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CN114304729B - Electromagnetic induction heating cigarette and preparation method thereof - Google Patents

Electromagnetic induction heating cigarette and preparation method thereof Download PDF

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Publication number
CN114304729B
CN114304729B CN202210170973.4A CN202210170973A CN114304729B CN 114304729 B CN114304729 B CN 114304729B CN 202210170973 A CN202210170973 A CN 202210170973A CN 114304729 B CN114304729 B CN 114304729B
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tobacco
metal foil
porous metal
electromagnetic induction
induction heating
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CN114304729A (en
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张敦铁
杨俊鹏
刘祥谋
王昊
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China Tobacco Hubei Industrial Co Ltd
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China Tobacco Hubei Industrial Co Ltd
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Priority to PCT/CN2022/131862 priority patent/WO2023160026A1/en
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/01Making cigarettes for simulated smoking devices
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/20Cigarettes specially adapted for simulated smoking devices
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40Constructional details, e.g. connection of cartridges and battery parts
    • A24F40/46Shape or structure of electric heating means
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F47/00Smokers' requisites not otherwise provided for

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  • Manufacture Of Tobacco Products (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The invention relates to the technical field of heating cigarettes, in particular to an electromagnetic induction heating cigarette and a preparation method thereof. The electromagnetic induction heating cigarette comprises a heating tobacco main body, wherein the heating tobacco main body is a paper roll structure formed by winding heating tobacco sheets; the heating tobacco sheet comprises a porous metal foil and plant fibers, wherein the plant fibers comprise a bonding section positioned on the front surface of the porous metal foil, a connecting section positioned in holes of the porous metal foil and a supporting section positioned on the back surface of the porous metal foil; the back surfaces of the supporting sections of the plant fibers and the porous metal foil are provided with metal oxide particles. In this application, through the structural design to the heating tobacco piece, make its arbitrary slice that winds the scroll structure of formation circle, be attached to the tip of the metal oxide granule of plant fiber support section can be opposite, even offset with the tobacco layer of its adjacent slice circle to form the bearing structure of flue gas passageway, can avoid flue gas passageway to seal, ensured the suction experience.

Description

一种电磁感应加热卷烟及其制备方法An electromagnetic induction heating cigarette and its preparation method

技术领域technical field

本发明涉及加热卷烟技术领域,尤其涉及一种电磁感应加热卷烟及其制备方法。The invention relates to the technical field of heated cigarettes, in particular to an electromagnetic induction heated cigarette and a preparation method thereof.

背景技术Background technique

传统的烟草是在被点燃之后,维持阴燃状态,并利用阴燃产生的温度加热燃烧区域附近的烟草原料,释放出可供抽吸的烟气。在这一过程中,根据距离燃烧锥的位置差异,不同位置的烟草物料温度各不相同。传统烟草的烟草产品其烟气释放过程是一个温度变化范围较大,加热均匀性不良的体系中发生的。而温度的不稳定导致了烟气成分中的化合物的成分构成变得非常复杂,这也导致了烟气的抽吸质量稳定性受到影响,并且也导致了诸多有害化学成分的释放难以控制。Traditional tobacco maintains a smoldering state after being ignited, and uses the temperature generated by smoldering to heat the tobacco raw material near the burning area to release smoke that can be smoked. During this process, the temperature of the tobacco material at different positions is different according to the position difference from the combustion cone. The smoke release process of traditional tobacco tobacco products occurs in a system with a large temperature range and poor heating uniformity. The instability of temperature makes the composition of the compounds in the smoke composition very complex, which also affects the stability of the smoke quality of the smoke, and also makes it difficult to control the release of many harmful chemical components.

而近年来科学研究表明有效控制降低烟支的燃烧温度,可以显著提升烟气中的有害成分释放量,提高烟草制品的安全性。依托这一理论,开发了加热不燃烧产品。这些加热不燃烧产品是通过加热元件对烟草物料进行加热烘培,并将加热温度控制在300℃左右,使烟草能够释放烟气但仍旧保持在不燃烧的状态下。相对于传统的燃吸卷烟,加热不燃烧烟草在很大程度改善了烟草释放烟气的温度稳定性,并进而减低了产品的危害性。In recent years, scientific research has shown that effective control and reduction of the combustion temperature of cigarettes can significantly increase the release of harmful components in smoke and improve the safety of tobacco products. Based on this theory, heat-not-burn products have been developed. These heat-not-burn products use heating elements to heat and bake the tobacco material, and the heating temperature is controlled at about 300°C, so that the tobacco can release smoke but still remain in a non-combustible state. Compared with traditional burning and smoking cigarettes, heat-not-burn tobacco has greatly improved the temperature stability of the smoke released by tobacco, and thus reduced the hazard of the product.

电磁感应加热,是通过高频电流产生交变磁场,对应金属表面切割交变磁力线从而产生交变的电流(即涡流),涡流使金属原子高速无规则运动,原子互相碰撞、摩擦而产生热能,起到加热物品的效果。因为是铁制容器自身发热,所以热转化效率远高于传统的接触型热量传递的加热方式。公开号为CN108835707A的专利文件公开了这样一种电磁感应加热卷烟,包括烟草段和嘴棒段,烟草段由烟草段卷烟纸包裹,烟草段由金属箔片和烟草复合后进行卷曲后形成烟支状结构,其中烟支状结构中的层与层之间具有一定的间隙。Electromagnetic induction heating is to generate an alternating magnetic field through a high-frequency current, and cut the alternating magnetic force line corresponding to the metal surface to generate an alternating current (ie eddy current). The eddy current makes the metal atoms move at high speed and irregularly, and the atoms collide and rub against each other to generate heat energy. Play the effect of heating items. Because the iron container generates heat by itself, the heat conversion efficiency is much higher than the traditional contact heat transfer heating method. The patent document with the publication number CN108835707A discloses such an electromagnetic induction heating cigarette, which includes a tobacco section and a mouthpiece section. The tobacco section is wrapped by tobacco section cigarette paper, and the tobacco section is made of metal foil and tobacco. There is a certain gap between the layers in the cigarette-like structure.

