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CN114406391A - Welding method for aluminum-based flexible circuit board and component - Google Patents

Welding method for aluminum-based flexible circuit board and component Download PDF

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Publication number
CN114406391A
CN114406391A CN202210198753.2A CN202210198753A CN114406391A CN 114406391 A CN114406391 A CN 114406391A CN 202210198753 A CN202210198753 A CN 202210198753A CN 114406391 A CN114406391 A CN 114406391A
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China
Prior art keywords
aluminum
circuit board
flexible circuit
based flexible
component
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唐小侠
王晓南
刘清
环鹏程
加藤彬
杨锋
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Suzhou University
Yancheng Weixin Electronics Co Ltd
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Suzhou University
Yancheng Weixin Electronics Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/005Soldering by means of radiant energy
    • B23K1/0056Soldering by means of radiant energy soldering by means of beams, e.g. lasers, E.B.
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
    • H05K3/34Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by soldering
    • H05K3/341Surface mounted components

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)

Abstract

The invention discloses a method for welding an aluminum-based flexible circuit board and a component, which comprises the following steps: carrying out surface treatment on the original aluminum-based flexible circuit board to obtain a treated aluminum-based flexible circuit board; pre-coating tin-based solder on the treated aluminum-based flexible circuit board to obtain a target aluminum-based flexible circuit board; and carrying out laser soldering on the target aluminum-based flexible circuit board and the component to be soldered to complete soldering. The influence of an oxide film on the surface of the aluminum-based flexible circuit board is removed through surface treatment, and the wettability of the joint is improved; by pre-coating tin-based brazing filler metal and introducing a laser soldering method, the problems of long welding time, low efficiency and high energy consumption caused by reflow soldering are solved on the basis of ensuring that the micron-sized aluminum substrate and the copper-based component are effectively connected, the pressure sensitivity and the temperature sensitivity in the traditional welding method are overcome, the high-efficiency and high-quality connection of the aluminum-based flexible circuit board and the component is realized, and the aluminum-based flexible circuit board can be further popularized and applied.

Description

一种铝基柔性线路板与元器件的焊接方法A kind of welding method of aluminum-based flexible circuit board and components

技术领域technical field

本发明涉及电子封装和汽车领域,具体涉及一种铝基柔性线路板与元器件的焊接方法。The invention relates to the fields of electronic packaging and automobiles, in particular to a welding method of an aluminum-based flexible circuit board and components.

背景技术Background technique

传统FPC(Flexible Printed Circuit,柔性线路板)行业大多使用铜基线路板(包括PCB和FPCB),但由于铝具有良好的导电性、导热性、轻质量(铜的30%)和低成本(铜的1/6)的明显优势,能够实现大幅降低成本的同时有效降低汽车整车重量,最终实现提高燃油经济性和降低排放从而实现碳减排。因此在汽车行业应用上,特别是新能源电动力汽车行业,铝基板有望替代传统的铜基线路板,从而在极大降低了生产成本的同时提高续航里程及降低能源消耗。The traditional FPC (Flexible Printed Circuit, flexible circuit board) industry mostly uses copper-based circuit boards (including PCB and FPCB), but due to aluminum's good electrical conductivity, thermal conductivity, light weight (30% of copper) and low cost (copper 1/6) of the obvious advantages, which can greatly reduce the cost and effectively reduce the weight of the vehicle, and ultimately improve fuel economy and reduce emissions to achieve carbon emission reduction. Therefore, in the application of the automotive industry, especially the new energy electric vehicle industry, aluminum substrates are expected to replace traditional copper-based circuit boards, thereby greatly reducing production costs while increasing cruising range and reducing energy consumption.

在现有技术中,第一方面,传统的铜基柔性线路板焊盘表面焊接元器件(其引脚或焊点大多数为铜基)的技术已经非常成熟(主要采用回流焊)。然而由于车载线路板表面上需要连接的元器件个数(焊点面积)与整个线路板面积相比很小,采用回流焊接的方法则带来了焊接时间长、效率低和能源浪费的问题。因此,不推荐将回流焊接方法应用于铝基柔性线路板和铜基元器件的焊接中。In the prior art, in the first aspect, the technology for soldering components (most of their pins or solder joints are copper-based) on the surface of traditional copper-based flexible circuit board pads is very mature (mainly by reflow soldering). However, since the number of components (solder joint area) that needs to be connected on the surface of the vehicle circuit board is very small compared to the entire circuit board area, the reflow soldering method brings the problems of long soldering time, low efficiency and energy waste. Therefore, it is not recommended to apply the reflow soldering method to the soldering of aluminum-based flexible circuit boards and copper-based components.

第二方面,当铜基板换成铝基板时,由于铝基板表面存在氧化铝(Al2O3)氧化膜且很难去除,这种致密的高熔点的氧化铝薄膜,使得铝基柔性线路板与锡基钎料难以润湿形成良好的焊接接头。为提高接头的润湿性,现有技术中主要是利用化学反应的焊接方法,该方法采用NaOH溶液先碱蚀去除铝基板表面的Al2O3氧化膜,再用HNO3钝化其表面,在HNO3钝化后立即上锡膏然后回流焊接,这样能最大限度地降低Al2O3氧化膜的厚度,同时在锡膏中添加Zn、Ga和Na等使得锡膏合金化,能有效提高接头的润湿性。但是该方法由于需要添加合金元素且Al2O3氧化膜不能完全去除,局部区域仍然存在Al2O3氧化膜,这就会导致这些局部区域可能出现虚焊,因此该方法不可避免会带来成本提高以及接头安全服役性能的不可控,此外由于该方法仍然采用传统回流焊接,其效率依然没有得到提高,也不适用于铝基柔性线路板和铜基元器件的焊接。On the other hand, when the copper substrate is replaced with an aluminum substrate, since there is an aluminum oxide (Al 2 O 3 ) oxide film on the surface of the aluminum substrate and it is difficult to remove, this dense high melting point aluminum oxide film makes the aluminum-based flexible circuit board Difficult to wet with tin-based solder to form a good solder joint. In order to improve the wettability of the joint, the prior art mainly utilizes the welding method of chemical reaction. This method uses NaOH solution to first remove the Al 2 O 3 oxide film on the surface of the aluminum substrate by alkaline etching, and then use HNO 3 to passivate the surface. Apply solder paste immediately after HNO 3 passivation and then reflow soldering, which can minimize the thickness of Al 2 O 3 oxide film. At the same time, adding Zn, Ga and Na to the solder paste makes the solder paste alloy, which can effectively improve the Wettability of the joint. However, due to the need to add alloying elements and the Al 2 O 3 oxide film cannot be completely removed in this method, the Al 2 O 3 oxide film still exists in local areas, which may lead to false welding in these local areas. Therefore, this method inevitably brings The cost is increased and the safe service performance of the joint is uncontrollable. In addition, because this method still uses traditional reflow soldering, its efficiency has not been improved, and it is not suitable for the welding of aluminum-based flexible circuit boards and copper-based components.

