CN114204068B - Integrated reversible hydrogen fuel cell high pressure sealing element - Google Patents
Integrated reversible hydrogen fuel cell high pressure sealing element Download PDFInfo
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- CN114204068B CN114204068B CN202111346565.1A CN202111346565A CN114204068B CN 114204068 B CN114204068 B CN 114204068B CN 202111346565 A CN202111346565 A CN 202111346565A CN 114204068 B CN114204068 B CN 114204068B
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- 238000007789 sealing Methods 0.000 title claims abstract 50
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract 14
- 239000001257 hydrogen Substances 0.000 title claims abstract 14
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract 14
- 239000000446 fuel Substances 0.000 title claims abstract 12
- 230000002441 reversible effect Effects 0.000 title claims abstract 6
- 239000002131 composite material Substances 0.000 claims abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 8
- 239000001301 oxygen Substances 0.000 claims 8
- 229910052760 oxygen Inorganic materials 0.000 claims 8
- 239000012528 membrane Substances 0.000 claims 3
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 238000001746 injection moulding Methods 0.000 claims 1
- 230000006835 compression Effects 0.000 abstract 1
- 238000007906 compression Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000000630 rising effect Effects 0.000 abstract 1
- 239000003566 sealing material Substances 0.000 abstract 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/0276—Sealing means characterised by their form
- H01M8/0278—O-rings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Abstract
Description
技术领域Technical Field
本发明涉及可逆氢燃料电池技术领域和电解池技术领域,具体涉及一体式可逆氢燃料电池高压密封元件。The present invention relates to the technical fields of reversible hydrogen fuel cells and electrolytic cells, and in particular to an integrated reversible hydrogen fuel cell high-pressure sealing element.
背景技术Background technique
一体式可逆氢燃料电池是一种将燃料电池(FC)发电过程和电解水(WE)过程集合于同一装置内运行的电化学装置,实现电能到化学能的可逆可控转换;以其极高的能量密度和较低的空间成本,在航空航天、无人机、潜艇等空间动力领域具有巨大的应用前景。一体式可逆氢燃料电池需实现燃料电池(FC)和电解池(WE)两种工作模式:在FC模式,分别通入H2和O2发生化合反应生成水,并向外输出电能;在WE模式,在外加电源的加载下,通入去离子水,发生水电解反应,同时析出H2和O2。An integrated reversible hydrogen fuel cell is an electrochemical device that integrates the fuel cell (FC) power generation process and the water electrolysis (WE) process in the same device to achieve reversible and controllable conversion of electrical energy to chemical energy. With its extremely high energy density and low space cost, it has great application prospects in aerospace, drones, submarines and other space power fields. An integrated reversible hydrogen fuel cell needs to realize two working modes: fuel cell (FC) and electrolyzer (WE). In the FC mode, H2 and O2 are introduced to react to generate water and output electrical energy. In the WE mode, deionized water is introduced under the load of an external power source to generate water electrolysis reaction and precipitate H2 and O2 at the same time.
在WE模式下,通过电池密封结构优化,电解生成的氢气和氧气可达到几十兆帕,可避免额外气体增压设备对系统空间、成本和能量转化效率的影响。因此,一体式可逆氢燃料电池内部产生的高压气体对系统的密封性能提出了极高的要求:如果系统密封性能不足,发生高压气体泄漏现象,则系统效率、紧凑性和安全性都会发生显著下降。因此,密封性能是制约一体式可逆氢燃料电池工作性能的重要因素。In WE mode, the hydrogen and oxygen generated by electrolysis can reach tens of MPa through optimization of the battery sealing structure, which can avoid the impact of additional gas boosting equipment on system space, cost and energy conversion efficiency. Therefore, the high-pressure gas generated inside the integrated reversible hydrogen fuel cell places extremely high demands on the sealing performance of the system: if the system sealing performance is insufficient and high-pressure gas leakage occurs, the system efficiency, compactness and safety will be significantly reduced. Therefore, sealing performance is an important factor restricting the working performance of the integrated reversible hydrogen fuel cell.
