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CN114213908A - Ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof paint and construction method thereof - Google Patents

Ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof paint and construction method thereof Download PDF

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Publication number
CN114213908A
CN114213908A CN202210000959.XA CN202210000959A CN114213908A CN 114213908 A CN114213908 A CN 114213908A CN 202210000959 A CN202210000959 A CN 202210000959A CN 114213908 A CN114213908 A CN 114213908A
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parts
rubber asphalt
emulsion
raw materials
water
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张志顺
高原
李堂飞
郗猛
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Qingdao Xinhuayou Construction Group Co Ltd
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Qingdao Xinhuayou Construction Group Co Ltd
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Priority to CN202210000959.XA priority Critical patent/CN114213908A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D121/00Coating compositions based on unspecified rubbers
    • C09D121/02Latex
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B12/00Arrangements for controlling delivery; Arrangements for controlling the spray area
    • B05B12/14Arrangements for controlling delivery; Arrangements for controlling the spray area for supplying a selected one of a plurality of liquids or other fluent materials or several in selected proportions to a spray apparatus, e.g. to a single spray outlet
    • B05B12/1472Arrangements for controlling delivery; Arrangements for controlling the spray area for supplying a selected one of a plurality of liquids or other fluent materials or several in selected proportions to a spray apparatus, e.g. to a single spray outlet separate supply lines supplying different materials to separate outlets of the spraying apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/16Halogen-containing compounds
    • C08K2003/162Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses an ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof coating, which comprises an aqueous rubber asphalt emulsion and a demulsifier, wherein the volume ratio of the aqueous rubber asphalt emulsion to the demulsifier is (1-2): 1, wherein the aqueous rubber asphalt emulsion is prepared from the following raw materials in parts by mass: the composition comprises the following substances in parts by mass: 40-70 parts of liquid rubber asphalt mastic emulsion, 3-10 parts of pH regulator, 4-22 parts of interface modifier, 2-8 parts of ultraviolet resistant agent, 0.1-0.7 part of antioxidant, 7-12 parts of epoxy resin and 1-20 parts of water-based spray coating. Has the advantages that: the coating has the functions of energy conservation, environmental protection, quick spraying and instant curing film forming, has perfect bonding effect, has strong elasticity, and has the advantages of good puncture resistance, aging resistance, self-sealing and self-healing property and overall seamless property.

Description

Ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof paint and construction method thereof
Technical Field
The invention relates to the field of waterproof construction, in particular to an ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof coating and a construction method thereof.
Background
The spray rubber asphalt waterproof paint is a novel solvent-free and pollution-free green product developed to meet the current construction and environmental protection requirements. The coating is a novel two-component spraying material, has the characteristics of aging resistance, convenient construction, excellent bonding property and the like, can be widely applied to the fields of waterproof, anticorrosion and protection, and the like, is used in large-scale projects in Beijing, Guangzhou and Shanghai at present, but does not have a mature standard for construction methods at present, so the application provides the ultralow-temperature flame-retardant rapid-setting spraying rubber asphalt waterproof coating and the construction method thereof.
An effective solution to the problems in the related art has not been proposed yet.
Disclosure of Invention
Aiming at the problems in the related art, the invention provides an ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof coating and a construction method thereof, so as to overcome the technical problems in the prior related art.
The technical scheme of the invention is realized as follows:
according to one aspect of the invention, an ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof coating is provided.
The ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof coating comprises water-based rubber asphalt emulsion and a demulsifier, wherein the volume ratio of the water-based rubber asphalt emulsion to the demulsifier is (1-2): 1, wherein,
the water-based rubber asphalt emulsion is prepared from the following raw materials in parts by weight: the composition comprises the following substances in parts by mass: 40-70 parts of liquid rubber asphalt mastic emulsion, 3-10 parts of pH regulator, 4-22 parts of interface modifier, 2-8 parts of ultraviolet resistant agent, 0.1-0.7 part of antioxidant, 7-12 parts of epoxy resin and 1-20 parts of water-based spray coating; the spraying capacity ratio of the water-based spray paint to the liquid rubber asphalt mastic emulsion is 2: 15-1: 3.5;
preferably, the liquid rubber asphalt mastic emulsion comprises the following raw materials in parts by weight: 53-79 parts of rubber latex with the solid content of 55-70%, 20-40 parts of asphalt emulsion with the solid content of 45-50%, 0.5-2 parts of carbon black, 2-3 parts of fine powder, 1-2 parts of anionic dispersant, 1-1.2 parts of anionic surfactant and 0.001-0.003 part of stabilizer.