该申请中,第一,烟草段由金属箔片和烟草复合后卷曲形成,其中,金属箔片能够被卷曲,必然具有较好的延展性和弹性,这就会导致其在卷曲成型后,被外力一捏,就容易变形,从而导致其层与层之间的供烟气流通的间隙封闭,影响烟气流通的问题。第二,其烟草和金属箔片是压制在一起的,当金属箔片受外力变形时,烟草与金属箔片的形变能力不一致,这就会导致烟草与金属箔片之间产生缝隙,使得烟草容易从金属箔片上脱落。In this application, firstly, the tobacco segment is formed by curling after the metal foil and tobacco are combined. Among them, the metal foil can be curled, and it must have good ductility and elasticity, which will cause it to be crimped after forming. When pinched by an external force, it is easy to deform, which leads to the closure of the gap between the layers for the circulation of smoke, which affects the flow of smoke. Second, the tobacco and the metal foil are pressed together. When the metal foil is deformed by an external force, the deformability of the tobacco and the metal foil is inconsistent, which will cause a gap between the tobacco and the metal foil, making the tobacco Comes off the foil easily.

发明内容Contents of the invention

本发明要解决上述问题,提供一种电磁感应加热卷烟及其制备方法。To solve the above problems, the present invention provides an electromagnetic induction heating cigarette and a preparation method thereof.

本发明解决问题的技术方案是,首先提供一种电磁感应加热卷烟,包括烟草段,所述烟草段包括加热烟草主体、以及包覆于所述加热烟草主体外的卷烟纸,所述加热烟草主体为由加热烟草片卷绕形成的纸卷结构,所述纸卷结构包括若干半径依次增大的片圈,相邻片圈之间形成烟气通道;其特征在于:所述加热烟草片包括多孔金属箔片和植物纤维,所述多孔金属箔片包括相对的正面和背面,所述植物纤维包括位于所述多孔金属箔片正面的黏结段、位于所述多孔金属箔片的孔洞内的连接段、以及位于所述多孔金属箔片背面的支撑段;若干所述植物纤维的黏结段通过胶粘剂黏结;若干所述植物纤维的支撑段、以及所述多孔金属箔片的背面设有金属氧化物颗粒。The technical solution of the present invention to solve the problem is to firstly provide an electromagnetic induction heating cigarette, which includes a tobacco section, the tobacco section includes a heated tobacco body, and cigarette paper wrapped outside the heated tobacco body, and the heated tobacco body It is a paper roll structure formed by winding heated tobacco sheets, the paper roll structure includes several coils with successively increasing radii, and smoke channels are formed between adjacent coils; it is characterized in that the heated tobacco sheet includes porous Metal foil and plant fibers, the porous metal foil includes opposite fronts and backs, the plant fibers include a bonding section located on the front side of the porous metal foil, a connecting section located in the holes of the porous metal foil , and a support section located on the back of the porous metal foil; some of the bonding sections of the plant fibers are bonded by an adhesive; some of the support sections of the plant fibers, and the back of the porous metal foil are provided with metal oxide particles .

基于上述结构,本发明还有一个目的是提供一种电磁感应加热卷烟的制备方法,包括以下步骤:Based on the above structure, another object of the present invention is to provide a method for preparing electromagnetic induction heating cigarettes, comprising the following steps:

S1.将植物纤维浸渍于烟草液中后取出烘干,所述烟草液包括烟草提取物;S1. After soaking the plant fiber in the tobacco liquid, take it out and dry it, and the tobacco liquid includes tobacco extract;

S2.于多孔金属箔片的正面上铺设植物纤维,振动后,于植物纤维上喷洒胶粘剂,固化形成烟草层;S2. Laying plant fibers on the front side of the porous metal foil, after vibration, spraying adhesive on the plant fibers, curing to form a tobacco layer;

S3.于烟草层上覆盖遮盖物,得到正面遮盖、背面暴露的多孔金属箔片;将多孔金属箔片加入到金属前驱体和络合剂的混合溶液中,然后向混合溶液中滴加沉淀剂,于100-200℃下反应后取出,得到加热烟草片;S3. Cover the tobacco layer with a covering to obtain a porous metal foil with the front side covered and the back side exposed; the porous metal foil is added to the mixed solution of the metal precursor and the complexing agent, and then the precipitant is added dropwise to the mixed solution , taken out after reacting at 100-200°C to obtain heated tobacco sheets;

S4.将加热烟草片的一端作为固定端固定,另一端以所述固定端为中心不断卷绕,得到加热烟草主体,于加热烟草主体外包覆卷烟纸,得到卷烟的烟草段。S4. Fix one end of the heated tobacco sheet as a fixed end, and continuously wind the other end around the fixed end to obtain a heated tobacco body, and wrap the heated tobacco body with cigarette paper to obtain a tobacco segment of a cigarette.

本申请用于卷绕成加热烟草主体的加热烟草片中,在正面上,为胶粘剂和植物纤维的黏结段复合形成的烟草层,通过将植物纤维或/和胶粘剂与烟草提取物复合,即可提供烟草抽吸效果。在背面上,在背面本体以及背面延伸出来的植物纤维支撑段上均附着有金属氧化物颗粒,基于此,当将此加热烟草片卷绕后,虽然形成与现有技术相似的纸卷结构,但是本申请中,这种纸卷结构的任一片圈上、附着于植物纤维支撑段的金属氧化物颗粒的端部可以与其相邻片圈的烟草层相对、甚至相抵,从而形成烟气通道的支撑结构,可以避免烟气通道封闭。In the heated tobacco sheet used in this application to be wound into the main body of heated tobacco, on the front side, the tobacco layer formed by compounding the binder and the bonding section of the plant fiber can be obtained by compounding the plant fiber or/and the binder with the tobacco extract. Provides a tobacco smoking effect. On the back side, metal oxide particles are attached to the back body and the plant fiber support section extending from the back side. Based on this, when the heated tobacco sheet is wound, although a paper roll structure similar to the prior art is formed, However, in the present application, the end of the metal oxide particles attached to the plant fiber support section on any coil of the paper roll structure can be opposite to or even against the tobacco layer of its adjacent coil, thereby forming the smoke channel. The support structure can avoid the closure of the flue gas channel.