对于密封问题,现在普遍采用的方法是在双极板上粘贴用来密封的橡胶圈,然后通过对电堆施加一定的压力来压缩橡胶圈。压缩后的橡胶圈能够隔离各个气体通道和电池外部,从而达到密封的目的。现有技术中,存在一种在矩形密封圈的底部添加阶梯形基底的密封元件构型设计方案,该方案利用底部阶梯形基底与密封槽的配合,避免了密封圈在压缩过程中的滑移,但是基于矩形密封圈的设计思路使得接触压强随装配力提升而提升的速度较慢,无法满足一体式可逆氢燃料电池WE模式下对高压气体的密封要求;又例如,现有技术中,存在一种利用锯齿形结构实现啮合密封的设计方案,该方案利用膜电极边框两侧密封圈的啮合现象,避免了密封结构的滑移,但是随着压缩过程中边框的变形,密封圈和边框间的接触应力分布会逐渐向矩形密封圈接近,与上一方案缺点相似;又例如,现有技术中存在一种矩形密封圈和单峰或多峰结构组合的密封设计方案,该方案能够方便地在密封圈和膜电极边框间产生高接触压强区域,但是随着气压的上升,接触压强会逐渐下降,这种趋势的存在使得该方案不是解决高压密封的长久之计;又例如,现有技术中,存在直接使用O形圈作为密封元件的设计方案,O形圈能够方便地在密封圈和膜电极边框间产生高接触压强区域,是压力容器的常用密封元件,但是燃料电池的密封结构是独特的双层相对密封结构,采用包括O形圈正对放置压缩在内的凸起与凸起相对压缩的密封结构很容易发生错位,进而使密封失效,两O形圈偏置的方案又极易使得基于冲压极板的燃料电池和一体式可逆氢燃料电池极板上的脊被压溃,因此O形圈的密封形式不适用于基于冲压极板的燃料电池或一体式可逆氢燃料电池。For the sealing problem, the commonly used method now is to stick a rubber ring for sealing on the bipolar plate, and then compress the rubber ring by applying a certain pressure to the battery stack. The compressed rubber ring can isolate each gas channel and the outside of the battery, thereby achieving the purpose of sealing. In the prior art, there is a sealing element configuration design scheme that adds a stepped base at the bottom of the rectangular sealing ring. This scheme uses the cooperation of the bottom stepped base and the sealing groove to avoid the slippage of the sealing ring during the compression process. However, based on the design concept of the rectangular sealing ring, the contact pressure increases slowly with the increase of the assembly force, which cannot meet the sealing requirements of the high-pressure gas in the WE mode of the integrated reversible hydrogen fuel cell; for another example, in the prior art, there is a design scheme that uses a serrated structure to achieve meshing sealing. This scheme uses the meshing phenomenon of the sealing rings on both sides of the membrane electrode frame to avoid the slippage of the sealing structure, but with the deformation of the frame during the compression process, the contact stress distribution between the sealing ring and the frame will gradually approach that of the rectangular sealing ring, which is similar to the shortcomings of the previous scheme; for another example, there is a sealing design scheme in the prior art that combines a rectangular sealing ring with a single-peak or multi-peak structure. This scheme can It is easy to generate a high contact pressure area between the sealing ring and the membrane electrode frame, but as the air pressure rises, the contact pressure will gradually decrease. The existence of this trend makes this solution not a long-term solution to high-pressure sealing. For example, in the prior art, there is a design scheme that directly uses O-rings as sealing elements. O-rings can easily generate high contact pressure areas between the sealing ring and the membrane electrode frame, and are commonly used sealing elements for pressure vessels. However, the sealing structure of fuel cells is a unique double-layer relative sealing structure. The sealing structure in which protrusions and protrusions are relatively compressed, including O-rings placed opposite to each other, is prone to misalignment, which in turn causes the seal to fail. The offset scheme of the two O-rings can easily cause the ridges on the plates of fuel cells based on stamped plates and integrated reversible hydrogen fuel cells to be crushed. Therefore, the sealing form of the O-ring is not suitable for fuel cells based on stamped plates or integrated reversible hydrogen fuel cells.
综合已有技术可知,O形圈和矩形截面密封圈是常用于压力容器密封的两种重要密封结构。其中,O形圈自紧效果好,和其他的密封结构相比,更容易达到更高的压缩率和更高的接触压强,但是实际密封接触面很窄,实际密封效果严重依赖较高的加工装配精度。矩形截面密封圈能够形成更大宽度的密封接触面,对加工装配误差的敏感性更弱,密封结构更稳定,但是不具备自紧功能,并且为了得到较高接触应力,不得不使用很大的装配力,提高了装配难度,降低了结构稳定性。矩形密封结构具有良好的稳定性,但是矩形密封结构会导致密封结构的内部应力过大,使得密封结构失效。O形圈具有良好的密封性能,但是在安装过程中容易发生错位。Based on the existing technologies, O-rings and rectangular cross-section sealing rings are two important sealing structures commonly used for pressure vessel sealing. Among them, O-rings have good self-tightening effects, and compared with other sealing structures, they are easier to achieve higher compression rates and higher contact pressures, but the actual sealing contact surface is very narrow, and the actual sealing effect is heavily dependent on high processing and assembly accuracy. Rectangular cross-section sealing rings can form a wider sealing contact surface, are less sensitive to processing and assembly errors, and have a more stable sealing structure, but do not have a self-tightening function, and in order to obtain higher contact stress, a large assembly force has to be used, which increases the difficulty of assembly and reduces structural stability. The rectangular sealing structure has good stability, but the rectangular sealing structure will cause excessive internal stress in the sealing structure, causing the sealing structure to fail. The O-ring has good sealing performance, but it is prone to misalignment during installation.
发明内容Summary of the invention
本发明的目的就是为了解决在使用过程中密封材料压缩应力过大、存在制造装配误差时密封圈容易发生错位以及密封接触压力随气体压强上升而减小的问题,而提供一种一体式可逆氢燃料电池高压密封元件,显著提升燃料电池密封性能。The purpose of the present invention is to solve the problems of excessive compressive stress of the sealing material during use, easy misalignment of the sealing ring when there are manufacturing and assembly errors, and decreased sealing contact pressure as the gas pressure increases, and to provide an integrated reversible hydrogen fuel cell high-pressure sealing element to significantly improve the sealing performance of the fuel cell.
本发明的目的通过以下技术方案实现:一体式可逆氢燃料电池高压密封元件,该密封元件为m个矩形密封结构和n个O形密封结构间隔排布且一体成型的复合密封结构,其中m≥1,n≥1,m+n为奇数。The purpose of the present invention is achieved through the following technical solution: an integrated reversible hydrogen fuel cell high-pressure sealing element, which is a composite sealing structure in which m rectangular sealing structures and n O-shaped sealing structures are arranged at intervals and formed in one piece, wherein m≥1, n≥1, and m+n is an odd number.
