CN114430785A - Fiber treatment agent, fiber for artificial hair, and hair dressing product - Google Patents
Fiber treatment agent, fiber for artificial hair, and hair dressing product Download PDFInfo
- Publication number
- CN114430785A CN114430785A CN202080066877.4A CN202080066877A CN114430785A CN 114430785 A CN114430785 A CN 114430785A CN 202080066877 A CN202080066877 A CN 202080066877A CN 114430785 A CN114430785 A CN 114430785A
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- Prior art keywords
- fiber
- artificial hair
- weight
- silicone oil
- parts
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- 239000000835 fiber Substances 0.000 title claims abstract description 136
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 44
- 229920002545 silicone oil Polymers 0.000 claims abstract description 56
- 239000002608 ionic liquid Substances 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 amino ions Chemical class 0.000 claims description 15
- 230000000052 comparative effect Effects 0.000 description 17
- 229920005989 resin Polymers 0.000 description 13
- 239000011347 resin Substances 0.000 description 13
- 239000012190 activator Substances 0.000 description 9
- 229920006026 co-polymeric resin Polymers 0.000 description 9
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 8
- 125000002091 cationic group Chemical group 0.000 description 8
- 229920002292 Nylon 6 Polymers 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920002302 Nylon 6,6 Polymers 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000002074 melt spinning Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920006122 polyamide resin Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 229920006312 vinyl chloride fiber Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-O Pyrrolidinium ion Chemical compound C1CC[NH2+]C1 RWRDLPDLKQPQOW-UHFFFAOYSA-O 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- BSVVEHIYIQCYHQ-UHFFFAOYSA-N butyl prop-2-enoate;chloroethene Chemical compound ClC=C.CCCCOC(=O)C=C BSVVEHIYIQCYHQ-UHFFFAOYSA-N 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- BMZQPXKCLRADET-UHFFFAOYSA-N chloroethene;2-ethylhexyl prop-2-enoate Chemical compound ClC=C.CCCCC(CC)COC(=O)C=C BMZQPXKCLRADET-UHFFFAOYSA-N 0.000 description 1
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 description 1
- BCBHWVAFKCCWBG-UHFFFAOYSA-N chloroethene;ethenyl propanoate Chemical compound ClC=C.CCC(=O)OC=C BCBHWVAFKCCWBG-UHFFFAOYSA-N 0.000 description 1
- GRFFKYTUNTWAGG-UHFFFAOYSA-N chloroethene;prop-2-enenitrile Chemical compound ClC=C.C=CC#N GRFFKYTUNTWAGG-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-P pyrimidine-1,3-diium Chemical compound C1=C[NH+]=C[NH+]=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-P 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41G—ARTIFICIAL FLOWERS; WIGS; MASKS; FEATHERS
- A41G3/00—Wigs
- A41G3/0083—Filaments for making wigs
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41G—ARTIFICIAL FLOWERS; WIGS; MASKS; FEATHERS
- A41G3/00—Wigs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/22—Polymers or copolymers of halogenated mono-olefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2503/00—Domestic or personal
- D10B2503/08—Wigs
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention aims to provide a fiber treatment agent for obtaining fibers for artificial hair with smooth touch. The fiber treatment agent of the present invention comprises water, silicone oil and an ionic liquid, and the content of the silicone oil with respect to the water and the total content of the ionic liquid with respect to the water are 2 parts by weight or more and less than 10 parts by weight. The content of the silicone oil with respect to the water is preferably more than 0.5 parts by weight and 9.5 parts by weight or less, and the content of the ionic liquid with respect to the water is preferably 0.2 parts by weight or more and 5.0 parts by weight or less.
Description
Technical Field
The present invention relates to a fiber treatment agent for fibers used for hair accessories such as wigs, wig pieces, knits, and extensions (hereinafter, simply referred to as "fibers for artificial hair"), fibers for artificial hair using the fiber treatment agent, and hair accessories.
Background
Patent document 1 discloses a fiber treatment agent for imparting smoothness and antistatic property to fibers for artificial hair.
