CN114315292B - Solidification treatment process for industrial solid waste smelting waste residue - Google Patents
Solidification treatment process for industrial solid waste smelting waste residue Download PDFInfo
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- 238000007711 solidification Methods 0.000 title claims abstract description 42
- 230000008023 solidification Effects 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000002699 waste material Substances 0.000 title claims abstract description 40
- 239000002910 solid waste Substances 0.000 title claims abstract description 34
- 238000003723 Smelting Methods 0.000 title claims abstract description 33
- 239000002002 slurry Substances 0.000 claims abstract description 58
- 238000003756 stirring Methods 0.000 claims abstract description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 34
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000003381 stabilizer Substances 0.000 claims abstract description 19
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000002562 thickening agent Substances 0.000 claims abstract description 19
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 14
- 239000010814 metallic waste Substances 0.000 claims abstract description 14
- 239000004568 cement Substances 0.000 claims description 20
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- -1 polyoxyethylene Polymers 0.000 claims description 10
- WPJGWJITSIEFRP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;hydrate Chemical compound O.NC1=NC(N)=NC(N)=N1 WPJGWJITSIEFRP-UHFFFAOYSA-N 0.000 claims description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 5
- 239000011398 Portland cement Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- 229940092782 bentonite Drugs 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- 239000008116 calcium stearate Substances 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 5
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- 239000010881 fly ash Substances 0.000 claims description 5
- 229910021485 fumed silica Inorganic materials 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 5
- 229960001545 hydrotalcite Drugs 0.000 claims description 5
- 239000004571 lime Substances 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 231100000252 nontoxic Toxicity 0.000 claims description 5
- 230000003000 nontoxic effect Effects 0.000 claims description 5
- 150000008301 phosphite esters Chemical class 0.000 claims description 5
- 229920005646 polycarboxylate Polymers 0.000 claims description 5
- 125000003367 polycyclic group Chemical group 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 229940080314 sodium bentonite Drugs 0.000 claims description 5
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 5
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000007787 solid Substances 0.000 description 6
- 239000002893 slag Substances 0.000 description 4
- 230000000740 bleeding effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 241000282414 Homo sapiens Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010813 municipal solid waste Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a solidification treatment process of industrial solid waste smelting waste residue, which relates to the technical field of industrial solid waste, and adopts the technical scheme that: the method comprises the following specific steps: s1, putting water and a surfactant into a stirrer for stirring to obtain a mixture A; s2, placing the mixture A and the heavy metal waste residues into a stirrer to be stirred, so as to obtain slurry A; s3, placing the slurry A and the stabilizer into a stirrer to be stirred, so as to obtain slurry B; s4, putting the cementing material and the water reducing agent into a stirrer for stirring to obtain a mixture B; s5, conveying the mixture B to a stirrer through a conveyor, wherein the solidification treatment process of the industrial solid waste smelting waste residue has the beneficial effects that: water in the slurry is quickly absorbed through the water reducing agent, the thickening agent and the cementing material, so that the solidification efficiency of smelting waste residues is improved, and the working efficiency is improved.
Description
Technical Field
The invention relates to the technical field of industrial solid wastes, in particular to a solidification treatment process of smelting waste residues of industrial solid wastes.
Background
The solid waste refers to solid and semi-solid waste materials generated in production, consumption, life and other activities of human beings, and is generally called garbage. The waste mainly comprises solid particles, garbage, slag, sludge, waste products, damaged vessels, defective products, animal bodies, deteriorated food, human and animal excreta and the like, the waste mostly refers to solid waste or waste containing a large amount of solids, and the discarded waste can become raw materials, fuels or consumer goods for production, which is the basis of the resource treatment of the solid waste. The smelting waste slag refers to various solid wastes generated in the production process of the smelting industry, and the smelting waste slag needs to be subjected to solidification treatment at present;
the prior art has the following defects: when the existing solidification treatment process is used for solidifying the smelting waste slag, the solidification efficiency is low, so that the working efficiency is reduced.
Therefore, the invention is necessary to develop a solidification treatment process of the industrial solid waste smelting waste.
Disclosure of Invention
The invention is provided in view of the above and/or the problems existing in the existing solidification treatment process of the smelting waste residue of the industrial solid waste.
Therefore, the invention aims to provide a solidification treatment process for smelting waste residues of industrial solid wastes, which can solve the problem that the prior solidification treatment process has low solidification efficiency and reduced working efficiency when the smelting waste residues are solidified by different addition sequences, reaction temperatures and proportion proportions of water, a surfactant, heavy metal waste residues, a stabilizer, a cementing material, a water reducing agent and a thickening agent.