优选地,所述的燃料电池的膜电极边框(6)两侧设有相对的密封元件:氧气侧密封圈(1)和氢气侧密封圈(2),氢气侧密封圈(2)位于氢气反应区外轮廓线上,氧气侧密封圈(1)位于氧气反应区外轮廓线上。Preferably, opposite sealing elements are provided on both sides of the membrane electrode frame (6) of the fuel cell: an oxygen side sealing ring (1) and a hydrogen side sealing ring (2), the hydrogen side sealing ring (2) is located on the outer contour line of the hydrogen reaction zone, and the oxygen side sealing ring (1) is located on the outer contour line of the oxygen reaction zone.
优选地,所述的氧气侧密封圈(1)直接面向燃料电池内部高压氧气的一层为矩形密封结构(14)。Preferably, a layer of the oxygen-side sealing ring (1) directly facing the high-pressure oxygen inside the fuel cell is a rectangular sealing structure (14).
优选地,所述的氢气侧密封圈(2)直接面向燃料电池内部高压氢气的一层为O形密封结构(21)。Preferably, a layer of the hydrogen side sealing ring (2) directly facing the high-pressure hydrogen inside the fuel cell is an O-shaped sealing structure (21).
优选地,所述的氧气侧密封圈(1)包括两个以上矩形密封结构层;Preferably, the oxygen side sealing ring (1) comprises two or more rectangular sealing structure layers;
优选地,所述的氢气侧密封圈(2)包括两个以上O形密封结构层。Preferably, the hydrogen side sealing ring (2) comprises more than two O-shaped sealing structure layers.
优选地,所述的O形密封结构的截面形状为圆形、椭圆形、正多边形、圆角多边形或花瓣形;Preferably, the cross-sectional shape of the O-shaped sealing structure is circular, elliptical, regular polygonal, rounded polygonal or petal-shaped;
优选地,所述矩形密封结构的截面形状为正方形、长方形、圆角矩形、梯形、马鞍形或波浪矩形。Preferably, the cross-sectional shape of the rectangular sealing structure is a square, a rectangle, a rounded rectangle, a trapezoid, a saddle shape or a wavy rectangle.
优选地,所述的氢气侧密封圈(2)的每一个O形密封结构层与氧气侧密封结构(1)的每一个矩形密封结构层间隔膜电极边框6相对;Preferably, each O-shaped sealing structure layer of the hydrogen side sealing ring (2) is opposite to each rectangular sealing structure layer of the oxygen side sealing structure (1) through the membrane electrode frame 6;
优选地,所述氧气侧密封结构(1)的每一个O形密封结构层与氢气侧密封结构(2)的每一个矩形密封结构层间隔膜电极边框(6)相对。Preferably, each O-shaped sealing structure layer of the oxygen side sealing structure (1) and each rectangular sealing structure layer of the hydrogen side sealing structure (2) are opposite to each other via a membrane electrode frame (6).
优选地,相同一侧的密封元件的所有矩形密封结构和O形密封结构截面的形心位于同一高度。Preferably, the centroids of the cross sections of all the rectangular sealing structures and O-shaped sealing structures of the sealing element on the same side are located at the same height.
优选地,相同一侧的密封元件中相邻矩形密封结构和O形密封结构之间通过薄层结构相连,薄层结构位于矩形密封结构和O形密封结构二者形心的连线上,薄层结构的形式可以为连续形结构,即连接蹼,或间断形结构,即连接桥。Preferably, adjacent rectangular sealing structures and O-shaped sealing structures in the sealing element on the same side are connected by a thin layer structure, and the thin layer structure is located on the line connecting the centroids of the rectangular sealing structure and the O-shaped sealing structure. The thin layer structure can be in the form of a continuous structure, i.e., a connecting web, or an intermittent structure, i.e., a connecting bridge.
优选地,所述的密封元件可通过注塑工艺成形的独立部件,或者直接注塑在燃料电池的极板密封槽道内。Preferably, the sealing element can be an independent component formed by an injection molding process, or can be directly injection molded into the sealing groove of the plate of the fuel cell.