Preferably, the fine powder comprises at least one of: porcelain powder, heavy calcium powder and light calcium powder; the anionic dispersant is an acrylate high-molecular dispersant; the anionic surfactant includes at least one of: soap, alkylbenzene sulfonate, alkylsulfonate ester salt, alkylsulfonate, alkylsulfate, fluorine-containing fatty acid salt, polysiloxane, fatty alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate, alpha-olefin sulfonate, fatty alcohol polyoxyethylene ether phosphate, alkylolamide, alkylsulfoacetamide, alkylsulfosuccinate sulfonate, alkylolamine alkylbenzene sulfonate, naphthenate, alkylphenol sulfonate, polyoxyethylene monolaurate; the stabilizer includes at least one of: soluble chloride salts, sulfates, nitrates, phosphates, silicates.
Preferably, the water-based spray coating comprises the following raw materials in parts by mass: 90-99.6 parts of calcium chloride, 0.3-3 parts of sodium chloride, 0.2-4 parts of composite aluminum-iron polymer and the balance of water, wherein the ratio of the total amount of the calcium chloride, the sodium chloride and the composite aluminum-iron polymer to the water is 1: 9.
preferably, the demulsifier is an acidic demulsifier, and the acidic demulsifier comprises the following raw materials in parts by weight; 20-30 parts of calcium chloride, 2-6 parts of phosphono-glycolic acid and 70-95 parts of water.
Preferably, the pH adjusting agent comprises at least one of: hydrochloric acid, sulfuric acid, glacial acetic acid, citric acid, fatty acids, salicylic acid, sodium hydroxide, potassium hydroxide, sodium carbonate, and sodium bicarbonate; the interface modifier is prepared by mixing the following raw materials in parts by weight: 0-2 parts of polyoxyethylene ether, 0-1 part of alkylamine and 2-4 parts of polycarboxylic acid type high molecular surfactant; the anti-ultraviolet agent is a hindered phenol antioxidant; the antioxidant comprises at least one of: sodium sulfite, sodium metabisulfite, dibutyl phenol, sodium bisulfite, sodium thiosulfate and tert-butyl p-hydroxyanisole.
According to another aspect of the invention, a construction method of the low-temperature flame-retardant quick-setting spraying rubber asphalt waterproof coating is provided.
The construction method comprises the following steps:
weighing raw materials according to a predetermined weight part, wherein the raw materials comprise: 40-70 parts of liquid rubber asphalt mastic emulsion, 3-10 parts of pH regulator, 4-22 parts of interface modifier, 2-8 parts of ultraviolet resistant agent, 0.1-0.7 part of antioxidant, 7-12 parts of epoxy resin and 1-20 parts of water-based spray coating, wherein the spraying capacity ratio of the water-based spray coating to the liquid rubber asphalt mastic emulsion is 2: 15-1: 3.5;
mixing and stirring the raw materials according to the weight parts and the spraying volume ratio to form a water-based rubber asphalt emulsion;
mixing the aqueous rubber asphalt emulsion with a pre-prepared demulsifier according to a volume ratio of 1-2: 1, running the paint to a spray gun of airless continuous spraying equipment through different pipelines to carry out spraying construction of the paint.
In addition, in the construction method, the preparation method of the liquid rubber asphalt mastic emulsion comprises the following steps: weighing raw materials according to a predetermined mass part, wherein the raw materials comprise: 53-79 parts of rubber latex with the solid content of 55-70%, 20-40 parts of asphalt emulsion with the solid content of 45-50%, 0.5-2 parts of carbon black, 2-3 parts of fine powder, 1-2 parts of anionic dispersant, 1-1.2 parts of anionic surfactant and 0.001-0.003 part of stabilizer; adding carbon black, fine powder, an anionic dispersant, an anionic surfactant and a stabilizer into the asphalt emulsion with the solid content of 45-50%, and fully and uniformly stirring to obtain a mixed raw material; adding the rubber latex with the solid content of 55-70% into the mixed raw materials, and fully and uniformly stirring to obtain the liquid rubber asphalt latex.