[ Prior art documents ]
[ patent document ]
[ patent document 1 ] Japanese patent laid-open No. 2011-184831
Disclosure of Invention
Problems to be solved by the invention
The fiber for artificial hair of patent document 1 is required to suppress stickiness while having smoothness and antistatic property.
Means for solving the problems
The present inventors have conducted intensive studies and found that a fiber for artificial hair having smoothness and antistatic properties and suppressed stickiness can be obtained by using a fiber treatment agent containing water, silicone oil, and an ionic liquid, and have completed the present invention.
According to the present invention, there is provided a fiber treatment agent further comprising water, a silicone oil and an ionic liquid, wherein the silicone oil is contained in an amount of more than 0.5 part by weight and not more than 9.5 parts by weight per 100 parts by weight of the water, and the ionic liquid is contained in an amount of 0.2 parts by weight or more and not more than 5.0 parts by weight per 100 parts by weight of the water.
Hereinafter, various embodiments of the present invention will be described by way of examples. The embodiments shown below can be combined with each other.
Preferably, the fiber treatment agent is a fiber treatment agent, wherein the silicone oil is an amino-modified silicone oil, and the ionic liquid contains an amino ion.
According to another aspect of the present invention, there is provided a fiber for artificial hair, the surface of which is treated with the above fiber treatment agent.
Preferably, the total amount of the silicone oil and the ionic liquid attached to the artificial hair fiber is 0.03 to 1.0 wt% based on the weight of the artificial hair fiber.
According to another aspect of the present invention, there is provided an artificial hair fiber having silicone oil and ionic liquid adhered thereto, wherein the amount of silicone oil adhered is 0.02 wt% to 0.5 wt% based on the weight of the artificial hair fiber, and the amount of ionic liquid adhered is 0.01 wt% to 0.5 wt% based on the weight of the artificial hair fiber.
According to another aspect of the present invention, there is provided a hair dressing product comprising the fiber for artificial hair.
Detailed Description
The fiber treatment agent of the present embodiment includes water, silicone oil, and an ionic liquid. The fiber treatment agent is applied to the surface of the fiber for artificial hair, thereby imparting smoothness and antistatic properties to the fiber for artificial hair and suppressing the occurrence of stickiness.
The silicone oil is used to impart smoothness to the fiber for artificial hair. The silicone oil may be a straight chain silicone oil or a modified silicone oil. Examples of the linear silicone oil include dimethyl silicone oil, methylphenyl silicone oil, and methylhydrogen silicone oil. Examples of the modified silicone oil include epoxy-modified silicone oil, amino-modified silicone oil, silanol-modified silicone oil, acrylic-modified silicone oil, and polyether-modified silicone oil. The silicone oil is preferably a modified silicone oil, and more preferably an amino-modified silicone oil.
The ionic liquid is used for imparting antistatic properties to the fibers for artificial hair. Examples of the cation of the ionic liquid include an ammonium ion, an imidazolium ion, a pyridinium ion, a pyrrolidinium ion, a pyrrolinium ion, a piperidinium ion, a pyrazinium ion, a pyrimidinium ion, a triazolium ion, a triazinium ion, a quinolinium ion, an isoquinolinium ion, an indolium ion, a quinoxalinium ion, a piperazinium ion, an oxazolinium ion, a thiazolinium ion, and a morpholinium ion. Examples of the anion of the ionic liquid include halogen-based ions, boron-based ions, phosphorus-based ions, and sulfonic acid-based anions. When the silicone oil is an amino-modified silicone oil, the ionic liquid preferably has an amino ion as a cation from the viewpoint of compatibility and dispersibility.