第三方面,铝基柔性线路板和铜基元器件的焊接实际为微米级的铜和铝的连接问题,前沿文献和技术报道的关于微米级的铜和铝的连接方法主要为固相焊接(包括搅拌摩擦焊接、超声波焊接等方法)和纳米激光焊接。针对固相焊接,例如超声波焊接,该方法运用超声波破碎铝基板表面氧化膜从而形成连接,但是铝基板为毫米级的,而柔性线路板的厚度为微米级且对压力极为敏感,由于铝基柔性线路板与元器件的尺寸效应(<100μm),在实际操作过程中存在工装难、大压力易损坏线路板等难以解决的问题。因此该方法也不适用于铝基柔性线路板和铜基元器件的焊接。针对纳米激光焊接,其能使得微米级的铝基板和铜板形成有效连接,但是基于纳米激光的高能量密度的特性,焊接接头不可避免会出现激光烧蚀后形成的缺陷,这会大大降低柔性线路板的服役安全性能,因此也不推荐应用于铝基柔性线路板和铜基元器件的焊接中。In the third aspect, the welding of aluminum-based flexible circuit boards and copper-based components is actually a connection problem of micron-level copper and aluminum. The connection method of micron-level copper and aluminum reported in cutting-edge literature and technology is mainly solid-phase welding ( Including friction stir welding, ultrasonic welding and other methods) and nano-laser welding. For solid-phase welding, such as ultrasonic welding, this method uses ultrasonic waves to break the oxide film on the surface of the aluminum substrate to form a connection, but the aluminum substrate is millimeter-level, while the thickness of the flexible circuit board is micrometer-level and is extremely sensitive to pressure. The size effect of circuit boards and components (<100μm), in the actual operation process, there are difficult problems such as difficult tooling, high pressure and easy damage to the circuit board. Therefore, this method is also not suitable for the welding of aluminum-based flexible circuit boards and copper-based components. For nano-laser welding, it can effectively connect the micron-scale aluminum substrate and copper plate, but based on the high energy density of nano-laser, the welding joint will inevitably have defects formed after laser ablation, which will greatly reduce the flexible circuit. Therefore, it is not recommended to be used in the welding of aluminum-based flexible circuit boards and copper-based components.

综上,如何实现铝基柔性线路板与元器件的高效优质的连接是制约铝基柔性线路板进一步推广运用的卡脖子问题。In summary, how to achieve efficient and high-quality connection between aluminum-based flexible circuit boards and components is a bottleneck problem that restricts the further promotion and application of aluminum-based flexible circuit boards.

发明内容SUMMARY OF THE INVENTION

有鉴于此,本发明实施例提供了一种铝基柔性线路板与元器件的焊接方法,以解决现有技术中铝基柔性线路板表面出现的氧化膜阻碍铝基柔性线路板和钎料的反应润湿、铝基柔性线路板在焊接过程中的高的温度敏感性和压力敏感性以及采用传统回流焊接的方法带来的焊接时间长、效率低和能耗高等问题,能够实现铝基柔性线路板与元器件的高效优质的连接,从而使得铝基柔性线路板能进一步得到推广运用。In view of this, the embodiment of the present invention provides a welding method of an aluminum-based flexible circuit board and a component, so as to solve the problem that the oxide film on the surface of the aluminum-based flexible circuit board in the prior art hinders the welding of the aluminum-based flexible circuit board and the solder. Reactive wetting, the high temperature sensitivity and pressure sensitivity of aluminum-based flexible circuit boards during the soldering process, and the long soldering time, low efficiency and high energy consumption caused by traditional reflow soldering methods can achieve aluminum-based flexible circuit boards. High-efficiency and high-quality connection between circuit boards and components, so that aluminum-based flexible circuit boards can be further popularized and used.

本发明实施例提供了一种铝基柔性线路板与元器件的焊接方法,包括:The embodiment of the present invention provides a welding method for an aluminum-based flexible circuit board and a component, including:

对原始铝基柔性线路板进行表面处理,得到处理铝基柔性线路板;Surface treatment of the original aluminum-based flexible circuit board to obtain a treated aluminum-based flexible circuit board;

对所述处理铝基柔性线路板预上锡基钎料,得到目标铝基柔性线路板;Pre-applying tin-based solder to the treated aluminum-based flexible circuit board to obtain a target aluminum-based flexible circuit board;

对所述目标铝基柔性线路板和待焊接元器件进行激光锡焊,完成焊接。Laser soldering is performed on the target aluminum-based flexible circuit board and the components to be welded to complete the welding.

可选地,所述对原始铝基柔性线路板进行表面处理,包括:Optionally, the surface treatment of the original aluminum-based flexible circuit board includes:

依次对所述原始铝基柔性线路板进行除油处理和碱蚀处理,得到第一铝基柔性线路板;Perform degreasing treatment and alkali etching treatment on the original aluminum-based flexible circuit board in sequence to obtain a first aluminum-based flexible circuit board;

采用纯净水,对所述第一铝基柔性线路板进行清洗,得到第二铝基柔性线路板。Using pure water, the first aluminum-based flexible circuit board is cleaned to obtain a second aluminum-based flexible circuit board.

