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CN114232325A - 一种涤纶基商标带 - Google Patents

一种涤纶基商标带 Download PDF

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CN114232325A
CN114232325A CN202111651890.9A CN202111651890A CN114232325A CN 114232325 A CN114232325 A CN 114232325A CN 202111651890 A CN202111651890 A CN 202111651890A CN 114232325 A CN114232325 A CN 114232325A
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parts
flame retardant
polyester
trademark tape
alcohol solvent
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李红艳
吴耀东
吴丹丹
洪彦
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Huzhou Siny Label Material Co ltd
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Huzhou Siny Label Material Co ltd
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Abstract

本发明涉及一种涤纶基商标带。涤纶基商标带厚度为0.100‑0.150 mm，涤纶基商标带的制备方法包括：纱线预制剂，基布纱线处理，织布，规型，浸洗，烘干，醇系溶剂涂覆，两段烘焙与分切；基布纱线采用规格为（60‑120）D，经纱密度为（70‑150）根/cm，纬线密度为（30‑60）根/cm，基布纱线处理通过1‑20 wt%的预制剂与0.2‑0.8 wt%抗静电剂混合浆液喷涂，在105‑120℃下烘干1‑3 min；织布规型后，采用弱碱混合液进行浸洗，在110‑150℃下烘干2‑10 min；采用多溶剂复配的10‑30 wt%醇系溶剂进行涂覆后采用梯度烘焙，在80‑120℃下进行第一段烘焙5‑10 mim，再升高温度至180‑200℃下进行第二段烘焙1‑3 min；烘干成型后进行分切制得涤纶基商标带。本涤纶基商标带醇系溶剂可涂覆，防静电阻燃，耐水洗，印刷效果好。

Description

一种涤纶基商标带
技术领域
本发明涉及一种醇系溶剂可涂覆的涤纶基商标带制备方法。
背景技术
在日常生活中商标带广泛应用于各种织物商品中，主要以小面积带状、块状为主，各使用厂家可以将厂家的信息、商品规格、大小、制造国家、制造产地、商品型号等标记在商标带上。目前商标带主要是由尼龙基或涤纶基（聚酯纤维PET）制作；其中，尼龙基商标带易潮湿，防潮性能和抗静电性不好，但醇系溶剂易涂覆；涤纶基防潮性与抗静电性较好，且更加柔软光润，但相比尼龙基商标带醇系溶剂更难涂覆于涤纶基上，水洗牢度不好。
发明内容
本发明的目的是解决醇系溶剂易涂覆于尼龙基商标带却不易涂覆于涤纶基商标带的技术问题，提供一种醇系溶剂可涂覆的涤纶基商标带的制备方法。
