成产量,促进雾化旋流火焰合成技术的规模化推广应用。Again, the atomized flame synthesis burner of the present invention has a simple structure, is convenient for design and processing, and has low manufacturing cost, which is conducive to improving the powder material synthesis output of a single atomization flame synthesis burner and promoting the atomization swirl flame synthesis technology. large-scale promotion and application.

以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述,然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。The technical features of the above-mentioned embodiments can be combined arbitrarily. To make the description concise, all possible combinations of the technical features in the above-mentioned embodiments are not described. However, as long as there is no contradiction in the combination of these technical features, should be considered as within the scope of this specification.

以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only express several implementation modes of the present invention, and the descriptions thereof are relatively specific and detailed, but should not be construed as limiting the patent scope of the invention. It should be noted that, for those skilled in the art, several modifications and improvements can be made without departing from the concept of the present invention, and these all belong to the protection scope of the present invention. Therefore, the protection scope of the patent for the present invention should be based on the appended claims.

Claims (10)

1. The utility model provides a can realize the nimble flame synthesis combustor who adjusts of axial, tangential combination nature whirl which characterized in that includes:
the axial air flow mixing section is internally provided with an axial air flow mixing cavity, a rotational flow atomizer is arranged in the axial air flow mixing cavity, fuel mixed with precursor salt can be atomized by the rotational flow atomizer and sprayed out, an axial downstream air inlet pipe communicated with the axial air flow mixing cavity and an axial countercurrent air inlet pipe are arranged on the axial air flow mixing section, the axial direction of the axial downstream air inlet pipe and the axial direction of the axial countercurrent air inlet pipe are tangential to the peripheral surface of the axial air flow mixing section, the communication position of the axial downstream air inlet pipe and the axial air flow mixing cavity, the communication position of the axial countercurrent air inlet pipe and the axial air flow mixing cavity are staggered along the axial direction of the axial air flow mixing section, air flowing into the axial air flow mixing cavity through the axial downstream air inlet pipe forms axial downstream air which spirally advances around the rotational flow atomizer, air flowing into the axial air mixing cavity through the axial countercurrent air inlet pipe forms axial countercurrent air which spirally advances around the atomizer, and the air flow of the axial downstream air inlet pipe and the axial countercurrent air inlet pipe is opposite to the rotational flow of the axial air inlet pipe, and the air flow of the axial countercurrent air inlet pipe is in the ratio of 100%:0% to 0%: variation between 100%.
2. The flame synthesis burner capable of realizing flexible adjustment of axial and tangential combined rotational flow according to claim 1, further comprising a tangential air flow mixing section, wherein the tangential air flow mixing section is sleeved outside the opening end of the axial air flow mixing section, the tangential air flow mixing section comprises a circular tangential air flow mixing cavity, a tangential forward air inlet pipe and a tangential reverse air inlet pipe which are communicated with the tangential air flow mixing cavity are arranged on the tangential air flow mixing section, the axial direction of the tangential forward air inlet pipe and the axial direction of the tangential reverse air inlet pipe are tangential to the outer circumferential surface of the tangential air flow mixing section, the communication position of the tangential forward air inlet pipe and the tangential air flow mixing cavity and the communication position of the tangential reverse air inlet pipe and the tangential air flow mixing cavity are staggered along the axial direction of the tangential air flow mixing section, the air flowing into the tangential airflow mixing cavity through the tangential downstream air inlet pipe spirally advances to form tangential downstream air surrounding the opening end, the air flowing into the tangential airflow mixing cavity through the tangential upstream air inlet pipe spirally advances to form tangential upstream air surrounding the opening end, the tangential downstream air and the tangential upstream air are opposite in rotation direction, and are positioned on the outer sides of the axial downstream air and the axial upstream air along the radial direction of the axial airflow mixing section, and the flow ratio of the air flow in the tangential downstream air inlet pipe to the air flow in the tangential upstream air inlet pipe is 100%:0% to 0%: variation between 100%.
