CN114236887A - Spacer manufacturing device and display panel - Google Patents
Spacer manufacturing device and display panel Download PDFInfo
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- CN114236887A CN114236887A CN202111526658.2A CN202111526658A CN114236887A CN 114236887 A CN114236887 A CN 114236887A CN 202111526658 A CN202111526658 A CN 202111526658A CN 114236887 A CN114236887 A CN 114236887A
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- spacer
- color filter
- filter substrate
- spacer material
- curing
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Images
Classifications
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/1303—Apparatus specially adapted to the manufacture of LCDs
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133509—Filters, e.g. light shielding masks
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1339—Gaskets; Spacers; Sealing of cells
- G02F1/13394—Gaskets; Spacers; Sealing of cells spacers regularly patterned on the cell subtrate, e.g. walls, pillars
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Mathematical Physics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Liquid Crystal (AREA)
Abstract
The invention provides a spacer manufacturing device and a display panel. The spacer manufacturing device comprises a first heating component, an exposure component, a developing component, a photocuring component and a second heating component, wherein the first heating component is used for carrying out first heating treatment on the color filter substrate coated with the spacer material so as to carry out first curing on the spacer material; the exposure component is used for carrying out exposure treatment on the spacer material after the first curing; the developing component is used for developing the spacer material after exposure treatment; the light curing component is used for carrying out secondary curing treatment on the spacer material subjected to exposure and development treatment; the second heating component is used for carrying out second heating treatment on the spacer material after the second curing to obtain the spacer. The invention can obtain finer spacers, and can reduce the loss of the aperture opening ratio of the display panel caused by the spacers under the condition of ensuring the pressure resistance of the display panel.
Description
Technical Field
The invention relates to the technical field of display, in particular to a spacer manufacturing device and a display panel.
Background
In the liquid crystal display panel, the spacer is used for supporting the thickness of a liquid crystal box, so that liquid crystal deflection is facilitated. The density of the spacers affects the aperture ratio and the compressive resistance of the liquid crystal display. The higher the aperture ratio, the higher the efficiency of light passing through, and the higher the display luminance of the display panel. The compressive resistance affects the resistance of the display panel to deformation.
In the prior art, the opening rate and the pressure resistance are generally in an inversely related relationship. That is, if the pressure resistance of the display panel is increased, the density of the spacers needs to be increased, which results in a decrease in the aperture ratio of the display panel.
Disclosure of Invention
Based on the above-mentioned deficiencies in the prior art, an object of the present invention is to provide a spacer manufacturing apparatus and a display panel, which can reduce the loss of the aperture ratio of the display panel caused by the spacer while ensuring the pressure resistance of the display panel.
In order to achieve the above object, the present invention provides a spacer manufacturing apparatus, comprising:
the first heating component is used for carrying out first heating treatment on the color filter substrate coated with the spacer material so as to carry out first curing on the spacer material;
the exposure component is used for carrying out exposure treatment on the spacer material after the first curing;
a developing member for developing the spacer material after the exposure treatment;
the light curing component is used for carrying out secondary curing treatment on the spacer material subjected to exposure and development treatment;
the second heating component is used for carrying out second heating treatment on the spacer material subjected to second curing to obtain a spacer;
the spacer comprises a first bottom surface, a second bottom surface and a side surface, the first bottom surface is positioned on the color filter substrate, the area of the first bottom surface is larger than or equal to that of the second bottom surface, and an included angle between the side surface and the first bottom surface is 60-90 degrees.
Alternatively, a light curing member is provided above or below the color filter substrate, and light emitted from the light curing member is irradiated to the upper surface or the lower surface of the spacer material.
Optionally, the device further comprises a vacuum box for performing vacuum treatment on the color filter substrate coated with the spacer material placed in the vacuum box to pre-cure the spacer material.
Optionally, the second heating member includes a baking oven, and when the spacer material after the second curing is subjected to the second heating process, the temperature of the baking oven is 200 to 300 degrees celsius.