本发明的上述技术目的是通过以下技术方案得以实现的：一种涤纶基商标带，其包括涤纶基布与涂覆层，所述的涤纶基商标带厚度为0.100-0.150 mm，其中涤纶基布厚度为0.090 mm-0.130 mm，涂覆层厚度为0.010 mm-0.040mm，其中，基布纱线通过1-20 wt%的预制剂与0.2-0.8 wt%抗静电剂混合浆液喷涂处理，涂覆层采用多溶剂复配的10-30 wt%醇系溶剂进行涂覆。
本发明针对涤纶基商标带开发了一种可涂覆于涤纶基表面的醇系溶剂及其制备方法，最终可得到水洗牢度、抗静电性能更优且醇系溶剂可涂覆的涤纶基商标带。
作为优选，涤纶基商标带，其特征在于：所用基布纱线采用规格为（60-120）D，经纱密度为（70-150）根/cm，纬线密度为（30-60）根/cm。
作为优选，预制剂与抗静电剂混合浆液中，基布纱线预制剂由乙醇、乙二醇、乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷、硬脂酸、去离子水中2-3种，采用(1-3):1:1的比例复配而成，用量至少为1-20 wt%。
作为优选，预制剂与抗静电剂混合浆液中，抗静电剂至少包含0.2-0.8 wt%，采用喷涂的方式对纱线进行处理。
作为优选，涤纶基商标带制备方法，包括基布纱线处理、烘干、浸洗、涂覆、两段烘焙与分切；在基布纱线处理时，先配制预制剂与抗静电剂的混合浆液，喷涂在纱线上，在105-120 ℃下烘干1-3 min；然后，织布定型后进行弱碱混合液浸洗以洗去残留在基布表面的化学试剂，在110-150 ℃下烘干2-10 min；然后，采用多溶剂复配的10-30 wt%醇系溶剂进行涂覆后采用梯度烘焙，在80-120 ℃下进行第一段烘焙5-10 min，再升高温度至180-200 ℃下进行第二段烘焙1-3 min；烘干成型后进行分切制得涤纶基商标带。
预制剂与抗静电剂混合浆液喷涂后，在105-120 ℃下烘干1-3 min，使得混合浆液附着与纱线表面，保持纱线表面干燥，利于织布；浸洗、淋洗后应立即在110-150 ℃下烘干2-10 min，使得表面水分去除，有利于醇系溶剂涂覆且能使商标带获得良好的印刷效果；涂覆好的布料应采用两段烘焙的方式进行处理，第一段烘焙在在80-120 ℃下烘焙5-10 mim，是在此温度下可加快醇系溶剂与处理好的基布表面的吸附作用；第二段烘焙，升高温度至180-200 ℃下烘焙1-3 min，是在此温度下使得醇系溶剂稳定附着、定型。
作为优选，在织布定型后应使用弱碱混合液浸洗以洗去残留在基布表面的化学试剂，包括纯碱用量为5-10 g/L,烧碱用量为0.5-2 g/L,去离子水与乙醇体积比为(10-15):1，浸洗时长为10-30 min，使得基布表面残留的化学药剂充分去除，然后再用纯水淋洗1-2次，淋洗可将弱碱混合浸洗液洗去，再在110-150 ℃下烘干2-10 min，在织布定型后应使用弱碱混合液浸洗且使基布表面完全干燥以有利于下一步醇系溶剂的涂覆且能使商标带获得良好的印刷效果。
作为优选，复配的醇系溶剂应包括甲基丙烯酸、丙烯酸乙酯、甲醇、乙二醇、有机硅、乙酸乙酯、过氧化氢与去离子水中3-5种溶剂按照(1-3):1:1:1:1的比例进行配制。
作为优选，醇系溶剂复配时，应采用行星式搅拌器进行混合，使得复配的醇系溶剂更容易涂覆均匀。
作为优选，复配好的醇系溶剂放置于聚四氟乙烯的料槽中，更好的保存醇系溶剂。