与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:
本发明可解决现有技术中燃料电池、电解池、一体式可逆燃料电池的密封结构缺乏自紧功能和高压密封性能不足的技术问题;实施本发明的技术方案,通过O形圈和矩形密封结构的交错偏置排布,可实现提升燃料电池密封性能的技术效果,满足高压密封需要。The present invention can solve the technical problems in the prior art that the sealing structures of fuel cells, electrolytic cells, and integrated reversible fuel cells lack self-tightening function and insufficient high-pressure sealing performance; by implementing the technical solution of the present invention, the staggered and offset arrangement of O-rings and rectangular sealing structures can achieve the technical effect of improving the sealing performance of fuel cells and meet the high-pressure sealing requirements.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为采用最少单元的矩形密封结构和O形密封结构相结合的多层密封结构示意图;FIG1 is a schematic diagram of a multi-layer sealing structure using a rectangular sealing structure with the least number of units combined with an O-shaped sealing structure;
图2为采用最少单元的矩形密封结构和O形密封结构相结合的多层密封结构在燃料电池极板间安装方式的三维示意图;FIG2 is a three-dimensional schematic diagram of the installation method of a multi-layer sealing structure combining a rectangular sealing structure with a minimum number of units and an O-shaped sealing structure between fuel cell plates;
图3为图2的爆炸图;FIG3 is an exploded view of FIG2 ;
图4为矩形密封结构和O形密封结构连接处的二维示意图;FIG4 is a two-dimensional schematic diagram of the connection between the rectangular sealing structure and the O-shaped sealing structure;
图5为矩形密封结构和O形密封结构连接处的三维示意图;FIG5 is a three-dimensional schematic diagram of the connection between the rectangular sealing structure and the O-shaped sealing structure;
图6为矩形密封结构和O形密封结构连接处的另一三维示意图;FIG6 is another three-dimensional schematic diagram of the connection between the rectangular sealing structure and the O-shaped sealing structure;
图7为采用多个单元的矩形密封结构和O形圈相结合的多层密封结构示意图;FIG7 is a schematic diagram of a multi-layer sealing structure using a rectangular sealing structure of multiple units and an O-ring in combination;
图8为采用最少单元的矩形类异形密封结构和O形类异形密封结构相结合的多层密封结构示意图;FIG8 is a schematic diagram of a multi-layer sealing structure that combines a rectangular-like special-shaped sealing structure with a minimum number of units and an O-shaped special-shaped sealing structure;
图9为另一种采用最少单元的矩形类异形密封结构和O形类异形密封结构相结合的多层密封结构示意图;FIG9 is a schematic diagram of another multi-layer sealing structure using a combination of a rectangular-like special-shaped sealing structure with the least number of units and an O-shaped special-shaped sealing structure;
图10为采用最少单元的用极板上成形出的矩形脊替换矩形密封结构的多层O形密封结构示意图;FIG10 is a schematic diagram of a multi-layer O-ring seal structure using a minimum number of units and replacing a rectangular seal structure with a rectangular ridge formed on a plate;
在上述附图中,各图号标记分别表示:In the above drawings, the figure numbers represent:
1氧气侧密封圈,11氧气侧密封圈高压气体侧矩形密封结构,12氧气侧密封圈O形密封结构,13氧气侧密封圈薄层连接结构,14氧气侧密封圈外界侧矩形密封结构,2氢气侧密封圈,21氢气侧密封圈高压气体侧O形密封结构,22氢气侧密封圈薄层连接结构,23氢气侧密封圈矩形密封结构,24氢气侧密封圈外界侧O形密封结构,3氧极板,4氢极板,5膜电极,6膜电极边框。1 oxygen side sealing ring, 11 oxygen side sealing ring high pressure gas side rectangular sealing structure, 12 oxygen side sealing ring O-shaped sealing structure, 13 oxygen side sealing ring thin layer connection structure, 14 oxygen side sealing ring external side rectangular sealing structure, 2 hydrogen side sealing ring, 21 hydrogen side sealing ring high pressure gas side O-shaped sealing structure, 22 hydrogen side sealing ring thin layer connection structure, 23 hydrogen side sealing ring rectangular sealing structure, 24 hydrogen side sealing ring external side O-shaped sealing structure, 3 oxygen electrode plate, 4 hydrogen electrode plate, 5 membrane electrode, 6 membrane electrode frame.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的目的、技术方案及优点进行进一步详细说明。应当理解,此处所描述的具体实施例仅是本发明的一部分实施例,并不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will further describe the purpose, technical solutions and advantages of the embodiments of the present invention in conjunction with the drawings in the embodiments of the present invention. It should be understood that the specific embodiments described herein are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
实施例1Example 1
一体式可逆氢燃料电池用高压密封元件,包括氢气侧密封圈和氧气侧密封圈;氢气侧密封圈采用矩形结构和O形结构间隔排布的奇数层复合密封结构,氧气侧密封圈采用O形结构和矩形结构间隔排布的奇数层复合密封结构。A high-pressure sealing element for an integrated reversible hydrogen fuel cell comprises a hydrogen side sealing ring and an oxygen side sealing ring; the hydrogen side sealing ring adopts an odd-numbered composite sealing structure in which a rectangular structure and an O-shaped structure are alternately arranged, and the oxygen side sealing ring adopts an odd-numbered composite sealing structure in which an O-shaped structure and a rectangular structure are alternately arranged.
如图1-6所示,在一个完整的一体式可逆燃料电池结构中包含有氧极板3、氢极板4、膜电极5和膜电极边框6,在氧极板3和膜电极边框6之间设有氧气侧密封圈1,氢极板4和膜电极边框6之间设有氢气侧密封圈2。在氢极板4、氧极板3和膜电极边框6之间设有氧气侧密封圈1和氢气侧密封圈2,从而保证良好的密封性能,减少燃料电池模式下氢气和氧气的泄漏以提高燃料电池的燃料利用率,减少电解池模式下产生的氢气和氧气的泄漏以提高一体式可逆燃料电池的循环效率。As shown in Fig. 1-6, a complete integrated reversible fuel cell structure includes an oxygen plate 3, a hydrogen plate 4, a membrane electrode 5 and a membrane electrode frame 6. An oxygen side sealing ring 1 is provided between the oxygen plate 3 and the membrane electrode frame 6, and a hydrogen side sealing ring 2 is provided between the hydrogen plate 4 and the membrane electrode frame 6. An oxygen side sealing ring 1 and a hydrogen side sealing ring 2 are provided between the hydrogen plate 4, the oxygen plate 3 and the membrane electrode frame 6 to ensure good sealing performance, reduce the leakage of hydrogen and oxygen in the fuel cell mode to improve the fuel utilization of the fuel cell, and reduce the leakage of hydrogen and oxygen generated in the electrolytic cell mode to improve the cycle efficiency of the integrated reversible fuel cell.
在一种优选的实施方式中,氢气侧密封圈采用矩形密封结构和O形密封结构间隔排布的奇数层复合密封结构。In a preferred embodiment, the hydrogen side sealing ring adopts an odd-numbered composite sealing structure in which rectangular sealing structures and O-shaped sealing structures are alternately arranged.