Optionally, the color filter further comprises a coating member for coating the spacer material on the color filter substrate.
Optionally, the coating member comprises:
a storage unit for storing a spacer material;
the moving unit is used for driving the storage unit to move;
the identification unit is used for identifying the shape of the color filter substrate and acquiring the area of the color filter substrate;
and the control unit is used for determining the coating amount of the spacer material according to the area of the color filter substrate, sending an instruction to the moving unit, enabling the moving unit to drive the storage unit to move in the range of the color filter substrate, and controlling the discharge nozzle of the storage unit to be closed or opened.
Optionally, the color filter substrate cleaning device further comprises a cleaning component, wherein the cleaning component is used for cleaning the color filter substrate before the spacer material is coated on the color filter substrate.
The invention also provides a display panel, which comprises a color filter substrate, a thin film transistor array substrate and a liquid crystal layer, wherein the color filter substrate is provided with a spacer which supports the color filter substrate and the thin film transistor array substrate;
the spacer is manufactured by the spacer manufacturing device and comprises a first bottom surface, a second bottom surface and a side surface, the first bottom surface is positioned on the color filter substrate, the area of the first bottom surface is larger than or equal to that of the second bottom surface, and the included angle between the side surface and the first bottom surface is 60-90 degrees.
Optionally, the spacers include a first spacer and a second spacer, the first spacer is disposed on the substrate of the color filter substrate and contacts with the thin film transistor array substrate, and the second spacer is disposed on the substrate of the color filter substrate.
Optionally, the height of the second spacer is smaller than that of the first spacer, and the bottom surface area of the second spacer is smaller than that of the first spacer.
Compared with the prior art, the invention has the beneficial effects that at least: the spacer manufacturing apparatus of the present invention includes a first heating member, an exposure member, a developing member, a photo-curing member, and a second heating member. The first heating component is used for carrying out first heating treatment on the color filter substrate coated with the spacer material so as to enable the spacer material to be cured for the first time; the exposure component is used for carrying out exposure treatment on the spacer material after the first curing; the developing component is used for developing the spacer material after exposure treatment; the light curing component is used for carrying out secondary curing treatment on the spacer material subjected to exposure and development treatment; the second heating component is used for carrying out second heating treatment on the spacer material after the second curing to obtain the spacer. The spacer comprises a first bottom surface, a second bottom surface and a side surface, wherein the first bottom surface is positioned on the color filter substrate, the area of the first bottom surface is larger than or equal to that of the second bottom surface, and an included angle between the side surface and the first bottom surface is 60-90 degrees, so that the shape of the spacer is as close to a cylindrical shape as possible. In the prior art, an included angle between the side surface of the spacer and the first bottom surface is generally 40 ° to 60 °, so that the area difference between the first bottom surface and the second bottom surface is large, and the first bottom surface needs to occupy a large area of the color filter substrate. According to the invention, the shape of the spacer is close to a cylinder, the area difference between the first bottom surface and the second bottom surface is smaller, the area of the first bottom surface is smaller than that of the first bottom surface of the spacer in the prior art, and under the same spacer density, the area of the color filter substrate occupied by the spacer is smaller, so that the aperture ratio loss of the display panel is reduced.
Drawings
In order to illustrate the embodiments or the technical solutions in the prior art more clearly, the drawings needed to be used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the invention, and it is obvious for a person skilled in the art that other drawings can be obtained according to these drawings without creative efforts.