作为优选，复配的醇系溶剂涂覆时，应先将基布浸至料槽液面下方1/2处，从料槽左端拉至右端，料槽内停留时间5-15 s，使得醇系溶剂有充分的时间与基布接触，从而有利于下一步醇系溶剂的涂覆且能使商标带获得良好的印刷效果。
作为优选，从料槽中拉出的布料应连接一台滚筒涂覆机，可回收布料上多余的醇系溶剂，还可以使醇系溶剂涂覆更加均匀。
作为优选，作为优选，两段烘焙处理后的布料的分切采用热切工艺，温度在80-120℃。
作为优选，采用多溶剂复配的10-30 wt%醇系溶剂进行涂覆后，进行阻燃浸渍，阻燃浸渍采用的阻燃剂包括氮系阻燃剂层胶料，
氮系阻燃剂层胶料包括以下重量份的组分：
氮系阻燃剂15-25份
聚酰胺50-70份
氯化钙10-15份
抗静电剂1-2份
偶氮二异丁腈3-7份
甲醇5-10份；
所述氮系阻燃剂为按照质量比3-5：1：1混合组成的MCA25、三聚氰胺树脂和MCA253混合物；
所述抗静电剂为聚乙烯乙二醇甲基丙烯酸共聚体，聚醚酯酰胺(PEEA)、聚醚酯乙酰胺(PEAI)、聚氧化乙烯、环氧丙烷共聚合物(PEO-ECH)、PEGMA、有机硅抗静电剂中的一种或两种以上。
本发明选用氮系阻燃剂、聚酰胺、偶氮二异丁腈和剩余物质混合制备的第二氮系阻燃层胶料，属于无卤阻燃胶料，绿色环保，发烟量低，前期烟密度低，阻燃性能提升，而且有利于后续定型阻燃层胶料的涂敷，能与定型阻燃层胶料发挥协同增强阻燃作用，且不影响商标带的印刷功能。
进一步优选地，所述氮系阻燃层胶料还包括4-9份季铵盐类衍生物。
本发明所述季铵盐类衍生物作为交联促进剂，可以更好地提高氮系阻燃层胶料的粘度和阻燃性，而且有利于后续涂敷的定型阻燃层胶料的有机结合，不易脱落，且不影响商标带的印刷功能。
更优选地，在用氮系阻燃剂层胶料浸渍后，进一步采用定型阻燃剂层胶料进行二次增强阻燃浸渍，所述定型阻燃剂层胶料包括以下重量份的组分：
磷-氮复合型阻燃剂30-40份
聚乙烯醇6-12份
聚氨酯乳液6-12份
3,5-二叔丁基-4-羟基苯丙酰胺和亚磷酸三（2,4-二叔丁基苯酚）酯组成的第二添加剂8-13份
复合调节剂4-9份
去离子水3-7份；
所述磷-氮复合型阻燃剂为2-甲基-2-丙烯酸-2-(膦酰基氧基)乙酯与、Ⅱ型长链聚磷酸铵与三聚氰胺聚磷酸盐按照质量比1：1-2：3-5组成的混合物；
所述复合调节剂包括按照摩尔比1：1：1混合的硅烷封端聚氨酯树脂、钛酸钾晶须和改性多孔二氧化硅。
本发明的定型阻燃层胶料热分解温度高，能够延长阻燃的时间，防止火苗上窜。本发明选用磷-氮复合型阻燃剂、聚氨酯乳液、聚乙烯醇和复合调节剂以及第二添加剂混合制备的定型阻燃层胶料，属于无卤阻燃胶料，绿色环保，发烟量低，前期烟密度低，阻燃性能提升，而且有利于前面阻燃层胶料的阻燃性能发挥，能共同发挥协同增强阻燃作用，且不影响商标带的印刷功能。
综上所述，本发明具有以下有益效果：本发明生产的涤纶基商标带，具有防潮、防静电、阻燃、更加柔和光润的性能，并可以将醇系溶剂涂覆于涤纶基商标带表面，耐水洗，印刷性能好，字迹、图案清晰、快干性好、无露白、无扩散、无脱墨现象，为后端厂家使用提供了极大的便利。
附图说明
图1是一种醇系溶剂可涂覆涤纶基商标带的制备方法流程;
图2是处理后涤纶基基布进行醇系溶剂涂覆时的示意图;
具体实施方式
实施例1
