CN114342931A - Improved method of solid chlorine preparation with fragrance - Google Patents
Improved method of solid chlorine preparation with fragrance Download PDFInfo
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- CN114342931A CN114342931A CN202210021550.6A CN202210021550A CN114342931A CN 114342931 A CN114342931 A CN 114342931A CN 202210021550 A CN202210021550 A CN 202210021550A CN 114342931 A CN114342931 A CN 114342931A
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- solid chlorine
- chlorine
- formulation
- fragrance
- solid
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 79
- 239000000460 chlorine Substances 0.000 title claims abstract description 79
- 239000007787 solid Substances 0.000 title claims abstract description 64
- 239000003205 fragrance Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 42
- 239000004094 surface-active agent Substances 0.000 claims abstract description 32
- 238000009472 formulation Methods 0.000 claims abstract description 28
- 239000007844 bleaching agent Substances 0.000 claims abstract description 15
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 10
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims abstract description 7
- 239000002304 perfume Substances 0.000 claims abstract description 7
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 12
- -1 quaternary ammonium salt compound Chemical class 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 9
- 230000009471 action Effects 0.000 claims description 7
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 6
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims description 4
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 4
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 3
- FAQVGPWFQGGIPP-UHFFFAOYSA-N 2-(2-methylpropyl)quinoline Chemical compound C1=CC=CC2=NC(CC(C)C)=CC=C21 FAQVGPWFQGGIPP-UHFFFAOYSA-N 0.000 claims description 3
- OMJKWVKPIOIQDM-UHFFFAOYSA-N 3-bromo-1-chloroimidazolidine-2,4-dione Chemical compound ClN1CC(=O)N(Br)C1=O OMJKWVKPIOIQDM-UHFFFAOYSA-N 0.000 claims description 3
- MENYRYNFSIBDQN-UHFFFAOYSA-N 5,5-dibromoimidazolidine-2,4-dione Chemical compound BrC1(Br)NC(=O)NC1=O MENYRYNFSIBDQN-UHFFFAOYSA-N 0.000 claims description 3
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 3
- 125000004076 pyridyl group Chemical group 0.000 claims description 3
- 239000011833 salt mixture Substances 0.000 claims description 3
- 229950009390 symclosene Drugs 0.000 claims description 3
- JWMKUKRBNODZFA-UHFFFAOYSA-N 1-ethoxy-2-methylbenzene Chemical compound CCOC1=CC=CC=C1C JWMKUKRBNODZFA-UHFFFAOYSA-N 0.000 claims description 2
- NUKAPDHENUQUOI-UHFFFAOYSA-N benzyl(18-methylnonadecyl)azanium;chloride Chemical compound [Cl-].CC(C)CCCCCCCCCCCCCCCCC[NH2+]CC1=CC=CC=C1 NUKAPDHENUQUOI-UHFFFAOYSA-N 0.000 claims description 2
- 230000007774 longterm Effects 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 3
- 230000001590 oxidative effect Effects 0.000 abstract description 2
- ZETHHMPKDUSZQQ-UHFFFAOYSA-N Betulafolienepentol Natural products C1C=C(C)CCC(C(C)CCC=C(C)C)C2C(OC)OC(OC)C2=C1 ZETHHMPKDUSZQQ-UHFFFAOYSA-N 0.000 description 4
- HEOKFDGOFROELJ-UHFFFAOYSA-N diacetal Natural products COc1ccc(C=C/c2cc(O)cc(OC3OC(COC(=O)c4cc(O)c(O)c(O)c4)C(O)C(O)C3O)c2)cc1O HEOKFDGOFROELJ-UHFFFAOYSA-N 0.000 description 4
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PCSMJKASWLYICJ-UHFFFAOYSA-N Succinic aldehyde Chemical compound O=CCCC=O PCSMJKASWLYICJ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention relates to the technical field of solid chlorine preparations, in particular to an improvement method of a fragrant solid chlorine preparation, which comprises the following steps: using a quaternary ammonium salt as a stabilizing surfactant for the perfume, which upon curing is intimately mixed with a solid chlorine formulation, the stabilizing surfactant protecting the perfume from the strong oxidizing and acid-base effects of chlorine-containing bleaching agents; the invention provides an aromatic solid chlorine preparation composition by providing an improvement method of a solid chlorine preparation, which has the advantages of long-term stable storage and certain fragrance to cover the chlorine smell of the solid chlorine preparation, solves the problems that the currently used solid chlorine preparation usually has no fragrance and cannot be used stably for a long time, ensures that the strength of the solid chlorine preparation cannot be weakened along with the time, and the fragrance property cannot be changed after long-term storage.
