CN114236412B - BP neural network-based battery health state diagnosis method and system - Google Patents
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Abstract
本发明公开了一种基于BP神经网络的电池健康状态诊断方法及系统,方法包括:采集充电桩和电动汽车电池的数据,构建原始数据序列;对原始数据序列进行一阶累加,生成数据时间序列;将数据时间序列的一部分作为模型输入,另一部分作为模型输出,进行模型训练,构建BP神经网络模型;系统包括数据采集模块、数据处理模块、数据分析模块和预测模块,通过各个模块之间的逻辑连接,实现对于电池健康状态的健康预测;本发明构思巧妙,预测准确,为电池的健康管理提供了技术参考。
The present invention discloses a battery health status diagnosis method and system based on BP neural network, the method comprising: collecting data of charging piles and electric vehicle batteries to construct an original data sequence; performing first-order accumulation on the original data sequence to generate a data time series; using a part of the data time series as a model input and the other part as a model output, performing model training, and constructing a BP neural network model; the system comprises a data acquisition module, a data processing module, a data analysis module, and a prediction module, and a healthy prediction of the battery health status is achieved through the logical connection between the modules; the present invention has ingenious conception and accurate prediction, and provides a technical reference for battery health management.
Description
技术领域Technical Field
本申请涉及电动汽车电池检测技术领域,具体而言,涉及一种基于BP神经网络的电池健康状态诊断方法及系统。The present application relates to the technical field of electric vehicle battery detection, and in particular to a battery health status diagnosis method and system based on a BP neural network.
背景技术Background technique
电动汽车电池分两大类,蓄电池和燃料电池。蓄电池适用于纯电动汽车,包括铅酸蓄电池、镍氢电池、钠硫电池、二次锂电池、空气电池、三元锂电池。Electric vehicle batteries are divided into two categories, storage batteries and fuel cells. Storage batteries are suitable for pure electric vehicles, including lead-acid batteries, nickel-metal hydride batteries, sodium-sulfur batteries, secondary lithium batteries, air batteries, and ternary lithium batteries.
燃料电池专用于燃料电池电动汽车,包括碱性燃料电池(AFC)、磷酸燃料电池(PAFC)、熔融碳酸盐燃料电池(MCFC)、固体氧化物燃料电池(SOFC)、质子交换膜燃料电池(PEMFC)、直接甲醇燃料电池(DMFC)Fuel cells are specifically used in fuel cell electric vehicles, including alkaline fuel cells (AFC), phosphoric acid fuel cells (PAFC), molten carbonate fuel cells (MCFC), solid oxide fuel cells (SOFC), proton exchange membrane fuel cells (PEMFC), direct methanol fuel cells (DMFC)
随着电动汽车的种类不同而略有差异。在仅装备蓄电池的纯电动汽车中,蓄电池的作用是汽车驱动系统的唯一动力源。而在装备传统发动机(或燃料电池)与蓄电池的混合动力汽车中,蓄电池既可扮演汽车驱动系统主要动力源的角色,也可充当辅助动力源的角色。可见在低速和启动时,蓄电池扮演的是汽车驱动系统主要动力源的角色;在全负荷加速时,充当的是辅助动力源的角色;在正常行驶或减速、制动时充当的是储存能量的角色。There are slight differences depending on the type of electric vehicle. In a pure electric vehicle equipped with only batteries, the battery serves as the sole power source for the vehicle's drive system. In a hybrid vehicle equipped with a traditional engine (or fuel cell) and a battery, the battery can serve as both the main power source and the auxiliary power source for the vehicle's drive system. It can be seen that at low speeds and when starting, the battery serves as the main power source for the vehicle's drive system; when accelerating at full load, it serves as an auxiliary power source; and when driving normally or decelerating or braking, it serves as an energy storage system.
随着电动汽车的广泛应用,那么,电动汽车的电池的健康管理将有利于电动汽车的维护以及行业技术发展,现有技术中,对于电动汽车电池的健康管理方法很多,但大多是通过检测电池本身性能实现健康管理,对于实际应用中都较为不便,由于电动汽车需要不定期充电,而充电桩又属于必备充电设备,那么,可以通过设计一种电池健康管理方法,通过收集电动汽车的充电数据对电池性能进行预测。With the widespread use of electric vehicles, the health management of electric vehicle batteries will be beneficial to the maintenance of electric vehicles and the development of industry technology. In the existing technology, there are many health management methods for electric vehicle batteries, but most of them achieve health management by detecting the performance of the battery itself, which is inconvenient for practical applications. Since electric vehicles need to be charged from time to time, and charging piles are essential charging equipment, a battery health management method can be designed to predict battery performance by collecting charging data of electric vehicles.