在本实施方式中,氢气侧密封圈2靠近膜电极6的一侧为反应腔室,与高压流体直接接触。氢气侧密封圈2最靠近与反应腔室的一侧的第一层密封圈为O形密封结构,相邻一层为矩形密封结构,其余各层密封圈为O形矩形间隔排布。O形结构密封圈位于相邻的两个矩形密封结构包围形成的间隙中,矩形密封结构的限位作用保证O形密封结构层不易发生错位。O形密封结构的直径略大于矩形密封结构的高度。在压缩过程中,O形密封结构首先被压缩,便于实现较大压缩率而产生较大接触压强。所有的矩形密封结构和O形密封结构的层数之和为奇数,保证密封结构的截面呈轴对称形式,便于设置三条密封胶线会聚处的密封圈布置形式。In this embodiment, the side of the hydrogen side sealing ring 2 close to the membrane electrode 6 is a reaction chamber, which is in direct contact with the high-pressure fluid. The first layer of sealing rings on the hydrogen side sealing ring 2 closest to the reaction chamber is an O-shaped sealing structure, the adjacent layer is a rectangular sealing structure, and the remaining layers of sealing rings are arranged in O-shaped rectangular intervals. The O-shaped structure sealing ring is located in the gap formed by the two adjacent rectangular sealing structures. The limiting effect of the rectangular sealing structure ensures that the O-shaped sealing structure layer is not easily misplaced. The diameter of the O-shaped sealing structure is slightly larger than the height of the rectangular sealing structure. During the compression process, the O-shaped sealing structure is compressed first, which is convenient for achieving a larger compression rate and generating a larger contact pressure. The sum of the number of layers of all rectangular sealing structures and O-shaped sealing structures is an odd number, which ensures that the cross-section of the sealing structure is axially symmetrical, which is convenient for setting the sealing ring arrangement at the convergence of the three sealing glue lines.
本发明密封元件由m个矩形密封结构和n个O形密封结构间隔排布且一体成型的复合密封结构,其中m≥1,n≥1,m+n为奇数。如图1所示,在一种优选的实施方式中,氢气侧密封圈2由一个矩形密封结构及其两侧的O形密封结构组成,即图1中依次设置的氢气侧密封圈高压气体侧O形密封结构21、氢气侧密封圈矩形密封结构23和氢气侧密封圈外界侧O形密封结构24,相邻密封结构间通过氢气侧密封圈薄层连接结构22相连。The sealing element of the present invention is a composite sealing structure in which m rectangular sealing structures and n O-shaped sealing structures are arranged at intervals and formed in one piece, wherein m≥1, n≥1, and m+n is an odd number. As shown in FIG1 , in a preferred embodiment, the hydrogen side sealing ring 2 is composed of a rectangular sealing structure and O-shaped sealing structures on both sides thereof, namely, the hydrogen side sealing ring high pressure gas side O-shaped sealing structure 21, the hydrogen side sealing ring rectangular sealing structure 23, and the hydrogen side sealing ring external side O-shaped sealing structure 24 arranged in sequence in FIG1 , and adjacent sealing structures are connected by a hydrogen side sealing ring thin layer connecting structure 22.
在一种优选的实施方式中,氧气侧密封圈采用矩形密封结构和O形密封结构间隔排布的奇数层复合密封结构。In a preferred embodiment, the oxygen side sealing ring adopts an odd-numbered composite sealing structure in which rectangular sealing structures and O-shaped sealing structures are alternately arranged.
在本实施方式中,氧气侧密封圈一侧为反应腔室,与高压流体直接接触。氧气侧密封圈最靠近与反应腔室的一侧的第一层密封圈为矩形密封结构,相邻一层为O形密封结构,其余各层密封圈为O形矩形间隔排布。O形密封结构位于相邻的两个矩形密封结构包围形成的间隙中,矩形密封结构的限位作用保证O形密封结构不易发生错位。O形密封结构的直径略大于矩形密封结构的高度。在压缩过程中,O形密封结构首先被压缩,便于实现较大压缩率而产生较大接触压强。所有的矩形截面密封圈和O形结构密封圈的层数之和为奇数,保证密封结构的截面呈轴对称形式,便于设置三条密封胶线会聚处的密封圈布置形式。In the present embodiment, one side of the oxygen side sealing ring is a reaction chamber, which is in direct contact with the high-pressure fluid. The first layer of sealing ring of the oxygen side sealing ring closest to the side of the reaction chamber is a rectangular sealing structure, the adjacent layer is an O-shaped sealing structure, and the remaining layers of sealing rings are arranged in O-shaped rectangular intervals. The O-shaped sealing structure is located in the gap formed by the two adjacent rectangular sealing structures, and the limiting effect of the rectangular sealing structure ensures that the O-shaped sealing structure is not easily misplaced. The diameter of the O-shaped sealing structure is slightly larger than the height of the rectangular sealing structure. During the compression process, the O-shaped sealing structure is compressed first, which is convenient for achieving a larger compression rate and generating a larger contact pressure. The sum of the number of layers of all rectangular cross-section sealing rings and O-shaped structure sealing rings is an odd number, which ensures that the cross-section of the sealing structure is axially symmetrical, which is convenient for setting the sealing ring arrangement at the convergence of the three sealing glue lines.