FIG. 1 is a frame diagram of a spacer producing apparatus according to an embodiment of the present invention;
FIG. 2 is a schematic perspective view of a spacer according to an embodiment of the present invention;
FIG. 3 is a cross-sectional view of a spacer according to an embodiment of the present invention;
FIG. 4 is a cross-sectional view of a prior art spacer;
FIG. 5 is a block diagram of a coating member according to an embodiment of the present invention;
FIG. 6 is a diagram illustrating a method for manufacturing a spacer according to an embodiment of the present invention;
FIG. 7 is a flow chart of a method of making a spacer according to an embodiment of the present invention;
FIG. 8 is a first view of a spacer according to an embodiment of the present invention;
FIG. 9 is a second view of a spacer according to an embodiment of the present invention;
FIG. 10 is a third view of a spacer according to an embodiment of the present invention;
FIG. 11 is a fourth illustration of a spacer in accordance with an embodiment of the present invention;
FIG. 12 is a schematic view of a spacer that is not subjected to a photo-curing treatment according to an embodiment of the present invention;
FIG. 13 is a first view of a spacer after photo-curing in accordance with one embodiment of the present invention;
FIG. 14 is a second schematic view of a spacer after photo-curing in accordance with an embodiment of the present invention;
FIG. 15 is a third schematic view of a spacer after photo-curing in accordance with an embodiment of the present invention;
fig. 16 is a cross-sectional view of a display panel according to an embodiment of the present invention.
Detailed Description
The following description of the various embodiments refers to the accompanying drawings that illustrate specific embodiments in which the invention may be practiced. In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", and the like, indicate orientations and positional relationships based on those shown in the drawings, and are used only for convenience of description and simplicity of description, and do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be considered as limiting the present invention. Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, features defined as "first", "second", may explicitly or implicitly include one or more of the described features. In the description of the present invention, "a plurality" means two or more unless specifically defined otherwise.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; may be mechanically connected, may be electrically connected or may be in communication with each other; either directly or indirectly through intervening media, either internally or in any other relationship. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
In the present invention, unless otherwise expressly stated or limited, "above" or "below" a first feature means that the first and second features are in direct contact, or that the first and second features are not in direct contact but are in contact with each other via another feature therebetween. Also, the first feature being "on," "above" and "over" the second feature includes the first feature being directly on and obliquely above the second feature, or merely indicating that the first feature is at a higher level than the second feature. A first feature being "under," "below," and "beneath" a second feature includes the first feature being directly under and obliquely below the second feature, or simply meaning that the first feature is at a lesser elevation than the second feature.
An embodiment of the present invention provides a spacer manufacturing apparatus, as shown in fig. 1, including a first heating member 1, an exposure member 2, a developing member 3, a photo-curing member 4, and a second heating member 5. The first heating member 1 is used for carrying out first heating treatment on the color filter substrate 100 coated with the spacer material 200 so as to carry out first curing on the spacer material 200; the exposure member 2 is used for performing exposure treatment on the spacer material 200 after the first curing; the developing member 3 is used for performing a developing process on the spacer material 200 after the exposure process; the light-curing member 4 is used for carrying out a second curing process on the spacer material 200 subjected to the exposure and development process; the second heating member 5 is used to perform a second heating process on the spacer material 200 after the second curing to obtain a spacer. As shown in fig. 2, the spacer of the present invention can be similar to a cylindrical structure, and includes a first bottom surface S1, a second bottom surface S2 and a side surface S3, the first bottom surface is located on the color filter substrate 100, the area of the first bottom surface is greater than or equal to the area of the second bottom surface, and as shown in fig. 3, the included angle θ between the side surface S3 and the first bottom surface S1 is 60 ° to 90 °.
The spacer material 200 may be a photoresist. After the spacer material 200 is exposed and developed, the surface of the spacer material 200 is in strong contact with a light source to generate strong cross-linking reaction, so that an inverted trapezoidal columnar structure is formed. After the photo-curing process, the cross-linking reaction on the surface and the bottom of the spacer material 200 is further enhanced, and the phenomenon of solvent flow inside the spacer material 200 is inhibited. After the post-baking process, a large amount of solvent components in the spacer material 200 volatilize, the surface of the spacer material 200 collapses downwards to form a regular trapezoidal columnar structure, so that the shape of the spacer is as close to a cylinder as possible, and a finer spacer is formed.
