CN114427019A - A kind of alloy steel flange groove heat treatment process - Google Patents
A kind of alloy steel flange groove heat treatment process Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 61
- 230000008569 process Effects 0.000 title claims abstract description 60
- 238000010438 heat treatment Methods 0.000 title claims abstract description 35
- 229910000851 Alloy steel Inorganic materials 0.000 title claims abstract description 25
- 238000010791 quenching Methods 0.000 claims abstract description 52
- 230000000171 quenching effect Effects 0.000 claims abstract description 51
- 238000005496 tempering Methods 0.000 claims abstract description 22
- 238000000137 annealing Methods 0.000 claims abstract description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 239000011889 copper foil Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 239000004065 semiconductor Substances 0.000 claims description 6
- 238000004321 preservation Methods 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 3
- 230000008878 coupling Effects 0.000 description 6
- 238000010168 coupling process Methods 0.000 description 6
- 238000005859 coupling reaction Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 230000006698 induction Effects 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- 239000002994 raw material Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
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- 238000005261 decarburization Methods 0.000 description 1
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- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
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- 230000003746 surface roughness Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/06—Surface hardening
- C21D1/09—Surface hardening by direct application of electrical or wave energy; by particle radiation
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
- C21D1/30—Stress-relieving
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
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Abstract
本发明涉及一种合金钢法兰槽热处理工艺,取合金钢法兰槽依次经调质、去应力退火、激光淬火,即完成。与现有技术相比,本发明的工艺可提高法兰槽立面硬度和耐磨性能,同时保证热处理前后的尺寸精度及表面质量。The invention relates to a heat treatment process for an alloy steel flange groove. The alloy steel flange groove is sequentially subjected to quenching and tempering, stress relief annealing and laser quenching, and the process is completed. Compared with the prior art, the process of the present invention can improve the vertical surface hardness and wear resistance of the flange groove, while ensuring the dimensional accuracy and surface quality before and after heat treatment.
Description
技术领域technical field
本发明属于机械制造技术领域,涉及一种合金钢法兰槽热处理工艺。The invention belongs to the technical field of mechanical manufacturing, and relates to a heat treatment process for an alloy steel flange groove.
背景技术Background technique
合金钢法兰是机械机构中常用的连接件,应用广泛。某些特殊用处的法兰会带有槽,为增加装配过程中的尺寸精度及实际使用过程中的耐磨性,需对槽的立面进行淬硬热处理。一般采用氧乙炔火焰加热或者高频感应淬火。氧乙炔火焰热输入量大且对操作者的熟练程度要求高,易造成局部微熔,畸变大且无规律。高频感应淬火加热速度快,畸变量较小,但需定制特殊形状的感应线圈,成本高,加工柔性差,非淬硬区因得不到保护而随之硬化,同时冷却时喷淋的淬火液会污染法兰表面,这些都对后续加工造成不良影响。Alloy steel flanges are commonly used connectors in mechanical mechanisms and are widely used. Some special-purpose flanges will have grooves. In order to increase the dimensional accuracy in the assembly process and the wear resistance in the actual use process, the vertical surface of the groove needs to be hardened and heat treated. Generally, oxyacetylene flame heating or high frequency induction hardening is used. Oxyacetylene flame has a large heat input and high requirements on the operator's proficiency, which is easy to cause local micro-melting, large and irregular distortion. High-frequency induction hardening has a fast heating speed and a small amount of distortion, but needs to customize a special-shaped induction coil, which is expensive and has poor processing flexibility. The non-hardened area is hardened because it is not protected. The liquid will contaminate the flange surface, which will adversely affect the subsequent processing.
发明内容SUMMARY OF THE INVENTION
本发明的目的就是为了提供一种合金钢法兰槽热处理工艺,可提高法兰槽立面硬度和耐磨性能,同时保证热处理前后的尺寸精度及表面质量。The purpose of the present invention is to provide an alloy steel flange groove heat treatment process, which can improve the vertical surface hardness and wear resistance of the flange groove, and at the same time ensure the dimensional accuracy and surface quality before and after heat treatment.