发明内容Summary of the invention
为了解决上述问题,本发明提供了一种基于BP神经网络的电池健康状态诊断方法,包括以下步骤:In order to solve the above problems, the present invention provides a battery health status diagnosis method based on BP neural network, comprising the following steps:
采集电动汽车的电池全生命周期运行数据,构建第一原始数据序列;Collect the battery operation data of electric vehicles throughout their life cycle and construct the first original data sequence;
对第一原始数据序列进行一阶累加,生成第一数据序列,其中,第一数据序列包括第一时间序列和第二时间序列,第一时间序列和第二时间序列用于表示电池全生命周期的特定时间段内的第一数据集合;Performing first-order accumulation on the first original data sequence to generate a first data sequence, wherein the first data sequence includes a first time series and a second time series, and the first time series and the second time series are used to represent a first data set within a specific time period of the entire life cycle of the battery;
将第一时间序列作为模型输入,第二时间序列作为模型输出,进行模型训练,构建第一BP神经网络模型;The first time series is used as the model input, and the second time series is used as the model output, and the model training is performed to construct a first BP neural network model;
采集充电桩的高频充电数据,构建第二原始数据序列;Collect high-frequency charging data of the charging pile and construct a second original data sequence;
对第二原始数据序列进行一介累加,生成第二数据序列,其中,第二数据序列包括第三时间序列和第四时间序列,第三时间序列和第四时间序列用于表示高频充电数据在特定时间段内的第二数据集合;Performing accumulation on the second original data sequence to generate a second data sequence, wherein the second data sequence includes a third time series and a fourth time series, and the third time series and the fourth time series are used to represent a second data set of high-frequency charging data within a specific time period;
将第二时间序列作为模型输入,将第二时间序列作为模型输出,进行模型训练,构建第二BP神经网络模型;Taking the second time series as model input and the second time series as model output, performing model training, and constructing a second BP neural network model;
分别对第一BP神经网络模型和第二BP神经网络模型赋值第一权重和第二权重,构建BP神经网络模型,BP神经网络模型用于根据当前的高频充电数据和电池运行数据,预测电池健康情况。The first BP neural network model and the second BP neural network model are assigned a first weight and a second weight respectively to construct a BP neural network model, and the BP neural network model is used to predict the battery health status according to the current high-frequency charging data and battery operation data.
优选地,第一原始数据序列或第二原始数据序列的表达式为:Preferably, the expression of the first original data sequence or the second original data sequence is:
X(0)={x(0)(1),x(0)(2),...,x(0)(n)}X (0) = {x (0) (1), x (0) (2),..., x (0) (n)}
其中,X(0)表示原始数据序列,x(0)(n)表示原始数据序列的第n个数据。Wherein, X (0) represents the original data sequence, and x (0) (n) represents the nth data in the original data sequence.
优选地,在生成第一数据序列或第二数据序列的过程中,一阶累加的过程为:Preferably, in the process of generating the first data sequence or the second data sequence, the first-order accumulation process is:
优选地,第一数据序列或第二数据序列的表达式为:Preferably, the expression of the first data sequence or the second data sequence is:
X(1)={x(1)(1),x(1)(2),...,x(1)(n)}。X (1) = {x (1) (1), x (1) (2), ..., x (1) (n)}.
优选地,在构建BP神经网络模型的过程中,构建BP神经网络模型包括输入层、隐藏层、输出层;Preferably, in the process of constructing the BP neural network model, the BP neural network model includes an input layer, a hidden layer, and an output layer;
隐藏层的隐层节点根据公式计算确定,m为输入神经元的个数,p为输出神经元的个数,q为1~10之间的常数。The hidden nodes of the hidden layer are calculated according to the formula Calculated and determined, m is the number of input neurons, p is the number of output neurons, and q is a constant between 1 and 10.
优选地,在构建第一BP神经网络模型或第二BP神经网络模型的过程中,第一BP神经网络模型或第二BP神经网络模型的方程表达式为:Preferably, in the process of constructing the first BP neural network model or the second BP neural network model, the equation expression of the first BP neural network model or the second BP neural network model is:
一种基于BP神经网络的电池健康状态诊断系统,包括:A battery health status diagnosis system based on BP neural network, comprising:
第一数据模块,用于采集电动汽车的电池全生命周期运行数据,构建第一原始数据序列;A first data module is used to collect the battery life cycle operation data of the electric vehicle and construct a first original data sequence;
第一数据处理模块,用于对第一原始数据序列进行一阶累加,生成第一数据序列,其中,第一数据序列包括第一时间序列和第二时间序列,第一时间序列和第二时间序列用于表示电池全生命周期的特定时间段内的第一数据集合;A first data processing module, used for performing first-order accumulation on the first original data sequence to generate a first data sequence, wherein the first data sequence includes a first time series and a second time series, and the first time series and the second time series are used to represent a first data set within a specific time period of the entire life cycle of the battery;
第一数据分析模块,用于将第一时间序列作为模型输入,第二时间序列作为模型输出,进行模型训练,构建第一BP神经网络模型;A first data analysis module is used to use the first time series as a model input and the second time series as a model output, perform model training, and construct a first BP neural network model;
第二数据采集模块,用于采集充电桩的高频充电数据,构建第二原始数据序列;A second data acquisition module is used to collect high-frequency charging data of the charging pile and construct a second original data sequence;
第二数据处理模块,用于对第二原始数据序列进行一介累加,生成第二数据序列,其中,第二数据序列包括第三时间序列和第四时间序列,第三时间序列和第四时间序列用于表示高频充电数据在特定时间段内的第二数据集合;A second data processing module, used for performing accumulation on the second original data sequence to generate a second data sequence, wherein the second data sequence includes a third time series and a fourth time series, and the third time series and the fourth time series are used to represent a second data set of high-frequency charging data within a specific time period;
第二数据分析模块,将第二时间序列作为模型输入,将第二时间序列作为模型输出,进行模型训练,构建第二BP神经网络模型;The second data analysis module uses the second time series as a model input and the second time series as a model output to perform model training and construct a second BP neural network model;
状态预测模块,用于分别对第一BP神经网络模型和第二BP神经网络模型赋值第一权重和第二权重,构建BP神经网络模型,BP神经网络模型用于根据当前的高频充电数据和电池运行数据,预测电池健康情况。The state prediction module is used to assign a first weight and a second weight to the first BP neural network model and the second BP neural network model respectively, and construct a BP neural network model. The BP neural network model is used to predict the battery health status according to the current high-frequency charging data and battery operation data.