此外,在多孔金属箔片卷绕形变时,由于孔洞的存在,孔洞的形变可以为实体部分的延展拉伸提供缓冲效用,避免多孔金属箔片在形变过程中开裂等问题。且植物纤维的一端插入多孔金属箔片的孔洞后,烟草层与多孔金属箔片除去在正面连接外,还在与正面垂直的垂直面连接,加热烟草片的卷绕对正面的形变影响大,但是对垂直面的影响小,因此保证了烟草层与多孔金属箔片之间的连接强度,避免了烟草层的脱落。In addition, when the porous metal foil is wound and deformed, due to the existence of holes, the deformation of the holes can provide a buffer effect for the extension and stretching of the solid part, and avoid problems such as cracking of the porous metal foil during the deformation process. And after one end of the plant fiber is inserted into the hole of the porous metal foil, the tobacco layer and the porous metal foil are connected not only on the front, but also on a vertical surface perpendicular to the front, and the winding of the heated tobacco sheet has a great influence on the deformation of the front. However, the impact on the vertical plane is small, so the connection strength between the tobacco layer and the porous metal foil is guaranteed, and the falling off of the tobacco layer is avoided.

作为本发明的优选,所述多孔金属箔片为铁磁性材料,使得多孔金属箔片可以作为电磁感应加热的媒介。As a preference of the present invention, the porous metal foil is a ferromagnetic material, so that the porous metal foil can be used as a medium for electromagnetic induction heating.

作为本发明的优选,所述多孔金属箔片包括泡沫不锈钢、泡沫铁、泡沫铁合金中的一种或几种。As a preference of the present invention, the porous metal foil includes one or more of foamed stainless steel, foamed iron, and foamed iron alloy.

基于泡沫金属的孔径大小,为保证植物纤维穿过孔洞。作为本发明的优选,所述植物纤维的外径不超过1mm。同时在制备过程中,作为本发明的优选,步骤S3中,所述振动包括横向振动和纵向振动,所述纵向振动的振动方向与所述多孔金属箔片垂直,所述横向振动的振动方向与所述多孔金属箔片平行。Based on the pore size of the metal foam, in order to ensure that the plant fibers pass through the holes. As a preference of the present invention, the outer diameter of the plant fiber does not exceed 1mm. At the same time, in the preparation process, as a preference of the present invention, in step S3, the vibration includes transverse vibration and longitudinal vibration, the vibration direction of the longitudinal vibration is perpendicular to the porous metal foil, and the vibration direction of the transverse vibration is perpendicular to the porous metal foil. The porous metal foils are parallel.

为了提高支撑效果,颗粒优选为硬度高、耐热性能好、不易形变的颗粒,作为本发明的优选,所述金属氧化物颗粒包括氧化铝颗粒、氧化镁颗粒中的一种或几种。In order to improve the support effect, the particles are preferably particles with high hardness, good heat resistance, and not easily deformed. As a preference in the present invention, the metal oxide particles include one or more of alumina particles and magnesium oxide particles.

基于此,在制备过程中,作为本发明的优选,所述金属前驱体包括硝酸铝、硝酸镁中的一种或几种。Based on this, in the preparation process, as a preference of the present invention, the metal precursor includes one or more of aluminum nitrate and magnesium nitrate.

作为本发明的优选,所述络合剂包括乙二胺四乙酸钠、N,N,N',N'-四(2-羟丙基)乙二胺中的一种或两种的混合。As a preference of the present invention, the complexing agent includes one or a mixture of sodium edetate, N,N,N',N'-tetrakis(2-hydroxypropyl)ethylenediamine.

作为本发明的优选,所述络合剂的浓度为0.05-0.1mol/L。As a preference of the present invention, the concentration of the complexing agent is 0.05-0.1 mol/L.

作为本发明的优选,所述沉淀剂包括氨水、氢氧化钠、氢氧化钾中的一种或几种。As a preference of the present invention, the precipitating agent includes one or more of ammonia water, sodium hydroxide and potassium hydroxide.

作为本发明的优选,所述沉淀剂的浓度为0.2-0.8mol/L。As a preference of the present invention, the concentration of the precipitation agent is 0.2-0.8 mol/L.

作为本发明的优选,所述沉淀剂滴加速度为0.04-0.08mL/min。As a preference of the present invention, the dropping rate of the precipitating agent is 0.04-0.08mL/min.

作为本发明的优选,于100-200℃下反应1-3h。As a preference of the present invention, the reaction is carried out at 100-200° C. for 1-3 hours.

本申请中烟气通道的支撑是基于附着在植物纤维上的金属氧化物颗粒,为了进一步提高金属氧化物颗粒在植物纤维上的附着强度,作为本发明的优选,所述烟草液还包括葡萄糖酸内酯。植物纤维中不可避免地会含有钙离子,吸收有葡萄糖酸内酯的植物纤维中,钙离子可以在葡萄糖酸内酯的诱导下释放出来,并在上述反应条件下、与金属前驱体中的金属离子形成钙铝水滑石、钙镁水滑石等,提高了金属氧化物颗粒在植物纤维上的附着强度。The support of the flue gas channel in this application is based on the metal oxide particles attached to the plant fibers. In order to further improve the adhesion strength of the metal oxide particles on the plant fibers, as a preference of the present invention, the tobacco liquid also includes gluconic acid Lactone. Calcium ions will inevitably be contained in plant fibers. In plant fibers absorbed with gluconolactone, calcium ions can be released under the induction of gluconolactone, and under the above reaction conditions, with the metal in the metal precursor The ions form calcium-aluminum hydrotalcite, calcium-magnesium hydrotalcite, etc., which improve the adhesion strength of metal oxide particles on plant fibers.

作为本发明的优选,所述烟草液还包括氯化钙,以提高植物纤维中的钙离子含量。As a preference of the present invention, the tobacco liquid also includes calcium chloride, so as to increase the calcium ion content in the plant fiber.

此外,本申请在制备过程中,由于不需要在烟草层上生长金属氧化物颗粒,因此在多孔金属箔片烟草层上覆盖了遮盖物。In addition, in the preparation process of the present application, since metal oxide particles do not need to be grown on the tobacco layer, a covering is covered on the tobacco layer of the porous metal foil.