In the prior art, as shown in fig. 4, an included angle θ between the side surface S3 of the spacer and the first bottom surface S1 is generally 40 ° to 60 °, so that the area difference between the first bottom surface S1 and the second bottom surface S2 is large, and the first bottom surface S1 needs to occupy a large area of the color filter substrate 100. In the invention, the shape of the spacer is approximate to a cylinder, the area difference between the first bottom surface S1 and the second bottom surface S2 is smaller, the area of the first bottom surface S1 is smaller than that of the first bottom surface S1 of the spacer in the prior art, and under the same density of the spacer, the area of the color filter substrate 100 occupied by the spacer is smaller, thereby reducing the aperture ratio loss of the display panel.
In one embodiment, the first heating member 1 may be a heating plate, and the color filter substrate 100 is placed on the heating plate, and the heating plate starts to generate heat, so that the spacer material 200 on the color filter substrate 100 is heated to start the first curing.
In one embodiment, a mask is disposed over the spacer material 200, and the exposure member 2 emits UV (ultraviolet) light, which is irradiated on the spacer material 200 through the mask. The developing member 3 may spray KOH developing solution to the spacer material 200 to pattern the spacer material 200, facilitating formation of the spacer.
In one embodiment, the light curing member 4 is disposed above or below the color filter substrate 100, and the light emitted from the light curing member 4 is irradiated to the upper surface or the lower surface of the spacer material 200. The light-curing member 4 irradiates the spacer material 200 with UV (ultraviolet) light, and the spacer material 200 is cured. The position where the light curing member 4 is disposed may be selected according to the production environment. The light-cured member 4 is beneficial to reduce the solvent flow of the spacer material 200 and reduce the surface collapse, so that the spacer material 200 is formed into a spacer shape closer to a cylindrical shape.
In one embodiment, the spacer manufacturing apparatus further includes a vacuum chamber 6 for vacuum-treating the color filter substrate 100 coated with the spacer material 200 placed in the vacuum chamber 6 to pre-cure the spacer material 200. The spacer material 200 can be rapidly solidified in a vacuum environment, and the curing speed is accelerated.
In one embodiment, the second heating member 5 includes a baking oven, and the temperature of the baking oven is 200 ℃ to 300 ℃ when the second heat treatment is performed on the spacer material 200 after the second curing. In the present embodiment, 230 ℃ may be preferable. After the baking process, the solvent component in the spacer material 200 is largely volatilized, and the surface of the spacer material 200 is downwardly collapsed to form the spacer with the trapezoidal columnar structure.
In one embodiment, the spacer manufacturing apparatus further includes a coating member 7, and the coating member 7 is used for coating the spacer material 200 on the color filter substrate 100.
Specifically, as shown in fig. 5, the coating member 7 may include a storage unit 71, a moving unit 72, an identifying unit 73, and a control unit 74. The storage unit 71 is used to store the spacer material 200. The moving unit 72 is used for driving the storage unit 71 to move. The recognition unit 73 is used to recognize the shape of the color filter substrate 100 and acquire the area of the color filter substrate 100. The control unit 74 is used for determining the coating amount of the spacer material 200 according to the area of the color filter substrate 100, sending an instruction to the moving unit 72, enabling the moving unit 72 to drive the storage unit 71 to move in the range of the color filter substrate 100, and controlling the discharge nozzle of the storage unit 71 to be closed or opened.
The coating member 7 of the embodiment can automatically identify the size and shape of the color filter substrate 100, and then accurately control the spraying amount of the spacer material 200, thereby avoiding that the spacer cannot be effectively formed due to too small spraying amount of the spacer material 200, or that the resource is wasted due to too much spraying amount of the spacer material 200.
In one embodiment, the spacer manufacturing apparatus further includes a cleaning component 8, and the cleaning component 8 is used for cleaning the color filter substrate 100 before the spacer material 200 is coated on the color filter substrate 100. This prevents impurities on the color filter substrate 100 from affecting the generation of spacers.