优选地,电池健康状态诊断系统还包括:Preferably, the battery health status diagnosis system further includes:
数据存储模块,用于存储第一数据集合、第二数据集合以及其他系统数据;A data storage module, used for storing the first data set, the second data set and other system data;
通信模块,用于电池健康状态诊断系统的数据交互工作;Communication module, used for data exchange of battery health status diagnosis system;
显示模块,用于显示系统数据以及电池健康情况;Display module, used to display system data and battery health status;
定位模块,用于对充电桩、电动汽车定位,并分别获取充电桩和电动汽车的位置信息;A positioning module is used to locate the charging pile and the electric vehicle, and obtain the location information of the charging pile and the electric vehicle respectively;
区块链模块,用于将系统数据上传至联盟链,并将系统数据存储至私有链。The blockchain module is used to upload system data to the alliance chain and store system data in the private chain.
优选地,电池健康状态诊断系统还包括一种计算机程序,应用于电池健康状态诊断系统,用于实现电池健康状态诊断方法。Preferably, the battery health state diagnosis system further includes a computer program, which is applied to the battery health state diagnosis system and is used to implement the battery health state diagnosis method.
优选地,电池健康状态诊断系统应用在一种电池健康状态诊断诊断装置中,电池健康状态诊断装置包括北斗定位装置、电压传感器、电流传感器、温度传感器、环境温度传感器、5G通信天线、存储器、芯片;电池健康状态诊断装置分别设置在充电桩、电动汽车中,用于充电桩对电动汽车进行识别定位,并进行数据采集后,将采集数据传输到后台服务器或云端服务器进行数据处理。Preferably, the battery health status diagnostic system is applied in a battery health status diagnostic device, which includes a Beidou positioning device, a voltage sensor, a current sensor, a temperature sensor, an ambient temperature sensor, a 5G communication antenna, a memory, and a chip; the battery health status diagnostic device is respectively arranged in a charging pile and an electric vehicle, and is used for the charging pile to identify and locate the electric vehicle, and after data collection, the collected data is transmitted to a background server or a cloud server for data processing.
本发明公开了以下技术效果:The present invention discloses the following technical effects:
本发明提出的方法和系统,通过采集充电桩数据以及电池全生命数据,生成的BP神经网络模型,该模型融合充电数据后,能够对电池全生命周期进行预测,并且预测准确,为电动汽车电池的生命周期预测提供了新的技术见解,并对电池的健康预测提出的新的技术思路。The method and system proposed in the present invention collect charging pile data and battery life data to generate a BP neural network model. After the model integrates the charging data, it can predict the entire life cycle of the battery and the prediction is accurate, providing new technical insights for the life cycle prediction of electric vehicle batteries and proposing new technical ideas for battery health prediction.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings required for use in the embodiments will be briefly introduced below. Obviously, the drawings described below are only some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative labor.
图1为本发明所述的方法流程图。FIG. 1 is a flow chart of the method of the present invention.
具体实施方式Detailed ways
下为使本申请实施例的目的、技术方案和优点更加清楚,下面将结合本申请实施例中附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。通常在此处附图中描述和示出的本申请实施例的组件可以以各种不同的配置来布置和设计。因此,以下对在附图中提供的本申请的实施例的详细描述并非旨在限制要求保护的本申请的范围,而是仅仅表示本申请的选定实施例。基于本申请的实施例,本领域技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purpose, technical scheme and advantages of the embodiments of the present application clearer, the technical scheme in the embodiments of the present application will be clearly and completely described below in conjunction with the drawings in the embodiments of the present application. Obviously, the described embodiments are only part of the embodiments of the present application, rather than all of the embodiments. The components of the embodiments of the present application generally described and shown in the drawings here can be arranged and designed in various different configurations. Therefore, the following detailed description of the embodiments of the present application provided in the drawings is not intended to limit the scope of the application claimed for protection, but merely represents the selected embodiments of the present application. Based on the embodiments of the present application, all other embodiments obtained by those skilled in the art without making creative work belong to the scope of protection of the present application.
如图1所示,本发明提供了一种基于BP神经网络的电池健康状态诊断方法,其特征在于,包括以下步骤:As shown in FIG1 , the present invention provides a battery health status diagnosis method based on BP neural network, which is characterized by comprising the following steps:
采集电动汽车的电池全生命周期运行数据,构建第一原始数据序列;Collect the battery operation data of electric vehicles throughout their life cycle and construct the first original data sequence;
对第一原始数据序列进行一阶累加,生成第一数据序列,其中,第一数据序列包括第一时间序列和第二时间序列,第一时间序列和第二时间序列用于表示电池全生命周期的特定时间段内的第一数据集合;Performing first-order accumulation on the first original data sequence to generate a first data sequence, wherein the first data sequence includes a first time series and a second time series, and the first time series and the second time series are used to represent a first data set within a specific time period of the entire life cycle of the battery;
将第一时间序列作为模型输入,第二时间序列作为模型输出,进行模型训练,构建第一BP神经网络模型;The first time series is used as the model input, and the second time series is used as the model output, and the model training is performed to construct a first BP neural network model;
采集充电桩的高频充电数据,构建第二原始数据序列;Collect high-frequency charging data of the charging pile and construct a second original data sequence;
对第二原始数据序列进行一介累加,生成第二数据序列,其中,第二数据序列包括第三时间序列和第四时间序列,第三时间序列和第四时间序列用于表示高频充电数据在特定时间段内的第二数据集合;Performing accumulation on the second original data sequence to generate a second data sequence, wherein the second data sequence includes a third time series and a fourth time series, and the third time series and the fourth time series are used to represent a second data set of high-frequency charging data within a specific time period;
将第二时间序列作为模型输入,将第二时间序列作为模型输出,进行模型训练,构建第二BP神经网络模型;Taking the second time series as model input and the second time series as model output, performing model training, and constructing a second BP neural network model;
分别对第一BP神经网络模型和第二BP神经网络模型赋值第一权重和第二权重,构建BP神经网络模型,BP神经网络模型用于根据当前的高频充电数据和电池运行数据,预测电池健康情况。The first BP neural network model and the second BP neural network model are assigned a first weight and a second weight respectively to construct a BP neural network model, and the BP neural network model is used to predict the battery health status according to the current high-frequency charging data and battery operation data.