可选地,在对所述第一铝基柔性线路板进行清洗之后,还包括:Optionally, after cleaning the first aluminum-based flexible circuit board, the method further includes:

对所述第二铝基柔性线路板进行化学浸锌,得到第三铝基柔性线路板;chemically dipping the second aluminum-based flexible circuit board to obtain a third aluminum-based flexible circuit board;

对所述第三铝基柔性线路板进行镀镍,得到所述处理铝基柔性线路板。Nickel plating is performed on the third aluminum-based flexible circuit board to obtain the treated aluminum-based flexible circuit board.

可选地,镀镍的厚度范围为4~7μm。Optionally, the thickness of the nickel plating ranges from 4 to 7 μm.

可选地,镀镍的厚度范围为5~6μm。Optionally, the thickness of the nickel plating ranges from 5 to 6 μm.

可选地,在对所述处理铝基柔性线路板预上锡基钎料之前,还包括:Optionally, before pre-applying tin-based solder to the processed aluminum-based flexible circuit board, the method further includes:

对所述处理铝基柔性线路板进行超声清洗;performing ultrasonic cleaning on the treated aluminum-based flexible circuit board;

对超声清洗后的所述处理铝基柔性线路板进行晾干处理。Air-drying is performed on the treated aluminum-based flexible circuit board after ultrasonic cleaning.

可选地,所述锡基钎料的厚度范围为15~20μm。Optionally, the thickness of the tin-based solder is in the range of 15-20 μm.

可选地,所述对所述目标铝基柔性线路板和待焊接元器件进行激光锡焊,包括:Optionally, performing laser soldering on the target aluminum-based flexible circuit board and the components to be welded includes:

对所述目标铝基柔性线路板进行固定;fixing the target aluminum-based flexible circuit board;

将所述待焊接元器件的引脚放置在固定后的所述目标铝基柔性线路板的上方,并对所述待焊接元器件进行固定;placing the pins of the components to be welded above the fixed target aluminum-based flexible circuit board, and fixing the components to be welded;

采用激光锡焊设备,对固定后的所述目标铝基柔性线路板和固定后的所述待焊接元器件的引脚进行焊接。Using laser soldering equipment, the fixed target aluminum-based flexible circuit board and the fixed pins of the components to be welded are welded.

可选地,所述激光焊接设备发出的激光光斑与所述待焊接元器件的引脚中心重合。Optionally, the laser spot emitted by the laser welding device coincides with the center of the pin of the component to be welded.

可选地,所述激光焊接设备提供的焊丝的直径范围为0.3~0.6mm。Optionally, the diameter of the welding wire provided by the laser welding equipment ranges from 0.3 to 0.6 mm.

可选地,在对所述目标铝基柔性线路板和所述待焊接元器件的引脚进行焊接中,还包括:Optionally, in the welding of the target aluminum-based flexible circuit board and the pins of the component to be welded, the process further includes:

采用红外温度检测设备,实时检测所述目标铝基柔性线路板与所述待焊接元器件的引脚之间的焊接温度;其中,所述焊接温度小于500℃。Infrared temperature detection equipment is used to detect the welding temperature between the target aluminum-based flexible circuit board and the pins of the component to be welded in real time; wherein, the welding temperature is less than 500°C.

本发明的有益效果:Beneficial effects of the present invention:

通过对原始铝基柔性线路板进行表面处理,一方面能去除铝基柔性线路板表面氧化膜的影响,进而避免氧化膜阻碍铝基柔性线路板和钎料的反应润湿,提高接头的润湿性,另一方面能避免采用传统回流焊接方法,确保焊接的高效性;通过对处理铝基柔性线路板预上锡基钎料,能便于利用锡基钎料发生熔化,并分别与元器件的铜引脚和镍层形成良好的冶金结合,实现了铝基柔性线路板和铜基元器件的高效优质的连接;基于锡基焊料,在目标铝基柔性线路板和待焊接元器件的焊接中引入激光锡焊方法,在确保微米级的铝基板与铜基元器件形成有效连接的基础上,能解决回流焊接带来的焊接时间长、效率低和能耗大的问题,进一步降低生产成本的同时促进了碳达峰和碳中和目标地实现;还一方面能避免传统固相焊接方法中的压力敏感性,不会存在工装难、大压力易损坏线路板等现象,另一方面能克服传统纳米激光焊接方法中的温度敏感性,不会出现激光烧蚀形成缺陷而降低柔性线路板的服役安全性能;By surface treatment of the original aluminum-based flexible circuit board, on the one hand, the influence of the oxide film on the surface of the aluminum-based flexible circuit board can be removed, thereby preventing the oxide film from hindering the reaction and wetting of the aluminum-based flexible circuit board and the solder, and improving the wetting of the joint. On the other hand, the traditional reflow soldering method can be avoided to ensure the high efficiency of soldering; by pre-applying tin-based solder to the processed aluminum-based flexible circuit board, it is easy to use the tin-based solder to melt, and separately and the components The copper pins and the nickel layer form a good metallurgical combination, which realizes the efficient and high-quality connection between the aluminum-based flexible circuit board and the copper-based components; based on the tin-based solder, in the welding of the target aluminum-based flexible circuit board and the components to be welded The introduction of the laser soldering method can solve the problems of long welding time, low efficiency and high energy consumption caused by reflow soldering on the basis of ensuring the effective connection between the micron-scale aluminum substrate and the copper-based components, and further reduce the production cost. At the same time, it promotes the realization of carbon peaking and carbon neutralization; on the one hand, it can avoid the pressure sensitivity in traditional solid-phase welding methods, and there will be no problems such as difficult tooling and easy damage to circuit boards under high pressure. On the other hand, it can overcome the The temperature sensitivity in the traditional nano-laser welding method will not cause laser ablation to form defects and reduce the service safety performance of the flexible circuit board;