本发明的目的可以通过以下技术方案来实现:The object of the present invention can be realized through the following technical solutions:
一种合金钢法兰槽热处理工艺,取合金钢法兰槽依次经调质、去应力退火、激光淬火,即完成。A heat treatment process for an alloy steel flange groove is completed by sequentially quenching and tempering, stress relief annealing and laser quenching of the alloy steel flange groove.
进一步的,所述调质过程包括淬火和高温回火两个工序,其中,淬火工序为将合金钢法兰槽加热后保温,再油淬冷却;高温回火工序为对淬火后的合金钢法兰槽继续加热保温,并出炉空气冷却。Further, the quenching and tempering process includes two processes: quenching and high temperature tempering, wherein, the quenching process is to heat the alloy steel flange groove, then heat preservation, and then oil quench and cool; the high temperature tempering process is to heat the alloy steel after quenching. The blue tank continues to be heated and kept warm, and the furnace is air-cooled.
更进一步的,所述淬火工序中的具体工艺条件为:加热至860℃,再保温2h。油淬时的油温为20~50℃。Further, the specific process conditions in the quenching process are: heating to 860° C., and then maintaining the temperature for 2 hours. The oil temperature during oil quenching is 20 to 50 °C.
更进一步的,所述高温回火工序中的具体工艺条件为:加热至580~600℃,保温4h。Further, the specific process conditions in the high temperature tempering process are: heating to 580-600° C., and keeping the temperature for 4 hours.
进一步的,所述去应力退火过程为:对工件加热保温,再出炉空冷。Further, the stress-relieving annealing process is as follows: heating the workpiece for heat preservation, and then air-cooling the workpiece.
更进一步的,去应力退火的具体工艺条件为:加热至560℃,保温2h。Further, the specific process conditions of stress relief annealing are: heating to 560° C. and holding for 2 hours.
进一步的,所述激光淬火过程为:在合金钢法兰槽的淬硬区(一般为其立面)喷涂激光涂料,其余非淬硬区覆盖铜箔,然后采用激光器进行激光扫描。Further, the laser quenching process is as follows: spray laser paint on the hardened area of the alloy steel flange groove (generally its facade), and cover the remaining non-hardened areas with copper foil, and then use a laser to perform laser scanning.
更进一步的,所述激光淬火过程中,所用激光涂料为市售的CT-150半导体激光专用淬火涂料,其涂覆厚度为0.03~0.06mm。Further, in the laser quenching process, the laser coating used is a commercially available CT-150 semiconductor laser special quenching coating, and its coating thickness is 0.03-0.06 mm.
更进一步的,所述激光淬火过程中,铜箔的覆盖厚度为1~2mm。Further, in the laser quenching process, the thickness of the copper foil is 1-2 mm.
更进一步的,所述激光器为半导体耦合光纤输出激光器系统(也可以为本领域其他常规符合对应使用要求的市售激光器),其输出功率为2.7-3.3KW,扫描速度为3-5mm/s,采用矩形光斑,光斑尺寸为(3-5)×(3-10)mm。Further, the laser is a semiconductor-coupled fiber output laser system (it can also be other conventional commercially available lasers in the field that meet the corresponding use requirements), and its output power is 2.7-3.3KW, and the scanning speed is 3-5mm/s, A rectangular spot is used, and the spot size is (3-5) × (3-10) mm.