The spacer manufacturing device of the embodiment is beneficial to improving the aperture opening ratio of the liquid crystal panel display; the problem of poor liquid crystal deflection caused by the adhesion of the spacers due to the small interval between the spacers of the high PPI product is solved; the cost investment of a high-resolution exposure machine is reduced; the fineness of the spacer material 200 is improved, and the research and development and operation costs brought by new material development are reduced.
The embodiment of the invention also provides a spacer manufacturing method, which provides a spacer manufacturing device by using the embodiment, as shown in fig. 6 and 7, and comprises the following steps:
in step 100, the color filter substrate 100 is cleaned by a cleaning agent through the cleaning member 8.
In step 200, a spacer material 200 is coated on the cleaned color filter substrate 100 by the coating member 7. The spacer material 200 may be a photoresist.
In step 500, the spacer material 200 after the first curing is subjected to exposure processing by the exposure means 2. The shape of the spacer material 200 at this time is as shown in fig. 8.
In step 600, the spacer material 200 after the exposure process is subjected to a development process by the developing unit 3. The shape of the spacer material 200 at this time is as shown in fig. 9.
In step 700, the developed spacer material 200 is subjected to a second curing process by the photo-curing member 4. The shape of the spacer material 200 at this time is as shown in fig. 10.
In this step, the crosslinking reaction on the surface and bottom of the spacer material 200 is further enhanced, and the phenomenon of solvent flow inside the spacer material 200 is suppressed. Wherein, UV light is adopted for light curing treatment, the illumination intensity of the UV light is different, and the shapes of the finally formed spacers are also different.
In step 800, the second heating treatment is performed on the spacer material 200 after the second curing by the second heating member 5, so as to obtain a spacer, the shape of which is shown in fig. 11. In this step, a large amount of solvent components in the spacer material 200 volatilize, and the surface of the spacer material 200 collapses downward to form a trapezoidal columnar structure, and finally a finer spacer is obtained. Wherein the baking temperature of the second heating may be 230 ℃.
In step 700, when the photo-curing treatment is not performed, that is, the UV light irradiation intensity is 0mJ/cm2The shape of the spacer is shown in figure 12; when the UV illumination intensity is 10mJ/cm2The shape of the spacer is shown in figure 13; when the UV illumination intensity is 100mJ/cm2Diaphragm (c)The shape of the pad is shown in figure 14; when the UV illumination intensity is 300mJ/cm2The shape of the spacer is shown in fig. 15.
An embodiment of the invention provides a display panel, as shown in fig. 16, including a color filter substrate 100, a thin film transistor array substrate 300 and a liquid crystal layer 400, wherein a spacer 210 is disposed on the color filter substrate 100, and the spacer 210 supports the color filter substrate 100 and the thin film transistor array substrate 300.
The spacer 210 is manufactured by the spacer manufacturing apparatus provided in the above embodiment, the spacer 210 includes a first bottom surface S1, a second bottom surface S2 and a side surface S3, the first bottom surface S1 is located on the color filter substrate 100, an area of the first bottom surface S1 is greater than or equal to an area of the second bottom surface S2, and an included angle θ between the side surface S3 and the first bottom surface S1 is 60 ° to 90 °. The shape of the spacer 210 may be similar to a circular truncated cone structure or a cylindrical structure.
In one embodiment, the spacers 210 include a first spacer 211 and a second spacer 212, the first spacer 211 is disposed on the color filter substrate 100 and contacts the tft array substrate 300, and the second spacer 212 is disposed on the color filter substrate 100. The first spacers 211 mainly support the color filter substrate 100 and the tft array substrate 300, and the second spacers 212 also play an auxiliary role when the display panel is pressed.
In one embodiment, the height of the second spacer 212 is less than the height of the first spacer 211. When the display panel receives pressure, the first spacers 211 are pressed to generate micro deformation, so that the height of the first spacers 211 is reduced, when the pressure is increased to a certain degree, the height of the first spacers 211 is reduced to be the same as the height of the second spacers 212, and at this time, the second spacers 212 and the first spacers 211 simultaneously support the color filter substrate 100 and the thin film transistor array substrate 300. The pressure resistance of the display panel is improved. On the color filter substrate 100, the area of the bottom surface of the second spacer 212 is smaller than that of the first spacer 211, so that the loss of the aperture ratio of the display panel caused by the second spacer can be reduced.