通过本发明中铝基柔性线路板与元器件的焊接方法,能有效解决现有技术中铝基柔性线路板表面出现的氧化膜阻碍铝基柔性线路板和钎料的反应润湿、铝基柔性线路板在焊接过程中的高的温度敏感性和压力敏感性以及采用传统回流焊接的方法带来的焊接时间长、效率低和能耗高等问题,能够实现铝基柔性线路板与元器件的高效优质的连接,从而使得铝基柔性线路板能进一步得到推广运用。The welding method of the aluminum-based flexible circuit board and the components in the present invention can effectively solve the problem that the oxide film on the surface of the aluminum-based flexible circuit board in the prior art hinders the reaction wetting of the aluminum-based flexible circuit board and the solder, and the aluminum-based flexible circuit board The high temperature sensitivity and pressure sensitivity of the circuit board during the soldering process, as well as the long soldering time, low efficiency and high energy consumption caused by the traditional reflow soldering method, can realize the high efficiency of aluminum-based flexible circuit boards and components. High-quality connection, so that the aluminum-based flexible circuit board can be further popularized and used.

附图说明Description of drawings

通过参考附图会更加清楚的理解本发明的特征和优点,附图是示意性的而不应理解为对本发明进行任何限制,在附图中:The features and advantages of the present invention will be more clearly understood by reference to the accompanying drawings, which are schematic and should not be construed as limiting the invention in any way, in which:

图1示出了本发明实施例中一种铝基柔性线路板与元器件的焊接方法的流程图;FIG. 1 shows a flowchart of a welding method for an aluminum-based flexible circuit board and components in an embodiment of the present invention;

图2示出了本发明实施例中得到处理铝基柔性线路板的流程图;FIG. 2 shows a flow chart of obtaining and processing an aluminum-based flexible circuit board in an embodiment of the present invention;

图3示出了本发明实施例中对处理铝基柔性线路板预上锡基钎料之前的步骤的流程图;FIG. 3 shows a flow chart of the steps before processing the aluminum-based flexible circuit board with tin-based solder in an embodiment of the present invention;

图4-1示出了本发明实施例中目标铝基柔性线路板的SEM表面形貌图;4-1 shows the SEM surface topography of the target aluminum-based flexible circuit board in the embodiment of the present invention;

图4-2示出了图4-1中虚线框部分的放大图;Figure 4-2 shows an enlarged view of the dashed box in Figure 4-1;

图5示出了本发明实施例中目标铝基柔性线路板的剖视面结构模型图;5 shows a cross-sectional structural model diagram of a target aluminum-based flexible circuit board in an embodiment of the present invention;

图6示出了本发明实施例中对目标铝基柔性线路板和待焊接元器件进行激光锡焊的流程图;6 shows a flowchart of laser soldering a target aluminum-based flexible circuit board and components to be welded in an embodiment of the present invention;

图7示出了本发明实施例中激光锡焊的模型图。FIG. 7 shows a model diagram of laser soldering in an embodiment of the present invention.

各附图标记说明如下:The description of each reference number is as follows:

100、目标铝基柔性线路板,110、原始铝基柔性线路板,120、镍层,130、锡基钎料,200、待焊接元器件,210、铜引脚,300、激光焊接设备,310、激光器,311、激光斑,320、送丝器,321、焊丝。100, target aluminum-based flexible circuit board, 110, original aluminum-based flexible circuit board, 120, nickel layer, 130, tin-based solder, 200, components to be welded, 210, copper pins, 300, laser welding equipment, 310 , Laser, 311, laser spot, 320, wire feeder, 321, welding wire.

具体实施方式Detailed ways

为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purposes, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments These are some embodiments of the present invention, but not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative efforts shall fall within the protection scope of the present invention.

本发明实施例提供了一种铝基柔性线路板与元器件的焊接方法,如图1所示,包括:An embodiment of the present invention provides a welding method for an aluminum-based flexible circuit board and components, as shown in FIG. 1 , including:

S10,对原始铝基柔性线路板进行表面处理,得到处理铝基柔性线路板;S10, performing surface treatment on the original aluminum-based flexible circuit board to obtain a treated aluminum-based flexible circuit board;

S20,对所述处理铝基柔性线路板预上锡基钎料,得到目标铝基柔性线路板;S20, pre-applying tin-based solder to the treated aluminum-based flexible circuit board to obtain a target aluminum-based flexible circuit board;

S30,对所述目标铝基柔性线路板和待焊接元器件进行激光锡焊,完成焊接。S30, laser soldering is performed on the target aluminum-based flexible circuit board and the components to be welded to complete the welding.

具体地,在本实施例S10中,选用100μm的铝基柔性线路板(其中的聚酰亚胺薄膜厚20μm)作为原始铝基柔性线路板进行表面处理。Specifically, in this embodiment S10 , a 100 μm aluminum-based flexible circuit board (with a polyimide film thickness of 20 μm) is selected as the original aluminum-based flexible circuit board for surface treatment.

优选地,如图2所示,步骤S10包括:Preferably, as shown in Figure 2, step S10 includes:

S101:依次对所述原始铝基柔性线路板进行除油处理和碱蚀处理,得到第一铝基柔性线路板;S101: Perform degreasing treatment and alkali etching treatment on the original aluminum-based flexible circuit board in sequence to obtain a first aluminum-based flexible circuit board;

S102:采用纯净水,对所述第一铝基柔性线路板进行清洗,得到第二铝基柔性线路板;S102: using pure water to clean the first aluminum-based flexible circuit board to obtain a second aluminum-based flexible circuit board;

S103:对所述第二铝基柔性线路板进行化学浸锌,得到第三铝基柔性线路板;S103: chemically dipping the second aluminum-based flexible circuit board to obtain a third aluminum-based flexible circuit board;

S104:对所述第三铝基柔性线路板进行镀镍,得到所述处理铝基柔性线路板。S104: Perform nickel plating on the third aluminum-based flexible circuit board to obtain the treated aluminum-based flexible circuit board.