The content of the silicone oil relative to 100 parts by weight of water is preferably more than 0.5 part by weight and 9.5 parts by weight or less, and more preferably 1.5 to 7.0 parts by weight. When the content of the silicone oil is more than 0.5 part by weight, sufficient smoothness can be imparted to the fiber for artificial hair. When the content of the silicone oil is 9.5 parts by weight or less, stickiness of the fiber for artificial hair can be sufficiently suppressed. The content of the silicone oil relative to 100 parts by weight of water is specifically, for example, 0.6, 0.7, 0.8, 0.9, 1.0, 1.5, 2.0, 2.5, 3.0, 3.2, 3.5, 4.0, 4.5, 5.0, 5.5, 6.0, 6.5, 7.0, 7.5, 7.9, 8.0, 8.5, 9.0, 9.5 parts by weight, and may be within a range between any two values exemplified herein. .
The content of the ionic liquid is preferably 0.2 to 5.0 parts by weight, more preferably 0.4 to 3.5 parts by weight, based on 100 parts by weight of water. When the content of the ionic liquid is 0.2 parts by weight or more, sufficient antistatic properties can be imparted to the fiber for artificial hair. When the content of the ionic liquid is 5.0 parts by weight or less, stickiness of the fiber for artificial hair can be sufficiently suppressed. The content of the ionic liquid relative to 100 parts by weight of water is specifically, for example, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1.0, 1.1, 1.5, 2.0, 2.2, 2.5, 3.0, 3.5, 4.0, 4.5, 5.0 parts by weight, and may be within a range between any two values exemplified herein.
The total content of the silicone oil and the ionic liquid is preferably less than 10 parts by weight with respect to 100 parts by weight of water. When the total content is less than 10 parts by weight, stickiness of the artificial hair fiber is suppressed.
The fiber treatment agent may contain an antibacterial treatment agent, a deodorizing treatment agent, a mildewproof treatment agent, an ultraviolet blocking agent, a softening agent, an SR treatment agent, a fragrance treatment agent, a flame retardant, an antistatic agent, an antifoaming agent, a perfume, and the like. On the other hand, the fiber treatment agent preferably contains substantially no cationic activator. For example, the fiber treatment agent does not contain any cationic activator, and even if it contains, the content of the ionic activator is preferably 1 part by weight or less, more preferably 0.1 part by weight or less, relative to 100 parts by weight of water. When a cationic activator is used instead of an ionic liquid to impart sufficient antistatic properties to fibers for artificial hair, stickiness may occur.
The fiber treatment agent is applied to the surface of the artificial hair fiber. The fiber for artificial hair after being coated with the fiber treatment agent is used for hair decoration products such as wigs, wig pieces, knits, extensions and the like. The hair cosmetic product according to one embodiment of the present invention is coated with the fiber treatment agent, and contains an artificial hair fiber to which an active ingredient is attached.
As a method for attaching the fiber treatment agent to the fibers for artificial hair, a conventionally known method of applying a liquid to the fibers for artificial hair is employed. For example, a means of winding fibers for artificial hair around a roll having a surface to which a fiber treatment is applied, a means of immersing fibers for artificial hair in a liquid tank for storing a fiber treatment agent, a means of applying a fiber treatment agent to fibers for artificial hair by an application tool such as a brush or a brush, and the like.
The fiber treatment agent preferably contains an active ingredient, i.e., a compound (silicone oil and ionic liquid) contained in the treatment agent, which is attached to the surface of the artificial hair fiber at a predetermined ratio. The total amount of silicone oil and ionic liquid adhering to the artificial hair fiber is preferably in the range of 0.03 to 1.0 wt% based on the weight of the artificial hair fiber. If the amount of the active ingredient attached is less than 0.03 wt%, the effect of the fiber treatment agent may not be expected, and the effect on the antistatic property or the smoothness may not be obtained. When the amount of the active ingredient attached exceeds 1.0 wt%, the fibers for artificial hair may have a sticky feeling. The total adhesion amount of the silicone oil and the ionic liquid is specifically, for example, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1.0% by weight, and may be within a range between any two values exemplified herein.
The amount of silicone oil adhering to the artificial hair fiber is preferably 0.02 to 0.5% by weight based on the weight of the artificial hair fiber. When the amount of silicone oil deposited is 0.02 wt% or more, sufficient smoothness can be imparted to the fiber for artificial hair. When the amount of silicone oil deposited is 0.5 wt% or less, the stickiness of the fiber for artificial hair is suppressed. The amount of silicone oil deposited is specifically, for example, 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5% by weight, and may be within a range between any two values exemplified herein.