在一种优选的实施方式中,氧气侧密封圈1由2个矩形密封结构夹设一个O形密封结构组成,即图1中依次设置的氧气侧密封圈高压气体侧矩形密封结构11,氧气侧密封圈O形密封结构12,氧气侧密封圈外界侧矩形密封结构14,两两之间通过氧气侧密封圈薄层连接结构13相连。In a preferred embodiment, the oxygen side sealing ring 1 is composed of two rectangular sealing structures sandwiched by an O-shaped sealing structure, namely, the oxygen side sealing ring high-pressure gas side rectangular sealing structure 11, the oxygen side sealing ring O-shaped sealing structure 12, and the oxygen side sealing ring external side rectangular sealing structure 14 are arranged in sequence in Figure 1, and the two are connected by the oxygen side sealing ring thin layer connecting structure 13.
在本实施方式中,氢气侧密封圈的每一个O形密封结构都与氧气侧密封圈的矩形密封结构相对,氧气侧密封圈的每一个O形密封结构也都与氢气侧密封圈的矩形密封结构相对。进一步保证了O形密封结构在压缩时不易发生错位。In this embodiment, each O-shaped sealing structure of the hydrogen side sealing ring is opposite to the rectangular sealing structure of the oxygen side sealing ring, and each O-shaped sealing structure of the oxygen side sealing ring is also opposite to the rectangular sealing structure of the hydrogen side sealing ring, which further ensures that the O-shaped sealing structure is not easily misaligned during compression.
在本实施方式中,O形密封结构的直径略大于矩形密封结构的高度,O形密封结构的结构刚度小于矩形密封结构的结构刚度。可以通过对结构尺寸的合理设计,实现氢气侧和氧气侧密封结构与膜电极边框接触的一侧保持平整,保证膜电极边框6不会受到扭曲力的长时间作用而造成损害。In this embodiment, the diameter of the O-shaped sealing structure is slightly larger than the height of the rectangular sealing structure, and the structural rigidity of the O-shaped sealing structure is smaller than that of the rectangular sealing structure. By reasonably designing the structural dimensions, the sides of the hydrogen-side and oxygen-side sealing structures in contact with the membrane electrode frame can be kept flat, ensuring that the membrane electrode frame 6 will not be damaged by the long-term action of the twisting force.
在本实施方式中,氢气侧密封圈的各层O形矩形密封圈层可以通过水平方向对称轴附近的微小脚蹼结构相连接,保证密封结构的整体性,方便加工装配。脚蹼结构尺寸远小于O形密封结构的直径和矩形密封结构的高度,不会对密封结构的自紧能力和压缩后接触压强造成很大影响。In this embodiment, each layer of the O-shaped rectangular sealing ring of the hydrogen side sealing ring can be connected by a tiny flipper structure near the horizontal symmetry axis to ensure the integrity of the sealing structure and facilitate processing and assembly. The flipper structure size is much smaller than the diameter of the O-shaped sealing structure and the height of the rectangular sealing structure, and will not have a significant impact on the self-tightening ability of the sealing structure and the contact pressure after compression.
在本实施方式中,氢气侧密封圈的O形密封结构层数最小为2,与氧气侧密封圈的矩形密封结构层数相等。氢气侧密封圈的O形密封结构层数最大值不限,可以在考虑结构紧凑程度和密封性能两方面因素时自由设计层数。如图7所示为,氢气侧密封圈2由2个矩形密封结构与3个O形密封结构间隔组成,氧气侧密封圈1由3个矩形密封结构与2个O形密封结构组成,可以根据需要设置更多层。In this embodiment, the minimum number of O-shaped sealing structure layers of the hydrogen side sealing ring is 2, which is equal to the number of rectangular sealing structure layers of the oxygen side sealing ring. The maximum number of O-shaped sealing structure layers of the hydrogen side sealing ring is unlimited, and the number of layers can be freely designed when considering the compactness of the structure and the sealing performance. As shown in FIG7 , the hydrogen side sealing ring 2 is composed of 2 rectangular sealing structures and 3 O-shaped sealing structures, and the oxygen side sealing ring 1 is composed of 3 rectangular sealing structures and 2 O-shaped sealing structures, and more layers can be set as needed.
在本实施方式中,O形密封结构的截面形状可以为圆形、椭圆形、正多边形、圆角多边形及花瓣形等异形。如图8-9所示。In this embodiment, the cross-sectional shape of the O-shaped sealing structure can be a circle, an ellipse, a regular polygon, a rounded polygon, a petal shape, or other special shapes, as shown in FIGS. 8-9 .
在本实施方式中,矩形密封结构的截面形状可以为正方形、长方形、圆角矩形、梯形、马鞍形及波浪矩形等异形。In this embodiment, the cross-sectional shape of the rectangular sealing structure can be a square, a rectangle, a rounded rectangle, a trapezoid, a saddle shape, a wavy rectangle or other special shapes.