作为本发明遮盖物一种方式的优选,所述遮盖物为塑料膜,步骤S4中,卷绕之前,剥离所述遮盖物。而在卷设之前,对加热烟草片进行存储时,可以先不剥离遮盖物,以避免烟草层香味的挥发散失。As a preferred form of the cover of the present invention, the cover is a plastic film, and in step S4, the cover is peeled off before winding. Before rolling, when the heated tobacco sheet is stored, the cover can not be peeled off to avoid the volatilization of the flavor of the tobacco layer.

作为本发明遮盖物另一种方式的优选,所述遮盖物为壳聚糖膜。壳聚糖膜不仅提供了良好的遮盖保护效果,而且在卷设时,也不需要剥离壳聚糖膜,可以进一步减少卷烟烟气危害。As another preference of the cover of the present invention, the cover is a chitosan film. The chitosan film not only provides a good covering protection effect, but also does not need to peel off the chitosan film during rolling, which can further reduce the harm of cigarette smoke.

本发明的有益效果:Beneficial effects of the present invention:

本申请中,通过对加热烟草片的结构设计,使其卷绕形成的纸卷结构的任一片圈上、附着于植物纤维支撑段的金属氧化物颗粒的端部可以与其相邻片圈的烟草层相对、甚至相抵,从而形成烟气通道的支撑结构,可以避免烟气通道封闭,保障了抽吸体验。In this application, through the structural design of the heated tobacco sheet, the end of the metal oxide particles attached to the plant fiber support segment on any lap of the paper roll structure formed by winding it can be separated from the tobacco of the adjacent lap. The layers are opposite or even offset to form a support structure for the smoke channel, which can avoid the closure of the smoke channel and ensure the smoking experience.

附图说明Description of drawings

图1是一种电磁感应加热卷烟烟草段的结构示意图;Fig. 1 is a structural schematic diagram of a tobacco section of an electromagnetic induction heating cigarette;

图中:片圈10,烟气通道101,多孔金属箔片11,植物纤维12,金属氧化物颗粒13。In the figure: sheet circle 10, flue gas channel 101, porous metal foil 11, plant fiber 12, metal oxide particles 13.

具体实施方式Detailed ways

以下是本发明的具体实施方式,并结合附图,对本发明的技术方案作进一步的描述,但本发明并不限于这些实施例。The following are specific embodiments of the present invention, and in conjunction with the accompanying drawings, further describe the technical solution of the present invention, but the present invention is not limited to these embodiments.

实施例1Example 1

一种电磁感应加热卷烟,通过以下步骤制备:An electromagnetic induction heating cigarette is prepared through the following steps:

S1.准备烟草液:按照质量份,将10份烟草提取液、5份烟用香精香料、15份作为雾化剂的甘油混合均匀。S1. Prepare tobacco liquid: mix 10 parts of tobacco extract, 5 parts of tobacco essence and fragrance, and 15 parts of glycerin as an atomizing agent in parts by mass.

植物纤维选用外径为1mm的烟草纤维,将5份烟草纤维浸渍在上述烟草液中,于45℃下浸渍3h后取出,于50℃的热风下烘干并打散,备用。Tobacco fibers with an outer diameter of 1 mm were selected as plant fibers, and 5 parts of tobacco fibers were dipped in the above-mentioned tobacco liquid, soaked at 45°C for 3 hours, taken out, dried and dispersed under hot air at 50°C, and set aside.

S2.多孔金属箔片选用泡沫铁镍片,取其任意一面为正面、与之相对的一面为背面。在振动装置上设置一平行的框架,将多孔金属箔片的边缘固定在框架上,使得多孔金属箔片中间的本体部分悬空,且正面朝上,背面朝下。于正面上铺设步骤S1中处理后得到植物纤维。启动振动装置,使得多孔金属箔片和植物纤维一起交替进行上下振动和左右振动,振动频率为50Hz,振动至观测到多孔金属箔片的背面有延伸出来的植物纤维。S2. The porous metal foil is made of foamed iron-nickel sheet, with any side as the front and the opposite side as the back. A parallel frame is set on the vibrating device, and the edge of the porous metal foil is fixed on the frame, so that the body part in the middle of the porous metal foil is suspended, with the front facing up and the back facing down. The plant fibers obtained after the treatment in step S1 are laid on the front side. Start the vibrating device, so that the porous metal foil and the plant fibers alternately vibrate up and down and left and right together, the vibration frequency is 50 Hz, and vibrate until plant fibers extending from the back of the porous metal foil are observed.

基于此步骤,可以得到加热烟草片的初步结构:如图1所示,图1中虽然已经将加热烟草片卷绕处理了,但是依旧可以看出,加热烟草片包括多孔金属箔片11和植物纤维12,多孔金属箔片11包括相对的正面和背面,植物纤维12包括位于多孔金属箔片11正面的黏结段、位于多孔金属箔片11的孔洞内的连接段、以及位于多孔金属箔片11背面的支撑段。Based on this step, the preliminary structure of the heated tobacco sheet can be obtained: as shown in Figure 1, although the heated tobacco sheet has been wound and processed in Figure 1, it can still be seen that the heated tobacco sheet includes a porous metal foil 11 and a plant The fiber 12, the porous metal foil 11 includes opposite front and back sides, the plant fiber 12 includes a bonding segment positioned at the front of the porous metal foil 11, a connecting segment positioned in the hole of the porous metal foil 11, and a bonding segment positioned at the porous metal foil 11. Support section on the back.

然后直接于多孔金属箔片11的正面喷洒20份胶粘剂,如图1所示,胶粘剂将植物纤维12的黏结段黏结在一起、并且黏结固定在多孔金属箔片11的正面上,固化后形成烟草层。Then directly spray 20 parts of adhesive on the front of the porous metal foil 11, as shown in Figure 1, the adhesive binds the bonding section of the plant fiber 12 together and is bonded and fixed on the front of the porous metal foil 11, and forms tobacco after curing. layer.