Description
Technical Field
The invention relates to the technical field of solid chlorine preparations, in particular to an improvement method of a fragrant solid chlorine preparation.
Background
The solid chlorine preparation is also called chlorine-containing bleaching agent, and is a chemical product for removing and lightening color or disinfecting and sterilizing through oxidation-reduction reaction. When the essence is added into the solid chlorine preparation, the emulsification and dispersion functions of the surfactant are required to be used, and the selected surfactant must be an inert dispersant which is not influenced by strong oxidation and acid-base action of the bleaching agent or is not substantially influenced, so that the surfactant is used as the surfactant. Secondly, it is necessary to use perfume or fragrance compositions which are also unaffected by oxidation of the bleaching agent. If the surfactant or fragrance is not stable in the presence of the solid chlorine formulation, the fragrance effect disappears. Another more serious problem is that the halogen-containing bleaching agents are easily reacted with and consumed by external additives, resulting in the reduction of the oxidation, bleaching and sterilizing strength of the chlorine preparations.
Since most of fragrance compositions resist oxidative destruction of chlorine by the chemical method, chlorine preparations on the market also have great limitations in use of solid chlorine preparations because the long-term stability of fragrance cannot be solved, the strength of the chlorine preparations is easily weakened with time, and the fragrance characteristics are easily changed after long-term storage.
Disclosure of Invention
It is an object of the present invention to provide an improved method of providing a flavoured solid chlorine formulation to address the problems set forth in the background above. ' Qiyi
In order to achieve the purpose, the invention provides the following technical scheme: an improved method of providing a flavored solid chlorine preparation, the method comprising the steps of:
s1: using quaternary ammonium salt as a stable surfactant of essence to prepare a stable surfactant containing fragrance, thereby obtaining a solid chlorine preparation composition with fragrance;
s2: a fragrance-containing stabilizing surfactant is uniformly dispersed in a solid chlorine formulation, the stabilizing surfactant protects the fragrance from strong oxidation and acid-base action of the chlorine-containing bleach, forming a stable solid combination to provide a solid chlorine-containing formulation containing a stable fragrance to mask the chlorine taste.
Preferably, in the step S1, the content of the essence is between 10 and 30 percent, and the content of the quaternary ammonium salt compound is between 70 and 90 percent.
Preferably, in step S2, the solid chlorine-containing formulation includes halogen-containing bleaching agents such as trichloroisocyanuric acid, sodium dichloroisocyanurate, calcium hypochlorite, bromochlorohydantoin, and dibromohydantoin.
Preferably, in the step S1, in the molecular expression of the perfume stabilizing surfactant, R1 is an alkyl group or an aromatic group containing 1 to 20 carbon atoms, R2 is selected from an alkyl group and an aromatic group containing 1 to 14 carbon atoms, a cycloalkyl group containing 5 to 18 carbon atoms, an alkyl group containing 7 to 10 carbon atoms, a pyridyl group and X, selected from fluorine, chlorine, chloride, nitrate, methyl sulfate, chlorate, hydroxide and X, by R7, n is 1 or 2 and is equal to X valence.
Preferably, the quaternary ammonium salt compound in the solid chlorine-containing formulation comprises cetyltrimethylammonium chloride.
Preferably, the quaternary ammonium compound in the solid chlorine-containing formulation comprises dodecyltrimethylammonium chloride.
Preferably, in said step S1, typical quaternary ammonium salts in the chlorine-containing bleach composition are cetyltrimethylammonium chloride, dodecyltrimethylammonium chloride, pentaalkyltriethylammonium chloride, dimethylstearylbenzylammonium chloride, tetramethyltrimethylammonium chloride, cetyltrimethylammonium chloride and mixtures of these materials.
Preferably, in step S1, the special essence includes 1, 8-xinol, 2-isobutylquinoline, di-diphenyl ether, benzophenone, diphenyl ether, diacetal ethyl acetyl, diphenyl ether, dimethyl ether, diacetal acetyl, diphenyl ether, 3, 4, 6, 7, 8-hexamethyl-2-2-anisole and methyl phenetole.
Preferably, in step S1, the fragrance-containing stable surfactant contains 10-30% of essence, and the stable surfactant is a quaternary ammonium salt mixture. .
Preferably, in step S1, the content of the odorous solid stable surfactant is between 0.05 and 0.15% by weight of the solid chlorine preparation.