The amount of ionic liquid attached to the artificial hair fiber is preferably 0.01 to 0.5 wt% based on the weight of the artificial hair fiber. When the amount of the ionic liquid to be attached is 0.01% by weight or more, sufficient antistatic properties can be imparted to the fiber for artificial hair. When the amount of the ionic liquid attached is 0.5 wt% or less, the stickiness of the fiber for artificial hair is suppressed. The amount of the ionic liquid deposited is, for example, specifically 0.01, 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5% by weight, and may be within a range between any two values exemplified herein.
Examples of the fibers for artificial hair include vinyl chloride fibers, polyester fibers, and polyamide fibers. The artificial hair fiber is produced through a melt spinning step, a drawing step, and an annealing step. In the melt spinning step, the resin composition is melt spun to produce an undrawn yarn. Specifically, a polyvinyl chloride resin, a polyester resin, or a polyamide resin, and, if necessary, various compounding agents such as a heat stabilizer, a lubricant, a flame retardant, and an ultraviolet absorber are melt-kneaded using a single-screw extruder, a twin-screw extruder, a roll, a banbury mixer, a kneader, or the like, and melt-spun by a general melt-spinning method. At this time, the undrawn yarn is obtained by adjusting the fineness and the winding speed.
In the drawing step, the obtained undrawn yarn is drawn by 1.5 to 5.0 times to produce a drawn yarn. The stretch ratio is preferably 2.0 to 4.0 times. This is because when the draw ratio is appropriately large, the strength of the fiber tends to occur appropriately, and when it is appropriately small, it tends to be less likely to cause yarn breakage at the time of the drawing treatment.
The temperature during the stretching treatment is preferably 80 to 120 ℃. When the stretching temperature is too low, the strength of the fiber tends to be low and yarn breakage tends to occur at the same time, and when it is too high, the hand feeling of the obtained fiber tends to become smooth like plastic.
In the annealing step, the drawn yarn is preferably heat-treated at a heat treatment temperature of 100 to 200 ℃. The heat treatment can reduce the heat shrinkage of the drawn yarn. The heat treatment may be carried out continuously after the stretching treatment, or may be carried out after a certain time interval after the winding.
The monofilament fineness of the fiber for artificial hair is preferably 20 to 100 dtex, and more preferably 35 to 80 dtex. In order to obtain the monofilament fineness, the fineness of the fiber (undrawn yarn) after the melt spinning step is preferably kept at 300 dtex or less. If the fineness of the undrawn yarn is small, the draw ratio can be reduced to obtain a fine artificial hair fiber, and the artificial hair fiber after the drawing treatment is less likely to show luster.
The artificial hair fiber is preferably (1) an artificial hair fiber made of a vinyl chloride resin or (2) an artificial hair fiber made of a polyamide resin. The vinyl chloride resin is obtained by bulk polymerization, solution polymerization, suspension polymerization, emulsion polymerization, or the like, and is preferably produced by suspension polymerization in view of initial colorability of the fiber, or the like. The vinyl chloride resin is a homopolymer resin of a homopolymer of polyvinyl chloride, various copolymer resins, or a mixture thereof. Examples of the copolymer resin include vinyl chloride-vinyl acetate copolymer resins, vinyl chloride-vinyl propionate copolymer resins and other vinyl chloride-vinyl ester copolymer resins, vinyl chloride-butyl acrylate copolymer resins, vinyl chloride-2-ethylhexyl acrylate copolymer resins and other vinyl chloride-acrylic ester copolymer resins, vinyl chloride-ethylene copolymer resins, vinyl chloride-propylene copolymer resins and other vinyl chloride-olefin copolymer resins, vinyl chloride-acrylonitrile copolymer resins, and the like. The content of the comonomer in the copolymer resin can be determined in accordance with the required quality such as the molding processing type and yarn characteristics. The vinyl chloride resin is preferably a mixture of 1 or more than 2 of vinyl chloride resin, a mixture of vinyl chloride resin and chlorinated vinyl chloride resin, and a vinyl chloride-acrylonitrile copolymer.