S3.于烟草层上覆盖一层塑料膜,得到正面遮盖、背面暴露的多孔金属箔片,备用。S3. Cover the tobacco layer with a layer of plastic film to obtain a porous metal foil with the front side covered and the back side exposed, and set aside.

按照质量份,将20份浓度为0.1 mol/L的硝酸铝和20份浓度为0.08mol/L的乙二胺四乙酸钠混合均匀得到混合溶液,将上述多孔金属箔片加入到混合溶液中,在搅拌状态下,将5份浓度为0.5mol/L的氨水以0.05mL/min的速度滴加到混合溶液中,然后在搅拌状态下,在150℃下反应2h后取出,剥离掉塑料膜,得到加热烟草片。According to parts by mass, 20 parts of aluminum nitrate with a concentration of 0.1 mol/L and 20 parts of sodium ethylenediaminetetraacetate with a concentration of 0.08 mol/L were mixed uniformly to obtain a mixed solution, and the above-mentioned porous metal foil was added to the mixed solution, Under stirring, add 5 parts of ammonia water with a concentration of 0.5mol/L dropwise at a rate of 0.05mL/min into the mixed solution, then react at 150°C for 2 hours under stirring, take it out, peel off the plastic film, A heated tobacco sheet is obtained.

基于此步骤,可以得到加热烟草片的最终结构:如图1所示,在多孔金属箔片11暴露的背面上、以及位于背面的植物纤维12支撑段上原位生成了氧化铝颗粒,植物纤维12较长的支撑段给予了氧化铝大量生长的基底,使得多孔金属箔片11背面形成若干大凸起结构(图1中仅画出少量示意)。Based on this step, the final structure of the heated tobacco sheet can be obtained: as shown in Figure 1, on the exposed back side of the porous metal foil 11, and on the plant fiber 12 support section on the back side, aluminum oxide particles have been generated in situ, and the plant fiber 12 The longer supporting section provides a substrate for the massive growth of alumina, so that several large convex structures are formed on the back of the porous metal foil 11 (only a few are schematically drawn in FIG. 1 ).

S4.将加热烟草片的一端作为固定端固定,另一端以所述固定端为中心不断卷绕,得到加热烟草主体。S4. Fix one end of the heated tobacco sheet as a fixed end, and continuously wind the other end around the fixed end to obtain a heated tobacco body.

基于此步骤,可以得到加热烟草主体的结构:如图1所示,加热烟草主体为由加热烟草片卷绕形成的纸卷结构,纸卷结构包括若干半径依次增大的片圈10,相邻片圈10之间形成烟气通道101。由于加热烟草片的背面具有若干大凸起结构,完成卷绕后,这些大凸起结构正好位于相邻两片圈10之间,形成支撑结构,避免了烟气通道101受外力而塌陷封闭。Based on this step, the structure of the heated tobacco body can be obtained: as shown in Figure 1, the heated tobacco body is a paper roll structure formed by winding heated tobacco sheets, and the paper roll structure includes several coils 10 with successively increasing radii. A flue gas channel 101 is formed between the rings 10 . Since the back of the heated tobacco sheet has several large convex structures, after winding, these large convex structures are just located between two adjacent coils 10, forming a support structure, which prevents the smoke channel 101 from being collapsed and closed by external force.

最后于加热烟草主体外包覆卷烟纸,得到卷烟的烟草段。Finally, the heated tobacco body is wrapped with cigarette paper to obtain the tobacco section of the cigarette.

实施例2Example 2

本实施例中电磁感应加热卷烟的结构与实施例1基本一致,仅在制备方法上有部分不同。The structure of the electromagnetic induction heating cigarette in this embodiment is basically the same as that in Embodiment 1, and only partly differs in the preparation method.

本实施例中:In this example:

S1.准备烟草液,按照质量份,将10份烟草提取液、5份烟用香精香料、12份作为雾化剂的甘油、3份葡萄糖酸内酯混合均匀。S1. To prepare tobacco liquid, mix 10 parts of tobacco extract liquid, 5 parts of tobacco flavor and fragrance, 12 parts of glycerin as an atomizing agent, and 3 parts of gluconolactone according to parts by mass.

实施例3Example 3

本实施例中电磁感应加热卷烟的结构与实施例1基本一致,仅在制备方法上有部分不同。The structure of the electromagnetic induction heating cigarette in this embodiment is basically the same as that in Embodiment 1, and only partly differs in the preparation method.

本实施例中:In this example:

S1.准备烟草液,按照质量份,将10份烟草提取液、5份烟用香精香料、12份作为雾化剂的甘油、3份浓度为0.1mol/L的氯化钙溶液混合均匀。S1. To prepare tobacco liquid, mix 10 parts of tobacco extract, 5 parts of tobacco flavor and fragrance, 12 parts of glycerin as an atomizer, and 3 parts of calcium chloride solution with a concentration of 0.1 mol/L according to parts by mass.

实施例4Example 4

本实施例中电磁感应加热卷烟的结构与实施例1基本一致,仅在制备方法上有部分不同。The structure of the electromagnetic induction heating cigarette in this embodiment is basically the same as that in Embodiment 1, and only partly differs in the preparation method.

本实施例中:In this example:

S1.准备烟草液,按照质量份,将10份烟草提取液、5份烟用香精香料、12份作为雾化剂的甘油、1份葡萄糖酸内酯、2份浓度为0.1mol/L的氯化钙溶液混合均匀。S1. To prepare tobacco liquid, according to mass parts, 10 parts of tobacco extract, 5 parts of tobacco flavor and fragrance, 12 parts of glycerin as atomizer, 1 part of gluconolactone, and 2 parts of chlorine with a concentration of 0.1mol/L Calcium solution mixed evenly.

实施例5Example 5

本实施例中电磁感应加热卷烟的结构与实施例1基本一致,仅在制备方法上有部分不同。The structure of the electromagnetic induction heating cigarette in this embodiment is basically the same as that in Embodiment 1, and only partly differs in the preparation method.

本实施例中:In this example:

S3.于烟草层上覆盖一层壳聚糖膜,得到正面遮盖、背面暴露的多孔金属箔片,备用。S3. Cover the tobacco layer with a layer of chitosan film to obtain a porous metal foil with the front side covered and the back side exposed, and set aside.