使用规格为60D的涤纶基布纱线，经纱密度为70 根/cm，纬线密度为30根/cm，采用乙醇、乙二醇、乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷、硬脂酸、去离子水中2-3种，采用1:1:1的比例复配的1 wt%预制剂与0.2 wt%抗静电剂的混合浆液进行喷涂处理，在105 ℃下烘干1 min后进行织布定型；采用15 wt%弱碱混合液（纯碱5 g/L，烧碱0.5 g/L，去离子水:乙醇=10:1）浸洗10 min，纯水淋洗1次，在110 ℃下烘干2 min，得到浸洗烘干后处理的布料。
将处理后布料，浸于聚四氟乙烯料槽中，醇系溶剂由甲基丙烯酸、丙烯酸乙酯、甲醇、乙二醇与去离子水按照1:1:1:1:1的比例，采用行星式搅拌器进行混合，配置成10 wt%复配液料槽内停留时间5 s，在料槽右端连接一台滚筒涂覆机，将醇系溶剂平整涂覆；均匀涂覆后采用两段烘焙的方法，第一段烘焙在80 ℃下烘焙8mim，再升高温度至180 ℃下进行第二段烘焙1 min；在80 ℃温度下进行热切；最终得到的涤纶基商标带厚度为0.106 mm，其中涤纶基布厚度为 0.093 mm，涂覆层厚度为0.013 mm，涂覆效果良好。
实施例2
使用规格为70D的涤纶基布纱线，经纱密度为80 根/cm，纬线密度为40根/cm，采用乙醇、乙二醇、乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷、硬脂酸、去离子水中2-3种，采用2:1:1的比例复配的8 wt%预制剂与0.4 wt%抗静电剂的混合浆液进行喷涂处理，在110 ℃下烘干2 min后进行织布定型；采用15 wt%弱碱混合液（纯碱6 g/L，烧碱0.8 g/L，去离子水:乙醇=10:1）浸洗10 min，纯水淋洗2次，在120 ℃下烘干10min，得到浸洗烘干后处理的布料。
将处理后布料，浸于聚四氟乙烯料槽中，醇系溶剂由甲醇、乙二醇、有机硅、乙酸乙酯、过氧化氢按照1.2:1:1:1:1的比例，采用行星式搅拌器进行混合，配置成10 wt%复配液料槽内停留时间10 s，在料槽右端连接一台滚筒涂覆机，将醇系溶剂平整涂覆；均匀涂覆后采用两段烘焙的方法，第一段烘焙在100 ℃下烘焙5 mim，再升高温度至190 ℃下进行第二段烘焙2 min；在100 ℃温度下进行热切；最终得到的涤纶基商标带厚度为0.119 mm，其中涤纶基布厚度为 0.101 mm，涂覆层厚度为0.018 mm，且较实例1涂覆层厚度增加，涂覆效果良好。
实施例3
使用规格为120D的涤纶基布纱线，经纱密度为150 根/cm，纬线密度为60根/cm，采用乙二醇、乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷，采用2:1:1的比例复配的20 wt%预制剂与0.8 wt%抗静电剂的混合浆液进行喷涂处理，在110 ℃下烘干2 min后进行织布定型；采用15 wt%弱碱混合液（纯碱6 g/L，烧碱0.8 g/L，去离子水:乙醇=10:1）浸洗10 min，纯水淋洗2次，在150 ℃下烘干8min，得到浸洗烘干后处理的布料。
将处理后布料，浸于聚四氟乙烯料槽中，醇系溶剂由乙酸乙酯、过氧化氢与去离子水按照3:1:1的比例，采用行星式搅拌器进行混合，配置成10 wt%复配液料槽内停留时间10s，在料槽右端连接一台滚筒涂覆机，将醇系溶剂平整涂覆；均匀涂覆后采用两段烘焙的方法，第一段烘焙在120 ℃下烘焙10 mim，再升高温度至200 ℃下进行第二段烘焙3 min；在120 ℃温度下进行热切；最终得到的涤纶基商标带厚度为0.119 mm，其中涤纶基布厚度为0.101 mm，涂覆层厚度为0.018 mm，且较实例1涂覆层厚度增加，涂覆效果良好。