本发明中,激光淬火利用聚焦后的高能量密度(104-105W/cm2)、高相干性、高方向性的激光束快速扫描工件表面,使其以较快速度(105-106℃/s)升温进行自冷淬火,形成淬硬层。激光淬火可以显著改善工件表面性能,具有畸变小、加工柔性好、表面质量高、自动化程度高、适用面广等优良特点。激光淬火后,硬化区可获得极细的马氏体组织,晶粒细小、位错度高,硬度比常规淬火提高约15%-20%,且只要工艺得当,淬火后表面几乎无氧化脱碳现象,表面粗糙度也几乎不变,可以作为工件加工的最后工序。In the present invention, laser quenching utilizes a focused laser beam with high energy density (10 4 -10 5 W/cm 2 ), high coherence and high directivity to rapidly scan the surface of the workpiece, so that the workpiece surface can be rapidly scanned (10 5 - 10 5 - 10 5 W/cm 2 ). 10 6 ℃/s) for self-cooling and quenching to form a hardened layer. Laser quenching can significantly improve the surface properties of the workpiece, and has excellent characteristics such as small distortion, good processing flexibility, high surface quality, high degree of automation, and wide application. After laser quenching, a very fine martensite structure can be obtained in the hardened zone, with fine grains and high dislocation, and the hardness is about 15%-20% higher than that of conventional quenching, and as long as the process is proper, the surface after quenching is almost free of oxidation and decarburization. phenomenon, the surface roughness is almost unchanged, and can be used as the final process of workpiece processing.
与现有技术相比,本发明通过调质处理使得法兰具有良好的机械性能和金相组织,采用去应力退火消除了法兰槽的残余加工应力,最终采用激光淬火的方式使槽的立面得到硬化,CT-150涂料使工件表面的激光吸收效率增高,铜箔使非淬硬区得到保护。该工艺使法兰槽立面得到均匀稳定的硬化层,而非淬硬区的硬度几乎不变,同时整个法兰的畸变极小,尺寸稳定性极佳。此外,该工艺具有自动化程度高、加工效率高、加工柔性好、质量稳定性高、绿色环保等诸多优点。Compared with the prior art, in the present invention, the flange has good mechanical properties and metallographic structure through quenching and tempering treatment, and the residual machining stress of the flange groove is eliminated by stress relief annealing, and finally, laser quenching is used to make the groove stand upright. The surface is hardened, the CT-150 coating increases the laser absorption efficiency of the workpiece surface, and the copper foil protects the non-hardened area. This process makes the flange groove facade get a uniform and stable hardened layer, the hardness of the non-hardened area is almost unchanged, and the distortion of the entire flange is extremely small and the dimensional stability is excellent. In addition, the process has many advantages such as high degree of automation, high processing efficiency, good processing flexibility, high quality stability, and environmental protection.
具体实施方式Detailed ways
下面结合具体实施例对本发明进行详细说明。本实施例以本发明技术方案为前提进行实施,给出了详细的实施方式和具体的操作过程,但本发明的保护范围不限于下述的实施例。The present invention will be described in detail below with reference to specific embodiments. This embodiment is implemented on the premise of the technical solution of the present invention, and provides a detailed implementation manner and a specific operation process, but the protection scope of the present invention is not limited to the following embodiments.
以下各实施例中,如无特别说明的原料、设备或处理技术,则表明其均为本领域的常规市售原料、或设备或常规处理技术。In the following examples, if there is no special description of the raw materials, equipment or processing technology, it means that they are all conventional commercially available raw materials, or equipment or conventional processing technology in the field.
实施例一Example 1
联轴器法兰,材料为35CrMo,外径为Φ350mm,调质后硬度为22-27HRC,盘面均匀环布16个槽,槽深5mm,槽立面硬度50-55HRC。Coupling flange, the material is 35CrMo, the outer diameter is Φ350mm, the hardness after quenching and tempering is 22-27HRC, the disk surface is evenly distributed with 16 grooves, the groove depth is 5mm, and the groove elevation hardness is 50-55HRC.
其热处理工艺包含以下步骤:Its heat treatment process includes the following steps:
第一步:调质处理。加热淬火,将法兰加热860℃并保温处理2h,出炉后油淬,油温36℃。The first step: conditioning treatment. Heating and quenching, heating the flange to 860°C and heat preservation for 2h, oil quenching after being released, the oil temperature is 36°C.