按照质量份,将20份浓度为0.1 mol/L的硝酸铝和20份浓度为0.08mol/L的乙二胺四乙酸钠混合均匀得到混合溶液,将上述多孔金属箔片加入到混合溶液中,在搅拌状态下,将5份浓度为0.5mol/L的氨水以0.05mL/min的速度滴加到混合溶液中,然后在搅拌状态下,在150℃下反应2h后取出,得到加热烟草片。According to parts by mass, 20 parts of aluminum nitrate with a concentration of 0.1 mol/L and 20 parts of sodium ethylenediaminetetraacetate with a concentration of 0.08 mol/L were mixed uniformly to obtain a mixed solution, and the above-mentioned porous metal foil was added to the mixed solution, Under stirring, 5 parts of ammonia water with a concentration of 0.5 mol/L was added dropwise to the mixed solution at a rate of 0.05 mL/min, then reacted at 150°C for 2 hours under stirring, and then taken out to obtain heated tobacco sheets.

实施例6Example 6

本实施例中电磁感应加热卷烟的结构与实施例1基本一致,仅在制备方法上有部分不同。The structure of the electromagnetic induction heating cigarette in this embodiment is basically the same as that in Embodiment 1, and only partly differs in the preparation method.

本实施例中:In this example:

S1.准备烟草液,按照质量份,将10份烟草提取液、10份烟用香精香料、7份作为雾化剂的柠檬酸、1份葡萄糖酸内酯、2份浓度为0.1mol/L的氯化钙溶液混合均匀。S1. To prepare tobacco liquid, according to parts by mass, 10 parts of tobacco extract, 10 parts of tobacco flavor and fragrance, 7 parts of citric acid as an atomizer, 1 part of gluconolactone, and 2 parts of 0.1mol/L The calcium chloride solution was mixed well.

植物纤维选用外径为0.5mm的芹菜纤维,将5份芹菜纤维浸渍在上述烟草液中,于50℃下浸渍1h后取出,于60℃的热风下烘干并打散,备用。The plant fibers are celery fibers with an outer diameter of 0.5 mm, 5 parts of celery fibers are immersed in the above tobacco liquid, soaked at 50°C for 1 hour, taken out, dried and dispersed under hot air at 60°C, and set aside.

S2.多孔金属箔片选用泡沫不锈钢片,取其任意一面为正面、与之相对的一面为背面。将其置于振动装置上,于正面上铺设步骤S1中处理后得到植物纤维。启动振动装置,使得多孔金属箔片和植物纤维一起交替进行上下振动和左右振动,振动频率为100Hz,振动至观测到多孔金属箔片的背面有延伸出来的植物纤维。然后直接于多孔金属箔片的正面喷洒10份胶粘剂,固化得到烟草层。S2. The porous metal foil is made of foamed stainless steel sheet, with any side as the front and the opposite side as the back. It is placed on a vibrating device, and the plant fiber obtained after processing in step S1 is laid on the front side. Start the vibrating device, so that the porous metal foil and the plant fibers alternately vibrate up and down and left and right, the vibration frequency is 100 Hz, and vibrate until plant fibers extending from the back of the porous metal foil are observed. Then directly spray 10 parts of adhesive on the front of the porous metal foil, and solidify to obtain the tobacco layer.

S3.于烟草层上覆盖一层塑料膜,得到正面遮盖、背面暴露的多孔金属箔片,备用。S3. Cover the tobacco layer with a layer of plastic film to obtain a porous metal foil with the front side covered and the back side exposed, and set aside.

按照质量份,将25份浓度为0.1 mol/L的硝酸镁和15份浓度为0.1mol/L的乙二胺四乙酸钠混合均匀得到混合溶液,将上述多孔金属箔片加入到混合溶液中,在搅拌状态下,将5份浓度为0.8mol/L的氨水以0.08mL/min的速度滴加到混合溶液中,然后在搅拌状态下,在200℃下反应1h后取出,剥离掉塑料膜,得到加热烟草片。According to parts by mass, 25 parts of magnesium nitrate with a concentration of 0.1 mol/L and 15 parts of sodium edetate with a concentration of 0.1 mol/L were mixed uniformly to obtain a mixed solution, and the above-mentioned porous metal foil was added to the mixed solution, Under stirring, 5 parts of ammonia water with a concentration of 0.8mol/L was added dropwise to the mixed solution at a rate of 0.08mL/min, and then reacted at 200°C for 1 hour under stirring, then removed, and the plastic film was peeled off. A heated tobacco sheet is obtained.

实施例7Example 7

本实施例中电磁感应加热卷烟的结构与实施例1基本一致,仅在制备方法上有部分不同。The structure of the electromagnetic induction heating cigarette in this embodiment is basically the same as that in Embodiment 1, and only partly differs in the preparation method.

本实施例中:In this example:

S1.准备烟草液,按照质量份,将15份烟草提取液、5份烟用香精香料、7份作为雾化剂的柠檬酸、2份葡萄糖酸内酯、1份浓度为0.1mol/L的氯化钙溶液混合均匀。S1. To prepare tobacco liquid, according to parts by mass, 15 parts of tobacco extract, 5 parts of tobacco flavor and fragrance, 7 parts of citric acid as atomizer, 2 parts of gluconolactone, 1 part of 0.1mol/L The calcium chloride solution was mixed well.

植物纤维选用外径为0.1mm的烟草纤维和芹菜纤维,将5份纤维浸渍在上述烟草液中,于40℃下浸渍5h后取出,于50℃的热风下烘干并打散,备用。Tobacco fibers and celery fibers with an outer diameter of 0.1 mm were selected as plant fibers, and 5 parts of fibers were dipped in the above-mentioned tobacco liquid, soaked at 40°C for 5 hours, then taken out, dried under hot air at 50°C and dispersed, and set aside.