实施例4
同实施例1，不同的是采用多溶剂复配的醇系溶剂进行涂覆后，进行阻燃浸渍，阻燃浸渍采用的阻燃剂包括氮系阻燃剂层胶料，
氮系阻燃层胶料配方1包括以下重量份的组分：
氮系阻燃剂15份
聚酰胺50份
氯化钙10份
抗静电剂1份
偶氮二异丁腈3份
甲醇10份；
氮系阻燃剂为按照质量比3：1：1混合组成的MCA25、三聚氰胺树脂和MCA253混合物；
抗静电剂为聚乙烯乙二醇甲基丙烯酸共聚体。
实施例5
同实施例2，不同的是不同的是采用多溶剂复配的醇系溶剂进行涂覆后，进行阻燃浸渍，阻燃浸渍采用的阻燃剂包括氮系阻燃剂层胶料，
氮系阻燃层胶料配方2包括以下重量份的组分：
氮系阻燃剂15份
聚酰胺50份
氯化钙10份
抗静电剂1份
偶氮二异丁腈3份
甲醇10份；
氮系阻燃剂为按照质量比3：1：1混合组成的MCA25、三聚氰胺树脂和MCA253混合物；
抗静电剂为聚醚酯酰胺(PEEA)、聚醚酯乙酰胺(PEAI)按照质量比1：1混合组成。
实施例6
同实施例3，不同的是不同的是采用多溶剂复配的醇系溶剂进行涂覆后，进行阻燃浸渍，阻燃浸渍采用的阻燃剂包括氮系阻燃剂层胶料，
氮系阻燃层胶料配方3包括以下重量份的组分：
氮系阻燃剂20份
聚酰胺60份
氯化钙12份
抗静电剂1.5份
偶氮二异丁腈5份
甲醇8份；
氮系阻燃剂为按照质量比4：1：1混合组成的MCA25、三聚氰胺树脂和MCA253混合物；
抗静电剂为环氧丙烷共聚合物(PEO-ECH)、PEGMA、有机硅抗静电剂按照质量比1：1：1混合组成。
实施例7
同实施例4，不同的是在用氮系阻燃剂浸渍后，进一步采用定型阻燃剂层胶料进行二次增强阻燃浸渍，
定型阻燃层胶料配方1包括以下重量份的组分：
磷-氮复合型阻燃剂30份
聚乙烯醇6份
聚氨酯乳液6份
3,5-二叔丁基-4-羟基苯丙酰胺和亚磷酸三（2,4-二叔丁基苯酚）酯组成的第二添加剂8份
复合调节剂4份
去离子水7份；
磷-氮复合型阻燃剂为2-甲基-2-丙烯酸-2-(膦酰基氧基)乙酯与、Ⅱ型长链聚磷酸铵与三聚氰胺聚磷酸盐按照质量比1：1：5组成的混合物；
复合调节剂包括按照摩尔比1：1：1混合的硅烷封端聚氨酯树脂、钛酸钾晶须和改性多孔二氧化硅。
实施例8
同实施例5，不同的是在用氮系阻燃剂浸渍后，进一步采用定型阻燃剂层胶料进行二次增强阻燃浸渍，
定型阻燃层胶料配方2包括以下重量份的组分：
磷-氮复合型阻燃剂40份
聚乙烯醇12份
聚氨酯乳液6-12份
3,5-二叔丁基-4-羟基苯丙酰胺和亚磷酸三（2,4-二叔丁基苯酚）酯组成的第二添加剂13份
复合调节剂9份
去离子水3份；
磷-氮复合型阻燃剂为2-甲基-2-丙烯酸-2-(膦酰基氧基)乙酯与、Ⅱ型长链聚磷酸铵与三聚氰胺聚磷酸盐按照质量比1：2：3组成的混合物；
复合调节剂包括按照摩尔比1：1：1混合的硅烷封端聚氨酯树脂、钛酸钾晶须和改性多孔二氧化硅。
实施例9
同实施例6，不同的是在用氮系阻燃剂浸渍后，进一步采用定型阻燃剂层胶料进行二次增强阻燃浸渍，
定型阻燃层胶料配方3包括以下重量份的组分：
磷-氮复合型阻燃剂35份
聚乙烯醇9份
聚氨酯乳液9份
3,5-二叔丁基-4-羟基苯丙酰胺和亚磷酸三（2,4-二叔丁基苯酚）酯组成的第二添加剂10份
复合调节剂7份
去离子水5份；
磷-氮复合型阻燃剂为2-甲基-2-丙烯酸-2-(膦酰基氧基)乙酯与、Ⅱ型长链聚磷酸铵与三聚氰胺聚磷酸盐按照质量比1：1：4组成的混合物；
复合调节剂包括按照摩尔比1：1：1混合的硅烷封端聚氨酯树脂、钛酸钾晶须和改性多孔二氧化硅。