Optionally, the demulsifier is prepared by mixing the following raw materials in parts by weight: 20-30 parts of calcium chloride, 2-6 parts of phosphono-glycolic acid and 70-95 parts of water.
In addition, the construction method further comprises the following steps: before spraying construction, preprocessing a base layer to be sprayed; after the spraying construction, maintaining the sprayed base layer; wherein the pre-treatment comprises at least one of: cleaning the base layer; drying the base layer; leveling the base layer; carrying out crack filling treatment on the base layer; reinforcing the base layer; and flattening and strengthening the surface of the base layer.
Has the advantages that:
the spraying rubber asphalt waterproof paint is a two-component material, the first component is water-based rubber asphalt emulsion, the second component is a demulsifier, the material spraying construction adopts matched airless continuous spraying equipment, the two components run to respective spray guns through different pipelines under the push of a power system, two gun mouths incline inwards during spraying, the material forms an atomized state at the moment of spraying, and the two components are fully mixed before and when reaching a base surface, so that a uniform rubber asphalt coating film is formed;
the coating has the functions of energy conservation, environmental protection, quick spraying and instant curing film forming, has perfect bonding effect, has strong elasticity, and has the advantages of good puncture resistance, aging resistance, self-sealing and self-healing property and overall seamless property; the difficult problem of leakage at the connection positions of internal and external corners, gaps and irregular structures is solved fundamentally; after the coating is cured into a film, the high elasticity and aging resistance of the rubber material are maintained, and the coating has the advantages of no water channeling, chemical corrosion resistance, high temperature resistance, freezing resistance, cracking resistance, self-extinguishing flame retardance, sound insulation, noise reduction, no toxicity, no peculiar smell, no environmental pollution and the like;
the invention also has ultrahigh elasticity, recovery rate and stronger adhesive force (attention is paid to the adhesive strength with the base surface is more than 0.7 MPa); the waterproof layer is fully adhered to the base surface, water cannot be leaked, the waterproof layer is self-sealed and self-healed, general mechanical puncture can be automatically repaired, and the waterproof layer is effectively prevented from being damaged by next procedure; self-extinguishing flame retardant, the combustion performance reaches B1 level; can resist the corrosion of acid, alkali, salt, chlorine and other solutions; the weather resistance is strong, the water-based environment-friendly effect is achieved, the work efficiency is high, and the whole body has no lap joint; the whole is in seamless lap joint, and the newly constructed coating and the original coating can be completely fused together to form a complete waterproof layer.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments that can be derived by one of ordinary skill in the art from the embodiments given herein are intended to be within the scope of the present invention.
The first embodiment is as follows:
the ultralow-temperature flame-retardant quick-setting spray rubber asphalt waterproof coating comprises the following components in parts by weight: the rubber asphalt emulsion, including the aqueous rubber asphalt emulsion: 1, wherein the aqueous rubber asphalt emulsion is prepared from the following raw materials in parts by mass: the composition comprises the following substances in parts by mass: 40 kg of liquid rubber asphalt mastic emulsion, 3 kg of fatty acid, 4 kg of interface modifier, 2 kg of hindered phenol antioxidant, 0.1 kg of sodium metabisulfite, 7 kg of epoxy resin and 1 kg of water-based spray coating; the spraying capacity ratio of the water-based spray paint to the liquid rubber asphalt mastic emulsion is 2: 15:
the liquid rubber asphalt mastic emulsion comprises the following raw materials in parts by weight: 53 kg of rubber latex with the solid content of 55%, 20 kg of asphalt emulsion with the solid content of 45%, 0.5 kg of carbon black, 2 kg of porcelain powder, 1 kg of acrylate macromolecular dispersant, 1 kg of fatty alcohol sulfate and 0.001 kg of soluble chloride salt.