In order to solve the above technical problems, according to one aspect of the present invention, the present invention provides the following technical solutions:
a solidification treatment process of industrial solid waste smelting waste residue comprises the following specific steps:
s1, putting water and a surfactant into a stirrer for stirring to obtain a mixture A;
s2, putting the mixture A and the heavy metal waste residue into a stirrer for stirring to obtain slurry A; .
S3, placing the slurry A and the stabilizer into a stirrer to be stirred, so as to obtain slurry B;
s4, placing the cementing material and the water reducing agent into a stirrer to be stirred, so as to obtain a mixture B;
s5, conveying the mixture B into a stirrer through a conveyor, conveying the slurry B into the stirrer at the same time, and stirring and mixing the mixture B and the slurry B after the conveying is finished so as to obtain slurry C;
s6, putting the slurry C and the thickening agent into a stirrer through a conveyor for stirring to obtain slurry D;
and S7, placing the slurry D into a mold, cooling and molding, demolding to obtain a solidified body, and placing the solidified body into a curing area.
As a preferable scheme of the solidification treatment process of the industrial solid waste smelting waste residue, the solidification treatment process comprises the following steps: the water, the surfactant, the heavy metal waste residue, the stabilizer, the cementing material, the water reducing agent and the thickening agent are respectively as follows by weight: 40g to 50g, 10g to 14g, 40g to 50g, 8g to 12g, 6g to 10g, 12g to 16g and 8g to 12g.
As a preferable scheme of the solidification treatment process of the industrial solid waste smelting waste residue, the solidification treatment process comprises the following steps: the surfactant is composed of polyoxyethylene castor oil, fatty alcohol-polyoxyethylene ether and polyoxyethylene sorbitan fatty acid ester, and the proportion is 1:1:2.
as a preferable scheme of the solidification treatment process of the industrial solid waste smelting waste residue, the solidification treatment process comprises the following steps: the stabilizer consists of calcium stearate, zinc stearate, nontoxic phosphite ester and hydrotalcite, and the proportion is 1:2:1:0.5.
as a preferable scheme of the solidification treatment process of the industrial solid waste smelting waste residue, the solidification treatment process comprises the following steps: the gelled material is composed of polyester fibers, glass fibers, lime, cement and fly ash, and the proportion is 1:1:1:0.5:2.
as a preferable scheme of the solidification treatment process of the industrial solid waste smelting waste residue, the solidification treatment process comprises the following steps: the cement consists of portland cement, aluminate cement and sulphoaluminate cement in a ratio of 2:1:1.
as a preferable scheme of the solidification treatment process of the industrial solid waste smelting waste residue, the invention comprises the following steps: the water reducing agent is one or more of polycyclic aromatic sulfonate formaldehyde condensate, sulfamate high-efficiency water reducing agent, powder polycarboxylate and melamine water reducing agent.
As a preferable scheme of the solidification treatment process of the industrial solid waste smelting waste residue, the solidification treatment process comprises the following steps: the thickening agent consists of fumed silica, sodium bentonite and organic bentonite, and the proportion is as follows: 2:1:1.
as a preferable scheme of the solidification treatment process of the industrial solid waste smelting waste residue, the solidification treatment process comprises the following steps: in the S1, the stirring time is 6min-10min, and the temperature is 30-40 ℃;
in the S2, the stirring time is 20min-40min, and the temperature is 42 ℃ to 48 ℃;
in the S3, the stirring time is 16min-20min, and the temperature is 35-45 ℃;
in the S4, the stirring time is 30-40 min, and the temperature is 40-45 ℃;
in the S5, the stirring time is 20min-30min, and the temperature is 60 ℃ to 65 ℃;
in the S6, the stirring time is 30-50 min, and the temperature is 50-55 ℃.
The beneficial effects of the invention are:
the method comprises the steps of putting water and a surfactant into a stirrer to be stirred to obtain a mixture A, putting the mixture A and heavy metal waste residues into the stirrer to be stirred to obtain slurry A, putting the slurry A and a stabilizer into the stirrer to be stirred to obtain slurry B, putting a cementing material and a water reducing agent into the stirrer to be stirred to obtain a mixture B, conveying the mixture B into the stirrer through a conveyor, conveying the slurry B into the stirrer at the same time, stirring and mixing the mixture B and the slurry B after the conveying is finished to obtain slurry C, putting the slurry C and a thickening agent into the stirrer through the conveyor to be stirred to obtain slurry D, putting the slurry D into a mold to be cooled and formed, demolding to obtain a solidified body after the forming, and putting the solidified body into a curing area.