进一步优选地,第一原始数据序列或第二原始数据序列的表达式为:Further preferably, the expression of the first original data sequence or the second original data sequence is:
X(0)={x(0)(1),x(0)(2),...,x(0)(n)}X (0) = {x (0) (1), x (0) (2),..., x (0) (n)}
其中,X(0)表示原始数据序列,x(0)(n)表示原始数据序列的第n个数据。Wherein, X (0) represents the original data sequence, and x (0) (n) represents the nth data in the original data sequence.
进一步优选地,在生成第一数据序列或第二数据序列的过程中,一阶累加的过程为:Further preferably, in the process of generating the first data sequence or the second data sequence, the first-order accumulation process is:
进一步优选地,第一数据序列或第二数据序列的表达式为:Further preferably, the expression of the first data sequence or the second data sequence is:
X(1)={x(1)(1),x(1)(2),...,x(1)(n)}。X (1) = {x (1) (1), x (1) (2), ..., x (1) (n)}.
进一步优选地,在构建BP神经网络模型的过程中,构建BP神经网络模型包括输入层、隐藏层、输出层;Further preferably, in the process of constructing the BP neural network model, the BP neural network model includes an input layer, a hidden layer, and an output layer;
隐藏层的隐层节点根据公式计算确定,m为输入神经元的个数,p为输出神经元的个数,q为1~10之间的常数。The hidden nodes of the hidden layer are calculated according to the formula Calculated and determined, m is the number of input neurons, p is the number of output neurons, and q is a constant between 1 and 10.
进一步优选地,在构建第一BP神经网络模型或第二BP神经网络模型的过程中,第一BP神经网络模型或第二BP神经网络模型的方程表达式为:Further preferably, in the process of constructing the first BP neural network model or the second BP neural network model, the equation expression of the first BP neural network model or the second BP neural network model is:
一种基于BP神经网络的电池健康状态诊断系统,包括:A battery health status diagnosis system based on BP neural network, comprising:
第一数据模块,用于采集电动汽车的电池全生命周期运行数据,构建第一原始数据序列;A first data module is used to collect the battery life cycle operation data of the electric vehicle and construct a first original data sequence;
第一数据处理模块,用于对第一原始数据序列进行一阶累加,生成第一数据序列,其中,第一数据序列包括第一时间序列和第二时间序列,第一时间序列和第二时间序列用于表示电池全生命周期的特定时间段内的第一数据集合;A first data processing module, used for performing first-order accumulation on the first original data sequence to generate a first data sequence, wherein the first data sequence includes a first time series and a second time series, and the first time series and the second time series are used to represent a first data set within a specific time period of the entire life cycle of the battery;
第一数据分析模块,用于将第一时间序列作为模型输入,第二时间序列作为模型输出,进行模型训练,构建第一BP神经网络模型;A first data analysis module is used to use the first time series as a model input and the second time series as a model output, perform model training, and construct a first BP neural network model;
第二数据采集模块,用于采集充电桩的高频充电数据,构建第二原始数据序列;A second data acquisition module is used to collect high-frequency charging data of the charging pile and construct a second original data sequence;
第二数据处理模块,用于对第二原始数据序列进行一介累加,生成第二数据序列,其中,第二数据序列包括第三时间序列和第四时间序列,第三时间序列和第四时间序列用于表示高频充电数据在特定时间段内的第二数据集合;A second data processing module, used for performing accumulation on the second original data sequence to generate a second data sequence, wherein the second data sequence includes a third time series and a fourth time series, and the third time series and the fourth time series are used to represent a second data set of high-frequency charging data within a specific time period;
第二数据分析模块,将第二时间序列作为模型输入,将第二时间序列作为模型输出,进行模型训练,构建第二BP神经网络模型;The second data analysis module uses the second time series as a model input and the second time series as a model output to perform model training and construct a second BP neural network model;
状态预测模块,用于分别对第一BP神经网络模型和第二BP神经网络模型赋值第一权重和第二权重,构建BP神经网络模型,BP神经网络模型用于根据当前的高频充电数据和电池运行数据,预测电池健康情况。The state prediction module is used to assign a first weight and a second weight to the first BP neural network model and the second BP neural network model respectively, and construct a BP neural network model. The BP neural network model is used to predict the battery health status according to the current high-frequency charging data and battery operation data.