实施例10
同实施例9，不同的是第二氮系阻燃层胶料还包括4-9份季铵盐类衍生物。
对比例1
同实施例1，不同的是采用1:1:1的比例复配的0.5 wt%预制剂与1wt%抗静电剂的混合浆液进行喷涂处理。
对比例2
同实施例2，不同的是涂覆层未采用多溶剂复配的10-30 wt%醇系溶剂进行涂覆。
检测
1、 将实施例1-10和对比例1-2获得的阻燃厚商标带的水洗牢度、干摩擦牢度和湿摩擦牢度采用ISO 105 X18进行检测；抗静电采用Meech 983V2静电测试仪测试，测试静电压。检测数据对比如下表1：
表1 水洗牢度、干摩擦牢度、湿摩擦牢度和抗静电实验数据对比表
Figure DEST_PATH_IMAGE002AAA
2、将实施例1-10和对比例1-2获得的阻燃厚商标带进行数码喷墨印刷性能测试，印刷车速设定为60m/min，分辨率600dpi，结果为实施例1-10的字迹、图案清晰、快干性好、无露白、无扩散、无脱墨现象，适用于喷墨打印。对比例1-2的字迹、图案清晰度有待改进，且印刷快干性差、有扩散和脱墨现象。
3、将实施例1-10和对比例1-2获得的阻燃厚商标带按照GB/T 5455-2014标准进行检测。用规定点火器产生的火焰，对垂直方向的试样底边中心点火，在规定的点火时间后，测量试样的续燃时间、阴燃时间及损毁长度。
燃烧时在垂直燃烧试验箱中操作，根据织物单位面积质量，选用质量为113.4g的重锤。根据GB/T 5455-2014标准中的具体实验步骤操作，得到的实施例及对比例的续燃时间、阴燃时间及损毁长度实验数据如下表2：
表2 续燃时间、阴燃时间及损毁长度实验数据表
Figure DEST_PATH_IMAGE004AAA
以上实验数据可以看出：
本发明实施例1-10的厚商标带阻燃性能、水洗牢度和印刷性能优于对比例1-2；实施例4-6的阻燃性能、水洗牢度和印刷性能优于实施例1-3，实施例7-10的阻燃性能、水洗牢度和印刷性能优于实施例4-6。
说明：采用本发明实施例1-10特定基布的涤纶基商标带，具有防静电、阻燃、更加柔和光润的性能，并可以将醇系溶剂涂覆于涤纶基商标带表面，耐水洗，印刷性能好，字迹、图案清晰、快干性好、无露白、无扩散、无脱墨现象。印刷产品可以满足TTR热转移条码打印要求；耐皂洗色牢度满足GB/T3921纺织品色牢度试验标准，适用于干墨印刷及湿墨印刷方式。
本具体实施例仅仅是对本发明的解释，其并不是对本发明的限制，本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改，但只要在本发明的权利要求范围内都受到专利法的保护。

Claims (10)

1.一种涤纶基商标带，其包括涤纶基布与涂覆层，其特征在于：所述的涤纶基商标带厚度为0.100-0.150 mm，其中涤纶基布厚度为0.090 mm-0.130 mm，涂覆层厚度为0.010 mm-0.040mm，涤纶基商标带克重为70-100 g/m2；
其中，基布纱线通过1-20 wt%的预制剂与0.2-0.8 wt%抗静电剂混合浆液喷涂处理，涂覆层采用多溶剂复配的10-30 wt%醇系溶剂进行涂覆。
2.根据权利要求1所述的涤纶基商标带，其特征在于：所用基布纱线采用规格为（60-120）D，经纱密度为（70-150）根/cm，纬线密度为（30-60）根/cm。