依次进行除油处理和碱蚀处理,能去除原始铝基柔性线路板表面的金属氧化膜,进而避免惰性的金属氧化膜所带来的不利影响,便于使得元器件和铝基柔性线路板能形成无缺陷、性能优异的焊接接头;通过纯净水的清洗,能清洗第一铝基柔性线路板表面残留的碱性溶液,同时清洗后得到的第二铝基柔性线路板表面残留有水膜,能最大可能隔绝铝表面与空气接触生成新的氧化膜;通过化学浸锌,能进一步保证得到的第三铝基柔性线路板表面为Zn层而不是Al2O3氧化膜,将铝基柔性线路板表面上的Al2O3氧化膜完全消除并形成隔断层阻止Al2O3氧化膜的形成,进一步有效避免金属氧化膜所带来的不利影响;通过在第三铝基柔性线路板表面镀镍,能保证经表面处理后最终得到的处理铝基柔性线路板的表面具有良好的结合力,有助于元器件和铝基柔性线路板能形成无缺陷、性能优异的焊接接头。Degreasing treatment and alkaline etching treatment are carried out in sequence to remove the metal oxide film on the surface of the original aluminum-based flexible circuit board, thereby avoiding the adverse effects of the inert metal oxide film, which is convenient for the formation of components and aluminum-based flexible circuit boards. Solder joints with no defects and excellent performance; through the cleaning of pure water, the residual alkaline solution on the surface of the first aluminum-based flexible circuit board can be cleaned, and at the same time, the surface of the second aluminum-based flexible circuit board obtained after cleaning It is possible to isolate the aluminum surface from contact with the air to generate a new oxide film; through chemical galvanization, it can further ensure that the surface of the third aluminum-based flexible circuit board obtained is a Zn layer instead of an Al 2 O 3 oxide film, and the aluminum-based flexible circuit board The Al 2 O 3 oxide film on the surface is completely eliminated and a barrier layer is formed to prevent the formation of the Al 2 O 3 oxide film, further effectively avoiding the adverse effects of the metal oxide film; by plating nickel on the surface of the third aluminum-based flexible circuit board , which can ensure that the surface of the aluminum-based flexible circuit board finally obtained after surface treatment has a good bonding force, which helps components and aluminum-based flexible circuit boards to form defect-free and excellent performance welding joints.

具体地,在本实施例S101中,选用酒精或丙酮对原始铝基柔性线路板进行除油处理,选用20%NaOH溶液进行浸泡3-5min对除油处理后的原始铝基柔性线路板进行浸泡,浸泡时间为3~5min,完成碱蚀处理。在本实施例S102中,当原始铝基柔性线路板进行除油处理和碱蚀处理后,将得到的第一铝基柔性线路板立即放入纯净水中,能清洗表面残留的20%NaOH溶液,此时铝基柔性线路板表面残留有水膜能最大可能隔绝铝表面与空气接触生成新的氧化膜。在本实施例S103中,当清洗后得到的第二铝基柔性线路板立即放进锌酸盐溶液中进行化学浸锌,锌酸盐溶液的浓度比例可以根据实际情况设置和调整。Specifically, in this embodiment S101, alcohol or acetone is used to degreasing the original aluminum-based flexible circuit board, and 20% NaOH solution is selected to soak for 3-5 minutes to soak the original aluminum-based flexible circuit board after the degreasing treatment. , the soaking time is 3 to 5 minutes, and the alkaline etching treatment is completed. In the present embodiment S102, after the original aluminum-based flexible circuit board is subjected to degreasing treatment and alkali etching treatment, the obtained first aluminum-based flexible circuit board is immediately put into pure water, which can clean the 20% NaOH solution remaining on the surface. At this time, the residual water film on the surface of the aluminum-based flexible circuit board can isolate the aluminum surface from contact with the air to the greatest extent and form a new oxide film. In this embodiment S103, the second aluminum-based flexible circuit board obtained after cleaning is immediately put into a zincate solution for chemical immersion zinc, and the concentration ratio of the zincate solution can be set and adjusted according to the actual situation.

其中,化学浸锌的化学反应方程式为:2Al+3Zn2+→3Zn+2Al3+Among them, the chemical reaction equation of chemical immersion zinc is: 2Al+3Zn 2+ →3Zn+2Al 3+ .

具体地,在本实施例S104中,镀镍的厚度范围为4~7μm,优选地,镀镍的厚度范围为5~6μm。Specifically, in the present embodiment S104, the thickness of the nickel plating is in the range of 4-7 μm, and preferably, the thickness of the nickel plating is in the range of 5-6 μm.

按照上述厚度范围进行镀镍,一方面能保证铝基柔性线路板表面的Ni镀层具有良好的结合力,另一方面能避免大厚度的Ni镀层会带来成本增加。According to the above thickness range, nickel plating can ensure that the Ni plating layer on the surface of the aluminum-based flexible circuit board has good bonding force, and on the other hand, it can avoid the cost increase caused by the large thickness of the Ni plating layer.

优选地,如图3所示,在S20之前,还包括:Preferably, as shown in FIG. 3, before S20, it also includes:

S201:对所述处理铝基柔性线路板进行超声清洗;S201: performing ultrasonic cleaning on the treated aluminum-based flexible circuit board;

S202:对超声清洗后的所述处理铝基柔性线路板进行晾干处理。S202 : drying the treated aluminum-based flexible circuit board after ultrasonic cleaning.

具体地,在本实施例S201中,采用无水乙醇对处理铝基柔性线路板进行超声清洗,能保证处理铝基柔性线路板表面的镍膜的完整度和清洁度。Specifically, in the present embodiment S201, using absolute ethanol to ultrasonically clean the processed aluminum-based flexible circuit board can ensure the integrity and cleanliness of the nickel film on the surface of the processed aluminum-based flexible circuit board.