Wherein the water-based spray coating comprises the following raw materials in parts by mass: 90 kg of calcium chloride, 0.3 kg of sodium chloride, 0.2 kg of composite aluminum-iron polymer and the balance of water, wherein the ratio of the total amount of the calcium chloride, the sodium chloride and the composite aluminum-iron polymer to the water is 1: 9; the demulsifier is an acidic demulsifier, and the acidic demulsifier comprises the following raw materials in parts by mass; 20 kg of calcium chloride, 2 kg of phosphonoglycolic acid and 70 kg of water.
The interface modifier is prepared by mixing the following raw materials in parts by weight: polyoxyethylene ether 0.5 kg, alkylamine 0.2 kg, and polycarboxylic acid type high molecular surfactant 2 kg;
when the aqueous rubber asphalt emulsion is used specifically, the liquid rubber asphalt emulsion, the pH regulator, the interface modifier, the ultraviolet resistant agent, the antioxidant, the epoxy resin and the water-based spray paint are weighed according to the preset weight parts, and the raw materials are mixed and stirred according to the weight parts and the spraying volume ratio to form the aqueous rubber asphalt emulsion; mixing the aqueous rubber asphalt emulsion with a pre-prepared demulsifier according to a volume ratio of 1: 1, running the paint to a spray gun of airless continuous spraying equipment through different pipelines to carry out spraying construction of the paint.
For the liquid rubber asphalt mastic emulsion, the preparation method can be as follows: weighing 53 kg of rubber latex with the solid content of 55%, 20 kg of asphalt emulsion with the solid content of 45%, 0.5 kg of carbon black, 2 kg of fine powder, 1 kg of anionic dispersant, 1 kg of anionic surfactant and 0.001 kg of stabilizer according to the predetermined parts by weight; adding carbon black, fine powder, an anionic dispersant, an anionic surfactant and a stabilizer into the asphalt emulsion with the solid content of 45%, and fully and uniformly stirring to obtain a mixed raw material; adding the rubber latex with the solid content of 55% into the mixed raw materials, and fully and uniformly stirring to obtain the liquid rubber asphalt mastic emulsion. For the demulsifier, it can be prepared by mixing 20 kg of calcium chloride, 2 kg of phosphono-glycolic acid and 70 kg of water.
Example two:
the ultralow-temperature flame-retardant quick-setting spray rubber asphalt waterproof coating comprises the following components in parts by weight: the rubber asphalt emulsion, including the aqueous rubber asphalt emulsion: 1, wherein the aqueous rubber asphalt emulsion is prepared from the following raw materials in parts by mass: the composition comprises the following substances in parts by mass: 55 kg of liquid rubber asphalt mastic emulsion, 7 kg of citric acid, 15 kg of interface modifier, 4 kg of hindered phenol antioxidant, 0.4 kg of sodium sulfite, 10 kg of epoxy resin and 10 kg of water-based spray coating; the spraying capacity ratio of the water-based spray paint to the liquid rubber asphalt mastic emulsion is 1: 3.5;
the liquid rubber asphalt mastic emulsion comprises the following raw materials in parts by weight: 65 kg of rubber latex with the solid content of 62 percent, 30 kg of asphalt emulsion with the solid content of 47 percent, 1 kg of carbon black, 2.5 kg of fine powder, 1.5 kg of anionic dispersant, 1.1 kg of anionic surfactant and 0.002 kg of stabilizer.
Wherein the water-based spray coating comprises the following raw materials in parts by mass: 95 kg of calcium chloride, 2 kg of sodium chloride, 2.5 kg of composite aluminum-iron polymer and the balance of water, wherein the ratio of the total amount of the calcium chloride, the sodium chloride and the composite aluminum-iron polymer to the water is 4: 9; the demulsifier is an acidic demulsifier, and the acidic demulsifier comprises the following raw materials in parts by mass; 25 kg of calcium chloride, 4 kg of phosphonoglycolic acid and 83 kg of water.