进一步优选地,电池健康状态诊断系统还包括:Further preferably, the battery health status diagnosis system further includes:
数据存储模块,用于存储第一数据集合、第二数据集合以及其他系统数据;A data storage module, used for storing the first data set, the second data set and other system data;
通信模块,用于电池健康状态诊断系统的数据交互工作;Communication module, used for data exchange of battery health status diagnosis system;
显示模块,用于显示系统数据以及电池健康情况;Display module, used to display system data and battery health status;
定位模块,用于对充电桩、电动汽车定位,并分别获取充电桩和电动汽车的位置信息;A positioning module is used to locate the charging pile and the electric vehicle, and obtain the location information of the charging pile and the electric vehicle respectively;
区块链模块,用于将系统数据上传至联盟链,并将系统数据存储至私有链。The blockchain module is used to upload system data to the alliance chain and store system data in the private chain.
进一步优选地,电池健康状态诊断系统还包括一种计算机程序,应用于电池健康状态诊断系统,用于实现电池健康状态诊断方法。Further preferably, the battery health status diagnosis system also includes a computer program, which is applied to the battery health status diagnosis system and is used to implement the battery health status diagnosis method.
进一步优选地,电池健康状态诊断系统应用在一种电池健康状态诊断诊断装置中,电池健康状态诊断装置包括北斗定位装置、电压传感器、电流传感器、温度传感器、环境温度传感器、5G通信天线、存储器、芯片;电池健康状态诊断装置分别设置在充电桩、电动汽车中,用于充电桩对电动汽车进行识别定位,并进行数据采集后,将采集数据传输到后台服务器或云端服务器进行数据处理。Further preferably, the battery health status diagnostic system is applied in a battery health status diagnostic device, which includes a Beidou positioning device, a voltage sensor, a current sensor, a temperature sensor, an ambient temperature sensor, a 5G communication antenna, a memory, and a chip; the battery health status diagnostic device is respectively arranged in a charging pile and an electric vehicle, and is used for the charging pile to identify and locate the electric vehicle, and after data collection, the collected data is transmitted to a background server or a cloud server for data processing.
实施例1:建立不等权灰色BP神经网络组合模型;Embodiment 1: Establishing an unequal weight grey BP neural network combination model;
(1)建立原始灰色预测模型(1) Establishing the original grey prediction model
建立原始数据序列:Create the original data sequence:
X(0)={x(0)(1),x(0)(2),...,x(0)(n)} (1)X (0) = {x (0) (1), x (0) (2),..., x (0) (n)} (1)
根据下式(2)According to the following formula (2)
对原始数据序列X(0)进行一阶累加,生成1-AGO序列:Perform first-order accumulation on the original data sequence X (0) to generate a 1-AGO sequence:
X(1)={x(1)(1),x(1)(2),...,x(1)(n)} (3)X (1) ={x (1) (1),x (1) (2),...,x (1) (n)} (3)
(2)原始灰色预测模型不等权优化(2) Unequal weight optimization of original grey prediction model
原始灰色预测模型仅对原始序列进行等权累加,并未考虑时间因素对于预测结果的影响,而在实际情况中,越接近预测的时间序列所含信息量越大,越能体现未来发展的趋势,所分配权重也应越大。因此采用层次分析法对原始灰色预测模型进行进一步优化,邀请专家采用德尔菲法对各因素两两比较,进行评估,分别确定近期时间序列权重为λ1,远期的权重为λ2,原始灰色预测模型不等权优化为:The original grey prediction model only performs equal weight accumulation of the original sequence, and does not consider the impact of time factors on the prediction results. In actual situations, the closer the time series is to the prediction, the greater the amount of information it contains, the more it can reflect the trend of future development, and the greater the weight assigned. Therefore, the hierarchical analysis method is used to further optimize the original grey prediction model, and experts are invited to use the Delphi method to compare and evaluate each factor pairwise, and determine the weight of the recent time series as λ1 and the weight of the long-term as λ2. The original grey prediction model is optimized to unequal weights:
进而生成不等权1-AGO序列模型:Then generate the unequal weight 1-AGO sequence model:
X′(1)={x′(1)(1),x′(1)(2),...,x′(1)(n)} (5)X′ (1) ={x′ (1) (1),x′ (1) (2),...,x′ (1) (n)} (5)
BP神经网络设计BP neural network design
建立一个含有输入层、隐层、输出层的三层网络:Establish a three-layer network with input layer, hidden layer, and output layer:
①在不等权1-AGO序列模型中选取时间序列值{x′(1)(1),x′(1)(2),...,x′(1)(m)}(m<n)作为BP神经网络的输入层;① In the unequal-weight 1-AGO sequence model, the time series values {x′ (1) (1), x′ (1) (2), ..., x′ (1) (m)} (m < n) are selected as the input layer of the BP neural network;
②以x′(1)(m+1)作为BP神经网络的输出层;②Use x′ (1) (m+1) as the output layer of the BP neural network;
③隐层节点可根据公式计算确定,m为输入神经元的个数,p为输出神经元的个数,q为1~10之间的常数;③The hidden layer nodes can be calculated according to the formula Calculate and determine, m is the number of input neurons, p is the number of output neurons, and q is a constant between 1 and 10;
④利用训练好的BP神经网络进行预测,对预测序列利用累减还原即得到对未来的预测值。④ Use the trained BP neural network to make predictions, and use cumulative reduction to restore the prediction sequence to get the predicted value for the future.
化学电池品种繁多,性能各异。常用以表征其性能的指标有:电性能、机械性能、贮存性能等,有时还包括使用性能和经济成本。我们主要介绍其电性能和贮存性能。电性能包括:电动势、额定电压、开路电压、工作电压、终止电压、充电电压、内阻、容量、比能量和比功率、贮存性能和自放电、寿命等。贮存性能主要取决于电池的自放电大小。There are many types of chemical batteries with different performances. The indicators commonly used to characterize their performance are: electrical properties, mechanical properties, storage performance, etc., and sometimes also include performance and economic cost. We mainly introduce its electrical properties and storage performance. Electrical properties include: electromotive force, rated voltage, open circuit voltage, operating voltage, termination voltage, charging voltage, internal resistance, capacity, specific energy and specific power, storage performance and self-discharge, life, etc. Storage performance mainly depends on the self-discharge of the battery.