3.根据权利要求2所述的涤纶基商标带，其特征在于：预制剂的配方是由乙醇、乙二醇、乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷、硬脂酸、去离子水中2-3种，采用(1-3):1:1的比例复配而成，用量为1-20 wt%。
4.根据权利要求3所述的涤纶基商标带，其特征在于：涤纶基商标带制备方法，包括基布纱线处理、烘干、浸洗、涂覆、两段烘焙与分切；在基布纱线处理时，先配制预制剂与抗静电剂的混合浆液，喷涂在纱线上，在105-120 ℃下烘干1-3 min；然后，织布定型后进行弱碱混合液浸洗以洗去残留在基布表面的化学试剂，在110-150 ℃下烘干2-10 min；然后，采用多溶剂复配的10-30 wt%醇系溶剂进行涂覆后采用梯度烘焙，在80-120 ℃下进行第一段烘焙5-10 min，再升高温度至180-200 ℃下进行第二段烘焙1-3 min；烘干成型后进行分切制得涤纶基商标带。
5.根据权利要求4所述的涤纶基商标带，其特征在于浸洗时弱碱混合液是由纯碱、烧碱、去离子与乙醇复配而成，其中纯碱用量为5-10 g/L,烧碱用量为0.5-2 g/L,去离子水与乙醇体积比为(10-15):1，浸洗时长为10-30 min，然后再用纯水淋洗1-2次，再在110-150℃下烘干2-10 min。
6.根据权利要求4所述的涤纶基商标带，其特征在于醇系溶剂的复配配方由甲基丙烯酸、丙烯酸乙酯、甲醇、乙二醇、有机硅、乙酸乙酯、过氧化氢与去离子水中3-5种溶剂按照(1-3):1:1:1:1的比例，采用行星式搅拌器进行混合，配置成10-30 wt%复配液。
7.根据权利要求4所述的涤纶基商标带，其特征在于涂覆过程，先将复配的醇系溶剂置于聚四氟乙烯材质的料槽中，将基布浸至料槽液面下方1/2处，从料槽左端拉至右端，料槽内停留时间5-15 s，在料槽右端连接一台滚筒涂覆机，将醇系溶剂平整涂覆。
8.根据权利要求4所述的涤纶基商标带，其特征在于：分切采用热切工艺，温度在80-120 ℃。
9.根据权利要求1-7任一项所述的涤纶基商标带，其特征在于：采用多溶剂复配的10-30 wt%醇系溶剂进行涂覆后，进行阻燃浸渍，阻燃浸渍采用的阻燃剂包括氮系阻燃剂层胶料，
氮系阻燃剂层胶料包括以下重量份的组分：
氮系阻燃剂15-25份
聚酰胺50-70份
氯化钙10-15份
抗静电剂1-2份
偶氮二异丁腈3-7份
甲醇5-10份；
所述氮系阻燃剂为按照质量比3-5：1：1混合组成的MCA25、三聚氰胺树脂和MCA253混合物；
所述抗静电剂为聚乙烯乙二醇甲基丙烯酸共聚体，聚醚酯酰胺(PEEA)、聚醚酯乙酰胺(PEAI)、聚氧化乙烯、环氧丙烷共聚合物(PEO-ECH)、PEGMA、有机硅抗静电剂中的一种或两种以上。
10.根据权利要求9所述的涤纶基商标带，其特征在于：在用氮系阻燃剂浸渍后，进一步采用定型阻燃剂层胶料进行二次增强阻燃浸渍，所述定型阻燃剂层胶料包括以下重量份的组分：
磷-氮复合型阻燃剂30-40份
聚乙烯醇6-12份
聚氨酯乳液6-12份
3,5-二叔丁基-4-羟基苯丙酰胺和亚磷酸三（2,4-二叔丁基苯酚）酯组成的第二添加剂8-13份
复合调节剂4-9份
去离子水3-7份；
所述磷-氮复合型阻燃剂为2-甲基-2-丙烯酸-2-(膦酰基氧基)乙酯与、Ⅱ型长链聚磷酸铵与三聚氰胺聚磷酸盐按照质量比1：1-2：3-5组成的混合物；
所述复合调节剂包括按照摩尔比1：1：1混合的硅烷封端聚氨酯树脂、钛酸钾晶须和改性多孔二氧化硅。
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