Compared with the prior art, the invention has the following beneficial effects:
the invention provides a solid chlorine preparation composition with fragrance, which has the advantages of long-term stable storage, certain fragrance and capability of covering the chlorine odor of the solid chlorine preparation, solves the problems that the conventional solid chlorine preparation usually has no fragrance and cannot be used stably for a long time, ensures that the strength of the solid chlorine preparation cannot be weakened along with the time, and ensures that the fragrance property cannot be changed after long-term storage, thereby improving the using effect of a bleaching agent or a disinfectant.
Drawings
Fig. 1 is a molecular structure expression of the perfume stability surfactant of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example (b):
an improved method of providing a flavored solid chlorine preparation, the method comprising the steps of:
s1: using quaternary ammonium salt as a stable surfactant of essence to prepare a stable surfactant containing fragrance, thereby obtaining a solid chlorine preparation composition with fragrance;
s2: a fragrance-containing stabilizing surfactant is uniformly dispersed in a solid chlorine formulation, the stabilizing surfactant protects the fragrance from strong oxidation and acid-base action of the chlorine-containing bleach, forming a stable solid combination to provide a solid chlorine-containing formulation containing a stable fragrance to mask the chlorine taste.
In the embodiment, the content of the essence is 10-30%, and the content of the quaternary ammonium salt compound is 70-90%.
In this example, the solid chlorine-containing formulation includes halogen-containing bleaches such as trichloroisocyanuric acid, sodium dichloroisocyanurate, calcium hypochlorite, bromochlorohydantoin, and dibromohydantoin.
In the embodiment, R1 in the molecular expression of the perfume stability surfactant is alkyl or aryl containing 1-20 carbon atoms, R2 is selected from alkyl and aryl containing 1-14 carbon atoms, cycloalkyl containing 5-18 carbon atoms, alkyl containing 7-10 carbon atoms, pyridyl and X through R7, and is selected from fluorine, chlorine, chloride, nitrate, methyl sulfate, chlorate, hydroxide and X, n is 1 or 2 and is equal to X valence.
In this example, the quaternary ammonium compound in the solid chlorine-containing formulation included cetyltrimethylammonium chloride.
In this example, the quaternary ammonium compound in the solid chlorine-containing formulation comprises dodecyltrimethylammonium chloride.
Typical quaternary ammonium salts in the chlorine-containing bleach compositions of this example are cetyltrimethylammonium chloride, dodecyltrimethylammonium chloride, pentaalkyltriethylammonium chloride, dimethylstearylacetylbenzylammonium chloride, tetramethyltrimethylammonium chloride, cetyltrimethylammonium chloride, and mixtures of these materials.
In this example, the special essence includes 1, 8-xinol, 2-isobutylquinoline, di-diphenyl ether, benzophenone, diphenyl ether, diacetal ethyl acetyl, diphenyl ether, dimethyl ether, diacetal, diphenyl ether, 3, 4, 6, 7, 8-hexamethyl-2-anisole, and methylphenylether.
In this embodiment, the fragrance-containing stable surfactant contains 10-30% of essence, and the stable surfactant is a quaternary ammonium salt mixture.
In this embodiment, the odoriferous solid stable surfactant is present in an amount of 0.05 to 0.15% by weight of the solid chlorine formulation.
The invention provides a solid chlorine preparation composition with fragrance, which has the advantages of long-term stable storage, certain fragrance and capability of covering the chlorine odor of the solid chlorine preparation, solves the problems that the conventional solid chlorine preparation usually has no fragrance and cannot be used stably for a long time, ensures that the strength of the solid chlorine preparation cannot be weakened along with the time, and ensures that the fragrance property cannot be changed after long-term storage, thereby improving the using effect of a bleaching agent or a disinfectant.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (10)
1. An improved method of providing a flavored solid chlorine formulation, comprising: the method comprises the following steps:
s1: using quaternary ammonium salt as a stable surfactant of essence to prepare a stable surfactant containing fragrance, thereby obtaining a solid chlorine preparation composition with fragrance;
s2: a fragrance-containing stabilizing surfactant is uniformly dispersed in a solid chlorine formulation, the stabilizing surfactant protects the fragrance from strong oxidation and acid-base action of the chlorine-containing bleach, forming a stable solid combination to provide a solid chlorine-containing formulation containing a stable fragrance to mask the chlorine taste.
2. The improved process of a flavored solid chlorine formulation as claimed in claim 1 wherein: in the step S1, the content of the essence is 10-30%, and the content of the quaternary ammonium salt compound is 70-90%.
3. The improved process of a flavored solid chlorine formulation as claimed in claim 1 wherein: in step S2, the solid chlorine-containing formulation includes halogen-containing bleaching agents such as trichloroisocyanuric acid, sodium dichloroisocyanurate, calcium hypochlorite, bromochlorohydantoin, and dibromohydantoin.