电动势Electromotive force
电池的电动势,又称电池标准电压或理论电压,为电池断路时正负两极间的电位差。The electromotive force of a battery, also known as the standard voltage or theoretical voltage of the battery, is the potential difference between the positive and negative poles when the battery is disconnected.
额定电压Rated voltage
额定电压(或公称电压),系指该电化学体系的电池工作时公认的标准电压。Rated voltage (or nominal voltage) refers to the recognized standard voltage when the battery of this electrochemical system is working.
开路电压Open circuit voltage
电池的开路电压是无负荷情况下的电池电压。开路电压不等于电池的电动势。必须指出,电池的电动势是从热力学函数计算而得到的,而电池的开路电压则是实际测量出来的。The open circuit voltage of a battery is the battery voltage under no-load conditions. The open circuit voltage is not equal to the electromotive force of the battery. It must be pointed out that the electromotive force of the battery is calculated from the thermodynamic function, while the open circuit voltage of the battery is actually measured.
工作电压Operating Voltage
系指电池在某负载下实际的放电电压,通常是指一个电压范围。Refers to the actual discharge voltage of the battery under a certain load, usually referring to a voltage range.
⑸终止电压⑸Termination voltage
系指放电终止时的电压值,视负载和使用要求不同而异。It refers to the voltage value at the end of discharge, which varies depending on the load and usage requirements.
充电电压Charging voltage
系指外电路直流电压对电池充电的电压。一般的充电电压要大于电池的开路电压,通常在一定的范围内Refers to the voltage of the external circuit DC voltage charging the battery. The general charging voltage is greater than the open circuit voltage of the battery, usually within a certain range.
内阻Internal resistance
蓄电池的内阻包括:正负极板的电阻,电解液的电阻,隔板的电阻和连接体的电阻等。The internal resistance of the battery includes: the resistance of the positive and negative plates, the resistance of the electrolyte, the resistance of the separator and the resistance of the connector, etc.
正负极电阻Positive and negative resistance
普遍使用的铅酸蓄电池正、负极板为涂膏式,由铅锑合金或铅钙合金板栅架和活性物质两部分构成。因此,极板电阻也由板栅电阻和活性物质电阻组成。板栅在活性物质内层,充放电时,不会发生化学变化,所以它的电阻是板栅的固有电阻。活性物质的电阻是随着电池充放电状态的不同而变化的。The commonly used positive and negative plates of lead-acid batteries are paste-coated, consisting of a lead-antimony alloy or lead-calcium alloy grid frame and an active material. Therefore, the plate resistance is also composed of the grid resistance and the active material resistance. The grid is in the inner layer of the active material and will not undergo chemical changes during charging and discharging, so its resistance is the inherent resistance of the grid. The resistance of the active material changes with the different charging and discharging states of the battery.
当电池放电时,极板的活性物质转变为硫酸铅(PbSO4),硫酸铅含量越大,其电阻越大。而电池充电时将硫酸铅还原为铅(Pb),硫酸铅含量越小,其电阻越小。When the battery is discharged, the active material of the plate is converted into lead sulfate (PbSO4). The higher the lead sulfate content, the greater its resistance. When the battery is charged, the lead sulfate is reduced to lead (Pb). The lower the lead sulfate content, the lower its resistance.
电解液电阻Electrolyte resistance
电解液的电阻视其浓度不同而异。在规定的浓度范围内一旦选定某一浓度后,电解液电阻将随充放电程度而变。电池充电时,在极板活性物质还原的同时电解液浓度增加,其电阻下降;电池放电时,在极板活性物质硫酸化的同时电解液浓度下降,其电阻增加。The resistance of the electrolyte varies depending on its concentration. Once a certain concentration is selected within the specified concentration range, the electrolyte resistance will change with the degree of charge and discharge. When the battery is charged, the electrolyte concentration increases while the plate active material is reduced, and its resistance decreases; when the battery is discharged, the electrolyte concentration decreases while the plate active material is sulfated, and its resistance increases.
隔板电阻Separator resistance
隔板的电阻视其孔率而异,新电池的隔板电阻是趋于一个固定值,但随电池运行时间的延长,其电阻有所增加。因为,电池在运行过程中有些铅渣和其他沉积物在隔板上,使得隔板孔率有所下降而增加了电阻。The resistance of the separator varies depending on its porosity. The resistance of the separator of a new battery tends to be fixed, but as the battery runs longer, its resistance increases. This is because some lead slag and other deposits are deposited on the separator during the operation of the battery, which reduces the porosity of the separator and increases the resistance.
连接体电阻Connector resistance
连接体包括单体电池串联时连接条等金属的固有电阻,电池极板间的连接电阻,以及正、负极板组成极群的连接体的金属电阻,若焊接和连接接触良好,连接体电阻可视为一固定电阻。The connector includes the inherent resistance of metals such as connecting bars when single cells are connected in series, the connection resistance between battery plates, and the metal resistance of the connector that forms the electrode group of positive and negative plates. If the welding and connection contact are good, the connector resistance can be regarded as a fixed resistance.