具体地,在本实施例S20中,所述锡基钎料的厚度范围为15~20μm。Specifically, in the present embodiment S20, the thickness of the tin-based solder is in the range of 15-20 μm.

为了保证铝基柔性线路板具有一定的刚性,常常在其背面贴上一层聚酰亚胺板(即PI板),本实施例通过上述厚度范围的锡基钎料,一方面能保证锡基钎料吸收激光辐射的热量,使得热量传导至PI板时不至于使得PI板发生变色;另一方面能避免大厚度的锡基钎料所带来成本增加,也会避免增加钎料凝固不均匀性以及增加激光辐射时间,从而确保焊接的高效性。In order to ensure that the aluminum-based flexible circuit board has a certain rigidity, a layer of polyimide board (ie PI board) is often attached to the back of the board. In this embodiment, the tin-based solder in the above thickness range can ensure the tin-based The solder absorbs the heat of the laser radiation, so that the heat will not cause discoloration of the PI board when the heat is transmitted to the PI board; on the other hand, it can avoid the increase in cost caused by the large thickness of tin-based solder, and also avoid increasing the uneven solidification of the solder. and increase the laser irradiation time, thus ensuring the high efficiency of welding.

更具体地,本实施例镀镍的厚度选用5μm,锡基钎料选择SAC305,厚度为18μm。如图4-1和图4-2所示,图4-1为分别镀上5μm镍层和18μm锡基钎料之后的目标铝基柔性线路板的SEM(扫描电子显微镜)表面形貌图,图4-2为图4-1中虚线框的放大图。通过观察扫描电子显微镜得到的表面形貌图,可以发现镀上5μm镍层之后,镍层沿着铝上侧均匀平整分布且未出现黑镍现象。镀上18μm锡基钎料之后,整个锡层由大小形状不一的锡晶粒组成,整个锡层在镍层上均匀平整分布,未出现裂纹、孔洞等缺陷。More specifically, the thickness of nickel plating in this embodiment is 5 μm, and the tin-based solder is SAC305, and the thickness is 18 μm. As shown in Figure 4-1 and Figure 4-2, Figure 4-1 is the SEM (Scanning Electron Microscope) surface topography of the target aluminum-based flexible circuit board after plating with 5μm nickel layer and 18μm tin-based solder, respectively. Figure 4-2 is an enlarged view of the dotted box in Figure 4-1. By observing the surface topography image obtained by scanning electron microscope, it can be found that after plating a 5 μm nickel layer, the nickel layer is evenly distributed along the upper side of the aluminum and there is no black nickel phenomenon. After plating 18μm tin-based solder, the entire tin layer is composed of tin grains of different sizes and shapes. The entire tin layer is evenly distributed on the nickel layer, and there are no defects such as cracks and holes.

本实施例经表面处理、镀镍和镀锡基钎料后得到的目标铝基柔性线路板100的模型图如图5所示,在图5中,原始铝基柔性线路板110表面镀有镍层120,镍层120上镀有锡基钎料130。The model diagram of the target aluminum-based flexible circuit board 100 obtained after surface treatment, nickel-plating and tin-based soldering in this embodiment is shown in FIG. 5 . In FIG. 5 , the surface of the original aluminum-based flexible circuit board 110 is plated with nickel. The nickel layer 120 is plated with a tin-based solder 130 .

优选地,如图6所示,S30包括:Preferably, as shown in Figure 6, S30 includes:

S301:对所述目标铝基柔性线路板进行固定;S301: Fix the target aluminum-based flexible circuit board;

S302:将所述待焊接元器件的引脚放置在固定后的所述目标铝基柔性线路板的上方,并对所述待焊接元器件进行固定;S302: Place the pins of the components to be welded above the fixed target aluminum-based flexible circuit board, and fix the components to be welded;

S303:采用激光锡焊设备,对固定后的所述目标铝基柔性线路板和固定后的所述待焊接元器件的引脚进行焊接。S303: Use laser soldering equipment to weld the fixed target aluminum-based flexible circuit board and the fixed pins of the component to be welded.

具体地,本实施例中激光焊接的模型图如图7所示,在图7中,激光锡焊设备300为德国Dr.Mergenthaler GmbH&Co.KG公司生产的,环形光源直径为0.7mm,包括激光器310和送丝器320。激光器310为半导体激光器,满功率为60W,波长为970nm,半导体激光器发出的激光斑311与待焊接元器件200的铜引脚210中心重合。送丝器320提供焊丝321,焊丝为锡基焊丝,焊丝的直径范围为0.3~0.6mm;更具体地,锡基焊丝选用0.3mm的lead-free F3 M705(Sn-3Ag-0.5Cu)焊丝。其中,送丝器320选用现有的送丝器,具体细节此处不再赘述。Specifically, the model diagram of laser welding in this embodiment is shown in FIG. 7 . In FIG. 7 , the laser soldering equipment 300 is produced by Dr. Mergenthaler GmbH & Co. KG in Germany. The diameter of the ring light source is 0.7 mm, including the laser 310 and wire feeder 320. The laser 310 is a semiconductor laser with a full power of 60W and a wavelength of 970nm. The laser spot 311 emitted by the semiconductor laser coincides with the center of the copper pin 210 of the component 200 to be welded. The wire feeder 320 provides the welding wire 321, the welding wire is a tin-based welding wire, and the diameter of the welding wire is 0.3-0.6 mm; more specifically, the tin-based welding wire is a lead-free F3 M705 (Sn-3Ag-0.5Cu) welding wire of 0.3 mm. The wire feeder 320 is an existing wire feeder, and details are not repeated here.