Examples of the polyamide resin include nylon 6, nylon 66, nylon 11, nylon 12, nylon 6 and 10, nylon 6 and 12, and copolymers thereof. Nylon 6, nylon 66, and copolymers of nylon 6 and nylon 66 are preferred.
[ examples ] A
The present invention will be described in detail below with reference to examples and comparative examples.
1. Formulation of fiber treatment agent
The formulations (components and their amounts (parts by weight)) of the fiber treatment agents of the examples and comparative examples are shown in table 1. The materials used for the fiber treatment agent are as follows. The compounding amount of the silicone oil shown in table 1 is the content of the silicone oil in the silicone emulsion. The cationic activator of comparative example 5 was an aqueous solution in a commercially available product, and the amount of the cationic activator shown in table 1 was the content of the cationic activator in the aqueous solution.
Silicone emulsion AS-50 (Jicun oil chemical Co., Ltd.)
Ionic liquid Amino ion AS300 (Japanese emulsifier Co., Ltd.)
Cationic activator QUARTAMIN60W (Kao corporation) [ TABLE 1 ]
2. Fiber for artificial hair
Examples 1 to 5 and comparative examples 1 to 5 used vinyl chloride fibers, example 6 used polyester fibers, and example 7 used polyamide fibers as fibers for artificial hair. The following materials were used for each fiber. The average fineness of each fiber is 55 to 70 dtex.
Vinyl chloride-based fiber-self-made product (polyvinyl chloride (Toyo polyvinyl chloride Co., Ltd.: TH-700))
Polyester fiber-based fiber A self-made product (using poly (terephthalic acid) (Mitsui chemical Co., Ltd.: J125S))
Polyamide fiber (Polyamide 66 (manufactured by Toray corporation: AMILAN CM3001-N))
3. Application of fiber treatment agent
In each of examples and comparative examples, after completion of stretching in the fiber production process, the fiber treatment agent was applied to the fibers for artificial hair by roll transfer. The amount (% by weight) of the fibers for artificial hair attached to the active ingredients (silicone oil and ionic liquid) of the fiber treatment agent for artificial hair is shown in table 1.
4. Evaluation of fiber for Artificial Hair
(1) Antistatic properties
For each of examples and comparative examples, fibers for artificial hair were bundled to a length of 250mm and a weight of 20g, and after being left for 24 hours in an environment of 23 ℃ C.. times.50% RH, the surface resistance value was measured under a condition of applying a voltage of 10V to the outside using a digital super resistance/micro ammeter (ADVANTEST: R8340). Then, the average of the measured values of N ═ 5 was obtained, and the antistatic properties were evaluated according to the following criteria.
The average of the surface resistance values was less than 1.0X 10 10Ω
Δ average of surface resistance values was 1.0X 1010Omega is more than or equal to 1.0 multiplied by 1012Ω
The average surface resistance value was 1.0X 1012Omega or more
(2) Smoothness and smoothness of the surface
The fibers for artificial hair of examples and comparative examples were bundled to a length of 250mm and a weight of 20g, and evaluated for smoothness according to the following evaluation criteria, judged by 10 persons (experience of 5 years or more) handling the fibers for artificial hair, and evaluated for hand feel.
Excellent performance evaluated by all technicians as good smoothness
Those who evaluated good smoothness were 90% or more and less than 100%
Delta, the technician who evaluates as good smoothness is more than 70 percent and less than 90 percent
X, the technician with good smoothness is evaluated to be less than 70 percent
(3) Stickiness
The artificial hair fibers of examples and comparative examples were bundled to a length of 250mm and a weight of 20g, and judged by 10 persons' hand feeling by an artificial hair fiber treatment technician (working experience was 5 years or more), and evaluation of tackiness was performed according to the following evaluation criteria.