Compared with the spacer in the prior art, the spacer of the embodiment is finer, and is beneficial to improving the aperture opening ratio of the liquid crystal panel display; the problem of poor liquid crystal deflection caused by the adhesion of the spacers due to the small interval between the spacers of the high PPI product is solved; the cost investment of a high-resolution exposure machine is reduced; the fineness of the spacer material 200 is improved, and the research and development and operation costs brought by new material development are reduced.
The spacer 210 of the display panel of the invention is finer, which is beneficial to improving the aperture opening ratio of the liquid crystal panel display; the problem of poor liquid crystal deflection caused by the adhesion of the spacers 210 due to the small interval between the spacers of the high PPI product is solved; the cost investment of a high-resolution exposure machine is reduced; the material fineness of the spacer is improved, and the research and development and operation costs brought by new material development are reduced.
The embodiment of the invention also provides a manufacturing method of the display panel, which comprises the following steps:
firstly, a color filter glass plate is provided, then RGB color resistance layers are manufactured under the color filter glass plate, and a liquid crystal layer, a black matrix and a TFT (thin film transistor) array are arranged under the RGB color resistance layers. Meanwhile, the spacer is generated in the middle of the liquid crystal layer by adopting the spacer manufacturing method provided by the embodiment. And obtaining the liquid crystal display panel with higher pressure resistance and aperture opening ratio in turn.
In one embodiment, the black matrix is used to prevent color mixing between pixels or light leakage at the edge of the color film substrate. The composition for manufacturing the black matrix comprises a light shielding material, resin, a polymer monomer, a photoinitiator and a solvent; wherein the light-shielding material comprises mesoporous carbon.
Specifically, in the composition for the black matrix, the mass percentages of the components are as follows: 10-25% of resin, 2-8% of polymer monomer, 10-20% of shading material, 3-7% of photoinitiator and 56-65% of solvent. The black matrix 13 prepared using the composition for the black matrix 13 can achieve a good light-shielding effect.
In one embodiment, in the composition for a black matrix, the mass percentages of the components are: 20% of resin, 5% of polymer monomer, 10% of light shielding material, 5% of photoinitiator and 60% of solvent. In the composition for the black matrix 13 provided in this embodiment, the solvent can sufficiently dissolve the light-shielding material, the resin, the polymer monomer, and the photoinitiator, and the mesoporous carbon can be uniformly dispersed in the resin, so that agglomeration is prevented, thereby blocking the transmission path of electrons.
Wherein the resin is used for maintaining the chemical and mechanical properties of the composition, and specifically can be one or more of phenolic resin, acrylic resin, polyvinyl alcohol cinnamate and siloxane resin.
The polymer monomer is a micromolecule containing a polymerizable functional group, is used for improving the crosslinking degree, improving the flexibility of a film layer, reducing the viscosity of resin and the like, can be a free radical type monomer or a cationic monomer, or a combination of the free radical and the cationic monomer, and specifically can be one or more combinations of acrylate monomers, vinyl ether monomers and epoxy monomers.
Among them, the photoinitiator is not particularly limited, and an existing material can be used as the photoinitiator. For example, one or a mixture of more than one of benzoin, benzophenone and anthraquinone photoinitiators.
The solvent may be propylene glycol methyl ether acetate, ethyl acetate, butyl acetate, 3-methoxybutyl acetate, or ethyl 3-ethoxypropionate, and can sufficiently dissolve the light-shielding material, the resin, the polymer monomer, and the photoinitiator, and adjust physical properties such as viscosity of the obtained composition for the black matrix 13.