利用焊接卡具将目标铝基柔性线路板固定在工作台上,待焊接元器件为8-SOIC(0.154"、3.90mm宽)的通用放大器,将待焊接元器件需要焊接的引脚放置在目标铝基柔性线路板的预上锡基钎料的位置上方,并用焊接卡具固定住,防止焊接过程中发生偏离。待焊接元器件通常有多个引脚需要与目标铝基柔性线路板进行焊接,在每个引脚的焊接过程中,均需要将所述激光焊接设备发出的激光光斑与所述待焊接元器件的引脚中心重合,进而保证良好的焊接效果。其中,焊接卡具为现有的焊接工具,具体细节此处不再赘述。Use a soldering fixture to fix the target aluminum-based flexible circuit board on the workbench. The components to be soldered are 8-SOIC (0.154", 3.90mm wide) general-purpose amplifiers. Place the pins to be soldered on the target The aluminum-based flexible circuit board is placed above the position of the pre-tin-based solder, and fixed with a welding fixture to prevent deviation during the welding process. The components to be welded usually have multiple pins that need to be welded with the target aluminum-based flexible circuit board. , in the welding process of each pin, the laser spot emitted by the laser welding equipment needs to be overlapped with the center of the pin of the component to be welded, so as to ensure a good welding effect. For some welding tools, the specific details will not be repeated here.

在激光锡焊过程中,半导体激光器先启动辐射对待焊接元器件的引脚进行升温预热处理,随后锡基焊丝在送丝器的作用下送进,并在半导体激光器所发出激光的辐射下熔化形成熔滴滴落在待焊接元器件的铜引脚上,熔滴形成滴落的同时,锡基焊丝在送丝器的回抽作用下回抽,半导体激光器同时关闭,焊接完成。In the process of laser soldering, the semiconductor laser first starts the radiation to heat up and preheat the pins of the components to be welded, and then the tin-based welding wire is fed under the action of the wire feeder and melted under the radiation of the laser emitted by the semiconductor laser. The formed droplets fall on the copper pins of the components to be welded. At the same time as the droplets form and drop, the tin-based welding wire is pulled back under the pullback action of the wire feeder, the semiconductor laser is turned off at the same time, and the welding is completed.

在上述激光锡焊过程中,熔化的锡基焊丝形成熔滴滴落在铜引脚上,通过热传导将热量进一步传递至引脚下方的锡基钎料,使得钎料发生熔化并分别与引脚和镍层形成良好的冶金结合,最终可以获得优质的元器件和铝基柔性线路板焊接接头。获得的焊接接头的力学性能取决于镍层与铝基柔性线路板的结合能力以及焊丝发生熔化融化后与镍层和引脚形成的冶金结合能力,根本上解决铝基柔性线路板表面惰性氧化膜带来的不利影响,使元器件和铝基柔性线路板能形成无缺陷、性能优异的焊接接头。In the above-mentioned laser soldering process, the molten tin-based welding wire forms droplets and drops on the copper pins, and the heat is further transferred to the tin-based solder under the pins through thermal conduction, so that the solder melts and separates with the pins. It forms a good metallurgical combination with the nickel layer, and finally can obtain high-quality components and welding joints of aluminum-based flexible circuit boards. The mechanical properties of the obtained welded joint depend on the bonding ability of the nickel layer and the aluminum-based flexible circuit board and the metallurgical bonding ability of the welding wire with the nickel layer and the pins after melting, which fundamentally solves the problem of the inert oxide film on the surface of the aluminum-based flexible circuit board. The adverse effects brought about by the components and aluminum-based flexible circuit boards can form defect-free and excellent solder joints.

优选地,在S303中,还包括:Preferably, in S303, it also includes:

采用红外温度检测设备,实时检测所述目标铝基柔性线路板与所述待焊接元器件的引脚之间的焊接温度;其中,所述焊接温度小于500℃。Infrared temperature detection equipment is used to detect the welding temperature between the target aluminum-based flexible circuit board and the pins of the component to be welded in real time; wherein, the welding temperature is less than 500°C.

通过实时检测目标铝基柔性线路板与待焊接元器件的引脚之间的焊接温度,并要求焊接温度小于500℃,能确保在激光锡焊过程中,充分考虑PI板的温度承受范围及整个铝基柔性线路板的温度敏感性范围,避免出现激光烧蚀形成缺陷而降低柔性线路板的服役安全性能。By detecting the welding temperature between the target aluminum-based flexible circuit board and the pins of the components to be welded in real time, and requiring the welding temperature to be less than 500 °C, it can ensure that the temperature tolerance range of the PI board and the entire The temperature sensitivity range of aluminum-based flexible circuit boards can avoid laser ablation to form defects and reduce the service safety performance of flexible circuit boards.

在一个具体实施例中,S303中的整个激光焊接过程分为五个步骤。第一步是激光开始辐照待焊接元件的铜引脚,并在0.1s内将圆形激光辐照区域内的温度提至T1;第二步是激光持续辐照,使得圆形激光辐照区域内的温度在T1下的保持时长为t1,实现预热;第三步是激光继续辐照,并使得圆形激光辐照区域内的温度在t1内,由T1提升到峰值温度T2;第四步是激光持续辐照,使得圆形激光辐照区域内的温度在T2下的保持时长为t2,与此同时送丝器开始送丝;第五步是当时间到t3时,送丝停止且激光停止辐照完成焊接。经过多组试验发现,当峰值温度T2≥500℃时,铝基柔性线路板底部PI板由于热传导的作用极易发生变色,如下表所示。因此实际激光锡焊过程中的焊接温度应小于500℃。In a specific embodiment, the entire laser welding process in S303 is divided into five steps. The first step is that the laser starts to irradiate the copper pins of the component to be welded, and the temperature in the circular laser irradiation area is raised to T1 within 0.1s; the second step is the continuous laser irradiation, so that the circular laser irradiation The temperature in the area is maintained for t1 under T1 to achieve preheating; the third step is to continue to irradiate the laser, and make the temperature in the circular laser irradiation area within t1, from T1 to the peak temperature T2; The fourth step is to continuously irradiate the laser, so that the temperature in the circular laser irradiation area is maintained at T2 for a length of t2, and at the same time, the wire feeder starts to feed the wire; the fifth step is to stop the wire feeding when the time reaches t3. And the laser stops irradiating to complete the welding. After several sets of tests, it was found that when the peak temperature T2 ≥ 500 °C, the PI board at the bottom of the aluminum-based flexible circuit board is prone to discoloration due to thermal conduction, as shown in the following table. Therefore, the welding temperature in the actual laser soldering process should be less than 500 °C.