The interface modifier is prepared by mixing the following raw materials in parts by weight: 1.2 kg of polyoxyethylene ether, 0.6 kg of alkylamine, and 3 kg of polycarboxylic acid type high molecular surfactant;
when the aqueous rubber asphalt emulsion is used specifically, the liquid rubber asphalt emulsion, the pH regulator, the interface modifier, the ultraviolet resistant agent, the antioxidant, the epoxy resin and the water-based spray paint are weighed according to the preset weight parts, and the raw materials are mixed and stirred according to the weight parts and the spraying volume ratio to form the aqueous rubber asphalt emulsion; mixing the aqueous rubber asphalt emulsion with a pre-prepared demulsifier according to a volume ratio of 1.5: 1, running the paint to a spray gun of airless continuous spraying equipment through different pipelines to carry out spraying construction of the paint.
For the liquid rubber asphalt mastic emulsion, the preparation method can be as follows: weighing 65 kg of rubber latex with the solid content of 62%, 30 kg of asphalt emulsion with the solid content of 47%, 1 kg of carbon black, 2.5 kg of fine powder, 1.5 kg of anionic dispersant, 1.1 kg of anionic surfactant and 0.002 kg of stabilizer according to the predetermined parts by weight; adding carbon black, fine powder, an anionic dispersant, an anionic surfactant and a stabilizer into the asphalt emulsion with the solid content of 45%, and fully and uniformly stirring to obtain a mixed raw material; adding the rubber latex with the solid content of 47% into the mixed raw materials, and fully and uniformly stirring to obtain the liquid rubber asphalt mastic emulsion. For the demulsifier, 25 kg of calcium chloride, 4 kg of phosphono-glycolic acid and 83 kg of water are mixed.
Example three:
the ultralow-temperature flame-retardant quick-setting spray rubber asphalt waterproof coating comprises the following components in parts by weight: the volume ratio of the water-based rubber asphalt emulsion to the demulsifier is 2: 1, wherein the aqueous rubber asphalt emulsion is prepared from the following raw materials in parts by mass: the composition comprises the following substances in parts by mass: 70 kg of liquid rubber asphalt mastic emulsion, 10 kg of hydrochloric acid, 22 kg of interface modifier, 8 kg of hindered phenol antioxidant, 0.7 kg of tert-butyl p-hydroxyanisole, 12 kg of epoxy resin and 20 kg of water-based spray coating; the spraying capacity ratio of the water-based spray paint to the liquid rubber asphalt mastic emulsion is 15: 3.5;
the liquid rubber asphalt mastic emulsion comprises the following raw materials in parts by weight: 79 kg of rubber latex with the solid content of 70 percent, 40 kg of asphalt emulsion with the solid content of 50 percent, 2 kg of carbon black, 3 kg of fine powder, 2 kg of anionic dispersant, 1.2 kg of anionic surfactant and 0.003 kg of stabilizer.
Wherein the water-based spray coating comprises the following raw materials in parts by mass: 99.6 kg of calcium chloride, 3 kg of sodium chloride, 4 kg of composite aluminum-iron polymer and the balance of water, wherein the ratio of the total amount of the calcium chloride, the sodium chloride and the composite aluminum-iron polymer to the water is 8: 9; the demulsifier is an acidic demulsifier, and the acidic demulsifier comprises the following raw materials in parts by mass; 30 kg of calcium chloride, 6 kg of phosphonoglycolic acid and 95 kg of water.
The interface modifier is prepared by mixing the following raw materials in parts by weight: 2 kg of polyoxyethylene ether, 1 kg of alkylamine and 4 kg of polycarboxylic acid type high molecular surfactant;
when the aqueous rubber asphalt emulsion is used specifically, the liquid rubber asphalt emulsion, the pH regulator, the interface modifier, the ultraviolet resistant agent, the antioxidant, the epoxy resin and the water-based spray paint are weighed according to the preset weight parts, and the raw materials are mixed and stirred according to the weight parts and the spraying volume ratio to form the aqueous rubber asphalt emulsion; mixing the aqueous rubber asphalt emulsion with a pre-prepared demulsifier according to a volume ratio of 2: 1, running the paint to a spray gun of airless continuous spraying equipment through different pipelines to carry out spraying construction of the paint.