3. The flame synthesis burner capable of realizing axial and tangential combined rotational flow flexible adjustment according to claim 2, wherein the tangential airflow mixing section comprises a ring-shaped side plate and an end plate connected with the end part of the side plate, the side plate is hollow inside to form the tangential airflow mixing cavity, the end plate is hollow inside to form a tangential airflow outlet ring communicated with the tangential airflow mixing cavity, a notch communicated with the tangential airflow outlet ring is arranged on the end plate, and the tangential forward airflow and the tangential reverse airflow flow along the circumferential direction of the tangential airflow outlet ring and flow out of the flame synthesis burner capable of realizing axial and tangential combined rotational flow flexible adjustment through the notch.
4. The flame synthesis burner capable of realizing flexible adjustment of axial and tangential combined rotational flow according to claim 3, further comprising an annular airflow separation section with two open ends, wherein the side plate and the end plate define a first installation cavity, the airflow separation section is installed on the cavity wall of the first installation cavity, the airflow separation section comprises a second installation cavity, the open end extends into the second installation cavity, and the airflow ejected through the open end and the fuel are ejected outwards through the notch.
5. The flame synthesizing burner capable of realizing flexible adjustment of axial and tangential combined swirl according to claim 4, wherein a height difference exists between an outer end of the air flow separation section and an outer end of the axial air flow mixing section along an axial direction of the axial air flow mixing section.
6. The flame synthesis burner capable of realizing flexible adjustment of axial and tangential combined rotational flow according to claim 2, wherein the communication position of the axial forward flow air inlet pipe and the axial air flow mixing cavity and the communication position of the axial reverse flow air inlet pipe and the axial air flow mixing cavity are respectively positioned at two ends of the axial air flow mixing section along the radial direction of the axial air flow mixing section; and/or the number of the groups of groups,
along the radial direction of the tangential airflow mixing section, the communication position of the tangential downstream air inlet pipe and the tangential airflow mixing cavity and the communication position of the tangential upstream air inlet pipe and the tangential airflow mixing cavity are respectively positioned at two ends of the tangential airflow mixing section.
7. The flame synthesis burner capable of realizing flexible adjustment of axial and tangential combined swirling flow according to any one of claims 2 to 6, further comprising a hollow swirling flow disk, wherein the hollow swirling flow disk is mounted at the opening end, the swirling flow atomizer penetrates through a central hole of the hollow swirling flow disk and extends outwards, a plurality of through holes are arranged on the swirling flow atomizer at intervals along the circumferential direction of the swirling flow atomizer, the through holes are positioned at the outer side of the central hole along the radial direction of the hollow swirling flow disk, and the axial concurrent air and the axial countercurrent air are sprayed out through the through holes.
8. The flame synthesis burner capable of realizing flexible adjustment of axial and tangential combined swirl according to claim 7, wherein the swirl atomizer comprises an atomizing nozzle and a main body part, the axial airflow mixing section comprises a closed end positioned at the opposite side of the open end, the main body part penetrates through the closed end to extend into the axial airflow mixing cavity and is inserted into the central hole, the main body part is fixedly connected with the closed end, the atomizing nozzle is propped against one side of the hollowed swirl disk, which is away from the axial airflow mixing cavity, the atomizing nozzle is fixedly connected with the main body part, and the fuel can flow in through the main body part and is sprayed out through the atomizing nozzle.
9. The flame synthesis burner capable of realizing flexible adjustment of axial and tangential combined rotational flow according to claim 1, wherein the axial direction of the axial forward flow air inlet pipe and the axial direction of the axial reverse flow air inlet pipe are inclined with respect to the end face of the axial air flow mixing section, the air flow direction in the axial forward flow air inlet pipe is gradually reduced along the air flow direction in the axial forward flow air inlet pipe, the air flow direction in the axial reverse flow air inlet pipe is gradually reduced along the air flow direction in the axial reverse flow air inlet pipe, and the air flow direction in the axial reverse flow air inlet pipe is gradually reduced along the air flow direction in the axial air flow mixing section.
10. The flame synthesis burner capable of realizing flexible adjustment of axial and tangential combined swirling flow according to claim 1, wherein a precursor central tube and an outer shearing air tube which extend along the axial direction of the axial air flow mixing section are arranged in the swirling atomizer, an outlet of the precursor central tube and an outlet of the outer shearing air tube are communicated with the atomizing nozzle, the outer shearing air tube is sleeved outside the precursor central tube, and air sprayed out from the atomizing nozzle is wrapped outside the fuel.
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