S2.多孔金属箔片选用泡沫铁片,取其任意一面为正面、与之相对的一面为背面,将其置于振动装置上,于正面上铺设步骤S1中处理后得到植物纤维。启动振动装置,使得多孔金属箔片和植物纤维一起交替进行上下振动和左右振动,振动频率为20Hz,振动至观测到多孔金属箔片的背面有延伸出来的植物纤维。然后直接于多孔金属箔片的正面喷洒30份胶粘剂,固化得到烟草层。S2. The porous metal foil is made of foamed iron sheet, and any one side thereof is taken as the front side, and the opposite side is taken as the back side, which is placed on a vibrating device, and the plant fiber obtained in step S1 is laid on the front side. Start the vibrating device, so that the porous metal foil and the plant fibers alternately vibrate up and down and left and right together, the vibration frequency is 20 Hz, and vibrate until plant fibers extending from the back of the porous metal foil are observed. Then directly spray 30 parts of adhesive on the front of the porous metal foil, and solidify to obtain the tobacco layer.

S3.于烟草层上覆盖一层壳聚糖膜,得到正面遮盖、背面暴露的多孔金属箔片,备用。S3. Cover the tobacco layer with a layer of chitosan film to obtain a porous metal foil with the front side covered and the back side exposed, and set aside.

按照质量份,将25份浓度为0.1 mol/L的硝酸铝和15份浓度为0.05mol/L的N,N,N',N'-四(2-羟丙基)乙二胺混合均匀得到混合溶液,将上述多孔金属箔片加入到混合溶液中,在搅拌状态下,将5份浓度为0.2mol/L的氢氧化钠以0.04mL/min的速度滴加到混合溶液中,然后在搅拌状态下,在100℃下反应3h后取出,得到加热烟草片。In parts by mass, 25 parts of aluminum nitrate with a concentration of 0.1 mol/L and 15 parts of N,N,N',N'-tetrakis(2-hydroxypropyl)ethylenediamine with a concentration of 0.05 mol/L were uniformly mixed to obtain Mix the solution, add the above-mentioned porous metal foil to the mixed solution, and add 5 parts of sodium hydroxide with a concentration of 0.2mol/L dropwise to the mixed solution at a speed of 0.04mL/min under stirring, and then stir In the state, it was taken out after reacting at 100°C for 3 hours to obtain a heated tobacco sheet.

对比例1Comparative example 1

一种电磁感应加热卷烟,通过以下步骤制备:An electromagnetic induction heating cigarette is prepared through the following steps:

S1.准备烟草液,按照质量份,将5份外径为1mm的烟草纤维、10份烟草提取液、5份烟用香精香料、15份作为雾化剂的甘油、20份胶粘剂混合均匀,备用。S1. To prepare the tobacco liquid, mix 5 parts of tobacco fibers with an outer diameter of 1 mm, 10 parts of tobacco extract, 5 parts of tobacco essence and spices, 15 parts of glycerin as an atomizer, and 20 parts of adhesive according to parts by mass, and set aside .

S2.选用实心铁镍片,取其任意一面为正面、与之相对的一面为背面。将烟草液涂覆于正面上,固化后形成烟草层。S2. Choose a solid iron-nickel sheet, take any side as the front and the opposite side as the back. Tobacco liquid is coated on the front and cured to form a tobacco layer.

S3.于烟草层上覆盖一层塑料膜,得到正面遮盖、背面暴露的实心铁镍片,备用。S3. Cover the tobacco layer with a plastic film to obtain a solid iron-nickel sheet with the front side covered and the back side exposed, and set aside.

按照质量份,将20份浓度为0.1 mol/L的硝酸铝和20份浓度为0.08mol/L的乙二胺四乙酸钠混合均匀得到混合溶液,将上述多孔金属箔片加入到混合溶液中,在搅拌状态下,将5份浓度为0.5mol/L的氨水以0.05mL/min的速度滴加到混合溶液中,然后在搅拌状态下,在150℃下反应2h后取出,剥离掉塑料膜,得到加热烟草片。According to parts by mass, 20 parts of aluminum nitrate with a concentration of 0.1 mol/L and 20 parts of sodium edetate with a concentration of 0.08 mol/L were mixed uniformly to obtain a mixed solution, and the above-mentioned porous metal foil was added to the mixed solution, Under stirring, add 5 parts of ammonia water with a concentration of 0.5mol/L dropwise at a rate of 0.05mL/min into the mixed solution, then react at 150°C for 2 hours under stirring, take it out, peel off the plastic film, A heated tobacco sheet is obtained.

S4.将加热烟草片的一端作为固定端固定,另一端以所述固定端为中心不断卷绕,得到加热烟草主体。S4. Fix one end of the heated tobacco sheet as a fixed end, and continuously wind the other end around the fixed end to obtain a heated tobacco body.

【加热烟草主体的抗压强度检测】[Determination of compressive strength of heated tobacco body]

取实施例和对比例制得的加热烟草主体,采用型号为DE50A-2的压力试验机进行抗压强度检测。检测时,加热烟草主体轴向与压力试验机的压力方向垂直,检测结果如下表1。The heated tobacco bodies prepared in Examples and Comparative Examples were used to test the compressive strength with a compression testing machine modeled as DE50A-2. During testing, the axial direction of the heated tobacco body is perpendicular to the pressure direction of the pressure testing machine, and the testing results are shown in Table 1 below.

表1.Table 1.

Figure SMS_1
Figure SMS_1

通过表1中实施例1和对比例1的对比可知,通过金属氧化物的支撑,加热烟草主体的抗压强度明显增加,能够有效避免烟气通道的封闭。From the comparison of Example 1 and Comparative Example 1 in Table 1, it can be seen that the compressive strength of the heated tobacco body is significantly increased through the support of the metal oxide, which can effectively avoid the sealing of the smoke passage.

本文中所描述的具体实施例仅仅是对本发明精神作举例说明。本发明所属技术领域的技术人员可以对所描述的具体实施例做各种各样的修改或补充或采用类似的方式替代,但并不会偏离本发明的精神或者超越所附权利要求书所定义的范围。The specific embodiments described herein are merely illustrative of the spirit of the invention. Those skilled in the art to which the present invention belongs can make various modifications or supplements to the described specific embodiments or adopt similar methods to replace them, but they will not deviate from the spirit of the present invention or go beyond the definition of the appended claims range.