Detailed Description
The preferred embodiments of the present invention are described below, and it should be understood that the preferred embodiments described herein are only for illustrating and explaining the present invention and are not to be construed as limiting the present invention.
Example 1:
the invention provides a solidification treatment process of industrial solid waste smelting waste residue, which comprises the following specific steps:
s1, putting water and a surfactant into a stirrer to be stirred, so as to obtain a mixture A, wherein the water and the surfactant are respectively as follows by weight: 40g and 10g, wherein the surfactant is composed of polyoxyethylene castor oil, fatty alcohol-polyoxyethylene ether and polyoxyethylene sorbitan fatty acid ester, and the proportion is 1:1:2, stirring for 6min at the temperature of 30 ℃;
s2, placing the mixture A and the heavy metal waste residues into a stirrer to be stirred, and thus obtaining slurry A, wherein the heavy metal waste residues comprise the following components in parts by weight: 40g, stirring for 20min at 42 ℃;
s3, putting the slurry A and a stabilizer into a stirrer to be stirred so as to obtain a slurry B, wherein the stabilizer comprises the following components in parts by weight: 8g, the stabilizer is composed of calcium stearate, zinc stearate, nontoxic phosphite ester and hydrotalcite, and the proportion is 1:2:1:0.5, stirring for 16min at 35 ℃;
s4, placing the cementing material and the water reducing agent into a stirrer to be stirred, and thus obtaining a mixture B, wherein the cementing material and the water reducing agent are respectively as follows by weight: 6g and 12g, wherein the cementing material consists of polyester fiber, glass fiber, lime, cement and fly ash, the cement consists of portland cement, aluminate cement and sulphoaluminate cement, and the proportion is 2:1:1 and the ratio is 1:1:1:0.5:2, the water reducing agent is one or more of polycyclic aromatic sulfonate formaldehyde condensate, sulfamate high-efficiency water reducing agent, powder polycarboxylate and melamine water reducing agent, the stirring time is 30min, and the temperature is 40 ℃;
s5, conveying the mixture B into a stirrer through a conveyor, conveying the slurry B into the stirrer at the same time, and after the conveying is finished, stirring and mixing the mixture B and the slurry B to obtain slurry C, wherein the stirring time is 20min, and the temperature is 60 ℃;
s6, putting the slurry C and the thickening agent into a stirrer through a conveyor for stirring to obtain slurry D, wherein the thickening agent comprises the following components in parts by weight: 8g, wherein the thickening agent consists of fumed silica, sodium bentonite and organic bentonite, and the proportion is as follows: 2:1:1, stirring for 30min at 50 ℃;
s7, placing the slurry D into a mold, cooling and molding, demolding to obtain a solidified body, and placing the solidified body into a curing area.
Example 2:
the invention provides a solidification treatment process of industrial solid waste smelting waste residues, which comprises the following specific steps:
s1, putting water and a surfactant into a stirrer to be stirred, so as to obtain a mixture A, wherein the water and the surfactant are respectively as follows by weight: 45g and 12g, wherein the surfactant is composed of polyoxyethylene castor oil, fatty alcohol-polyoxyethylene ether and polyoxyethylene sorbitan fatty acid ester, and the proportion is 1:0.5:2, stirring for 8min at the temperature of 35 ℃;
s2, placing the mixture A and the heavy metal waste residues into a stirrer to be stirred, and thus obtaining slurry A, wherein the heavy metal waste residues comprise the following components in parts by weight: 45g, stirring for 30min and keeping the temperature at 45 ℃;
s3, putting the slurry A and a stabilizer into a stirrer to be stirred, so as to obtain a slurry B, wherein the stabilizer comprises the following components in parts by weight: 10g, the stabilizer consists of calcium stearate, zinc stearate, nontoxic phosphite ester and hydrotalcite, and the proportion is 1:0.5:1:0.5, stirring for 18min at 40 ℃;
s4, placing the cementing material and the water reducing agent into a stirrer to be stirred, so as to obtain a mixture B, wherein the cementing material and the water reducing agent are respectively as follows by weight: 8g and 14g, wherein the cementing material consists of polyester fiber, glass fiber, lime, cement and fly ash, the cement consists of portland cement, aluminate cement and sulphoaluminate cement, and the proportion is 2:0.5:1, and the ratio is 1:0.5:1:0.5:2, the water reducing agent is one or more of polycyclic aromatic sulfonate formaldehyde condensate, sulfamate high-efficiency water reducing agent, powder polycarboxylate and melamine water reducing agent, the stirring time is 35min, and the temperature is 42.5 ℃;
s5, conveying the mixture B into a stirrer through a conveyor, conveying the slurry B into the stirrer, and after the conveying is finished, stirring and mixing the mixture B and the slurry B to obtain slurry C, wherein the stirring time is 25min, and the temperature is 62.5 ℃;
s6, putting the slurry C and the thickening agent into a stirrer through a conveyor for stirring to obtain slurry D, wherein the thickening agent comprises the following components in parts by weight: 10g, wherein the thickening agent consists of fumed silica, sodium bentonite and organic bentonite, and the proportion is as follows: 2:0.5:1, stirring for 40min at 52.5 ℃;
s7, placing the slurry D into a mold, cooling and molding, demolding to obtain a solidified body, and placing the solidified body into a curing area.