The mesoporous carbon is a novel non-silicon-based mesoporous material and has huge specific surface area and pore volume. Mesoporous carbon generally refers to a mesoporous material in which the main component constituting the mesoporous material is carbon element, and examples of the mesoporous carbon include, but are not limited to, one or any combination of CMK-1, CMK-2, CMK-3, CMK-4, CMK-5, C-MSU-H, N-OMC, G-CMK-3, OMC, and the like.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present invention are included in the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.
Claims (10)
1. A spacer manufacturing device is characterized by comprising:
the first heating component is used for carrying out first heating treatment on the color filter substrate coated with the spacer material so as to enable the spacer material to be cured for the first time;
the exposure component is used for carrying out exposure treatment on the spacer material after the first curing;
a developing member for developing the spacer material after the exposure treatment;
the light curing component is used for carrying out secondary curing treatment on the spacer material subjected to exposure and development treatment;
the second heating component is used for carrying out second heating treatment on the spacer material subjected to second curing to obtain a spacer;
the shock insulator comprises a first bottom surface, a second bottom surface and a side surface, the first bottom surface is located on the color filter substrate, the area of the first bottom surface is larger than or equal to that of the second bottom surface, and an included angle between the side surface and the first bottom surface is 60-90 degrees.
2. The spacer producing apparatus according to claim 1, wherein the photo-curing member is provided above or below the color filter substrate, and light emitted from the photo-curing member is irradiated to an upper surface or a lower surface of the spacer material.
3. The spacer producing apparatus according to claim 1, further comprising a vacuum chamber for vacuum-treating the color filter substrate coated with the spacer material placed in the vacuum chamber to pre-cure the spacer material.
4. The spacer manufacturing apparatus according to claim 1, wherein the second heating means includes a baking oven, and the temperature of the baking oven is 200 to 300 degrees celsius when the spacer material after the second curing is subjected to the second heating process.
5. The spacer producing apparatus according to any one of claims 1 to 4, further comprising a coating member for coating a spacer material on the color filter substrate.
6. The spacer making device according to claim 5, wherein said coating member comprises:
a storage unit for storing the spacer material;
the moving unit is used for driving the storage unit to move;
the identification unit is used for identifying the shape of the color filter substrate and acquiring the area of the color filter substrate;
and the control unit is used for determining the coating amount of the spacer material according to the area of the color filter substrate, sending an instruction to the moving unit, enabling the moving unit to drive the storage unit to move in the range of the color filter substrate, and controlling the discharge nozzle of the storage unit to be closed or opened.
7. The spacer producing apparatus according to claim 5, further comprising a cleaning member for cleaning the color filter substrate before the spacer material is applied to the color filter substrate.
8. A display panel is characterized by comprising a color filter substrate, a thin film transistor array substrate and a liquid crystal layer, wherein a spacer is arranged on the color filter substrate and supports the color filter substrate and the thin film transistor array substrate;
the spacer is manufactured by the spacer manufacturing device according to any one of claims 1 to 7, and the spacer includes a first bottom surface, a second bottom surface and a side surface, the first bottom surface is located on the color filter substrate, the area of the first bottom surface is greater than or equal to the area of the second bottom surface, and the included angle between the side surface and the first bottom surface is 60 degrees to 90 degrees.
9. The display panel according to claim 8, wherein the spacers include a first spacer and a second spacer, the first spacer being disposed on the color filter substrate and contacting the thin film transistor array substrate, and the second spacer being disposed on the color filter substrate.
10. The display panel according to claim 9, wherein the second spacer has a height smaller than that of the first spacer, and a bottom surface area of the second spacer is smaller than that of the first spacer.
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CN105549273A (en) * | 2016-02-03 | 2016-05-04 | 京东方科技集团股份有限公司 | Spacer making method, substrate, display panel and display device |
CN107402471A (en) * | 2017-09-07 | 2017-11-28 | 深圳市华星光电半导体显示技术有限公司 | Liquid crystal display panel and preparation method thereof |
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CN1501129A (en) * | 2002-11-14 | 2004-06-02 | ���ǵ�����ʽ���� | Panel for liquid crystal display and manufacturing method thereof |
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