Claims (7)

1.一种电磁感应加热卷烟的制备方法,其特征在于:1. A preparation method for electromagnetic induction heating cigarettes, characterized in that: 所述电磁感应加热卷烟,包括烟草段,所述烟草段包括加热烟草主体、以及包覆于所述加热烟草主体外的卷烟纸,所述加热烟草主体为加热烟草片卷绕形成的纸卷结构,所述纸卷结构包括若干半径依次增大的片圈(10),相邻片圈(10)之间形成烟气通道(101);所述加热烟草片包括多孔金属箔片(11)和植物纤维(12),所述多孔金属箔片(11)包括相对的正面和背面,所述植物纤维(12)包括位于所述多孔金属箔片(11)正面的黏结段、位于所述多孔金属箔片(11)的孔洞内的连接段、以及位于所述多孔金属箔片(11)背面的支撑段;若干所述植物纤维(12)的黏结段通过胶粘剂黏结;若干所述植物纤维(12)的支撑段、以及所述多孔金属箔片(11)的背面设有金属氧化物颗粒(13);The electromagnetic induction heating cigarette includes a tobacco section, the tobacco section includes a heated tobacco body, and cigarette paper wrapped outside the heated tobacco body, and the heated tobacco body is a paper roll structure formed by winding heated tobacco sheets , the paper roll structure includes several coils (10) with successively increasing radii, and smoke channels (101) are formed between adjacent coils (10); the heated tobacco sheet includes porous metal foils (11) and The plant fiber (12), the porous metal foil (11) includes opposite front and back sides, the plant fiber (12) includes a bonding section on the front of the porous metal foil (11), The connection section in the hole of the foil (11) and the support section located on the back of the porous metal foil (11); the bonding sections of several plant fibers (12) are bonded by adhesive; the several plant fibers (12) ) and the back of the porous metal foil (11) are provided with metal oxide particles (13); 所述多孔金属箔片(11)包括泡沫不锈钢、泡沫铁、泡沫铁合金中的一种或几种;The porous metal foil (11) includes one or more of foamed stainless steel, foamed iron, and foamed iron alloy; 所述金属氧化物颗粒(13)包括氧化铝颗粒、氧化镁颗粒中的一种或两种;The metal oxide particles (13) include one or both of alumina particles and magnesium oxide particles; 所述电磁感应加热卷烟的制备方法,包括以下步骤:The preparation method of the electromagnetic induction heating cigarette comprises the following steps: S1.将植物纤维(12)浸渍于烟草液中后取出烘干,所述烟草液包括烟草提取物;S1. The plant fiber (12) is soaked in the tobacco liquid and then taken out and dried, and the tobacco liquid includes tobacco extract; S2.于多孔金属箔片(11)的正面上铺设植物纤维,振动后,于植物纤维(12)上喷洒胶粘剂,固化形成烟草层;S2. laying plant fibers on the front surface of the porous metal foil (11), and spraying adhesive on the plant fibers (12) after vibration, curing to form a tobacco layer; S3.于烟草层上覆盖遮盖物,得到正面遮盖、背面暴露的多孔金属箔片(11);将多孔金属箔片(11)加入到金属前驱体和络合剂的混合溶液中,然后向混合溶液中滴加沉淀剂,于100-200℃下反应后取出,得到加热烟草片;S3. Cover the tobacco layer with a covering to obtain a porous metal foil (11) with the front covered and the back exposed; add the porous metal foil (11) to the mixed solution of the metal precursor and complexing agent, and then add the porous metal foil (11) to the mixture Add a precipitating agent dropwise into the solution, take it out after reacting at 100-200°C, and obtain heated tobacco sheets; S4.将加热烟草片的一端作为固定端固定,另一端以所述固定端为中心不断卷绕,得到加热烟草主体;于加热烟草主体外包覆卷烟纸,得到卷烟的烟草段。S4. Fix one end of the heated tobacco sheet as a fixed end, and continuously wind the other end around the fixed end to obtain a heated tobacco body; wrap the heated tobacco body with cigarette paper to obtain a tobacco segment of a cigarette. 2.根据权利要求1所述的一种电磁感应加热卷烟的制备方法,其特征在于:所述植物纤维(12)的外径不超过1mm。2. The method for preparing electromagnetic induction heating cigarettes according to claim 1, characterized in that: the outer diameter of the plant fibers (12) does not exceed 1 mm. 3.根据权利要求1所述的一种电磁感应加热卷烟的制备方法,其特征在于:所述烟草液还包括葡萄糖酸内酯。3 . The method for preparing electromagnetic induction heating cigarettes according to claim 1 , wherein the tobacco liquid further includes gluconolactone. 4 . 4.根据权利要求1所述的一种电磁感应加热卷烟的制备方法,其特征在于:所述烟草液还包括氯化钙。4 . The method for preparing electromagnetic induction heating cigarettes according to claim 1 , wherein the tobacco liquid further includes calcium chloride. 5.根据权利要求1所述的一种电磁感应加热卷烟的制备方法,其特征在于:所述遮盖物为塑料膜,步骤S4中,卷绕之前,剥离所述遮盖物。5 . The method for preparing electromagnetic induction heating cigarettes according to claim 1 , wherein the cover is a plastic film, and in step S4 , the cover is peeled off before winding. 6 . 6.根据权利要求1所述的一种电磁感应加热卷烟的制备方法,其特征在于:所述遮盖物为壳聚糖膜。6 . The method for preparing electromagnetic induction heating cigarettes according to claim 1 , wherein the covering is a chitosan film. 7 . 7.根据权利要求1所述的一种电磁感应加热卷烟的制备方法,其特征在于:步骤S2中,所述振动包括横向振动和纵向振动,所述纵向振动的振动方向与所述多孔金属箔片(11)垂直,所述横向振动的振动方向与所述多孔金属箔片(11)平行。7. A method for preparing electromagnetic induction heating cigarettes according to claim 1, characterized in that in step S2, the vibration includes transverse vibration and longitudinal vibration, and the vibration direction of the longitudinal vibration is the same as that of the porous metal foil The sheet (11) is vertical, and the vibration direction of the transverse vibration is parallel to the porous metal foil (11).
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