每只电池所呈现的内阻就是上述物体电阻的总和,电池内阻R与电动势、端电压及放电电流的关系:Rs=(E-Uf)÷IfThe internal resistance of each battery is the sum of the resistances of the above objects. The relationship between the battery internal resistance R and the electromotive force, terminal voltage and discharge current is: Rs = (E-Uf) ÷ If
电池的内阻在放电过程中会逐渐增加,而在充电过程中则逐渐减小。所以,电池在充放电过程中,端电压也会因其内阻的变化而变动。故端电压在放电时低于电池的电动势,充电时又高于电池的电动势。The internal resistance of the battery will gradually increase during the discharge process, and gradually decrease during the charging process. Therefore, during the charging and discharging process of the battery, the terminal voltage will also change due to the change of its internal resistance. Therefore, the terminal voltage is lower than the electromotive force of the battery during discharge, and higher than the electromotive force of the battery during charging.
容量capacity
电池的容量单位为库仑(C)或安时(Ah)。表征电池容量特性的专用术语有三个:The capacity of a battery is measured in coulombs (C) or ampere-hours (Ah). There are three special terms that characterize battery capacity characteristics:
a.理论容量。系指根据参加电化学反应的活性物质电化学当量数计算得到的电量。通常,理论上1电化当量物质将放出1法拉第电量,即96500C或26.8Ah(1电化当量物质的量,等于活性物质的原子量或分子量除以反应的电子数)。a. Theoretical capacity. Refers to the amount of electricity calculated based on the number of electrochemical equivalents of active substances participating in the electrochemical reaction. Generally, theoretically, 1 electrochemical equivalent of substance will release 1 Faraday of electricity, that is, 96500C or 26.8Ah (the amount of 1 electrochemical equivalent of substance is equal to the atomic weight or molecular weight of the active substance divided by the number of electrons in the reaction).
b.额定容量。系指在设计和生产电池时,规定或保证在指定放电条件下电池应该放出的最低限度的电量。b. Rated capacity: refers to the minimum amount of electricity that should be discharged by the battery under specified discharge conditions, which is stipulated or guaranteed when the battery is designed and produced.
c.实际容量。系指在一定的放电条件下,即在一定的放电电流和温度下,电池在终止电压前所能放出的电量。c. Actual capacity. It refers to the amount of electricity that the battery can discharge before the termination voltage under certain discharge conditions, that is, under certain discharge current and temperature.
电池的实际容量通常比额定容量大10%~20%。The actual capacity of a battery is usually 10% to 20% greater than its rated capacity.
电池容量的大小,与正、负极上活性物质的数量和活性有关,也与电池的结构和制造工艺与电池的放电条件(电流、温度)有关。The capacity of a battery is related to the quantity and activity of active materials on the positive and negative electrodes, as well as the structure and manufacturing process of the battery and the discharge conditions (current and temperature) of the battery.
影响电池容量因素的综合指标是活性物质的利用率。换言之,活性物质利用得越充分,电池给出的容量也就越高。The comprehensive index of factors affecting battery capacity is the utilization rate of active materials. In other words, the more fully the active materials are utilized, the higher the capacity of the battery.
活性物质的利用率可以定义为:The utilization rate of active substances can be defined as:
利用率=(电池实际容量/电池理论容量)×100%Utilization rate = (battery actual capacity/battery theoretical capacity) × 100%
或,利用率=(活性物质理论用量/活性物质实际用量)×100%。Or, utilization rate = (theoretical amount of active substance/actual amount of active substance) × 100%.
比能量Specific Energy
电池的输出能量是指在一定的放电条件下,电池所能作出的电功,它等于电池的放电容量和电池平均工作电压的乘积,其单位常用瓦时(Wh)表示。The output energy of a battery refers to the electrical work that the battery can produce under certain discharge conditions. It is equal to the product of the battery's discharge capacity and the battery's average operating voltage. Its unit is usually expressed in watt-hours (Wh).
电池的比能量有两种。一种叫重量比能量,用瓦时/千克(Wh/kg)表示;另一种叫体积比能量,用瓦时/升(Wh/L)表示。比能量的物理意义是电池为单位重量或单位体积时所具有的有效电能量。它的比较电池性能优劣的重要指标。There are two types of battery specific energy. One is called weight specific energy, expressed in watt-hours/kilogram (Wh/kg); the other is called volume specific energy, expressed in watt-hours/liter (Wh/L). The physical meaning of specific energy is the effective electrical energy of the battery per unit weight or unit volume. It is an important indicator for comparing the performance of batteries.
比功率Specific power
电池的功率是指在一定的放电条件下,电池在单位时间内所能输出的能量。单位是瓦(W),或千瓦(kW)。电池的单位重量或单位体积的功率称为电池的比功率,它的单位是瓦/千克(W/kg)或瓦/升(W/L)。如果一个电池的比功率较大,则表明在单位时间内,单位重量或单位体积中给出的能量较多,即表示此电池能用较大的电流放电。因此,电池的比功率也是评价电池性能优劣的重要指标之一。The power of a battery refers to the energy that the battery can output per unit time under certain discharge conditions. The unit is watt (W) or kilowatt (kW). The power per unit weight or per unit volume of a battery is called the specific power of the battery, and its unit is watt/kilogram (W/kg) or watt/liter (W/L). If the specific power of a battery is large, it means that more energy is given per unit weight or per unit volume per unit time, which means that the battery can be discharged with a larger current. Therefore, the specific power of a battery is also one of the important indicators for evaluating the performance of a battery.