高温回火,加热至580℃并保温4h,出炉空冷。调质后硬度24.5HRC。Tempered at high temperature, heated to 580°C and kept for 4h, then air-cooled. The hardness after quenching and tempering is 24.5HRC.
第二步:去应力退火。将法兰加热至560℃并保温2h,出炉空冷。The second step: stress relief annealing. The flange was heated to 560°C and kept for 2h, and then air-cooled.
第三步:激光淬火。在法兰槽立面均匀喷涂0.05mm厚度CT-150涂料,采用LASERLINE原装LDF4000-400半导体耦合光纤输出激光器(最大功率4KW),输出功率为2.7KW,扫描速度为4mm/s,矩形光斑尺寸为3×5mm。非淬硬区采用1mm厚度的铜箔覆盖保护。The third step: laser quenching. The 0.05mm thick CT-150 paint is evenly sprayed on the facade of the flange groove, using LASERLINE original LDF4000-400 semiconductor-coupled fiber output laser (maximum power 4KW), the output power is 2.7KW, the scanning speed is 4mm/s, and the rectangular spot size is 3×5mm. The non-hardened area is covered with 1mm thick copper foil.
工艺完成后,法兰槽立面硬度51-53HRC,非淬硬区硬度26.2HRC,盘面最大变形为0.05mm。After the process is completed, the hardness of the flange groove elevation is 51-53HRC, the hardness of the non-hardened area is 26.2HRC, and the maximum deformation of the disk surface is 0.05mm.
对比例一Comparative Example 1
采用与实施例一同批联轴器法兰,前两步也采用相同参数的调质处理和去应力退火,仅第三步采取高频感应淬火(电流频率:150KHz,淬火温度900℃,使用淬火油进行冷却,加热至180℃低温回火2h)。工艺完成后法兰槽立面硬度48-51HRC,非淬硬区硬度45HRC,法兰盘面最大变形为0.65mm。畸变量过大以至无法进行后续的加工。Using the same batch of coupling flanges as in the embodiment, the first two steps also use quenching and tempering treatment and stress relief annealing with the same parameters. The oil is cooled, heated to 180°C and tempered at low temperature for 2h). After the process is completed, the hardness of the flange groove elevation is 48-51HRC, the hardness of the non-hardened area is 45HRC, and the maximum deformation of the flange surface is 0.65mm. The amount of distortion is too large to allow subsequent processing.
对比例二Comparative Example 2
采用与实施例一同批联轴器法兰,采用相同参数的调质处理和激光淬火,省略第二步的去应力退火工序。工艺完成后法兰槽立面硬度48-51HRC,非淬硬区硬度45HRC,法兰盘面最大变形为0.17mm。畸变量较大以至无法进行后续的加工。Using the same batch of coupling flanges as in the embodiment, quenching and tempering treatment and laser quenching with the same parameters, the stress relief annealing process of the second step is omitted. After the process is completed, the hardness of the flange groove elevation is 48-51HRC, the hardness of the non-hardened area is 45HRC, and the maximum deformation of the flange surface is 0.17mm. The amount of distortion is so large that subsequent processing cannot be performed.
实施例二Embodiment 2
联轴器法兰,材料为42CrMo,外径为Φ310mm,调质后硬度为28-32HRC,盘面均匀环布16个槽,槽深7mm,槽立面硬度53-58HRC。Coupling flange, the material is 42CrMo, the outer diameter is Φ310mm, the hardness after quenching and tempering is 28-32HRC, the disk surface is evenly distributed with 16 grooves, the groove depth is 7mm, and the groove elevation hardness is 53-58HRC.
其热处理工艺包含以下步骤:Its heat treatment process includes the following steps:
第一步:调质处理。加热淬火,将法兰加热至860℃并保温2h,出炉后油淬,油温28℃。The first step: conditioning treatment. Heating and quenching, the flange is heated to 860 ° C and kept for 2 hours, and oil quenched after being released, the oil temperature is 28 ° C.