4. The improved process of a flavored solid chlorine formulation as claimed in claim 1 wherein: in the step S1, R1 in the molecular expression of the perfume stability surfactant is alkyl or aryl containing 1-20 carbon atoms, R2 is selected from alkyl and aryl containing 1-14 carbon atoms, cycloalkyl containing 5-18 carbon atoms, alkyl containing 7-10 carbon atoms, pyridyl and X, selected from fluorine, chlorine, chloride, nitrate, methyl sulfate, chlorate, hydroxide and X through R7, n is 1 or 2 and is equal to X valence.
5. The improved process of a flavored solid chlorine formulation as claimed in claim 4 wherein: the quaternary ammonium salt compound in the solid chlorine-containing preparation comprises hexadecyl trimethyl ammonium chloride.
6. The improved process of a flavored solid chlorine formulation as claimed in claim 4 wherein: the quaternary ammonium compound in the solid chlorine-containing formulation comprises dodecyl trimethyl ammonium chloride.
7. The improved process of a flavored solid chlorine formulation as claimed in claim 1 wherein: typical quaternary ammonium salts in the chlorine-containing bleach composition in said step S1 are cetyltrimethylammonium chloride, dodecyltrimethylammonium chloride, pentaalkyltriethylammonium chloride, dimethylstearylbenzylammonium chloride, tetramethyltrimethylammonium chloride, cetyltrimethylammonium chloride and mixtures of these materials.
8. The improved process of a flavored solid chlorine formulation as claimed in claim 1 wherein: in step S1, the special essence includes 1, 8-xinol, 2-isobutylquinoline, di-diphenyl ether, benzophenone, diphenyl ether, diacetal-ethyl acetyl, diphenyl ether, dimethyl ether, diethyl acetyl, diphenyl ether, 3, 4, 6, 7, 8-hexamethyl-2-2-anisole, and methyl phenetole.
9. The improved process of a flavored solid chlorine formulation as claimed in claim 1 wherein: in the step S1, the fragrance-containing stable surfactant contains 10-30% of essence, and the stable surfactant is a quaternary ammonium salt mixture.
10. The improved process of a flavored solid chlorine formulation as claimed in claim 1 wherein: in the step S1, the content of the fragrant solid stable surfactant is 0.05-0.15% by weight of the solid chlorine preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210021550.6A CN114342931A (en) | 2022-01-10 | 2022-01-10 | Improved method of solid chlorine preparation with fragrance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210021550.6A CN114342931A (en) | 2022-01-10 | 2022-01-10 | Improved method of solid chlorine preparation with fragrance |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202210021550.6A Pending CN114342931A (en) | 2022-01-10 | 2022-01-10 | Improved method of solid chlorine preparation with fragrance |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4954316A (en) * | 1987-10-03 | 1990-09-04 | Globus Alfred R | Stable, active chlorine containing anti-microbial compositions |
| CN1109097A (en) * | 1994-12-09 | 1995-09-27 | 陈晓和 | Three-in-one detergent and its production |
| CN103666790A (en) * | 2013-11-28 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Mould-proof shrink-proof cleaning agent for wool fabrics and preparation method of cleaning agent |
| CN104420397A (en) * | 2013-08-19 | 2015-03-18 | 天津市浩宇助剂有限公司 | Compounding papermaking bactericide |
| CN108603142A (en) * | 2016-02-12 | 2018-09-28 | 金诺斯公司 | Composition and method for surface cleaning |
| CN111972421A (en) * | 2019-05-21 | 2020-11-24 | 山东佳洁净水处理科技有限公司 | Fragrant chlorine-containing disinfection tablet |
-
2022
- 2022-01-10 CN CN202210021550.6A patent/CN114342931A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4954316A (en) * | 1987-10-03 | 1990-09-04 | Globus Alfred R | Stable, active chlorine containing anti-microbial compositions |
| CN1109097A (en) * | 1994-12-09 | 1995-09-27 | 陈晓和 | Three-in-one detergent and its production |
| CN104420397A (en) * | 2013-08-19 | 2015-03-18 | 天津市浩宇助剂有限公司 | Compounding papermaking bactericide |
| CN103666790A (en) * | 2013-11-28 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Mould-proof shrink-proof cleaning agent for wool fabrics and preparation method of cleaning agent |
| CN108603142A (en) * | 2016-02-12 | 2018-09-28 | 金诺斯公司 | Composition and method for surface cleaning |
| CN111972421A (en) * | 2019-05-21 | 2020-11-24 | 山东佳洁净水处理科技有限公司 | Fragrant chlorine-containing disinfection tablet |
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Application publication date: 20220415 |
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