Example 3:
the invention provides a solidification treatment process of industrial solid waste smelting waste residue, which comprises the following specific steps:
s1, putting water and a surfactant into a stirrer to be stirred, so as to obtain a mixture A, wherein the water and the surfactant are respectively as follows by weight: 50g and 14g, wherein the surfactant is composed of polyoxyethylene castor oil, fatty alcohol-polyoxyethylene ether and polyoxyethylene sorbitan fatty acid ester, and the proportion is 0.5:1:2, stirring for 10min at 40 ℃;
s2, placing the mixture A and the heavy metal waste residues into a stirrer to be stirred, and thus obtaining slurry A, wherein the heavy metal waste residues comprise the following components in parts by weight: 50g, stirring for 40min at 48 ℃;
s3, putting the slurry A and a stabilizer into a stirrer to be stirred, so as to obtain a slurry B, wherein the stabilizer comprises the following components in parts by weight: 12g, the stabilizer is composed of calcium stearate, zinc stearate, nontoxic phosphite ester and hydrotalcite, and the proportion is 1.5:2:1:0.5, stirring for 20min at 45 ℃;
s4, placing the cementing material and the water reducing agent into a stirrer to be stirred, so as to obtain a mixture B, wherein the cementing material and the water reducing agent are respectively as follows by weight: 10g and 16g, wherein the cementing material consists of polyester fiber, glass fiber, lime, cement and fly ash, the cement consists of portland cement, aluminate cement and sulphoaluminate cement, and the proportion is 1:0.5:1 and the ratio is 2:1:0.5:0.5:2, the water reducing agent is one or more of polycyclic aromatic sulfonate formaldehyde condensate, sulfamate high-efficiency water reducing agent, powder polycarboxylate and melamine water reducing agent, the stirring time is 40min, and the temperature is 45 ℃;
s5, conveying the mixture B into a stirrer through a conveyor, conveying the slurry B into the stirrer, and after the conveying is finished, stirring and mixing the mixture B and the slurry B to obtain slurry C, wherein the stirring time is 30min, and the temperature is 65 ℃;
s6, putting the slurry C and the thickening agent into a stirrer through a conveyor for stirring to obtain slurry D, wherein the thickening agent comprises the following components in parts by weight: 12g, the thickening agent consists of fumed silica, sodium bentonite and organic bentonite, and the proportion is as follows: 1:1:2, stirring for 50min at the temperature of 55 ℃;
and S7, placing the slurry D into a mold, cooling and molding, demolding to obtain a solidified body, and placing the solidified body into a curing area.
The following data were obtained by comparing the solidified waste residues prepared in examples 1 to 3 above:
| example 1 | Example 2 | Example 3 | |
| Solid content | 35%-50% | 60%-80% | 40%-55% |
| Bleeding rate | 3%-4% | 4%-5% | 2%-4% |
| Efficiency of curing | Saves 15% of time compared with the prior art | Saves 25% of time compared with the prior art | Compared with the prior art, the method saves 20 percent of time |
As can be seen from the above table, the solidified waste residues prepared in examples 1 to 3 have better performance in terms of solid content, bleeding rate and solidification efficiency, but the effects of the solidified waste residues in terms of solid content, bleeding rate and solidification efficiency are different due to different addition sequences, reaction temperatures and proportion ratios of water, surfactant, heavy metal waste residues, stabilizer, cementing material, water reducing agent and thickener.
The above description is only a preferred embodiment of the present invention, and any person skilled in the art may modify the present invention or modify it to an equivalent technical solution by using the technical solution described above. Therefore, any simple modifications or equivalent substitutions made in accordance with the technical solution of the present invention are within the scope of the claims of the present invention.