For the liquid rubber asphalt mastic emulsion, the preparation method can be as follows: weighing 79 kg of rubber latex with the solid content of 70%, 40 kg of asphalt emulsion with the solid content of 50%, 2 kg of carbon black, 3 kg of fine powder, 2 kg of anionic dispersant, 1.2 kg of anionic surfactant and 0.003 kg of stabilizer according to the predetermined parts by weight; adding carbon black, fine powder, an anionic dispersant, an anionic surfactant and a stabilizer into an asphalt emulsion with the solid content of 50%, and fully and uniformly stirring to obtain a mixed raw material; adding rubber latex with solid content of 70% into the mixed raw materials, and fully and uniformly stirring to obtain liquid rubber asphalt mastic emulsion; for the demulsifier, 30 kg of calcium chloride, 6 kg of phosphono-glycolic acid and 95 kg of water are mixed.
In addition, in specific application, the base layer to be sprayed can be pretreated before spraying construction; after the spraying construction, maintaining the sprayed base layer; wherein the pre-treatment comprises cleaning the substrate; drying the base layer; leveling the base layer; carrying out crack filling treatment on the base layer; reinforcing the base layer; and flattening and strengthening the surface of the base layer.
Specifically, before and after the construction process, the base course is required to be subjected to base course acceptance, base course treatment, detail joint treatment, large-area spraying construction, maintenance and drying. Whether the waterproof basic unit of basic unit acceptance detection accords with the construction requirement is the leading cause that directly influences construction quality, needs to satisfy following condition: (1) the surface of the base layer is smooth and clean, the base layer is fully dried, and the phenomena of sanding, hollowing and the like are avoided; (2) the surface of the base layer cannot have defects such as floating slurry, holes and the like, and if the defects exist, the base layer is required to be repaired and leveled; (3) the surface of the base layer has no open water or seepage points, and the base layer is firm and compact and has the water content of below 80 percent; (4) the slope of the internal and external corners in each construction surface is well found, and the construction surface is flat, continuous and has no missing.
Base layer treatment: the method comprises the following steps of treating a base surface constructed on the same day, wherein the base surface is firm, loose, sand-forming and uneven, the base surface is required to be clean and can be wet, but clear water, oil stain, sundries and other materials which can damage a waterproof layer cannot be obtained, when the surface of the base layer is obviously uneven, cement mortar is used for leveling, whether cracks exist at the positive and negative corners is checked, crack filling treatment is carried out, whether improper protrusions exist on the surface of the base layer is checked, the improper protrusions are eliminated, whether sand-forming, peeling and weathering phenomena exist in the base layer or not is checked for the winter and old roofs, and if yes, the base layer is reinforced, so that the phenomena of poor bonding and film breakage caused after construction are avoided;
detail node processing: for waterproof weak positions such as internal and external corners, post-cast strips, pre-buried pipeline openings, water stop bolt spaces, drainage ditches and the like in the construction process, surface leveling and strengthening treatment is firstly carried out according to the actual situation on site, and if arcs are carried out at the internal and external corners or slope finding treatment is carried out at 45 degrees, additional layer treatment is carried out on the same material, so that the perfect waterproof effect is achieved.
Large-area spraying construction: after the base layer and the nodes are treated and the experience is collected, large-area spraying construction can be carried out, the water-based rubber asphalt emulsion and the demulsifier are fully stirred before spraying operation, a spray gun is preferably perpendicular to the base layer to be sprayed during spraying operation, the distance is moderate, the spray gun is preferably moved at a constant speed, and the cross spraying is carried out to the thickness required by the design according to the integral continuous operation after the detailed construction for once and many times;
and (3) maintaining and drying the coating: the coating must reach corresponding adhesive strength and tensile strength after 4h is dried, need protect the finished product, waterproof finished product after the completion, organize as early as possible and accept, after the inspection is qualified, must fill in hidden record, the record is accepted to the quality, and deliver follow-up protective layer construction, in order to prevent the waterproof layer damage, other construction teams must not damage the waterproof layer when construction operation, in particular, need avoid the damage of shovel, the iron bucket, hopper car etc. to the waterproof layer, when damage damages the waterproof layer condition, in time inform waterproof teams, in time, repair and done visa and repair record, in order to avoid causing the seepage hidden danger.