Very good non-tacky feel as evaluated by all technicians
Good technicians rated no sticky hand feel 90% or more and less than 100%
Delta, the technicians rated as having no sticky hand feel was 70% or more, less than 90%
X is less than 70 percent for technicians with no sticky hand feeling
From the results of examples 1 to 10 and comparative example 1, it is understood that when the total amount of the silicone oil content and the ionic liquid content in the fiber treatment agent per 100 parts by weight of water is 2 parts by weight or more, sufficient smoothness is imparted to the fiber for artificial hair. From the results of examples 1 to 10 and comparative example 2, it is understood that when the total amount of the silicone oil content and the ionic liquid content in the fiber treatment agent per 100 parts by mass of water is less than 10 parts by weight, stickiness of the fiber for artificial hair can be sufficiently suppressed.
Further, it is understood from the results of examples 1 to 10 and comparative example 1 that the smoothness of the fiber for artificial hair is improved when the amount of silicone oil deposited on the fiber for artificial hair is 0.02 wt% or more. From the results of examples 1 to 10 and comparative example 2, it is understood that when the amount of silicone oil adhering to the fibers for artificial hair is 0.5 wt% or less, stickiness of the fibers for artificial hair is suppressed.
From the results of examples 1 to 10 and comparative example 3, it is understood that when the content of the ionic liquid in the fiber treatment agent is 0.2 parts by weight or more based on 100 parts by weight of water, sufficient antistatic property can be imparted to the fiber for artificial hair. From the results of examples 1 to 10 and comparative example 4, it is understood that when the content of the ionic liquid is 5 parts by weight or less with respect to 100 parts by weight of water, stickiness of the fiber for artificial hair can be sufficiently suppressed.
Further, it is understood from the results of examples 1 to 10 and comparative example 3 that the antistatic property of the fiber for artificial hair is improved when the amount of the ionic liquid attached to the fiber for artificial hair is 0.01 wt% or more. From the results of examples 1 to 10 and comparative example 4, it is understood that when the amount of ionic liquid attached to the fibers for artificial hair is 0.5 wt% or less, the stickiness of the fibers for artificial hair is sufficiently suppressed.
From the results of examples 1 to 10 and comparative example 5, it is understood that stickiness occurs when a sufficient antistatic property is imparted to the fiber for artificial hair by using a cationic activator instead of an ionic liquid.
Claims (6)
1. A fiber treating agent comprises water, silicone oil and ionic liquid,
the content of the silicone oil is more than 0.5 parts by weight and 9.5 parts by weight or less relative to 100 parts by weight of the water,
the content of the ionic liquid is 0.2 to 5.0 parts by weight with respect to 100 parts by weight of the water.
2. The fiber-treating agent according to claim 1,
the silicone oil is amino-modified silicone oil,
the ionic liquid contains amino ions.
3. A fiber for artificial hair, the surface of which has been treated with the fiber treatment agent according to claim 1 or 2.
4. The fiber for artificial hair according to claim 3, wherein,
the total amount of the silicone oil and the ionic liquid attached to the artificial hair fiber is 0.03 to 1.0 wt% based on the weight of the artificial hair fiber.
5. A fiber for artificial hair, which has silicone oil and ionic liquid adhered thereto,
the amount of silicone oil deposited is 0.02 to 0.5 wt% based on the weight of the artificial hair fiber,
the amount of the ionic liquid attached is 0.01 to 0.5 wt% based on the weight of the artificial hair fiber.