氧气侧密封圈和氢气侧密封圈采用O形密封结构和矩形密封结构间隔排布的奇数层复合密封结构。氧气侧和氢气侧采用的O形密封结构和矩形密封结构交错的多层密封结构,保证了氧气侧密封圈1和氧极板3、膜电极边框6之间具有良好的接触宽度、较大的接触压强、横截面良好的稳定性,以及显著的自紧性能;同时保证了氢气侧密封圈2和氧极板3、膜电极边框6之间的相同性质。本发明一体式可逆氢燃料电池新型高压密封结构合理利用O形圈的良好自紧功能和较大接触应力,采用O形密封结构和矩形截面密封结构交错分布既保证了膜电极边框6不会产生较大的内部应力,继而影响燃料电池的使用寿命。使得安装更加简易,在安装过程当中不容易发生错位,节约了安装的成本,保证了燃料电池的密封性,保证了燃料电池具有较长使用寿命和耐用性。The oxygen side sealing ring and the hydrogen side sealing ring adopt an odd-numbered composite sealing structure in which an O-shaped sealing structure and a rectangular sealing structure are arranged at intervals. The multi-layer sealing structure of the staggered O-shaped sealing structure and the rectangular sealing structure adopted by the oxygen side and the hydrogen side ensures that the oxygen side sealing ring 1 and the oxygen electrode plate 3 and the membrane electrode frame 6 have good contact width, large contact pressure, good cross-sectional stability, and significant self-tightening performance; at the same time, the same properties between the hydrogen side sealing ring 2 and the oxygen electrode plate 3 and the membrane electrode frame 6 are ensured. The new high-pressure sealing structure of the integrated reversible hydrogen fuel cell of the present invention rationally utilizes the good self-tightening function and large contact stress of the O-ring, and adopts the staggered distribution of the O-shaped sealing structure and the rectangular cross-section sealing structure to ensure that the membrane electrode frame 6 will not generate large internal stress, thereby affecting the service life of the fuel cell. It makes the installation easier, and it is not easy to be misaligned during the installation process, which saves the installation cost, ensures the sealing of the fuel cell, and ensures that the fuel cell has a long service life and durability.
实施例2Example 2
一种一体式可逆氢燃料电池新型高压密封结构,包括氢气侧密封圈和氧气侧密封圈;氢气侧密封圈采用极板矩形凸起和O形密封元件间隔排布的奇数层复合密封结构,氧气侧密封圈采用O形结构和极板矩形凸起间隔排布的奇数层复合密封结构。A new type of high-pressure sealing structure for an integrated reversible hydrogen fuel cell comprises a hydrogen side sealing ring and an oxygen side sealing ring; the hydrogen side sealing ring adopts an odd-numbered composite sealing structure in which rectangular protrusions of a plate and O-shaped sealing elements are arranged at intervals, and the oxygen side sealing ring adopts an odd-numbered composite sealing structure in which O-shaped structures and rectangular protrusions of a plate are arranged at intervals.
在一个完整的一体式可逆燃料电池结构中包含有氧极板3、氢极板4、膜电极5和膜电极边框6,在氧极板3和膜电极边框6之间设有氧气侧密封结构1,氢极板4和膜电极边框6之间设有氢气侧密封结构2。在氢极板4、氧极板3和膜电极边框6之间设有氧气侧密封结构1和氢气侧密封结构2可以保证膜电极5的良好的密封性能。A complete integrated reversible fuel cell structure includes an oxygen plate 3, a hydrogen plate 4, a membrane electrode 5 and a membrane electrode frame 6. An oxygen side sealing structure 1 is provided between the oxygen plate 3 and the membrane electrode frame 6, and a hydrogen side sealing structure 2 is provided between the hydrogen plate 4 and the membrane electrode frame 6. The oxygen side sealing structure 1 and the hydrogen side sealing structure 2 are provided between the hydrogen plate 4, the oxygen plate 3 and the membrane electrode frame 6 to ensure good sealing performance of the membrane electrode 5.
在一种优选的实施方式中,氢气侧密封圈采用极板矩形凸起和O形密封元件间隔排布的奇数层复合密封结构。如图10所示。In a preferred embodiment, the hydrogen side sealing ring adopts an odd-numbered composite sealing structure in which rectangular protrusions of the electrode plate and O-shaped sealing elements are arranged at intervals, as shown in FIG10 .
在本实施方式中,氢气侧密封圈一侧为反应腔室,与高压流体直接接触。氢气侧密封圈最靠近与反应腔室的一侧的第一层密封结构为O形密封结构,相邻一层为极板矩形凸起,其余各层密封圈为O形结构密封圈和极板矩形凸起间隔排布。O形结构密封圈位于相邻的两个极板矩形凸起包围形成的矩形密封槽间隙中,密封槽的限位作用保证O形结构密封圈不易发生错位。O形结构密封圈的直径略大于极板矩形凸起的高度。在压缩过程中,O形结构密封圈首先被压缩,便于实现较大压缩率而产生较大接触压强。所有的极板矩形凸起和O形结构密封圈的层数之和为奇数,保证密封结构的截面呈轴对称形式,便于设置三条密封胶线会聚处的密封圈布置形式。In this embodiment, one side of the hydrogen side sealing ring is a reaction chamber, which is in direct contact with the high-pressure fluid. The first layer of sealing structure of the hydrogen side sealing ring closest to the side of the reaction chamber is an O-shaped sealing structure, the adjacent layer is a rectangular protrusion of the pole plate, and the remaining layers of sealing rings are O-shaped structure sealing rings and rectangular protrusions of the pole plate arranged at intervals. The O-shaped structure sealing ring is located in the gap of the rectangular sealing groove formed by the two adjacent rectangular protrusions of the pole plate. The limiting effect of the sealing groove ensures that the O-shaped structure sealing ring is not easy to be misplaced. The diameter of the O-shaped structure sealing ring is slightly larger than the height of the rectangular protrusion of the pole plate. During the compression process, the O-shaped structure sealing ring is compressed first, which is convenient for achieving a larger compression rate and generating a larger contact pressure. The sum of the number of layers of all the rectangular protrusions of the pole plate and the O-shaped structure sealing ring is an odd number, which ensures that the cross-section of the sealing structure is axially symmetrical, which is convenient for setting the sealing ring arrangement at the convergence of the three sealing glue lines.
在一种优选的实施方式中,氧气侧密封圈采用极板矩形凸起和O形密封元件间隔排布的奇数层复合密封结构。In a preferred embodiment, the oxygen side sealing ring adopts an odd-numbered composite sealing structure in which rectangular protrusions of the electrode plates and O-shaped sealing elements are arranged at intervals.