高温回火,加热至600℃并保温4h,出炉空冷。调质后硬度30HRC。Tempering at high temperature, heating to 600°C and holding for 4h, then air-cooled. After quenching and tempering, the hardness is 30HRC.
第二步:去应力退火。将法兰加热至560℃并保温2h,出炉空冷。The second step: stress relief annealing. The flange was heated to 560°C and kept for 2h, and then air-cooled.
第三步:激光淬火。在法兰槽立面均匀喷涂0.05mm厚度CT-150涂料,采用LASERLINE原装LDF4000-400半导体耦合光纤输出激光器(最大功率4KW),输出功率为3.0KW,扫描速度为4mm/s,矩形光斑尺寸为3×7mm。非淬硬区采用1mm厚度的铜箔覆盖保护。The third step: laser quenching. Evenly spray 0.05mm thick CT-150 paint on the facade of the flange groove, use LASERLINE original LDF4000-400 semiconductor-coupled fiber output laser (maximum power 4KW), the output power is 3.0KW, the scanning speed is 4mm/s, and the rectangular spot size is 3×7mm. The non-hardened area is covered with 1mm thick copper foil.
工艺完成后,法兰槽立面硬度56-57HRC,非淬硬区硬度31.8HRC,盘面最大变形为0.03mm。After the process is completed, the hardness of the flange groove elevation is 56-57HRC, the hardness of the non-hardened area is 31.8HRC, and the maximum deformation of the disk surface is 0.03mm.
对比例三Comparative example three
采用与实施例二同批联轴器法兰,前两步也采用相同参数的调质处理和去应力退火,仅第三步采取高频感应淬火(电流频率:200KHz,淬火温度900℃,使用淬火油进行冷却,加热至180℃低温回火2h)。工艺完成后法兰槽立面硬度53-56HRC,非淬硬区硬度49HRC,法兰盘面最大变形为0.40mm。畸变量过大以至无法进行后续的加工。Using the same batch of coupling flanges as in the second embodiment, the first two steps also use quenching and tempering treatment and stress relief annealing with the same parameters, and only the third step adopts high-frequency induction quenching (current frequency: 200KHz, quenching temperature 900℃, using Quenching oil for cooling, heating to 180 ℃ low temperature tempering 2h). After the process is completed, the hardness of the flange groove elevation is 53-56HRC, the hardness of the non-hardened area is 49HRC, and the maximum deformation of the flange surface is 0.40mm. The amount of distortion is too large to allow subsequent processing.
对比例四Comparative Example 4
采用与实施例二同批联轴器法兰,采用相同参数的调质处理和激光淬火,省略第二步的去应力退火工序。工艺完成后法兰槽立面硬度55-57HRC,非淬硬区硬度45HRC,法兰盘面最大变形为0.16mm。畸变量较大以至无法进行后续的加工。Using the same batch of coupling flanges as in the second embodiment, quenching and tempering treatment and laser quenching with the same parameters, the stress relief annealing process of the second step is omitted. After the process is completed, the hardness of the flange groove elevation is 55-57HRC, the hardness of the non-hardened area is 45HRC, and the maximum deformation of the flange surface is 0.16mm. The amount of distortion is so large that subsequent processing cannot be performed.
上述的对实施例的描述是为便于该技术领域的普通技术人员能理解和使用发明。熟悉本领域技术的人员显然可以容易地对这些实施例做出各种修改,并把在此说明的一般原理应用到其他实施例中而不必经过创造性的劳动。因此,本发明不限于上述实施例,本领域技术人员根据本发明的揭示,不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。The foregoing description of the embodiments is provided to facilitate understanding and use of the invention by those of ordinary skill in the art. It will be apparent to those skilled in the art that various modifications to these embodiments can be readily made, and the generic principles described herein can be applied to other embodiments without inventive step. Therefore, the present invention is not limited to the above-mentioned embodiments, and improvements and modifications made by those skilled in the art according to the disclosure of the present invention without departing from the scope of the present invention should all fall within the protection scope of the present invention.
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