贮存性能Storage performance
电池经过干贮存(不带电解液)或湿贮存(带电解液)一定时间后,其容量会自行降低,这个现象称自放电。所谓“贮存性能”是指电池开路时,在一定的条件下(如温度、湿度)贮存一定时间后自放电的大小。After a certain period of dry storage (without electrolyte) or wet storage (with electrolyte), the capacity of the battery will decrease automatically. This phenomenon is called self-discharge. The so-called "storage performance" refers to the self-discharge of the battery after being stored for a certain period of time under certain conditions (such as temperature and humidity) when the battery is open-circuited.
电池在贮存期间,虽然没有放出电能量,但是在电池内部总是存在着自放电现象。即使是干贮存,也会由于密封不严,进入水份、空气及二氧化碳等物质,使处于热力学不稳定状态的部分正极和负极活性物质构成微电池腐蚀机理,自行发生氧化还原反应而白白消耗掉。如果是湿贮存,更是如此。长期处在电解液中的活性物质也是不稳定的。负极活性物质大多是活泼金属,都会发生阳极自溶。酸性溶液中,负极金属是不稳定的,在碱性溶液及中性溶液中也非十分稳定。Although the battery does not release electrical energy during storage, there is always self-discharge inside the battery. Even if it is stored dry, due to poor sealing, water, air, carbon dioxide and other substances will enter, causing some of the positive and negative active materials in a thermodynamically unstable state to form a micro-battery corrosion mechanism, and undergo redox reactions and be consumed in vain. This is even more true if it is stored wet. Active materials in electrolytes for a long time are also unstable. Most of the negative active materials are active metals, and anode self-dissolution will occur. In acidic solutions, negative metals are unstable, and they are not very stable in alkaline and neutral solutions.
自放电Self-discharge
电池自放电的大小,一般用单位时间内容量减少的百分比表示,即:The size of battery self-discharge is generally expressed as the percentage of capacity reduction per unit time, that is:
自放电=(Co-Ct/Cot)×100%Self-discharge = (Co-Ct/Cot) × 100%
式中:Co──贮存前电池容量,Ah;Where: Co - battery capacity before storage, Ah;
Ct──贮存后电池容量,Ah;Ct - battery capacity after storage, Ah;
t──贮存时间,用天、周、月或年表示。t – storage time, expressed in days, weeks, months or years.
自放电的大小,也能用电池贮存至某规定容量时的天数表示,称为贮存寿命。贮存寿命有两种,即干贮存寿命和湿贮存寿命。对于在使用时才加入电解液的电池贮存寿命,习惯上也称为干贮存寿命。干贮存寿命可以很长。对于出厂前已加入电解液的电池贮存寿命,习惯上称为湿贮存寿命(或湿荷电寿命)。湿贮存时自放电严重,寿命较短。如银锌电池的干贮存寿命可达5~8年,但它的湿贮存寿命通常只有几个月。The size of self-discharge can also be expressed by the number of days when the battery is stored to a certain specified capacity, which is called storage life. There are two types of storage life, namely dry storage life and wet storage life. The storage life of batteries that are added with electrolyte only when in use is also customarily called dry storage life. Dry storage life can be very long. The storage life of batteries that have electrolyte added before leaving the factory is customarily called wet storage life (or wet charge life). Self-discharge is serious during wet storage and the life is short. For example, the dry storage life of silver-zinc batteries can reach 5 to 8 years, but its wet storage life is usually only a few months.
降低电池中自放电的措施,一般是采用纯度较高的原材料,或将原材料预先处理,除去有害杂质。也可在负极金属板栅中加入氢过电位较高的金属,如Ag、Cd等,还有的在溶液中加入缓蚀剂,目的都是抑制氢的析出,减少自放电反应的发生。The measures to reduce the self-discharge in the battery are generally to use raw materials with higher purity, or to pre-treat the raw materials to remove harmful impurities. Metals with higher hydrogen overpotential, such as Ag, Cd, etc., can also be added to the negative electrode metal grid, and corrosion inhibitors can also be added to the solution, all of which aim to inhibit the precipitation of hydrogen and reduce the occurrence of self-discharge reactions.
应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步定义和解释,此外,术语“第一”、“第二”、“第三”等仅用于区分描述,而不能理解为指示或暗示相对重要性。It should be noted that similar numbers and letters represent similar items in the following figures. Therefore, once an item is defined in one figure, it does not need to be further defined and explained in subsequent figures. In addition, the terms "first", "second", "third", etc. are only used to distinguish the description and are not to be understood as indicating or implying relative importance.
最后应说明的是:以上所述实施例,仅为本发明的具体实施方式,用以说明本发明的技术方案,而非对其限制,本发明的保护范围并不局限于此,尽管参照前述实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,其依然可以对前述实施例所记载的技术方案进行修改或可轻易想到变化,或者对其中部分技术特征进行等同替换;而这些修改、变化或者替换,并不使相应技术方案的本质脱离本发明实施例技术方案的精神和范围。都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应所述以权利要求的保护范围为准。Finally, it should be noted that the above-described embodiments are only specific implementations of the present invention, which are used to illustrate the technical solutions of the present invention, rather than to limit them. The protection scope of the present invention is not limited thereto. Although the present invention is described in detail with reference to the above-described embodiments, those skilled in the art should understand that any person skilled in the art can still modify the technical solutions described in the above-described embodiments within the technical scope disclosed by the present invention, or can easily think of changes, or perform equivalent replacements on some of the technical features thereof; and these modifications, changes or replacements do not make the essence of the corresponding technical solutions deviate from the spirit and scope of the technical solutions of the embodiments of the present invention. They should all be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.
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