Claims (7)
1. A solidification treatment process of industrial solid waste smelting waste residue is characterized in that: the method comprises the following specific steps:
s1, putting water and a surfactant into a stirrer to be stirred, so as to obtain a mixture A;
s2, placing the mixture A and the heavy metal waste residues into a stirrer to be stirred, so as to obtain slurry A;
s3, placing the slurry A and the stabilizer into a stirrer to be stirred, so as to obtain slurry B;
s4, putting the cementing material and the water reducing agent into a stirrer for stirring to obtain a mixture B;
s5, conveying the mixture B into a stirrer through a conveyor, conveying the slurry B into the stirrer at the same time, and stirring and mixing the mixture B and the slurry B after the conveying is finished so as to obtain slurry C;
s6, putting the slurry C and the thickening agent into a stirrer through a conveyor for stirring to obtain slurry D;
s7, placing the slurry D into a mold, cooling and molding, demolding to obtain a solidified body, and placing the solidified body into a curing area;
the water, the surfactant, the heavy metal waste residue, the stabilizer, the cementing material, the water reducing agent and the thickening agent are respectively as follows by weight: 40g-50g, 10g-14g, 40g-50g, 8g-12g, 6g-10g, 12g-16g and 8g-12g;
in the S1, the stirring time is 6min-10min, and the temperature is 30-40 ℃;
in the S2, the stirring time is 20min-40min, and the temperature is 42 ℃ to 48 ℃;
in the S3, the stirring time is 16min-20min, and the temperature is 35-45 ℃;
in the S4, the stirring time is 30-40 min, and the temperature is 40-45 ℃;
in the S5, the stirring time is 20min-30min, and the temperature is 60-65 ℃;
in the S6, the stirring time is 30-50 min, and the temperature is 50-55 ℃.
2. The solidification treatment process of the industrial solid waste smelting waste residue according to claim 1, characterized in that: the surfactant is composed of polyoxyethylene castor oil, fatty alcohol-polyoxyethylene ether and polyoxyethylene sorbitan fatty acid ester, and the proportion is 1:1:2.
3. the solidification treatment process of the industrial solid waste smelting waste residue according to claim 1, characterized in that: the stabilizer consists of calcium stearate, zinc stearate, nontoxic phosphite ester and hydrotalcite, and the proportion is 1:2:1:0.5.
4. the solidification treatment process of industrial solid waste smelting waste residue according to claim 1, characterized in that: the cementing material is composed of polyester fiber, glass fiber, lime, cement and fly ash, and the proportion is 1:1:1:0.5:2.
5. the solidification treatment process of the industrial solid waste smelting waste residue according to claim 4, characterized in that: the cement consists of portland cement, aluminate cement and sulphoaluminate cement in a ratio of 2:1:1.
6. the solidification treatment process of the industrial solid waste smelting waste residue according to claim 1, characterized in that: the water reducing agent is one or more of polycyclic aromatic sulfonate formaldehyde condensate, sulfamate high-efficiency water reducing agent, powder polycarboxylate and melamine water reducing agent.
7. The solidification treatment process of industrial solid waste smelting waste residue according to claim 1, characterized in that: the thickening agent consists of fumed silica, sodium bentonite and organic bentonite, and the proportion is as follows: 2:1:1.
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| JPH07204605A (en) * | 1994-01-28 | 1995-08-08 | Kanegafuchi Chem Ind Co Ltd | Waste disposal material |
| JP2007000741A (en) * | 2005-06-22 | 2007-01-11 | Unitika Ltd | Stabilizing agent for harmful substance in ash and stabilizing method |
| CN101972766A (en) * | 2010-08-30 | 2011-02-16 | 天津渤海环保工程有限公司 | Refuse incineration fly ash solidification/stabilization treatment method |
| CN105776984B (en) * | 2016-02-03 | 2018-02-16 | 辽宁绿源再生能源开发有限公司 | A kind of recycling processing method of Industrial Solid Waste |
| CN206189231U (en) * | 2016-10-12 | 2017-05-24 | 深圳市永丰生态环境有限公司 | Gardens permeable pavement structure |
| CN110408166A (en) * | 2019-07-31 | 2019-11-05 | 河北雄发新材料科技发展有限公司 | A kind of OBS organic stabilizer and preparation method thereof |
| CN110759680B (en) * | 2019-11-14 | 2021-02-23 | 山东大学 | Red mud utilization method based on cooperative treatment of industrial tail gas, sewage treatment and green high-performance civil functional material |
| CN111515225A (en) * | 2020-04-28 | 2020-08-11 | 南方科技大学 | A kind of treatment method of waste incineration fly ash |
| CN113634577B (en) * | 2021-06-11 | 2024-10-15 | 深圳市长隆科技有限公司 | Medicament for acid catalysis long-period stabilization of heavy metals in fly ash and use method thereof |
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