表 不同峰值温度下铝基柔性线路板底部PI板变色Table Discoloration of the PI board at the bottom of the aluminum-based flexible circuit board at different peak temperatures

Figure BDA0003528316180000091
Figure BDA0003528316180000091

Figure BDA0003528316180000101
Figure BDA0003528316180000101

具体地,本实施例S303中,选择合适的参数进行激光锡焊,包括T1=140℃,T2=342℃,t1=0.1s,t2=0.36s,t3=0.66s。在该参数下,按照本发明所述的步骤镀镍和镀锡基钎料,并对铝基柔性线路板与待焊接元器件激光锡焊接头上表面成形和横截面形貌进行对比观察。结果发现,表面未镀锡的锡基钎料未向铜引脚四周铺展连接,而是在铜引脚上凝固团缩成圆球状,铜引脚与铝基柔性线路板未形成有效连接,整个锡基钎料团聚在铜引脚上,没有完全铺展润湿;而镀锡铝基柔性线路板与待焊接元器件则形成有效连接,整个锡基钎料并没有团聚收缩在铜引脚上,而是在铝基板和铜引脚上完全润湿铺展开。Specifically, in this embodiment S303, suitable parameters are selected for laser soldering, including T1=140°C, T2=342°C, t1=0.1s, t2=0.36s, t3=0.66s. Under this parameter, nickel-plating and tin-plating-based solder were performed according to the steps of the present invention, and the upper surface forming and cross-sectional morphology of the aluminum-based flexible circuit board and the laser tin welding joint of the components to be welded were compared and observed. It was found that the tin-based solder without tin plating on the surface did not spread and connect around the copper pins, but solidified and shrunk into a spherical shape on the copper pins, and the copper pins did not form an effective connection with the aluminum-based flexible circuit board. The tin-based solder is agglomerated on the copper pins and does not fully spread and wet; while the tin-plated aluminum-based flexible circuit board forms an effective connection with the components to be soldered, and the entire tin-based solder does not agglomerate and shrink on the copper pins. Instead, it is fully wetted and spread on the aluminum substrate and copper pins.

虽然结合附图描述了本发明的实施例,但是本领域技术人员可以在不脱离本发明的精神和范围的情况下作出各种修改和变型,这样的修改和变型均落入由所附权利要求所限定的范围之内。Although the embodiments of the present invention have been described in conjunction with the accompanying drawings, various modifications and variations can be made by those skilled in the art without departing from the spirit and scope of the present invention, such modifications and variations falling within the scope of the appended claims within the limited range.

Claims (10)

1. A method for welding an aluminum-based flexible circuit board and a component is characterized by comprising the following steps:
carrying out surface treatment on the original aluminum-based flexible circuit board to obtain a treated aluminum-based flexible circuit board;
pre-coating tin-based brazing filler metal on the treated aluminum-based flexible circuit board to obtain a target aluminum-based flexible circuit board;
and carrying out laser soldering on the target aluminum-based flexible circuit board and the component to be welded to finish welding.
2. The method for welding the aluminum-based flexible circuit board and the component as claimed in claim 1, wherein the surface treatment of the original aluminum-based flexible circuit board comprises:
sequentially carrying out oil removal treatment and alkaline etching treatment on the original aluminum-based flexible circuit board to obtain a first aluminum-based flexible circuit board;
and cleaning the first aluminum-based flexible circuit board by adopting purified water to obtain a second aluminum-based flexible circuit board.
3. The method for soldering the aluminum-based flexible circuit board and the component as claimed in claim 2, further comprising, after the first aluminum-based flexible circuit board is cleaned:
chemically zincating the second aluminum-based flexible circuit board to obtain a third aluminum-based flexible circuit board;
and carrying out nickel plating on the third aluminum-based flexible circuit board to obtain the treated aluminum-based flexible circuit board.
4. The method for welding the aluminum-based flexible circuit board and the component as claimed in claim 3, wherein the thickness of the nickel plating is 5-6 μm.
5. A method for soldering an al-based flexible wiring board and a component as claimed in claim 1, wherein before the pre-application of the tin-based solder to the processed al-based flexible wiring board, the method further comprises:
carrying out ultrasonic cleaning on the aluminum-based flexible circuit board to be treated;
and carrying out air drying treatment on the aluminum-based flexible circuit board after ultrasonic cleaning.
6. The method for welding the aluminum-based flexible circuit board and the component as claimed in claim 1, wherein the thickness of the tin-based solder is in a range of 15 to 20 μm.
7. The method for welding the aluminum-based flexible circuit board and the component according to claim 1, wherein the laser soldering of the target aluminum-based flexible circuit board and the component to be welded comprises:
fixing the target aluminum-based flexible circuit board;
placing the pin of the component to be welded above the fixed target aluminum-based flexible circuit board, and fixing the component to be welded;
and welding the fixed target aluminum-based flexible circuit board and the fixed pin of the component to be welded by adopting laser soldering equipment.
8. The method for welding the aluminum-based flexible circuit board and the component as claimed in claim 7, wherein a laser spot emitted by the laser welding equipment coincides with the center of a pin of the component to be welded.
9. The welding method of the aluminum-based flexible circuit board and the component as claimed in claim 7, wherein the diameter range of the welding wire provided by the laser welding equipment is 0.3-0.6 mm.
10. The method for soldering the aluminum-based flexible circuit board and the component according to claim 7, wherein in soldering the target aluminum-based flexible circuit board and the pin of the component to be soldered, the method further comprises:
detecting the welding temperature between the target aluminum-based flexible circuit board and the pin of the component to be welded in real time by adopting infrared temperature detection equipment; wherein the welding temperature is less than 500 ℃.
CN202210198753.2A 2022-03-02 2022-03-02 Welding method for aluminum-based flexible circuit board and component Pending CN114406391A (en)

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