6. A hair dressing product comprising the fiber for artificial hair according to any one of claims 3 to 5.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019-175343 | 2019-09-26 | ||
| JP2019175343 | 2019-09-26 | ||
| PCT/JP2020/027700 WO2021059691A1 (en) | 2019-09-26 | 2020-07-16 | Fiber treatment agent, fibers for artificial hair and headdress product |
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| CN114430785A true CN114430785A (en) | 2022-05-03 |
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| CN202080066877.4A Pending CN114430785A (en) | 2019-09-26 | 2020-07-16 | Fiber treatment agent, fiber for artificial hair, and hair dressing product |
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| Country | Link |
|---|---|
| US (1) | US20220290366A1 (en) |
| JP (1) | JP7492970B2 (en) |
| KR (1) | KR20220069056A (en) |
| CN (1) | CN114430785A (en) |
| WO (1) | WO2021059691A1 (en) |
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| JPH11246364A (en) * | 1997-12-03 | 1999-09-14 | L'oreal Sa | Aqueous dispersion containing a water-insoluble cationic surfactant and an organosiloxane UV-screening agent having a benzalmalonate functional group |
| CN101994256A (en) * | 2009-08-17 | 2011-03-30 | 河南瑞贝卡发制品股份有限公司 | Method for preparing artificial synthetic fiber after finishing auxiliary agent and impregnation process |
| JP2011526263A (en) * | 2008-07-03 | 2011-10-06 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | Salts containing pyrimidinecarboxylic acid derivatives for cosmetic applications |
| CN109619734A (en) * | 2019-01-22 | 2019-04-16 | 安徽美源发制品有限公司 | A kind of preparation process of the smooth wig of anti-deformation |
| US20190216705A1 (en) * | 2016-10-03 | 2019-07-18 | L'oreal | Hair care compositions comprising thiolactic acid-based ionic liquids or thiolactic acid-based ionic mixtures |
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| JPH04178317A (en) * | 1990-11-13 | 1992-06-25 | Pola Chem Ind Inc | Agent for wig maintenance |
| FR2839644B1 (en) * | 2002-05-14 | 2005-09-09 | Oreal | USE OF A PARTICULAR ORGANIC SALT AND COMPOSITION COMPRISING THE SAME FOR THE WASHING AND / OR CONDITIONING OF KERATINIC MATERIALS. |
| ATE501636T1 (en) * | 2006-06-14 | 2011-04-15 | Basf Se | ANTIMICROBIAL COMPOSITIONS |
| JP5453142B2 (en) | 2010-03-10 | 2014-03-26 | 電気化学工業株式会社 | Textile treatment agents, artificial hair fibers and hair ornaments |
| EP2997958B1 (en) * | 2014-09-22 | 2021-03-10 | Evonik Operations GmbH | Emulsion comprising liquid ester quats and polymer thickener |
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2020
- 2020-07-16 WO PCT/JP2020/027700 patent/WO2021059691A1/en active Application Filing
- 2020-07-16 US US17/632,944 patent/US20220290366A1/en active Pending
- 2020-07-16 JP JP2021548370A patent/JP7492970B2/en active Active
- 2020-07-16 KR KR1020227013362A patent/KR20220069056A/en active Pending
- 2020-07-16 CN CN202080066877.4A patent/CN114430785A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11246364A (en) * | 1997-12-03 | 1999-09-14 | L'oreal Sa | Aqueous dispersion containing a water-insoluble cationic surfactant and an organosiloxane UV-screening agent having a benzalmalonate functional group |
| JP2011526263A (en) * | 2008-07-03 | 2011-10-06 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | Salts containing pyrimidinecarboxylic acid derivatives for cosmetic applications |
| CN101994256A (en) * | 2009-08-17 | 2011-03-30 | 河南瑞贝卡发制品股份有限公司 | Method for preparing artificial synthetic fiber after finishing auxiliary agent and impregnation process |
| US20190216705A1 (en) * | 2016-10-03 | 2019-07-18 | L'oreal | Hair care compositions comprising thiolactic acid-based ionic liquids or thiolactic acid-based ionic mixtures |
| CN109619734A (en) * | 2019-01-22 | 2019-04-16 | 安徽美源发制品有限公司 | A kind of preparation process of the smooth wig of anti-deformation |
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| WO2021059691A1 (en) | 2021-04-01 |
| JPWO2021059691A1 (en) | 2021-04-01 |
| US20220290366A1 (en) | 2022-09-15 |
| JP7492970B2 (en) | 2024-05-30 |
| KR20220069056A (en) | 2022-05-26 |
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