When the base course is checked and accepted, floating ash, pine animals, various oil stains, wall-penetrating steel wires and steel bar sharp protrusions of the base course are removed, the surface of concrete and exposed steel bar heads are polished to be flat, and the concrete is required to be clean, dustless and free of clear water.
When the base surface is damaged or loose or the base surface has pits and depressions and gaps larger than 3mm, the base surface is leveled by 1:2.5 common cement mortar.
In conclusion, the spraying rubber asphalt waterproof coating is a two-component material, the first component is water-based rubber asphalt emulsion, the second component is a demulsifier, the material spraying construction adopts matched airless continuous spraying equipment, the two components run to respective spray guns through different pipelines under the push of a power system, two gun mouths incline inwards during spraying, the material is sprayed out to form an atomized state instantly, and the two components are fully mixed before and when reaching a base surface, so that a uniform rubber asphalt coating film is formed. The coating has the functions of energy conservation, environmental protection, quick spraying and instant curing film forming, has perfect bonding effect, has strong elasticity, and has the advantages of good puncture resistance, aging resistance, self-sealing and self-healing property and overall seamless property; the difficult problem of leakage at the connection positions of internal and external corners, gaps and irregular structures is solved fundamentally; after the coating is cured into a film, the high elasticity and aging resistance of the rubber material are maintained, and the coating has the advantages of no water channeling, chemical corrosion resistance, high temperature resistance, freezing resistance, cracking resistance, self-extinguishing flame retardance, sound insulation, noise reduction, no toxicity, no peculiar smell, no environmental pollution and the like.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (10)

1. The ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof coating is characterized by comprising an aqueous rubber asphalt emulsion and a demulsifier, wherein the volume ratio of the aqueous rubber asphalt emulsion to the demulsifier is 1-2: 1, wherein,
the water-based rubber asphalt emulsion is prepared from the following raw materials in parts by weight: the composition comprises the following substances in parts by mass: 40-70 parts of liquid rubber asphalt mastic emulsion, 3-10 parts of pH regulator, 4-22 parts of interface modifier, 2-8 parts of ultraviolet resistant agent, 0.1-0.7 part of antioxidant, 7-12 parts of epoxy resin and 1-20 parts of water-based spray coating;
the spraying capacity ratio of the water-based spray paint to the liquid rubber asphalt mastic emulsion is 2: 15-1: 3.5;
2. the ultra-low temperature flame-retardant quick-setting spray coating rubber asphalt waterproof coating material as claimed in claim 1, wherein the liquid rubber asphalt mastic emulsion comprises the following raw materials in parts by mass:
53-79 parts of rubber latex with the solid content of 55-70%, 20-40 parts of asphalt emulsion with the solid content of 45-50%, 0.5-2 parts of carbon black, 2-3 parts of fine powder, 1-2 parts of anionic dispersant, 1-1.2 parts of anionic surfactant and 0.001-0.003 part of stabilizer.
3. The ultra-low temperature flame retardant quick setting spray coating rubberized asphalt waterproofing paint according to claim 2, wherein the fine powder comprises at least one of: porcelain powder, heavy calcium powder and light calcium powder; the anionic dispersant is an acrylate high-molecular dispersant; the anionic surfactant includes at least one of: soap, alkylbenzene sulfonate, alkylsulfonate ester salt, alkylsulfonate, alkylsulfate, fluorine-containing fatty acid salt, polysiloxane, fatty alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate, alpha-olefin sulfonate, fatty alcohol polyoxyethylene ether phosphate, alkylolamide, alkylsulfoacetamide, alkylsulfosuccinate sulfonate, alkylolamine alkylbenzene sulfonate, naphthenate, alkylphenol sulfonate, polyoxyethylene monolaurate; the stabilizer includes at least one of: soluble chloride salts, sulfates, nitrates, phosphates, silicates.
4. The ultra-low temperature flame-retardant quick-setting spray coating rubber asphalt waterproof coating as claimed in claim 1, wherein the water-based spray coating comprises the following raw materials in parts by mass:
90-99.6 parts of calcium chloride, 0.3-3 parts of sodium chloride, 0.2-4 parts of composite aluminum-iron polymer and the balance of water, wherein the ratio of the total amount of the calcium chloride, the sodium chloride and the composite aluminum-iron polymer to the water is 1: 9.