在本实施方式中,氧气侧密封结构一侧为反应腔室,与高压流体直接接触。氢气侧密封结构最靠近与反应腔室的一侧的第一层密封结构为极板矩形凸起,相邻一层为O形密封元件,其余各层密封圈为O形密封元件和极板矩形凸起间隔排布。O形密封元件位于相邻的两个极板矩形凸起包围形成的矩形密封槽间隙中,密封槽的限位作用保证O形结构密封圈不易发生错位。O形结构密封圈的直径略大于极板矩形凸起的高度。在压缩过程中,O形结构密封圈首先被压缩,便于实现较大压缩率而产生较大接触压强。所有的极板矩形凸起和O形结构密封圈的层数之和为奇数,保证密封结构的截面呈轴对称形式,便于设置三条密封胶线会聚处的密封圈布置形式。In this embodiment, one side of the oxygen side sealing structure is a reaction chamber, which is in direct contact with the high-pressure fluid. The first layer of sealing structure of the hydrogen side sealing structure closest to the side of the reaction chamber is a rectangular protrusion of the electrode plate, and the adjacent layer is an O-shaped sealing element. The remaining layers of sealing rings are arranged in intervals between the O-shaped sealing elements and the rectangular protrusions of the electrode plates. The O-shaped sealing element is located in the gap of the rectangular sealing groove formed by the two adjacent rectangular protrusions of the electrode plates. The limiting effect of the sealing groove ensures that the O-shaped structure sealing ring is not easily misplaced. The diameter of the O-shaped structure sealing ring is slightly larger than the height of the rectangular protrusion of the electrode plate. During the compression process, the O-shaped structure sealing ring is compressed first, which is convenient for achieving a larger compression rate and generating a larger contact pressure. The sum of the number of layers of all the rectangular protrusions of the electrode plates and the O-shaped structure sealing rings is an odd number, which ensures that the cross-section of the sealing structure is axially symmetrical, which is convenient for setting the sealing ring arrangement at the convergence of the three sealing glue lines.
在本实施方式中,氢气侧密封结构的每一个O形结构层都与氧气侧密封结构的极板矩形凸起相对,氧气侧密封结构的每一个O形结构层也都与氢气侧密封圈的极板矩形凸起相对。进一步保证了O形结构密封圈在压缩时不易发生错位。In this embodiment, each O-shaped structural layer of the hydrogen side sealing structure is opposite to the rectangular protrusion of the electrode plate of the oxygen side sealing structure, and each O-shaped structural layer of the oxygen side sealing structure is also opposite to the rectangular protrusion of the electrode plate of the hydrogen side sealing ring, which further ensures that the O-shaped structural sealing ring is not easily misaligned during compression.
在本实施方式中,O形结构密封圈的直径略大于极板矩形凸起的高度,O形结构密封圈的结构刚度小于极板矩形凸起的刚度。可以通过对结构尺寸的合理设计,实现氢气侧和氧气侧密封结构与膜电极边框接触的一侧保持平整,保证膜电极边框6不会受到扭曲力的长时间作用而造成损害。In this embodiment, the diameter of the O-shaped structure sealing ring is slightly larger than the height of the rectangular protrusion of the electrode plate, and the structural rigidity of the O-shaped structure sealing ring is smaller than the rigidity of the rectangular protrusion of the electrode plate. By reasonably designing the structural dimensions, the side of the hydrogen side and oxygen side sealing structures in contact with the membrane electrode frame can be kept flat, ensuring that the membrane electrode frame 6 will not be damaged by the long-term action of the twisting force.
在本实施方式中,氢气侧密封圈的O形结构密封圈层数最小为2,与氧气侧密封圈的极板矩形凸起层数相等。氢气侧密封圈的O形结构密封圈层数最大值不限,可以在考虑结构紧凑程度和密封性能两方面因素时自由设计层数。In this embodiment, the minimum number of O-shaped sealing ring layers of the hydrogen side sealing ring is 2, which is equal to the number of rectangular protrusion layers of the electrode plate of the oxygen side sealing ring. The maximum number of O-shaped sealing ring layers of the hydrogen side sealing ring is not limited, and the number of layers can be freely designed by considering the factors of structural compactness and sealing performance.
在本实施方式中,O形结构密封圈的截面形状可以采用椭圆形、正圆形、正多边形及异形结构。In this embodiment, the cross-sectional shape of the O-shaped sealing ring can be an ellipse, a regular circle, a regular polygon or a special-shaped structure.
在本实施方式中,极板矩形凸起的截面形状可以采用正方形、长方形、马鞍形及异形结构。In this embodiment, the cross-sectional shape of the rectangular protrusion of the electrode plate can be a square, a rectangle, a saddle shape or a special-shaped structure.
本实施方式除具有与实施例1相同的优点外,有一个额外的缺点:极板矩形凸起受到较高接触压强作用后会坍塌。因此使用该实施例之前应对极板强度进行合理校核,或者将本实施例应用于较低压的工况下。In addition to the same advantages as Example 1, this embodiment has an additional disadvantage: the rectangular protrusions of the plate will collapse when subjected to a higher contact pressure. Therefore, the strength of the plate should be properly checked before using this embodiment, or this embodiment should be applied to a lower pressure condition.
需要指出的是,以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。It should be pointed out that the above is only a preferred embodiment of the present invention and is not intended to limit the present invention. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention should be included in the protection scope of the present invention.
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