5. the low-temperature flame-retardant quick-setting spray coating rubber asphalt waterproof coating material according to claim 1, wherein the demulsifier is an acidic demulsifier, and the acidic demulsifier comprises the following raw materials in parts by mass; 20-30 parts of calcium chloride, 2-6 parts of phosphono-glycolic acid and 70-95 parts of water.
6. The low temperature flame retardant quick setting spray rubberized asphalt waterproofing coating according to claim 1, wherein the pH adjusting agent comprises at least one of: hydrochloric acid, sulfuric acid, glacial acetic acid, citric acid, fatty acids, salicylic acid, sodium hydroxide, potassium hydroxide, sodium carbonate, and sodium bicarbonate; the interface modifier is prepared by mixing the following raw materials in parts by weight: 0.5-2 parts of polyoxyethylene ether, 0.2-1 part of alkylamine and 2-4 parts of polycarboxylic acid type high molecular surfactant; the anti-ultraviolet agent is a hindered phenol antioxidant; the antioxidant comprises at least one of: sodium sulfite, sodium metabisulfite, dibutyl phenol, sodium bisulfite, sodium thiosulfate and tert-butyl p-hydroxyanisole.
7. A construction method of a low-temperature flame-retardant quick-setting spray rubber asphalt waterproof coating is characterized by comprising the following steps: weighing raw materials according to a predetermined weight part, wherein the raw materials comprise: 40-70 parts of liquid rubber asphalt mastic emulsion, 3-10 parts of pH regulator, 4-22 parts of interface modifier, 2-8 parts of ultraviolet resistant agent, 0.1-0.7 part of antioxidant, 7-12 parts of epoxy resin and 1-20 parts of water-based spray coating, wherein the spraying capacity ratio of the water-based spray coating to the liquid rubber asphalt mastic emulsion is 2: 15-1: 3.5;
mixing and stirring the raw materials according to the weight parts and the spraying volume ratio to form a water-based rubber asphalt emulsion;
mixing the aqueous rubber asphalt emulsion with a pre-prepared demulsifier according to a volume ratio of 1-2: 1, running the paint to a spray gun of airless continuous spraying equipment through different pipelines to carry out spraying construction of the paint.
8. The method for applying the low-temperature flame-retardant quick-setting spray rubber asphalt waterproof coating material according to claim 7, wherein the preparation method of the liquid rubber asphalt mastic emulsion comprises the following steps:
weighing raw materials according to a predetermined mass part, wherein the raw materials comprise: 53-79 parts of rubber latex with the solid content of 55-70%, 20-40 parts of asphalt emulsion with the solid content of 45-50%, 0.5-2 parts of carbon black, 2-3 parts of fine powder, 1-2 parts of anionic dispersant, 1-1.2 parts of anionic surfactant and 0.001-0.003 part of stabilizer;
adding carbon black, fine powder, an anionic dispersant, an anionic surfactant and a stabilizer into the asphalt emulsion with the solid content of 45-50%, and fully and uniformly stirring to obtain a mixed raw material;
adding the rubber latex with the solid content of 55-70% into the mixed raw materials, and fully and uniformly stirring to obtain the liquid rubber asphalt latex.
9. The construction method of the low-temperature flame-retardant quick-setting spray rubber asphalt waterproof coating according to claim 7, wherein the demulsifier is prepared by mixing the following raw materials in parts by weight: 20-30 parts of calcium chloride, 2-6 parts of phosphono-glycolic acid and 70-95 parts of water.
10. The construction method of the warm flame retardant quick setting spray coating rubberized asphalt waterproofing paint according to claim 7,
further comprising:
before spraying construction, preprocessing a base layer to be sprayed;
after the spraying construction, maintaining the sprayed base layer;
wherein the pre-treatment comprises at least one of:
cleaning the base layer; drying the base layer; leveling the base layer; carrying out crack filling treatment on the base layer; reinforcing the base layer; and flattening and strengthening the surface of the base layer.
CN202210000959.XA 2022-01-04 2022-01-04 Ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof paint and construction method thereof Pending CN114213908A (en)

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Application publication date: 20220322